SE322764B - - Google Patents
Info
- Publication number
- SE322764B SE322764B SE323/67A SE32367A SE322764B SE 322764 B SE322764 B SE 322764B SE 323/67 A SE323/67 A SE 323/67A SE 32367 A SE32367 A SE 32367A SE 322764 B SE322764 B SE 322764B
- Authority
- SE
- Sweden
- Prior art keywords
- glycidol
- epoxidation
- allyl alcohol
- glycerol
- jan
- Prior art date
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 9
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 abstract 8
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 abstract 6
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 abstract 4
- 238000006735 epoxidation reaction Methods 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
- C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
- C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,153,971. Glycidol; glycerol. FMC CORP. 9 Jan., 1967 [11 Jan., 1966], No. 1108/67. Heading C2C. Glycidol is produced by epoxidation of allyl alcohol in the absence of water at 25-100‹ C. using a 15-40% by wt. solution of peracetic acid in an inert solvent, the ratio of allyl alcohol to peracetic acid being 5À0-0À7 mols alcohol per mol acid, and continuing epoxidation until at least 70% by wt. of the minor reactant has reached to convert allyl alcohol to glycidol in a yield of at least 90%. The glycidol recovered from the reaction mixture may be hydrolysed to glycerol at 25-170‹ C. using 10-100 mols water per mol glycidol. Specified solvents for the epoxidation are lower ketones, esters, ethers and alcohols, alone or in admixture with halogenated alkanes. Epoxidation is preferably effected at 25-100‹ C. using excess allyl alcohol and rapidly and continuously removing solvent and by-product acetic acid by distillation under reduced pressure, e.g., below 400 mm. Hg, and recovering glycidol which can be further purified and will yield a pure glycerol on hydrolysis. The process is illustrated by reference to flow sheet and apparatus drawings (not shown).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51984166A | 1966-01-11 | 1966-01-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SE322764B true SE322764B (en) | 1970-04-20 |
Family
ID=24070021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE323/67A SE322764B (en) | 1966-01-11 | 1967-01-10 |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS5118407B1 (en) |
| AT (1) | AT274759B (en) |
| BE (1) | BE692370A (en) |
| CH (1) | CH481089A (en) |
| DE (1) | DE1618336C3 (en) |
| FR (1) | FR1509277A (en) |
| GB (1) | GB1153971A (en) |
| NL (1) | NL6700329A (en) |
| SE (1) | SE322764B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5752341B2 (en) * | 1972-12-27 | 1982-11-06 | ||
| JPS59132856U (en) * | 1983-02-24 | 1984-09-05 | 山田 庄造 | Concrete shade block |
| CN116041281A (en) * | 2022-12-01 | 2023-05-02 | 杭州蔚远医药科技有限公司 | Industrial production method and device of glycidol |
| CN118852060A (en) * | 2024-06-28 | 2024-10-29 | 浙江大学衢州研究院 | A method for preparing organochlorine-free glycidyl ether |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB917747A (en) * | 1960-04-23 | 1963-02-06 | Uddeholms Ab | A method for the manufacture of glycerin |
-
1967
- 1967-01-05 DE DE1618336A patent/DE1618336C3/en not_active Expired
- 1967-01-05 FR FR90123A patent/FR1509277A/en not_active Expired
- 1967-01-09 NL NL6700329A patent/NL6700329A/xx unknown
- 1967-01-09 BE BE692370D patent/BE692370A/xx unknown
- 1967-01-09 GB GB0108/67A patent/GB1153971A/en not_active Expired
- 1967-01-10 AT AT22567A patent/AT274759B/en active
- 1967-01-10 JP JP42001600A patent/JPS5118407B1/ja active Pending
- 1967-01-10 CH CH29367A patent/CH481089A/en not_active IP Right Cessation
- 1967-01-10 SE SE323/67A patent/SE322764B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1153971A (en) | 1969-06-04 |
| DE1618336B2 (en) | 1974-05-22 |
| CH481089A (en) | 1969-11-15 |
| NL6700329A (en) | 1967-07-12 |
| JPS5118407B1 (en) | 1976-06-09 |
| BE692370A (en) | 1967-07-10 |
| FR1509277A (en) | 1968-01-12 |
| DE1618336C3 (en) | 1975-01-23 |
| DE1618336A1 (en) | 1972-04-13 |
| AT274759B (en) | 1969-09-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0137749A3 (en) | Recovering ethanol from aqueous acetic acid solutions | |
| ES2006295A6 (en) | Process for the recovery of alcohols using a perfluorinated ionomer membrane. | |
| US4691034A (en) | Purification of propylene oxide by treatment with calcium hydroxide in glycerol or sugar water | |
| SE322764B (en) | ||
| GB1347859A (en) | Aqueous hydrogen peroxide solutions | |
| IE43099L (en) | Process for the preparation of anhydrous percarboxylic acid¹solutions in benzene. | |
| GB1458864A (en) | Recovery of anhydrous dioxane | |
| Mukaiyama et al. | Optical interconversion of enantiomeric secondary alcohols using 2-fluorobenzothiazolium salt | |
| ES285966A1 (en) | Procedure for obtaining saturated aliphatic perºcids (Machine-translation by Google Translate, not legally binding) | |
| GB1397659A (en) | Process for preparing glycidol | |
| JPS53147018A (en) | Preparation of carboxylic acid glycidyl ester | |
| GB992742A (en) | Preparation of permonosulphates | |
| CA2025746A1 (en) | Process for the recovery of a water-insoluble epoxy alcohol | |
| GB1165309A (en) | Process for the preparation of Higher Aliphatic Alcohols | |
| ES8306697A1 (en) | Process for the production of methacrylic acid from isobutyraldehyde. | |
| GB975715A (en) | A process for the preparation of solutions of pure percarboxylic acids | |
| SU441703A1 (en) | The method of obtaining anhydrous solutions of aliphatic percarboxylic acids | |
| US3609198A (en) | Process for the continuous manufacture of glycerin by simultaneous reaction and water-addition azeotropic distillation | |
| US3454655A (en) | Conversion of allyl alcohol to glycerol | |
| GB1231532A (en) | ||
| JPS57130980A (en) | Preparation of epoxyalkyl ester | |
| GB1223028A (en) | Preparation of carboxylic acids and/or esters | |
| GB1207680A (en) | Oxidation of saturated hydrocarbons to alcohols | |
| FR2429774A1 (en) | Continuous (meth)allyl di:glycol carbonate prepn. - comprises reacting bis:chloroformate, (meth)allyl alcohol and alkali hydroxide in several mixing zones | |
| FR2279740A1 (en) | Propylene oxide recovery from propylene oxidn. - reaction mixt. by removing acid by-products before distn. to separate unreacted propylene |