SE452773B - Friflytande, spraytorkat perlmaterial och uppslamning for dess framstellning - Google Patents

Friflytande, spraytorkat perlmaterial och uppslamning for dess framstellning

Info

Publication number: SE452773B
Authority: SE; Sweden
Prior art keywords: weight; range; zeolite; sodium; water
Prior art date: 1981-02-26

Application number

SE8201170A

Other languages

English (en)

Swedish (sv)

Other versions

SE8201170L (sv

Inventor

J J Grecsek

S W Giordano

S Grey

Original Assignee

Colgate Palmolive Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-02-26

Filing date

1982-02-25

Publication date

1987-12-14

1982-02-25 Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co

1982-08-27 Publication of SE8201170L publication Critical patent/SE8201170L/

1987-12-14 Publication of SE452773B publication Critical patent/SE452773B/sv

Links

239000000463 material Substances 0.000 title claims description 131
238000002360 preparation method Methods 0.000 title description 11
239000012530 fluid Substances 0.000 title 2
239000003599 detergent Substances 0.000 claims description 168
239000011324 bead Substances 0.000 claims description 131
239000010457 zeolite Substances 0.000 claims description 125
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 108
229910021536 Zeolite Inorganic materials 0.000 claims description 101
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 98
229910001868 water Inorganic materials 0.000 claims description 93
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 89
229920000058 polyacrylate Polymers 0.000 claims description 58
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 54
239000000440 bentonite Substances 0.000 claims description 50
229910000278 bentonite Inorganic materials 0.000 claims description 50
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 50
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 43
229910000029 sodium carbonate Inorganic materials 0.000 claims description 43
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 37
239000004115 Sodium Silicate Substances 0.000 claims description 35
229910052911 sodium silicate Inorganic materials 0.000 claims description 35
235000017557 sodium bicarbonate Nutrition 0.000 claims description 27
229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 27
238000001694 spray drying Methods 0.000 claims description 25
239000007787 solid Substances 0.000 claims description 24
235000019341 magnesium sulphate Nutrition 0.000 claims description 21
239000011734 sodium Substances 0.000 claims description 21
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 20
229910052943 magnesium sulfate Inorganic materials 0.000 claims description 20
239000002245 particle Substances 0.000 claims description 19
229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 18
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 17
239000002671 adjuvant Substances 0.000 claims description 16
238000004519 manufacturing process Methods 0.000 claims description 15
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
239000002002 slurry Substances 0.000 claims description 14
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 13
229910001424 calcium ion Inorganic materials 0.000 claims description 13
IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 12
235000013799 ultramarine blue Nutrition 0.000 claims description 12
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
229910052708 sodium Inorganic materials 0.000 claims description 11
229910004298 SiO 2 Inorganic materials 0.000 claims description 10
239000007844 bleaching agent Substances 0.000 claims description 8
239000004927 clay Substances 0.000 claims description 8
229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
239000001509 sodium citrate Substances 0.000 claims description 7
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 7
230000008961 swelling Effects 0.000 claims description 7
238000005342 ion exchange Methods 0.000 claims description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
235000012239 silicon dioxide Nutrition 0.000 claims description 2
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims 1
229910052681 coesite Inorganic materials 0.000 claims 1
229910052906 cristobalite Inorganic materials 0.000 claims 1
HDFXRQJQZBPDLF-UHFFFAOYSA-L disodium hydrogen carbonate Chemical compound [Na+].[Na+].OC([O-])=O.OC([O-])=O HDFXRQJQZBPDLF-UHFFFAOYSA-L 0.000 claims 1
239000000377 silicon dioxide Substances 0.000 claims 1
229910052682 stishovite Inorganic materials 0.000 claims 1
229910052905 tridymite Inorganic materials 0.000 claims 1
239000000203 mixture Substances 0.000 description 150
239000000047 product Substances 0.000 description 76
235000012216 bentonite Nutrition 0.000 description 44
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 42
229940092782 bentonite Drugs 0.000 description 40
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 35
235000017550 sodium carbonate Nutrition 0.000 description 32
238000002156 mixing Methods 0.000 description 28
238000005406 washing Methods 0.000 description 27
239000007788 liquid Substances 0.000 description 25
102000004190 Enzymes Human genes 0.000 description 19
108090000790 Enzymes Proteins 0.000 description 19
229940088598 enzyme Drugs 0.000 description 19
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 18
239000012467 final product Substances 0.000 description 18
