SK280902B6 - Vo vode dispergovateľný granulárny herbicídny prostriedok a spôsob jeho výroby - Google Patents

Vo vode dispergovateľný granulárny herbicídny prostriedok a spôsob jeho výroby Download PDF

Info

Publication number: SK280902B6
Authority: SK; Slovakia
Prior art keywords: weight; water; herbicidal composition; herbicide; carbon atoms
Prior art date: 1992-12-23

Application number

SK1430-93A

Other languages

English (en)

Slovak (sk)

Other versions

SK143093A3 (en

Inventor

Joseph Kimler

Robert Kubisch

Original Assignee

American Cyanamid Company

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-12-23

Filing date

1993-12-15

Publication date

2000-09-12

1993-12-15 Application filed by American Cyanamid Company filed Critical American Cyanamid Company

1994-07-06 Publication of SK143093A3 publication Critical patent/SK143093A3/sk

2000-09-12 Publication of SK280902B6 publication Critical patent/SK280902B6/sk

Links

239000000203 mixture Substances 0.000 title claims abstract description 74
230000002363 herbicidal effect Effects 0.000 title claims abstract description 35
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 18
239000004009 herbicide Substances 0.000 claims abstract description 31
LZGUHMNOBNWABZ-UHFFFAOYSA-N n-nitro-n-phenylnitramide Chemical compound [O-][N+](=O)N([N+]([O-])=O)C1=CC=CC=C1 LZGUHMNOBNWABZ-UHFFFAOYSA-N 0.000 claims abstract description 14
CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical compound O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 claims abstract description 13
239000003795 chemical substances by application Substances 0.000 claims abstract description 13
239000000080 wetting agent Substances 0.000 claims abstract description 11
239000000969 carrier Substances 0.000 claims abstract description 10
239000000375 suspending agent Substances 0.000 claims abstract description 10
238000000034 method Methods 0.000 claims abstract description 9
239000002585 base Substances 0.000 claims abstract description 7
238000002156 mixing Methods 0.000 claims abstract description 7
CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 claims abstract description 6
239000005981 Imazaquin Substances 0.000 claims abstract description 5
CLQMBPJKHLGMQK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=CC=C1C(O)=O CLQMBPJKHLGMQK-UHFFFAOYSA-N 0.000 claims abstract description 4
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims abstract description 3
150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract 2
150000001412 amines Chemical class 0.000 claims abstract 2
239000003507 refrigerant Substances 0.000 claims abstract 2
239000006185 dispersion Substances 0.000 claims description 14
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 12
125000004432 carbon atom Chemical group C* 0.000 claims description 12
239000000440 bentonite Substances 0.000 claims description 11
229910000278 bentonite Inorganic materials 0.000 claims description 11
229920000642 polymer Polymers 0.000 claims description 10
-1 nortronite Inorganic materials 0.000 claims description 9
239000000463 material Substances 0.000 claims description 6
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 5
125000001309 chloro group Chemical group Cl* 0.000 claims description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
239000000126 substance Substances 0.000 claims description 4
PVSGXWMWNRGTKE-UHFFFAOYSA-N 5-methyl-2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]pyridine-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=C(C)C=C1C(O)=O PVSGXWMWNRGTKE-UHFFFAOYSA-N 0.000 claims description 3
239000002518 antifoaming agent Substances 0.000 claims description 2
239000000460 chlorine Substances 0.000 claims description 2
229910052801 chlorine Inorganic materials 0.000 claims description 2
229920001519 homopolymer Polymers 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
229910000275 saponite Inorganic materials 0.000 claims description 2
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 abstract description 5
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract description 3
238000001035 drying Methods 0.000 abstract description 3
229910052901 montmorillonite Inorganic materials 0.000 abstract description 2
125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
125000003342 alkenyl group Chemical group 0.000 abstract 2
125000000304 alkynyl group Chemical group 0.000 abstract 2
238000003801 milling Methods 0.000 abstract 2
125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
235000012216 bentonite Nutrition 0.000 description 11
239000008187 granular material Substances 0.000 description 11
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
238000009472 formulation Methods 0.000 description 5
