SU519137A3 - Способ получени дихлорангидрида 2-хлорэтилфосфоновой кислоты - Google Patents

Способ получени дихлорангидрида 2-хлорэтилфосфоновой кислоты

Info

Publication number: SU519137A3
Authority: SU; USSR - Soviet Union
Prior art keywords: acid dichloride; chloroethylphosphonic; chloroethylphosphonic acid; fraction; mol
Prior art date: 1970-03-28

Application number

SU1635746A

Other languages

English (en)

Russian (ru)

Inventor

Кляйнер Генс-Иерг

Резингер Зигурд

Original Assignee

Хехст Аг (Фирма)

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1970-03-28

Filing date

1971-03-28

Publication date

1976-06-25

1970-03-28 Priority claimed from DE19702015163 external-priority patent/DE2015163A1/de

1971-01-19 Priority claimed from DE2102264A external-priority patent/DE2102264C3/de

1971-03-28 Application filed by Хехст Аг (Фирма) filed Critical Хехст Аг (Фирма)

1976-06-25 Application granted granted Critical

1976-06-25 Publication of SU519137A3 publication Critical patent/SU519137A3/ru

Links

LOUZURPQCYZSJH-UHFFFAOYSA-N 1-chloro-2-dichlorophosphorylethane Chemical compound ClCCP(Cl)(Cl)=O LOUZURPQCYZSJH-UHFFFAOYSA-N 0.000 title description 22
238000004519 manufacturing process Methods 0.000 title 1
238000000034 method Methods 0.000 description 19
238000005660 chlorination reaction Methods 0.000 description 15
OWGJXSYVHQEVHS-UHFFFAOYSA-N 1-dichlorophosphorylethane Chemical compound CCP(Cl)(Cl)=O OWGJXSYVHQEVHS-UHFFFAOYSA-N 0.000 description 14
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 9
239000000460 chlorine Substances 0.000 description 9
229910052801 chlorine Inorganic materials 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
239000011541 reaction mixture Substances 0.000 description 8
GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 7
SPYUGXBMJVRZBP-UHFFFAOYSA-N 1-chloro-1-dichlorophosphorylethane Chemical compound CC(Cl)P(Cl)(Cl)=O SPYUGXBMJVRZBP-UHFFFAOYSA-N 0.000 description 6
238000004821 distillation Methods 0.000 description 6
CNGZUJQPNVPPCJ-UHFFFAOYSA-N 1-chloroethylphosphonic acid Chemical compound CC(Cl)P(O)(O)=O CNGZUJQPNVPPCJ-UHFFFAOYSA-N 0.000 description 4
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 4
UDPGUMQDCGORJQ-UHFFFAOYSA-N (2-chloroethyl)phosphonic acid Chemical group OP(O)(=O)CCCl UDPGUMQDCGORJQ-UHFFFAOYSA-N 0.000 description 3
FQHUXIRBYRGSIR-UHFFFAOYSA-N 2,2-dichloroethylphosphonic acid Chemical compound ClC(CP(O)(O)=O)Cl FQHUXIRBYRGSIR-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
239000004342 Benzoyl peroxide Substances 0.000 description 3
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
235000019400 benzoyl peroxide Nutrition 0.000 description 3
239000011521 glass Substances 0.000 description 3
239000007858 starting material Substances 0.000 description 3
HMFOJAFEYQWZBR-UHFFFAOYSA-N 1,1-dichloro-2-dichlorophosphorylethane Chemical compound ClC(Cl)CP(Cl)(Cl)=O HMFOJAFEYQWZBR-UHFFFAOYSA-N 0.000 description 2
NHYCGSASNAIGLD-UHFFFAOYSA-N Chlorine monoxide Chemical compound Cl[O] NHYCGSASNAIGLD-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
239000012320 chlorinating reagent Substances 0.000 description 2
238000004508 fractional distillation Methods 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
239000000203 mixture Substances 0.000 description 2
XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
230000005855 radiation Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 2
MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 2
FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
DEWLEGDTCGBNGU-UHFFFAOYSA-N 1,3-dichloropropan-2-ol Chemical compound ClCC(O)CCl DEWLEGDTCGBNGU-UHFFFAOYSA-N 0.000 description 1
GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 description 1
206010062717 Increased upper airway secretion Diseases 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
239000004157 Nitrosyl chloride Substances 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
-1 acetylcyclohexylsulfonyl Chemical group 0.000 description 1
238000007872 degassing Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
230000001678 irradiating effect Effects 0.000 description 1
125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
VPCDQGACGWYTMC-UHFFFAOYSA-N nitrosyl chloride Chemical compound ClN=O VPCDQGACGWYTMC-UHFFFAOYSA-N 0.000 description 1
235000019392 nitrosyl chloride Nutrition 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
208000026435 phlegm Diseases 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000004445 quantitative analysis Methods 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/123—Ultraviolet light
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/42—Halides thereof

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
Molecular Biology (AREA)
Physics & Mathematics (AREA)
Electromagnetism (AREA)
Toxicology (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

SU1635746A 1970-03-28 1971-03-28 Способ получени дихлорангидрида 2-хлорэтилфосфоновой кислоты SU519137A3 (ru)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19702015163 DE2015163A1 (de)	1970-03-28	1970-03-28	Verfahren zur Herstellung von 2 Chlor athanphosphonsauredichlorid
DE2102264A DE2102264C3 (de)	1971-01-19	1971-01-19	Verfahren zur Herstellung von 2-Chloraethanphosphonsäuredichlorid

Publications (1)