239000002304 perfume Substances 0.000 description 18
239000007921 spray Substances 0.000 description 17
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 15
239000004614 Process Aid Substances 0.000 description 15
229920002125 Sokalan® Polymers 0.000 description 15
239000000654 additive Substances 0.000 description 14
239000000843 powder Substances 0.000 description 13
239000007864 aqueous solution Substances 0.000 description 12
230000000694 effects Effects 0.000 description 12
238000000034 method Methods 0.000 description 12
239000006081 fluorescent whitening agent Substances 0.000 description 11
-1 alkali metal salts Chemical class 0.000 description 10
239000000126 substance Substances 0.000 description 10
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 9
239000013078 crystal Substances 0.000 description 9
238000000151 deposition Methods 0.000 description 9
238000001035 drying Methods 0.000 description 9
238000002474 experimental method Methods 0.000 description 9
239000011521 glass Substances 0.000 description 9
238000012360 testing method Methods 0.000 description 9
229920000742 Cotton Polymers 0.000 description 8
230000008021 deposition Effects 0.000 description 8
238000001879 gelation Methods 0.000 description 8
239000002609 medium Substances 0.000 description 8
239000000049 pigment Substances 0.000 description 8
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 8
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 7
230000000996 additive effect Effects 0.000 description 7
238000000354 decomposition reaction Methods 0.000 description 7
239000000975 dye Substances 0.000 description 7
239000002808 molecular sieve Substances 0.000 description 7
230000008569 process Effects 0.000 description 7
239000000243 solution Substances 0.000 description 7
229910052783 alkali metal Inorganic materials 0.000 description 6
238000004140 cleaning Methods 0.000 description 6
230000036571 hydration Effects 0.000 description 6
238000006703 hydration reaction Methods 0.000 description 6
238000007711 solidification Methods 0.000 description 6
230000008023 solidification Effects 0.000 description 6
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 5
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
229910019142 PO4 Inorganic materials 0.000 description 5
230000008901 benefit Effects 0.000 description 5
238000005260 corrosion Methods 0.000 description 5
239000008367 deionised water Substances 0.000 description 5
229910021641 deionized water Inorganic materials 0.000 description 5
239000004744 fabric Substances 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
239000010452 phosphate Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
239000006057 Non-nutritive feed additive Substances 0.000 description 4
108091005804 Peptidases Proteins 0.000 description 4
102000035195 Peptidases Human genes 0.000 description 4
108010056079 Subtilisins Proteins 0.000 description 4
102000005158 Subtilisins Human genes 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 4
239000012736 aqueous medium Substances 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
230000008859 change Effects 0.000 description 4
150000002191 fatty alcohols Chemical class 0.000 description 4
230000006872 improvement Effects 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
239000011368 organic material Substances 0.000 description 4
239000004014 plasticizer Substances 0.000 description 4
229920000728 polyester Polymers 0.000 description 4
238000003756 stirring Methods 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
230000002411 adverse Effects 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
238000004061 bleaching Methods 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
239000011575 calcium Substances 0.000 description 3
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000007859 condensation product Substances 0.000 description 3
230000007423 decrease Effects 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
239000000945 filler Substances 0.000 description 3
229910010272 inorganic material Inorganic materials 0.000 description 3
239000011147 inorganic material Substances 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
239000011591 potassium Substances 0.000 description 3
230000000717 retained effect Effects 0.000 description 3
159000000000 sodium salts Chemical class 0.000 description 3
238000005507 spraying Methods 0.000 description 3
239000000725 suspension Substances 0.000 description 3
108091005658 Basic proteases Proteins 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical group [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
239000004677 Nylon Substances 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
230000000844 anti-bacterial effect Effects 0.000 description 2
239000002585 base Substances 0.000 description 2
229940043430 calcium compound Drugs 0.000 description 2
150000001674 calcium compounds Chemical class 0.000 description 2
239000000292 calcium oxide Substances 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
239000012876 carrier material Substances 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
150000001860 citric acid derivatives Chemical class 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
238000010410 dusting Methods 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
229940091250 magnesium supplement Drugs 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
