RU2012157780A - Способ получения метана из биомассы - Google Patents

Способ получения метана из биомассы Download PDF

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RU2012157780A
RU2012157780A RU2012157780/04A RU2012157780A RU2012157780A RU 2012157780 A RU2012157780 A RU 2012157780A RU 2012157780/04 A RU2012157780/04 A RU 2012157780/04A RU 2012157780 A RU2012157780 A RU 2012157780A RU 2012157780 A RU2012157780 A RU 2012157780A
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methane
product
stream
hydroconversion
coal
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RU2012157780/04A
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RU2573567C2 (ru
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Терри Л. МАРКЕР
Ларри Дж. ФЕЛИКС
Мартин Б. ЛИНК
Ховард С. Мейер
Деннис Леппин
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Гэз Текнолоджи Инститьют
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Abstract

1. Способ получения метана из биомассы, включающий следующие стадии:а) гидропиролиз биомассы в реакторном сосуде гидропиролиза, содержащем молекулярный водород и катализатор дезоксигенирования, при температуре гидропиролиза выше приблизительно 1000°F (538°C) и при давлении гидропиролиза в интервале от приблизительно 100 до приблизительно 600 фунт/кв.дюйм (690-4140 кПа) с получением одиночного выпускного потока продукта гидропиролиза, содержащего уголь и газ;b) отделение указанного угля от указанного продукта гидропиролиза с получением продукта гидропиролиза со сниженным содержанием угля;с) гидроконверсия указанного продукта гидропиролиза со сниженным содержанием угля в реакторном сосуде гидроконверсии с использованием катализатора гидроконверсии при температуре гидроконверсии выше приблизительно 800°F (427°C) и при давлении гидроконверсии в интервале от приблизительно 100 до приблизительно 600 фунт/кв.дюйм (690-4140 кПа) с получением продукта гидроконверсии;d) охлаждение и введение указанного продукта гидроконверсии в реактор конверсии вода-газ, получение продукта конверсии вода-газ, содержащего воду и газообразную смесь, содержащую СО, Ни метан; ие) разделение указанных СО, Ни метана с получением потока СО, потока Ни потока метанового продукта.2. Способ по п. 1, в котором, по меньшей мере, часть указанного потока метанового продукта вводят в установку парового реформинга, в которой указанный метан подвергается реформингу с получением СО-реформера и Н-реформера.3. Способ по п. 2, в котором, по меньшей мере, часть указанного Н-реформера вводится в реактор метанирования вместе с потоком метанового продукта, взаимодействует с лю

Claims (20)

1. Способ получения метана из биомассы, включающий следующие стадии:
а) гидропиролиз биомассы в реакторном сосуде гидропиролиза, содержащем молекулярный водород и катализатор дезоксигенирования, при температуре гидропиролиза выше приблизительно 1000°F (538°C) и при давлении гидропиролиза в интервале от приблизительно 100 до приблизительно 600 фунт/кв.дюйм (690-4140 кПа) с получением одиночного выпускного потока продукта гидропиролиза, содержащего уголь и газ;
b) отделение указанного угля от указанного продукта гидропиролиза с получением продукта гидропиролиза со сниженным содержанием угля;
с) гидроконверсия указанного продукта гидропиролиза со сниженным содержанием угля в реакторном сосуде гидроконверсии с использованием катализатора гидроконверсии при температуре гидроконверсии выше приблизительно 800°F (427°C) и при давлении гидроконверсии в интервале от приблизительно 100 до приблизительно 600 фунт/кв.дюйм (690-4140 кПа) с получением продукта гидроконверсии;
d) охлаждение и введение указанного продукта гидроконверсии в реактор конверсии вода-газ, получение продукта конверсии вода-газ, содержащего воду и газообразную смесь, содержащую СО2, Н2 и метан; и
е) разделение указанных СО2, Н2 и метана с получением потока СО2, потока Н2 и потока метанового продукта.
2. Способ по п. 1, в котором, по меньшей мере, часть указанного потока метанового продукта вводят в установку парового реформинга, в которой указанный метан подвергается реформингу с получением СО2-реформера и Н2-реформера.
3. Способ по п. 2, в котором, по меньшей мере, часть указанного Н2-реформера вводится в реактор метанирования вместе с потоком метанового продукта, взаимодействует с любым остаточным СО и/или СО2 в потоке метанового продукта и образует дополнительный метан.
4. Способ по п. 2, в котором указанная вода вводится в указанную установку парового реформинга для реформинга указанного метана.
