RS51276B - ENVIRONMENTALLY FREE OIL ENGINE - Google Patents
ENVIRONMENTALLY FREE OIL ENGINEInfo
- Publication number
- RS51276B RS51276B YUP-1041/04A YUP104104A RS51276B RS 51276 B RS51276 B RS 51276B YU P104104 A YUP104104 A YU P104104A RS 51276 B RS51276 B RS 51276B
- Authority
- RS
- Serbia
- Prior art keywords
- vol
- components
- type
- iob
- kpa
- Prior art date
Links
Landscapes
- Gas Separation By Absorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fuel Cell (AREA)
- Hybrid Cells (AREA)
- Inert Electrodes (AREA)
Abstract
Ekološki bezolovni motorni benzin od min 90 do min 95 IOB, naznačen time da sadrži podkomponentu A-a1 - tipa od 37,00 do 64,08 vol%. b1- tipa od 4,34 do 9,00 vol% b2-tipa od 7,25 do 8,20 vol% b2- tipa od 5,00 do 30,50 vol%, b4- tipa od 17,99 do 29,89 vol%, b5- tipa od 5,00 do 17,62 vol% i sastava n-P od 13,51 do 22,85 vol%, i-P od 6,27 do 19,93 vol%, P- od 19,78 do 42,78 vol%, O od 5,79 do 13,46, N od 6,93 do 24,48 vol%, A-od 25.14 do 39,87 vol% kiseonika od 2,5 do 2,89 mas%, napona pare min 45,09 do 74.72 kpa i gustine od 711 do 789 kg/m3.Prijava sadrži još 8 patentnih zahteva.Organic unleaded motor gasoline from min 90 to min 95 IOB, characterized in that it contains a sub-component A-a1 - type from 37.00 to 64.08 vol%. b1- type from 4.34 to 9.00 vol% b2-type from 7.25 to 8.20 vol% b2- type from 5.00 to 30.50 vol%, b4- type from 17.99 to 29, 89 vol%, b5- type from 5.00 to 17.62 vol% and composition nP from 13.51 to 22.85 vol%, iP from 6.27 to 19.93 vol%, P- from 19.78 to 42.78 vol%, O from 5.79 to 13.46, N from 6.93 to 24.48 vol%, A-from 25.14 to 39.87 vol% oxygen from 2.5 to 2.89 wt%, steam voltages min 45.09 to 74.72 kpa and densities from 711 to 789 kg / m3. The application contains 8 more claims.
Description
EKOLOŠKI BEZOLOVNI MOTORNI BENZINECOLOGICAL UNLEADED MOTOR GASOLINE
OBLAST TEHNIKETECHNICAL FIELD
Ekološki bezolovni motorni benzin , pripada oblasti tečnih ugljovodoničnih goriva , baziranih na kombinaciji komponenti A i Btipa ,različitihPONAEcological unleaded motor gasoline, belongs to the field of liquid hydrocarbon fuels, based on a combination of A and B type components, of different PONA
(u daljem tekstu ^parafina od normalnih i izo-parafina,olefina,naftena i aromata) sastva i etra MTBE(metil-tercijalni butil etar), a u opisu će biti detaljno opisane podkomponente Atipa,označene od ai do aio A tipa, (hereinafter ^paraffins from normal and iso-paraffins, olefins, naphthenes and aromatics) composition and ether MTBE (methyl-tertiary butyl ether), and the description will describe in detail the sub-components of Atip, marked from ai to aio A type,
a iste se kombinuju u različitim odnosima sa podkomponentama Btipaoznačenim od bi do b?i dajuEKOLOŠKI BEZOLOVNI MOTORNIand the same are combined in different ratios with B-type sub-components marked from bi to b?i to give an ECO-FRIENDLY LEAD-FREE MOTOR
BENZIN.GASOLINE.
Int.CL .: C10L<4>ViInt.CL .: C10L<4>Vi
TEHNIČKI PROBLEMTECHNICAL PROBLEM
Ekološki bezolovni motorni benzinprema pronalasku , rešava problem ostvarenja ugljovodoničnog goriva od navedenih komponenti A i Btipai MTBE-a, od procesa petrohemijske i rafinerijske proizvodnje , smanjenjem sadržaja štetnih supstanci po motor i okolinu i to: teških metala, ukupnih aromata od Cć, C7 , C8i C9+, olefina , sumpora , sadržaja ugljenmonoksida , oksida sumpora, čađi i dima u izduvnim gasovima . Ecological unleaded motor gasoline according to the invention, solves the problem of producing hydrocarbon fuel from the above components A and Btype MTBE, from the process of petrochemical and refinery production, by reducing the content of harmful substances for the engine and the environment, namely: heavy metals, total aromatics of Cć, C7, C8 and C9+, olefins, sulfur, the content of carbon monoxide, sulfur oxides, soot and smoke in the exhaust gases.
Tehnički problemje rešiv kombinovanjem,frakcionog odvajanja na koloni odgovarajuće konstrukcije i ekstrakcionog tehnolpškog postupka , kod komponente petrohemijsko-rafinerijske proizvodnjeA tipa, visoko-aromatičnog(ido 85vol%)sastavaodC(,do C9+iod alifatičnihsu zastupljeni nezasićeni i zasićeni normalni i izo-parafini i naftcni , sastava od C3do C9-1-. Frakcionim odvajanjem i uz doradu ekstrakcijom se dobijajupodkomponente oda\doam,koje daju veće mogućnosti kombinovanja The technical problem can be solved by combining fractional separation on a column of appropriate construction and an extraction technological procedure, in the case of components of petrochemical-refinery production of type A, highly aromatic (or 85 vol%) composition from C(, to C9+, and aliphatic ones are represented by unsaturated and saturated normal and iso-paraffins and petroleum, composition from C3 to C9-1-. Fractional separation and with further extraction are they get sub-components of oda\doam, which give greater possibilities of combining
,međusobno i sa podkomponentama Btipai MTBE-a za namešavanje u kvalitetnijiekološki bezolovni motorni benzin ,a kako je pronalaskom definisano u opisu ,primerima i patentnim zahtevima. , among themselves and with the sub-components of Btip and MTBE for mixing into higher-quality ecological unleaded motor gasoline, and as defined by the invention in the description, examples and patent claims.
Predviđen je i tehnološki proces hidro-desulfurizacije obzirom daje pronalaskom predviđena proizvodnja EBMB sa koncentracijom sumpora od 50 ppm do nule odnosno istog u tragovima. The technological process of hydro-desulfurization is also foreseen, considering that the invention envisages the production of EBMB with a concentration of sulfur from 50 ppm to zero, i.e. the same in traces.
STANJE TEHNIKESTATE OF THE ART
Uobičajena tečna goriva za motore sa unutrašnjim sagorevanjem sastoje se od mešavine ugljovodonika i uglavnom se dobijaju iz nafte. Ova goriva , koja sadrže olovo-alkil koji katalizuje sagorevanje , ispuštaju olovo-alkil, ugljenmonoksid i druge supstance koje zagađuju životnu sredinu . Iz tih raz-loga vršeni su mnogi pokušaji da se obezbede goriva koja bi imala visoku vrednost IOB-a(u daljem tekstuistražni oktanski broj) , koja ne sadrže jedinjenja olova ili ih sadrže u tragovima i koja prilikom sagorevanja ne ispuštaju ugljenmonoksid . Za poboljšanje kvaliteta benzina predlagana je primena različitih jedinjenja koja nisu ugljovodoničnog tipa . Common liquid fuels for internal combustion engines consist of a mixture of hydrocarbons and are mainly derived from petroleum. These fuels, which contain lead-alkyl which catalyzes combustion, release lead-alkyl, carbon monoxide and other substances that pollute the environment. For these reasons, many attempts have been made to provide fuels that would have a high value of IOB (in the following text, research octane number), which do not contain lead compounds or contain them in traces and which do not release carbon monoxide during combustion. To improve the quality of gasoline, the application of various compounds that are not of the hydrocarbon type is proposed.