238000002844 melting Methods 0.000 description 5
230000008018 melting Effects 0.000 description 5
239000004480 active ingredient Substances 0.000 description 4
CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
238000012360 testing method Methods 0.000 description 4
229920002785 Croscarmellose sodium Polymers 0.000 description 3
239000005591 Pendimethalin Substances 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 3
239000004927 clay Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 3
239000004562 water dispersible granule Substances 0.000 description 3
SQAINHDHICKHLX-UHFFFAOYSA-N 1-naphthaldehyde Chemical compound C1=CC=C2C(C=O)=CC=CC2=C1 SQAINHDHICKHLX-UHFFFAOYSA-N 0.000 description 2
CGNBQYFXGQHUQP-UHFFFAOYSA-N 2,3-dinitroaniline Chemical class NC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O CGNBQYFXGQHUQP-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
244000025254 Cannabis sativa Species 0.000 description 2
241000196324 Embryophyta Species 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
229920000168 Microcrystalline cellulose Polymers 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000000378 calcium silicate Substances 0.000 description 2
229910052918 calcium silicate Inorganic materials 0.000 description 2
239000002826 coolant Substances 0.000 description 2
229960001681 croscarmellose sodium Drugs 0.000 description 2
235000010947 crosslinked sodium carboxy methyl cellulose Nutrition 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
238000000227 grinding Methods 0.000 description 2
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
235000019813 microcrystalline cellulose Nutrition 0.000 description 2
239000008108 microcrystalline cellulose Substances 0.000 description 2
229940016286 microcrystalline cellulose Drugs 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
230000008961 swelling Effects 0.000 description 2
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
230000007306 turnover Effects 0.000 description 2
LQIAZOCLNBBZQK-UHFFFAOYSA-N 1-(1,2-Diphosphanylethyl)pyrrolidin-2-one Chemical compound PCC(P)N1CCCC1=O LQIAZOCLNBBZQK-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
239000005471 Benfluralin Substances 0.000 description 1
239000004135 Bone phosphate Substances 0.000 description 1
XVOKUMIPKHGGTN-UHFFFAOYSA-N Imazethapyr Chemical compound OC(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 XVOKUMIPKHGGTN-UHFFFAOYSA-N 0.000 description 1
NEKOXWSIMFDGMA-UHFFFAOYSA-N Isopropalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(C)C)C=C1[N+]([O-])=O NEKOXWSIMFDGMA-UHFFFAOYSA-N 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000005599 alkyl carboxylate group Chemical group 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
SMDHCQAYESWHAE-UHFFFAOYSA-N benfluralin Chemical compound CCCCN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O SMDHCQAYESWHAE-UHFFFAOYSA-N 0.000 description 1
OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
229940063834 carboxymethylcellulose sodium Drugs 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
239000012050 conventional carrier Substances 0.000 description 1
239000003599 detergent Substances 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
239000007884 disintegrant Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000004495 emulsifiable concentrate Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000003517 fume Substances 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
229910052622 kaolinite Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000012669 liquid formulation Substances 0.000 description 1
239000006194 liquid suspension Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
CRVVHBFLWWQMPT-UHFFFAOYSA-N naphthalene-1-sulfonic acid;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 CRVVHBFLWWQMPT-UHFFFAOYSA-N 0.000 description 1
229910000273 nontronite Inorganic materials 0.000 description 1
UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 description 1
UNAHYJYOSSSJHH-UHFFFAOYSA-N oryzalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(S(N)(=O)=O)C=C1[N+]([O-])=O UNAHYJYOSSSJHH-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000000361 pesticidal effect Effects 0.000 description 1
229910000160 potassium phosphate Inorganic materials 0.000 description 1
235000011009 potassium phosphates Nutrition 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000012216 screening Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
229920005552 sodium lignosulfonate Polymers 0.000 description 1
229940045905 sodium tallowate Drugs 0.000 description 1
HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
239000004557 technical material Substances 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds

Landscapes

Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Dentistry (AREA)
Plant Pathology (AREA)
Engineering & Computer Science (AREA)
Pest Control & Pesticides (AREA)
Agronomy & Crop Science (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Toxicology (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Glanulating (AREA)
Fertilizers (AREA)

SK1430-93A 1992-12-23 1993-12-15 Vo vode dispergovateľný granulárny herbicídny prostriedok a spôsob jeho výroby SK280902B6 (sk)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/996,412 US5296450A (en)	1992-12-23	1992-12-23	Water dispersible granular herbicidal compositions comprising dinitroaniline herbicides, montmorillonite carrier, and a base

Publications (2)

Publication Number	Publication Date
SK143093A3 SK143093A3 (en)	1994-07-06
SK280902B6 true SK280902B6 (sk)	2000-09-12

Family

ID=25542885

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK1430-93A SK280902B6 (sk)	1992-12-23	1993-12-15	Vo vode dispergovateľný granulárny herbicídny prostriedok a spôsob jeho výroby

Country Status (19)

Country	Link
US (1)	US5296450A (da)
EP (1)	EP0604906B1 (da)
JP (1)	JP3360293B2 (da)
KR (1)	KR100284118B1 (da)
AT (1)	ATE180383T1 (da)
AU (1)	AU668779B2 (da)
BR (1)	BR9305193A (da)
CZ (1)	CZ284787B6 (da)
DE (1)	DE69325085T2 (da)
DK (1)	DK0604906T3 (da)
ES (1)	ES2132169T3 (da)
GR (1)	GR3030929T3 (da)
HU (1)	HU214222B (da)
IL (1)	IL108102A (da)
NZ (1)	NZ250542A (da)
RU (1)	RU2137366C1 (da)
SK (1)	SK280902B6 (da)
TW (1)	TW264373B (da)
ZA (1)	ZA939630B (da)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1070338C (zh) *	1993-03-19	2001-09-05	纽法姆澳大利亚有限公司	固体、可分散于水的、橙色稳定的氟乐灵制剂
US5696024A (en) *	1995-06-06	1997-12-09	American Cyanmid	Herbicidal water soluble granular compositions
US5629261A (en) *	1995-08-08	1997-05-13	Isp Investments Inc.	Free-flowing, non-dusting water dispersible granules of a water-insoluble, hydrophobic agriculturally active chemical having low friability and superior crush strength
FR2791869A1 (fr) *	1999-04-09	2000-10-13	American Cyanamid Co	Procede et composition pour la lutte synergique contre des plantes indesirables
JP4932096B2 (ja) *	2001-07-27	2012-05-16	株式会社エス・ディー・エスバイオテック	除草活性成分を含有する顆粒水和剤及びその製造方法
RU2217913C1 (ru) *	2002-05-23	2003-12-10	Государственное учреждение "Научно-исследовательский технологический институт гербицидов и регуляторов роста растений с опытно-экспериментальным производством"	Гербицидный суспоэмульсионный концентрат
US8288320B2 (en) *	2007-10-04	2012-10-16	Oms Investments, Inc.	Methods for preparing granular weed control products having improved distribution of agriculturally active ingredients coated thereon
CA2714065A1 (en) *	2008-02-05	2009-08-13	Arysta Lifescience North America, Llc	Solid formulation of low melting active compound

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4007258A (en) *	1973-09-10	1977-02-08	Union Corporation	Sustained release pesticidal composition
DE2803991A1 (de) *	1977-02-05	1978-08-10	Fisons Ltd	Sulfonate, verfahren zu deren herstellung und herbizide zusammensetzungen
CA1209363A (en) *	1982-09-30	1986-08-12	Thomas M. Kaneko	Pesticide granules
US4511395A (en) *	1982-12-20	1985-04-16	American Cyanamid Company	Method for the preparation of water dispersible granular herbicidal compositions with increased thermal stability
DK147284A (da) *	1983-03-30	1984-10-01	Lilly Co Eli	Granulaert herbicidt praeparat
US4657582A (en) *	1985-05-30	1987-04-14	Pennwalt Corporation	Polyhydroxy polymer delivery systems
JP2515124B2 (ja) *	1987-08-25	1996-07-10	塩野義製薬株式会社	水分散性粒状組成物
JP2870541B2 (ja) *	1988-07-15	1999-03-17	アメリカン・サイアナミド・カンパニー	除草性粒状組成物
JP3069665B2 (ja) *	1990-03-15	2000-07-24	住友化学工業株式会社	農業用粒状水和剤組成物
RU2096955C1 (ru) *	1991-03-01	1997-11-27	Е.И.Дюпон Де Немур Энд Компани	Вододиспергируемая гранулированная пестицидная композиция, получаемая методом экструзии, и способ ее получения

