SE524960C2 - Polymerisationsförfarande vid förhöjt tryck i närvaro av dendritisk polymer - Google Patents

Polymerisationsförfarande vid förhöjt tryck i närvaro av dendritisk polymer

Info

Publication number: SE524960C2
Authority: SE; Sweden
Prior art keywords: process according; polymerization process; pressure polymerization; vinyl; pph
Prior art date: 2003-02-12

Application number

SE0300373A

Other languages

English (en)

Swedish (sv)

Other versions

SE0300373L (sv

SE0300373D0 (sv

Inventor

Ola J Karlsson

Jan-Erik Joensson

Original Assignee

Celanese Emulsions Norden Ab

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-02-12

Filing date

2003-02-12

Publication date

2004-11-02

2003-02-12 Application filed by Celanese Emulsions Norden Ab filed Critical Celanese Emulsions Norden Ab

2003-02-12 Priority to SE0300373A priority Critical patent/SE524960C2/sv

2003-02-12 Publication of SE0300373D0 publication Critical patent/SE0300373D0/xx

2004-02-03 Priority to US10/542,442 priority patent/US20060106172A1/en

2004-02-03 Priority to DE602004008888T priority patent/DE602004008888T2/de

2004-02-03 Priority to AT04707703T priority patent/ATE373019T1/de

2004-02-03 Priority to CNA2004800041398A priority patent/CN1751068A/zh

2004-02-03 Priority to PCT/SE2004/000142 priority patent/WO2004072125A1/en

2004-02-03 Priority to EP04707703A priority patent/EP1601700B1/de

2004-02-11 Priority to TW093103161A priority patent/TWI278457B/zh

2004-08-13 Publication of SE0300373L publication Critical patent/SE0300373L/xx

2004-11-02 Publication of SE524960C2 publication Critical patent/SE524960C2/sv

Links

238000006116 polymerization reaction Methods 0.000 title claims abstract description 62
239000000412 dendrimer Substances 0.000 title claims abstract description 21
229920000736 dendritic polymer Polymers 0.000 title claims abstract description 21
239000000178 monomer Substances 0.000 claims abstract description 90
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 56
239000005977 Ethylene Substances 0.000 claims abstract description 56
229920001577 copolymer Polymers 0.000 claims abstract description 27
229920001567 vinyl ester resin Polymers 0.000 claims abstract description 19
229920000728 polyester Polymers 0.000 claims abstract description 10
229920000570 polyether Polymers 0.000 claims abstract description 7
239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 6
229920002614 Polyether block amide Polymers 0.000 claims abstract description 4
229920006149 polyester-amide block copolymer Polymers 0.000 claims abstract description 4
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 30
238000004132 cross linking Methods 0.000 claims description 28
230000000087 stabilizing effect Effects 0.000 claims description 19
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
239000004970 Chain extender Substances 0.000 claims description 6
CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 claims description 6
150000002148 esters Chemical class 0.000 claims description 5
150000007524 organic acids Chemical class 0.000 claims description 5
XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 claims description 4
-1 2-ethyl Chemical group 0.000 claims description 4
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
150000008064 anhydrides Chemical class 0.000 claims description 4
239000000839 emulsion Substances 0.000 claims description 4
238000000034 method Methods 0.000 claims description 4
KCTMTGOHHMRJHZ-UHFFFAOYSA-N n-(2-methylpropoxymethyl)prop-2-enamide Chemical compound CC(C)COCNC(=O)C=C KCTMTGOHHMRJHZ-UHFFFAOYSA-N 0.000 claims description 4
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 4
229920002554 vinyl polymer Polymers 0.000 claims description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
125000003545 alkoxy group Chemical group 0.000 claims description 3
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
238000007720 emulsion polymerization reaction Methods 0.000 claims description 3
HSOOIVBINKDISP-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CCC)OC(=O)C(C)=C HSOOIVBINKDISP-UHFFFAOYSA-N 0.000 claims description 2
VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 claims description 2
GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims description 2
DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 2
JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical group C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims description 2
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
CQHKDHVZYZUZMJ-UHFFFAOYSA-N [2,2-bis(hydroxymethyl)-3-prop-2-enoyloxypropyl] prop-2-enoate Chemical class C=CC(=O)OCC(CO)(CO)COC(=O)C=C CQHKDHVZYZUZMJ-UHFFFAOYSA-N 0.000 claims description 2
150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 2
125000002947 alkylene group Chemical group 0.000 claims description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 2
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
IGBZOHMCHDADGY-UHFFFAOYSA-N ethenyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OC=C IGBZOHMCHDADGY-UHFFFAOYSA-N 0.000 claims description 2
WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 claims description 2
GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 claims description 2
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 claims description 2
NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical group CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 2
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
150000004820 halides Chemical class 0.000 claims description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 claims description 2
125000005395 methacrylic acid group Chemical group 0.000 claims description 2
UTSYWKJYFPPRAP-UHFFFAOYSA-N n-(butoxymethyl)prop-2-enamide Chemical compound CCCCOCNC(=O)C=C UTSYWKJYFPPRAP-UHFFFAOYSA-N 0.000 claims description 2
DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 claims description 2
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims description 2
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 2
229920006395 saturated elastomer Polymers 0.000 claims description 2
150000005846 sugar alcohols Polymers 0.000 claims description 2
