SE438160B - Forfarande for reduktion av metallmalm - Google Patents

Forfarande for reduktion av metallmalm

Info

Publication number: SE438160B
Authority: SE; Sweden
Prior art keywords: reducing agent; blast furnace; carbon monoxide; ore; carbonaceous reducing
Prior art date: 1978-05-16

Application number

SE7904267A

Other languages

English (en)

Swedish (sv)

Other versions

SE7904267L (sv

Inventor

J L Blumenthal

M Burk

N A Richardson

Original Assignee

Trw Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-05-16

Filing date

1979-05-15

Publication date

1985-04-01

1979-05-15 Application filed by Trw Inc filed Critical Trw Inc

1979-11-17 Publication of SE7904267L publication Critical patent/SE7904267L/

1985-04-01 Publication of SE438160B publication Critical patent/SE438160B/sv

Links

238000000034 method Methods 0.000 title claims description 35
239000003638 chemical reducing agent Substances 0.000 claims description 62
239000007789 gas Substances 0.000 claims description 58
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 44
229910002091 carbon monoxide Inorganic materials 0.000 claims description 43
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 42
229910052751 metal Inorganic materials 0.000 claims description 34
239000002184 metal Substances 0.000 claims description 34
239000003054 catalyst Substances 0.000 claims description 32
239000000571 coke Substances 0.000 claims description 28
229910052799 carbon Inorganic materials 0.000 claims description 21
229910052742 iron Inorganic materials 0.000 claims description 21
239000000203 mixture Substances 0.000 claims description 19
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 17
238000006243 chemical reaction Methods 0.000 claims description 16
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
239000001257 hydrogen Substances 0.000 claims description 12
229910052739 hydrogen Inorganic materials 0.000 claims description 12
238000002347 injection Methods 0.000 claims description 12
239000007924 injection Substances 0.000 claims description 12
239000000446 fuel Substances 0.000 claims description 7
238000007323 disproportionation reaction Methods 0.000 claims description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
239000000295 fuel oil Substances 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 5
229910052759 nickel Inorganic materials 0.000 claims description 5
229910052717 sulfur Inorganic materials 0.000 claims description 5
239000011593 sulfur Substances 0.000 claims description 5
239000010941 cobalt Substances 0.000 claims description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 3
238000003756 stirring Methods 0.000 claims description 2
239000007858 starting material Substances 0.000 claims 3
229910000531 Co alloy Inorganic materials 0.000 claims 1
229910000640 Fe alloy Inorganic materials 0.000 claims 1
229910000990 Ni alloy Inorganic materials 0.000 claims 1
238000007664 blowing Methods 0.000 claims 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 16
229910002092 carbon dioxide Inorganic materials 0.000 description 11
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
239000003245 coal Substances 0.000 description 7
239000000463 material Substances 0.000 description 7
239000000565 sealant Substances 0.000 description 7
238000011946 reduction process Methods 0.000 description 6
239000001569 carbon dioxide Substances 0.000 description 5
239000003575 carbonaceous material Substances 0.000 description 5
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
238000002156 mixing Methods 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
239000004215 Carbon black (E152) Substances 0.000 description 4
230000008021 deposition Effects 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
239000007787 solid Substances 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000012159 carrier gas Substances 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
239000000470 constituent Substances 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
230000020169 heat generation Effects 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000010742 number 1 fuel oil Substances 0.000 description 2
239000003921 oil Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000001105 regulatory effect Effects 0.000 description 2
238000007789 sealing Methods 0.000 description 2
239000002893 slag Substances 0.000 description 2
239000004071 soot Substances 0.000 description 2
239000004484 Briquette Substances 0.000 description 1
229910000975 Carbon steel Inorganic materials 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
235000019738 Limestone Nutrition 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
239000010962 carbon steel Substances 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
229910000428 cobalt oxide Inorganic materials 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
238000005336 cracking Methods 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
238000010494 dissociation reaction Methods 0.000 description 1
230000005593 dissociations Effects 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000005485 electric heating Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000011888 foil Substances 0.000 description 1
238000002309 gasification Methods 0.000 description 1
229910052595 hematite Inorganic materials 0.000 description 1
239000011019 hematite Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
239000004571 lime Substances 0.000 description 1
239000006028 limestone Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
229910000480 nickel oxide Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000011236 particulate material Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000012256 powdered iron Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
238000010517 secondary reaction Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000010959 steel Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
229910001845 yogo sapphire Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/06—Making pig-iron in the blast furnace using top gas in the blast furnace process
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
- C21B2100/22—Increasing the gas reduction potential of recycled exhaust gases by reforming
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
- C21B2100/44—Removing particles, e.g. by scrubbing, dedusting
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Inorganic Chemistry (AREA)
Manufacture And Refinement Of Metals (AREA)
Catalysts (AREA)
Carbon And Carbon Compounds (AREA)
Manufacture Of Iron (AREA)

