SU509213A3 - Способ получени уксусной кислоты - Google Patents

Способ получени уксусной кислоты

Info

Publication number: SU509213A3
Authority: SU; USSR - Soviet Union
Prior art keywords: acetic acid; ethylene; oxygen; phosphoric acid; palladium
Prior art date: 1970-12-17

Application number

SU1726576A

Other languages

English (en)

Russian (ru)

Inventor

Мария Макклэйн Дароти

Энн Хеллер Карол

Лестер Мадор Ирвинг

Original Assignee

Нэшнл Дистиллерз Эндкемикал Корпорейшн (Фирма)

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1970-12-17

Filing date

1971-12-16

Publication date

1976-03-30

1971-12-16 Application filed by Нэшнл Дистиллерз Эндкемикал Корпорейшн (Фирма) filed Critical Нэшнл Дистиллерз Эндкемикал Корпорейшн (Фирма)

1976-03-30 Application granted granted Critical

1976-03-30 Publication of SU509213A3 publication Critical patent/SU509213A3/ru

Links

QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title description 100
238000000034 method Methods 0.000 title description 24
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 48
239000000203 mixture Substances 0.000 description 26
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 24
229910000147 aluminium phosphate Inorganic materials 0.000 description 24
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 23
239000005977 Ethylene Substances 0.000 description 23
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 21
239000003054 catalyst Substances 0.000 description 21
238000006243 chemical reaction Methods 0.000 description 21
239000001301 oxygen Substances 0.000 description 21
229910052760 oxygen Inorganic materials 0.000 description 21
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 20
230000003197 catalytic effect Effects 0.000 description 17
238000002474 experimental method Methods 0.000 description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
239000007789 gas Substances 0.000 description 9
229910052763 palladium Inorganic materials 0.000 description 9
238000007254 oxidation reaction Methods 0.000 description 8
239000000047 product Substances 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 7
230000003647 oxidation Effects 0.000 description 7
239000000463 material Substances 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
239000000969 carrier Substances 0.000 description 5
238000002485 combustion reaction Methods 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
239000003153 chemical reaction reagent Substances 0.000 description 3
239000003701 inert diluent Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
229910000510 noble metal Inorganic materials 0.000 description 3
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
-1 for example Substances 0.000 description 2
238000009472 formulation Methods 0.000 description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000012808 vapor phase Substances 0.000 description 2
229910001020 Au alloy Inorganic materials 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
235000011089 carbon dioxide Nutrition 0.000 description 1
239000003245 coal Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000008021 deposition Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
OCLXJTCGWSSVOE-UHFFFAOYSA-N ethanol etoh Chemical compound CCO.CCO OCLXJTCGWSSVOE-UHFFFAOYSA-N 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
238000007710 freezing Methods 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
239000003353 gold alloy Substances 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
238000002386 leaching Methods 0.000 description 1
238000011068 loading method Methods 0.000 description 1
230000007774 longterm Effects 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
150000002940 palladium Chemical class 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
239000001294 propane Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
238000002791 soaking Methods 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
239000006104 solid solution Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
229910000406 trisodium phosphate Inorganic materials 0.000 description 1
235000019801 trisodium phosphate Nutrition 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

SU1726576A 1970-12-17 1971-12-16 Способ получени уксусной кислоты SU509213A3 (ru)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US9928270A	1970-12-17	1970-12-17
US19752871A	1971-11-10	1971-11-10

Publications (1)

Publication Number	Publication Date
SU509213A3 true SU509213A3 (ru)	1976-03-30

Family

ID=26795912

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU1726576A SU509213A3 (ru)	1970-12-17	1971-12-16	Способ получени уксусной кислоты

Country Status (15)

Country	Link
AT (1)	AT319912B (cs)
AU (1)	AU462428B2 (cs)
BE (1)	BE776752A (cs)
CA (1)	CA958722A (cs)
DE (1)	DE2162779A1 (cs)
ES (1)	ES398560A1 (cs)
FR (1)	FR2118774A5 (cs)
GB (1)	GB1349100A (cs)
IL (1)	IL38386A (cs)
IT (1)	IT944107B (cs)
NL (1)	NL7117356A (cs)
PL (1)	PL84586B1 (cs)
RO (1)	RO59379A (cs)
SU (1)	SU509213A3 (cs)
TR (1)	TR17801A (cs)

