RU2248323C2 - Способ селективного окисления монооксида углерода в водородсодержащем потоке - Google Patents

Способ селективного окисления монооксида углерода в водородсодержащем потоке Download PDF

Info

Publication number: RU2248323C2
Authority: RU; Russia
Prior art keywords: mixture; carbon monoxide; catalyst; acid; temperature
Prior art date: 1999-12-28

Application number

RU2002120497/15A

Other languages

English (en)

Russian (ru)

Other versions

RU2002120497A (ru

Inventor

Скотт БРАУН (US)

Скотт БРАУН

Original Assignee

Филлипс Петролеум Компани

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-12-28

Filing date

2000-11-10

Publication date

2005-03-20

2000-11-10 Application filed by Филлипс Петролеум Компани filed Critical Филлипс Петролеум Компани

2004-01-27 Publication of RU2002120497A publication Critical patent/RU2002120497A/ru

2005-03-20 Application granted granted Critical

2005-03-20 Publication of RU2248323C2 publication Critical patent/RU2248323C2/ru

Links

UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 88
229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract description 88
238000000034 method Methods 0.000 title claims abstract description 41
230000003647 oxidation Effects 0.000 title claims abstract description 25
238000007254 oxidation reaction Methods 0.000 title claims abstract description 25
239000003054 catalyst Substances 0.000 claims abstract description 74
239000001257 hydrogen Substances 0.000 claims abstract description 52
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 52
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 49
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 46
239000000203 mixture Substances 0.000 claims abstract description 45
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 38
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 38
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 26
239000001301 oxygen Substances 0.000 claims abstract description 26
229910052760 oxygen Inorganic materials 0.000 claims abstract description 26
239000002253 acid Substances 0.000 claims abstract description 25
229910052697 platinum Inorganic materials 0.000 claims abstract description 22
239000001569 carbon dioxide Substances 0.000 claims abstract description 19
229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 19
229910052742 iron Inorganic materials 0.000 claims abstract description 19
239000008246 gaseous mixture Substances 0.000 claims abstract description 18
239000007789 gas Substances 0.000 claims description 18
238000010438 heat treatment Methods 0.000 claims description 17
239000000463 material Substances 0.000 claims description 16
238000006243 chemical reaction Methods 0.000 claims description 14
239000012876 carrier material Substances 0.000 claims description 11
230000003197 catalytic effect Effects 0.000 claims description 10
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
239000002904 solvent Substances 0.000 claims description 9
230000001590 oxidative effect Effects 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 6
-1 magnesium aluminate Chemical class 0.000 claims description 5
150000002506 iron compounds Chemical class 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 4
150000003058 platinum compounds Chemical class 0.000 claims description 4
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical group O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
238000010306 acid treatment Methods 0.000 claims description 3
229910052749 magnesium Inorganic materials 0.000 claims description 3
239000011777 magnesium Substances 0.000 claims description 3
229910017604 nitric acid Inorganic materials 0.000 claims description 3
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
239000000446 fuel Substances 0.000 abstract description 20
230000000694 effects Effects 0.000 abstract description 5
239000000126 substance Substances 0.000 abstract description 4
238000004519 manufacturing process Methods 0.000 abstract description 2
238000002485 combustion reaction Methods 0.000 abstract 2
239000002994 raw material Substances 0.000 abstract 1
239000000758 substrate Substances 0.000 abstract 1
239000000243 solution Substances 0.000 description 11
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
150000002431 hydrogen Chemical class 0.000 description 8
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
238000005470 impregnation Methods 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
239000012018 catalyst precursor Substances 0.000 description 4
239000011521 glass Substances 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
239000010453 quartz Substances 0.000 description 4
238000006722 reduction reaction Methods 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
125000005595 acetylacetonate group Chemical group 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
229940045985 antineoplastic platinum compound Drugs 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 2
229910003446 platinum oxide Inorganic materials 0.000 description 2
229910052573 porcelain Inorganic materials 0.000 description 2
238000005215 recombination Methods 0.000 description 2
230000006798 recombination Effects 0.000 description 2
239000011029 spinel Substances 0.000 description 2
229910052596 spinel Inorganic materials 0.000 description 2
238000005507 spraying Methods 0.000 description 2
238000005303 weighing Methods 0.000 description 2
VEJOYRPGKZZTJW-FDGPNNRMSA-N (z)-4-hydroxypent-3-en-2-one;platinum Chemical compound [Pt].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O VEJOYRPGKZZTJW-FDGPNNRMSA-N 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
230000004075 alteration Effects 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
229910010293 ceramic material Inorganic materials 0.000 description 1
239000002826 coolant Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000005611 electricity Effects 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
239000003517 fume Substances 0.000 description 1
239000003502 gasoline Substances 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
AQBLLJNPHDIAPN-LNTINUHCSA-K iron(3+);(z)-4-oxopent-2-en-2-olate Chemical compound [Fe+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O AQBLLJNPHDIAPN-LNTINUHCSA-K 0.000 description 1
230000001788 irregular Effects 0.000 description 1
239000003949 liquefied natural gas Substances 0.000 description 1
239000003915 liquefied petroleum gas Substances 0.000 description 1
239000012528 membrane Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
HRGDZIGMBDGFTC-UHFFFAOYSA-N platinum(2+) Chemical compound [Pt+2] HRGDZIGMBDGFTC-UHFFFAOYSA-N 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
229920000867 polyelectrolyte Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000002407 reforming Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000000629 steam reforming Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8906—Iron and noble metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/25—Nitrates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/12—Oxidising
- B01J37/14—Oxidising with gases containing free oxygen

