SK86596A3 - Manufacturing process of amines from olefins on aluminium-beta-zeolites without transition metals and prepared without treatment with halogens - Google Patents

Manufacturing process of amines from olefins on aluminium-beta-zeolites without transition metals and prepared without treatment with halogens Download PDF

Info

Publication number: SK86596A3
Authority: SK; Slovakia
Prior art keywords: zeolite; amines; aluminum; formula; preparation
Prior art date: 1995-07-04

Application number

SK86596A

Other languages

English (en)

Slovak (sk)

Inventor

Uwe Dingerdissen

Rudolf Kummer

Peter Stops

Juergen Herrmann

Hans-Juergen Luetzel

Karsten Eller

Original Assignee

Basf Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-07-04

Filing date

1996-07-02

Publication date

1997-03-05

1996-07-02 Application filed by Basf Ag filed Critical Basf Ag

1997-03-05 Publication of SK86596A3 publication Critical patent/SK86596A3/sk

Links

239000010457 zeolite Substances 0.000 title claims abstract description 54
150000001412 amines Chemical class 0.000 title claims abstract description 25
150000001336 alkenes Chemical class 0.000 title claims abstract description 19
229910052736 halogen Inorganic materials 0.000 title claims abstract description 12
150000002367 halogens Chemical class 0.000 title claims abstract description 12
229910052723 transition metal Inorganic materials 0.000 title claims abstract description 6
150000003624 transition metals Chemical class 0.000 title claims abstract description 6
238000004519 manufacturing process Methods 0.000 title claims description 5
239000003054 catalyst Substances 0.000 claims abstract description 43
125000003118 aryl group Chemical group 0.000 claims abstract description 4
125000005119 alkyl cycloalkyl group Chemical group 0.000 claims abstract description 3
125000003710 aryl alkyl group Chemical group 0.000 claims abstract 2
229910021536 Zeolite Inorganic materials 0.000 claims description 32
238000000034 method Methods 0.000 claims description 19
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 18
230000008569 process Effects 0.000 claims description 17
239000000203 mixture Substances 0.000 claims description 15
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 14
238000006243 chemical reaction Methods 0.000 claims description 10
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 9
238000002360 preparation method Methods 0.000 claims description 9
229910052782 aluminium Inorganic materials 0.000 claims description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 4
229910017855 NH 4 F Inorganic materials 0.000 claims description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 4
LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 claims description 4
235000006408 oxalic acid Nutrition 0.000 claims description 4
150000003335 secondary amines Chemical class 0.000 claims description 4
239000007858 starting material Substances 0.000 claims description 4
239000002253 acid Substances 0.000 claims description 3
150000002431 hydrogen Chemical class 0.000 claims description 3
229920006395 saturated elastomer Polymers 0.000 claims description 3
229910052783 alkali metal Inorganic materials 0.000 claims description 2
150000001340 alkali metals Chemical class 0.000 claims description 2
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
150000001342 alkaline earth metals Chemical class 0.000 claims description 2
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
229910052791 calcium Inorganic materials 0.000 claims description 2
239000003153 chemical reaction reagent Substances 0.000 claims description 2
229910052749 magnesium Inorganic materials 0.000 claims description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
229910052761 rare earth metal Inorganic materials 0.000 claims description 2
150000002910 rare earth metals Chemical class 0.000 claims description 2
229910052708 sodium Inorganic materials 0.000 claims description 2
FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical compound CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 claims 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
229920002367 Polyisobutene Polymers 0.000 claims 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
239000011575 calcium Substances 0.000 claims 1
239000011777 magnesium Substances 0.000 claims 1
229910000510 noble metal Inorganic materials 0.000 claims 1
239000011591 potassium Substances 0.000 claims 1
239000011734 sodium Substances 0.000 claims 1
229910052716 thallium Inorganic materials 0.000 claims 1
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims 1
125000003342 alkenyl group Chemical group 0.000 abstract description 5
125000002947 alkylene group Chemical group 0.000 abstract description 3
125000001316 cycloalkyl alkyl group Chemical group 0.000 abstract description 3
125000000217 alkyl group Chemical group 0.000 abstract description 2
125000000753 cycloalkyl group Chemical group 0.000 abstract description 2
125000002877 alkyl aryl group Chemical group 0.000 abstract 1
125000000304 alkynyl group Chemical group 0.000 abstract 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 12
229910021529 ammonia Inorganic materials 0.000 description 11
238000001125 extrusion Methods 0.000 description 9
238000004898 kneading Methods 0.000 description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 7
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 6
235000019253 formic acid Nutrition 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
-1 Na and K Chemical class 0.000 description 5
230000004048 modification Effects 0.000 description 5
238000012986 modification Methods 0.000 description 5
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
238000005576 amination reaction Methods 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 4
230000007704 transition Effects 0.000 description 4
229920002472 Starch Polymers 0.000 description 3
238000004817 gas chromatography Methods 0.000 description 3
239000000047 product Substances 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
235000019698 starch Nutrition 0.000 description 3
239000008107 starch Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
229910004298 SiO 2 Inorganic materials 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
238000001354 calcination Methods 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000000605 extraction Methods 0.000 description 2
239000007789 gas Substances 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
239000008188 pellet Substances 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
229920000098 polyolefin Polymers 0.000 description 2
150000003141 primary amines Chemical class 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 1
125000004343 1-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C([H])([H])[H] 0.000 description 1
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
125000001622 2-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C(*)C([H])=C([H])C2=C1[H] 0.000 description 1
125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 1
125000004860 4-ethylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])C([H])([H])[H] 0.000 description 1
125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
229910002016 Aerosil® 200 Inorganic materials 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
125000004649 C2-C8 alkynyl group Chemical group 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
229910010413 TiO 2 Inorganic materials 0.000 description 1
238000007259 addition reaction Methods 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910001593 boehmite Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
230000002860 competitive effect Effects 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
238000005336 cracking Methods 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
NISGSNTVMOOSJQ-UHFFFAOYSA-N cyclopentanamine Chemical compound NC1CCCC1 NISGSNTVMOOSJQ-UHFFFAOYSA-N 0.000 description 1
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
238000006471 dimerization reaction Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000284 extract Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000010335 hydrothermal treatment Methods 0.000 description 1
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
150000005673 monoalkenes Chemical class 0.000 description 1
238000000465 moulding Methods 0.000 description 1
QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
238000006384 oligomerization reaction Methods 0.000 description 1
125000003884 phenylalkyl group Chemical group 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229910052573 porcelain Inorganic materials 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000005215 recombination Methods 0.000 description 1
230000006798 recombination Effects 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000012360 testing method Methods 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/60—Preparation of compounds containing amino groups bound to a carbon skeleton by condensation or addition reactions, e.g. Mannich reaction, addition of ammonia or amines to alkenes or to alkynes or addition of compounds containing an active hydrogen atom to Schiff's bases, quinone imines, or aziranes