U američkom patentu US 2 334 006 opisana je primena alifatičnog estra mravlje kiseline i/ili sirćetne kiseline US patent US 2 334 006 describes the use of an aliphatic ester of formic acid and/or acetic acid
U američkom patentu US 3 009 792 opisana je primena arilamino-mono-karbonske kiseline kao dodatka benzinu In US patent US 3 009 792, the use of arylamino-mono-carboxylic acid as a gasoline additive is described.
U američkom patentu US 3 168 385 opisana je zajednička primena A common application is described in US Patent US 3,168,385
terc-alkil-estera monokarbonskih kiselina dialkil etera. tert-alkyl esters of monocarboxylic acids dialkyl ethers.
U američkom patentu US 2 210 942 opisano je dodavanje izobutil aldehida. US Patent US 2,210,942 describes the addition of isobutyl aldehyde.
Ujugoslovenskoj patentnoj prijavi P 2511/74 „SASTAV GORIVA ZA OTTO MOTORE" , opisan je sastav goriva bez olova , ili sa niskom koncentracijom olova , koji pored ugljovodoničnih komponenti sadrži 6% do 30% smeše jednog ili više alifatičnih alkohola sa 4C - atoma ugljenika , ili mešavine istih , jednog ili više etara tipa R1-O-R2. In the Yugoslav patent application P 2511/74 "FUEL COMPOSITION FOR OTTO MOTORS", the composition of fuel without lead, or with a low concentration of lead, is described, which, in addition to hydrocarbon components, contains 6% to 30% of a mixture of one or more aliphatic alcohols with 4C carbon atoms, or a mixture of the same, one or more ethers of the R1-O-R2 type.
kod kojih Rjpredstavlja metil- ili etil radikal, a R2predstavlja tercijalni-butil radikal ili mešavinu istih . Kod ovih goriva odnos alkohola prema etru je od 20: 80 do 80:20. Koncentracija olova je najviše do 0.5 g/kg . where R represents a methyl- or ethyl radical, and R2 represents a tertiary-butyl radical or a mixture thereof. With these fuels, the ratio of alcohol to ether is from 20:80 to 80:20. The concentration of lead is up to 0.5 g/kg.
U američkom patentu US 2 334 006 opisana je primena alifatičnog estra mravlje i/ili sirćetne kiseline olova je najviše do 0,5 g/kg. US patent US 2 334 006 describes the use of aliphatic ester of formic and/or acetic acid of lead up to 0.5 g/kg at most.
YU P-772/95-49024 od 19.3.2003. YU P-772/95-49024 dated 19.3.2003.
BEZOLOVNI MOTORNI BENZIN OD PETROHEMIJSKIH PROIZVODA I RAFINERIJSKIH BENZINA TIPA PRIMARNOG UNLEADED MOTOR GASOLINE FROM PETROCHEMICAL PRODUCTS AND PRIMARY TYPE REFINERY GASOLINE
P 558/2002 prioritet SE ,24.01.2001. Br. PCT/SE01/00040 P 558/2002 priority SE, 24.01.2001. No. PCT/SE01/00040
PST Nacionalna faza PST National Phase
"POSTUPAK ZA SMANJENJE PRITISKA PARE MOTORNIH GORIVA KOJI SADRŽE ETANOL ZA MOTORE SA UNUTRAŠNJIM SAGOREVANJEM SA SVEĆICAMA" "PROCEDURE FOR REDUCING THE VAPOR PRESSURE OF MOTOR FUELS CONTAINING ETHANOL FOR SPARK PLUG INTERNAL COMBUSTION ENGINES"
HULL, Angelica HULL, Angelica
OPIS PRONALASKADESCRIPTION OF THE INVENTION
EKOLOŠKI BEZOLOVNI MOTORNI BENZIN ,prema pronalasku , baziran je na kombinacijama navedenih komponenti A I B - tipa različitogPONAsastava . ECOLOGICAL UNLEADED MOTOR GASOLINE, according to the invention, is based on combinations of the above-mentioned components A and B-type with different compositions.
Karakteristike komponente A-tipa-po sastavu visoko-aromatična i olefinska ,a obzirom na visok sadržaj aromata i visoko oktanska . Istražna oktanska vrednost ili IOB(dalje u tekstu) se najčešće kreće od 95 do 110 ali pronalaskom ista nije ograničena , kao ni procentualniPONAsastav . Izabrane suAIkomponenta gde su ukupni aromati 77,14 vol % i AH komponenta sa 66,61 vol % ukupnih aromata , što daje razliku sastava EBMB-a. Characteristics of the A-type component - by composition, highly aromatic and olefinic, and due to the high content of aromatics and high octane. The research octane value or IOB (further on in the text) usually ranges from 95 to 110, but according to the invention, it is not limited, nor is the percentage PONA composition. The AI component where the total aromatics are 77.14 vol % and the AH component with 66.61 vol % of the total aromatics were chosen, which gives the difference in the composition of EBMB.
Najčešće zastupljena aromatična jedinjenja subenzenod 30-40 vol %,toluenod 12 do 19 vol%,etilbenzenod 1 do 8,00vol%,m- ksilenod 1,1 do 4,00vol%, p-ksilen od 1,2 do 2,50vol% , p+m ksilen od 5,1 do 6,50 vol%, o-ksilen od 1,25 do 2,55 vol% , stiren od 0,08 do 5,57 vol% , C9+od 10 do 15,12 vol%. Ovo je uobičajeni sastav aromata komponente tipa-A u datim granicama koje pronalaskom nisu ograničene. The most common aromatic compounds subbenzene from 30-40 vol %, toluene from 12 to 19 vol %, ethylbenzene from 1 to 8.00 vol %, m-xylene from 1.1 to 4.00 vol %, p-xylene from 1.2 to 2.50 vol %, p+m xylene from 5.1 to 6.50 vol %, o-xylene from 1.25 to 2.55 vol%, styrene from 0.08 to 5.57 vol%, C9+ from 10 to 15.12 vol%. This is the usual aromatic composition of the type-A component within the given limits which are not limited by the invention.
Ukupni aromati se obično kreću u granicama od 55 do 85 vol%, a samim tim ostala alifatična jedinjenja(I normalnih i izo parafina, olefina i naftena) su u granicama od 15 do 45 vol%. Total aromatics usually range from 55 to 85 vol%, and therefore other aliphatic compounds (both normal and iso-paraffins, olefins and naphthenes) range from 15 to 45 vol%.
Koncentracije, pojedinačnog raznolikog gasnohromatografskog Concentrations, individual diverse gas chromatographic
sastava date u vol% za A-Ii A-IIće biti predstavljene u tabelama br. 1 i br.2 . composition given in vol% for A-Ii and A-II will be presented in tables no. 1 and No. 2.
Značajno za pronalazak je sadržajukupnih olefina, u smislu njihovog rasporeda od C3do C9+.Obično su zastupljeni od C3do C7, a C8+su uglavnom u tragovima ili ih nema, što se jasno vidi iz tabela . Za ostvarenje pronalaskom predviđenih kombinacija za EBMB sa olefinima u tragovima ili do 1,50 vol% je neophodna upotreba A komponente po sastavu olefina,kako je opisano. Significant for the invention is the content of total olefins, in terms of their arrangement from C3 to C9+. They are usually represented from C3 to C7, and C8+ are mostly in traces or absent, which is clearly seen from the tables. In order to achieve the combinations foreseen by the invention for EBMB with trace olefins or up to 1.50 vol%, it is necessary to use the A component according to the olefin composition, as described.