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Physics & Mathematics (AREA)
Thermal Sciences (AREA)
Catalysts (AREA)
Carbon And Carbon Compounds (AREA)
Hydrogen, Water And Hydrids (AREA)

RU2002120497/15A 1999-12-28 2000-11-10 Способ селективного окисления монооксида углерода в водородсодержащем потоке RU2248323C2 (ru)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US47315799A	1999-12-28	1999-12-28
US09/473,157		1999-12-28

Publications (2)

Publication Number	Publication Date
RU2002120497A RU2002120497A (ru)	2004-01-27
RU2248323C2 true RU2248323C2 (ru)	2005-03-20

Family

ID=23878436

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
RU2002120497/15A RU2248323C2 (ru)	1999-12-28	2000-11-10	Способ селективного окисления монооксида углерода в водородсодержащем потоке

Country Status (11)

Country	Link
EP (1)	EP1257502A4 (de)
JP (1)	JP2003519067A (de)
KR (1)	KR20020074465A (de)
CN (1)	CN1414923A (de)
AU (1)	AU774521B2 (de)
BR (1)	BR0016815A (de)
CA (1)	CA2395761A1 (de)
MX (1)	MXPA02006437A (de)
NO (1)	NO20023180L (de)
RU (1)	RU2248323C2 (de)
WO (1)	WO2001047806A1 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20020061277A1 (en)	2000-09-25	2002-05-23	Engelhard Corporation	Non-pyrophoric water-gas shift reaction catalysts
JP4812248B2 (ja)	2003-01-22	2011-11-09	日東電工株式会社	燃料電池
US7029640B2 (en)	2003-06-17	2006-04-18	Conocophillips Company	Process for selective oxidation of carbon monoxide in a hydrogen containing stream
US20050255028A1 (en) *	2004-05-17	2005-11-17	Jianhua Yao	Process for selective oxidation of carbon monoxide in a hydrogen containing stream
KR101193163B1 (ko) *	2005-10-21	2012-10-19	삼성에스디아이 주식회사	일산화탄소 산화 촉매 및 그의 제조 방법
EP2565176B1 (de) *	2006-05-08	2015-08-19	Virent, Inc.	Verfahren zur Erzeugung von Polyolen
US7439206B2 (en)	2006-07-18	2008-10-21	Conocophillips Company	Process for selective oxidation of carbon monoxide in a hydrogen containing stream
US20180029003A1 (en) *	2015-02-25	2018-02-01	SGC Energia Co., LLC	Systems, methods, and apparatuses for fischer-tropsch reactor cascade

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5017357A (en) *	1989-06-14	1991-05-21	Phillips Petroleum Company	Catalytic process for oxidation of carbon monoxide
RU2069584C1 (ru) *	1994-11-24	1996-11-27	Виктор Владимирович Барелко	Катализатор для химических процессов, например конверсии аммиака, окисления углеводородов, диоксида серы, очистки выхлопных газов

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6093670A (en) *	1998-12-11	2000-07-25	Phillips Petroleum Company	Carbon monoxide oxidation catalyst and process therefor

2000
- 2000-11-10 EP EP00993603A patent/EP1257502A4/de not_active Withdrawn
- 2000-11-10 WO PCT/US2000/042050 patent/WO2001047806A1/en not_active Ceased
- 2000-11-10 RU RU2002120497/15A patent/RU2248323C2/ru not_active IP Right Cessation
- 2000-11-10 CA CA002395761A patent/CA2395761A1/en not_active Abandoned
- 2000-11-10 AU AU29239/01A patent/AU774521B2/en not_active Ceased
- 2000-11-10 KR KR1020027008283A patent/KR20020074465A/ko not_active Abandoned
- 2000-11-10 JP JP2001549290A patent/JP2003519067A/ja active Pending
- 2000-11-10 MX MXPA02006437A patent/MXPA02006437A/es not_active Application Discontinuation
- 2000-11-10 BR BR0016815-7A patent/BR0016815A/pt not_active Application Discontinuation
- 2000-11-10 CN CN00817964A patent/CN1414923A/zh active Pending
2002
- 2002-06-28 NO NO20023180A patent/NO20023180L/no not_active Application Discontinuation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5017357A (en) *	1989-06-14	1991-05-21	Phillips Petroleum Company	Catalytic process for oxidation of carbon monoxide
RU2069584C1 (ru) *	1994-11-24	1996-11-27	Виктор Владимирович Барелко	Катализатор для химических процессов, например конверсии аммиака, окисления углеводородов, диоксида серы, очистки выхлопных газов

Also Published As

Publication number	Publication date
RU2002120497A (ru)	2004-01-27
AU774521B2 (en)	2004-07-01
JP2003519067A (ja)	2003-06-17
BR0016815A (pt)	2002-10-01
NO20023180L (no)	2002-08-19
AU2923901A (en)	2001-07-09
WO2001047806A1 (en)	2001-07-05
CA2395761A1 (en)	2001-07-05
KR20020074465A (ko)	2002-09-30
EP1257502A4 (de)	2007-04-25
MXPA02006437A (es)	2002-11-29
NO20023180D0 (no)	2002-06-28
EP1257502A1 (de)	2002-11-20
CN1414923A (zh)	2003-04-30

Legal Events

Date	Code	Title	Description
2010-07-27	MM4A	The patent is invalid due to non-payment of fees	Effective date: 20071111

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