SG50357A1 - Epoxidation process and catalyst therefore - Google Patents
Epoxidation process and catalyst thereforeInfo
- Publication number
- SG50357A1 SG50357A1 SG1995001519A SG1995001519A SG50357A1 SG 50357 A1 SG50357 A1 SG 50357A1 SG 1995001519 A SG1995001519 A SG 1995001519A SG 1995001519 A SG1995001519 A SG 1995001519A SG 50357 A1 SG50357 A1 SG 50357A1
- Authority
- SG
- Singapore
- Prior art keywords
- catalyst
- mixture
- molecular sieve
- containing molecular
- framework
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000006735 epoxidation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 229910052719 titanium Inorganic materials 0.000 abstract 3
- 239000010936 titanium Substances 0.000 abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000002808 molecular sieve Substances 0.000 abstract 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- -1 benzylsubstituted ammonium Chemical class 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 150000002432 hydroperoxides Chemical class 0.000 abstract 1
- 238000010335 hydrothermal treatment Methods 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 150000003377 silicon compounds Chemical class 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7057—Zeolite Beta
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
- B01J37/033—Using Hydrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
- C07D211/18—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D211/26—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/27—Beta, e.g. NU-2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/172,405 US5374747A (en) | 1993-12-23 | 1993-12-23 | Epoxidation process and catalyst therefore |
| US30255494A | 1994-09-08 | 1994-09-08 | |
| US08/329,732 US5453511A (en) | 1993-12-23 | 1994-10-26 | Bis-piperidinium compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SG50357A1 true SG50357A1 (en) | 1998-07-20 |
Family
ID=27390135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SG1995001519A SG50357A1 (en) | 1993-12-23 | 1994-12-16 | Epoxidation process and catalyst therefore |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US5453511A (de) |
| EP (2) | EP0659685B1 (de) |
| JP (1) | JPH07242649A (de) |
| KR (1) | KR100339284B1 (de) |
| AT (1) | ATE215051T1 (de) |
| CA (1) | CA2138840A1 (de) |
| DE (1) | DE69430234T2 (de) |
| ES (1) | ES2170766T3 (de) |
| SG (1) | SG50357A1 (de) |
| TW (1) | TW426641B (de) |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4419195A1 (de) * | 1993-07-12 | 1995-01-19 | Degussa | Strukturierter Katalysator, bestehend aus mikroporösen Oxiden von Silicium, Aluminium und Titan |
| US5374747A (en) * | 1993-12-23 | 1994-12-20 | Arco Chemical Technology, L.P. | Epoxidation process and catalyst therefore |
| US5554356A (en) * | 1995-06-07 | 1996-09-10 | Arco Chemical Technology, L.P. | Method of making essentially silicic zeolite beta |
| DE19528219A1 (de) * | 1995-08-01 | 1997-02-06 | Degussa | Verfahren zur Herstellung von Epoxiden aus Olefinen |
| US5591875A (en) * | 1995-08-02 | 1997-01-07 | Chang; Te | Epoxidation Process |
| FR2737482B1 (fr) * | 1995-08-02 | 1997-09-19 | Elf Aquitaine | Procede d'obtention de zeolithes au titane insere dans le reseau et application |