238000010557 suspension polymerization reaction Methods 0.000 claims description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims 2
239000004575 stone Substances 0.000 claims 2
CHPNMYQJQQGAJS-UHFFFAOYSA-N 3-tri(propan-2-yloxy)silylpropyl 2-methylprop-2-enoate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)CCCOC(=O)C(C)=C CHPNMYQJQQGAJS-UHFFFAOYSA-N 0.000 claims 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
125000000217 alkyl group Chemical group 0.000 claims 1
NLVXSWCKKBEXTG-UHFFFAOYSA-M ethenesulfonate Chemical group [O-]S(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-M 0.000 claims 1
LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 claims 1
OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 1
150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims 1
AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 claims 1
FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 claims 1
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 26
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
239000006185 dispersion Substances 0.000 description 12
239000000126 substance Substances 0.000 description 10
229910001870 ammonium persulfate Inorganic materials 0.000 description 9
238000004519 manufacturing process Methods 0.000 description 9
230000035484 reaction time Effects 0.000 description 9
239000004160 Ammonium persulphate Substances 0.000 description 8
235000019395 ammonium persulphate Nutrition 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 7
229940001584 sodium metabisulfite Drugs 0.000 description 7
235000010262 sodium metabisulphite Nutrition 0.000 description 7
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 6
239000000203 mixture Substances 0.000 description 6
239000002736 nonionic surfactant Substances 0.000 description 6
239000001632 sodium acetate Substances 0.000 description 6
235000017281 sodium acetate Nutrition 0.000 description 6
229920000642 polymer Polymers 0.000 description 5
239000003381 stabilizer Substances 0.000 description 5
YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
239000004372 Polyvinyl alcohol Substances 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
239000013530 defoamer Substances 0.000 description 4
229920000166 polytrimethylene carbonate Polymers 0.000 description 4
229920002451 polyvinyl alcohol Polymers 0.000 description 4
238000007334 copolymerization reaction Methods 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical class OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
239000004831 Hot glue Substances 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
150000001252 acrylic acid derivatives Chemical class 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
150000001414 amino alcohols Chemical class 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
238000000576 coating method Methods 0.000 description 2
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
150000002118 epoxides Chemical class 0.000 description 2
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
125000002768 hydroxyalkyl group Chemical group 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
150000002921 oxetanes Chemical class 0.000 description 2
150000004756 silanes Chemical class 0.000 description 2
ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
CPWXVNZFDXZIMS-UHFFFAOYSA-N 1-hydroxypropyl prop-2-enoate Chemical class CCC(O)OC(=O)C=C CPWXVNZFDXZIMS-UHFFFAOYSA-N 0.000 description 1
CXYBOJHPEWPLKC-UHFFFAOYSA-N 1-methoxysilyl-2-methylprop-2-en-1-one Chemical compound CO[SiH2]C(=O)C(C)=C CXYBOJHPEWPLKC-UHFFFAOYSA-N 0.000 description 1
KAMTZKXSJRGXHX-UHFFFAOYSA-N 2,2-di(propan-2-yloxy)ethenyl-propylsilane Chemical compound C(CC)[SiH2]C=C(OC(C)C)OC(C)C KAMTZKXSJRGXHX-UHFFFAOYSA-N 0.000 description 1
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical class OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
101100298295 Drosophila melanogaster flfl gene Proteins 0.000 description 1
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
101100244625 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) pph-1 gene Proteins 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
235000010323 ascorbic acid Nutrition 0.000 description 1
239000011668 ascorbic acid Chemical class 0.000 description 1
229960005070 ascorbic acid Drugs 0.000 description 1
230000001588 bifunctional effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
229920006037 cross link polymer Polymers 0.000 description 1
125000004386 diacrylate group Chemical group 0.000 description 1
238000003618 dip coating Methods 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
235000003891 ferrous sulphate Nutrition 0.000 description 1
239000011790 ferrous sulphate Substances 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
125000005113 hydroxyalkoxy group Chemical group 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000011090 industrial biotechnology method and process Methods 0.000 description 1
239000003999 initiator Substances 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
238000010409 ironing Methods 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Chemical class 0.000 description 1
230000002794 monomerizing effect Effects 0.000 description 1
239000004745 nonwoven fabric Substances 0.000 description 1
239000003973 paint Substances 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000004848 polyfunctional curative Substances 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
238000007761 roller coating Methods 0.000 description 1
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical class [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
239000005060 rubber Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000004753 textile Substances 0.000 description 1
NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical class OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
239000001993 wax Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/005—Dendritic macromolecules
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Graft Or Block Polymers (AREA)
Polymerisation Methods In General (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Polyesters Or Polycarbonates (AREA)
Glass Compositions (AREA)
Steering Control In Accordance With Driving Conditions (AREA)