A komponentu karakteriše i različit napon pare uglavnom od 10 do 20 Kpa na 15°C u zavisnosti od sastava ugljovodonika sa niskim ili višim tačkama ključanja , a sa tim je u vezi i niži ili viši početak destilacije od 45°C do 60°,a kraj destilacije od 175 do 215°C u zavisnosti od sadržaja težih komponenti odnosno najčešće težih aromata. Gustina je uglavnom od 810 do 860 kg/m3. And the component is characterized by a different vapor pressure, mostly from 10 to 20 Kpa at 15°C, depending on the composition of hydrocarbons with low or higher boiling points, and related to this is a lower or higher start of distillation from 45°C to 60°, and the end of distillation from 175 to 215°C, depending on the content of heavier components, i.e. usually heavier aromatics. The density is generally from 810 to 860 kg/m3.
Koncentracija sumpora je najčešće od 50 dol 50 mg/kg ,ali se ista smanjuje kako je u zamisli pronalaska ispod 50 do nule ili u tragovima. Koncentracija olova je <30 ppb. The concentration of sulfur is most often from 50 to 50 mg/kg, but it decreases, as in the idea of the invention, from below 50 to zero or in traces. Lead concentration is <30 ppb.
Najznačajnija A podkomponenta , koja se izdvaja za proizvodnju EBMB-a je The most significant A subcomponent, which is allocated for the production of EBMB, is
A- a^ .Ona je po sastavu komponenta A bez benzena ( ili isti u tragovima) PONA sastav prikazan u tabeli br.3. A- a^ .It is compositionally component A without benzene (or the same in traces) PONA composition shown in table no. 3.
PONA voI% za sastav A-l i A-II i A-I-aii A-II-a, -K% tabela br.3 PONA voI% for composition A-l and A-II and A-I-aii A-IIa, -K% table no. 3
A-a2podkomponenta je po sastavu frakcija C() minus, minus benzen . The A-a2 subcomponent is composed of fractions C() minus, minus benzene.
Bitno za EBMB je to što primenom ove komponente upotrebljavamo većinski sadržaj OLEFINA iz komponente A,znači nepogodna za kombinacije istog sa olefinima u tragovima ili do max 1.50 ,kako je u zamisli pronalaska . It is important for EBMB that by applying this component we use the majority of OLEFIN content from component A, which means that it is unsuitable for combinations of the same with olefins in traces or up to max 1.50, as in the idea of the invention.
A-a3podkomponenta je frakcija C71do kraja The A-a3 subcomponent is a fraction of C71 to the end
A-a.4 podkomponenta je frakcija A minus benzen i minus toluen . A-a.4 subcomponent is fraction A minus benzene and minus toluene.
A-aspodkomponenta predstavlja frakciju €7+bez toluena. The A-as subcomponent represents the fraction €7+without toluene.
A-af, podkomponenta je mikstura orto, meta i para ksilena.etil-benzena i stirena. A-af, subcomponent is a mixture of ortho, meta and para xylene, ethyl-benzene and styrene.
A-a7 podkomponenta je destilat od 150°C do kraja. A-a7 subcomponent is the distillate from 150°C to the end.
A-aspodkomponenta predstavlja po sastavu A minus benzen i minus destilat od 150°C do kraja.Ova komponenta je od značaja zanamešavanje EBMB-a predviđenim pronalaskom sa krajem destilacijeThe A-subcomponent is composed of A minus benzene and minus distillate from 150°C until the end. This component is important for stirring up the EBMB foreseen by the invention with the end of distillation.
do 150°C.up to 150°C.
A-a9podkomponenta, je po sastavu frakcija C7+, minus frakcija od , 150°C do kraja.. A-a9 subcomponent, is composed of fraction C7+, minus fraction from , 150°C until the end..
A-aio podkomponenta posastavu je toluen , A-aio subcomponent of the composition is toluene,
Kombinacijom ovih komponenti sa komponentama B-tipa se ostvaruje proizvodnja pronalaskom definisanog EBMB-a. By combining these components with B-type components, the production of the invention defined EBMB is realized.
KomponenteB-tipa karakteriše to što su uglavnom niskooktanske(osim bijD2) i sa višim naponom pare(u daljem tekstu napon pare po Reidu na 15°C R.v.pr.) ,po sastavu uglavnom parafinsko-naftenskog tipa sa olefinima u tragovima najčešće do 1 vol% (osim komponente b2) i aromata od 1 do 15 vol% , i sa nižim gustinama u odnosu na komponentu A tipa , što pokazuje tabelabr.7 The B-type components are characterized by the fact that they are mostly low-octane (except bijD2) and with a higher vapor pressure (hereinafter referred to as the Reid vapor pressure at 15°C R.v.p.), in composition mainly of the paraffinic-naphthenic type with trace olefins usually up to 1 vol% (except for component b2) and aromatics from 1 to 15 vol%, and with lower densities compared to the A-type component, which shows table no. 7
PONA- vol% sastav,IOBi R v.pr. i gustina na15°C za komponente od bido b7-u vol%tabela br.7 PONA- vol% composition, IOBi R v.pr. and density at 15°C for components made of bido b7-u vol%table no. 7
Komponentabije po sastavu uglavnom smeša butana i izobutana u granicama od 58 do 75 vol% nC4i i C4od 39 do 27,50 sa primesama propana do 3 vol% , pentana u tragovima i olefinima u tragovima ,a najviše do lvol% . Navedene granice su uobičajene , ali pronalazak iste ne ograničava već podrazumeva kombinaciju n-C4i i- C4u različitim procentualnim odnosima .Zastupljena su i sumporna jedinjenja , izražena kao ukupan sumpor do max 0,0050% mas , međutim obično je do max. 0,0005%mas. Napon pare je visok od 360 do 410 kpa na temperaturi od 15<0>C pa je dobra za kombinaciju u EBMB-u za povećanje napona pare . Koncentracija iste će biti prilagođena potrebama , u smislu letnje ili zimske recepture odnosno u mestima sa žarkom klimom , predviđene su kombinacije bez istog . U patentnim primerima EBMB-a je zastupljena od 0 do max 10 vol%„ The composition of the components is mainly a mixture of butane and isobutane in the range of 58 to 75 vol% nC4i and C4 from 39 to 27.50 with admixtures of propane up to 3 vol%, traces of pentane and traces of olefins, and at most up to lvol%. The stated limits are common, but the invention does not limit it, but implies a combination of n-C4i and - C4u in different percentage ratios. Sulfur compounds are also represented, expressed as total sulfur up to max 0.0050% mass, however, it is usually up to max. 0.0005%wt. The steam pressure is high from 360 to 410 kpa at a temperature of 15<0>C, so it is good for combination in EBMB to increase the steam pressure. Its concentration will be adapted to the needs, in terms of summer or winter recipes, that is, in places with a hot climate, combinations without it are provided. In patent examples of EBMB, it is represented from 0 to max 10 vol%"
Komponenta b2- je nuz proizvod petrohemijske proizvodnje ekstrakcije MTBE-a , sa većinskim sadržajem C4- olefina , zatim parafina u granicama datim u tabeli . Pored parafina i olefina postoji i trag butadiena do lOOmg/kg ,pa je primena ove komponente ograničena u smislu da u EBMB-u sadržaj butadiena bude ispod 3mg/100ml zbog mogućnosti polimerizacije . Pored ovih može sadržati i metanola do max 5 %mas i MTBE-a do max 0,1 %mas. Sumpor je do max 5 mg/kg ali ga uglavnom nema..Ova komponenta se može upotrebiti u svim kombinacijama gde i komponenta biali sa ograničenjem po sadržaju olefina . Za patentne primere EBMB-a sa ograničenim olefinima do max 1,50 vol% i u EBMB-u do max. kraja destilacije do 150° C takođe sa smanjenim sadržajem olefina nemože se upotrebiti . Component b2- is a by-product of the petrochemical production of MTBE extraction, with the majority content of C4-olefins, followed by paraffin within the limits given in the table. In addition to paraffin and olefins, there is also a trace of butadiene up to 100mg/kg, so the application of this component is limited in the sense that in EBMB the butadiene content should be below 3mg/100ml due to the possibility of polymerization. In addition to these, it can also contain methanol up to 5% by weight and MTBE up to 0.1% by weight. Sulfur is up to a maximum of 5 mg/kg, but it is mostly absent. This component can be used in all combinations, including the white component with a limit on the olefin content. For patent examples of EBMB with limited olefins up to max 1.50 vol% and in EBMB up to max. at the end of distillation up to 150° C, also with reduced olefin content, cannot be used.
