SE509728C2 - Immobiliserade grenade polyalkyleniminer, sätt för framställning därav och deras användning som komplexbildare - Google Patents

Immobiliserade grenade polyalkyleniminer, sätt för framställning därav och deras användning som komplexbildare

Info

Publication number: SE509728C2
Authority: SE; Sweden
Prior art keywords: branched; group; polyalkyleneimine; ligand; carrier
Prior art date: 1994-06-21

Application number

SE9604808A

Other languages

English (en)

Swedish (sv)

Other versions

SE9604808L (sv

SE9604808D0 (sv

Inventor

Leonard Francis Lindoy

Peter Lewis Eaglen

Robert Louis Alldredge

Original Assignee

Metre International Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-06-21

Filing date

1996-12-20

Publication date

1999-03-01

1996-12-20 Application filed by Metre International Inc filed Critical Metre International Inc

1996-12-20 Publication of SE9604808L publication Critical patent/SE9604808L/

1996-12-20 Publication of SE9604808D0 publication Critical patent/SE9604808D0/xx

1999-03-01 Publication of SE509728C2 publication Critical patent/SE509728C2/sv

Links

238000000034 method Methods 0.000 title claims description 18
238000002360 preparation method Methods 0.000 title description 4
239000008139 complexing agent Substances 0.000 title description 2
150000002466 imines Chemical class 0.000 title 1
229920001281 polyalkylene Polymers 0.000 title 1
239000003446 ligand Substances 0.000 claims abstract description 29
239000007790 solid phase Substances 0.000 claims abstract description 9
229920002873 Polyethylenimine Polymers 0.000 claims description 40
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 33
229910021645 metal ion Inorganic materials 0.000 claims description 26
239000000741 silica gel Substances 0.000 claims description 22
229910002027 silica gel Inorganic materials 0.000 claims description 22
239000002245 particle Substances 0.000 claims description 21
125000005647 linker group Chemical group 0.000 claims description 16
150000001412 amines Chemical class 0.000 claims description 12
150000003973 alkyl amines Chemical class 0.000 claims description 10
229910052736 halogen Inorganic materials 0.000 claims description 6
150000002367 halogens Chemical class 0.000 claims description 6
OXYZDRAJMHGSMW-UHFFFAOYSA-N 3-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCl OXYZDRAJMHGSMW-UHFFFAOYSA-N 0.000 claims description 3
229910052739 hydrogen Inorganic materials 0.000 claims description 3
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
239000011521 glass Substances 0.000 claims description 2
229920000333 poly(propyleneimine) Polymers 0.000 claims description 2
239000004576 sand Substances 0.000 claims description 2
GFDFZTFQPIBNSQ-UHFFFAOYSA-N (+)-homo-18-epiormosanine Natural products C1C(C23)CCCN3CN3CCCCC3C32CN2CCCCC2C1C3 GFDFZTFQPIBNSQ-UHFFFAOYSA-N 0.000 claims 1
GFDFZTFQPIBNSQ-LDIYZUBKSA-N Homoormosanine Natural products N12[C@H]3[C@H](C[C@H]4[C@@H]5N(C[C@@]3([C@@H]3N(C1)CCCC3)C4)CCCC5)CCC2 GFDFZTFQPIBNSQ-LDIYZUBKSA-N 0.000 claims 1
GFDFZTFQPIBNSQ-WSBLSWJJSA-N jamine Chemical compound C([C@H]([C@H]12)C3)CCN2CN2CCCC[C@@H]2[C@]21CN1CCCC[C@@H]1[C@H]3C2 GFDFZTFQPIBNSQ-WSBLSWJJSA-N 0.000 claims 1
238000004519 manufacturing process Methods 0.000 claims 1
229910052751 metal Inorganic materials 0.000 abstract description 3
239000002184 metal Substances 0.000 abstract description 3
150000001768 cations Chemical class 0.000 abstract 1
239000000243 solution Substances 0.000 description 23
150000002500 ions Chemical class 0.000 description 20
239000000047 product Substances 0.000 description 19
239000000463 material Substances 0.000 description 10
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
229910001385 heavy metal Inorganic materials 0.000 description 7
235000012239 silicon dioxide Nutrition 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
230000015556 catabolic process Effects 0.000 description 6
230000000536 complexating effect Effects 0.000 description 6
239000010949 copper Substances 0.000 description 6
238000006731 degradation reaction Methods 0.000 description 6
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 5
239000011133 lead Substances 0.000 description 5
239000007788 liquid Substances 0.000 description 5
239000000203 mixture Substances 0.000 description 5
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
229910052802 copper Inorganic materials 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
229910000077 silane Inorganic materials 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
239000011701 zinc Substances 0.000 description 4
229910052725 zinc Inorganic materials 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
102000004190 Enzymes Human genes 0.000 description 3
108090000790 Enzymes Proteins 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
239000011324 bead Substances 0.000 description 3
229910052793 cadmium Inorganic materials 0.000 description 3
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
239000011575 calcium Substances 0.000 description 3
239000000969 carrier Substances 0.000 description 3
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 3
231100000053 low toxicity Toxicity 0.000 description 3
