SG11201804364SA - Methods for gas phase oxidative desulphurization of hydrocarbons using cuznal catalysts promoted with vib metal oxides - Google Patents
Methods for gas phase oxidative desulphurization of hydrocarbons using cuznal catalysts promoted with vib metal oxidesInfo
- Publication number
- SG11201804364SA SG11201804364SA SG11201804364SA SG11201804364SA SG11201804364SA SG 11201804364S A SG11201804364S A SG 11201804364SA SG 11201804364S A SG11201804364S A SG 11201804364SA SG 11201804364S A SG11201804364S A SG 11201804364SA SG 11201804364S A SG11201804364S A SG 11201804364SA
- Authority
- SG
- Singapore
- Prior art keywords
- international
- novosibirsk
- apt
- hydrocarbons
- vib metal
- Prior art date
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- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
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- Enzymes And Modification Thereof (AREA)
Abstract
INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property -' Organization International Bureau ires.. 00) (43) International Publication Date .... ....r .....) 13 July 2017 (13.07.2017) WI P0 I P CT (10) WO International 1111111111113111111111111111111111111111111111111111111111111111111111111111111111111111 2017/120130 Publication Number Al (51) International Patent Classification: (71) Applicants: SAUDI ARABIAN OIL COMPANY BOM 23/885 (2006.01) BO1J 35/02 (2006.01) [SA/SA]; Box 5000, Dhahran 31311 (SA). BORESKOV B01J 23/00 (2006.01) BO1J 35/10 (2006.01) INSTITUTE OF CATALYSIS [RU/RU]; Lavrentieva 5, B01J 37/03 (2006.01) BOlD 53/48 (2006.01) Novosibirsk 630090 (RU). BO1J 35/00 (2006.01) (72) Inventors; and (21) International Application Number: (71) Applicants (for US only): KOSEOGLU, Omer, Refa PCT/US2017/012017 [US/SA]; P.O. Box 8560, Saudi Aramco, Dhahran 31311 (SA). JIN, Yaming [US/SA]; P.O. Box 5060, Saudi Ara- (22) International Filing Date: mco, Dhahran 31311 (SA). ISMAGILOV, Zinfer 3 January 2017 (03.01.2017) [RU/RU]; Ul. Pravdy 1, Apt. 3, Novosibirsk 630090 (RU). (25) Filing Language: English YASHNIK, Svetlana [RU/RU]; Ul. Uchenykh 8, Apt. 116, Novosibirsk 630090 (RU). SALNIKOV, Anton (26) Publication Language: English [RU/RU]; Ul. Polevaya 14, Apt. 128, Novosibirsk 630128 (30) Priority Data: (RU). KERZHENTSEV, Mikhail [RU/MD]; Ul. Pol- 14/987,141 4 January 2016 (04.01.2016) US evaya 14, Apt. 128, Novosibirsk 630128 (RU). PARMON, Valentin [RU/RU]; Ul. Voyevodskogo 4, Novosibirsk 630128 (RU). (74) Agent: HANSON, Norman, D.; Abelman, Frayne & Schwab, 666 Third Avenue, New York, NY 10017 (US). [Continued on next page] (54) Title: METHODS FOR GAS PHASE OXIDATIVE DESULPHURIZATION OF HYDROCARBONS USING CUZNAL CATALYSTS PROMOTED WITH VIB METAL OXIDES (57) : A catalytic composition is disclosed, which exhibits an X- foiinula, ZnO, CuO, Fla 1 ray amorphous oxide with a spinel and crystals of and at least one Group VIB metal oxide, and preferably, at least one acid - Sulfur removal ; % A (Liquid phasei analysis) is oxide of B, P, or Si, as well. The composition is useful in oxidative 4n for removing sulfur from gaseous hydrocarbons. processes Su lfur remova l, % N. ) C O a d i 0 CD 0 0 CD 0 0 C;) O C --A--V628 -4--V637 -0-V653 4t-- --- -t ------- ..e -------' . 