Komponenta b3- je rafinerijski proizvod uobičajenog sastava i karakteristika datih u tabeli .Destilacija je uglavnom sa početkom od min 28 do max 215° C. Navedene brojne vrednosti su uobičajene ali pronalaskom nisu ograničene. Koncentracija sumpora je do max. 0,0800 mas% najčešće je od 0,0050 do 0,0150 mas% ponekad do 0,0300 mas%. Koncentracija olova je najčešće do 50 ppb . Obzirom da je ova komponenta u EBMB-u zastupljena u granicama od min 8,80 do 43,25vol% tako da ova koncentracija ne utiče bitno na promenu kvaliteta EBMB-a. Component b3- is a refinery product with the usual composition and characteristics given in the table. Distillation generally starts from min 28 to max 215° C. The numerous values listed are common but not limited by the invention. Sulfur concentration is up to max. 0.0800 wt% is usually from 0.0050 to 0.0150 wt%, sometimes up to 0.0300 wt%. The concentration of lead is usually up to 50 ppb. Given that this component in EBMB is represented in the limits of min 8.80 to 43.25 vol%, so this concentration does not significantly affect the change in the quality of EBMB.
Komponentaba.je proizvod rafinerijske proizvodnje sastava datog u tabeli br.7 ,ali su kod ove komponente mogući razni sastavi za ukupne parafine od 20 do 80 vol%, olefina uglavnom nema ,naftena od 23 do 68 i sa aromatima u tragovima. Naponi para su u granicama od 70 do 120kpa, IOB vrednost od 60 do 90 , zatim početak destilacije je od 36 do maksimalno 108 . ukupni sumpor je do max 0.0150mas%.Ova komponenta se može koristiti u svim primerima gde je upotrebljena bjkomponenta ,samo bi bio izmenjen procentualni sadržaj zbog malo više IOB vrednosti . U EBMB-u je zastupljena od 9,00 do 27,00 vol % u primerima. Sadržaj sumpora od ove komponente bio do max 0,0060%mas , ali obzirom da je predviđena HDS(hidro- desulfurizacija) nije od značaja. Ova komponenta može sadržati tragove zaprljanja od arsena do max 1,41 ppm mas .zatim hlor 1,1 ppm mas, bakar 0,5 ppm , 0,5 ppm olova ,što zavisi od nafte , od koje je ista proizvedena.Zaprljanja nisu od značaja obzirom na zastupljeni procentualni sadržaj. Ova komponenta je značajna za kombinacije EBMB sa krajem destilacije do 150<0>C i sa niskim sadržajem olefina, odnosno značajna za sve kombinacije istog . Komponentaba. is a product of refinery production with the composition given in table no. 7, but with this component various compositions are possible for total paraffins from 20 to 80 vol%, olefins are mostly absent, naphthen from 23 to 68 and with traces of aromatics. Steam pressures range from 70 to 120kpa, IOB value from 60 to 90, then the start of distillation is from 36 to a maximum of 108. total sulfur is up to max 0.0150 mass%. This component can be used in all examples where bjcomponent is used, only the percentage content would be changed due to a slightly higher IOB value. In EBMB, it is represented from 9.00 to 27.00 vol % in examples. The sulfur content of this component was up to a maximum of 0.0060% mass, but considering that HDS (hydro-desulfurization) is planned, it is not important. This component may contain traces of contamination from arsenic up to max 1.41 ppm mass, then chlorine 1.1 ppm mass, copper 0.5 ppm, 0.5 ppm lead, which depends on the oil from which it was produced. The contamination is not significant considering the represented percentage content. This component is significant for combinations of EBMB with the end of distillation up to 150<0>C and with a low olefin content, that is, significant for all combinations of the same.
Komponenta bg. je rafinerijski proizvod uglavnom parafinskog sastava sa tragovima olefina ,bez naftena i sa nešto aromata što se vidi na primeru iz tabele br.7. Napon pare je 30 kpa ,početak destilacije je 65° C , a kraj 97° C , IOB vrednost jc 59 , a gustina je 682 kg/m<3>. Obzirom daje kraj destilacije do 100° C može se koristiti u kombinaciji za EiBMB sa krajem destilacije do 150<0>C i u kombinacijama za EBMB sa niskim sadržajem olefina . Odlična je komponenta i u kombinaciji sa komponentom a3jer je ova komponenta sa početkom destilacije preko 90<0>C , kao komplementarna ,a ova kombinacija je značajna zbog indeksa napona pare . Ova komponenta je zastupljena u kombinacijama po primerimerima do 45 vol % ali pronalazakom nije ograničena. Component bg. is a refinery product mainly of paraffinic composition with traces of olefins, without naphthenes and with some aromatics, which can be seen in the example from table no. 7. The steam pressure is 30 kpa, the start of distillation is 65° C, and the end is 97° C, the IOB value is 59, and the density is 682 kg/m<3>. Considering that the end of distillation up to 100° C can be used in combination for EiBMB with the end of distillation up to 150<0>C and in combinations for EBMB with low olefin content. It is an excellent component in combination with component a3 because this component with the start of distillation above 90<0>C is complementary, and this combination is significant because of the vapor pressure index. This component is represented in combinations according to examples up to 45 vol%, but is not limited by the invention.
Komponenta b<-, - je rafinerijski proizvod sa visokim sadržajem parafina ,kako je dato u tabeli 79,90 vol% , olefina ima u tragovima do lvol% , naftena 4,70 i aromata 14,60vol%, IOB vrednost je 65,5 a napon pare od 27-30 kpa i gustina jc 713 kg/m<3>.Može se koristiti sa ograničenim sadržajem , obzirom da su zastupljeni aromati Cg i C7tipa , predviđena ekstrakcija ili primena za EBMB sa benzenom do max 1.00vol%. Component b<-, - is a refinery product with a high paraffin content, as given in the table 79.90 vol%, traces of olefins up to lvol%, naphthenes 4.70 and aromatics 14.60vol%, IOB value is 65.5 and vapor pressure of 27-30 kpa and density jc 713 kg/m<3>. It can be used with limited content, considering that they are represented aromas of Cg and C7 type, planned extraction or application for EBMB with benzene up to max 1.00vol%.
Komponenta bj_ Koristi se za namešavanje EBMB sa benzenom manje od lvol% ili u tragovima , sa krajem destilacije do 150<0>C. sa olefinima u tragovima . Component bj_ It is used to mix EBMB with benzene less than lvol% or in traces, with the end of distillation up to 150<0>C. with traces of olefins.
Od oksigenata pronalaskom je predviđeno korišćenje etra IVITBE Visokooktanska komponenta , sličnih osobina kao laki benzini u pogledu isparavanja , a u prisustvu vode u benzinima ne rastvara se i ne raslojava čak sprečava raslojavanje u benzinu, odlično se meša sa benzinskim komponentama . Pri sagorevanju omogućava sagorevanje do CO?, zbog prisutne metoksi grupe.U sastav komponente MTBE ima i primesa metanola do max.5 mas% i sumpora do max 0,0005 mas % ali je uglavnom manji od 0,0001 mas%,ostalih primesa C5i niže do max 0.5mas%. Of the oxygenates, the invention envisages the use of ether IVITBE High octane component, similar properties to light gasoline in terms of evaporation, and in the presence of water in gasoline, it does not dissolve and does not stratify, it even prevents stratification in gasoline, it mixes well with gasoline components. During combustion, it enables combustion to CO?, due to the presence of the methoxy group. In the composition of the MTBE component, there is also an admixture of methanol up to max. 5 mass% and sulfur up to max. 0.0005 mass%, but it is generally less than 0.0001 mass%, other impurities C5 and lower up to max. 0.5mass%.
