SE510775C2 - Svavelfri kokning av kemisk massa - Google Patents
Svavelfri kokning av kemisk massaInfo
- Publication number
- SE510775C2 SE510775C2 SE9603518A SE9603518A SE510775C2 SE 510775 C2 SE510775 C2 SE 510775C2 SE 9603518 A SE9603518 A SE 9603518A SE 9603518 A SE9603518 A SE 9603518A SE 510775 C2 SE510775 C2 SE 510775C2
- Authority
- SE
- Sweden
- Prior art keywords
- cooking
- delignification
- pulp
- bleaching
- boiling
- Prior art date
Links
- 238000010411 cooking Methods 0.000 title claims abstract description 107
- 229920001131 Pulp (paper) Polymers 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 79
- 238000004061 bleaching Methods 0.000 claims abstract description 60
- 239000007788 liquid Substances 0.000 claims abstract description 48
- 230000008569 process Effects 0.000 claims abstract description 40
- 238000005470 impregnation Methods 0.000 claims abstract description 35
- 150000001875 compounds Chemical class 0.000 claims abstract description 34
- 150000002500 ions Chemical class 0.000 claims abstract description 16
- 239000013543 active substance Substances 0.000 claims abstract description 4
- 238000009835 boiling Methods 0.000 claims description 45
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 239000002023 wood Substances 0.000 claims description 21
- 239000001301 oxygen Substances 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 10
- 239000011122 softwood Substances 0.000 claims description 10
- 150000004056 anthraquinones Chemical class 0.000 claims description 8
- 239000008139 complexing agent Substances 0.000 claims description 8
- 238000006073 displacement reaction Methods 0.000 claims description 4
- 239000011121 hardwood Substances 0.000 claims description 4
- XNGBCVRGPNWAGY-UHFFFAOYSA-N 1,4-dihydroanthracene-9,10-diol Chemical compound C1=CC=C2C(O)=C(CC=CC3)C3=C(O)C2=C1 XNGBCVRGPNWAGY-UHFFFAOYSA-N 0.000 claims description 3
- 150000004696 coordination complex Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 claims description 2
- 229930192627 Naphthoquinone Natural products 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 239000002657 fibrous material Substances 0.000 claims description 2
- 150000002791 naphthoquinones Chemical class 0.000 claims description 2
- 150000004053 quinones Chemical class 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 150000004054 benzoquinones Chemical class 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 14
- 238000004519 manufacturing process Methods 0.000 abstract description 13
- 239000000463 material Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 239000005864 Sulphur Substances 0.000 abstract 2
- 229920002678 cellulose Polymers 0.000 abstract 2
- 239000001913 cellulose Substances 0.000 abstract 2
- 238000002474 experimental method Methods 0.000 description 30
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 19
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 18
- 239000000460 chlorine Substances 0.000 description 15
- 229910021653 sulphate ion Inorganic materials 0.000 description 15
- 229910052717 sulfur Inorganic materials 0.000 description 12
- 239000011593 sulfur Substances 0.000 description 12
- -1 soda ash anthraquinone Chemical class 0.000 description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 6
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 6
- 150000002978 peroxides Chemical class 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 102100030386 Granzyme A Human genes 0.000 description 3
- 101001009599 Homo sapiens Granzyme A Proteins 0.000 description 3
- 208000036343 KIF1A related neurological disease Diseases 0.000 description 3
- 150000001720 carbohydrates Chemical class 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 235000019645 odor Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 1
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241001148717 Lygeum spartum Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 244000081757 Phalaris arundinacea Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/22—Other features of pulping processes
- D21C3/222—Use of compounds accelerating the pulping processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9603518A SE510775C2 (sv) | 1996-09-26 | 1996-09-26 | Svavelfri kokning av kemisk massa |
| EP97943269A EP0928349B1 (de) | 1996-09-26 | 1997-09-25 | Schwefelfreies verfahren zur herstellung eines chemischen zellstoffs |
| AT97943269T ATE241033T1 (de) | 1996-09-26 | 1997-09-25 | Schwefelfreies verfahren zur herstellung eines chemischen zellstoffs |
| DE69722226T DE69722226D1 (de) | 1996-09-26 | 1997-09-25 | Schwefelfreies verfahren zur herstellung eines chemischen zellstoffs |
| PCT/SE1997/001610 WO1998013547A1 (en) | 1996-09-26 | 1997-09-25 | Cooking of chemical pulp in sulphur-free liquor containing a delignification-accelerating compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9603518A SE510775C2 (sv) | 1996-09-26 | 1996-09-26 | Svavelfri kokning av kemisk massa |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE9603518D0 SE9603518D0 (sv) | 1996-09-26 |
| SE9603518L SE9603518L (sv) | 1998-03-27 |
| SE510775C2 true SE510775C2 (sv) | 1999-06-21 |
Family
ID=20404039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE9603518A SE510775C2 (sv) | 1996-09-26 | 1996-09-26 | Svavelfri kokning av kemisk massa |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0928349B1 (de) |
| AT (1) | ATE241033T1 (de) |
| DE (1) | DE69722226D1 (de) |
| SE (1) | SE510775C2 (de) |
| WO (1) | WO1998013547A1 (de) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6241851B1 (en) | 1998-03-03 | 2001-06-05 | Andritz-Ahlstrom Inc. | Treatment of cellulose material with additives while producing cellulose pulp |
| CA2318027C (en) | 1999-09-13 | 2008-07-08 | Andritz-Ahlstrom Inc. | Treating pulp with yield or strength-enhancing additive |
| CN105200838A (zh) * | 2015-09-18 | 2015-12-30 | 新疆国力源投资有限公司 | 一种制备竹柳漂白浆的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4181565A (en) * | 1976-12-10 | 1980-01-01 | Honshu Seishi Kabushiki Kaisha | Process for cooking lignocellulosic material in the presence of hydroxyanthracenes and derivatives thereof |
| AU516988B2 (en) * | 1977-05-02 | 1981-07-02 | Australian Paper Manufacturers Limited | Alkaline pulping process |
| CA1132763A (en) * | 1978-10-25 | 1982-10-05 | Harry H. Holton | Use of cyclic keto compounds as additives in vapor phase pulping process |
| SE502667C2 (sv) * | 1993-07-12 | 1995-12-04 | Kvaerner Pulping Tech | Behandling av fibermaterial med komplexbildare före kokning |
-
1996
- 1996-09-26 SE SE9603518A patent/SE510775C2/sv not_active IP Right Cessation
-
1997
- 1997-09-25 AT AT97943269T patent/ATE241033T1/de not_active IP Right Cessation
- 1997-09-25 EP EP97943269A patent/EP0928349B1/de not_active Expired - Lifetime
- 1997-09-25 WO PCT/SE1997/001610 patent/WO1998013547A1/en not_active Ceased
- 1997-09-25 DE DE69722226T patent/DE69722226D1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0928349B1 (de) | 2003-05-21 |
| DE69722226D1 (de) | 2003-06-26 |
| ATE241033T1 (de) | 2003-06-15 |
| EP0928349A1 (de) | 1999-07-14 |
| SE9603518D0 (sv) | 1996-09-26 |
| WO1998013547A1 (en) | 1998-04-02 |
| SE9603518L (sv) | 1998-03-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |