SG185809A1 - Integrated vacuum resid to chemicals coversion process - Google Patents

Integrated vacuum resid to chemicals coversion process Download PDF

Info

Publication number: SG185809A1
Authority: SG; Singapore
Prior art keywords: resid; reactor; transfer line; fluidized; gasifier
Prior art date: 2010-07-09

Application number

SG2012088290A

Other languages

English (en)

Inventor

S Mark Davis

Larry L Iaccino

Richard C Stell

Steven E Silverberg

Jiunn-Shyan Liou

Howard Freund

Original Assignee

Exxonmobil Chem Patents Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2010-07-09

Filing date

2011-06-09

Publication date

2013-01-30

2010-07-09 Priority claimed from US12/833,485 external-priority patent/US8361311B2/en

2011-06-09 Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc

2013-01-30 Publication of SG185809A1 publication Critical patent/SG185809A1/en

Links

238000000034 method Methods 0.000 title claims abstract description 103
230000008569 process Effects 0.000 title claims abstract description 98
239000000126 substance Substances 0.000 title description 10
229930195733 hydrocarbon Natural products 0.000 claims abstract description 91
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 91
239000000571 coke Substances 0.000 claims abstract description 69
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 65
239000007788 liquid Substances 0.000 claims abstract description 53
239000002245 particle Substances 0.000 claims abstract description 51
238000006243 chemical reaction Methods 0.000 claims abstract description 50
150000001336 alkenes Chemical class 0.000 claims abstract description 36
239000007791 liquid phase Substances 0.000 claims abstract description 21
238000005336 cracking Methods 0.000 claims abstract description 19
239000012808 vapor phase Substances 0.000 claims abstract description 10
238000010438 heat treatment Methods 0.000 claims abstract description 7
238000012546 transfer Methods 0.000 claims description 67
239000007787 solid Substances 0.000 claims description 52
238000004230 steam cracking Methods 0.000 claims description 47
239000012530 fluid Substances 0.000 claims description 30
238000000197 pyrolysis Methods 0.000 claims description 23
239000003054 catalyst Substances 0.000 claims description 19
238000004891 communication Methods 0.000 claims description 18
239000012071 phase Substances 0.000 claims description 17
239000007789 gas Substances 0.000 claims description 16
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
239000000203 mixture Substances 0.000 claims description 13
239000001301 oxygen Substances 0.000 claims description 13
229910052760 oxygen Inorganic materials 0.000 claims description 13
238000004064 recycling Methods 0.000 claims description 12
238000004523 catalytic cracking Methods 0.000 claims description 6
238000002156 mixing Methods 0.000 claims description 5
241001164238 Zulia Species 0.000 claims description 4
230000003134 recirculating effect Effects 0.000 claims description 4
239000000047 product Substances 0.000 description 43
238000004939 coking Methods 0.000 description 26
239000003921 oil Substances 0.000 description 16
238000012545 processing Methods 0.000 description 9
239000000463 material Substances 0.000 description 8
238000000926 separation method Methods 0.000 description 8
230000008901 benefit Effects 0.000 description 6
-1 ethylene, propylene, butylenes Chemical class 0.000 description 6
239000010779 crude oil Substances 0.000 description 5
239000002737 fuel gas Substances 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 4
239000000295 fuel oil Substances 0.000 description 4
238000002309 gasification Methods 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
238000004227 thermal cracking Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
238000009835 boiling Methods 0.000 description 3
238000010924 continuous production Methods 0.000 description 3
238000010586 diagram Methods 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
238000010791 quenching Methods 0.000 description 3
230000009467 reduction Effects 0.000 description 3
238000007670 refining Methods 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
238000009834 vaporization Methods 0.000 description 3
230000008016 vaporization Effects 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
238000013459 approach Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000001816 cooling Methods 0.000 description 2
238000013461 design Methods 0.000 description 2
238000004821 distillation Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000003546 flue gas Substances 0.000 description 2
239000000446 fuel Substances 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000012535 impurity Substances 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
230000010354 integration Effects 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
239000011707 mineral Substances 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
238000010926 purge Methods 0.000 description 2
230000000171 quenching effect Effects 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
102220532733 SPARC-like protein 1_I15A_mutation Human genes 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
235000013844 butane Nutrition 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000007233 catalytic pyrolysis Methods 0.000 description 1
230000008859 change Effects 0.000 description 1
239000012707 chemical precursor Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
238000011033 desalting Methods 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000003628 erosive effect Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000004231 fluid catalytic cracking Methods 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
239000003502 gasoline Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
125000005608 naphthenic acid group Chemical group 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000001294 propane Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000010517 secondary reaction Methods 0.000 description 1
230000000153 supplemental effect Effects 0.000 description 1
238000010998 test method Methods 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
230000000699 topical effect Effects 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
239000008096 xylene Substances 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/005—Coking (in order to produce liquid products mainly)
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G51/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only
- C10G51/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only
- C10G51/023—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only only thermal cracking steps
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G51/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only
- C10G51/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only
- C10G51/04—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only including only thermal and catalytic cracking steps
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
- C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4006—Temperature
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/708—Coking aspect, coke content and composition of deposits
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/805—Water
- C10G2300/807—Steam
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Physics & Mathematics (AREA)
Thermal Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

SG2012088290A 2010-07-09 2011-06-09 Integrated vacuum resid to chemicals coversion process SG185809A1 (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US12/833,485 US8361311B2 (en)	2010-07-09	2010-07-09	Integrated vacuum resid to chemicals conversion process
EP10178215		2010-09-22
PCT/US2011/039782 WO2012005862A1 (fr)	2010-07-09	2011-06-09	Procédé intégré de conversion d'un résidu sous vide en des produits chimiques

Publications (1)

Publication Number	Publication Date
SG185809A1 true SG185809A1 (en)	2013-01-30

Family

ID=44303699

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SG2012088290A SG185809A1 (en)	2010-07-09	2011-06-09	Integrated vacuum resid to chemicals coversion process

Country Status (4)

Country	Link
EP (1)	EP2591069A1 (fr)
CN (1)	CN103003394B (fr)
SG (1)	SG185809A1 (fr)
WO (1)	WO2012005862A1 (fr)

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US8937186B2 (en)	2012-08-21	2015-01-20	Uop Llc	Acids removal and methane conversion process using a supersonic flow reactor
US8933275B2 (en)	2012-08-21	2015-01-13	Uop Llc	Production of oxygenates from a methane conversion process
US9707530B2 (en)	2012-08-21	2017-07-18	Uop Llc	Methane conversion apparatus and process using a supersonic flow reactor
US9689615B2 (en)	2012-08-21	2017-06-27	Uop Llc	Steady state high temperature reactor
US20140058093A1 (en) *	2012-08-21	2014-02-27	Uop Llc	Removal of solids and methane conversion process using a supersonic flow reactor
US9434663B2 (en)	2012-08-21	2016-09-06	Uop Llc	Glycols removal and methane conversion process using a supersonic flow reactor
US9308513B2 (en)	2012-08-21	2016-04-12	Uop Llc	Production of vinyl chloride from a methane conversion process
US9656229B2 (en)	2012-08-21	2017-05-23	Uop Llc	Methane conversion apparatus and process using a supersonic flow reactor
US8927769B2 (en)	2012-08-21	2015-01-06	Uop Llc	Production of acrylic acid from a methane conversion process
US9370757B2 (en)	2012-08-21	2016-06-21	Uop Llc	Pyrolytic reactor
US9205398B2 (en)	2012-08-21	2015-12-08	Uop Llc	Production of butanediol from a methane conversion process
US9327265B2 (en)	2012-08-21	2016-05-03	Uop Llc	Production of aromatics from a methane conversion process
US9023255B2 (en)	2012-08-21	2015-05-05	Uop Llc	Production of nitrogen compounds from a methane conversion process
CN110257091B (zh) *	2019-07-23	2020-09-18	北京燕泰博嘉科技有限公司	一种可拆装立式半圆形管体的生物质热解炉

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2011
- 2011-06-09 WO PCT/US2011/039782 patent/WO2012005862A1/fr not_active Ceased
- 2011-06-09 CN CN201180033757.5A patent/CN103003394B/zh not_active Expired - Fee Related
- 2011-06-09 SG SG2012088290A patent/SG185809A1/en unknown
- 2011-06-09 EP EP11726295.6A patent/EP2591069A1/fr not_active Withdrawn

Also Published As

Publication number	Publication date
WO2012005862A1 (fr)	2012-01-12
CN103003394A (zh)	2013-03-27
CN103003394B (zh)	2015-04-29
EP2591069A1 (fr)	2013-05-15

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