SK460090A3 - Catalytic agent for polymerization of olefins - Google Patents

Catalytic agent for polymerization of olefins Download PDF

Info

Publication number: SK460090A3
Authority: SK; Slovakia
Prior art keywords: polymerization; catalyst; tert; alkyl; catalyst composition
Prior art date: 1989-09-21

Application number

SK4600-90A

Other languages

English (en)

Slovak (sk)

Other versions

SK279025B6 (sk

Inventor

Charles R Hoppin

Benjamin S Tovrog

Original Assignee

Amoco Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-09-21

Filing date

1990-09-21

Publication date

1998-05-06

1990-09-21 Application filed by Amoco Corp filed Critical Amoco Corp

1998-05-06 Publication of SK279025B6 publication Critical patent/SK279025B6/sk

1998-05-06 Publication of SK460090A3 publication Critical patent/SK460090A3/sk

Links

150000001336 alkenes Chemical class 0.000 title claims abstract description 12
238000006116 polymerization reaction Methods 0.000 title description 49
230000003197 catalytic effect Effects 0.000 title description 4
-1 alkyl aluminum compound Chemical class 0.000 claims abstract description 43
239000010936 titanium Substances 0.000 claims abstract description 43
229910052719 titanium Inorganic materials 0.000 claims abstract description 31
239000011777 magnesium Substances 0.000 claims abstract description 28
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 24
229910052749 magnesium Inorganic materials 0.000 claims abstract description 23
239000007787 solid Substances 0.000 claims abstract description 12
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 8
239000002685 polymerization catalyst Substances 0.000 claims abstract description 6
239000003054 catalyst Substances 0.000 claims description 69
239000000203 mixture Substances 0.000 claims description 35
125000004432 carbon atom Chemical group C* 0.000 claims description 25
125000000217 alkyl group Chemical group 0.000 claims description 20
150000001875 compounds Chemical class 0.000 claims description 9
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 4
PBDYQPOAXBEPJI-UHFFFAOYSA-N CCCCO[SiH](OC)OC Chemical class CCCCO[SiH](OC)OC PBDYQPOAXBEPJI-UHFFFAOYSA-N 0.000 claims description 3
AQPCDBILXLZJIX-UHFFFAOYSA-N tert-butyl-dimethoxy-[(2-methylpropan-2-yl)oxy]silane Chemical compound CO[Si](OC)(C(C)(C)C)OC(C)(C)C AQPCDBILXLZJIX-UHFFFAOYSA-N 0.000 claims description 3
DCTQUAARZIKYLB-UHFFFAOYSA-N 2,2-dimethylpropyl-dimethoxy-[(2-methylpropan-2-yl)oxy]silane Chemical compound CC(C)(C)C[Si](OC)(OC)OC(C)(C)C DCTQUAARZIKYLB-UHFFFAOYSA-N 0.000 claims description 2
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
LRFNMLCCLJJFRM-UHFFFAOYSA-N cyclohexyl-dimethoxy-[(2-methylpropan-2-yl)oxy]silane Chemical compound CC(C)(C)O[Si](OC)(OC)C1CCCCC1 LRFNMLCCLJJFRM-UHFFFAOYSA-N 0.000 claims 1
SATOQMZHIOYKGM-UHFFFAOYSA-N dimethoxy-[(2-methylpropan-2-yl)oxy]-propan-2-ylsilane Chemical compound CO[Si](OC)(C(C)C)OC(C)(C)C SATOQMZHIOYKGM-UHFFFAOYSA-N 0.000 claims 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 16
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 44
229920000642 polymer Polymers 0.000 description 22
239000000047 product Substances 0.000 description 16
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 14
239000007788 liquid Substances 0.000 description 14
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 14
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 14
229910000077 silane Inorganic materials 0.000 description 14
238000009826 distribution Methods 0.000 description 12
239000003607 modifier Substances 0.000 description 9
239000000126 substance Substances 0.000 description 9
239000011701 zinc Substances 0.000 description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
229910052782 aluminium Inorganic materials 0.000 description 8
229910052799 carbon Inorganic materials 0.000 description 8
239000002841 Lewis acid Substances 0.000 description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