| US6086848A (en) * | 1995-12-01 | 2000-07-11 | Chevron U.S.A. Inc. | Process for preparing zeolites using substituted-piperidinium cations |
| US5741749A (en) * | 1996-02-13 | 1998-04-21 | Arco Chemical Technology, L.P. | Regeneration of a titanium-containing molecular sieve |
| WO1997029991A1 (es) * | 1996-02-16 | 1997-08-21 | Consejo Superior Investigaciones Cientificas | PROCEDIMIENTO DE PREPARACION DE ZEOLITA BETA CONTENIENDO Ti, Y SIN Al |
| US5663384A (en) * | 1996-03-06 | 1997-09-02 | Arco Chemical Technology, L.P. | Asymetric epoxidation using a titanium-containing zeolite and a chiral hydroperoxide |
| ES2126485B1 (es) * | 1996-05-16 | 1999-12-01 | Univ Valencia Politecnica | Procedimiento y catalizadores para la obtencion de epoxidos y derivados hidroxilados de acidos y esteres de acidos grasos. |
| DE19623608A1 (de) * | 1996-06-13 | 1997-12-18 | Basf Ag | Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid oder Hydroperoxiden |
| BE1010716A3 (fr) * | 1996-10-25 | 1998-12-01 | Solvay | Procede de regeneration de catalyseurs de type silicalite au titane. |
| DE19644348A1 (de) * | 1996-10-25 | 1998-04-30 | Degussa | Verfahren zur Herstellung von titanhaltigen Molekularsieben |
| US6054112A (en) * | 1996-10-25 | 2000-04-25 | Degussa-Huls Ag | Process for the preparation of titanium containing molecular sieves |
| US5965104A (en) * | 1996-12-31 | 1999-10-12 | Chevron U.S.A. Inc. | Zeolite SSZ-43 |
| GB9703093D0 (en) * | 1997-02-14 | 1997-04-02 | Exxon Chemical Patents Inc | Metal molecular sieve catalysts |
| US5977009A (en) * | 1997-04-02 | 1999-11-02 | Arco Chemical Technology, Lp | Catalyst compositions derived from titanium-containing molecule sieves |
| US6042807A (en) * | 1997-04-02 | 2000-03-28 | Arco Chemical Technology, L.P. | Tellurium-containing molecular sieves |
| GB9707981D0 (en) * | 1997-04-21 | 1997-06-11 | Exxon Chemical Patents Inc | Molecular sieve |
| WO1998051811A1 (en) * | 1997-05-16 | 1998-11-19 | E.I. Du Pont De Nemours And Company | Process for the selective oxidation of organic compounds |
| WO1998056780A1 (es) * | 1997-06-10 | 1998-12-17 | Universidad Politecnica De Valencia | Procedimiento y catalizadores para la obtencion de epoxidos y derivados hidroxilados de acidos y esteres de acidos grasos |
| US6024840A (en) * | 1997-08-08 | 2000-02-15 | Arco Chemical Technology, L.P. | Propylene oxide purification |
| US5863391A (en) * | 1997-08-15 | 1999-01-26 | Arco Chemical Technology, L.P. | Purification of a methanol stream |
| US5849938A (en) * | 1997-09-02 | 1998-12-15 | Arco Chemical Technology, L.P. | Separation of methanol and propylene oxide from a reaction mixture |
| BE1011577A3 (fr) * | 1997-11-27 | 1999-11-09 | Solvay | Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur. |
| BE1011578A3 (fr) * | 1997-11-27 | 1999-11-09 | Solvay | Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de ce catalyseur. |
| KR100429675B1 (ko) * | 1998-03-26 | 2004-05-03 | 렙솔 퀴미카 에스.에이. | 올레핀계 화합물을 과산화수소로 에폭시화시키는 방법 |
| US6008388A (en) * | 1998-04-16 | 1999-12-28 | Arco Chemical Technology, L.P. | Epoxidation process |
| SG82626A1 (en) * | 1998-08-04 | 2001-08-21 | Sumitomo Chemical Co | Titanium-containing silicon oxide catalyst |
| US5906954A (en) * | 1998-10-13 | 1999-05-25 | Engelhard Corporation | Removal of titanium atoms from titanium silicate molecular sieves |