4V 325 350 400 425 450 Bed Temperature (`C) B Ratio: Sulfur Removal to Fuel Oxidation ) 130 Al 111111111111111 20 -8-V628 c o ,-3 -A-V636 Qzi 16 -c-- - ves - 7 - - 7 --E-V653 o 7312 >, ° 8 0 E 2 ..... Il 0 325 350 375 400 425 450 Bed Temperature CC) IN Il C ei O WO 2017/120130 Al I IIIII IMOMOIDIONOIDEMOMOHMIIMMIONIONVOIMIE (81) Designated States (unless otherwise indicated, for every (84) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, kind of regional protection available): ARIPO (BW, GH, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, LY, NA, QA, SM, MA, MD, ME, MG, MK, MN, MW, MX, MY, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, MZ, PT, SL, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: GA, US, UZ, VC, VN, ZA, ZM, ZW. — with international search report (Art. 21(3))
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/987,141 US10882801B2 (en) | 2016-01-04 | 2016-01-04 | Methods for gas phase oxidative desulphurization of hydrocarbons using CuZnAl catalysts promoted with group VIB metal oxides |
| PCT/US2017/012017 WO2017120130A1 (en) | 2016-01-04 | 2017-01-03 | Methods for gas phase oxidative desulphurization of hydrocarbons using cuznal catalysts promoted with vib metal oxides |
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| SG11201804364SA true SG11201804364SA (en) | 2018-07-30 |
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| SG11201804364SA SG11201804364SA (en) | 2016-01-04 | 2017-01-03 | Methods for gas phase oxidative desulphurization of hydrocarbons using cuznal catalysts promoted with vib metal oxides |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US10882801B2 (en) |
| EP (1) | EP3400101B1 (en) |
| JP (1) | JP6843143B2 (en) |
| KR (1) | KR102092284B1 (en) |
| CN (1) | CN108430623B (en) |
| SG (1) | SG11201804364SA (en) |
| WO (1) | WO2017120130A1 (en) |
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| US10384197B2 (en) | 2016-07-26 | 2019-08-20 | Saudi Arabian Oil Company | Additives for gas phase oxidative desulfurization catalysts |
| US11174441B2 (en) | 2018-10-22 | 2021-11-16 | Saudi Arabian Oil Company | Demetallization by delayed coking and gas phase oxidative desulfurization of demetallized residual oil |
| US10703998B2 (en) | 2018-10-22 | 2020-07-07 | Saudi Arabian Oil Company | Catalytic demetallization and gas phase oxidative desulfurization of residual oil |
| US10894923B2 (en) | 2018-10-22 | 2021-01-19 | Saudi Arabian Oil Company | Integrated process for solvent deasphalting and gas phase oxidative desulfurization of residual oil |
| CN112742203B (en) * | 2019-10-30 | 2023-09-05 | 中国石油化工股份有限公司 | Gas desulfurizing agent, preparation method thereof and gas desulfurizing method |
| US11278871B2 (en) * | 2020-03-13 | 2022-03-22 | Toyota Motor Engineering & Manufacturing North America, Inc. | Direct no decomposition catalyst |
| CN121222434B (en) * | 2025-12-02 | 2026-04-03 | 湖北荟煌科技股份有限公司 | A method for preparing a desulfurization purification catalyst |
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| IN147123B (en) * | 1976-10-19 | 1979-11-17 | Standard Oil Co Ohio | |
| US4085065A (en) * | 1976-10-19 | 1978-04-18 | The Standard Oil Company (Ohio) | Process for the preparation of unsaturated acids from unsaturated aldehydes |
| CN1037778C (en) * | 1992-11-28 | 1998-03-18 | 大阪瓦斯株式会社 | Method for desulfurization of hydrocarbon |
| DE4419486C2 (en) * | 1994-06-03 | 1996-09-05 | Daimler Benz Ag | Catalyst, process for its preparation and use of the catalyst |