SE7904267A 1978-05-16 1979-05-15 Forfarande for reduktion av metallmalm SE438160B (sv)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/906,506 US4248627A (en)	1978-05-16	1978-05-16	Process for the manufacture and use of high purity carbonaceous reductant from carbon monoxide-containing gas mixtures

Publications (2)

Publication Number	Publication Date
SE7904267L SE7904267L (sv)	1979-11-17
SE438160B true SE438160B (sv)	1985-04-01

Family

ID=25422560

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE7904267A SE438160B (sv)	1978-05-16	1979-05-15	Forfarande for reduktion av metallmalm

Country Status (13)

Country	Link
US (1)	US4248627A (fr)
JP (1)	JPS54150388A (fr)
AU (1)	AU530313B2 (fr)
BE (1)	BE876295A (fr)
BR (1)	BR7902940A (fr)
CA (1)	CA1149135A (fr)
DE (1)	DE2919552A1 (fr)
FR (1)	FR2426089B1 (fr)
GB (1)	GB2021153B (fr)
IT (1)	IT1120958B (fr)
LU (1)	LU81258A1 (fr)
NL (1)	NL7903856A (fr)
SE (1)	SE438160B (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0125357B1 (fr) *	1983-05-11	1989-04-19	Trw Inc.	Matériaux carbonés oxydés et compositions à base de caoutchouc comprenant ces matériaux carbonés
EP0431819A1 (fr) *	1989-11-28	1991-06-12	Yutaka Tamaura	Méthode pour décomposer des oxydes gazeux et catalyseur utilisé à cet effet
US5234490A (en) *	1991-11-29	1993-08-10	Armco Inc.	Operating a blast furnace using dried top gas
EP2838844A4 (fr) *	2012-04-16	2015-10-28	Seerstone Llc	Procédé de traitement d'un dégagement gazeux contenant des oxydes de carbone
US9284190B2 (en)	2012-07-13	2016-03-15	Corning Incorporated	Electrochemical high rate storage materials, process and electrodes
JP7463174B2 (ja)	2020-04-06	2024-04-08	三菱重工業株式会社	固体炭素生成装置および固体炭素生成方法
JPWO2023214563A1 (fr) *	2022-05-02	2023-11-09
JP7718507B2 (ja) *	2022-08-08	2025-08-05	Ｊｆｅスチール株式会社	炭素塊成化物の製造方法
CA3268443A1 (fr) *	2022-09-20	2024-03-28	Pyrogenesis Canada Inc.	Procédé de production de silicium à faible émission de carbone
AU2023390914A1 (en) *	2022-12-09	2025-06-19	Alterna Materials, Llc	Metal ore reduction reactor with self-generating reductant
JPWO2024154412A1 (fr)	2023-01-19	2024-07-25

