SE444005B - Forfarande for selektivt avlegsnande av antimon och vismut ur en elektrolytlosning - Google Patents
Forfarande for selektivt avlegsnande av antimon och vismut ur en elektrolytlosningInfo
- Publication number
- SE444005B SE444005B SE7810593A SE7810593A SE444005B SE 444005 B SE444005 B SE 444005B SE 7810593 A SE7810593 A SE 7810593A SE 7810593 A SE7810593 A SE 7810593A SE 444005 B SE444005 B SE 444005B
- Authority
- SE
- Sweden
- Prior art keywords
- electrolyte
- electrolyte solution
- antimony
- bismuth
- solution
- Prior art date
Links
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 title claims description 19
- 238000000034 method Methods 0.000 title claims description 11
- 239000008151 electrolyte solution Substances 0.000 title claims description 7
- QBWLKDFBINPHFT-UHFFFAOYSA-L 1,3,2$l^{2}-benzodioxabismin-4-one;hydrate Chemical compound O.C1=CC=C2C(=O)O[Bi]OC2=C1 QBWLKDFBINPHFT-UHFFFAOYSA-L 0.000 title 1
- 239000003792 electrolyte Substances 0.000 claims description 40
- 229910052797 bismuth Inorganic materials 0.000 claims description 24
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 22
- 229910052787 antimony Inorganic materials 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 14
- 238000001556 precipitation Methods 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 238000000746 purification Methods 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 2
- -1 salt cations Chemical class 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- 238000000975 co-precipitation Methods 0.000 claims 2
- 101100298295 Drosophila melanogaster flfl gene Proteins 0.000 claims 1
- 235000011149 sulphuric acid Nutrition 0.000 claims 1
- 239000002244 precipitate Substances 0.000 description 10
- 239000002002 slurry Substances 0.000 description 7
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Inorganic materials [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 5
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910000003 Lead carbonate Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229940021013 electrolyte solution Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
- C22B3/46—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes by substitution, e.g. by cementation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI772999A FI57619C (fi) | 1977-10-11 | 1977-10-11 | Foerfarande foer selektivt avlaegsnande av vismut och antimon ur elektrolyt speciellt vid elektrolytisk rening av koppar |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7810593L SE7810593L (sv) | 1979-04-12 |
| SE444005B true SE444005B (sv) | 1986-03-17 |
Family
ID=8511126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7810593A SE444005B (sv) | 1977-10-11 | 1978-10-10 | Forfarande for selektivt avlegsnande av antimon och vismut ur en elektrolytlosning |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4157946A (fr) |
| JP (1) | JPS5810995B2 (fr) |
| AU (1) | AU522663B2 (fr) |
| BR (1) | BR7806699A (fr) |
| CA (1) | CA1121301A (fr) |
| DD (1) | DD139727A1 (fr) |
| DE (1) | DE2844289C2 (fr) |
| ES (1) | ES473919A1 (fr) |
| FI (1) | FI57619C (fr) |
| IN (1) | IN150544B (fr) |
| MX (1) | MX150596A (fr) |
| PH (1) | PH15537A (fr) |
| SE (1) | SE444005B (fr) |
| ZA (1) | ZA785405B (fr) |
| ZM (1) | ZM8878A1 (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2002916A1 (de) * | 1970-01-23 | 1971-07-29 | Hoechst Ag | Verfahren zum Faerben oder Bedrucken von Textilmaterial aus Polymerisaten oder Mischpolymerisaten des Acrylnitrils |