Destiliše sa početkom na 510 C i kraj destilacije na 68° C . IOB vrednosti su od 115 do 135 u zavisnosti od primesa i gustina je od 740 do 750 kg/m<3>na 15°C. Koncentracija istog u primerima je od 8.62 do 20,70vol% ili O2od 1.55do3,76vol% radi širih granica zaštite. Uglavnom je zastupljen sa -15 vol% ili kiseonika-2,7 vol%(obzirom da nije čist). Pronalaskom su predviđene kombinacije za EBMB i bez istog. Distills with the beginning at 510 C and the end of distillation at 68° C. The IOB values are from 115 to 135 depending on the admixture and the density is from 740 to 750 kg/m<3>at 15°C. The concentration of the same in the examples is from 8.62 to 20.70 vol% or O2 from 1.55 to 3.76 vol% for wider protection limits. It is mainly represented by -15 vol% or oxygen-2.7 vol% (since it is not pure). The invention provides combinations for EBMB and without it.
NOVI EBMB-a ostvarenje kombinacijom komponenti A i B-tipa , definisanog kvaliteta kako je dato u tabelama i opisu istih . Zajednička karakteristika svih komponenti je da su oslobođene benzena ili je isti od 1 vol% do nule ili trag .Koncentracija sumpora bez dorade HDS je u granicama od 50 do 300 mg/kg.Pronalaskom je data mogućnost proizvodnje sa sumporom od max 50 smanjenjem do nule-sumpor u tragovima.Olovo je po primerima manje od 30 ppb ali je pronalaskom dozvoljena koncentracija istog od max 50 ppb do nule ili u tragovima(trag<20ppb). The NEW EBMB is realized by a combination of A and B-type components, of defined quality as given in the tables and their description. The common feature of all components is that they are free of benzene or it is the same from 1 vol% to zero or a trace. The concentration of sulfur without finishing HDS is within the limits of 50 to 300 mg/kg. The invention gave the possibility of production with sulfur from max 50 by reducing it to zero-trace sulfur. Lead is, according to examples, less than 30 ppb, but the same concentration is allowed by the invention from max 50 ppb to zero or in traces (trace<20ppb).
Primerima su prikazane mogućnosti proizvodnje EBMB po primerima bez benzena (u tragovima) primenom podkomponenti A- a^ do A- a^ , zatim primenom podkomponente AI- a.< ili AH- ag bez benzena i toluena i kombinacije sa ukupnim smanjenjem aromata do min 20,05 vol% što pronalaskom nije ograničeno već varira u zavisnosti od ukupnog sadržaja benzena ,toluena i ukupnih aromata u komponenti A- tipa . Ukupni aromati po primerima su od 20,05 a najviše do 48,00vol%. The examples show the possibilities of producing EBMB by examples without benzene (in traces) using subcomponents A-a^ to A-a^, then using subcomponents AI-a.< or AH-ag without benzene and toluene and combinations with a total reduction of aromatics up to min 20.05 vol%, which is not limited by the invention but varies depending on the total content of benzene, toluene and total aromatics in the A-type component. The total aromatics according to the examples are from 20.05 and up to 48.00vol% at most.
Data je mogućnost proizvodnje EBMB-a po primerima sa smanjenom koncentracijom olefina od min trag (ili0.001vol%) do max.l,46vol% (za navedeni kvalitet AI i A1I-komponente u vol%, gde su ukupni olefini uglavnom doC7+) It is possible to produce EBMB according to examples with a reduced concentration of olefins from min trace (or 0.001vol%) to max.1.46vol% (for the specified quality of AI and A1I-components in vol%, where total olefins are mostly up to C7+)
Data je mogućnost proizvodnje po primerima , sa krajem destilacije na 150°C i olefini u tragovima , a u zamisli pronalaska je mogućnost od 150°C±10 °C zavisno od sadržaja C<h aromata. The possibility of production according to examples is given, with the end of distillation at 150°C and olefins in traces, and in the idea of the invention, the possibility of 150°C±10°C depends on the content of C<h aromatics.
NOVI EBMB je po primerima po PONA sastavu u granicama i to : n-P od 8,00 do 28,00vol% , i-P od 5,88 do 22,00 vol% , P od 15,00 do 47,00 vol% , O od 0,001 do 19,50 vol% , N od 0,30 do 25,00 vol% i A od 20,05(minl9.00u zamisli pronalaska) do 48,00 vol%. Napon pare je u granicama od 26 do 75 kpa po primerima ,ali se isti prilagođava u zavisnosti od klimatskih uslova područja korišćenja istog što je u zamisli pronalaska. According to examples, the PONA composition of NEW EBMB is within the following limits: n-P from 8.00 to 28.00 vol%, i-P from 5.88 to 22.00 vol%, P from 15.00 to 47.00 vol%, O from 0.001 to 19.50 vol%, N from 0.30 to 25.00 vol% and A from 20.05 (minl9.00 in the idea of the invention) to 48.00 vol%. The steam pressure is within the limits of 26 to 75 kpa according to the examples, but it is adjusted depending on the climatic conditions of the area of use, which is in the idea of the invention.
NOVI EBMB je sa poboljšanim motornim karakteristikama po pitanju korozije , sagorevanja sa smanjenim mogućnostima pirolize i sadržaja ukupnih guma . NEW EBMB has improved motor characteristics in terms of corrosion, combustion with reduced pyrolysis possibilities and total tire content.
Poboljšan je kvalitet za skladištenje na duže vreme - rezerve( gorivo sa smanjenim sadržajem olefina) . The quality for long-term storage - reserves (fuel with reduced olefin content) has been improved.
Što se tiče EKOLOGIJE , smanjen sadržaj čađi (aromati pri sagorevanju daju čađ) , dima ,(sumpor u tragovima) sumpordioksida , ugljenmonoksida , teških metala u izduvnim gasovima , a po pitanju ambijentne emisije smanjena opasnost oboljenja od kancera (naročito za točioce istog na benzinskim pumpama)jer je bez benzena(u tragovima). As for ECOLOGY, reduced content of soot (aromas during combustion give soot), smoke, (traces of sulfur), sulfur dioxide, carbon monoxide, heavy metals in exhaust gases, and in terms of ambient emissions, the risk of cancer is reduced (especially for dispensers of the same at gas stations) because it is benzene-free (traces).
U sledećim primerima navedeni su PONA - vol% sastavi EBMB-a od navedenih komponenti u različitim odnosima đa su IOB vrednosti od min 90 do min 95 ,a naponi para od 29 do 80 kpa prema pronalasku.EBMB sadrži još i komponentu MTBE od min 8,62 do 20,70 vol% po primerima, a može i od min 0 do 20,70vol%. In the following examples, the PONA - vol% compositions of EBMB from the above components are listed in different ratios, i.e. IOB values from min 90 to min 95, and vapor pressures from 29 to 80 kpa according to the invention. EBMB also contains the MTBE component from min 8.62 to 20.70 vol% according to the examples, and it can also be from min 0 to 20.70 vol%.
Primerom br 1 detaljno je dat način obračuna recepture za EBMB-a sa podacima vol% sastava , podkomponenti i komponenti iz napred datih tabela . Example No. 1 shows in detail how to calculate the recipe for EBMB with vol% composition data, subcomponents and components from the tables given above.