| ES2156506B1 (es) * | 1998-10-14 | 2002-03-01 | Sumitomo Chemical Co | Metodo para la produccion de oxido de propileno. |
| US6087514A (en) * | 1998-10-20 | 2000-07-11 | Engelhard Corporation | Titanium silicate molecular sieve oxidation catalysts and the production thereof |
| BE1012303A3 (fr) | 1998-11-20 | 2000-09-05 | Solvay | Procede de fabrication d'un oxiranne. |
| US6514578B1 (en) | 1999-06-30 | 2003-02-04 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Polymerizable mesogenic tolanes |
| JP2001031662A (ja) | 1999-07-14 | 2001-02-06 | Sumitomo Chem Co Ltd | プロピレンオキサイドの製造方法 |
| ES2165771B1 (es) * | 1999-07-20 | 2003-05-01 | Sumitomo Chemical Co | Catalizador de oxido de silicio que contiene titanio. |
| JP4399913B2 (ja) * | 1999-08-25 | 2010-01-20 | 住友化学株式会社 | オキシラン化合物の製造方法 |
| US6114551A (en) * | 1999-10-04 | 2000-09-05 | Mobil Oil Corporation | Olefin epoxidation catalysts |
| DE19954322A1 (de) * | 1999-11-10 | 2001-05-17 | Basf Ag | Oxid und Verfahren zu dessen Herstellung |
| DE60121914D1 (de) * | 2000-02-02 | 2006-09-14 | Sumitomo Chemical Co | Geformter katalysator, verfahren zu dessen herstellung sowie verfahren zur herstellung einer oxirankomponente |
| EP1129991A1 (de) * | 2000-03-02 | 2001-09-05 | Degussa AG | Verfahren zur Herstellung eines titanhaltigen Zeolithen |
| EP1138387A1 (de) * | 2000-03-29 | 2001-10-04 | Degussa AG | Verfahren zur Herstellung eines Titansilicalitformkörpers |
| EP1138386A1 (de) | 2000-03-29 | 2001-10-04 | Degussa AG | Verfahren zur Herstellung eines Titansilicalitformkörpers |
| US6281369B1 (en) | 2000-12-07 | 2001-08-28 | Arco Chemical Technology, L.P. | Epoxidation catalyst and process |
| US6417378B1 (en) * | 2001-10-09 | 2002-07-09 | Arco Chemical Technology, L.P. | Direct epoxidation process using pre-treated titanium zeolite |
| AU2002356941A1 (en) * | 2001-11-15 | 2003-06-10 | Pq Holding, Inc. | Method for controlling synthesis conditions during molecular sieve synthesis using combinations of quaternary ammonium hydroxides and halides |
| WO2004078739A1 (ja) * | 2003-03-06 | 2004-09-16 | Sumitomo Chemical Company, Limited | プロピレンオキサイドの製造方法 |
| JP4639606B2 (ja) * | 2003-03-06 | 2011-02-23 | 住友化学株式会社 | プロピレンオキサイドの製造方法 |
| US20050277542A1 (en) * | 2004-06-14 | 2005-12-15 | Kaminsky Mark P | Catalyst regeneration process |
| US20060094893A1 (en) * | 2004-10-29 | 2006-05-04 | Darbha Srinivas | Process for preparing cyclic carbonates |
| WO2007123309A1 (en) * | 2006-04-20 | 2007-11-01 | Amorepacific Corporation | Mesoporous inorganic composite powder containing metal element in its structure and the method for manufacturing thereof |
| KR100726279B1 (ko) * | 2006-04-20 | 2007-06-11 | (주)아모레퍼시픽 | 골격 구조내에 금속원소가 치환된 중형기공성 분자체물질의 제조방법 및 그 분자체 물질 |
| FR2918050B1 (fr) * | 2007-06-29 | 2011-05-06 | Inst Francais Du Petrole | Solide cristallise izm-2 et son procede de preparation |
| KR101345560B1 (ko) | 2011-12-06 | 2014-01-10 | 한국화학연구원 | 디시클로펜타디엔다이머의 에폭시화 반응용 고활성 촉매 및 이의 제조방법 |
| TWI589567B (zh) * | 2012-12-24 | 2017-07-01 | China Petrochemical Development Corporation Taipei (Taiwan) | Method of making epoxides |
| ES2692818B2 (es) | 2017-06-05 | 2019-11-28 | Univ Valencia Politecnica | Sintesis de la zeolita beta en su forma nanocristalina, procedimiento de sintesis y su uso en aplicaciones cataliticas |
| EP3702329A4 (de) | 2017-10-25 | 2020-11-25 | Mitsui Mining & Smelting Co., Ltd. | Beta-zeolith, verfahren zur herstellung davon und katalysator |
| CN109438393A (zh) * | 2018-10-29 | 2019-03-08 | 辽宁石油化工大学 | 一种环氧增塑剂合成方法 |
| CN113371729B (zh) * | 2021-07-09 | 2022-01-04 | 中国矿业大学 | 一种含有三元环的全硅Beta分子筛的改性方法 |
| KR102734396B1 (ko) * | 2022-06-20 | 2024-11-26 | 주식회사 루브캠코리아 | 에폭시화 대두유를 이용한 친환경 윤활그리스의 제조방법 |
| CN118356939B (zh) * | 2024-04-01 | 2025-11-25 | 中国天辰工程有限公司 | 一种用于己二酸合成的催化剂及其制备方法、应用 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4367342A (en) * | 1969-04-02 | 1983-01-04 | Shell Oil Company | Olefin epoxidation |
| GR66589B (de) * | 1978-06-22 | 1981-03-30 | Snam Progetti | |
| IT1127311B (it) * | 1979-12-21 | 1986-05-21 | Anic Spa | Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi |
| AU544046B2 (en) * | 1981-10-17 | 1985-05-16 | Aannemers Combinatie Zinkwerken B.V. | Unloading chute for vessels |
| IT1152299B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'espossidazione di composti olefinici |
| US4576805A (en) * | 1982-08-27 | 1986-03-18 | Mobil Oil Corporation | Increasing lattice metal content of porous inorganic crystalline compositions |
| US4642226A (en) * | 1984-04-16 | 1987-02-10 | Mobil Oil Corporation | Process for the preparation of zeolite Beta using dibenzyldimethylammonium ions and the product produced |
| US4554145A (en) * | 1984-04-16 | 1985-11-19 | Mobil Oil Corporation | Preparation of crystalline silicate zeolite Beta |
| CA1254188A (en) * | 1984-04-26 | 1989-05-16 | Bonita K. Marcus | Titanium-aluminum-silicon-oxide molecular sieve compositions |
| US4539193A (en) * | 1984-05-23 | 1985-09-03 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-12 |
| US5246690A (en) * | 1985-12-19 | 1993-09-21 | Eniricerche S.P.A. | Synthetic, crystalline, porous material containing silicon oxide, titanium oxide and aluminum oxide |
| ES2033693T3 (es) * | 1986-01-28 | 1993-04-01 | Eniricerche S.P.A. | Un procedimiento para la exposidacion de compuestos olefinicos. |
| IT1222868B (it) * | 1987-10-12 | 1990-09-12 | Montedipe Spa | Metodo per la preparazione di titanio silicaliti |
| US4828812A (en) * | 1987-12-29 | 1989-05-09 | Mobil Oil Corporation | Titanosilicates of enhanced ion exchange capacity and their preparation |
| JPH02116843A (ja) * | 1988-10-27 | 1990-05-01 | Konica Corp | 帯電防止されたハロゲン化銀写真感光材料 |
| CA2002341A1 (en) * | 1988-11-09 | 1990-05-09 | Takehisa Nakanishi | Method for preparing epichlorohydrins |
| FR2669618B1 (fr) * | 1990-11-26 | 1993-05-07 | Elf Aquitaine | Procede de desalumination des zeolithes synthetiques a larges pores, catalyseurs et adsorbants organophiles selectifs renfermant les zeolithes desaluminees obtenues selon le procede et zeolithe beta essentiellement silicique. |
| ES2037596B1 (es) * | 1991-07-31 | 1994-02-16 | Univ Politecnica De Valencia E | Sintesis de un silicoaluminotitanato isomorfo a la zeolita beta, activo para la oxidacion selectiva de compuestos organicos. |
| DE4138155A1 (de) * | 1991-11-21 | 1993-05-27 | Basf Ag | Verfahren zur herstellung von im wesentlichen alkalifreien titansilikat-kristallen mit zeolithstruktur |