229910052901 montmorillonite Inorganic materials 0.000 description 2
229920001778 nylon Polymers 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
238000010298 pulverizing process Methods 0.000 description 2
230000009467 reduction Effects 0.000 description 2
239000004576 sand Substances 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
UCTWMZQNUQWSLP-VIFPVBQESA-N (R)-adrenaline Chemical class CNC[C@H](O)C1=CC=C(O)C(O)=C1 UCTWMZQNUQWSLP-VIFPVBQESA-N 0.000 description 1
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
XCMDVRAWAIYDEE-UHFFFAOYSA-N 1,2-diphenyl-3h-pyrazole Chemical class C1C=CN(C=2C=CC=CC=2)N1C1=CC=CC=C1 XCMDVRAWAIYDEE-UHFFFAOYSA-N 0.000 description 1
QWZHDKGQKYEBKK-UHFFFAOYSA-N 3-aminochromen-2-one Chemical compound C1=CC=C2OC(=O)C(N)=CC2=C1 QWZHDKGQKYEBKK-UHFFFAOYSA-N 0.000 description 1
REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(e)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
206010067484 Adverse reaction Diseases 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
102000005701 Calcium-Binding Proteins Human genes 0.000 description 1
108010045403 Calcium-Binding Proteins Proteins 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
239000004129 EU approved improving agent Substances 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
241000282376 Panthera tigris Species 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
239000004111 Potassium silicate Substances 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
108090000787 Subtilisin Proteins 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
239000012190 activator Substances 0.000 description 1
230000006838 adverse reaction Effects 0.000 description 1
238000007605 air drying Methods 0.000 description 1
125000003158 alcohol group Chemical group 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
102000004139 alpha-Amylases Human genes 0.000 description 1
108090000637 alpha-Amylases Proteins 0.000 description 1
229940024171 alpha-amylase Drugs 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
230000003625 amylolytic effect Effects 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 1
210000000988 bone and bone Anatomy 0.000 description 1
150000003842 bromide salts Chemical class 0.000 description 1
238000001354 calcination Methods 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000001175 calcium sulphate Substances 0.000 description 1
235000011132 calcium sulphate Nutrition 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
HFNQLYDPNAZRCH-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O.OC(O)=O HFNQLYDPNAZRCH-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical class O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
150000001767 cationic compounds Chemical class 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
230000001934 delay Effects 0.000 description 1
ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
239000000428 dust Substances 0.000 description 1
229910052675 erionite Inorganic materials 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000000834 fixative Substances 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
150000004677 hydrates Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
230000003165 hydrotropic effect Effects 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000011068 loading method Methods 0.000 description 1
239000002932 luster Substances 0.000 description 1
229960005336 magnesium citrate Drugs 0.000 description 1
235000002538 magnesium citrate Nutrition 0.000 description 1
239000004337 magnesium citrate Substances 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000003595 mist Substances 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
229910052680 mordenite Inorganic materials 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
239000003973 paint Substances 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000867 polyelectrolyte Polymers 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
229910052913 potassium silicate Inorganic materials 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
239000010453 quartz Substances 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
238000001226 reprecipitation Methods 0.000 description 1
238000012958 reprocessing Methods 0.000 description 1
210000002374 sebum Anatomy 0.000 description 1
239000000344 soap Substances 0.000 description 1
239000000429 sodium aluminium silicate Substances 0.000 description 1
235000012217 sodium aluminium silicate Nutrition 0.000 description 1
229940080314 sodium bentonite Drugs 0.000 description 1
229910000280 sodium bentonite Inorganic materials 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
239000002904 solvent Substances 0.000 description 1
235000015096 spirit Nutrition 0.000 description 1
235000021286 stilbenes Nutrition 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
239000008400 supply water Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
230000009974 thixotropic effect Effects 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
PLSARIKBYIPYPF-UHFFFAOYSA-H trimagnesium dicitrate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O PLSARIKBYIPYPF-UHFFFAOYSA-H 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
238000005303 weighing Methods 0.000 description 1
210000004885 white matter Anatomy 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Biochemistry (AREA)
Detergent Compositions (AREA)

