RU2017126366A - Композиция для удаления серосодержащих соединений - Google Patents
Композиция для удаления серосодержащих соединений Download PDFInfo
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- RU2017126366A RU2017126366A RU2017126366A RU2017126366A RU2017126366A RU 2017126366 A RU2017126366 A RU 2017126366A RU 2017126366 A RU2017126366 A RU 2017126366A RU 2017126366 A RU2017126366 A RU 2017126366A RU 2017126366 A RU2017126366 A RU 2017126366A
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- Prior art keywords
- hydrocarbon
- sulfur
- oil
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1468—Removing hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/02—Non-metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/12—Oxygen-containing compounds
- C23F11/122—Alcohols; Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
- C10G29/24—Aldehydes or ketones
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Water Supply & Treatment (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Gas Separation By Absorption (AREA)
Claims (10)
1. Композиция для удаления серосодержащего соединения из углеводорода, где серосодержащее соединение представляет собой сероводород, соединение, содержащее группу -SH, или их смесь,
при этом композиция содержит диальдегид, имеющий от 6 до 16 атомов углерода, и полиалкиленгликоль.
2. Композиция по п. 1, где диальдегид представляет собой, по меньшей мере, одно соединение, выбранное из группы, которая состоит из 3-метилглутарового альдегида, 1,9-нонандиаля и 2-метил-1,8-октандиаля.
3. Композиция по п. 1 или 2, где полиалкиленгликоль представляет собой, по меньшей мере, одно соединение, выбранное из группы, которая состоит из полиэтиленгликоля, полипропиленгликоля и полибутиленгликоля.
4. Композиция по п. 1 или 2, где выбранным в качестве объекта углеводородом, из которого необходимо удалить серосодержащее соединение, является, по меньшей мере, один углеводород, выбранный из группы, состоящей из природного газа, сжиженного природного газа, сернистого нефтяного газа, сырой нефти, лигроина, обогащенного ароматикой тяжелого лигроина, бензина, керосина, дизельного масла, газойля, тяжелого масла, смеси из процесса каталитического крекинга, асфальта и нефтяного концентрата.
5. Способ удаления серосодержащего соединения из углеводорода, включающий введение углеводорода в контакт с композицией по любому из пп. 1-4, с целью удаления серосодержащего соединения из углеводорода, где серосодержащее соединение представляет собой сероводород, соединение, содержащее группу -SH, или их смесь.
6. Способ по п. 5, где углеводород представляет собой, по меньшей мере, один углеводород, выбранный из группы, состоящей из природного газа, сжиженного природного газа, сернистого нефтяного газа, сырой нефти, лигроина, обогащенного ароматикой тяжелого лигроина, бензина, керосина, дизельного масла, газойля, тяжелого масла, смеси из процесса каталитического крекинга, асфальта и нефтяного концентрата.
7. Способ по п. 5 или 6, где диальдегид, содержащийся в композиции по любому из пп. 1-4, добавляют в количестве от 0,1 до 100 моль по отношению к 1 моль серосодержащего соединения, имеющегося в углеводороде.
8. Способ по п. 5 или 6, включающий введение углеводорода в контакт с композицией по любому из пп. 1-4 в диапазоне температур от 0°С до 200°С.
