SE450707B - Forfarande for framstellning av fenolhartsskum - Google Patents
Forfarande for framstellning av fenolhartsskumInfo
- Publication number
- SE450707B SE450707B SE8105917A SE8105917A SE450707B SE 450707 B SE450707 B SE 450707B SE 8105917 A SE8105917 A SE 8105917A SE 8105917 A SE8105917 A SE 8105917A SE 450707 B SE450707 B SE 450707B
- Authority
- SE
- Sweden
- Prior art keywords
- foam
- phenol
- weight
- acid
- composition
- Prior art date
Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims description 108
- 239000006260 foam Substances 0.000 title claims description 78
- 238000000034 method Methods 0.000 title claims description 19
- 238000002360 preparation method Methods 0.000 title description 18
- 239000000203 mixture Substances 0.000 claims description 133
- 229920005989 resin Polymers 0.000 claims description 54
- 239000011347 resin Substances 0.000 claims description 54
- 229920003987 resole Polymers 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000004094 surface-active agent Substances 0.000 claims description 27
- 239000004604 Blowing Agent Substances 0.000 claims description 19
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 14
- 229920002866 paraformaldehyde Polymers 0.000 claims description 13
- 239000011342 resin composition Substances 0.000 claims description 8
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 claims description 8
- 229940029284 trichlorofluoromethane Drugs 0.000 claims description 8
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
- 239000003377 acid catalyst Substances 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 4
- 230000014759 maintenance of location Effects 0.000 claims description 3
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 44
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 39
- 239000002253 acid Substances 0.000 description 31
- 229920001568 phenolic resin Polymers 0.000 description 28
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 22
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 20
- 239000003054 catalyst Substances 0.000 description 19
- 230000032683 aging Effects 0.000 description 14
- 238000002156 mixing Methods 0.000 description 14
- 239000011541 reaction mixture Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 11
- 235000019253 formic acid Nutrition 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 229920001296 polysiloxane Polymers 0.000 description 11
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 10
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 10
- 125000003118 aryl group Chemical group 0.000 description 10
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 210000004027 cell Anatomy 0.000 description 9
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 150000002989 phenols Chemical class 0.000 description 8
- 229940044654 phenolsulfonic acid Drugs 0.000 description 8
- 238000010992 reflux Methods 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 229940098779 methanesulfonic acid Drugs 0.000 description 5
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- -1 phenol compound Chemical class 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 239000002801 charged material Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 description 2
- LPCJHUPMQKSPDC-UHFFFAOYSA-N 3,5-diethylphenol Chemical compound CCC1=CC(O)=CC(CC)=C1 LPCJHUPMQKSPDC-UHFFFAOYSA-N 0.000 description 2
