SK6682003A3 - Polymerization process - Google Patents

Info

Publication number

SK6682003A3

SK6682003A3 SK668-2003A SK6682003A SK6682003A3 SK 6682003 A3 SK6682003 A3 SK 6682003A3 SK 6682003 A SK6682003 A SK 6682003A SK 6682003 A3 SK6682003 A3 SK 6682003A3

Authority

SK

Slovakia

Prior art keywords

catalyst

group

catalyst component

compound

slurry

Prior art date

2000-12-04

Links

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• 238000006116 polymerization reaction Methods 0.000 title claims abstract description 106
• 239000003054 catalyst Substances 0.000 claims abstract description 649
• 238000000034 method Methods 0.000 claims abstract description 146
• 239000000203 mixture Substances 0.000 claims abstract description 126
• 239000002002 slurry Substances 0.000 claims abstract description 123
• 229920000642 polymer Polymers 0.000 claims abstract description 122
• 150000001875 compounds Chemical class 0.000 claims description 323
• 239000000243 solution Substances 0.000 claims description 203
• 239000012190 activator Substances 0.000 claims description 188
• 239000000725 suspension Substances 0.000 claims description 155
• 239000003446 ligand Substances 0.000 claims description 122
• -1 n-propylcyclopentadienyl Chemical group 0.000 claims description 107
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 93
• 229910052751 metal Inorganic materials 0.000 claims description 72
• 239000002184 metal Substances 0.000 claims description 72
• 230000008569 process Effects 0.000 claims description 68
• 239000007789 gas Substances 0.000 claims description 58
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 52
• 239000005977 Ethylene Substances 0.000 claims description 51
• 239000012968 metallocene catalyst Substances 0.000 claims description 51
• 239000001257 hydrogen Substances 0.000 claims description 49
• 229910052739 hydrogen Inorganic materials 0.000 claims description 49
• 125000004432 carbon atom Chemical group C* 0.000 claims description 45
• 239000000377 silicon dioxide Substances 0.000 claims description 45
• 125000005842 heteroatom Chemical group 0.000 claims description 41
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 35
• 239000000463 material Substances 0.000 claims description 35
• 239000002480 mineral oil Substances 0.000 claims description 34
• 235000010446 mineral oil Nutrition 0.000 claims description 34
• 230000000737 periodic effect Effects 0.000 claims description 34
• 239000007788 liquid Substances 0.000 claims description 33
• 229910052723 transition metal Inorganic materials 0.000 claims description 33
• 150000001336 alkenes Chemical class 0.000 claims description 31
• 238000002347 injection Methods 0.000 claims description 31
• 239000007924 injection Substances 0.000 claims description 31
• 150000003624 transition metals Chemical class 0.000 claims description 31
• 125000000217 alkyl group Chemical group 0.000 claims description 28
• 125000004429 atom Chemical group 0.000 claims description 27
• 239000007787 solid Substances 0.000 claims description 23
• 239000002904 solvent Substances 0.000 claims description 23
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 21
• 239000000155 melt Substances 0.000 claims description 21
• 229910052760 oxygen Inorganic materials 0.000 claims description 21
• 239000001301 oxygen Substances 0.000 claims description 21
• 229910052710 silicon Inorganic materials 0.000 claims description 21
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 20
• 229910052736 halogen Inorganic materials 0.000 claims description 20
• 150000002367 halogens Chemical class 0.000 claims description 20
• 150000002430 hydrocarbons Chemical group 0.000 claims description 20
• 239000010703 silicon Substances 0.000 claims description 20
• 238000009826 distribution Methods 0.000 claims description 19
• 239000000178 monomer Substances 0.000 claims description 18
• 150000001335 aliphatic alkanes Chemical class 0.000 claims description 17
• 239000012876 carrier material Substances 0.000 claims description 17
• 239000007921 spray Substances 0.000 claims description 17
• 230000003213 activating effect Effects 0.000 claims description 16
• 125000003118 aryl group Chemical group 0.000 claims description 16
• 239000006229 carbon black Substances 0.000 claims description 15
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 14
• 229910052698 phosphorus Inorganic materials 0.000 claims description 14
• 239000011574 phosphorus Substances 0.000 claims description 14
• 230000036961 partial effect Effects 0.000 claims description 13
• 125000000129 anionic group Chemical group 0.000 claims description 12
