SE438269B - Katalysator for framstellning av vinylkloridmonomer samt kontinuerligt forfarande for syntes av vinylkloridmonomer - Google Patents

Katalysator for framstellning av vinylkloridmonomer samt kontinuerligt forfarande for syntes av vinylkloridmonomer

Info

Publication number: SE438269B
Authority: SE; Sweden
Prior art keywords: catalyst; salt; reactor; ethylene; alumina
Prior art date: 1977-10-19

Application number

SE7810845A

Other languages

English (en)

Swedish (sv)

Other versions

SE7810845L (sv

Inventor

M F Lemanski

F C Leitert

Jr C G Vinson

Original Assignee

Goodrich Co B F

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-10-19

Filing date

1978-10-18

Publication date

1985-04-15

1978-10-18 Application filed by Goodrich Co B F filed Critical Goodrich Co B F

1979-04-20 Publication of SE7810845L publication Critical patent/SE7810845L/xx

1985-04-15 Publication of SE438269B publication Critical patent/SE438269B/sv

Links

239000003054 catalyst Substances 0.000 title claims abstract description 91
238000004519 manufacturing process Methods 0.000 title claims abstract description 8
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 50
238000000034 method Methods 0.000 title claims description 40
230000015572 biosynthetic process Effects 0.000 title claims description 5
239000000178 monomer Substances 0.000 title claims 3
238000003786 synthesis reaction Methods 0.000 title claims 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 31
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 19
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
239000010948 rhodium Substances 0.000 claims abstract description 17
150000003839 salts Chemical class 0.000 claims abstract description 15
229910052742 iron Inorganic materials 0.000 claims abstract description 14
229910052703 rhodium Inorganic materials 0.000 claims abstract description 14
239000011701 zinc Substances 0.000 claims abstract description 14
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 11
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 11
229910052725 zinc Inorganic materials 0.000 claims abstract description 11
229910052802 copper Inorganic materials 0.000 claims abstract description 10
239000010949 copper Substances 0.000 claims abstract description 10
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 9
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 9
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 8
229910052697 platinum Inorganic materials 0.000 claims abstract description 6
239000000377 silicon dioxide Substances 0.000 claims abstract description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 5
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 43
239000005977 Ethylene Substances 0.000 claims description 43
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 40
238000006243 chemical reaction Methods 0.000 claims description 40
230000008569 process Effects 0.000 claims description 28
239000000460 chlorine Substances 0.000 claims description 22
229910052801 chlorine Inorganic materials 0.000 claims description 20
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 19
229910052751 metal Inorganic materials 0.000 claims description 12
239000002184 metal Substances 0.000 claims description 12
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
239000000463 material Substances 0.000 claims description 11
239000001301 oxygen Substances 0.000 claims description 11
229910052760 oxygen Inorganic materials 0.000 claims description 11
KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 4
229910001948 sodium oxide Inorganic materials 0.000 claims description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
238000010924 continuous production Methods 0.000 claims description 3
239000000376 reactant Substances 0.000 claims description 3
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
150000003751 zinc Chemical class 0.000 claims description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
150000002505 iron Chemical class 0.000 claims 2
150000003283 rhodium Chemical class 0.000 claims 2
230000000977 initiatory effect Effects 0.000 claims 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
229920002554 vinyl polymer Polymers 0.000 claims 1
239000000203 mixture Substances 0.000 description 26
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 24
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 24
229910000041 hydrogen chloride Inorganic materials 0.000 description 24
238000000197 pyrolysis Methods 0.000 description 17
239000007789 gas Substances 0.000 description 13
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 12
239000006227 byproduct Substances 0.000 description 11
229910052744 lithium Inorganic materials 0.000 description 11
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 10
238000004817 gas chromatography Methods 0.000 description 9
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 8
150000001875 compounds Chemical class 0.000 description 8
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 7
238000005660 chlorination reaction Methods 0.000 description 7
238000001704 evaporation Methods 0.000 description 6
230000008020 evaporation Effects 0.000 description 6
238000011065 in-situ storage Methods 0.000 description 6
239000000047 product Substances 0.000 description 6
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
239000000654 additive Substances 0.000 description 4
230000000996 additive effect Effects 0.000 description 4
229910002090 carbon oxide Inorganic materials 0.000 description 4
150000001805 chlorine compounds Chemical class 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
239000003607 modifier Substances 0.000 description 4
239000001103 potassium chloride Substances 0.000 description 4
235000011164 potassium chloride Nutrition 0.000 description 4
238000000926 separation method Methods 0.000 description 4
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 3
229910021592 Copper(II) chloride Inorganic materials 0.000 description 3
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
238000001354 calcination Methods 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
238000005470 impregnation Methods 0.000 description 3
238000000746 purification Methods 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000011592 zinc chloride Substances 0.000 description 3
235000005074 zinc chloride Nutrition 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 2
101100298295 Drosophila melanogaster flfl gene Proteins 0.000 description 2
229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
229910001514 alkali metal chloride Inorganic materials 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
-1 chlorine hydrocarbons Chemical class 0.000 description 2
239000000470 constituent Substances 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000010586 diagram Methods 0.000 description 2
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
239000007788 liquid Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000010453 quartz Substances 0.000 description 2
238000004064 recycling Methods 0.000 description 2
SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 2
FGDZQCVHDSGLHJ-UHFFFAOYSA-M rubidium chloride Chemical compound [Cl-].[Rb+] FGDZQCVHDSGLHJ-UHFFFAOYSA-M 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000004575 stone Substances 0.000 description 2
LMDZBCPBFSXMTL-UHFFFAOYSA-N 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide Substances CCN=C=NCCCN(C)C LMDZBCPBFSXMTL-UHFFFAOYSA-N 0.000 description 1
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical class CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
101150071146 COX2 gene Proteins 0.000 description 1
101100114534 Caenorhabditis elegans ctc-2 gene Proteins 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
241000698776 Duma Species 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
229910003594 H2PtCl6.6H2O Inorganic materials 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
101150000187 PTGS2 gene Proteins 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000003570 air Substances 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
229910001626 barium chloride Inorganic materials 0.000 description 1
230000008901 benefit Effects 0.000 description 1
AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
230000008859 change Effects 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical class CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
238000001816 cooling Methods 0.000 description 1
MPTQRFCYZCXJFQ-UHFFFAOYSA-L copper(II) chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Cu+2] MPTQRFCYZCXJFQ-UHFFFAOYSA-L 0.000 description 1
238000007033 dehydrochlorination reaction Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000000227 grinding Methods 0.000 description 1
238000007038 hydrochlorination reaction Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
WSSMOXHYUFMBLS-UHFFFAOYSA-L iron dichloride tetrahydrate Chemical compound O.O.O.O.[Cl-].[Cl-].[Fe+2] WSSMOXHYUFMBLS-UHFFFAOYSA-L 0.000 description 1
239000006166 lysate Substances 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
210000004197 pelvis Anatomy 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
229940102127 rubidium chloride Drugs 0.000 description 1
239000004576 sand Substances 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/10—Chlorides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/04—Chloro-alkenes
- C07C21/06—Vinyl chloride