SE8201170A 1981-02-26 1982-02-25 Friflytande, spraytorkat perlmaterial och uppslamning for dess framstellning SE452773B (sv)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date
US23861981A	1981-02-26	1981-02-26
US23862081A	1981-02-26	1981-02-26
US27955081A	1981-07-01	1981-07-01

Publications (2)

Publication Number	Publication Date
SE8201170L SE8201170L (sv)	1982-08-27
SE452773B true SE452773B (sv)	1987-12-14

Family

ID=27399126

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
SE8201170A SE452773B (sv)	1981-02-26	1982-02-25	Friflytande, spraytorkat perlmaterial och uppslamning for dess framstellning
SE8703474A SE502089C2 (sv)	1981-02-26	1987-09-08	Detergentkomposition som består av ett pärlmaterial i vilket absorberats en nonjonaktiv detergent

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
SE8703474A SE502089C2 (sv)	1981-02-26	1987-09-08	Detergentkomposition som består av ett pärlmaterial i vilket absorberats en nonjonaktiv detergent

Country Status (22)

Country	Link
AT (1)	AT388172B (de)
AU (1)	AU549000B2 (de)
BR (1)	BR8200996A (de)
CA (1)	CA1188953A (de)
CH (1)	CH652416A5 (de)
DE (1)	DE3206265C2 (de)
DK (1)	DK160885C (de)
DO (1)	DOP1982003096A (de)
ES (1)	ES8305412A1 (de)
FR (1)	FR2500475B1 (de)
GB (1)	GB2097419B (de)
GR (1)	GR76028B (de)
HK (1)	HK36190A (de)
IE (1)	IE52739B1 (de)
IT (1)	IT1147643B (de)
MX (1)	MX158565A (de)
NL (1)	NL8200804A (de)
NO (1)	NO153736C (de)
NZ (1)	NZ199773A (de)
PT (1)	PT74486B (de)
SE (2)	SE452773B (de)
ZW (2)	ZW3382A1 (de)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU549122B2 (en) *	1981-02-26	1986-01-16	Colgate-Palmolive Pty. Ltd.	Spray dried base beads and detergent compositions
EP0124913B1 (de) *	1983-04-08	1986-06-18	THE PROCTER & GAMBLE COMPANY	Granulierte Detergenszusammensetzungen, welche ein gemischtes Polymerzusatzsystem enthalten
US4490271A (en) *	1983-06-30	1984-12-25	The Procter & Gamble Company	Detergent compositions containing polyethylene glycol and polyacrylate
US4510066A (en) *	1983-07-06	1985-04-09	Colgate-Palmolive Company	Retarding setting of crutcher slurry for manufacturing base beads for detergent compositions
FR2568790B1 (fr) *	1984-08-10	1990-01-12	Rhone Poulenc Chim Base	Procede d'obtention d'une suspension aqueuse stable et pompable de zeolite et suspension ainsi obtenue
DE3444960A1 (de) *	1984-12-10	1986-06-12	Henkel KGaA, 4000 Düsseldorf	Koerniges adsorptionsmittel
SE466963B (sv) *	1984-12-24	1992-05-04	Colgate Palmolive Co	Textilmjukgoerande hoegverkande flytande detergent med stabil viskositet
CA1297376C (en) *	1985-11-01	1992-03-17	David Philip Jones	Detergent compositions, components therefor, and processes for theirpreparation
GB8526999D0 (en) *	1985-11-01	1985-12-04	Unilever Plc	Detergent compositions
DE3545947A1 (de) *	1985-12-23	1987-07-02	Henkel Kgaa	Phosphatfreies, granulares waschmittel
GB8607388D0 (en) *	1986-03-25	1986-04-30	Unilever Plc	Activator compositions
CA1286563C (en) *	1986-04-04	1991-07-23	Jan Hendrik Eertink	Detergent powders and processes for preparing them
GB8609044D0 (en) *	1986-04-14	1986-05-21	Unilever Plc	Detergent powders
DE3641314A1 (de) *	1986-12-03	1988-06-09	Henkel Kgaa	Waeschenachbehandlungsmittel auf der basis von schichtsilikat
GB8709057D0 (en) *	1987-04-15	1987-05-20	Unilever Plc	Composition for softening fabrics
DE3715052A1 (de) *	1987-05-06	1988-11-17	Degussa	Koerniges adsorptionsmittel