• 238000002156 mixing Methods 0.000 claims description 12
• 239000004215 Carbon black (E152) Substances 0.000 claims description 10
• 229910052732 germanium Inorganic materials 0.000 claims description 10
• GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 10
• 229930195733 hydrocarbon Natural products 0.000 claims description 10
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 10
• 239000003085 diluting agent Substances 0.000 claims description 9
• 230000003647 oxidation Effects 0.000 claims description 8
• 238000007254 oxidation reaction Methods 0.000 claims description 8
• 238000003756 stirring Methods 0.000 claims description 8
• ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
• 229910052718 tin Inorganic materials 0.000 claims description 6
• 125000006165 cyclic alkyl group Chemical group 0.000 claims description 5
• 125000003107 substituted aryl group Chemical group 0.000 claims description 5
• 125000003367 polycyclic group Chemical group 0.000 claims description 4
• 150000001491 aromatic compounds Chemical class 0.000 claims description 2
• 150000001924 cycloalkanes Chemical class 0.000 claims description 2
• 229920002545 silicone oil Polymers 0.000 claims description 2
• 150000002431 hydrogen Chemical class 0.000 claims 3
• 238000002844 melting Methods 0.000 claims 1
• 230000008018 melting Effects 0.000 claims 1
• 239000002685 polymerization catalyst Substances 0.000 abstract description 4
• 239000004743 Polypropylene Substances 0.000 description 121
• QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 83
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 73
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 56
• AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 41
• 229910052757 nitrogen Inorganic materials 0.000 description 41
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 39
• 239000002245 particle Substances 0.000 description 35
• LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 34
• CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 32
• 239000000047 product Substances 0.000 description 28
• 230000003197 catalytic effect Effects 0.000 description 27
• 238000004519 manufacturing process Methods 0.000 description 25
• NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 22
• 239000010936 titanium Substances 0.000 description 21
• 229910052782 aluminium Inorganic materials 0.000 description 20
• 229910052719 titanium Inorganic materials 0.000 description 17
• 229910052726 zirconium Inorganic materials 0.000 description 17
• QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 16
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 16
• 229920005989 resin Polymers 0.000 description 16
• 239000011347 resin Substances 0.000 description 16
• LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 15
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 15
• 125000004122 cyclic group Chemical group 0.000 description 15
• 229910052799 carbon Inorganic materials 0.000 description 14
• 229910052796 boron Inorganic materials 0.000 description 13
• ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 13
• 239000012530 fluid Substances 0.000 description 13
• 125000004435 hydrogen atom Chemical group [H]* 0.000 description 13
• 239000000843 powder Substances 0.000 description 13
• ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 12
• RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 11
• 229910007926 ZrCl Inorganic materials 0.000 description 11
• 230000002902 bimodal effect Effects 0.000 description 11
• 239000000460 chlorine Substances 0.000 description 11
• 230000007935 neutral effect Effects 0.000 description 11
• 238000001542 size-exclusion chromatography Methods 0.000 description 11
• 125000001424 substituent group Chemical group 0.000 description 11
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
• 125000005234 alkyl aluminium group Chemical group 0.000 description 10
• 239000002216 antistatic agent Substances 0.000 description 10
• 239000012159 carrier gas Substances 0.000 description 10
• 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 10
• 239000011148 porous material Substances 0.000 description 10
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 10
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 10
• YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 9
• STWBNOBMOCQPLR-UHFFFAOYSA-N 2-bromo-n-(2-hydroxy-5-nitrophenyl)acetamide Chemical compound OC1=CC=C([N+]([O-])=O)C=C1NC(=O)CBr STWBNOBMOCQPLR-UHFFFAOYSA-N 0.000 description 9
• 230000000694 effects Effects 0.000 description 9
• 229910052735 hafnium Inorganic materials 0.000 description 9
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