Tabela br.1.1 jeprimer kombinacija komponentiAI-aisa b( ,b3i kiseonika od 2,73 vol% Table no. 1.1 is an example of a combination of components AI-aisa b( ,b3 and oxygen of 2.73 vol%
(MTBE okol5,00vol% i dalje u primerima gde je kiseonik 2,73% ), ostvaren je EBMB od min 90 do 95 IOB , napona pare (Rvpr ruTl5°C) od min 45(47,17) do~50(49,93) kpa , gustine od 786 do789 kg/m<3>i PONA - vol% sastava u datim granicama koncentracija kao i koncentracija komponenti u vol% dato u tabeli br.l .1 (MTBE around 5.00vol% and still in examples where oxygen is 2.73%), EBMB was achieved from min 90 to 95 IOB, vapor pressure (Rvpr ruTl5°C) from min 45(47.17) to~50(49.93) kpa, density from 786 to 789 kg/m<3> and PONA - vol% composition within the given concentration limits as well as concentration of components in vol% given in table no.l .1
Tabela br.l.2je primer kombinacija komponentiAII-aisa b| , b3i kiseonika od 2.82 do 2,89 vol% (MTBE odi 5,50 do 15,92 vol% ), ostvaren je EBMB od min 90 do min 95 IOB napona pare (Rvpr na 15°C) od~50 kpa(49,88 do 51,63 kpa ) , gustine od 763 do 786 kg/m<3>i PONA - vol% sastava u datim granicama koncentracija kao i koncentracija komponenti u vol% . Table no.1.2 is an example of combinations of components AII-aisa b| , b3i of oxygen from 2.82 to 2.89 vol% (MTBE from 5.50 to 15.92 vol% ), achieved EBMB from min 90 to min 95 IOB vapor pressure (Rvpr at 15°C) of ~50 kpa (49.88 to 51.63 kpa ), density from 763 to 786 kg/m<3>i PONA - vol% of the composition within the given concentration limits as well as the concentration of components in vol%.
Dalje kombinacije u zamisli pronalaska će biti predstavljene tabelarno sa podacima u četiri kolone i to: prva kolona je sa izabranim podkomponentama A-tipa i komponentama tipa B, u drugoj koloni je dat odnos sastava u vol% od najniže do najveće vrednosti koncentracije. Treća kolona daje PONA sastav u vol%, odnosno parafini razloženi na normalne i izo parafine , ukupne parafine, olefine , naftene i aromate . Četvrta kolona sadrži podatke odnosa PONA vol% sastava od najniže do najviše vrednosti . Further combinations in the idea of the invention will be presented tabularly with data in four columns, namely: the first column is with the selected sub-components of type A and components of type B, in the second column the composition ratio in vol% from the lowest to the highest concentration value is given. The third column gives the PONA composition in vol%, i.e. paraffins broken down into normal and iso-paraffins, total paraffins, olefins, naphthenes and aromatics. The fourth column contains data on the ratio of PONA vol% composition from the lowest to the highest value.
Primerom br2, kombinacijama komponenti AI- aiiliAII-ai,sa b|, bj, b.s Example no. 2, combinations of components AI- ai or AII-ai, with b|, bj, b.s
i kiseonika do max.2,7 vol% , ostvarenje EBMB od min 90 do min 95 IOB , napona pare od min 45 kpa i gustine od 755 do 787 kg/m<3>i PONA - vol% sastava u sledećim granicama koncentracije kao i odnos granica koncentracija komponenti u vol% dato u and oxygen up to max. 2.7 vol%, achievement of EBMB from min. 90 to min. 95 IOB, vapor pressure from min. 45 kpa and density from 755 to 787 kg/m<3> and PONA - vol% composition in the following concentration limits as well as the ratio of the concentration limits of the components in vol% given in
Primerom 3 kombinacijama komponentiAI-aiiliAII-ai,sa b\, b3, b$Example 3 combinations of components AI-ai or AII-ai, with b\, b3, b$
i kiseonika do max.2,5 vol% ,ostvarenjeEBMBodmin90 domin95IOB, napona pare > 50(oko 55) kpa ,gustina od 750 do 775 kg/m<3>i PONA - vol% sastava u sledećim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u and oxygen up to max. 2.5 vol%, realization of EBMBodmin90 domin95IOB, vapor pressure > 50 (about 55) kpa, density from 750 to 775 kg/m<3> and PONA - vol% composition in the following concentration limits as well as the concentration limits of components in vol% given in
Primerom4, kombinacijama komponenti AI-aiili AII-ai , sa bi, b4i bsi kiseonika do max.2,5 vol% , ostvaren jc EBMB od min 90 do min 95 IOB , napona pare od min 67,89 do 74,72 kpa,gustina od 711 do 761 kg/m<3>i PONA - vol% sastava u sledećim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli 4 Example 4, with combinations of components AI-ai or AII-ai, with bi, b4 and bsi oxygen up to max. 2.5 vol%, achieved EBMB from min 90 to min 95 IOB, vapor pressure from min 67.89 to 74.72 kpa, density from 711 to 761 kg/m<3> and PONA - vol% composition in the following concentration limits as well as the concentration limits of the components in vol% given in summary table 4
Primerom5, kombinacijama komponenti AI-a2, Al-as, AI-aiosa bi, b3i b4i Example 5, combinations of components AI-a2, Al-as, AI-aiosa bi, b3i b4i
AII-a2, All-a?,, sa bi, b3i kiseonika do max.2,7 vol% , ostvaren je EBMB od min 90 IOB napona pare od 54,32 do min 66,90 kpa,gustine 725 do 748 kg/m<3>i PONA vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli 5. AII-a2, All-a?,, with bi, b3i oxygen up to max. 2.7 vol%, EBMB was achieved from min 90 IOB, vapor pressure from 54.32 to min 66.90 kpa, density 725 to 748 kg/m<3> and PONA vol% composition in the specified concentration limits as well as the concentration limits of the components in vol% given in summary table 5.