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

SK86596A 1995-07-04 1996-07-02 Manufacturing process of amines from olefins on aluminium-beta-zeolites without transition metals and prepared without treatment with halogens SK86596A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE1995124241 DE19524241A1 (de)	1995-07-04	1995-07-04	Verfahren zur Herstellung von Aminen aus Olefinen an übergangsmetallfreien, ohne Halogenbehandlung hergestellten Aluminium-BETA-Zeolithen

Publications (1)

Publication Number	Publication Date
SK86596A3 true SK86596A3 (en)	1997-03-05

Family

ID=7765918

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK86596A SK86596A3 (en)	1995-07-04	1996-07-02	Manufacturing process of amines from olefins on aluminium-beta-zeolites without transition metals and prepared without treatment with halogens

Country Status (5)

Country	Link
EP (1)	EP0752410A3 (fr)
JP (1)	JPH09104660A (fr)
CZ (1)	CZ193796A3 (fr)
DE (1)	DE19524241A1 (fr)
SK (1)	SK86596A3 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19707386A1 (de) *	1997-02-25	1998-08-27	Basf Ag	Verfahren zur Herstellung von Aminen aus Olefinen an NU-85-Zeolithen
ATE537138T1 (de) *	2008-04-09	2011-12-15	Basf Se	Verfahren zur vorbehandlung von hydroaminierungskatalysatoren

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3308069A (en) *	1964-05-01	1967-03-07	Mobil Oil Corp	Catalytic composition of a crystalline zeolite
NL7610766A (nl) *	1975-10-03	1977-04-05	Ici Ltd	Werkwijze ter bereiding van zeolieten.
CA2092964A1 (fr) *	1992-12-03	1994-06-04	John Frederick Knifton	Synthese de 2-methylpropan-2-amine

1995
- 1995-07-04 DE DE1995124241 patent/DE19524241A1/de not_active Withdrawn
1996
- 1996-06-25 EP EP96110197A patent/EP0752410A3/fr not_active Withdrawn
- 1996-07-01 CZ CZ961937A patent/CZ193796A3/cs unknown
- 1996-07-02 SK SK86596A patent/SK86596A3/sk unknown
- 1996-07-03 JP JP8173995A patent/JPH09104660A/ja not_active Withdrawn

Also Published As

Publication number	Publication date
EP0752410A3 (fr)	1999-04-21
EP0752410A2 (fr)	1997-01-08
DE19524241A1 (de)	1997-01-09
CZ193796A3 (en)	1997-03-12
JPH09104660A (ja)	1997-04-22

Publication	Publication Date	Title
US5900508A (en)	1999-05-04	Preparation of amines from olefins over zeolites of the type PSH-3, MCM-22, SSZ-25 or mixtures thereof
US5874621A (en)	1999-02-23	Preparation of amines from olefins over NU-85 zeolites
US5763668A (en)	1998-06-09	Process for aminating a mixture obtained in cracking a mineral oil fraction with ammonia or a primary or secondary amine over specific heterogeneous catalysts
SK86596A3 (en)	1997-03-05	Manufacturing process of amines from olefins on aluminium-beta-zeolites without transition metals and prepared without treatment with halogens
US5780680A (en)	1998-07-14	Preparation of amines from olefins over mesoporous oxides having a high surface area
US5877352A (en)	1999-03-02	Preparation of amines from olefins on boron-MCM-22 or ERB-1 zeolites
SK20298A3 (en)	1998-11-04	Method of preparing amines from olefins over boron 'beta'-zeolites
US5840988A (en)	1998-11-24	Preparation of amines from olefins on zeolites of the MCM-49 or MCM-56 type
US5773660A (en)	1998-06-30	Preparation of amines from olefins over hexagonal faujasites
US5886226A (en)	1999-03-23	Process for producing amines from olefins on zeolites of types SSZ-33, CIT-1 or mixtures thereof
US5739405A (en)	1998-04-14	Preparation of amines from olefins over zeolites of the type SSZ-37
US5786510A (en)	1998-07-28	Preparation of amines from olefins over crystalline oxides based on aluminum phosphates and having faujasite structure
SK86696A3 (en)	1997-01-08	A producing method of amines from olefins over pillared clay
JP3091258B2 (ja)	2000-09-25	環状アルキレンイミンのｎ−アルキル化物の製造法