RU2012121872A - Способ получения этанола из уксусной кислоты с использованием кислотных катализаторов - Google Patents

Способ получения этанола из уксусной кислоты с использованием кислотных катализаторов Download PDF

Info

Publication number: RU2012121872A
Authority: RU; Russia
Prior art keywords: group; metal; metal oxides; catalyst comprises; acid modifier
Prior art date: 2009-10-26

Application number

RU2012121872/04A

Other languages

English (en)

Russian (ru)

Inventor

Радмила ЕВТИЦ

Виктор Дж. ДЖОНСТОН

Р. Джей УОРНЕР

Хейко ВИНЕР

Original Assignee

Селаниз Интернэшнл Корпорейшн

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2009-10-26

Filing date

2010-10-26

Publication date

2013-12-10

2009-10-26 Priority claimed from US12/588,727 external-priority patent/US8309772B2/en

2010-02-02 Priority claimed from US12/699,024 external-priority patent/US8680317B2/en

2010-02-02 Priority claimed from US12/698,947 external-priority patent/US8471075B2/en

2010-08-06 Priority claimed from US12/852,269 external-priority patent/US8304586B2/en

2010-08-06 Priority claimed from US12/852,227 external-priority patent/US8309773B2/en

2010-10-26 Application filed by Селаниз Интернэшнл Корпорейшн filed Critical Селаниз Интернэшнл Корпорейшн

2013-12-10 Publication of RU2012121872A publication Critical patent/RU2012121872A/ru

Links

QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title claims abstract 21
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract 14
238000004519 manufacturing process Methods 0.000 title claims abstract 3
239000003377 acid catalyst Substances 0.000 title 1
238000000034 method Methods 0.000 claims abstract 22
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 17
229910052751 metal Inorganic materials 0.000 claims abstract 13
239000002184 metal Substances 0.000 claims abstract 13
239000003054 catalyst Substances 0.000 claims abstract 11
239000002253 acid Substances 0.000 claims abstract 10
229910044991 metal oxide Inorganic materials 0.000 claims abstract 10
239000003607 modifier Substances 0.000 claims abstract 10
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract 10
150000004706 metal oxides Chemical class 0.000 claims abstract 9
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract 8
239000000377 silicon dioxide Substances 0.000 claims abstract 8
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 7
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract 6
229910052702 rhenium Inorganic materials 0.000 claims abstract 6
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims abstract 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 5
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract 5
239000000463 material Substances 0.000 claims abstract 5
229910052697 platinum Inorganic materials 0.000 claims abstract 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract 4
239000000203 mixture Substances 0.000 claims abstract 4
229910052763 palladium Inorganic materials 0.000 claims abstract 4
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract 3
239000011651 chromium Substances 0.000 claims abstract 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract 2
235000012241 calcium silicate Nutrition 0.000 claims abstract 2
229910052918 calcium silicate Inorganic materials 0.000 claims abstract 2
OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims abstract 2
229910052799 carbon Inorganic materials 0.000 claims abstract 2
238000006243 chemical reaction Methods 0.000 claims abstract 2
229910052804 chromium Inorganic materials 0.000 claims abstract 2
229910017052 cobalt Inorganic materials 0.000 claims abstract 2
239000010941 cobalt Substances 0.000 claims abstract 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract 2
229910052802 copper Inorganic materials 0.000 claims abstract 2
239000010949 copper Substances 0.000 claims abstract 2
229910021485 fumed silica Inorganic materials 0.000 claims abstract 2
229910052741 iridium Inorganic materials 0.000 claims abstract 2
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract 2
229910052742 iron Inorganic materials 0.000 claims abstract 2
229910052750 molybdenum Inorganic materials 0.000 claims abstract 2
239000011733 molybdenum Substances 0.000 claims abstract 2
229910052759 nickel Inorganic materials 0.000 claims abstract 2
229910052762 osmium Inorganic materials 0.000 claims abstract 2
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims abstract 2
229910052703 rhodium Inorganic materials 0.000 claims abstract 2
239000010948 rhodium Substances 0.000 claims abstract 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract 2
229910052719 titanium Inorganic materials 0.000 claims abstract 2
239000010936 titanium Substances 0.000 claims abstract 2
239000004408 titanium dioxide Substances 0.000 claims abstract 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract 2
229910052721 tungsten Inorganic materials 0.000 claims abstract 2
239000010937 tungsten Substances 0.000 claims abstract 2
229910052725 zinc Inorganic materials 0.000 claims abstract 2
239000011701 zinc Substances 0.000 claims abstract 2
235000012239 silicon dioxide Nutrition 0.000 claims 4
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims 3
238000005984 hydrogenation reaction Methods 0.000 claims 2
229910018072 Al 2 O 3 Inorganic materials 0.000 claims 1
229910015902 Bi 2 O 3 Inorganic materials 0.000 claims 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
229910010413 TiO 2 Inorganic materials 0.000 claims 1
229910052782 aluminium Inorganic materials 0.000 claims 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
239000012876 carrier material Substances 0.000 claims 1
239000007789 gas Substances 0.000 claims 1
229910052739 hydrogen Inorganic materials 0.000 claims 1
239000001257 hydrogen Substances 0.000 claims 1
239000000376 reactant Substances 0.000 claims 1
229910052814 silicon oxide Inorganic materials 0.000 claims 1
239000012808 vapor phase Substances 0.000 claims 1
-1 VIB metal oxides Chemical class 0.000 abstract 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/94—Use of additives, e.g. for stabilisation
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/08—Ethanol
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Physics & Mathematics (AREA)
Thermal Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