150000002148 esters Chemical class 0.000 description 7
238000012685 gas phase polymerization Methods 0.000 description 7
239000001257 hydrogen Substances 0.000 description 7
229910052739 hydrogen Inorganic materials 0.000 description 7
150000007517 lewis acids Chemical class 0.000 description 7
239000000178 monomer Substances 0.000 description 7
150000001282 organosilanes Chemical class 0.000 description 7
239000004711 α-olefin Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
125000005234 alkyl aluminium group Chemical group 0.000 description 6
239000000460 chlorine Substances 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
239000003085 diluting agent Substances 0.000 description 6
239000000463 material Substances 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
238000000034 method Methods 0.000 description 6
150000007524 organic acids Chemical class 0.000 description 6
235000005985 organic acids Nutrition 0.000 description 6
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
239000007795 chemical reaction product Substances 0.000 description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
150000004756 silanes Chemical class 0.000 description 4
239000011949 solid catalyst Substances 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
229920001585 atactic polymer Polymers 0.000 description 3
238000007906 compression Methods 0.000 description 3
230000006835 compression Effects 0.000 description 3
HKMWUVMCBHGIEB-UHFFFAOYSA-N dimethoxy-[(2-methylpropan-2-yl)oxy]-(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(OC)OC(C)(C)C HKMWUVMCBHGIEB-UHFFFAOYSA-N 0.000 description 3
NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000002245 particle Substances 0.000 description 3
231100000614 poison Toxicity 0.000 description 3
229920001155 polypropylene Polymers 0.000 description 3
229910052710 silicon Inorganic materials 0.000 description 3
239000007858 starting material Substances 0.000 description 3
239000000725 suspension Substances 0.000 description 3
238000010557 suspension polymerization reaction Methods 0.000 description 3
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
229910001868 water Inorganic materials 0.000 description 3
229910052725 zinc Inorganic materials 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
101100025412 Arabidopsis thaliana XI-A gene Proteins 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 2
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
UUGLJVMIFJNVFH-UHFFFAOYSA-N Hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1 UUGLJVMIFJNVFH-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
125000005907 alkyl ester group Chemical group 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
238000005452 bending Methods 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
238000010924 continuous production Methods 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
150000001991 dicarboxylic acids Chemical class 0.000 description 2
FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
239000012632 extractable Substances 0.000 description 2
239000007789 gas Substances 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
239000012535 impurity Substances 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
229910001507 metal halide Inorganic materials 0.000 description 2
QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
150000007522 mineralic acids Chemical class 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
150000002902 organometallic compounds Chemical class 0.000 description 2
239000012071 phase Substances 0.000 description 2
239000002574 poison Substances 0.000 description 2
229920013639 polyalphaolefin Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 2
239000010703 silicon Substances 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000002002 slurry Substances 0.000 description 2
238000012721 stereospecific polymerization Methods 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
150000003609 titanium compounds Chemical class 0.000 description 2
JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 1
HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
ABYCGAKJMGFSPY-UHFFFAOYSA-N 2-hexan-3-yloxycarbonylbenzoic acid Chemical compound CCCC(CC)OC(=O)C1=CC=CC=C1C(O)=O ABYCGAKJMGFSPY-UHFFFAOYSA-N 0.000 description 1
DUAYDERMVQWIJD-UHFFFAOYSA-N 2-n,2-n,6-trimethyl-1,3,5-triazine-2,4-diamine Chemical compound CN(C)C1=NC(C)=NC(N)=N1 DUAYDERMVQWIJD-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
RVDLHGSZWAELAU-UHFFFAOYSA-N 5-tert-butylthiophene-2-carbonyl chloride Chemical compound CC(C)(C)C1=CC=C(C(Cl)=O)S1 RVDLHGSZWAELAU-UHFFFAOYSA-N 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
229910006113 GeCl4 Inorganic materials 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
229910003910 SiCl4 Inorganic materials 0.000 description 1
229910003074 TiCl4 Inorganic materials 0.000 description 1
229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
150000004703 alkoxides Chemical group 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
125000004104 aryloxy group Chemical group 0.000 description 1
KYZHGEFMXZOSJN-UHFFFAOYSA-N benzoic acid isobutyl ester Natural products CC(C)COC(=O)C1=CC=CC=C1 KYZHGEFMXZOSJN-UHFFFAOYSA-N 0.000 description 1
SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
ABZISLDDVVJFKA-UHFFFAOYSA-N butan-2-yl-dimethoxy-[(2-methylpropan-2-yl)oxy]silane Chemical compound CCC(C)[Si](OC)(OC)OC(C)(C)C ABZISLDDVVJFKA-UHFFFAOYSA-N 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
150000004770 chalcogenides Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
150000001924 cycloalkanes Chemical class 0.000 description 1
DQZKGSRJOUYVPL-UHFFFAOYSA-N cyclohexyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1CCCCC1 DQZKGSRJOUYVPL-UHFFFAOYSA-N 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
238000004821 distillation Methods 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229940052296 esters of benzoic acid for local anesthesia Drugs 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
NBBSIMLSNFENNF-UHFFFAOYSA-N ethyl 2,6-dimethylbenzoate Chemical compound CCOC(=O)C1=C(C)C=CC=C1C NBBSIMLSNFENNF-UHFFFAOYSA-N 0.000 description 1
BIHHBTVQFPVSTE-UHFFFAOYSA-N ethyl 2-bromobenzoate Chemical compound CCOC(=O)C1=CC=CC=C1Br BIHHBTVQFPVSTE-UHFFFAOYSA-N 0.000 description 1
RETLCWPMLJPOTP-UHFFFAOYSA-N ethyl 2-chlorobenzoate Chemical compound CCOC(=O)C1=CC=CC=C1Cl RETLCWPMLJPOTP-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000007380 fibre production Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
OAFMYIADTCIEFV-UHFFFAOYSA-N hexane;triethylalumane Chemical compound CCCCCC.CC[Al](CC)CC OAFMYIADTCIEFV-UHFFFAOYSA-N 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000004678 hydrides Chemical group 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000000155 melt Substances 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
SWGQITQOBPXVRC-UHFFFAOYSA-N methyl 2-bromobenzoate Chemical compound COC(=O)C1=CC=CC=C1Br SWGQITQOBPXVRC-UHFFFAOYSA-N 0.000 description 1
229940095102 methyl benzoate Drugs 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
125000004043 oxo group Chemical group O=* 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
125000004437 phosphorous atom Chemical group 0.000 description 1
FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
230000007096 poisonous effect Effects 0.000 description 1
238000010094 polymer processing Methods 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
239000003380 propellant Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
230000000707 stereoselective effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 1
IEXRMSFAVATTJX-UHFFFAOYSA-N tetrachlorogermane Chemical compound Cl[Ge](Cl)(Cl)Cl IEXRMSFAVATTJX-UHFFFAOYSA-N 0.000 description 1
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
238000005303 weighing Methods 0.000 description 1
238000004260 weight control Methods 0.000 description 1
230000004580 weight loss Effects 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