| US4444666A (en) * | 1982-09-17 | 1984-04-24 | Sumitomo Metal Mining Company Limited | Method of removing antimony from an antimony-containing copper electrolyte |
| US4881971A (en) * | 1988-02-03 | 1989-11-21 | Thom Michael J | Refining of lead-debismuthizing |
| US5133948A (en) * | 1991-07-11 | 1992-07-28 | Asarco Incorporated | Process for the removal of bismuth from copper refining electrolyte by using lead oxide |
| US5573739A (en) * | 1994-10-28 | 1996-11-12 | Noranda, Inc. | Selective bismuth and antimony removal from copper electrolyte |
| JP2012067354A (ja) * | 2010-09-24 | 2012-04-05 | Dowa Metals & Mining Co Ltd | 非鉄金属の電解採取方法 |
| EA201691798A1 (ru) | 2014-03-07 | 2017-04-28 | Басф Се | Способы и системы для контроля концентрации металлических примесей во время металлургических процессов |
| US10208389B2 (en) | 2015-08-26 | 2019-02-19 | Basf Se | Methods and systems for reducing impurity metal from a refinery electrolyte solution |
| CN105568002B (zh) * | 2015-12-28 | 2017-06-06 | 中南大学 | 一种污酸硫化渣中铋富集与回收的方法 |
| CN106086935B (zh) * | 2016-08-29 | 2017-12-05 | 江西理工大学 | 一种从铜电解液除去砷、锑、铋的方法 |
| WO2020050418A1 (fr) * | 2018-09-07 | 2020-03-12 | パンパシフィック・カッパー株式会社 | Procédé de production de cuivre électrolytique |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US607646A (en) * | 1898-07-19 | Pascal marino | ||
| US1979229A (en) * | 1932-05-02 | 1934-10-30 | American Smelting Refining | Removing impurities from metallurgical solutions |
| JPS5128950B2 (fr) * | 1972-07-18 | 1976-08-23 | ||
| US3914163A (en) * | 1974-05-17 | 1975-10-21 | Mineral Research & Dev Corp | Recovery of metal and sulfate values from electrochemical mining electrolytes |
| JPS51100908A (fr) * | 1975-03-04 | 1976-09-06 | Nitsuso Kinzoku Kk |
-
1977
- 1977-10-11 FI FI772999A patent/FI57619C/fi not_active IP Right Cessation
-
1978
- 1978-09-14 JP JP53112463A patent/JPS5810995B2/ja not_active Expired
- 1978-09-22 ZA ZA00785405A patent/ZA785405B/xx unknown
- 1978-10-02 US US05/947,849 patent/US4157946A/en not_active Expired - Lifetime
- 1978-10-03 CA CA000312546A patent/CA1121301A/fr not_active Expired
- 1978-10-03 ES ES473919A patent/ES473919A1/es not_active Expired
- 1978-10-05 ZM ZM88/78A patent/ZM8878A1/xx unknown
- 1978-10-06 IN IN1096/CAL/78A patent/IN150544B/en unknown
- 1978-10-10 BR BR7806699A patent/BR7806699A/pt unknown
- 1978-10-10 AU AU40568/78A patent/AU522663B2/en not_active Expired
- 1978-10-10 SE SE7810593A patent/SE444005B/sv not_active IP Right Cessation
- 1978-10-10 MX MX175188A patent/MX150596A/es unknown
- 1978-10-11 DE DE2844289A patent/DE2844289C2/de not_active Expired
- 1978-10-11 DD DD78208396A patent/DD139727A1/de unknown
- 1978-10-11 PH PH21693A patent/PH15537A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES473919A1 (es) | 1979-04-01 |
| SE7810593L (sv) | 1979-04-12 |
| DE2844289C2 (de) | 1983-02-17 |
| JPS54119327A (en) | 1979-09-17 |
| JPS5810995B2 (ja) | 1983-02-28 |
| BR7806699A (pt) | 1979-05-08 |
| ZA785405B (en) | 1979-08-29 |
| FI57619C (fi) | 1980-09-10 |
| AU4056878A (en) | 1980-04-17 |
| MX150596A (es) | 1984-06-06 |
| DD139727A1 (de) | 1980-01-16 |
| ZM8878A1 (en) | 1979-06-21 |
| CA1121301A (fr) | 1982-04-06 |
| PH15537A (en) | 1983-02-09 |
| DE2844289A1 (de) | 1979-04-12 |
| IN150544B (fr) | 1982-11-13 |
| FI772999A7 (fi) | 1979-04-12 |
| AU522663B2 (en) | 1982-06-17 |
| US4157946A (en) | 1979-06-12 |
| FI57619B (fi) | 1980-05-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
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