RU2012121872/04A 2009-10-26 2010-10-26 Способ получения этанола из уксусной кислоты с использованием кислотных катализаторов RU2012121872A (ru)

Applications Claiming Priority (17)

Application Number	Priority Date	Filing Date	Title
US12/588,727 US8309772B2 (en)	2008-07-31	2009-10-26	Tunable catalyst gas phase hydrogenation of carboxylic acids
US12/588,727		2009-10-26
US30081510P	2010-02-02	2010-02-02
US12/699,024 US8680317B2 (en)	2008-07-31	2010-02-02	Processes for making ethyl acetate from acetic acid
US12/699,024		2010-02-02
US12/698,947 US8471075B2 (en)	2008-07-31	2010-02-02	Processes for making ethanol from acetic acid
US61/300,815		2010-02-02
US12/698,947		2010-02-02
US33269910P	2010-05-07	2010-05-07
US33269610P	2010-05-07	2010-05-07
US61/332,699		2010-05-07
US61/332,696		2010-05-07
US12/852,269 US8304586B2 (en)	2010-02-02	2010-08-06	Process for purifying ethanol
US12/852,227 US8309773B2 (en)	2010-02-02	2010-08-06	Process for recovering ethanol
US12/852,269		2010-08-06
US12/852,227		2010-08-06
PCT/US2010/054136 WO2011056597A2 (fr)	2009-10-26	2010-10-26	Procédé de fabrication d'éthanol à partir d'acide acétique à l'aide de catalyseurs acides

Publications (1)

Publication Number	Publication Date
RU2012121872A true RU2012121872A (ru)	2013-12-10

Family

ID=56291204

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
RU2012121872/04A RU2012121872A (ru)	2009-10-26	2010-10-26	Способ получения этанола из уксусной кислоты с использованием кислотных катализаторов

Country Status (12)

Country	Link
EP (1)	EP2493610A2 (fr)
JP (1)	JP2013508424A (fr)
KR (1)	KR20120086717A (fr)
CN (1)	CN102307657B (fr)
AU (1)	AU2010315554A1 (fr)
BR (1)	BR112012009824A2 (fr)
CA (1)	CA2778959A1 (fr)
MX (1)	MX2012004842A (fr)
NZ (1)	NZ599463A (fr)
RU (1)	RU2012121872A (fr)
WO (1)	WO2011056597A2 (fr)
ZA (1)	ZA201202850B (fr)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8552225B2 (en) *	2010-02-02	2013-10-08	Celanese International Corporation	Process for vaporizing acetic acid for hydrogenation processes to produce ethanol
US9272970B2 (en)	2010-07-09	2016-03-01	Celanese International Corporation	Hydrogenolysis of ethyl acetate in alcohol separation processes
US9073816B2 (en)	2011-04-26	2015-07-07	Celanese International Corporation	Reducing ethyl acetate concentration in recycle streams for ethanol production processes
CN103080053B (zh) *	2011-04-26	2015-08-12	国际人造丝公司	使用叠置床反应器生产乙醇的方法
WO2012149137A1 (fr)	2011-04-26	2012-11-01	Celanese International Corporation	Procédé de production d'éthanol à partir d'une charge d'acide acétique et d'une charge d'acétate d'éthyle recyclé
WO2013019230A1 (fr) *	2011-08-03	2013-02-07	Celanese International Corporation	Procédé de séparation d'éthanol pauvre en acide
US8895786B2 (en)	2011-08-03	2014-11-25	Celanese International Corporation	Processes for increasing alcohol production
US8440866B2 (en)	2011-08-03	2013-05-14	Celanese International Corporation	Process for separating ethanol having low acid
DE102012002274A1 (de) *	2012-02-06	2013-08-08	Oxea Gmbh	Verfahren zur Koppelproduktion von Vinylestern und Essigsäurefolgeprodukten oder Propionsäurefolgeprodukten
US9051235B2 (en) *	2012-02-07	2015-06-09	Celanese International Corporation	Process for producing ethanol using a molar excess of hydrogen
CN102584524A (zh) *	2012-02-29	2012-07-18	付顺林	一种酒精回收塔
US8802903B2 (en) *	2012-03-13	2014-08-12	Celanese International Corporation	Stacked bed reactor with diluents for producing ethanol
CN103373899B (zh) *	2012-04-27	2016-01-06	上海浦景化工技术股份有限公司	一种醋酸或醋酸酯催化加氢反应制乙醇的装置及方法
CN103570495B (zh) *	2012-07-25	2016-02-17	上海浦景化工技术股份有限公司	一种多段醋酸或醋酸酯催化加氢制乙醇的装置及方法
CN103664524B (zh) *	2012-09-05	2016-01-13	中国石油化工股份有限公司	1,4-环己烷二甲酸加氢制1,4-环己烷二甲醇的方法
US9834491B2 (en) *	2013-03-20	2017-12-05	Cj Cheiljedang Corporation	Method for producing bio-based homoserine lactone and bio-based organic acid from O-acyl homoserine produced by microorganisms
DE102013106790A1 (de)	2013-06-28	2014-12-31	Oxea Gmbh	Verfahren zur Herstellung von 1,3-Butandiol
DE102013106787A1 (de)	2013-06-28	2014-12-31	Oxea Gmbh	Verfahren zur Herstellung von n-Butanderivaten
JP2016026864A (ja) *	2014-06-25	2016-02-18	積水化学工業株式会社	酢酸エチル合成用の触媒、酢酸エチルの製造装置及び酢酸エチルの製造方法
CN104307557B (zh) *	2014-09-19	2016-08-17	东营海纳新材料有限公司	一种二氟乙酸甲酯加氢制备二氟乙醇的催化剂的制备方法
WO2016175747A1 (fr) *	2015-04-27	2016-11-03	Celanese International Corporation	Catalyseurs d'hydrogénation comprenant un oxyde mixte contenant du bismuth et procédé de production d'éthanol
JP2019107590A (ja) *	2017-12-15	2019-07-04	株式会社ダイセル	触媒、アルデヒド類および／またはアルコール類の製造方法
EP4059916A1 (fr)	2021-03-15	2022-09-21	Linde GmbH	Méthode et installation pour la production d'un produit hydrocarboné
US20250129303A1 (en)	2021-12-08	2025-04-24	Linde Gmbh	Process and Plant for Producing One or More Hydrocarbons