229910052749 magnesium Inorganic materials 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
229910017464 nitrogen compound Inorganic materials 0.000 description 3
150000002830 nitrogen compounds Chemical class 0.000 description 3
-1 polyethylene Polymers 0.000 description 3
239000011591 potassium Substances 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
150000003141 primary amines Chemical class 0.000 description 3
108090000623 proteins and genes Proteins 0.000 description 3
239000013535 sea water Substances 0.000 description 3
239000011734 sodium Substances 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
238000001042 affinity chromatography Methods 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
239000011651 chromium Substances 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
239000000470 constituent Substances 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
229910003480 inorganic solid Inorganic materials 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
238000011068 loading method Methods 0.000 description 2
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
101150009274 nhr-1 gene Proteins 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
238000000918 plasma mass spectrometry Methods 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
102000004169 proteins and genes Human genes 0.000 description 2
229910052705 radium Inorganic materials 0.000 description 2
HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 2
239000012492 regenerant Substances 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
238000011069 regeneration method Methods 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
238000010189 synthetic method Methods 0.000 description 2
150000003512 tertiary amines Chemical group 0.000 description 2
229910052718 tin Inorganic materials 0.000 description 2
239000011135 tin Substances 0.000 description 2
238000003828 vacuum filtration Methods 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004113 Sepiolite Substances 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000004075 alteration Effects 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000003321 atomic absorption spectrophotometry Methods 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
239000012504 chromatography matrix Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
230000009918 complex formation Effects 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000011243 crosslinked material Substances 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
238000013461 design Methods 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
239000000499 gel Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
150000002483 hydrogen compounds Chemical class 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910001960 metal nitrate Inorganic materials 0.000 description 1
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
238000005457 optimization Methods 0.000 description 1
230000008447 perception Effects 0.000 description 1
239000012071 phase Substances 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
238000004321 preservation Methods 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
150000003335 secondary amines Chemical group 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052624 sepiolite Inorganic materials 0.000 description 1
235000019355 sepiolite Nutrition 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
239000002904 solvent Substances 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000006188 syrup Substances 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
238000012360 testing method Methods 0.000 description 1
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
238000011179 visual inspection Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

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- B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
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- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
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- B01J20/26—Synthetic macromolecular compounds
- B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
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- B01J20/3219—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond involving a particular spacer or linking group, e.g. for attaching an active group
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3268—Macromolecular compounds
- B01J20/3272—Polymers obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
- B01J2220/58—Use in a single column

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Analytical Chemistry (AREA)
Inorganic Chemistry (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Treatment Of Liquids With Adsorbents In General (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

SE9604808A 1994-06-21 1996-12-20 Immobiliserade grenade polyalkyleniminer, sätt för framställning därav och deras användning som komplexbildare SE509728C2 (sv)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
AUPM6328A AUPM632894A0 (en)	1994-06-21	1994-06-21	Immobilised branched polyalkyleneimines
PCT/AU1995/000362 WO1995035165A1 (fr)	1994-06-21	1995-06-21	Polyalkylene imines ramifiees et immobilisees

Publications (3)