DE3717227A1 (de) *	1987-05-21	1988-12-01	Henkel Kgaa	Phosphatfreies waschmittel mit reduzierter inkrustierungstendenz
DE3818660A1 (de) *	1987-06-05	1988-12-15	Colgate Palmolive Co	Freifliessendes, pulvriges geschirrwaschmittel und verfahren zur herstellung desselben
GB2194793A (en) *	1987-10-15	1988-03-16	Unilever Plc	Mottled liquid detergents
GB8823008D0 (en) *	1988-09-30	1988-11-09	Unilever Plc	Composition for softening fabrics
DE3835918A1 (de) *	1988-10-21	1990-04-26	Henkel Kgaa	Verfahren zur herstellung von tensidhaltigen granulaten
GB8918984D0 (en) *	1989-08-21	1989-10-04	Unilever Plc	Detergent compositions
DE3943019A1 (de) *	1989-12-27	1991-07-04	Henkel Kgaa	Granulares, avivierend wirkendes waschmitteladditiv und verfahren zu seiner herstellung
GB9008462D0 (en) *	1990-04-12	1990-06-13	Ecc Int Ltd	Granules for detergent compositions
EP0477974B1 (de) *	1990-09-28	1995-09-13	Kao Corporation	Nichtionische pulverförmige Detergentzusammensetzung
AU649504B2 (en) *	1991-07-03	1994-05-26	Kao Corporation	Nonionic powder detergent composition
AU3524093A (en) *	1992-03-27	1993-09-30	Kao Corporation	Nonionic powdery detergent composition and process for producing the same
AU4324693A (en) *	1992-06-18	1994-01-04	Unilever Plc	Machine dishwashing composition
AU660101B2 (en) *	1992-08-07	1995-06-08	Colgate-Palmolive Company, The	Heavy duty laundry detergent compositions of reduced dye transfer properties
TR27896A (tr) *	1993-08-05	1995-10-11	Colgate Palmolive Co	Boya transferi özellikleri düsürülmüs agir is camasir deterjani bilesimleri.
DE19538029A1 (de) *	1995-10-12	1997-04-17	Sued Chemie Ag	Waschmittelzusatz
DE19538028A1 (de) *	1995-10-12	1997-04-17	Sued Chemie Ag	Waschmittelzusatz
US5962389A (en) *	1995-11-17	1999-10-05	The Dial Corporation	Detergent having improved color retention properties
US5726142A (en) *	1995-11-17	1998-03-10	The Dial Corp	Detergent having improved properties and method of preparing the detergent
DE19858888A1 (de) *	1998-12-19	2000-06-21	Henkel Kgaa	Verhinderung von Ablagerungen
CN1163580C (zh) *	1998-12-28	2004-08-25	花王株式会社	表面活性剂载体颗粒的制造方法
GB2348435A (en) *	1999-04-01	2000-10-04	Procter & Gamble	Softening compositions
GB2348434A (en) *	1999-04-01	2000-10-04	Procter & Gamble	Detergent compositions
US6864221B1 (en)	1999-06-14	2005-03-08	Kao Corporation	Granules for carrying surfactant and method for producing the same
CN1170921C (zh) *	1999-06-14	2004-10-13	花王株式会社	基本颗粒物和颗粒状洗涤剂
DE60040462D1 (de) *	1999-06-16	2008-11-20	Kao Corp	Teilchenförmiges waschmitteladditiv
US6333005B1 (en) *	1999-06-16	2001-12-25	Hercules Incorporated	Methods of preventing scaling involving inorganic compositions in combination with copolymers of maleic anhydride and isobutylene, and compositions therefor
DE19938640A1 (de) *	1999-08-14	2001-02-15	Henkel Kgaa	Verhinderung von Ablagerungen
DE10032127A1 (de) *	2000-07-05	2002-01-24	Henkel Kgaa	Mechanisch stabile Soda-Partikel
DE10040631A1 (de) *	2000-08-16	2002-03-07	Wolfram Koch	Vergilbungshemmer für Blue Denim Textilien
US20090029896A1 (en) *	2006-02-24	2009-01-29	Andrew Paul Chapple	Fast Release Granules
JP5388860B2 (ja) *	2007-11-16	2014-01-15	花王株式会社	洗剤ビルダー顆粒
US20240156100A1 (en) *	2022-11-11	2024-05-16	Ken W Donovan	Odor and microbial mitigation solution
WO2024240519A1 (en) *	2023-05-22	2024-11-28	Basf Se	Solid detergent formulation