5. Способ по п. 4, в котором дополнительная вода из внешнего по отношению к способу источника вводится в указанную установку парового реформинга для реформинга указанного метана.
6. Способ по п. 1, в котором первая часть указанного потока метанового продукта вводится в установку сжигания и сжигается, нагревая тем самым вторую часть указанного потока метанового продукта, и указанная вторая часть указанного потока метанового продукта вводится вместе с водяным паром в установку парового реформинга метана, образуя продукт-реформер СО, СО2 и Н2.
7. Способ по п. 1, в котором часть угля, отделенного от потока продуктов гидропиролиза, сжигается в печи, нагревая указанный поток метанового продукта, и указанный поток метанового продукта вводится в установку парового реформинга вместе с водой, образуя СО2-реформер и Н2-реформер.
8. Способ по п. 2, в котором часть указанного угля сжигается в камере сгорания парового котла с получением водяного пара, при этом этот пар вводится в установку парового реформинга вместе с частью указанного потока метана.
9. Способ по п. 6, в котором, по меньшей мере, часть указанного Н2-реформера вводится в реактор метанирования, где он взаимодействует с любым остаточным СО2 в потоке метанового продукта и образует дополнительный метан.
10. Способ по п. 2, в котором, по меньшей мере, часть указанного Н2-реформера рециклируют в указанный реакторный сосуд гидропиролиза для указанного гидропиролиза указанной биомассы.
11. Способ по п. 1, в котором указанный метан отделяется от указанной газовой смеси способом извлечения гидрата метана для того, чтобы снизить пропорцию потока метанового продукта, содержащего дополнительное количество Н2, который затем сразу рециклируют на стадию гидропиролиза.
12. Способ по п. 1, в котором, по меньшей мере, один из указанного катализатора дезоксигенирования и указанного катализатора гидроконверсии является стеклокерамическим материалом.
13. Способ по п. 1, в котором указанный гидропиролиз выполняется при массовой часовой пространственной скорости в интервале от приблизительно 0,2 до приблизительно 10 г биомассы/г катализатора/ч.
14. Способ по п. 1, в котором указанная гидроконверсия выполняется при массовой часовой пространственной скорости в интервале от приблизительно 0,2 до приблизительно 3 г биомассы/г катализатора/ч.
15. Способ по п. 1, в котором указанным реакторным сосудом гидропиролиза является реактор с псевдоожиженным слоем, содержащий псевдоожиженный слой.
16. Способ по п. 15, в котором время пребывания газа в указанном реакторном сосуде гидропиролиза составляет менее приблизительно одной минуты.
17. Способ по п. 15, в котором указанный уголь удаляется из указанного реактора с псевдоожиженным слоем по существу только из вышеуказанного псевдоожиженного слоя.
18. Способ по п. 1, в котором указанным реакторным сосудом гидропиролиза является реактор с псевдоожиженным слоем, содержащий псевдоожиженный слой, и указанный уголь удаляется из указанного реактора с псевдоожиженным слоем энергетическим отделением угля с использованием, по меньшей мере, одного из инерционного, электростатического и магнитного способов.
19. Способ по п. 1, в котором указанный катализатор дезоксигенирования выбран из группы, состоящей из сульфидированного СоМо, сульфидированного NiMo, каталитически активной стеклокерамики, боксита, угля и их смесей и комбинаций.
20. Способ по п. 1, в котором фильтр горячего газа, предварительно нагретый введением смесей или одиночных выбранных адсорбентов, используется для удаления выбранных загрязнений из газа, выходящего из одного из реакторного сосуда гидропиролиза и реакторного сосуда гидроконверсии.