1971
- 1971-12-15 AU AU36917/71A patent/AU462428B2/en not_active Expired
- 1971-12-15 BE BE776752A patent/BE776752A/xx unknown
- 1971-12-16 TR TR17801A patent/TR17801A/xx unknown
- 1971-12-16 SU SU1726576A patent/SU509213A3/ru active
- 1971-12-16 ES ES71398560A patent/ES398560A1/es not_active Expired
- 1971-12-16 AT AT1083071A patent/AT319912B/de not_active IP Right Cessation
- 1971-12-16 IL IL38386A patent/IL38386A/xx unknown
- 1971-12-16 PL PL1971152211A patent/PL84586B1/pl unknown
- 1971-12-17 IT IT32587/71A patent/IT944107B/it active
- 1971-12-17 NL NL7117356A patent/NL7117356A/xx unknown
- 1971-12-17 FR FR7145518A patent/FR2118774A5/fr not_active Expired
- 1971-12-17 RO RO69094A patent/RO59379A/ro unknown
- 1971-12-17 GB GB5879271A patent/GB1349100A/en not_active Expired
- 1971-12-17 DE DE19712162779 patent/DE2162779A1/de active Pending
- 1971-12-17 CA CA130,427A patent/CA958722A/en not_active Expired

Also Published As

Publication number	Publication date
CA958722A (en)	1974-12-03
DE2162779A1 (cs)	1972-06-29
AU3691771A (en)	1973-06-21
IL38386A0 (en)	1972-02-29
TR17801A (tr)	1976-09-01
AU462428B2 (en)	1975-06-26
IL38386A (en)	1974-05-16
IT944107B (it)	1973-04-20
AT319912B (de)	1975-01-10
NL7117356A (cs)	1972-06-20
BE776752A (fr)	1972-06-15
ES398560A1 (es)	1975-06-01
PL84586B1 (cs)	1976-04-30
RO59379A (cs)	1976-02-15
GB1349100A (en)	1974-03-27
FR2118774A5 (cs)	1972-07-28

Publication	Publication Date	Title
US2040782A (en)	1936-05-12	Manufacture of olefine oxides
US4175115A (en)	1979-11-20	Process for the production of synthesis gas by the catalyzed decomposition of methanol
Otsuka et al.	1989	Synthesis of C2H4 by partial oxidation of CH4 over LiCl/NiO
GB2025950A (en)	1980-01-30	The Preparation of Esters of Oxalic Acid
JPS6015609B2 (ja)	1985-04-20	不飽和カルボン酸エステルの製造方法
US3282981A (en)	1966-11-01	Activated addition of hydrogen cyanide to olefins
US4605781A (en)	1986-08-12	Production of 2-methylbutanal
EP0490507B1 (en)	1995-01-11	Acetic acid from ethylene
US3476808A (en)	1969-11-04	Catalytic oxidative dehydrogenation of ketones
SU1111684A3 (ru)	1984-08-30	Способ получени смеси уксусной кислоты,уксусного альдегида,этанола и олефинов @ - @
Hayashi et al.	1963	Kinetics of the catalytic oxidation of benzene
US4010198A (en)	1977-03-01	Process for the preparation of allyl acetate
SU641872A3 (ru)	1979-01-05	Способ получени бутендолдиацетатов
EP0040414B1 (en)	1983-06-08	Process for producing acetaldehyde
EP0299995B1 (en)	1991-10-30	Process for converting carbon monoxide and water to hydrogen and carbon dioxide
US4345104A (en)	1982-08-17	Process for the production of ethylene glycol
Janz et al.	1947	The reaction of cyanogen with 1, 3-butadiene
Lambert et al.	2002	Kinetics of One-Stage Wacker-Type Oxidation of C2–C4 Olefins Catalysed by an Aqueous PdCl2–Heteropoly-Anion System
US3792087A (en)	1974-02-12	Vapor phase oxidation of ethylene to acetic acid
US3163652A (en)	1964-12-29	Production of piperidine and substituted piperidines from tetrahydrofurfuryl alcohol
SU586838A3 (ru)	1977-12-30	Способ получени оксима циклогексанона
KR100280261B1 (ko)	2001-02-01	팔라듐/산화아연계 촉매를 이용한 이산화탄소로 부터의 메탄올 제조방법
KR870000802B1 (ko)	1987-04-20	아질산에스테르의 제조방법
US4978803A (en)	1990-12-18	Vapor phase oxidation process for making glyoxal
US4243593A (en)	1981-01-06	Preparation of furan compounds