SU589740A1 - Способ получени сложных эфиров - Google Patents

Способ получени сложных эфиров

Info

Publication number: SU589740A1
Authority: SU; USSR - Soviet Union
Prior art keywords: reactor; pressure; acid; residual; anhydride
Prior art date: 1976-06-29

Application number

SU762381280A

Other languages

English (en)

Russian (ru)

Inventor

Ю.Е. Носовский

Г.К. Кочергина

А.И. Куценко

В.И. Житков

В.А. Воробьев

Original Assignee

Предприятие П/Я М-5885

Предприятие П/Я Р-6914

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-06-29

Filing date

1976-06-29

Publication date

1978-08-25

1976-06-29 Application filed by Предприятие П/Я М-5885, Предприятие П/Я Р-6914 filed Critical Предприятие П/Я М-5885

1976-06-29 Priority to SU762381280A priority Critical patent/SU589740A1/ru

1977-06-20 Priority to CS406277A priority patent/CS188760B1/cs

1977-06-27 Priority to DD19972077A priority patent/DD132337A1/de

1977-06-28 Priority to BG7736747A priority patent/BG31289A1/xx

1977-06-29 Priority to YU160377A priority patent/YU39807B/xx

1978-08-25 Application granted granted Critical

1978-08-25 Publication of SU589740A1 publication Critical patent/SU589740A1/ru

Links

238000000034 method Methods 0.000 title claims description 31
150000002148 esters Chemical class 0.000 title claims description 5
239000002253 acid Substances 0.000 claims description 22
230000008569 process Effects 0.000 claims description 20
229910052719 titanium Inorganic materials 0.000 claims description 16
239000010936 titanium Substances 0.000 claims description 16
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 15
239000003054 catalyst Substances 0.000 claims description 15
238000006243 chemical reaction Methods 0.000 claims description 13
150000008064 anhydrides Chemical class 0.000 claims description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 7
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 7
150000001298 alcohols Chemical class 0.000 claims description 6
239000000203 mixture Substances 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 5
239000003153 chemical reaction reagent Substances 0.000 claims description 5
238000005886 esterification reaction Methods 0.000 claims description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
125000003118 aryl group Chemical group 0.000 claims description 4
230000015572 biosynthetic process Effects 0.000 claims description 4
238000005516 engineering process Methods 0.000 claims description 4
238000003786 synthesis reaction Methods 0.000 claims description 4
238000006555 catalytic reaction Methods 0.000 claims description 3
238000005265 energy consumption Methods 0.000 claims description 3
230000032050 esterification Effects 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims description 3
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
125000004429 atom Chemical group 0.000 claims 1
238000009835 boiling Methods 0.000 claims 1
150000002191 fatty alcohols Chemical class 0.000 claims 1
230000001228 trophic effect Effects 0.000 claims 1
239000011541 reaction mixture Substances 0.000 description 17
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 8
238000009434 installation Methods 0.000 description 6
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 4
230000000737 periodic effect Effects 0.000 description 4
230000035484 reaction time Effects 0.000 description 4
238000010438 heat treatment Methods 0.000 description 3
239000004014 plasticizer Substances 0.000 description 3
239000002594 sorbent Substances 0.000 description 3
QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
235000021355 Stearic acid Nutrition 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
-1 aromatic dicarboxylic acid esters Chemical class 0.000 description 2
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
230000007423 decrease Effects 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000003993 interaction Effects 0.000 description 2
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
239000008117 stearic acid Substances 0.000 description 2
LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 2
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
WGQVJOPQTOUKDI-UHFFFAOYSA-N 2-dodecoxycarbonylbenzoic acid Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(O)=O WGQVJOPQTOUKDI-UHFFFAOYSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
240000006394 Sorghum bicolor Species 0.000 description 1
235000011684 Sorghum saccharatum Nutrition 0.000 description 1
230000009471 action Effects 0.000 description 1
230000001154 acute effect Effects 0.000 description 1
WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
239000003513 alkali Substances 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
230000002706 hydrostatic effect Effects 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000000463 material Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000004451 qualitative analysis Methods 0.000 description 1
239000010453 quartz Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000004904 shortening Methods 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000017550 sodium carbonate Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1