Publication Number	Publication Date
SU519137A3 true SU519137A3 (ru)	1976-06-25

Family

ID=25758902

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU1635746A SU519137A3 (ru)	1970-03-28	1971-03-28	Способ получени дихлорангидрида 2-хлорэтилфосфоновой кислоты

Country Status (11)

Country	Link
JP (1)	JPS5441572B1 (fr)
AT (1)	AT306053B (fr)
BE (1)	BE764873A (fr)
CA (1)	CA937939A (fr)
CH (1)	CH550826A (fr)
FR (1)	FR2085140A5 (fr)
GB (1)	GB1283678A (fr)
IL (1)	IL36500A (fr)
NL (1)	NL168231C (fr)
RO (1)	RO60462A (fr)
SU (1)	SU519137A3 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3629579A1 (de) *	1986-08-30	1988-03-03	Hoechst Ag	Verfahren zur herstellung von 2-chlorethanphosphonsaeuredichlorid
RU2281287C1 (ru) *	2005-07-20	2006-08-10	Федеральное государственное образовательное учреждение высшего профессионального образования Чувашский государственный университет им. И.Н. Ульянова	Способ получения хлорангидрида 2,4-дихлор-2-дихлорфосфорилбутановой кислоты
RU2290407C1 (ru) *	2005-07-20	2006-12-27	Федеральное государственное образовательное учреждение высшего профессионального образования Чувашский государственный университет им. И.Н. Ульянова	Способ получения хлорангидрида 2,4-дихлор-2-дихлорфосфорилбутановой кислоты

1971
- 1971-03-23 NL NLAANVRAGE7103873,A patent/NL168231C/xx not_active IP Right Cessation
- 1971-03-25 FR FR7110588A patent/FR2085140A5/fr not_active Expired
- 1971-03-26 AT AT259171A patent/AT306053B/de not_active IP Right Cessation
- 1971-03-26 CA CA108796A patent/CA937939A/en not_active Expired
- 1971-03-26 BE BE764873A patent/BE764873A/fr not_active IP Right Cessation
- 1971-03-26 IL IL36500A patent/IL36500A/en unknown
- 1971-03-26 JP JP1731971A patent/JPS5441572B1/ja active Pending
- 1971-03-26 CH CH445471A patent/CH550826A/xx not_active IP Right Cessation
- 1971-03-27 RO RO66405A patent/RO60462A/ro unknown
- 1971-03-28 SU SU1635746A patent/SU519137A3/ru active
- 1971-04-19 GB GB25392/71A patent/GB1283678A/en not_active Expired

Also Published As

Publication number	Publication date
RO60462A (fr)	1976-08-15
IL36500A0 (en)	1971-05-26
CH550826A (de)	1974-06-28
NL7103873A (fr)	1971-09-30
GB1283678A (en)	1972-08-02
IL36500A (en)	1973-07-30
BE764873A (fr)	1971-09-27
JPS5441572B1 (fr)	1979-12-08
AT306053B (de)	1973-03-26
NL168231C (nl)	1982-03-16
FR2085140A5 (fr)	1971-12-17
CA937939A (en)	1973-12-04
NL168231B (nl)	1981-10-16

Publication	Publication Date	Title
Srinivasan	1959	Photoisomerization Processes in Cyclic Ketones. II. Cyclohexanone and 2-Methylcyclohexanone1
Suryanarayanan et al.	1972	Photolysis of solid dimethylnitramine. Nitrogen-15 study and evidence for nitrosamide rearrangement
Box et al.	1970	Photolysis of dibenzoyl peroxide
US2420975A (en)	1947-05-20	Process of producing a solid pentachloropropane
IL36500A (en)	1973-07-30	Process for the manufacture of 2-chloroethanephosphonic acid dichloride
US3871975A (en)	1975-03-18	Electrolytic process for production of perfluorocyclohexane derivatives
US3637479A (en)	1972-01-25	Halogenation process using ultraviolet light
EP0105637A1 (fr)	1984-04-18	Méthode pour séparer des isotopes de zirconium
US3773810A (en)	1973-11-20	Process for the preparation of 2,3-disubstituted 1,3-butadienes
US2399641A (en)	1946-05-07	Purification of crude trichloroacetyl chloride
US4049516A (en)	1977-09-20	Photochemical process for the production of halogeno-alkanes
US2865825A (en)	1958-12-23	Process for preparing symmetrical tetrachlorethane from symmetrical dichlorethylene
Gladstone	1954	The Decomposition of Benzoyl Peroxide in Glacial Acetic Acid
US1246739A (en)	1917-11-13	Process for manufacturing side-chain chlorin derivatives of toluol.
US3751353A (en)	1973-08-07	Process for the manufacture of 2-chlorethanephosphonic acid dichloride
SU387958A1 (ru)	1973-06-22	Способ получения монохлорадамантана
US2106579A (en)	1938-01-25	Manufacture of formamide
US3480534A (en)	1969-11-25	Transbromination process
EP0018481B1 (fr)	1983-01-12	Procédé de préparation de fluorure d'alpha, alpha, alpha-trifluoro-o-toluoyle
US3026257A (en)	1962-03-20	Method of adding hydrogen bromide to vinylaryl compounds
US3340168A (en)	1967-09-05	Production of 2, 6-dichlorobenzylidene-chloride
SU477992A1 (ru)	1975-07-25	Способ получени пентахлорпропанола
US2759981A (en)	1956-08-21	Sulphur dioxide chlorination of phenol
SU426988A1 (ru)	1975-05-05	Способ получени алкиладамантанов
SU416317A1 (fr)	1974-02-25