SE0300373A 2003-02-12 2003-02-12 Polymerisationsförfarande vid förhöjt tryck i närvaro av dendritisk polymer SE524960C2 (sv)

Priority Applications (8)

Application Number	Priority Date	Filing Date	Title
SE0300373A SE524960C2 (sv)	2003-02-12	2003-02-12	Polymerisationsförfarande vid förhöjt tryck i närvaro av dendritisk polymer
US10/542,442 US20060106172A1 (en)	2003-02-12	2004-02-03	Pressure polymerisation process
DE602004008888T DE602004008888T2 (de)	2003-02-12	2004-02-03	Druckpolymerisationsverfahren
AT04707703T ATE373019T1 (de)	2003-02-12	2004-02-03	Druckpolymerisationsverfahren
CNA2004800041398A CN1751068A (zh)	2003-02-12	2004-02-03	压力聚合方法
PCT/SE2004/000142 WO2004072125A1 (en)	2003-02-12	2004-02-03	Pressure polymerisation process
EP04707703A EP1601700B1 (de)	2003-02-12	2004-02-03	Druckpolymerisationsverfahren
TW093103161A TWI278457B (en)	2003-02-12	2004-02-11	Pressure polymerisation process

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
SE0300373A SE524960C2 (sv)	2003-02-12	2003-02-12	Polymerisationsförfarande vid förhöjt tryck i närvaro av dendritisk polymer

Publications (3)

Publication Number	Publication Date
SE0300373D0 SE0300373D0 (sv)	2003-02-12
SE0300373L SE0300373L (sv)	2004-08-13
SE524960C2 true SE524960C2 (sv)	2004-11-02

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SE0300373A SE524960C2 (sv)	2003-02-12	2003-02-12	Polymerisationsförfarande vid förhöjt tryck i närvaro av dendritisk polymer