CN114939414A (zh) *	2022-06-23	2022-08-26	山东亮剑环保新材料有限公司	一种负载型氧化铜催化剂的制备方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2882244A (en)	1953-12-24	1959-04-14	Union Carbide Corp	Molecular sieve adsorbents
US3130007A (en)	1961-05-12	1964-04-21	Union Carbide Corp	Crystalline zeolite y
US5026908A (en)	1984-05-03	1991-06-25	Hoechst Celanese Corporation	Methanol carbonylation process
US5001259A (en)	1984-05-03	1991-03-19	Hoechst Celanese Corporation	Methanol carbonylation process
US5144068A (en)	1984-05-03	1992-09-01	Hoechst Celanese Corporation	Methanol carbonylation process
GB8509530D0 (en) *	1985-04-13	1985-05-15	Bp Chem Int Ltd	Hydrogenation of carboxylic acids
CA1299195C (fr)	1986-06-16	1992-04-21	G. Paull Torrence	Ajout d'hydrogene a un gaz d'alimentation contenant du monoxyde de carboneen vue de produire de l'acide acetique par carbonylateur du methanol
GB8828616D0 (en) *	1988-12-07	1989-01-11	Bp Chem Int Ltd	Chemical process
JPH06116182A (ja) *	1992-10-09	1994-04-26	Mitsubishi Kasei Corp	有機カルボン酸及び／又は有機カルボン酸エステルの水素化方法
US5821111A (en)	1994-03-31	1998-10-13	Bioengineering Resources, Inc.	Bioconversion of waste biomass to useful products
USRE35377E (en)	1993-05-27	1996-11-12	Steinberg; Meyer	Process and apparatus for the production of methanol from condensed carbonaceous material
US5599976A (en)	1995-04-07	1997-02-04	Hoechst Celanese Corporation	Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process
IN192600B (fr)	1996-10-18	2004-05-08	Hoechst Celanese Corp
US6232352B1 (en)	1999-11-01	2001-05-15	Acetex Limited	Methanol plant retrofit for acetic acid manufacture
US6627770B1 (en)	2000-08-24	2003-09-30	Celanese International Corporation	Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process
US6657078B2 (en)	2001-02-07	2003-12-02	Celanese International Corporation	Low energy carbonylation process
US6685754B2 (en)	2001-03-06	2004-02-03	Alchemix Corporation	Method for the production of hydrogen-containing gaseous mixtures
US7115772B2 (en)	2002-01-11	2006-10-03	Celanese International Corporation	Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream
US7005541B2 (en)	2002-12-23	2006-02-28	Celanese International Corporation	Low water methanol carbonylation process for high acetic acid production and for water balance control
US7208624B2 (en)	2004-03-02	2007-04-24	Celanese International Corporation	Process for producing acetic acid
US8502001B2 (en) *	2007-11-14	2013-08-06	Bp P.L.C.	Process for the production of alcohol from a carbonaceous feedstock
US8471075B2 (en)	2008-07-31	2013-06-25	Celanese International Corporation	Processes for making ethanol from acetic acid
US7608744B1 (en)	2008-07-31	2009-10-27	Celanese International Corporation	Ethanol production from acetic acid utilizing a cobalt catalyst
US7863489B2 (en) *	2008-07-31	2011-01-04	Celanese International Corporation	Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
US8680317B2 (en)	2008-07-31	2014-03-25	Celanese International Corporation	Processes for making ethyl acetate from acetic acid
US7855303B2 (en) *	2008-11-14	2010-12-21	Celanese International Corporation	Integrated process for the production of vinyl acetate from acetic acid via ethylene