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4166039A (en) *	1973-10-15	1979-08-28	The Proctor & Gamble Company	Detergent composition and process
DE2547389A1 (de) *	1975-10-23	1977-05-05	Henkel & Cie Gmbh	Phosphatfreies waschmittel
NZ188469A (en) *	1977-10-06	1980-12-19	Colgate Palmolive Co	Detergent composition comprising a univalent cation-exchanging zeolite a nonionic detergent and builder salts
US4303556A (en) *	1977-11-02	1981-12-01	The Procter & Gamble Company	Spray-dried detergent compositions
GB2063289B (en) *	1979-11-13	1984-02-22	Unilever Ltd	Low phosphate spray-dried powders

1982
- 1982-02-09 AU AU80283/82A patent/AU549000B2/en not_active Ceased
- 1982-02-10 DO DO1982003096A patent/DOP1982003096A/es unknown
- 1982-02-17 GR GR67338A patent/GR76028B/el unknown
- 1982-02-18 NZ NZ199773A patent/NZ199773A/en unknown
- 1982-02-20 DE DE3206265A patent/DE3206265C2/de not_active Expired
- 1982-02-23 ZW ZW33/82A patent/ZW3382A1/xx unknown
- 1982-02-23 ZW ZW32/82A patent/ZW3282A1/xx unknown
- 1982-02-24 CH CH1136/82A patent/CH652416A5/de not_active IP Right Cessation
- 1982-02-24 AT AT0069082A patent/AT388172B/de not_active IP Right Cessation
- 1982-02-25 SE SE8201170A patent/SE452773B/sv not_active IP Right Cessation
- 1982-02-25 FR FR8203113A patent/FR2500475B1/fr not_active Expired
- 1982-02-25 PT PT74486A patent/PT74486B/pt not_active IP Right Cessation
- 1982-02-25 ES ES509904A patent/ES8305412A1/es not_active Expired
- 1982-02-25 DK DK083382A patent/DK160885C/da active
- 1982-02-25 IT IT47865/82A patent/IT1147643B/it active
- 1982-02-25 NO NO820589A patent/NO153736C/no unknown
- 1982-02-25 BR BR8200996A patent/BR8200996A/pt not_active IP Right Cessation
- 1982-02-25 CA CA000397017A patent/CA1188953A/en not_active Expired
- 1982-02-26 MX MX191612A patent/MX158565A/es unknown
- 1982-02-26 GB GB8205685A patent/GB2097419B/en not_active Expired
- 1982-02-26 NL NL8200804A patent/NL8200804A/nl active Search and Examination
- 1982-02-26 IE IE433/82A patent/IE52739B1/en not_active IP Right Cessation
1987
- 1987-09-08 SE SE8703474A patent/SE502089C2/sv not_active IP Right Cessation
1990
- 1990-05-10 HK HK361/90A patent/HK36190A/xx unknown

Also Published As

Publication number	Publication date
IE52739B1 (en)	1988-02-03
CA1188953A (en)	1985-06-18
ES509904A0 (es)	1983-04-01
AT388172B (de)	1989-05-10
GB2097419A (en)	1982-11-03
FR2500475B1 (fr)	1985-06-28
IT1147643B (it)	1986-11-19
HK36190A (en)	1990-05-18
DOP1982003096A (es)	1987-11-17
BR8200996A (pt)	1983-01-04
IE820433L (en)	1982-08-26
PT74486B (en)	1983-09-01
SE8703474L (sv)	1987-09-08
ATA69082A (de)	1988-10-15
DK160885B (da)	1991-04-29
CH652416A5 (de)	1985-11-15
GB2097419B (en)	1985-04-17
IT8247865A0 (it)	1982-02-25
NO153736C (no)	1986-05-14
ZW3382A1 (en)	1982-06-16
DK83382A (da)	1982-08-27
FR2500475A1 (fr)	1982-08-27
NO153736B (no)	1986-02-03
SE8201170L (sv)	1982-08-27
NZ199773A (en)	1984-11-09
GR76028B (de)	1984-08-03
SE502089C2 (sv)	1995-08-14
DK160885C (da)	1991-10-21
NL8200804A (nl)	1982-09-16
DE3206265A1 (de)	1982-11-04
ES8305412A1 (es)	1983-04-01
MX158565A (es)	1989-02-15
NO820589L (no)	1982-08-27
SE8703474D0 (sv)	1987-09-08
ZW3282A1 (en)	1982-07-21
AU549000B2 (en)	1986-01-09
AU8028382A (en)	1982-09-02
DE3206265C2 (de)	1987-04-09

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