SK4600-90A 1989-09-21 1990-09-21 Catalytic agent for polymerization of olefins SK460090A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/410,663 US4990478A (en)	1989-09-21	1989-09-21	Silane-modified supported polyolefin catalyst to produce a broadened molecular weight distribution product

Publications (2)

Publication Number	Publication Date
SK279025B6 SK279025B6 (sk)	1998-05-06
SK460090A3 true SK460090A3 (en)	1998-05-06

Family

ID=23625688

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK4600-90A SK460090A3 (en)	1989-09-21	1990-09-21	Catalytic agent for polymerization of olefins

Country Status (10)

Country	Link
US (1)	US4990478A (de)
EP (1)	EP0419249B1 (de)
JP (1)	JP2889674B2 (de)
AT (1)	ATE118791T1 (de)
CZ (1)	CZ284012B6 (de)
DE (1)	DE69017128T2 (de)
HU (1)	HU209774B (de)
PL (1)	PL165098B1 (de)
RU (1)	RU2114864C1 (de)
SK (1)	SK460090A3 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5034365A (en) *	1990-05-09	1991-07-23	Quantum Chemical Corporation	Silica supported polymerization catalyst
CA2040598A1 (en) *	1990-04-20	1991-10-21	Masatoshi Toda	Process for producing polyolefins
US5218052A (en) *	1991-02-04	1993-06-08	Amoco Corporation	Olefin polymerization and copolymerization process
US5767215A (en) *	1991-05-09	1998-06-16	Borealis Holding A/S	Coarse-grained polyolefin, its production method and a catalyst used in the method
JP2879391B2 (ja) *	1992-04-14	1999-04-05	昭和電工株式会社	オレフィン重合用触媒およびオレフィン重合体の製造法
US5693729A (en) *	1993-08-27	1997-12-02	Showa Denko K.K.	Catalyst for polymerization of olefin and process for the preparation of olefin polymer
US6133385A (en) *	1994-04-06	2000-10-17	Fina Technology, Inc.	Catalyst systems for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins
FR2728181B1 (fr)	1994-12-16	1997-01-31	Appryl Snc	Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
DE69600346T2 (de) *	1995-03-28	1998-12-17	Tonen Corp., Tokio/Tokyo	Katalysator für die Olefinpolymerisation und Verfahren zur Olefinpolymerisation unter Anwendung desselben
US6063727A (en) *	1996-12-19	2000-05-16	Japan Polyolefins Co., Ltd.	Catalyst for olefin polymerization and method for preparing polyolefins
KR100620358B1 (ko) *	2001-09-20	2006-09-05	삼성토탈 주식회사	강성, 내충격성, 내열성이 우수한 올레핀의 중합방법
JP4174425B2 (ja) *	2002-01-03	2008-10-29	イネオス・ユーエスエイ・エルエルシー	二重供与体触媒系を用いる気相オレフィン重合
CA2478105A1 (en) *	2002-03-04	2003-09-12	Akzo Nobel Nv	Treatment of a titanium tetrachloride-containing waste stream
DE60309020T2 (de) *	2002-05-29	2007-05-10	Basell Poliolefine Italia S.R.L.	Buten-1-(co)polymere und verfahren zu ihrer herstellung
RU2221813C1 (ru) *	2002-12-09	2004-01-20	Институт катализа им. Г.К.Борескова СО РАН	Способ приготовления катализатора и способ получения высокомолекулярных полиальфаолефинов с использованием этого катализатора
DE602004024994D1 (de) *	2003-06-24	2010-02-25	Union Carbide Chem Plastic	Katalysatorzusammensetzung und Polymerisationsverfahren mit einer Mischung von Silane Elektrondonoren
US7078468B2 (en) *	2003-06-27	2006-07-18	Fina Technology, Inc.	Polymerization catalyst system using di-sec-butyldimethoxysilane for preparation of polypropylene
RU2464282C2 (ru) *	2007-03-06	2012-10-20	ИНЕОС ЮЭсЭй ЭлЭлСи	Способ полимеризации олефинов
CN102746425B (zh)	2011-04-22	2014-04-02	中国石油天然气股份有限公司	一种含噻吩基取代硅烷的烯烃聚合反应催化剂

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6031504A (ja) *	1983-07-29	1985-02-18	Nippon Oil Co Ltd	ポリオレフインの製造方法
JPS60115603A (ja) *	1983-11-29	1985-06-22	Toa Nenryo Kogyo Kk	オレフインの重合方法
JPH0617400B2 (ja) *	1985-03-14	1994-03-09	チッソ株式会社	オレフインの重合方法
JPH06104693B2 (ja) *	1986-01-06	1994-12-21	東邦チタニウム株式会社	オレフイン類重合用触媒
JPH0735410B2 (ja) *	1986-01-31	1995-04-19	三菱油化株式会社	オレフィンの立体規則性重合用触媒
US4829038A (en) *	1986-06-17	1989-05-09	Amoco Corporation	Alpha-olefin polymerization catalyst system including an advantageous modifier component
KR940010330B1 (ko) *	1986-06-17	1994-10-22	아모코 코포레이션	유리한 개질제 성분을 포함하는 알파-올레핀 중합 촉매 시스템
US4814314A (en) *	1986-09-26	1989-03-21	Mitsubishi Petrochemical Company Limited	Catalyst for olefin polymerization
CA1306579C (en) *	1987-12-15	1992-08-18	Mamoru Kioka	Process for producing polypropylene and stretched polypropylene film