Publication Number	Publication Date
SE9604808L SE9604808L (sv)	1996-12-20
SE9604808D0 SE9604808D0 (sv)	1996-12-20
SE509728C2 true SE509728C2 (sv)	1999-03-01

Family

ID=3780897

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE9604808A SE509728C2 (sv)	1994-06-21	1996-12-20	Immobiliserade grenade polyalkyleniminer, sätt för framställning därav och deras användning som komplexbildare

Country Status (7)

Country	Link
US (1)	US5914044A (fr)
JP (1)	JP3704624B2 (fr)
AU (2)	AUPM632894A0 (fr)
CA (1)	CA2193241C (fr)
DE (1)	DE19581676B4 (fr)
SE (1)	SE509728C2 (fr)
WO (1)	WO1995035165A1 (fr)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6077421A (en) *	1996-07-18	2000-06-20	The United States Of America As Represented By The Secretary Of The Navy	Metal complexing
US20030195109A1 (en) *	1996-10-31	2003-10-16	Jose Sancho Royo	Catalytic systems for the polimerisation and copolimerisation of alpha-olefins
DE19821665A1 (de) *	1997-05-28	1998-12-03	Basf Ag	Compositpigmente auf Basis von polyalkylenpolyaminmodifizierten nanopartikulären Metalloxiden und anionischen Farbstoffen
DE69914012T2 (de)	1998-04-27	2004-12-09	Repsol Quimica S.A.	Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
DE69916358T2 (de) *	1998-04-29	2005-04-21	Repsol Quimica Sa	Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation
US6339039B1 (en)	1998-06-12	2002-01-15	Jerker Porath	Hydrogel product for adsorption purposes
SE512234C2 (sv) *	1998-06-12	2000-02-14	Jerker Porath	Hydrogelprodukt för adsorptionsändamål bestående av en vattenolöslig stödmatris som är tvärbunden med polymerer
AUPR393601A0 (en) *	2001-03-23	2001-04-26	Oretek Limited	Metal ion extraction materials and processes using same
AUPR791601A0 (en) *	2001-09-26	2001-10-18	Oretek Limited	Metal ion recovery
RU2270056C2 (ru) *	2004-01-15	2006-02-20	Владимир Михайлович Полосин	Комплексообразующий сорбент, способ его получения и использования
RU2282906C2 (ru) *	2004-01-15	2006-08-27	Владимир Михайлович Полосин	Способ очистки радиоактивных водных растворов
US7964380B2 (en) *	2005-01-21	2011-06-21	Argylia Technologies	Nanoparticles for manipulation of biopolymers and methods of thereof
JP5248904B2 (ja) *	2008-04-18	2013-07-31	Ｈｏｙａ株式会社	被覆粒子、被覆粒子の製造方法および吸着装置
US20110186522A1 (en) *	2009-12-18	2011-08-04	University Of South Florida	Removal of nuisance anion and anionic materials using polyalkyleneimines such as polyethyleneimine
CN102068967B (zh) *	2010-12-14	2012-12-19	浙江大学	一种负载化聚丙烯亚胺材料及其制备方法和用途
EP2811983B1 (fr)	2012-09-17	2019-05-01	W.R. Grace & CO. - CONN.	Matière de support particulaire fonctionnalisée et procédés de sa réalisation et de son utilisation
EP2812091B1 (fr)	2012-09-17	2021-03-10	W.R. Grace & CO. - CONN.	Milieu de chromatographie et dispositifs associés
ES2887110T3 (es)	2014-01-16	2021-12-21	Grace W R & Co	Medios para cromatografía de afinidad y dispositivos para cromatografía
PL3137209T3 (pl)	2014-05-02	2023-01-02	W.R. Grace & Co. - Conn.	Funkcjonalizowany materiał nośnikowy i sposoby wytwarzania oraz stosowania funkcjonalizowanego materiału nośnikowego
KR102566292B1 (ko)	2015-06-05	2023-08-10	더블유.알. 그레이스 앤드 캄파니-콘.	흡착성 바이오프로세싱 정화제와 이의 제조 및 사용 방법
RU2618295C2 (ru) *	2015-09-09	2017-05-03	Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС"	Способ получения сорбента из хлорида аммония
US10596488B1 (en) *	2018-01-17	2020-03-24	University Of South Florida	Lithium ion extraction methods
KR20250013145A (ko)	2022-02-16	2025-01-31	퓨라피니티 엘티디	물에서 오염원을 제거하기 위한 작용화된 알루미나 흡착제 재료
GB202202072D0 (en) *	2022-02-16	2022-03-30	Puraffinity Ltd	Functionalised alumina adsorbent materials for removal of contaminants from water