- HMNKTRSOROOSPP-UHFFFAOYSA-N 3-Ethylphenol Chemical compound CCC1=CC=CC(O)=C1 HMNKTRSOROOSPP-UHFFFAOYSA-N 0.000 description 2
- ZCLXQTGLKVQKFD-UHFFFAOYSA-N 3-hydroxybenzenesulfonic acid Chemical compound OC1=CC=CC(S(O)(=O)=O)=C1 ZCLXQTGLKVQKFD-UHFFFAOYSA-N 0.000 description 2
- 101100298295 Drosophila melanogaster flfl gene Proteins 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N Furaldehyde Natural products O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 2
- 229910001863 barium hydroxide Inorganic materials 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- SLGOCMATMKJJCE-UHFFFAOYSA-N 1,1,1,2-tetrachloro-2,2-difluoroethane Chemical compound FC(F)(Cl)C(Cl)(Cl)Cl SLGOCMATMKJJCE-UHFFFAOYSA-N 0.000 description 1
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- AHFMSNDOYCFEPH-UHFFFAOYSA-N 1,2-difluoroethane Chemical compound FCCF AHFMSNDOYCFEPH-UHFFFAOYSA-N 0.000 description 1
- DIZBQMTZXOUFTD-UHFFFAOYSA-N 2-(furan-2-yl)-3h-benzimidazole-5-carboxylic acid Chemical compound N1C2=CC(C(=O)O)=CC=C2N=C1C1=CC=CO1 DIZBQMTZXOUFTD-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- RILZRCJGXSFXNE-UHFFFAOYSA-N 2-[4-(trifluoromethoxy)phenyl]ethanol Chemical compound OCCC1=CC=C(OC(F)(F)F)C=C1 RILZRCJGXSFXNE-UHFFFAOYSA-N 0.000 description 1
- IULJSGIJJZZUMF-UHFFFAOYSA-N 2-hydroxybenzenesulfonic acid Chemical compound OC1=CC=CC=C1S(O)(=O)=O IULJSGIJJZZUMF-UHFFFAOYSA-N 0.000 description 1
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 description 1
- 150000000469 3,5-xylenols Chemical class 0.000 description 1
- BZOVBIIWPDQIHF-UHFFFAOYSA-N 3-hydroxy-2-methylbenzenesulfonic acid Chemical compound CC1=C(O)C=CC=C1S(O)(=O)=O BZOVBIIWPDQIHF-UHFFFAOYSA-N 0.000 description 1
- HTVITOHKHWFJKO-UHFFFAOYSA-N Bisphenol B Chemical compound C=1C=C(O)C=CC=1C(C)(CC)C1=CC=C(O)C=C1 HTVITOHKHWFJKO-UHFFFAOYSA-N 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 240000006927 Foeniculum vulgare Species 0.000 description 1
- 235000004204 Foeniculum vulgare Nutrition 0.000 description 1
- 241001406875 Mambara Species 0.000 description 1
- 241001659863 Panna Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920006266 Vinyl film Polymers 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- QDHFHIQKOVNCNC-UHFFFAOYSA-N butane-1-sulfonic acid Chemical compound CCCCS(O)(=O)=O QDHFHIQKOVNCNC-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 210000000497 foam cell Anatomy 0.000 description 1
- 238000013012 foaming technology Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 150000002672 m-cresols Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002883 o-cresols Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002931 p-cresols Chemical class 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/10—Applying counter-pressure during expanding
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/02—Molding cellular aldehyde resins
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/195,457 US4423163A (en) | 1980-10-09 | 1980-10-09 | Method of producing phenolic foam using pressure and foam produced by the method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE8105917L SE8105917L (sv) | 1982-04-10 |
| SE450707B true SE450707B (sv) | 1987-07-20 |
Family
ID=22721498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8105917A SE450707B (sv) | 1980-10-09 | 1981-10-07 | Forfarande for framstellning av fenolhartsskum |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US4423163A (fr) |
| JP (1) | JPS6013819B2 (fr) |
| AT (1) | AT380026B (fr) |
| AU (1) | AU540512B2 (fr) |
| BE (1) | BE890667A (fr) |
| CA (1) | CA1209746A (fr) |
| CH (1) | CH648050A5 (fr) |
| DE (1) | DE3139890C2 (fr) |
| ES (1) | ES8302746A1 (fr) |
| FI (1) | FI74425C (fr) |
| FR (1) | FR2491817B1 (fr) |
| GB (1) | GB2085886B (fr) |
| IE (1) | IE52481B1 (fr) |
| LU (1) | LU83689A1 (fr) |
| MX (1) | MX159777A (fr) |
| NL (1) | NL8104537A (fr) |
| NO (1) | NO157492C (fr) |
| SE (1) | SE450707B (fr) |
| ZA (1) | ZA816967B (fr) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4900759A (en) * | 1981-05-20 | 1990-02-13 | Monsanto Company | Phenolic foams |
| JPS581730A (ja) * | 1981-05-20 | 1983-01-07 | モンサント・カンパニ− | 硬化フエノ−ル系フオ−ム |
| US4444912A (en) * | 1981-07-10 | 1984-04-24 | Koppers Company, Inc. | Phenolic foam and composition and method for preparing the same |
| FI73445C (fi) * | 1982-07-09 | 1987-10-09 | Koppers Co Inc | Fenolformaldehydresoler foer framstaellning av fenolskum. |
| FI80896C (fi) * | 1984-05-25 | 1990-08-10 | Bp Chem Int Ltd | Foerfarande foer framstaellning av fenolskum. |
| US4546119A (en) * | 1984-11-29 | 1985-10-08 | Fiberglas Canada, Inc. | Closed cell phenolic foam |
| US4576972A (en) * | 1984-11-29 | 1986-03-18 | Fiberglas Canada, Inc. | Closed cell phenolic foam |
| DE3582432D1 (de) * | 1985-06-10 | 1991-05-08 | Dow Chemical Co | Verfahren zur herstellung eines phenol-aldehydschaums mit geschlossenen zellen und niedrigem k-faktor. |
| US4687787A (en) * | 1985-12-20 | 1987-08-18 | Allied Corporation | Foaming system for phenolic foams |
| US4713400A (en) * | 1985-12-20 | 1987-12-15 | Allied Corporation | Foaming system for phenolic foams |
| ZA894589B (en) * | 1989-02-09 | 1991-02-27 | K Sudan Krishan | Semi-flexible or flexible phenolic foam |
| US4956394A (en) * | 1989-12-12 | 1990-09-11 | Thermal Products International | Closed cell phenolic foam containing alkyl glucosides |
| DE69325823T2 (de) * | 1992-03-26 | 2000-04-27 | Positron Uk Ltd., London | Verfahren zur herstellung von schaumplatten aus phenol-formaldehyde |
| DE4303289C2 (de) * | 1993-02-05 | 1996-09-19 | Schuller Gmbh Glaswerk | Decklagenmaterial |
| US5407963A (en) * | 1994-06-09 | 1995-04-18 | Willson; Jennifer | Non-CFC foam produced using blended surfactants |
| EP0977804A1 (fr) * | 1997-05-02 | 2000-02-09 | Jiffy Foam, Inc. | Procede de formation d'une resine phenolique expansee a cellules fermees |
| JP3837226B2 (ja) * | 1998-02-05 | 2006-10-25 | 旭化成建材株式会社 | フェノール樹脂発泡体積層板およびその製造方法 |
| US6492432B1 (en) * | 1999-11-09 | 2002-12-10 | American Foam Technologies, Inc. | Novolac-epoxy resin foam, foamable composition for making novolac-epoxy resin foam and method of making novolac-epoxy resin foam |
| KR20120120474A (ko) * | 2010-03-26 | 2012-11-01 | 아사히 가세이 겐자이 가부시키가이샤 | 페놀 수지 발포체 적층판 및 그 제조 방법 |
| CN105593277B (zh) | 2013-06-21 | 2019-06-25 | 泽费罗斯股份有限公司 | 热稳定的软质可膨胀密封剂组合物 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB586199A (en) * | 1944-07-20 | 1947-03-11 | Semtex Ltd | Improvements in or relating to the production of cellular synthetic resin compositions |
| US2653139A (en) * | 1950-05-20 | 1953-09-22 | Westinghouse Electric Corp | In-place expanded cellular resinous bodies and processes for producing them from phenol-aldehyde resins with the aid of a peroxide |
| US2979469A (en) * | 1957-12-30 | 1961-04-11 | Owens Corning Fiberglass Corp | Production of phenolic foams |
| US3182104A (en) * | 1962-02-14 | 1965-05-04 | Glidden Co | Process for making thick-skinned articles comprising polyurethane foam |