9. Применение композиции по любому из пп. 1-4 для удаления из углеводорода таких серосодержащих соединений как сероводород, соединение, содержащее группу -SH, или их смесь.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015015380 | 2015-01-29 | ||
| JP2015-015380 | 2015-01-29 | ||
| PCT/JP2016/052157 WO2016121747A1 (ja) | 2015-01-29 | 2016-01-26 | 含硫黄化合物除去用の組成物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2017126366A true RU2017126366A (ru) | 2019-03-01 |
| RU2017126366A3 RU2017126366A3 (ru) | 2019-05-21 |
| RU2693494C2 RU2693494C2 (ru) | 2019-07-03 |
Family
ID=56543358
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2017126366A RU2693494C2 (ru) | 2015-01-29 | 2016-01-26 | Композиция для удаления серосодержащих соединений |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10294428B2 (ru) |
| EP (1) | EP3252129B1 (ru) |
| JP (1) | JP6621030B2 (ru) |
| KR (1) | KR20170110079A (ru) |
| CN (1) | CN107207974B (ru) |
| CA (1) | CA2974070A1 (ru) |
| RU (1) | RU2693494C2 (ru) |
| TW (1) | TWI678395B (ru) |
| WO (1) | WO2016121747A1 (ru) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3202266B1 (en) * | 2014-09-19 | 2019-11-27 | Kuraray Co., Ltd. | Biological corrosion inhibitor for metals |
| JPWO2018062254A1 (ja) * | 2016-09-27 | 2019-08-15 | 株式会社クラレ | 金属腐食の抑制方法 |
| JPWO2018097108A1 (ja) * | 2016-11-22 | 2019-10-17 | 株式会社クラレ | 含硫黄化合物除去用の組成物 |
| WO2018207657A1 (ja) | 2017-05-12 | 2018-11-15 | 株式会社クラレ | 含硫黄化合物除去装置および含硫黄化合物除去方法 |
| EA039258B1 (ru) * | 2017-06-21 | 2021-12-23 | Курарей Ко., Лтд. | Композиция для удаления серосодержащего соединения |
| JP2020143170A (ja) * | 2017-06-29 | 2020-09-10 | 株式会社クラレ | アスファルト中の含硫黄化合物除去用の組成物 |
| US11286433B2 (en) * | 2017-08-01 | 2022-03-29 | Gaps Technology, Llc | Compositions and methods for remediating hydrogen sulfide in hydrocarbon based liquids |
| EP3760293A4 (en) * | 2018-02-28 | 2021-11-10 | Kuraray Co., Ltd. | COMPOSITION FOR THE REMOVAL OF A SULFURY COMPOUND |
| JP2020019898A (ja) * | 2018-08-01 | 2020-02-06 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 生産流体処理システム及び生産流体の処理方法 |
| US11840669B2 (en) | 2018-12-21 | 2023-12-12 | Kuraray Co., Ltd. | Method for hydrocarbon production, purification method, and purifier |
| US20220017833A1 (en) | 2019-10-17 | 2022-01-20 | Nexgen Oilfield Chemicals, Llc | Methods and Compositions for Scavenging Sulfides from Hydrocarbon Fluids and Aqueous Streams |
| CA3165699A1 (en) | 2020-01-23 | 2021-07-29 | Timothy TIDWELL | Compositions of heterocyclic compounds and uses as sulfidogenesis inhibitors |
| CN114159946B (zh) * | 2022-02-11 | 2022-04-29 | 河北精致科技有限公司 | 一种用于脱除烟气中二氧化硫的吸收剂及其应用 |
| US11946008B2 (en) | 2022-05-04 | 2024-04-02 | Nexgen Oilfield Chemicals, Llc | Compositions and methods for scavenging hydrogen sulfide |
| CN118546664B (zh) * | 2024-05-15 | 2024-12-24 | 九江蓝卓新材料科技有限公司 | 一种高效的油田用除总硫剂 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1991765A (en) | 1932-01-23 | 1935-02-19 | Dupont Viscoloid Company | Aldehyde-hydrogen sulphide reaction product |
| JPS58157739A (ja) * | 1982-03-12 | 1983-09-19 | Kuraray Co Ltd | １，９−ノナンジア−ルの製造方法 |
| US4532117A (en) * | 1983-12-20 | 1985-07-30 | Union Oil Company Of California | Method for reconditioning bacteria-contaminated hydrogen sulfide removal systems |
| US4680127A (en) | 1985-12-13 | 1987-07-14 | Betz Laboratories, Inc. | Method of scavenging hydrogen sulfide |
| US5284635A (en) | 1989-09-05 | 1994-02-08 | Societe Francaise Hoechst | Process for the elimination of hydrogen sulfide by using water-in-oil emulsions |
