SE508111C2 - Förfarande för framställning av väteperoxid genom hydrering av en kinonlösning samt anordning för utövande av förfarandet - Google Patents
Förfarande för framställning av väteperoxid genom hydrering av en kinonlösning samt anordning för utövande av förfarandetInfo
- Publication number
- SE508111C2 SE508111C2 SE9604763A SE9604763A SE508111C2 SE 508111 C2 SE508111 C2 SE 508111C2 SE 9604763 A SE9604763 A SE 9604763A SE 9604763 A SE9604763 A SE 9604763A SE 508111 C2 SE508111 C2 SE 508111C2
- Authority
- SE
- Sweden
- Prior art keywords
- working solution
- solution
- catalyst
- grams
- hydrogen peroxide
- Prior art date
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 30
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 230000036571 hydration Effects 0.000 title description 3
- 238000006703 hydration reaction Methods 0.000 title description 3
- 239000012224 working solution Substances 0.000 claims abstract description 77
- 239000003054 catalyst Substances 0.000 claims abstract description 42
- 230000003647 oxidation Effects 0.000 claims abstract description 21
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 21
- 238000000605 extraction Methods 0.000 claims abstract description 18
- 239000000243 solution Substances 0.000 claims abstract description 18
- SNDGLCYYBKJSOT-UHFFFAOYSA-N 1,1,3,3-tetrabutylurea Chemical compound CCCCN(CCCC)C(=O)N(CCCC)CCCC SNDGLCYYBKJSOT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000000926 separation method Methods 0.000 claims abstract description 10
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 claims abstract description 9
- INPHIYULSHLAHR-UHFFFAOYSA-N 1-pentylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CCCCC INPHIYULSHLAHR-UHFFFAOYSA-N 0.000 claims abstract description 7
- HSKPJQYAHCKJQC-UHFFFAOYSA-N 1-ethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CC HSKPJQYAHCKJQC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000005984 hydrogenation reaction Methods 0.000 claims description 30
- 239000001257 hydrogen Substances 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 19
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000010802 sludge Substances 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000007872 degassing Methods 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 150000004040 pyrrolidinones Chemical class 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 7
- 239000006227 byproduct Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000008187 granular material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 description 1
- HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000012636 effector Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- QOSATHPSBFQAML-UHFFFAOYSA-N hydrogen peroxide;hydrate Chemical compound O.OO QOSATHPSBFQAML-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/006—Separating solid material from the gas/liquid stream by filtration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9604763A SE508111C2 (sv) | 1996-12-23 | 1996-12-23 | Förfarande för framställning av väteperoxid genom hydrering av en kinonlösning samt anordning för utövande av förfarandet |
| AT97949322T ATE215513T1 (de) | 1996-12-23 | 1997-12-16 | Verfahren zur herstellung von wasserstoffperoxid durch hydrierung einer chinonlösung und vorrichtung zur durchführung des verfahrens |
| AU78724/98A AU7872498A (en) | 1996-12-23 | 1997-12-16 | Method for the production of hydrogen peroxide by hydrating chinone solution an d arrangement for performing the methods |
| CA002275726A CA2275726A1 (en) | 1996-12-23 | 1997-12-16 | Method for the production of hydrogen peroxide by hydrating a chinone solution and arrangement for performing the methods |
| DE69711711T DE69711711D1 (de) | 1996-12-23 | 1997-12-16 | Verfahren zur herstellung von wasserstoffperoxid durch hydrierung einer chinonlösung und vorrichtung zur durchführung des verfahrens |
| EP97949322A EP0958238B1 (de) | 1996-12-23 | 1997-12-16 | Verfahren zur herstellung von wasserstoffperoxid durch hydrierung einer chinonlösung und vorrichtung zur durchführung des verfahrens |