| FR1524032A (fr) * | 1963-05-03 | 1968-05-10 | Bayer Ag | Procédé de fabrication de pièces moulées en matières synthétiques à l'état de mousse |
| US3298973A (en) * | 1963-10-10 | 1967-01-17 | Union Carbide Corp | Phenolic foam compositions |
| US3354503A (en) * | 1964-04-02 | 1967-11-28 | Gen Tire & Rubber Co | Urethane foaming apparatus |
| DE1778708A1 (de) * | 1968-05-27 | 1971-08-12 | Hanning Kunststoffe R | Verfahren und Vorrichtung zur fortlaufenden Herstellung von Strangprofilen aus fluessig verschaeumbaren Kunststoffen auf Zwei-oder Mehrkomponentenbasis |
| DE1769506A1 (de) * | 1968-06-04 | 1971-07-29 | Dynamit Nobel Ag | Verfahren zur Herstellung von Platten oder Formkoerpern aus schaeumbaren Phenolharzen |
| DE1920867C3 (de) * | 1969-04-24 | 1975-10-02 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von Phenolharzschaumstoffen |
| PL82451B1 (fr) * | 1969-06-23 | 1975-10-31 | Dynamit Nobel Ag | |
| CH542703A (de) * | 1971-07-07 | 1973-10-15 | Contraves Ag | Verfahren zum Herstellen von Bauelementen durch Verkleben von Feststoffpartikeln mit Kunstharz |
| ZA721386B (en) * | 1971-12-02 | 1972-11-29 | Dynamit Nobel Ag | Process and device for the continous production of phenolic-resin foam in endless runs |
| US3835208A (en) * | 1972-06-09 | 1974-09-10 | Exxon Research Engineering Co | Method for producing an integral skin phenolic foam |
| US3821337A (en) * | 1973-05-07 | 1974-06-28 | Exxon Research Engineering Co | Process for controlled curing of foams |
| GB1489871A (en) * | 1973-11-05 | 1977-10-26 | Ici Ltd | Resin-containing mouldings and process for the manufacture thereof |
| AT351242B (de) * | 1974-01-28 | 1979-07-10 | Oesterr Heraklith Ag | Verfahren und form zur diskontinuierlichen herstellung von hartschaumstoffkoerpern |
| US3968300A (en) * | 1975-02-24 | 1976-07-06 | The Celotex Corporation | Phenolic polymer, related products and processes thereof |
| US4107107A (en) * | 1976-06-16 | 1978-08-15 | Westinghouse Electric Corp. | Process for the manufacture of a flame resistant, insulating, energy-absorbing, porous phenolic foam |
| DE2632302C3 (de) * | 1976-07-17 | 1980-09-18 | Maschinenfabrik Hennecke Gmbh, 5090 Leverkusen | Vorrichtung zum kontinuierlichen Herstellen von Schaumstoffblöcken mit rechteckigem Querschnitt |
| CA1105649A (fr) * | 1977-04-26 | 1981-07-21 | Jean C. Paladini | Procede pour la fabrication de mousses de phenol- formaldehyde |
| US4176216A (en) * | 1977-07-28 | 1979-11-27 | Union Carbide Corporation | Cellular products derived from phenol/formaldehyde resoles |
| FR2413198A1 (fr) * | 1977-12-30 | 1979-07-27 | Stratiforme Sa | Panneau en resine phenolique expanse et son procede de fabrication |
| FR2414403A1 (fr) * | 1978-01-16 | 1979-08-10 | Stratiforme | Panneau a base de resine phenolique et son procede de fabrication |
| US4256803A (en) * | 1979-01-11 | 1981-03-17 | Societe Anonyme Dite Stratiforme | Panel based on polycondensable resin and a method for the manufacture of this panel |
-
1980
- 1980-10-09 US US06/195,457 patent/US4423163A/en not_active Expired - Lifetime
-
1981
- 1981-10-02 AU AU75977/81A patent/AU540512B2/en not_active Ceased
- 1981-10-06 NL NL8104537A patent/NL8104537A/nl active Search and Examination
- 1981-10-07 FI FI813106A patent/FI74425C/fi not_active IP Right Cessation
- 1981-10-07 SE SE8105917A patent/SE450707B/sv not_active IP Right Cessation