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Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2501788A4 (en) 2009-11-18 2013-12-04 G4 Insights Inc BY SORPTION REINFORCED METHANIZATION OF BIOMASS
EP2501787B1 (en) * 2009-11-18 2015-10-07 G4 Insights Inc. Method for biomass hydrogasification
US8383871B1 (en) * 2010-09-03 2013-02-26 Brian G. Sellars Method of hydrogasification of biomass to methane with low depositable tars
US8841495B2 (en) 2011-04-18 2014-09-23 Gas Technology Institute Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor
DE112012002578T5 (de) * 2011-06-23 2014-08-07 Foster Wheeler Usa Corp. Pyrolyse von Biomasse bei der Herstellung von Biokraftstoffen
US8859831B2 (en) * 2011-08-02 2014-10-14 Gas Technology Institute Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors
US8203024B2 (en) 2011-08-23 2012-06-19 Advanced Toffefaction Systems, LLC Torrefaction systems and methods including catalytic oxidation and/or reuse of combustion gases directly in a torrefaction reactor, cooler, and/or dryer/preheater
IN2014CN02732A (ru) * 2011-11-14 2015-07-03 Shell Int Research
DE102011086499A1 (de) * 2011-11-16 2013-05-16 New Power Pack GmbH Vorrichtung und Verfahren zur Energiegewinnung aus Biomasse
GB2499404B (en) 2012-02-14 2019-08-14 Anergy Ltd Fuel processing using pyrolyser
CA2866278C (en) 2012-03-07 2017-09-26 Research Triangle Institute Catalytic biomass pyrolysis process
US10155908B2 (en) 2012-03-07 2018-12-18 Research Triangle Institute Catalyst compositions and use thereof in catalytic biomass pyrolysis
FI2895630T3 (en) 2012-09-14 2023-08-15 Voestalpine Stahl Gmbh METHOD FOR STORING DISCONTINUOUSLY OBTAINED ENERGY IN IRON ORE REDUCTION PROCESS
US20160032196A1 (en) * 2013-03-15 2016-02-04 Battelle Memorial Institute Vapor Phase Catalytic Reactor for Upgarde of Fuels Produced by Fast Pyrolysis of Biomass
AU2014278607C1 (en) * 2013-06-12 2018-10-04 Gas Technology Institute Entrained-flow gasifier and method for removing molten slag
WO2015038754A1 (en) * 2013-09-11 2015-03-19 Research Triangle Institute Reactive catalytic fast pyrolysis process and system
FR3012468B1 (fr) * 2013-10-28 2016-03-11 Gdf Suez Dispositif et procede de production de gaz naturel de substitution et reseau le comportant
DK3099762T3 (da) 2014-01-28 2020-01-20 Shell Int Research Konvertering af biomasse- eller restaffaldsmateriale til biobrændstoffer
US10190056B2 (en) 2014-07-01 2019-01-29 Shell Oil Company Conversion of solid biomass into a liquid hydrocarbon material
AU2015282667B2 (en) 2014-07-01 2017-10-19 Shell Internationale Research Maatschappij B.V. Conversion of solid biomass into a liquid hydrocarbon material
US9650574B2 (en) * 2014-07-01 2017-05-16 Gas Technology Institute Hydropyrolysis of biomass-containing feedstocks
AU2015282725B2 (en) 2014-07-01 2017-11-30 Shell Internationale Research Maatschappij B.V. Conversion of solid biomass into a liquid hydrocarbon material
WO2016009333A1 (en) 2014-07-17 2016-01-21 Sabic Global Technologies B.V. Upgrading hydrogen deficient streams using hydrogen donor streams in a hydropyrolysis process
US10392566B2 (en) 2015-04-27 2019-08-27 Gas Technology Institute Co-processing for control of hydropyrolysis processes and products thereof
DK3289047T3 (da) * 2015-04-27 2019-11-18 Shell Int Research Konvertering af biomasse eller restaffaldsmateriale til biobrændsler.
PL231090B1 (pl) * 2015-07-02 2019-01-31 Jjra Spolka Z Ograniczona Odpowiedzialnoscia Sposób i układ wytwarzania biometanu i ekometanu
CN105132056B (zh) * 2015-08-25 2018-07-06 中国五环工程有限公司 褐煤蒸汽加氢气化制天然气工艺及其系统
MY189091A (en) * 2015-09-07 2022-01-25 Shell Int Research Conversion of biomass into a liquid hydrocarbon material
EP3353263A1 (en) 2015-09-25 2018-08-01 Shell International Research Maatschappij B.V. Conversion of biomass into methane
CN108137432B (zh) 2015-10-07 2020-01-17 美国燃气技术研究院 将甲烷转化成包括液体燃料的更高级烃的方法
CN106566566A (zh) * 2015-10-10 2017-04-19 中国石油化工股份有限公司 一种含氧原料的甲烷化方法
US9822048B2 (en) * 2015-12-14 2017-11-21 Shell Oil Company Method of extending biomass conversion catalyst life
US10106746B2 (en) * 2016-12-08 2018-10-23 Shell Oil Company Methods and systems for supplying hydrogen to a hydrocatalytic reaction
CN111566042B (zh) 2017-11-15 2024-02-13 美国燃气技术研究院 用于重整甲烷和其他烃类的贵金属催化剂及方法
FI3710562T3 (fi) 2017-11-15 2023-12-14 Gas Technology Inst Menetelmä metaanin ja kevyiden hiilivetyjen reformoimiseksi nestemäisiksi hiilivetypolttoaineiksi
