SK279697B6 - Spôsob prípravy polyesteru - Google Patents

Spôsob prípravy polyesteru Download PDF

Info

Publication number: SK279697B6
Authority: SK; Slovakia
Prior art keywords: ppm; germanium; polycondensation; manganese; salt
Prior art date: 1991-01-16

Application number

SK2827-92A

Other languages

English (en)

Slovak (sk)

Inventor

Josiane Enggasser

Roland St�Hlin

Paul Gesche

Original Assignee

Rhone-Poulenc Viscosuisse Sa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-01-16

Filing date

1992-01-14

Publication date

1999-02-11

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=4179434&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=SK279697(B6) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1992-01-14 Application filed by Rhone-Poulenc Viscosuisse Sa filed Critical Rhone-Poulenc Viscosuisse Sa

1999-02-11 Publication of SK279697B6 publication Critical patent/SK279697B6/sk

Links

229920000728 polyester Polymers 0.000 title claims abstract description 11
238000000034 method Methods 0.000 title claims description 7
238000004519 manufacturing process Methods 0.000 title claims description 4
239000003054 catalyst Substances 0.000 claims abstract description 20
238000006068 polycondensation reaction Methods 0.000 claims abstract description 14
229910052732 germanium Inorganic materials 0.000 claims abstract description 10
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 10
-1 terephthalic acid ester Chemical class 0.000 claims abstract description 8
KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 4
150000002290 germanium Chemical class 0.000 claims abstract description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 26
239000011572 manganese Substances 0.000 claims description 15
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 10
229910052748 manganese Inorganic materials 0.000 claims description 10
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims description 6
229910052787 antimony Inorganic materials 0.000 claims description 5
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 5
238000002360 preparation method Methods 0.000 claims description 5
230000000052 comparative effect Effects 0.000 claims description 4
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
239000011574 phosphorus Substances 0.000 claims description 4
229910052698 phosphorus Inorganic materials 0.000 claims description 4
229920000642 polymer Polymers 0.000 claims description 4
239000000835 fiber Substances 0.000 claims description 3
150000002696 manganese Chemical class 0.000 claims description 2
OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
229940117389 dichlorobenzene Drugs 0.000 claims 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
239000000203 mixture Substances 0.000 claims 1
238000006555 catalytic reaction Methods 0.000 abstract description 2
150000003839 salts Chemical class 0.000 abstract 2
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
229920000139 polyethylene terephthalate Polymers 0.000 abstract 1
239000005020 polyethylene terephthalate Substances 0.000 abstract 1
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
239000000654 additive Substances 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
230000000903 blocking effect Effects 0.000 description 2
150000001785 cerium compounds Chemical class 0.000 description 2
238000005886 esterification reaction Methods 0.000 description 2
239000011888 foil Substances 0.000 description 2
150000002903 organophosphorus compounds Chemical class 0.000 description 2
150000003018 phosphorus compounds Chemical class 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
231100000167 toxic agent Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
WYOFTXWVYIGTCT-UHFFFAOYSA-K [OH-].[Sb+3].OCC([O-])=O.OCC([O-])=O Chemical compound [OH-].[Sb+3].OCC([O-])=O.OCC([O-])=O WYOFTXWVYIGTCT-UHFFFAOYSA-K 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000001154 acute effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 1
150000001463 antimony compounds Chemical class 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
XWTXZJITNNRDLC-UHFFFAOYSA-K bis[(2-hydroxyacetyl)oxy]alumanyl 2-hydroxyacetate Chemical compound [Al+3].OCC([O-])=O.OCC([O-])=O.OCC([O-])=O XWTXZJITNNRDLC-UHFFFAOYSA-K 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
FNIHDXPFFIOGKL-UHFFFAOYSA-N disodium;dioxido(oxo)germane Chemical compound [Na+].[Na+].[O-][Ge]([O-])=O FNIHDXPFFIOGKL-UHFFFAOYSA-N 0.000 description 1
235000019441 ethanol Nutrition 0.000 description 1
239000008187 granular material Substances 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
KTOXGWMDJYFBKK-UHFFFAOYSA-L manganese(2+);diacetate;dihydrate Chemical compound O.O.[Mn+2].CC([O-])=O.CC([O-])=O KTOXGWMDJYFBKK-UHFFFAOYSA-L 0.000 description 1
239000006224 matting agent Substances 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
238000006864 oxidative decomposition reaction Methods 0.000 description 1
150000003017 phosphorus Chemical class 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
239000003440 toxic substance Substances 0.000 description 1
239000002351 wastewater Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
- C08G63/86—Germanium, antimony, or compounds thereof
- C08G63/863—Germanium or compounds thereof

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyesters Or Polycarbonates (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

SK2827-92A 1991-01-16 1992-01-14 Spôsob prípravy polyesteru SK279697B6 (sk)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CH10791		1991-01-16
PCT/CH1992/000007 WO1992013022A1 (de)	1991-01-16	1992-01-14	Verfahren zur herstellung eines polyesters, einen polyester sowie dessen verwendung

Publications (1)

Publication Number	Publication Date
SK279697B6 true SK279697B6 (sk)	1999-02-11

Family

ID=4179434

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK2827-92A SK279697B6 (sk)	1991-01-16	1992-01-14	Spôsob prípravy polyesteru

Country Status (15)

Country	Link
EP (1)	EP0520051B1 (cs)
JP (1)	JP2693038B2 (cs)
KR (1)	KR100210220B1 (cs)
AT (1)	ATE145656T1 (cs)
AU (1)	AU652418B2 (cs)
BR (1)	BR9204103A (cs)
CA (1)	CA2077997A1 (cs)
CS (1)	CS282792A3 (cs)
DE (1)	DE59207572D1 (cs)
HU (1)	HU212900B (cs)
PL (1)	PL168199B1 (cs)
RU (1)	RU2086573C1 (cs)
SK (1)	SK279697B6 (cs)
TR (1)	TR27025A (cs)
WO (1)	WO1992013022A1 (cs)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP3248348B2 (ja) *	1994-03-15	2002-01-21	松下電器産業株式会社	通信方法及び通信装置
BG100572A (en) *	1995-06-01	1996-12-31	Enichem S.P.A.	Low speed crystallization polyesters and catalytic system for their preparation
GB9725419D0 (en) *	1997-12-02	1998-01-28	Tioxide Specialties Ltd	Esterification catalysts
US6699545B2 (en) *	2001-12-21	2004-03-02	E. I. Du Pont De Nemours And Company	Method for increasing solid state polymerization rate of polyester polymers
US6953768B2 (en) *	2002-11-26	2005-10-11	Teck Cominco Metals Ltd.	Multi-component catalyst system for the polycondensation manufacture of polyesters
CZ303857B6 (cs) *	2012-01-23	2013-05-29	Technická univerzita v Liberci	Zpusob chemické recyklace polyethylentereftalátu (PET) a zpusob výroby nanovláken z aromaticko-alifatických kopolyesteru získaných tímto zpusobem

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1274858A (en) *	1968-11-29	1972-05-17	Agfa Gevaert	Improvements in the manufacture of polyesters
JPS4843669A (cs) *	1971-10-04	1973-06-23
DE2811982A1 (de) *	1978-03-18	1979-09-27	Huels Chemische Werke Ag	Verfahren zur herstellung von hochmolekularem poly(ethylenterephthalat)
FR2570077B1 (fr) *	1984-09-11	1987-05-29	Rhone Poulenc Films	Procede de preparation de polyester
PL306375A1 (en) *	1992-04-27	1995-03-20	Schweizerische Viscose	Method of obtaining a polyester and application thereof

1992
- 1992-01-14 KR KR1019920702223A patent/KR100210220B1/ko not_active Expired - Fee Related
- 1992-01-14 HU HU9202940A patent/HU212900B/hu not_active IP Right Cessation
- 1992-01-14 SK SK2827-92A patent/SK279697B6/sk unknown
- 1992-01-14 PL PL92296093A patent/PL168199B1/pl unknown
- 1992-01-14 BR BR929204103A patent/BR9204103A/pt not_active IP Right Cessation
- 1992-01-14 WO PCT/CH1992/000007 patent/WO1992013022A1/de not_active Ceased
- 1992-01-14 CA CA002077997A patent/CA2077997A1/en not_active Abandoned
- 1992-01-14 RU SU925053138A patent/RU2086573C1/ru active
- 1992-01-14 AU AU11589/92A patent/AU652418B2/en not_active Ceased
- 1992-01-14 EP EP92901742A patent/EP0520051B1/de not_active Expired - Lifetime
- 1992-01-14 DE DE59207572T patent/DE59207572D1/de not_active Expired - Fee Related
- 1992-01-14 AT AT92901742T patent/ATE145656T1/de not_active IP Right Cessation
- 1992-01-14 JP JP4502036A patent/JP2693038B2/ja not_active Expired - Lifetime
- 1992-04-17 TR TR00381/92A patent/TR27025A/xx unknown
- 1992-09-14 CS CS922827A patent/CS282792A3/cs unknown

Also Published As

Publication number	Publication date
EP0520051B1 (de)	1996-11-27
AU652418B2 (en)	1994-08-25
EP0520051A1 (de)	1992-12-30
JPH05505418A (ja)	1993-08-12
HU9202940D0 (en)	1992-11-30
CA2077997A1 (en)	1992-07-17
ATE145656T1 (de)	1996-12-15
RU2086573C1 (ru)	1997-08-10
BR9204103A (pt)	1993-06-08
JP2693038B2 (ja)	1997-12-17
KR100210220B1 (ko)	1999-07-15
AU1158992A (en)	1992-08-27
KR937000574A (ko)	1993-03-15
TR27025A (tr)	1994-10-10
DE59207572D1 (de)	1997-01-09
CS282792A3 (en)	1992-12-16
HUT62620A (en)	1993-05-28
PL168199B1 (pl)	1996-01-31
HU212900B (en)	1996-12-30
WO1992013022A1 (de)	1992-08-06
PL296093A1 (en)	1993-11-15

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US5417908A (en)	1995-05-23	Process for the preparation of polyester, a polyester and its use
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