| US5347004A (en) * | 1992-10-09 | 1994-09-13 | Baker Hughes, Inc. | Mixtures of hexahydrotriazines useful as H2 S scavengers |
| US5462721A (en) * | 1994-08-24 | 1995-10-31 | Crescent Holdings Limited | Hydrogen sulfide scavenging process |
| US5688478A (en) * | 1994-08-24 | 1997-11-18 | Crescent Holdings Limited | Method for scavenging sulfides |
| JPH10235130A (ja) * | 1997-02-25 | 1998-09-08 | Matsushita Electric Works Ltd | フィルタ |
| CA2445422A1 (en) * | 2001-04-25 | 2002-10-31 | Clearwater International, Llc | Treatment of hydrocarbons containing sulfides |
| JP2004168663A (ja) * | 2002-11-15 | 2004-06-17 | Osaka Industrial Promotion Organization | 硫黄化合物の酸化方法および脱硫油の製造方法 |
| RU2385180C1 (ru) * | 2008-08-21 | 2010-03-27 | Владимир Сергеевич Арутюнов | Способ очистки углеводородных газов |
| US8778172B2 (en) | 2009-05-05 | 2014-07-15 | Dorf Ketal Chemicals (I) Private Limited | Method of scavenging hydrogen sulfide from hydrocarbon stream |
| US20110147272A1 (en) | 2009-12-23 | 2011-06-23 | General Electric Company | Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers |
| ES2549530T3 (es) * | 2010-11-22 | 2015-10-29 | Dorf Ketal Chemicals (I) Private Limited | Composición de aditivo y procedimiento para captar sulfuro de hidrógeno en corrientes de hidrocarburos |
| US9260669B2 (en) | 2011-03-24 | 2016-02-16 | Baker Hughes Incorporated | Synergistic H2S/mercaptan scavengers using glyoxal |
| US9463989B2 (en) * | 2011-06-29 | 2016-10-11 | Baker Hughes Incorporated | Synergistic method for enhanced H2S/mercaptan scavenging |
| US20130089460A1 (en) | 2011-10-05 | 2013-04-11 | Baker Hughes Incorporated | Inhibiting corrosion caused by aqueous aldehyde solutions |
| US9638018B2 (en) * | 2012-12-19 | 2017-05-02 | Ecolab Usa Inc. | Scavenging hydrogen sulfide |
| US9587181B2 (en) * | 2013-01-10 | 2017-03-07 | Baker Hughes Incorporated | Synergistic H2S scavenger combination of transition metal salts with water-soluble aldehydes and aldehyde precursors |
| WO2014210166A1 (en) * | 2013-06-27 | 2014-12-31 | Ecolab Usa Inc. | Epoxide-based hydrogen sulfide scavengers |
| CA2942276C (en) * | 2014-03-17 | 2021-12-14 | Kuraray Co., Ltd. | Composition for removal of sulfur-containing compounds |
-
2016
- 2016-01-26 JP JP2016572051A patent/JP6621030B2/ja active Active
- 2016-01-26 EP EP16743350.7A patent/EP3252129B1/en active Active
- 2016-01-26 CA CA2974070A patent/CA2974070A1/en not_active Abandoned
- 2016-01-26 US US15/546,091 patent/US10294428B2/en active Active
- 2016-01-26 RU RU2017126366A patent/RU2693494C2/ru not_active IP Right Cessation
- 2016-01-26 WO PCT/JP2016/052157 patent/WO2016121747A1/ja not_active Ceased
- 2016-01-26 KR KR1020177019893A patent/KR20170110079A/ko not_active Withdrawn
- 2016-01-26 CN CN201680007120.1A patent/CN107207974B/zh not_active Expired - Fee Related
- 2016-01-27 TW TW105102444A patent/TWI678395B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US20180010056A1 (en) | 2018-01-11 |
| CN107207974B (zh) | 2019-11-15 |
| CN107207974A (zh) | 2017-09-26 |
| TWI678395B (zh) | 2019-12-01 |
| KR20170110079A (ko) | 2017-10-10 |
| US10294428B2 (en) | 2019-05-21 |
| JP6621030B2 (ja) | 2019-12-18 |
| RU2017126366A3 (ru) | 2019-05-21 |
| RU2693494C2 (ru) | 2019-07-03 |
| JPWO2016121747A1 (ja) | 2017-11-16 |
| EP3252129A4 (en) | 2018-07-25 |
| EP3252129B1 (en) | 2019-08-14 |
| CA2974070A1 (en) | 2016-08-04 |
| TW201634579A (zh) | 2016-10-01 |
| EP3252129A1 (en) | 2017-12-06 |
| WO2016121747A1 (ja) | 2016-08-04 |
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