| PCT/SE1997/002100 WO1998028225A1 (en) | 1996-12-23 | 1997-12-16 | Method for the production of hydrogen peroxide by hydrating a chinone solution and arrangement for performing the methods |
| NO993033A NO993033L (no) | 1996-12-23 | 1999-06-18 | Fremgangsmåte for fremstilling av hydrogenperoksid ved hydrogenering av en kinonlösning, og arrangement for utförelse derav |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9604763A SE508111C2 (sv) | 1996-12-23 | 1996-12-23 | Förfarande för framställning av väteperoxid genom hydrering av en kinonlösning samt anordning för utövande av förfarandet |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE9604763D0 SE9604763D0 (sv) | 1996-12-23 |
| SE9604763L SE9604763L (sv) | 1998-06-24 |
| SE508111C2 true SE508111C2 (sv) | 1998-08-31 |
Family
ID=20405118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE9604763A SE508111C2 (sv) | 1996-12-23 | 1996-12-23 | Förfarande för framställning av väteperoxid genom hydrering av en kinonlösning samt anordning för utövande av förfarandet |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0958238B1 (de) |
| AT (1) | ATE215513T1 (de) |
| AU (1) | AU7872498A (de) |
| CA (1) | CA2275726A1 (de) |
| DE (1) | DE69711711D1 (de) |
| NO (1) | NO993033L (de) |
| SE (1) | SE508111C2 (de) |
| WO (1) | WO1998028225A1 (de) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2250094T3 (es) * | 1999-11-22 | 2006-04-16 | Akzo Nobel N.V. | Procedimieto y composicion para la produccion de peroxido de hidrogeno. |
| AU2001236000A1 (en) * | 2000-03-01 | 2001-09-12 | Bayer A.G. | Process for producing hydrogenated unsaturated ring-containing hydrocarbon polymer |
| CN101837957B (zh) * | 2010-04-29 | 2011-09-28 | 扬州惠通化工技术有限公司 | 一种用于过氧化氢生产的氢化系统 |
| CN107032306B (zh) * | 2017-06-15 | 2023-07-14 | 扬州惠通科技股份有限公司 | 流化床生产过氧化氢的系统及方法 |
| CN107032305B (zh) * | 2017-06-15 | 2023-07-14 | 扬州惠通科技股份有限公司 | 一种过氧化氢的生产系统及生产方法 |
| JP7322363B2 (ja) * | 2018-07-11 | 2023-08-08 | 三菱瓦斯化学株式会社 | 過酸化水素水溶液の製造方法 |
| CN110436418A (zh) * | 2019-09-23 | 2019-11-12 | 扬州荣祥科技发展有限公司 | 一种蒽醌法生产双氧水的工艺 |
| CN111137863B (zh) * | 2019-12-31 | 2021-08-31 | 聊城鲁西双氧水新材料科技有限公司 | 一种氢化塔催化剂在线切换方法、系统及应用 |
| CN111137864B (zh) * | 2020-01-02 | 2024-04-05 | 黎明化工研究设计院有限责任公司 | 一种蒽醌法制备过氧化氢的氧化塔 |
| AU2022418834A1 (en) * | 2021-12-22 | 2024-05-09 | Solvay Sa | Novel process for the production of hydrogen peroxide |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2532819C3 (de) * | 1975-07-23 | 1978-10-05 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Verfahren zur Herstellung von Wasserstoffperoxid |
| SE459919C (sv) * | 1987-03-27 | 1991-03-25 | Eka Nobel Ab | Foerfarande foer framstaellning av vaeteperoxid genom reduktion och oxidation av en antrakinon |
| FI82671C (fi) * | 1989-09-18 | 1991-04-10 | Kemira Oy | Foerfarande foer framstaellning av vaeteperoxid och loesningsmedelssystem foer anvaendning i detta foerfarande. |
| WO1995004702A1 (en) * | 1993-08-11 | 1995-02-16 | Conoco Specialty Products Inc. | Peroxide treatment process |
| NO941388D0 (no) * | 1994-04-15 | 1994-04-15 | Kvaerner Process Systems As | Produksjon av kjemikalier som kan anvendes i celluloseindustrien |
-
1996
- 1996-12-23 SE SE9604763A patent/SE508111C2/sv not_active IP Right Cessation
-
1997
- 1997-12-16 CA CA002275726A patent/CA2275726A1/en not_active Abandoned
- 1997-12-16 AT AT97949322T patent/ATE215513T1/de not_active IP Right Cessation
- 1997-12-16 DE DE69711711T patent/DE69711711D1/de not_active Expired - Lifetime
- 1997-12-16 EP EP97949322A patent/EP0958238B1/de not_active Revoked
- 1997-12-16 AU AU78724/98A patent/AU7872498A/en not_active Abandoned
- 1997-12-16 WO PCT/SE1997/002100 patent/WO1998028225A1/en not_active Ceased
-
1999
- 1999-06-18 NO NO993033A patent/NO993033L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2275726A1 (en) | 1998-07-02 |
| AU7872498A (en) | 1998-07-17 |
| ATE215513T1 (de) | 2002-04-15 |
| NO993033L (no) | 1999-08-23 |
| SE9604763L (sv) | 1998-06-24 |
| EP0958238A1 (de) | 1999-11-24 |
| DE69711711D1 (de) | 2002-05-08 |
| WO1998028225A1 (en) | 1998-07-02 |
| SE9604763D0 (sv) | 1996-12-23 |
| EP0958238B1 (de) | 2002-04-03 |
| NO993033D0 (no) | 1999-06-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
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