• 229920001155 polypropylene Polymers 0.000 description 9
• IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
• 230000004913 activation Effects 0.000 description 8
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
• 238000006243 chemical reaction Methods 0.000 description 8
• 238000001125 extrusion Methods 0.000 description 8
• 239000010419 fine particle Substances 0.000 description 8
• 238000005227 gel permeation chromatography Methods 0.000 description 8
• VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 8
• 150000002736 metal compounds Chemical class 0.000 description 8
• ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 8
• 230000001681 protective effect Effects 0.000 description 8
• 238000012360 testing method Methods 0.000 description 8
• MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 8
• RURFJXKOXIWFJX-UHFFFAOYSA-N (2,3,4,6-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C=C(F)C(F)=C1F RURFJXKOXIWFJX-UHFFFAOYSA-N 0.000 description 7
• 239000004698 Polyethylene Substances 0.000 description 7
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
• 239000007983 Tris buffer Substances 0.000 description 7
• 150000001450 anions Chemical class 0.000 description 7
• 239000004305 biphenyl Substances 0.000 description 7
• 235000010290 biphenyl Nutrition 0.000 description 7
• 239000000969 carrier Substances 0.000 description 7
• 125000002091 cationic group Chemical group 0.000 description 7
• 150000001768 cations Chemical class 0.000 description 7
• 230000008859 change Effects 0.000 description 7
• 229910052801 chlorine Inorganic materials 0.000 description 7
• 229920001577 copolymer Polymers 0.000 description 7
• 150000001993 dienes Chemical class 0.000 description 7
• 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 7
• 238000009616 inductively coupled plasma Methods 0.000 description 7
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 7
• 229910052696 pnictogen Inorganic materials 0.000 description 7
• 229920000573 polyethylene Polymers 0.000 description 7
• 230000003068 static effect Effects 0.000 description 7
• 229910052717 sulfur Inorganic materials 0.000 description 7
• JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 7
• 229910052720 vanadium Inorganic materials 0.000 description 7
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
• YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 6
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
• ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
• JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 6
• VVIYDDGGBMUXOF-UHFFFAOYSA-L dichlorozirconium(2+) Chemical compound Cl[Zr+2]Cl VVIYDDGGBMUXOF-UHFFFAOYSA-L 0.000 description 6
• 239000006185 dispersion Substances 0.000 description 6
• 239000011737 fluorine Substances 0.000 description 6
• 229910052731 fluorine Inorganic materials 0.000 description 6
• 239000011888 foil Substances 0.000 description 6
• 238000012685 gas phase polymerization Methods 0.000 description 6
• 150000004820 halides Chemical class 0.000 description 6
• 239000002667 nucleating agent Substances 0.000 description 6
• 238000002360 preparation method Methods 0.000 description 6
• 230000002829 reductive effect Effects 0.000 description 6
• LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 6
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
• 238000000441 X-ray spectroscopy Methods 0.000 description 5
• 125000003342 alkenyl group Chemical group 0.000 description 5
• 125000003545 alkoxy group Chemical group 0.000 description 5
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
• 230000015572 biosynthetic process Effects 0.000 description 5
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
• 229910052794 bromium Inorganic materials 0.000 description 5
• 125000001309 chloro group Chemical group Cl* 0.000 description 5
• 239000000945 filler Substances 0.000 description 5
• 150000008282 halocarbons Chemical group 0.000 description 5
• 229920001903 high density polyethylene Polymers 0.000 description 5
• 150000004678 hydrides Chemical class 0.000 description 5
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
• 150000002602 lanthanoids Chemical class 0.000 description 5
• 230000000670 limiting effect Effects 0.000 description 5
• 229920000092 linear low density polyethylene Polymers 0.000 description 5
• 125000002524 organometallic group Chemical group 0.000 description 5
• 150000003254 radicals Chemical class 0.000 description 5
• 229910001220 stainless steel Inorganic materials 0.000 description 5
• 239000010935 stainless steel Substances 0.000 description 5
• 239000000126 substance Substances 0.000 description 5
