SU605542A3 - Способ получени амида натри - Google Patents
Способ получени амида натриInfo
- Publication number
- SU605542A3 SU605542A3 SU741995922A SU1995922A SU605542A3 SU 605542 A3 SU605542 A3 SU 605542A3 SU 741995922 A SU741995922 A SU 741995922A SU 1995922 A SU1995922 A SU 1995922A SU 605542 A3 SU605542 A3 SU 605542A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- sodium
- pressure
- amide
- liquid ammonia
- hydrogen
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 5
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 title claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 229910052708 sodium Inorganic materials 0.000 claims 3
- 239000011734 sodium Substances 0.000 claims 3
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 150000001408 amides Chemical class 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 241000670727 Amida Species 0.000 claims 1
- 241001026509 Kata Species 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/087—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms
- C01B21/092—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms containing also one or more metal atoms
- C01B21/0923—Metal imides or amides
- C01B21/0926—Metal imides or amides of alkali metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Claims (2)
- (54) СПОСОБ ПОЖЧЕНИЯ АМИДА НАТРИЯ Пример. 8,02 г чистого натри , 120 г теплого жидкого аммиака и 36 г азида натри помещают в реактор высокого удавлени емкостью 300 см, оборудованный мешалкой. Процесс провод т при 30° С и давлении 21 кг/см, непрерывно удал водород совместно с парами аммиака, которые немедленно промьтают разбавленной серной кислотой. Общий объем собранного водорода равен 3881 см в нормальных услови х По объему собранного газа устанавливают, что вьсход амида составл ет 99,3%. Продукт не содержит включений катализатора. Формула изобретени 1. Способ получени амида натри путем взаИ модействи жидкого аммиака с расплавленным нат рием на катализаторе с одновременным отводом во дорода при повышенном давлении, отличающийс тем, что, с целью повьпиени выхода и чистоты продукта, в качестве ката;шзатора ийпользуют азид натри в количестве от 1 до 35% от веса жидкого аммиака. 2. Способ по п. 1, отличающийс тем, что процесс получени амида натрт провод т при давлении 12-30 атм и температуре 20-40°С. , Источники информации, прин тые во внимание при зкспертизе: 1.Патент США № 2373800, кл. 23-401, 1945.
- 2.Патент США № 2202994, кл. 23-101, 1940.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB799073A GB1407120A (en) | 1973-02-19 | 1973-02-19 | Manufacture of alkali metal amides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU605542A3 true SU605542A3 (ru) | 1978-04-30 |
Family
ID=9843654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU741995922A SU605542A3 (ru) | 1973-02-19 | 1974-02-18 | Способ получени амида натри |
Country Status (19)
| Country | Link |
|---|---|
| JP (1) | JPS5417320B2 (ru) |
| AR (1) | AR198267A1 (ru) |
| AU (1) | AU474994B2 (ru) |
| BE (1) | BE811266A (ru) |
| BR (1) | BR7401211D0 (ru) |
| CA (1) | CA1012329A (ru) |
| DE (1) | DE2400907B2 (ru) |
| ES (1) | ES423382A1 (ru) |
| FI (1) | FI55021C (ru) |
| FR (1) | FR2218284B1 (ru) |
| GB (1) | GB1407120A (ru) |
| IN (1) | IN138174B (ru) |
| IT (1) | IT1002820B (ru) |
| NL (1) | NL7402089A (ru) |
| NO (1) | NO137992C (ru) |
| PH (1) | PH10542A (ru) |
| SE (1) | SE386144B (ru) |
| SU (1) | SU605542A3 (ru) |
| ZA (1) | ZA7456B (ru) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007106623A (ja) * | 2005-10-12 | 2007-04-26 | Taiheiyo Cement Corp | 金属アミド複合物およびその製造方法 |
| JP5060504B2 (ja) * | 2009-03-25 | 2012-10-31 | 太平洋セメント株式会社 | 金属アミドの製造方法および金属アミド製造装置 |
| JP6253366B2 (ja) * | 2013-11-22 | 2017-12-27 | 太平洋セメント株式会社 | 金属アミドの製造方法および製造装置 |
-
1973
- 1973-02-19 GB GB799073A patent/GB1407120A/en not_active Expired
-
1974
- 1974-01-02 AU AU64106/74A patent/AU474994B2/en not_active Expired
- 1974-01-09 DE DE19742400907 patent/DE2400907B2/de active Granted
- 1974-01-13 ZA ZA00740056A patent/ZA7456B/xx unknown
- 1974-01-24 FR FR7402365A patent/FR2218284B1/fr not_active Expired
- 1974-01-29 AR AR252110A patent/AR198267A1/es active
- 1974-01-31 IT IT48069/74A patent/IT1002820B/it active
- 1974-02-01 CA CA191,592A patent/CA1012329A/en not_active Expired
- 1974-02-01 FI FI285/74A patent/FI55021C/fi active
- 1974-02-05 PH PH15478A patent/PH10542A/en unknown
- 1974-02-11 SE SE7401791A patent/SE386144B/xx unknown
- 1974-02-15 IN IN326/CAL/74A patent/IN138174B/en unknown
- 1974-02-15 NL NL7402089A patent/NL7402089A/xx unknown
- 1974-02-18 SU SU741995922A patent/SU605542A3/ru active
- 1974-02-18 JP JP1864874A patent/JPS5417320B2/ja not_active Expired
- 1974-02-18 NO NO740531A patent/NO137992C/no unknown
- 1974-02-19 ES ES423382A patent/ES423382A1/es not_active Expired
- 1974-02-19 BE BE141122A patent/BE811266A/xx unknown
- 1974-02-19 BR BR1211/74A patent/BR7401211D0/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE811266A (fr) | 1974-06-17 |
| SE386144B (sv) | 1976-08-02 |
| IT1002820B (it) | 1976-05-20 |
| FR2218284B1 (ru) | 1977-06-10 |
| DE2400907B2 (de) | 1976-11-04 |
| BR7401211D0 (pt) | 1974-11-05 |
| AU474994B2 (en) | 1976-08-05 |
| JPS49114599A (ru) | 1974-11-01 |
| FI55021C (fi) | 1979-05-10 |
| NO740531L (no) | 1974-08-20 |
| FI55021B (fi) | 1979-01-31 |
| DE2400907A1 (de) | 1974-08-22 |
| ZA7456B (en) | 1975-08-27 |
| CA1012329A (en) | 1977-06-21 |
| FR2218284A1 (ru) | 1974-09-13 |
| NL7402089A (ru) | 1974-08-21 |
| GB1407120A (en) | 1975-09-24 |
| AU6410674A (en) | 1975-07-03 |
| PH10542A (en) | 1977-06-07 |
| JPS5417320B2 (ru) | 1979-06-28 |
| ES423382A1 (es) | 1976-05-16 |
| IN138174B (ru) | 1975-12-27 |
| AR198267A1 (es) | 1974-06-07 |
| NO137992C (no) | 1978-06-07 |
| NO137992B (no) | 1978-02-27 |
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