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

SE7810845A 1977-10-19 1978-10-18 Katalysator for framstellning av vinylkloridmonomer samt kontinuerligt forfarande for syntes av vinylkloridmonomer SE438269B (sv)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/843,721 US4115323A (en)	1977-10-19	1977-10-19	Catalyst and process for production of VCM

Publications (2)

Publication Number	Publication Date
SE7810845L SE7810845L (sv)	1979-04-20
SE438269B true SE438269B (sv)	1985-04-15

Family

ID=25290834

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE7810845A SE438269B (sv)	1977-10-19	1978-10-18	Katalysator for framstellning av vinylkloridmonomer samt kontinuerligt forfarande for syntes av vinylkloridmonomer

Country Status (10)

Country	Link
US (1)	US4115323A (fr)
AU (1)	AU4068878A (fr)
BE (1)	BE871340A (fr)
DE (1)	DE2845403A1 (fr)
IN (1)	IN151550B (fr)
MX (2)	MX148584A (fr)
RO (1)	RO77346A (fr)
SE (1)	SE438269B (fr)
YU (1)	YU244078A (fr)
ZA (1)	ZA785867B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ITMI20030630A1 (it) *	2003-03-31	2004-10-01	Sued Chemie Mt Srl	Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano.
KR100882312B1 (ko) *	2005-11-17	2009-02-10	주식회사 엘지화학	1,2-디클로로에탄의 열분해에 의한 염화비닐의 제조장치 및이를 이용한 염화비닐의 제조방법
DE102006062331A1 (de) *	2006-12-22	2008-06-26	Uhde Gmbh	Herstellung von Vinylchlorid
CN112657524A (zh) *	2019-10-15	2021-04-16	新疆大学	一种用于乙炔氢氯化制氯乙烯的非汞催化剂及其制备和使用方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3641121A (en) *	1968-01-12	1972-02-08	Gulf Research Development Co	Preparation of vinyl acetate
US3651167A (en) *	1970-08-03	1972-03-21	Universal Oil Prod Co	Selective hydrogenation of c4-acetylenic hydrocarbons
FR2127310A5 (fr) *	1971-03-03	1972-10-13	Inst Francais Du Petrole
HU168073B (fr) *	1973-12-19	1976-02-28
US4055512A (en) *	1974-05-09	1977-10-25	Mitsubishi Chemical Industries Ltd.	Catalyst for producing cycloolefin and method for making the same

1977
- 1977-10-19 US US05/843,721 patent/US4115323A/en not_active Expired - Lifetime
1978
- 1978-09-18 IN IN1024/CAL/78A patent/IN151550B/en unknown
- 1978-10-13 AU AU40688/78A patent/AU4068878A/en active Pending
- 1978-10-16 RO RO7895413A patent/RO77346A/fr unknown
- 1978-10-18 SE SE7810845A patent/SE438269B/sv unknown
- 1978-10-18 ZA ZA00785867A patent/ZA785867B/xx unknown
- 1978-10-18 DE DE19782845403 patent/DE2845403A1/de not_active Withdrawn
- 1978-10-18 BE BE191177A patent/BE871340A/fr unknown
- 1978-10-18 MX MX175283A patent/MX148584A/es unknown
- 1978-10-18 MX MX175288A patent/MX148927A/es unknown
- 1978-10-18 YU YU02440/78A patent/YU244078A/xx unknown

Also Published As

Publication number	Publication date
YU244078A (en)	1982-10-31
SE7810845L (sv)	1979-04-20
DE2845403A1 (de)	1979-04-26
US4115323A (en)	1978-09-19
AU4068878A (en)	1980-04-17
MX148584A (es)	1983-05-12
ZA785867B (en)	1979-12-27
RO77346A (fr)	1981-08-17
MX148927A (es)	1983-07-12
BE871340A (fr)	1979-04-18
IN151550B (fr)	1983-05-21

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US5097081A (en)	1992-03-17	Hydrodechlorination of higher chloromethanes
CA1127186A (fr)	1982-07-06	Production de composes chlores a l'aide de sels en fusion
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