1989
- 1989-09-21 US US07/410,663 patent/US4990478A/en not_active Expired - Fee Related
1990
- 1990-09-19 JP JP2247638A patent/JP2889674B2/ja not_active Expired - Lifetime
- 1990-09-20 AT AT90310283T patent/ATE118791T1/de active
- 1990-09-20 EP EP90310283A patent/EP0419249B1/de not_active Expired - Lifetime
- 1990-09-20 RU SU4831127A patent/RU2114864C1/ru active
- 1990-09-20 HU HU905993A patent/HU209774B/hu not_active IP Right Cessation
- 1990-09-20 DE DE69017128T patent/DE69017128T2/de not_active Expired - Fee Related
- 1990-09-21 SK SK4600-90A patent/SK460090A3/sk unknown
- 1990-09-21 CZ CS904600A patent/CZ284012B6/cs not_active IP Right Cessation
- 1990-09-21 PL PL90286997A patent/PL165098B1/pl unknown

Also Published As

Publication number	Publication date
EP0419249A3 (en)	1991-11-27
DE69017128D1 (de)	1995-03-30
PL165098B1 (pl)	1994-11-30
SK279025B6 (sk)	1998-05-06
CZ460090A3 (en)	1997-12-17
EP0419249B1 (de)	1995-02-22
JP2889674B2 (ja)	1999-05-10
HU905993D0 (en)	1991-03-28
EP0419249A2 (de)	1991-03-27
DE69017128T2 (de)	1995-06-14
JPH03119004A (ja)	1991-05-21
ATE118791T1 (de)	1995-03-15
HU209774B (en)	1994-10-28
US4990478A (en)	1991-02-05
HUT56587A (en)	1991-09-30
PL286997A1 (en)	1991-05-06
CZ284012B6 (cs)	1998-07-15
RU2114864C1 (ru)	1998-07-10

Publication	Publication Date	Title
US4829038A (en)	1989-05-09	Alpha-olefin polymerization catalyst system including an advantageous modifier component
EP0250229B2 (de)	2002-10-02	Verfahren für alpha-Olefinpolymerisation
US4581342A (en)	1986-04-08	Supported olefin polymerization catalyst
SK460090A3 (en)	1998-05-06	Catalytic agent for polymerization of olefins
US4866022A (en)	1989-09-12	Olefin polymerization catalyst
US4988656A (en)	1991-01-29	Olefin polymerization catalyst
US5013702A (en)	1991-05-07	Olefin polymerization catalyst
CZ282716B6 (cs)	1997-09-17	Kompozice na bázi polymeru propylenu a způsob její výroby
WO1997014723A1 (en)	1997-04-24	Morphology-controlled olefin polymerization catalyst formed from an emulsion
EP0417346A1 (de)	1991-03-20	Verfahren zur Herstellung eines festen Katalysators zur Anwendung in der Olefinpolymerisation
US4159256A (en)	1979-06-26	Catalyst for polymerizing olefins and polymerization method of olefins carried out therewith
WO2002096957A1 (en)	2002-12-05	Olefin polymerization catalyst compositions and method of preparation
CA2128314C (en)	1997-09-30	Process for the production of polypropylene
EP0262987A2 (de)	1988-04-06	Katalysatoren für die Herstellung elastomerer Olefincopolymere und damit hergestellte Copolymere
CN101472681B (zh)	2012-09-26	烯烃聚合催化剂组分
USH1722H (en)	1998-04-07	Process for producing polypropylene impact block copolymers
US6051524A (en)	2000-04-18	Olefin polymerization and copolymerization catalyst
EP0361371A2 (de)	1990-04-04	Verfahren zur Herstellung von alpha-Olefinen
EP0489536A2 (de)	1992-06-10	Olefinpolymerisationkatalysator
JPH09194651A (ja)	1997-07-29	ポリプロピレン樹脂組成物
CA1320737C (en)	1993-07-27	Alpha-olefin polymerization catalyst system including an advantageous modifier component
US5498676A (en)	1996-03-12	Process for olefin polymerization
EP4476274A1 (de)	2024-12-18	Katalysatorkomponente
EP4469494A1 (de)	2024-12-04	Katalysatorzusammensetzung
CN120303311A (zh)	2025-07-11	催化剂组分