US10759722B2 (en) 2018-01-11 2020-09-01 Gas Technology Institute Production of liquids and reduced sulfur gaseous products from sour natural gas
EP3830219A1 (en) 2018-07-27 2021-06-09 Gas Technology Institute Fluidized bed processes and catalyst systems for fischer-tropsch conversion
US12122962B2 (en) 2018-09-18 2024-10-22 Gti Energy Processes and catalysts for reforming of impure methane-containing feeds
CN109810739B (zh) * 2019-03-01 2021-08-20 新地能源工程技术有限公司 一种耐硫甲烷合成工艺和装置
CN109776248A (zh) * 2019-03-12 2019-05-21 重庆大学 一种脂肪酸水热法制备甲烷的方法
CN110092702B (zh) * 2019-05-23 2020-10-09 北京化工大学 一种生物焦催化加氢制备甲烷的方法
PH12021553236A1 (en) * 2019-06-27 2022-09-19 Douglas John Frederick Hallett Process for reducing an organic material to produce methane and/or hydrogen
US12128355B2 (en) * 2020-01-29 2024-10-29 Hago Energetics Benefit Corporation Conversion of flue gas carbon dioxide to valuable carbons and hydrocarbons
CN111363572B (zh) * 2020-03-04 2021-04-20 华中科技大学 生物质催化热解联产气液燃料、化学品和炭材料的方法
WO2021189137A1 (en) * 2020-03-23 2021-09-30 G4 Insights Inc. Hydrogen production with sequestration
US12173238B2 (en) * 2020-06-29 2024-12-24 Uop Llc Integrated process for hydrotreating a renewable feedstock with improved carbon monoxide management
US12403439B2 (en) 2020-10-30 2025-09-02 Gti Energy Electrically heated reforming reactor for reforming of methane and other hydrocarbons
CN112980482B (zh) * 2021-03-05 2022-04-01 宁波钢铁有限公司 一种美国焦煤参与配煤炼焦方法
US20220401906A1 (en) * 2021-05-18 2022-12-22 Obantarla Corp. Autonomous Modular Flare Gas Conversion Systems and Methods
CN115926848B (zh) * 2021-11-29 2024-02-13 北京工商大学 一种废旧风电叶片的资源化处理装置以及处理方法
US11967745B2 (en) * 2022-04-27 2024-04-23 Saudi Arabian Oil Company Co-production of hydrogen, carbon, and electricity with carbon dioxide capture
CA3258783A1 (en) * 2022-06-23 2023-12-28 Shell Internationale Research Maatschappij B.V. PARTICLE REMOVAL SYSTEM INTENDED FOR USE IN HYDROTREADING
US12473199B2 (en) * 2022-09-28 2025-11-18 Saudi Arabian Oil Company Co-production of hydrogen, carbon, electricity, and carbon monoxide with carbon dioxide capture for refining of crude oil
US20240194916A1 (en) * 2022-12-08 2024-06-13 Saudi Arabian Oil Company Co-production of hydrogen, carbon, electricity, and concrete with carbon dioxide capture
EP4450483A1 (en) * 2023-04-17 2024-10-23 Paul Scherrer Institut Method and system for flexible production of hydrogen and hydrocarbons from product gas

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3625664A (en) * 1967-04-05 1971-12-07 Carlo Padovani Process for the production of rich fuel to replace natural gas by means of catalytic hydrogasification under pressure of fluid hydrocarbons
US4013543A (en) * 1975-10-20 1977-03-22 Cities Service Company Upgrading solid fuel-derived tars produced by low pressure hydropyrolysis
US3997423A (en) * 1975-10-20 1976-12-14 Cities Service Company Short residence time low pressure hydropyrolysis of carbonaceous materials
US4166786A (en) * 1976-06-25 1979-09-04 Occidental Petroleum Corporation Pyrolysis and hydrogenation process
US4260473A (en) * 1979-05-03 1981-04-07 Occidental Research Corporation Removal of particulates from pyrolytic oil
GB2071132A (en) * 1979-10-19 1981-09-16 Coal Industry Patents Ltd Fuel oils from coal
US4326944A (en) * 1980-04-14 1982-04-27 Standard Oil Company (Indiana) Rapid hydropyrolysis of carbonaceous solids
CA1199039A (en) * 1982-10-01 1986-01-07 Jacob Silverman Hydropyrolysis process
CA1300885C (en) 1986-08-26 1992-05-19 Donald S. Scott Hydrogasification of biomass to produce high yields of methane
US4808289A (en) * 1987-07-09 1989-02-28 Amoco Corporation Resid hydrotreating with high temperature flash drum recycle oil
US5055181A (en) * 1987-09-30 1991-10-08 Exxon Research And Engineering Company Hydropyrolysis-gasification of carbonaceous material
US5096569A (en) * 1990-02-27 1992-03-17 Exxon Research And Engineering Company Catalytic hydropyrolysis of carbonaceous material with char recycle
GB9224783D0 (en) * 1992-11-26 1993-01-13 Univ Waterloo An improved process for the thermal conversion of biomass to liquids
RU2124547C1 (ru) 1997-10-24 1999-01-10 Антоненко Владимир Федорович Способ термической переработки биомассы
NL1010288C2 (nl) 1998-10-12 2000-04-13 Stichting Energie Werkwijze voor de conversie van waterstof in substituut aardgas.