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4071546A (en) *	1976-08-30	1978-01-31	Dow Corning Corporation	Silicon-containing chelating composition and method therefor
US5066395A (en) *	1986-03-06	1991-11-19	J. T. Baker Inc.	N-acylated derivatives of polyethyleneimine bonded phase silica products
IL86766A (en) *	1987-09-04	1992-02-16	Bradshaw Jerald S	Macrocyclic ligands bonded to sand or silica gel and their use in selectively and quantitatively removing and concentrating ions present at low concentrations from mixtures thereof with other ions
GB8913183D0 (en) *	1989-06-08	1989-07-26	Central Blood Lab Authority	Chemical products
US5078978A (en) *	1989-11-06	1992-01-07	Brigham Young University	Pyridine-containing alkoxysilanes bonded to inorganic supports and processes of using the same for removing and concentrating desired ions from solutions
AU646889B2 (en) *	1990-10-10	1994-03-10	Brigham Young University	Polytetraalkylammonium and polytrialkylamine containing ligands bonded to inorganic supports and processes of using the same for removing and concentrating desired ions from solution
US5244856A (en) *	1990-10-10	1993-09-14	Brigham Young University	Polytetraalkylammonium and polytrialkylamine-containing ligands bonded to inorganic supports and processes of using the same for removing and concentrating desired ions from solutions
US5334316A (en) *	1990-10-10	1994-08-02	Brigham Young University	Process of using polytetraalkylammonium and polytrialkylamine-containing ligands bonded to inorganic supports for removing and concentrating desired ions from solutions
US5120443A (en) *	1991-06-03	1992-06-09	Brigham Young University	Processes for removing, separating and concentrating rhodium, iridium, and ruthenium from solutions using macrocyclic and nonmacrocyclic polyalkylene-polyamine-containing ligands bonded to inorganic supports
US5190660A (en) *	1992-06-04	1993-03-02	Lindoy Leonard F	Ion complexation by silica-immobilized polyethyleneimines

1994
- 1994-06-21 AU AUPM6328A patent/AUPM632894A0/en not_active Abandoned
1995
- 1995-06-21 AU AU27075/95A patent/AU692266B2/en not_active Ceased
- 1995-06-21 CA CA002193241A patent/CA2193241C/fr not_active Expired - Fee Related
- 1995-06-21 JP JP50140296A patent/JP3704624B2/ja not_active Expired - Fee Related
- 1995-06-21 WO PCT/AU1995/000362 patent/WO1995035165A1/fr not_active Ceased
- 1995-06-21 US US08/765,485 patent/US5914044A/en not_active Expired - Lifetime
- 1995-06-21 DE DE19581676T patent/DE19581676B4/de not_active Expired - Fee Related
1996
- 1996-12-20 SE SE9604808A patent/SE509728C2/sv not_active IP Right Cessation

Also Published As

Publication number	Publication date
JP3704624B2 (ja)	2005-10-12
CA2193241A1 (fr)	1995-12-28
WO1995035165A1 (fr)	1995-12-28
DE19581676B4 (de)	2005-09-01
AU2707595A (en)	1996-01-15
US5914044A (en)	1999-06-22
SE9604808L (sv)	1996-12-20
JPH10501827A (ja)	1998-02-17
AUPM632894A0 (en)	1994-07-14
CA2193241C (fr)	2005-09-27
AU692266B2 (en)	1998-06-04
DE19581676T1 (de)	1997-06-19
SE9604808D0 (sv)	1996-12-20

Legal Events

Date	Code	Title	Description
2013-01-29	NUG	Patent has lapsed

Publication	Publication Date	Title
SE509728C2 (sv)	1999-03-01	Immobiliserade grenade polyalkyleniminer, sätt för framställning därav och deras användning som komplexbildare
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