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Country	Link
US (1)	US20060106172A1 (de)
EP (1)	EP1601700B1 (de)
CN (1)	CN1751068A (de)
AT (1)	ATE373019T1 (de)
DE (1)	DE602004008888T2 (de)
SE (1)	SE524960C2 (de)
TW (1)	TWI278457B (de)
WO (1)	WO2004072125A1 (de)

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WO2008071687A1 (de) *	2006-12-15	2008-06-19	Basf Se	Herstellung von polymerdispersionen in gegenwart von organischen polymerteilchen
EP2225337B1 (de) *	2007-11-19	2017-08-23	Basf Se	Verwendung hochverzweigter polymere in polymerdispersionen für glanzfarben
BRPI0820427A2 (pt)	2007-11-19	2015-05-26	Basf Se	Usos de pelo menos um polímero elevadamente ramificado, e de uma dispersão polimérica aquosa, método para produzir uma dispersão polimérica aquosa, dispersão polimérica aquosa, composição aglutinante, agente de revestimento na forma de uma composição aquosa, e, método para aperfeiçoar a estabilidade de congelamento / descongelamento de uma dispersão polimérica aquosa
US8722796B2 (en) *	2010-01-20	2014-05-13	Basf Se	Process for preparing an aqueous polymer dispersion
EP2526124B1 (de)	2010-01-20	2014-03-19	Basf Se	Verfahren zur herstellung einer wässrigen polymerisatdispersion
CN103848942B (zh) *	2012-11-30	2016-06-08	中国石油天然气股份有限公司	一种提高压力附聚后大粒径胶乳稳定性的方法

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DE19654168A1 (de) *	1996-12-23	1998-06-25	Basf Ag	Verfahren zur Herstellung wäßriger Polymerisatdispersionen durch radikalische, wäßrige Emulsionspolymerisation
US6534590B1 (en) *	1999-10-29	2003-03-18	Dow Corning Toray Silicone Co., Ltd.	Silicone-grafted vinyl copolymer emulsion composition
AU2000251762A1 (en) *	2000-06-02	2001-12-24	National Starch And Chemical Investment Holding Corporation	Water soluble ampiphilic heteratom star polymers and their use as emulsion stabilizers in emulsion polymerization
US6350819B1 (en) *	2000-10-27	2002-02-26	Union Carbide Chemicals & Plastics Technology Corporation	Dendritic macromolecules for metal-ligand catalyzed processes

2003
- 2003-02-12 SE SE0300373A patent/SE524960C2/sv not_active IP Right Cessation
2004
- 2004-02-03 AT AT04707703T patent/ATE373019T1/de not_active IP Right Cessation
- 2004-02-03 WO PCT/SE2004/000142 patent/WO2004072125A1/en not_active Ceased
- 2004-02-03 CN CNA2004800041398A patent/CN1751068A/zh active Pending
- 2004-02-03 EP EP04707703A patent/EP1601700B1/de not_active Expired - Lifetime
- 2004-02-03 US US10/542,442 patent/US20060106172A1/en not_active Abandoned
- 2004-02-03 DE DE602004008888T patent/DE602004008888T2/de not_active Expired - Fee Related
- 2004-02-11 TW TW093103161A patent/TWI278457B/zh not_active IP Right Cessation

Also Published As

Publication number	Publication date
TWI278457B (en)	2007-04-11
US20060106172A1 (en)	2006-05-18
WO2004072125A1 (en)	2004-08-26
SE0300373L (sv)	2004-08-13
DE602004008888D1 (de)	2007-10-25
SE0300373D0 (sv)	2003-02-12
TW200426157A (en)	2004-12-01
DE602004008888T2 (de)	2008-01-17
EP1601700A1 (de)	2005-12-07
ATE373019T1 (de)	2007-09-15
CN1751068A (zh)	2006-03-22
EP1601700B1 (de)	2007-09-12

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2008-10-14	NUG	Patent has lapsed

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