EP1184443A1 (en) 2000-09-04 2002-03-06 Biofuel B.V. Process for the production of liquid fuels from biomass
US6685754B2 (en) * 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
RU2238962C1 (ru) * 2003-04-07 2004-10-27 Российская Федерация в лице государственного заказчика Министерства промышленности, науки и технологии Российской Федерации и исполнителя Федерального государственного унитарного предприятия "Центральный научно-исследовательский и проектный институт лесохимической промышленности" Способ получения газообразного топлива
US7909895B2 (en) * 2004-11-10 2011-03-22 Enertech Environmental, Inc. Slurry dewatering and conversion of biosolids to a renewable fuel
US7467660B2 (en) * 2005-03-31 2008-12-23 Hce, Llc Pumped carbon mining methane production process
US8070840B2 (en) * 2005-04-22 2011-12-06 Shell Oil Company Treatment of gas from an in situ conversion process
EP1772202A1 (de) * 2005-10-04 2007-04-11 Paul Scherrer Institut Verfahren zur Erzeugung von Methan und/oder Methanhydrat aus Biomasse
JP4878824B2 (ja) 2005-11-30 2012-02-15 Ｊｘ日鉱日石エネルギー株式会社 環境低負荷型燃料の製造方法および環境低負荷型燃料
US7511181B2 (en) * 2006-05-02 2009-03-31 Uop Llc Production of diesel fuel from biorenewable feedstocks
JP2007308564A (ja) 2006-05-17 2007-11-29 Nippon Oil Corp 水素化精製方法
US7686856B2 (en) * 2006-06-19 2010-03-30 Praxair Technology, Inc. Method and apparatus for producing synthesis gas
US20080006519A1 (en) * 2006-07-06 2008-01-10 Badger Phillip C Method and system for accomplishing flash or fast pyrolysis with carbonaceous materials
US7578927B2 (en) * 2006-08-31 2009-08-25 Uop Llc Gasoline and diesel production from pyrolytic lignin produced from pyrolysis of cellulosic waste
US7994375B2 (en) * 2006-09-26 2011-08-09 Uop Llc Production of gasoline, diesel, naphthenes and aromatics from lignin and cellulosic waste by one step hydrocracking
US8084655B2 (en) * 2007-06-15 2011-12-27 E. I. Du Pont De Nemours And Company Catalytic process for converting renewable resources into paraffins for use as diesel blending stocks
US8217211B2 (en) * 2007-08-27 2012-07-10 Purdue Research Foundation Process for producing liquid hydrocarbon by pyrolysis of biomass in presence of hydrogen from a carbon-free energy source
US8217210B2 (en) * 2007-08-27 2012-07-10 Purdue Research Foundation Integrated gasification—pyrolysis process
US8003834B2 (en) * 2007-09-20 2011-08-23 Uop Llc Integrated process for oil extraction and production of diesel fuel from biorenewable feedstocks
US7982076B2 (en) * 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks
US7999142B2 (en) 2007-09-20 2011-08-16 Uop Llc Production of diesel fuel from biorenewable feedstocks
US8198492B2 (en) 2008-03-17 2012-06-12 Uop Llc Production of transportation fuel from renewable feedstocks
US8999020B2 (en) * 2008-04-01 2015-04-07 Greatpoint Energy, Inc. Processes for the separation of methane from a gas stream
PT2141217E (pt) 2008-07-01 2015-07-30 Neste Oil Oyj Processo para o fabrico de combustível para aviação ou stocks de mistura para combustível para aviação de origem biológica

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