Landscapes

Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

SU762381280A 1976-06-29 1976-06-29 Способ получени сложных эфиров SU589740A1 (ru)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
SU762381280A SU589740A1 (ru)	1976-06-29	1976-06-29	Способ получени сложных эфиров
CS406277A CS188760B1 (en)	1976-06-29	1977-06-20	Method of esters production
DD19972077A DD132337A1 (de)	1976-06-29	1977-06-27	Verfahren zur herstellung von estern
BG7736747A BG31289A1 (en)	1976-06-29	1977-06-28	Method for obtaining of esters
YU160377A YU39807B (en)	1976-06-29	1977-06-29	Process for obtaining esters

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
SU762381280A SU589740A1 (ru)	1976-06-29	1976-06-29	Способ получени сложных эфиров

Publications (1)

Publication Number	Publication Date
SU589740A1 true SU589740A1 (ru)	1978-08-25

Family

ID=20668862

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU762381280A SU589740A1 (ru)	1976-06-29	1976-06-29	Способ получени сложных эфиров

Country Status (5)

Country	Link
BG (1)	BG31289A1 (de)
CS (1)	CS188760B1 (de)
DD (1)	DD132337A1 (de)
SU (1)	SU589740A1 (de)
YU (1)	YU39807B (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NZ195265A (en) *	1979-10-27	1983-05-10	British Petroleum Co	Catalytic esterification of carboxylic acids or anhydrides thereof

1976
- 1976-06-29 SU SU762381280A patent/SU589740A1/ru active
1977
- 1977-06-20 CS CS406277A patent/CS188760B1/cs unknown
- 1977-06-27 DD DD19972077A patent/DD132337A1/de unknown
- 1977-06-28 BG BG7736747A patent/BG31289A1/xx unknown
- 1977-06-29 YU YU160377A patent/YU39807B/xx unknown

Also Published As

Publication number	Publication date
YU39807B (en)	1985-04-30
YU160377A (en)	1982-05-31
DD132337A1 (de)	1978-09-20
BG31289A1 (en)	1981-12-15
CS188760B1 (en)	1979-03-30

Publication	Publication Date	Title
US5424466A (en)	1995-06-13	Improved process for the production of esters from fatty substances having a natural origin
US5175323A (en)	1992-12-29	Preparation of esterified propoxylated glycerin by transesterification
US4007218A (en)	1977-02-08	Esterification reaction
US1939116A (en)	1933-12-12	Process for the continuous production of esters of ethyl alcohol
US4011251A (en)	1977-03-08	Method of preparing esters of glycerol and polyglycerols and C5-C9 monocarboxylic fatty acids
US3096324A (en)	1963-07-02	Process for manufacturing sugar esters
DE69416313T2 (de)	1999-10-14	Verfahren zum Herstellen von Estern ungesättigter Carbonsäuren und Einrichtung zum Herstellen derselben
CN111960943A (zh)	2020-11-20	一种半连续法生产对苯二甲酸二辛酯的工艺
US4032563A (en)	1977-06-28	Process for the recovery of high purity diesters of terephthalic or isophthalic acids
US4506091A (en)	1985-03-19	Removal of catalyst residues from polyesters
US2722541A (en)	1955-11-01	Process of esterifying butyl lactate
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SU592815A1 (ru)	1978-02-15	Способ очистки сложных эфиров
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RU2004533C1 (ru)	1993-12-15	Способ получени сложных эфиров
RU2791393C1 (ru)	2023-03-07	Способ получения ди-(2-этилгексилового) эфира азелаиновой или себациновой кислоты
SU1038334A1 (ru)	1983-08-30	Способ получени сложных эфиров