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US1120682A (en) *	1913-11-07	1914-12-15	Nitrogen Products Company	Method of fixing nitrogen.
US1352162A (en) *	1918-01-24	1920-09-07	Nitrogen Products Company	Production of substantially pure carbon and the like
US1792507A (en) *	1926-06-10	1931-02-17	William W Percy	Process of reducing the iron in iron oxides to its metallic form
US1803855A (en) *	1926-07-13	1931-05-05	Ig Farbenindustrie Ag	Manufacture of carbon
US1964744A (en) *	1930-02-20	1934-07-03	William W Odell	Process of making carbon black
US2008270A (en) *	1930-04-16	1935-07-16	Gen Carbonalpha Company	Method of manufacturing carbon black
US2107980A (en) *	1936-03-16	1938-02-08	Elian John	Method for preparing iron and steel
US2598735A (en) *	1948-07-16	1952-06-03	Hydrocarbon Research Inc	Iron oxide reduction
FR980962A (fr) *	1948-08-26	1951-05-21	Standard Oil Dev Co	Procédé perfectionné de marche des hauts-fourneaux
US2711951A (en) *	1951-08-02	1955-06-28	Illinois Clay Products Co	Process for producing a briquette of iron ore
FR1076087A (fr) *	1952-09-13	1954-10-22	Dalmine Spa	Procédé pour la réduction, en phase solide, de minerais oxydés, en particulier de minerais de fer, au moyen d'hydrocarbures gazeux et liquéfiables craqués, et installation appropriée à la mise en oeuvre dudit procédé
US2780537A (en) *	1952-11-24	1957-02-05	Stelling	Process of treating pulverulent iron oxides
US2799576A (en) *	1953-11-11	1957-07-16	Strikfeldt & Co W	Process for operating shaft blast furnaces
US2873183A (en) *	1954-07-07	1959-02-10	Kenneth B Ray And The St Trust	Continuous iron ore reduction process
GB830592A (en) *	1958-05-27	1960-03-16	Inland Steel Co	Process for reducing iron oxides
US3151974A (en) *	1961-04-26	1964-10-06	Huttenwerk Salzgitter Ag	Process for the operation of blast furnaces
US3257199A (en) *	1963-07-19	1966-06-21	Reynolds Metals Co	Thermal reduction
US3356488A (en) *	1964-02-24	1967-12-05	John H Walsh	Process for utilizing hydrocarbon injection into hot reducing gases in steelmaking
US3321303A (en) *	1966-09-06	1967-05-23	Treadwell Corp	Recovery of copper
GB1127145A (en) *	1965-06-23	1968-09-11	Centro Sperimentale Metallurgico Spa	Process of producing pure iron powder and product thereof
US3392008A (en) *	1965-07-29	1968-07-09	Exxon Research Engineering Co	Production of iron
DE1508081A1 (de) *	1966-01-07	1970-03-12	Schenk Dr Ing Dr Ing E H Herma	Verfahren zur Reduktion von Eisenerzen mit Kohlenwasserstoffen
DE1508082A1 (de) *	1966-02-11	1970-04-09	Schenck Dr Ing Hermann	Verfahren und Vorrichtung zur Gewinnung von fluessigem Eisen aus Eisenerzen mit Kohlenwasserstoffen
US3392218A (en) *	1966-03-31	1968-07-09	Exxon Research Engineering Co	Method of heating carbon monoxidecontaining gases without carbon deposition
US3475160A (en) *	1967-02-15	1969-10-28	Exxon Research Engineering Co	Method of producing reducing gases for the fluidized bed reduction of ores
US3494738A (en) *	1968-03-14	1970-02-10	Phillips Petroleum Co	Preparation of iron carbide (fe3c)
US3637368A (en) *	1968-10-16	1972-01-25	Exxon Research Engineering Co	Increased metallizations of iron ore from fluidized bed processes
US3841849A (en) *	1970-09-25	1974-10-15	F Beckmann	Process of manufacturing fuel briquettes
US3788835A (en) *	1970-12-30	1974-01-29	Exxon Research Engineering Co	Iron ore reduction process(nu-9)
US3861885A (en) *	1971-09-22	1975-01-21	Inst Gas Technology	Carbon black fuel production
JPS4981295A (fr) *	1972-12-12	1974-08-06
US3885023A (en) *	1973-02-15	1975-05-20	Phillips Petroleum Co	Preparation of iron carbide (Fe{hd 3{b C)
GB1473723A (en) *	1973-08-06	1977-05-18	Ontario Research Foundation	Recovery of sponge chromium from chromite ore
US3890142A (en) *	1973-10-16	1975-06-17	Fierro Esponja	Method for gaseous reduction of metal ores
US4065296A (en) *	1975-03-13	1977-12-27	Verkaufsgesellschaft Fur Teererzeugnisse (Vft)	Process for preparing composition containing carbon and low sulfur, nitrogen and ash content
US4116680A (en) *	1976-02-24	1978-09-26	Robert Kenneth Jordan	Coproduction of iron and carbon black

1978
- 1978-05-16 US US05/906,506 patent/US4248627A/en not_active Expired - Lifetime
1979
- 1979-05-04 GB GB7915537A patent/GB2021153B/en not_active Expired
- 1979-05-08 AU AU46799/79A patent/AU530313B2/en not_active Ceased
- 1979-05-11 JP JP5796279A patent/JPS54150388A/ja active Pending
- 1979-05-14 BR BR7902940A patent/BR7902940A/pt unknown
- 1979-05-14 IT IT68019/79A patent/IT1120958B/it active
- 1979-05-14 FR FR7912243A patent/FR2426089B1/fr not_active Expired
- 1979-05-15 DE DE19792919552 patent/DE2919552A1/de not_active Ceased
- 1979-05-15 LU LU81258A patent/LU81258A1/fr unknown
- 1979-05-15 CA CA000327681A patent/CA1149135A/fr not_active Expired
- 1979-05-15 SE SE7904267A patent/SE438160B/sv not_active IP Right Cessation
- 1979-05-16 BE BE0/195195A patent/BE876295A/fr not_active IP Right Cessation
- 1979-05-16 NL NL7903856A patent/NL7903856A/xx not_active Application Discontinuation

Also Published As

Publication number	Publication date
FR2426089A1 (fr)	1979-12-14
JPS54150388A (en)	1979-11-26
DE2919552A1 (de)	1979-11-22
US4248627A (en)	1981-02-03
FR2426089B1 (fr)	1985-10-18
NL7903856A (nl)	1979-11-20
GB2021153B (en)	1982-08-18
GB2021153A (en)	1979-11-28
SE7904267L (sv)	1979-11-17
IT1120958B (it)	1986-03-26
BR7902940A (pt)	1979-11-27
LU81258A1 (fr)	1979-09-10
BE876295A (fr)	1979-11-16
CA1149135A (fr)	1983-07-05
IT7968019A0 (it)	1979-05-14
AU4679979A (en)	1979-11-22
AU530313B2 (en)	1983-07-14

Legal Events

Date

Code

Title

Description

1995-01-31

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Effective date: 19880318

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