| US7427581B2 (en) * | 1999-12-14 | 2008-09-23 | China Petroleum & Chemical Corporation | Desulfurization process and novel bimetallic sorbent systems for same |
| US6693057B1 (en) * | 2002-03-22 | 2004-02-17 | Sud-Chemie Inc. | Water gas shift catalyst |
| AU2003293874A1 (en) * | 2002-12-19 | 2004-07-14 | Basf Aktiengesellschaft | Method for removing sulfur compounds from gases containing hydrocarbons |
| US7749376B2 (en) * | 2005-08-15 | 2010-07-06 | Sud-Chemie Inc. | Process for sulfur adsorption using copper-containing catalyst |
| CN104136116B (en) * | 2011-07-27 | 2017-02-08 | 沙特阿拉伯石油公司 | For from gaseous hydrocarbon remove sulphur compound catalyst composition, manufacture their method and uses thereof |
| US20130026072A1 (en) | 2011-07-27 | 2013-01-31 | Abdennour Bourane | Catalytic compositions useful in removal of sulfur compounds from gaseous hydrocarbons, processes for making these and uses thereof |
| CN103028365B (en) * | 2011-09-29 | 2014-12-31 | 中国石油化工股份有限公司 | Gas desulfurization sorbent and preparation method thereof and desulfurization method of sulfur-containing gas |
| FR2984760B1 (en) * | 2011-12-22 | 2014-01-17 | IFP Energies Nouvelles | HYDROCONVERSION USING CATALYST COMPRISING AT LEAST ONE ZEOLITHE AND METALS OF GROUP VIII AND VIB AND PREPARATION OF CATALYST |
| US8906227B2 (en) * | 2012-02-02 | 2014-12-09 | Suadi Arabian Oil Company | Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds |
| US9043572B2 (en) * | 2012-07-16 | 2015-05-26 | International Business Machines Corporation | Automatically preventing large block writes from starving small block writes in a storage device |
| KR101409293B1 (en) * | 2012-11-09 | 2014-06-27 | 한국과학기술연구원 | Cu/Zn/Al catalyst comprising copper nano particles of high surface area and method for preparing the same |
| US8920635B2 (en) * | 2013-01-14 | 2014-12-30 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| WO2014191874A1 (en) * | 2013-05-28 | 2014-12-04 | Saudi Basic Industries Corporation | Promoted molybdenum catalyst composition for production of aromatics from methane |
| CN104437518B (en) * | 2013-09-22 | 2017-03-29 | 中国石油化工股份有限公司 | A kind of catalyst for selectively hydrodesulfurizing and its preparation and application |
| CN104560250B (en) * | 2013-10-28 | 2018-06-08 | 中国石油化工股份有限公司 | Cleanser and preparation method thereof |
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- 2016-01-04 US US14/987,141 patent/US10882801B2/en active Active
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2017
- 2017-01-03 WO PCT/US2017/012017 patent/WO2017120130A1/en not_active Ceased
- 2017-01-03 SG SG11201804364SA patent/SG11201804364SA/en unknown
- 2017-01-03 JP JP2018534151A patent/JP6843143B2/en not_active Expired - Fee Related
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| JP2019505633A (en) | 2019-02-28 |
| WO2017120130A1 (en) | 2017-07-13 |
| US20170190641A1 (en) | 2017-07-06 |
| US20210230084A1 (en) | 2021-07-29 |
| CN108430623A (en) | 2018-08-21 |
| EP3400101A1 (en) | 2018-11-14 |
| EP3400101B1 (en) | 2023-04-05 |
| US11603341B2 (en) | 2023-03-14 |
| CN108430623B (en) | 2021-11-05 |
| US10882801B2 (en) | 2021-01-05 |
| KR102092284B1 (en) | 2020-03-24 |
| JP6843143B2 (en) | 2021-03-17 |
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