Primerom 6 kombinacijama komponenti AI-a2, Al-as, AI-ai0sa bi, b4i bsi Example 6 combinations of components AI-a2, Al-as, AI-ai0sa bi, b4i bsi
AII-a2, AH-aji Ali- ai() sa b3i kiseonika do max.2,7 mas% , ostvaren je EBMB od min 95 IOB napona pare od min 45 do 52,53 kpa , gustine od 736 do 753 kg/m<3>i PONA - vol% sastava u datim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli 6.1 AII-a2, AH-aji Ali-ai() with b3i oxygen up to max.2.7 mass%, achieved EBMB of min. 95 IOB, vapor pressure from min. 45 to 52.53 kpa, density from 736 to 753 kg/m<3> and PONA - vol% composition in the given concentration limits as well as the concentration limits of the components in vol% given in summary table 6.1
Primerom7, kombinacijama komponenti AI-a4i AII-a4, sa bi , b3, i b4i ( ista kombinacija , koja daje veći napon pare i umesto b| koristi se b2) AII-a4, sa b2, bj, i b4kiseonika od .2,05 do 3,40vol% (MTBE od 11,30 dol8,73vol%), ostvaren je EBMB od min 90 IOB napona pare od min 45 do min 55kpa , gustine od 727 do 743 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli 7 Primerom8 kombinacijama komponentiAI-a4i AII-a4,sabii b4,kiseonika od 2.4 do 2.9 vol% (MTBE od 14 do 16,00vol%) ,ostvaren je EBMB od min 95 IOBnapona pare od min 68,52 do71,20 kpa , gustine od 722 do 732 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato uzbirnoj tabeli 8 Primerom 9.kombinacijama komponentiA-I-a4i A-II-a4, sa b|, b4i kiseonika od 2,3 do2,46 vol%(MTBE od 13.58 do 15,47vol%),ostvaren je EBMB od min 95 IOBnapona pare od min 45,66 do 58,61 kpa . gustine od 732 do 738 kg/m<3>i PONA vol% sastava u navedenim granicama konce ntracije kao i granice koncentracija komponenti u vol% dato uzbirnoj tabeli 9 Primerom10 kombinacijama komponenti A-I-a2A-I-a^A-I-a7, sa bibj, kiseonika od 3,28 do 3,37 vol%(MTBE od 18.09 do 18,58), ostvaren je EBMB od min 90 IOB napona pare od min 45(46,01) do min 50(51,89) kpa , gustine od 741 do 762 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli 10 Example 7, with combinations of components AI-a4i AII-a4, with bi, b3, and b4i (the same combination, which gives a higher vapor pressure and b2 is used instead of b) AII-a4, with b2, bj, and b4 oxygen from .2.05 to 3.40vol% (MTBE from 11.30 to 8.73vol%), an EBMB of min. 90 IOB vapor pressure from min. 45 to min 55kpa, density from 727 to 743 kg/m<3> and PONA - vol% composition in the specified concentration limits as well as the concentration limits of components in vol% given in summary table 7 Example8 combinations of components AI-a4 and AII-a4, sabi b4, oxygen from 2.4 to 2.9 vol% (MTBE from 14 to 16.00vol%), EBMB was achieved from min. 95 IOB of steam voltage from min 68.52 to 71.20 kpa, density from 722 to 732 kg/m<3> and PONA - vol% composition in the specified concentration limits as well as the concentration limits of the components in vol% given in summary table 8 Example 9. combinations of components A-I-a4 and A-II-a4, with b|, b4i oxygen from 2.3 to 2.46 vol% (MTBE from 13.58 to 15.47vol%), an EBMB of min. 95 IOB was achieved, and steam pressure from min. 45.66 to 58.61 kpa. density from 732 to 738 kg/m<3>and PONA vol% composition within the specified concentration limits as well as the concentration limits of components in vol% given in summary table 9 Example10 combinations of components A-I-a2A-I-a^A-I-a7, with bibj, oxygen from 3.28 to 3.37 vol% (MTBE from 18.09 to 18.58), EBMB was achieved from min. 90 IOB of steam pressure from min. 45(46.01) to min. 50(51.89) kpa, density from 741 to 762 kg/m<3> and PONA - vol% composition in the specified concentration limits as well as the concentration limits of the components in vol% given in summary table 10
Primerom10.1 kombinacijama komponenti A-I-a2A-I-a^A-l-a7, sa bib3, kiseo- Example 10.1 with combinations of components A-I-a2A-I-a^A-l-a7, with bib3, acid-
nika do2,04 do 3,76 vol% ,(MTBE od 11.26 do20,7 vol%) ostvaren je EBMB od min 95 IOB ,napona pare od min 46,47 do max 55,04 kpa , gustine od 744 do 761 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli 10.1 range from 2.04 to 3.76 vol%, (MTBE from 11.26 to 20.7 vol%) achieved EBMB of min 95 IOB, vapor pressure from min 46.47 to max 55.04 kpa, density from 744 to 761 kg/m<3> and PONA - vol% composition in the specified concentration limits as well as the concentration limits of components in vol% given in summary table 10.1
Primer 11 kombinacijama komponenti A-I-ajiA-I-a4sa b3, kiseonika od 1,55 do 2,86 vol% ,ostvaren je EBMB od min 90 do min 95 IOB,napona pare od min 26,30 do max 30 kpa, gustine od 752 do 808 kg/m<3>i PONA vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli br 11 Example 11 with combinations of components A-I-ajiA-I-a4sa b3, oxygen from 1.55 to 2.86 vol%, EBMB from min 90 to min 95 IOB, vapor pressure from min 26.30 to max 30 kpa, density from 752 to 808 kg/m<3> and PONA vol% composition in the specified concentration limits as well as the concentration limits of the components in vol% were achieved summary table no. 11
Navodi primera kombinacija komponenti gde je ostvaren EBMB sa olefinima uLists examples of combinations of components where EBMB with olefins was achieved
tragovima ili do~max.l,50 vol%traces or up to ~ max. 1.50 vol%
Primerom12 kombinacijama komponentiAI-a3saAII-a3sabi, b4, b* kiseonika 2.7 mas% ,ostvaren je EBMB od min 90 IOB,napona pare od min 45 do min 55,58 kpa , gustine od 757 do 774 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnojtabeli 12Example 12 combinations of componentsAI-a3saAII-a3sabi, b4, b* oxygen 2.7 mass%, achieved EBMB of min 90 IOB, vapor pressure from min 45 to min 55.58 kpa, density from 757 to 774 kg/m<3> and PONA - vol% composition in the specified concentration limits as well as the concentration limits of components in vol% given in summary table 12
Primerom 12.1 kombinacijama komponenti, AI-a3sa b|, b^ i AI-a3sa bi, b4 , b$kiseonika od 2,7 do 3,52vol% (MTBE od 14,93 do 19,37vol%), ostvaren je EBMB od' min 95 IOB napona pare od min 49,51 do 65,3 kpa , gustine od 780 do 785 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% datih u zbirnoj tabeli 12.1 Example 12.1 with combinations of components, AI-a3sa b|, b^ and AI-a3sa bi, b4 , b$oxygen from 2.7 to 3.52vol% (MTBE from 14.93 to 19.37vol%), achieved EBMB of min 95 IOB vapor pressure from min 49.51 to 65.3 kpa, density from 780 to 785 kg/m<3>i PONA - vol% of the composition in the specified concentration limits as well as the concentration limits of the components in vol% given in summary table 12.1
Primerom 13 kombinacijama komponentiAII-a3sabi, b3, bsi AII-a3sab|, b$kiseonika 2,7 mas% ,ostvaren je EBMB od min90 do min 95 IOB,napona pare od min 37,28 do 47,17 kpa , gustine od 731 do 775 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnojtabeli 13 Mogućnost proizvodnje EBMB-a sa olefinima u tragovima je dat ovim specifičnim primerima 12,12.1 i 13 sa komponentom AI-a3i AII-a3, a postoji mogućnost proizvodnje istog sa komponentama Al-a?i AH-a?,zatim AI- aoi AII-ac, AI-a7i AII-a7u kombinacijama sa komponentama bi, b3, b4i b.s ,a što je u zamisli pronalaska.. Example 13 combinations of components AII-a3sabi, b3, bsi AII-a3sab|, b$oxygen 2.7 mass%, achieved EBMB from min90 to min 95 IOB, vapor pressure from min 37.28 to 47.17 kpa, density from 731 to 775 kg/m<3> and PONA - vol% composition within the specified concentration limits as well as the concentration limits of the components in vol% given in summary table 13 The possibility of producing EBMB with trace olefins is given by these specific examples 12,12.1 and 13 with the component AI-a3i AII-a3, and there is the possibility of producing the same with the components Al-a?i AHa?, then AI-aoi AII-ac, AI-a7i AII-a7in combinations with the components bi, b3, b4i b.s, which is in the idea of invention..