1992
- 1992-12-23 US US07/996,412 patent/US5296450A/en not_active Expired - Lifetime
1993
- 1993-11-23 TW TW082109859A patent/TW264373B/zh active
- 1993-12-08 CZ CZ932678A patent/CZ284787B6/cs not_active IP Right Cessation
- 1993-12-15 SK SK1430-93A patent/SK280902B6/sk not_active IP Right Cessation
- 1993-12-20 IL IL108102A patent/IL108102A/xx not_active IP Right Cessation
- 1993-12-20 JP JP34458093A patent/JP3360293B2/ja not_active Expired - Fee Related
- 1993-12-21 NZ NZ250542A patent/NZ250542A/en not_active IP Right Cessation
- 1993-12-22 RU RU93057731A patent/RU2137366C1/ru not_active IP Right Cessation
- 1993-12-22 HU HU9303719A patent/HU214222B/hu not_active IP Right Cessation
- 1993-12-22 KR KR1019930029021A patent/KR100284118B1/ko not_active Expired - Fee Related
- 1993-12-22 ZA ZA939630A patent/ZA939630B/xx unknown
- 1993-12-22 AU AU52643/93A patent/AU668779B2/en not_active Ceased
- 1993-12-22 BR BR9305193A patent/BR9305193A/pt not_active IP Right Cessation
- 1993-12-23 DK DK93120784T patent/DK0604906T3/da active
- 1993-12-23 DE DE69325085T patent/DE69325085T2/de not_active Expired - Fee Related
- 1993-12-23 ES ES93120784T patent/ES2132169T3/es not_active Expired - Lifetime
- 1993-12-23 AT AT93120784T patent/ATE180383T1/de not_active IP Right Cessation
- 1993-12-23 EP EP93120784A patent/EP0604906B1/en not_active Expired - Lifetime
1999
- 1999-08-06 GR GR990402010T patent/GR3030929T3/el unknown

Also Published As

Publication number	Publication date
IL108102A0 (en)	1994-04-12
HU214222B (hu)	1998-01-28
CZ267893A3 (en)	1994-07-13
RU2137366C1 (ru)	1999-09-20
AU668779B2 (en)	1996-05-16
JPH06199610A (ja)	1994-07-19
US5296450A (en)	1994-03-22
ATE180383T1 (de)	1999-06-15
NZ250542A (en)	1995-10-26
KR940013328A (ko)	1994-07-15
EP0604906A1 (en)	1994-07-06
TW264373B (da)	1995-12-01
SK143093A3 (en)	1994-07-06
DE69325085D1 (de)	1999-07-01
CZ284787B6 (cs)	1999-03-17
KR100284118B1 (ko)	2001-04-02
GR3030929T3 (en)	1999-11-30
EP0604906B1 (en)	1999-05-26
JP3360293B2 (ja)	2002-12-24
HK1013217A1 (en)	1999-08-20
DE69325085T2 (de)	1999-09-30
BR9305193A (pt)	1994-06-28
ZA939630B (en)	1994-08-15
IL108102A (en)	1997-09-30
ES2132169T3 (es)	1999-08-16
DK0604906T3 (da)	1999-11-08
AU5264393A (en)	1994-07-07
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Publication	Publication Date	Title
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BR112021010244A2 (pt)	2021-08-17	formulação inseticida para o controle de vetor e praga com eficácia de contato aumentada
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