• 239000011593 sulfur Substances 0.000 description 5
• 239000011135 tin Substances 0.000 description 5
• GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 5
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
• 239000004711 α-olefin Substances 0.000 description 5
• BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 4
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
• 239000002841 Lewis acid Substances 0.000 description 4
• 239000002879 Lewis base Substances 0.000 description 4
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
• 229910052768 actinide Inorganic materials 0.000 description 4
• 150000001255 actinides Chemical class 0.000 description 4
• 239000000654 additive Substances 0.000 description 4
• 150000004703 alkoxides Chemical class 0.000 description 4
• UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 4
• 239000003795 chemical substances by application Substances 0.000 description 4
• DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
• 239000000835 fiber Substances 0.000 description 4
• 239000004700 high-density polyethylene Substances 0.000 description 4
• 229910052809 inorganic oxide Inorganic materials 0.000 description 4
• 229910052747 lanthanoid Inorganic materials 0.000 description 4
• 239000004707 linear low-density polyethylene Substances 0.000 description 4
• PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
• QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
• KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
• 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
• 238000010926 purge Methods 0.000 description 4
• 239000004071 soot Substances 0.000 description 4
• 238000001694 spray drying Methods 0.000 description 4
• 239000004094 surface-active agent Substances 0.000 description 4
• 239000000454 talc Substances 0.000 description 4
• 229910052623 talc Inorganic materials 0.000 description 4
• IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 4
• 238000011144 upstream manufacturing Methods 0.000 description 4
• KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 3
• VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
• OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
• 239000004793 Polystyrene Substances 0.000 description 3
• ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
• 239000002253 acid Substances 0.000 description 3
• 125000002015 acyclic group Chemical group 0.000 description 3
• CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 3
• 229940063655 aluminum stearate Drugs 0.000 description 3
• 150000001412 amines Chemical class 0.000 description 3
• 125000005239 aroylamino group Chemical group 0.000 description 3
• 125000003710 aryl alkyl group Chemical group 0.000 description 3
• 239000011230 binding agent Substances 0.000 description 3
• 238000000071 blow moulding Methods 0.000 description 3
• 238000007664 blowing Methods 0.000 description 3
• 150000007942 carboxylates Chemical class 0.000 description 3
• 229910052804 chromium Inorganic materials 0.000 description 3
• 239000011651 chromium Substances 0.000 description 3
• 125000000753 cycloalkyl group Chemical group 0.000 description 3
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
• IVTQDRJBWSBJQM-UHFFFAOYSA-L dichlorozirconium;indene Chemical compound C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)C1C2=CC=CC=C2C=C1 IVTQDRJBWSBJQM-UHFFFAOYSA-L 0.000 description 3
• 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
• 125000000623 heterocyclic group Chemical group 0.000 description 3
• 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
• 230000007062 hydrolysis Effects 0.000 description 3
• 238000006460 hydrolysis reaction Methods 0.000 description 3
• 239000003622 immobilized catalyst Substances 0.000 description 3
• 150000007517 lewis acids Chemical class 0.000 description 3
• 150000007527 lewis bases Chemical class 0.000 description 3
• 229920001684 low density polyethylene Polymers 0.000 description 3
• 239000004702 low-density polyethylene Substances 0.000 description 3
• 229910044991 metal oxide Inorganic materials 0.000 description 3
• 150000004706 metal oxides Chemical class 0.000 description 3
• PYLWMHQQBFSUBP-UHFFFAOYSA-N monofluorobenzene Chemical compound FC1=CC=CC=C1 PYLWMHQQBFSUBP-UHFFFAOYSA-N 0.000 description 3
• 238000000465 moulding Methods 0.000 description 3
• 239000007800 oxidant agent Substances 0.000 description 3
• 238000004806 packaging method and process Methods 0.000 description 3
• YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 3
• 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 3
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