2010
- 2010-10-26 CN CN201080003928.5A patent/CN102307657B/zh not_active Expired - Fee Related
- 2010-10-26 KR KR1020127013286A patent/KR20120086717A/ko not_active Withdrawn
- 2010-10-26 EP EP10773795A patent/EP2493610A2/fr not_active Withdrawn
- 2010-10-26 RU RU2012121872/04A patent/RU2012121872A/ru unknown
- 2010-10-26 AU AU2010315554A patent/AU2010315554A1/en not_active Abandoned
- 2010-10-26 NZ NZ599463A patent/NZ599463A/en not_active IP Right Cessation
- 2010-10-26 BR BR112012009824A patent/BR112012009824A2/pt not_active Application Discontinuation
- 2010-10-26 JP JP2012535458A patent/JP2013508424A/ja active Pending
- 2010-10-26 WO PCT/US2010/054136 patent/WO2011056597A2/fr not_active Ceased
- 2010-10-26 CA CA2778959A patent/CA2778959A1/fr not_active Abandoned
- 2010-10-26 MX MX2012004842A patent/MX2012004842A/es unknown
2012
- 2012-04-18 ZA ZA2012/02850A patent/ZA201202850B/en unknown

Also Published As

Publication number	Publication date
KR20120086717A (ko)	2012-08-03
AU2010315554A1 (en)	2012-05-17
CN102307657A (zh)	2012-01-04
JP2013508424A (ja)	2013-03-07
CN102307657B (zh)	2014-10-08
ZA201202850B (en)	2013-06-26
BR112012009824A2 (pt)	2016-11-22
WO2011056597A3 (fr)	2011-07-14
WO2011056597A2 (fr)	2011-05-12
EP2493610A2 (fr)	2012-09-05
CA2778959A1 (fr)	2011-05-12
MX2012004842A (es)	2012-05-29
NZ599463A (en)	2014-05-30

Publication	Publication Date	Title
RU2012121872A (ru)	2013-12-10	Способ получения этанола из уксусной кислоты с использованием кислотных катализаторов
JP7222092B2 (ja)	2023-02-14	１，４－シクロヘキサンジメタノールの製造方法
CA2763124C (fr)	2018-05-01	Catalyseurs de reformage a la vapeur de methanol
CN101279271B (zh)	2010-09-29	用于甲烷催化部分氧化制备合成气的催化剂及其制备方法
RU2011147128A (ru)	2013-05-27	Медь- и марганецсодержащие катализаторы на основе неблагородных металлов для окисления монооксида углерода и летучих органических соединений
TW201016648A (en)	2010-05-01	Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
US10618038B2 (en)	2020-04-14	Functionalized boron nitride catalysts for the production of light olefins from alkane feeds via oxidative dehydrogenation
US20120197029A1 (en)	2012-08-02	Method for producing cyclicised compounds from organic acids having from 4 to 6 carbon atoms
WO2018085957A1 (fr)	2018-05-17	Procédé de production de composés aromatiques comprenant au moins deux fonctions amine
Nakagawa et al.	2015	Combination of supported bimetallic rhodium–molybdenum catalyst and cerium oxide for hydrogenation of amide
CN107427819A (zh)	2017-12-01	用于选择性甲烷化一氧化碳的钌‑铼基催化剂
Vasiliadou et al.	2011	Parameters affecting the formation of 1, 2-propanediol from glycerol over Ru/SiO2 catalyst
CN103769149A (zh)	2014-05-07	由丙烯醛氧化制备丙烯酸的催化剂、制备方法及其用途
US20140148616A1 (en)	2014-05-29	Processo catalitico oxidativo para sintese de acido latico
US10023549B2 (en)	2018-07-17	Process for the production of 1,4-butanediol and tetrahydrofuran from furan
dos Santos et al.	2005	Performance of RuSn catalysts supported on different oxides in the selective hydrogenation of dimethyl adipate
KR20190135799A (ko)	2019-12-09	산화마그네슘-알루미나 복합 지지체를 이용한 알코올의 이산화탄소 개질 반응용 촉매 및 이를 이용한 합성가스의 제조방법
US9415375B2 (en)	2016-08-16	Catalyst compositions for producing mixed alcohols
CN106513001A (zh)	2017-03-22	一种由合成气合成乙醇的催化剂及制法和应用
EP2488483B1 (fr)	2014-06-25	Procédé de préparation de 2-(2-aminoéthoxy) éthanol (2aee) et morpholine avec 2aee: morpholine >3
JPWO2018146978A1 (ja)	2020-01-09	３，４−ジヒドロキシテトラヒドロフランの還元反応用触媒及び３，４−ジヒドロキシテトラヒドロフラン還元物の製造方法
CN115364861B (zh)	2024-01-26	一种加氢催化剂组合物及其应用和草酸二甲酯加氢合成乙二醇的方法
WO2012050804A1 (fr)	2012-04-19	Utilisation de compositions de catalyseur à base d'un hétéropoly composé de type anderson dans la conversion de gaz de synthèse en des oxygénats
EP4663290A1 (fr)	2025-12-17	Catalyseur contenant de l'oxo-carbonate de ruthénium comme phase active pour l'hyrogénation de co2 en méthane à basses températures de réaction
EP2462101B1 (fr)	2013-07-31	Procédé de préparation d'un ester