- 1981-10-07 DE DE3139890A patent/DE3139890C2/de not_active Expired
- 1981-10-08 GB GB8130438A patent/GB2085886B/en not_active Expired
- 1981-10-08 AT AT0431781A patent/AT380026B/de not_active IP Right Cessation
- 1981-10-08 CA CA000387559A patent/CA1209746A/fr not_active Expired
- 1981-10-08 ES ES506113A patent/ES8302746A1/es not_active Expired
- 1981-10-08 NO NO813409A patent/NO157492C/no unknown
- 1981-10-08 ZA ZA816967A patent/ZA816967B/xx unknown
- 1981-10-08 CH CH6462/81A patent/CH648050A5/de not_active IP Right Cessation
- 1981-10-08 BE BE0/206192A patent/BE890667A/fr not_active IP Right Cessation
- 1981-10-09 LU LU83689A patent/LU83689A1/fr unknown
- 1981-10-09 JP JP56161905A patent/JPS6013819B2/ja not_active Expired
- 1981-10-09 FR FR8119046A patent/FR2491817B1/fr not_active Expired
- 1981-10-09 IE IE2371/81A patent/IE52481B1/en not_active IP Right Cessation
- 1981-10-09 MX MX189583A patent/MX159777A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE3139890C2 (de) | 1988-03-03 |
| ES506113A0 (es) | 1983-01-16 |
| NO813409L (no) | 1982-04-13 |
| AT380026B (de) | 1986-03-25 |
| ATA431781A (de) | 1985-08-15 |
| MX159777A (es) | 1989-08-18 |
| ZA816967B (en) | 1982-09-29 |
| FI813106L (fi) | 1982-04-10 |
| JPS5791244A (en) | 1982-06-07 |
| NO157492B (no) | 1987-12-21 |
| BE890667A (fr) | 1982-02-01 |
| DE3139890A1 (de) | 1982-06-09 |
| FI74425B (fi) | 1987-10-30 |
| NL8104537A (nl) | 1982-05-03 |
| AU540512B2 (en) | 1984-11-22 |
| AU7597781A (en) | 1982-04-22 |
| IE812371L (en) | 1982-04-09 |
| CH648050A5 (de) | 1985-02-28 |
| FR2491817B1 (fr) | 1985-07-12 |
| CA1209746A (fr) | 1986-08-12 |
| IE52481B1 (en) | 1987-11-11 |
| NO157492C (no) | 1988-03-30 |
| GB2085886B (en) | 1985-04-03 |
| ES8302746A1 (es) | 1983-01-16 |
| US4423163A (en) | 1983-12-27 |
| FR2491817A1 (fr) | 1982-04-16 |
| JPS6013819B2 (ja) | 1985-04-09 |
| SE8105917L (sv) | 1982-04-10 |
| LU83689A1 (fr) | 1982-02-18 |
| FI74425C (fi) | 1988-02-08 |
| GB2085886A (en) | 1982-05-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SE450707B (sv) | Forfarande for framstellning av fenolhartsskum | |
| KR101937118B1 (ko) | 페놀 수지 발포체 적층판 및 그 제조 방법 | |
| KR102185122B1 (ko) | 멜라민/포름알데히드 발포체의 제조 방법 | |
| US4444912A (en) | Phenolic foam and composition and method for preparing the same | |
| US9957368B2 (en) | Phenolic resin foam board, and method for manufacturing same | |
| US4478958A (en) | Method for preparing phenolic foams using anhydrous aryl sulfonic acid catalysts | |
| US20230312854A1 (en) | Phenolic foam | |
| BE1002739A6 (nl) | Hoofdzakelijk gesloten celvorming hard fenolschuim en werkwijze voor het bereiden van dit fenolschuim. | |
| EP0432355A2 (fr) | Mousse phénolique améliorée à cellules fermées contenant des alkylglucosides | |
| US4720510A (en) | Process for producing phenolic foams | |
| US20100204351A1 (en) | Phenolic novolac foams and compositions for preparing them | |
| DK169351B1 (da) | Fremgangsmåde til fremstilling af phenolharpiksskumstoffer under anvendelse af tryk | |
| EP0028956A1 (fr) | Fabrication en continu de plaques en mousse phénolique | |
| NZ212187A (en) | Process for the production of phenolic foams | |
| IE55615B1 (en) | Improvements in or relating to phenolic foams |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NAL | Patent in force |
Ref document number: 8105917-2 Format of ref document f/p: F |
|
| NUG | Patent has lapsed |
Ref document number: 8105917-2 Format of ref document f/p: F |