| US5262550A (en) * | 1992-04-30 | 1993-11-16 | Arco Chemical Technology, L.P. | Epoxidation process using titanium-rich silicalite catalysts |
| US5214168A (en) * | 1992-04-30 | 1993-05-25 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
| ATE175590T1 (de) * | 1992-07-24 | 1999-01-15 | Exxon Chemical Patents Inc | Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffen |
| FR2694549A1 (fr) * | 1992-08-06 | 1994-02-11 | Atochem Elf Sa | Procédé de préparation de zéolites bêta au titane et zéolites bêta nouvelles. |
| US5271921A (en) * | 1992-10-09 | 1993-12-21 | Chevron Research And Technology Company | Process for preparing molecular sieves using 3,7-diazabicyclo[3.3.1] |
| WO1994012277A1 (de) * | 1992-12-03 | 1994-06-09 | Leuna-Katalysatoren Gmbh | Oxidationskatalysatoren |
| US5354875A (en) * | 1993-12-23 | 1994-10-11 | Uop | Epoxidation of olefins using a titania-supported titanosilicate |
| US5374747A (en) * | 1993-12-23 | 1994-12-20 | Arco Chemical Technology, L.P. | Epoxidation process and catalyst therefore |
| US5412122A (en) * | 1993-12-23 | 1995-05-02 | Arco Chemical Technology, L.P. | Epoxidation process |
| US5384418A (en) * | 1994-01-25 | 1995-01-24 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
| US5508019A (en) * | 1994-06-30 | 1996-04-16 | Arco Chemical Technology, L.P. | Dealumination of aluminosilicates |
| US5474754A (en) * | 1994-08-15 | 1995-12-12 | Arco Chemical Technology, L.P. | Preparation of an aluminosilicotitanate isomorphous with zeolite beta |
| US5463090A (en) * | 1994-10-27 | 1995-10-31 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
| US5523426A (en) * | 1995-01-04 | 1996-06-04 | Arco Chemical Technology, L.P. | Integrated process for epoxidation |
-
1994
- 1994-10-26 US US08/329,732 patent/US5453511A/en not_active Expired - Fee Related
- 1994-12-16 EP EP94309421A patent/EP0659685B1/de not_active Expired - Lifetime
- 1994-12-16 AT AT94309421T patent/ATE215051T1/de not_active IP Right Cessation
- 1994-12-16 SG SG1995001519A patent/SG50357A1/en unknown
- 1994-12-16 EP EP01110173A patent/EP1151999A2/de not_active Withdrawn
- 1994-12-16 DE DE69430234T patent/DE69430234T2/de not_active Expired - Fee Related
- 1994-12-16 ES ES94309421T patent/ES2170766T3/es not_active Expired - Lifetime
- 1994-12-22 JP JP6335466A patent/JPH07242649A/ja active Pending
- 1994-12-22 CA CA002138840A patent/CA2138840A1/en not_active Abandoned
- 1994-12-23 KR KR1019940036241A patent/KR100339284B1/ko not_active Expired - Fee Related
-
1995
- 1995-01-09 TW TW084100122A patent/TW426641B/zh not_active IP Right Cessation
- 1995-04-11 US US08/420,187 patent/US5527520A/en not_active Expired - Fee Related
- 1995-04-11 US US08/419,775 patent/US5621122A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| TW426641B (en) | 2001-03-21 |
| JPH07242649A (ja) | 1995-09-19 |
| KR950016874A (ko) | 1995-07-20 |
| EP0659685A1 (de) | 1995-06-28 |
| EP1151999A2 (de) | 2001-11-07 |
| DE69430234T2 (de) | 2002-10-17 |
| CA2138840A1 (en) | 1995-06-24 |
| EP0659685B1 (de) | 2002-03-27 |
| ES2170766T3 (es) | 2002-08-16 |
| US5453511A (en) | 1995-09-26 |
| US5621122A (en) | 1997-04-15 |
| US5527520A (en) | 1996-06-18 |
| ATE215051T1 (de) | 2002-04-15 |
| DE69430234D1 (de) | 2002-05-02 |
| KR100339284B1 (ko) | 2002-11-27 |
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