PRIMERI EBMB-a SA KRAJEM DESTILACIJE DO 150 C i OLEFINI U EXAMPLES OF EBMB WITH THE END OF DISTILLATION UP TO 150 C and OLEFINS U
TRAGOVIMA (u većini kombinacija ) TRACE (in most combinations)
Primerom 14 kombinacijama komponenti Al-a«sa bi , bs i kiseonika od 2,43 do 2,72 vol% , ostvaren je EBMB od min 90 do min 95 IOB sa krajem destilacije dol50°C ,napona pare od min 44,5 do 47,69 kpa , gustine od 735 do 748 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli 14 Example 14 with combinations of components Al-a« with bi, bs and oxygen from 2.43 to 2.72 vol%, achieved EBMB from min 90 to min 95 IOB with the end of distillation below 50°C, vapor pressure from min 44.5 to 47.69 kpa, density from 735 to 748 kg/m<3> and PONA - vol% composition within the specified concentration limits as well as concentration limits of components in vol% given in summary table 14
Primerom15 kombinacijama komponenti All-assa b], bs, i All-assa bi , b.skiseonika od 3,22 do 3,41 vol% , ostvaren je BMB od min 90 do min 95 IOB sa krajem destilacije đol50°C ,napona pare od min 45,45 do 62,59 kpa ,gustine od 688 do690 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli 15 Example 15 combinations of All-assa b], bs, and All-assa bi components, b.oxygen from 3.22 to 3.41 vol%, achieved BMB from min 90 to min 95 IOB with the end of distillation at 50°C, vapor pressure from min 45.45 to 62.59 kpa, density from 688 to 690 kg/m<3> and PONA - vol% composition in the specified concentration limits as well as the concentration limits of the components in vol% given in summary table 15
Primerom16 kombinacijama komponenti AI-a»sa bi, b7, napona pare >45, i AI-assa bib5 napona pare >50,kiseonika od 3,12 do 3,20 vol%(MTBE od 17,42 do 18,26vol%), ostvaren je EBMB od min 90 do min 95 IOB sa krajem destilacije dol50°C , gustine od 744 do 778 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u tabeli 16 Primerom 17kombinacijama komponentiAI-assabi ,b7,napona pare 43.40 do 43,72kpa, i Al-agsabi, b7napona pare>50,kiseonika od 2,49 do 2,8 voI% ,ostvaren je BMB 90 IOB sa krajem destilacije dol50"C, gustine od 774 do 782 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli17 Primerom18 kombinacijama komponenti AH-ag sa bi, b4, b7i AH-a« sa bi, b4, b7napona pare od59,97do 63,50 kpa ,kiseonika od 2,7 do 3,49 vol% , ostvaren je EBMB min 90 do min 95 IOB sa krajem destilacije dol50°C , gustine od 689 do 690 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnoj tabeli 18 Primerom 19kombinacijama komponentiAI-a9, AII-a9iAI- ai0sabi , bs, napona pare od 45 do 48,19 kpa,kiseonika do 2,7 vol % ,ostvaren je EBMB 90 IOB sa krajem destilacije dol50°C, gustine od 739 do 775kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato utabeli 19 Primerom 20kombinacijama komponentiAI-a9AII-a9iAI- amsabi,bj,napona pa-re od 45 do 50 kpa,kiseonika do 2,7 vol% ,ostvaren je EBMB 95 IOB sa krajem destilacije dol50°C, gustine od 738 do 748 kg/m<3>i PONA - vol% sastava u navedenim granicama koncentracije kao i granice koncentracija komponenti u vol% dato u zbirnojtabeli br.20 Example 16 combinations of components AI-a»sa bi, b7, vapor pressure >45, and AI-assa bib5 vapor pressure >50, oxygen from 3.12 to 3.20 vol% (MTBE from 17.42 to 18.26vol%), achieved EBMB from min 90 to min 95 IOB with the end of distillation below 50°C, density from 744 to 778 kg/m<3> and PONA - vol% of the composition in the specified concentration limits as well as the concentration limits of the components in vol% given in table 16. Using example 17 combinations of components AI-assabi, b7, vapor pressure 43.40 to 43.72 kpa, and Al-agsabi, b7 vapor pressure>50, oxygen from 2.49 to 2.8 voI%, BMB 90 IOB with the end of distillation was achieved dol50"C, density from 774 to 782 kg/m<3> and PONA - vol% composition in the specified concentration limits as well as the concentration limits of the components in vol% given in the summary table17 For example18 combinations of components AH-ag with bi, b4, b7 and AH-a« with bi, b4, b7 steam pressure from 59.97 to 63.50 kpa, oxygen from 2.7 to 3.49 vol%, EBMB min 90 to min was achieved 95 IOB with the end of distillation below 50°C, density from 689 to 690 kg/m<3> and PONA - vol% composition in the specified concentration limits as well as the concentration limits of components in vol% given in summary table 18 Example 19combinations of components AI-a9, AII-a9iAI-ai0sabi, bs, vapor pressure from 45 to 48.19 kpa, oxygen up to 2.7 vol % , EBMB 90 IOB was achieved with the end of distillation below 50°C, density from 739 to 775 kg/m<3> and PONA - vol% composition in the specified concentration limits as well as the concentration limits of the components in vol% given in table 19 Example 20 combinations of components AI-a9AII-a9iAI- amsabi,bj, steam pressure from 45 to 50 kpa, oxygen up to 2.7 vol%, EBMB was achieved 95 IOB with the end of distillation below 50°C, density from 738 to 748 kg/m<3> and PONA - vol% of the composition in the specified concentration limits as well as the concentration limits of the components in vol% given in summary table no. 20
Pronalazak je opisan na specifičnim primerima kombinacija komponenti na kojima se isti bazira , ali su moguće i druge varijante kombinacija istih , što je u okviru zamisli pronalaska, definisano opisom , primerima i patentnim zahtevima. The invention is described on specific examples of combinations of components on which it is based, but other variants of combinations of the same are possible, which is within the scope of the invention, defined by the description, examples and patent claims.
Claims (9)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| YUP-1041/04A RS51276B (en) | 2004-11-30 | 2004-11-30 | ENVIRONMENTALLY FREE OIL ENGINE |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| YUP-1041/04A RS51276B (en) | 2004-11-30 | 2004-11-30 | ENVIRONMENTALLY FREE OIL ENGINE |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RS104104A RS104104A (en) | 2007-02-05 |
| RS51276B true RS51276B (en) | 2010-12-31 |
Family
ID=43645934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| YUP-1041/04A RS51276B (en) | 2004-11-30 | 2004-11-30 | ENVIRONMENTALLY FREE OIL ENGINE |
Country Status (1)
| Country | Link |
|---|---|
| RS (1) | RS51276B (en) |
-
2004
- 2004-11-30 RS YUP-1041/04A patent/RS51276B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RS104104A (en) | 2007-02-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103210067B (en) | The turbine of biogenetic derivation and diesel-fuel | |
| US10683462B2 (en) | Aviation gasoline composition, its preparation and use | |
| CN105062577B (en) | Fuel composition for internal combustion engine | |
| PL194561B1 (en) | Method of reducing the vapour pressure of ethanol-containing motor fuels for spark ignition combustion engines | |
| RU2006126121A (en) | COMPOSITION AND METHOD FOR MIXING GASOLINS IN TERMINALS | |
| CN104593095A (en) | High octane unleaded aviation gasoline | |
| RS51276B (en) | ENVIRONMENTALLY FREE OIL ENGINE | |
| CN105255527B (en) | Rich alkane gasification oxygenation clean gasoline | |
| CN107849469B (en) | Gasoline composition with improved octane number | |
| RU2549179C1 (en) | Alternative motor fuel | |
| JP4920185B2 (en) | Gasoline composition | |
| JP2024516726A (en) | Blended gasoline composition | |
| JP4626954B2 (en) | Gasoline composition | |
| Алиева et al. | Effect of oxygen-containing additives on the fuel properties | |
| RU2167918C1 (en) | Lead-free gasoline composition | |
| RU2212433C1 (en) | Gasoline additive and fuel composition | |
| JP4294519B2 (en) | Gasoline composition | |
| CA3014883C (en) | Process for preparing tier 3 reference fuel | |
| RU2640199C1 (en) | Alternative car fuel | |
| WO2018122691A1 (en) | Lead-free, oxygenated, high-octane gasoline blend | |
| US20100000483A1 (en) | Gasoline compositions | |
| Roy et al. | Boosting Octane Number of Gasoline by Natural Gas Concentrated with Methane. | |
| RU2167916C1 (en) | Lead-free gasoline composition | |
| WO2024054196A1 (en) | Method for producing an alternative motor fuel for petrol engines | |
| UA125999C2 (en) | Composition for production of high-octane gasoline for spark-ignition engines using bioadditives |