SE503455C2 - Beredning av sulfitinnehållande kokvätska och användning av kokvätskan för förimpregnering - Google Patents
Beredning av sulfitinnehållande kokvätska och användning av kokvätskan för förimpregneringInfo
- Publication number
- SE503455C2 SE503455C2 SE9303137A SE9303137A SE503455C2 SE 503455 C2 SE503455 C2 SE 503455C2 SE 9303137 A SE9303137 A SE 9303137A SE 9303137 A SE9303137 A SE 9303137A SE 503455 C2 SE503455 C2 SE 503455C2
- Authority
- SE
- Sweden
- Prior art keywords
- liquid
- gas
- sulphite
- impregnation
- cooking
- Prior art date
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 78
- 238000010411 cooking Methods 0.000 title claims abstract description 40
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 title claims abstract description 32
- 238000005470 impregnation Methods 0.000 title claims description 20
- 238000002360 preparation method Methods 0.000 title claims description 19
- 239000007789 gas Substances 0.000 claims abstract description 65
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000003513 alkali Substances 0.000 claims abstract description 24
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920002678 cellulose Polymers 0.000 claims abstract description 17
- 239000001913 cellulose Substances 0.000 claims abstract description 17
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 12
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 11
- 230000003647 oxidation Effects 0.000 claims abstract description 6
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims abstract description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 32
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 24
- 238000002309 gasification Methods 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 239000004744 fabric Substances 0.000 claims description 10
- 238000001704 evaporation Methods 0.000 claims description 9
- 238000009835 boiling Methods 0.000 claims description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 6
- 239000002826 coolant Substances 0.000 claims description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 239000002655 kraft paper Substances 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 4
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
- 239000008139 complexing agent Substances 0.000 claims description 3
- 230000029087 digestion Effects 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 239000002250 absorbent Substances 0.000 claims 1
- 230000002745 absorbent Effects 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 239000002657 fibrous material Substances 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 36
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 2
- 239000001257 hydrogen Substances 0.000 abstract description 2
- 241001062472 Stokellia anisodon Species 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 7
- 238000011069 regeneration method Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 6
- 238000004064 recycling Methods 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 150000003464 sulfur compounds Chemical class 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- 150000003568 thioethers Chemical class 0.000 description 5
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 4
- 150000004056 anthraquinones Chemical class 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 230000001172 regenerating effect Effects 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- PVXVWWANJIWJOO-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-N-ethylpropan-2-amine Chemical compound CCNC(C)CC1=CC=C2OCOC2=C1 PVXVWWANJIWJOO-UHFFFAOYSA-N 0.000 description 1
- XXQGYGJZNMSSFD-UHFFFAOYSA-N 2-[2-(dimethylcarbamoyl)phenoxy]acetic acid Chemical compound CN(C)C(=O)C1=CC=CC=C1OCC(O)=O XXQGYGJZNMSSFD-UHFFFAOYSA-N 0.000 description 1
- 102100022443 CXADR-like membrane protein Human genes 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- QMMZSJPSPRTHGB-UHFFFAOYSA-N MDEA Natural products CC(C)CCCCC=CCC=CC(O)=O QMMZSJPSPRTHGB-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- SSQRVOQKVAXHJE-UHFFFAOYSA-N anthracene-9,10-dione;methanol;sulfurous acid Chemical compound OC.OS(O)=O.C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 SSQRVOQKVAXHJE-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- HFNQLYDPNAZRCH-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O.OC(O)=O HFNQLYDPNAZRCH-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000009993 causticizing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- UNHKSXOTUHOTAB-UHFFFAOYSA-N sodium;sulfane Chemical compound [Na].S UNHKSXOTUHOTAB-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/06—Treatment of pulp gases; Recovery of the heat content of the gases; Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds
- D21C11/08—Deodorisation ; Elimination of malodorous compounds, e.g. sulfur compounds such as hydrogen sulfide or mercaptans, from gas streams
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/0064—Aspects concerning the production and the treatment of green and white liquors, e.g. causticizing green liquor
- D21C11/0071—Treatment of green or white liquors with gases, e.g. with carbon dioxide for carbonation; Expulsion of gaseous compounds, e.g. hydrogen sulfide, from these liquors by this treatment (stripping); Optional separation of solid compounds formed in the liquors by this treatment
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/12—Combustion of pulp liquors
- D21C11/125—Decomposition of the pulp liquors in reducing atmosphere or in the absence of oxidants, i.e. gasification or pyrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/40—Production or processing of lime, e.g. limestone regeneration of lime in pulp and sugar mills
Landscapes
- Paper (AREA)
- Cookers (AREA)
- Compounds Of Unknown Constitution (AREA)
- Treating Waste Gases (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9303137A SE503455C2 (sv) | 1993-09-27 | 1993-09-27 | Beredning av sulfitinnehållande kokvätska och användning av kokvätskan för förimpregnering |
| DE69419024T DE69419024T2 (de) | 1993-09-27 | 1994-09-05 | Herstellung einer sulfit-enthaltenden kochlauge |
| PCT/SE1994/000816 WO1995009269A1 (en) | 1993-09-27 | 1994-09-05 | Preparation of cooking liquor containing sulphite |
| AT94928525T ATE181119T1 (de) | 1993-09-27 | 1994-09-05 | Herstellung einer sulfit-enthaltenden kochlauge |
| CA002171748A CA2171748C (en) | 1993-09-27 | 1994-09-05 | Preparation of cooking liquor containing sulphite |
| EP94928525A EP0721527B1 (de) | 1993-09-27 | 1994-09-05 | Herstellung einer sulfit-enthaltenden kochlauge |
| AU77927/94A AU7792794A (en) | 1993-09-27 | 1994-09-05 | Preparation of cooking liquor containing sulphite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9303137A SE503455C2 (sv) | 1993-09-27 | 1993-09-27 | Beredning av sulfitinnehållande kokvätska och användning av kokvätskan för förimpregnering |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE9303137D0 SE9303137D0 (sv) | 1993-09-27 |
| SE9303137L SE9303137L (sv) | 1995-03-28 |
| SE503455C2 true SE503455C2 (sv) | 1996-06-17 |
Family
ID=20391220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE9303137A SE503455C2 (sv) | 1993-09-27 | 1993-09-27 | Beredning av sulfitinnehållande kokvätska och användning av kokvätskan för förimpregnering |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0721527B1 (de) |
| AT (1) | ATE181119T1 (de) |
| AU (1) | AU7792794A (de) |
| CA (1) | CA2171748C (de) |
| DE (1) | DE69419024T2 (de) |
| SE (1) | SE503455C2 (de) |
| WO (1) | WO1995009269A1 (de) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE9703365D0 (sv) * | 1997-09-18 | 1997-09-18 | Kvaerner Pulping Tech | Method in connection with impregnation and digestion of lignocelulosic material |
| SE0103241D0 (sv) * | 2001-09-28 | 2001-09-28 | Skogsind Tekn Foskningsinst | Method for recovery of pulping chemicals in an alkaline sulphite pulping process and for production of steam |
| CN116064167B (zh) * | 2021-10-30 | 2025-05-02 | 中国石油化工股份有限公司 | 一种生物质制合成气的方法和系统 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3353906A (en) * | 1964-08-25 | 1967-11-21 | Lummus Co | Method of recovering chemicals from spent pulping liquors |
| FI63790C (fi) * | 1982-02-11 | 1983-08-10 | Ahlstroem Oy | Saett att reglera matningscirkulationens alkalitet vid foerhydrolysering av traeflis |
| SE500263C2 (sv) * | 1993-03-11 | 1994-05-24 | Chemrec Ab | Process för separation av svavelföreningar ur en koldioxid- och vätesulfidinnehållande gasström |
-
1993
- 1993-09-27 SE SE9303137A patent/SE503455C2/sv not_active IP Right Cessation
-
1994
- 1994-09-05 AU AU77927/94A patent/AU7792794A/en not_active Abandoned
- 1994-09-05 EP EP94928525A patent/EP0721527B1/de not_active Expired - Lifetime
- 1994-09-05 AT AT94928525T patent/ATE181119T1/de not_active IP Right Cessation
- 1994-09-05 CA CA002171748A patent/CA2171748C/en not_active Expired - Fee Related
- 1994-09-05 WO PCT/SE1994/000816 patent/WO1995009269A1/en not_active Ceased
- 1994-09-05 DE DE69419024T patent/DE69419024T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2171748C (en) | 2005-03-22 |
| AU7792794A (en) | 1995-04-18 |
| SE9303137L (sv) | 1995-03-28 |
| EP0721527A1 (de) | 1996-07-17 |
| WO1995009269A1 (en) | 1995-04-06 |
| DE69419024T2 (de) | 2000-02-03 |
| DE69419024D1 (de) | 1999-07-15 |
| EP0721527B1 (de) | 1999-06-09 |
| ATE181119T1 (de) | 1999-06-15 |
| CA2171748A1 (en) | 1995-04-06 |
| SE9303137D0 (sv) | 1993-09-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |