SU645528A3 - Катализатор дл гидрориформинга углеводородов - Google Patents
Катализатор дл гидрориформинга углеводородовInfo
- Publication number
- SU645528A3 SU645528A3 SU742078930A SU2078930A SU645528A3 SU 645528 A3 SU645528 A3 SU 645528A3 SU 742078930 A SU742078930 A SU 742078930A SU 2078930 A SU2078930 A SU 2078930A SU 645528 A3 SU645528 A3 SU 645528A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- catalyst
- catalysts
- aromatization
- reforming
- hydrocarbon
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title description 25
- 229930195733 hydrocarbon Natural products 0.000 title description 4
- 150000002430 hydrocarbons Chemical class 0.000 title description 4
- 239000004215 Carbon black (E152) Substances 0.000 title 1
- 238000002407 reforming Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
- 238000005899 aromatization reaction Methods 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 150000002790 naphthalenes Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/8995—Catalyst and recycle considerations
- Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
(54) КАТАЛИЗАТОР ДЛЯ ГИДРОРИФОРМИНГА 12
УГЛЕВОДОРОДОВ
ставе катализатора 0,35 вес. %. После сушки при 100°С катализатор прокаливают при 530° С.
Пример 3. Катализатор готов т по методике примера 2, но иа носитель нанос т также олово путем добавлени к пропитывающему раствору хлорида двухвалентного олова.
В табл. 1 приведены составы катализаторов с различным содержанием компонентов .
Таблица I.
Катализаторы различного состава испытывают при следующих услови х: в реактор из нержавеющей стали помещают 2,5 см катализатора, затем черезнего пропускают сухой водород в течение 2 ч при 500° С и давление 9 бар. После этого температуру довод т до 510°С и .ввод т нормальный гептан со скоростью 2 ч при отношении водорода к гептану 5. Результаты испытани предложенных катализаторов приведены в табл. 2. Таблица2 Примечание:. У сех катализаторов октановое число 103. - -;--; м - - - - : .-о..- .::: Из табл. 2следует,ЧТОтрийеталлические катализаторы (3,5) болееактавны,чём биметаллические. Пример 4. Применение катализатора дл ароматизации углеводородов. Готов т 3 катализатора, содержащих платину, олово, цирконий, вольфрам или титан, осаждаемые на окись алюмини , при следующем содержании компонентов, вес. %: Pt 0,36, Sn 0,20, Zn 0,20, Cl 1,13 (катализатор 9); Pt 0,37, Sn 0,20, Ti 0,13, Cl 1,19 (катализатор 10); Pt 0,36, Sn 0,19, W 0,23, Cl 1,26 (катализатор 11). -.- . , . . л : Испь1тани провод т при атмосферном давлении и 520° С с «-гейсаном (превращаемым в бейзол путем ароматизации) и водородом при отношении водорода к н-гексану 15,9. Установлено, что с катализаторами 9- 11 превращение происходит фактически полным, причем избирательность (селективность ) бензола оказываетс соотв.етственйо равной 60,8% дл катализатора 9, 68,4% дл катализатора 10 и 64,6% дл катализатора 11., - : Таким образом. Предложенныекатализаторы оказьшаютс хорощими .катализаторами ароматизации.. П р им ёр 5. Использов.ание катализатора в процессе ароматизации под давлением .,- . ., -.... Готов т катализатор (12) состава. вес. %: ; : 0,35 платины (ос-аждаёмой и помбщью psfCTBOpa гёкёа слорйлатиновой кислоты); 0,21 олоба (бсажДаёмоГ10 р помощью раствора хлористого соединени с двухвалентным оловом);
0,16 циркони (осаждаемого с помощью раствора нитрата циркони );
0,84 хлора.
При испытании катализатора 12 дл реакции ароматизации расцолагагот двум загрузкйми А и Б, анализ которых приведен в табл. 3.
Таблица 3
Реакци ароматизации происходит аналогично примеру 1 при 520° С, давлении 10 бар, объемной скорости 2 ч и мол рном отношении водорода к углеводородам 5.
6
Установлено, что дл загрузки А превращение парафинов и нафталинов равно 94,1%, а селективность ароматических соединений 45,8%; а дл загрузки Б превращение парафинов и нафталинов равно 92,4%; а селективность ароматических соединений 53,8%.
Claims (2)
1.Суханов В. П. Каталитические процессы в нефтепереработке. М., «Хими , 1973, с. 192.
2.Патент СССР № 47170,3 кл. В 01 J 23/42, 1971.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7341827A FR2252394B1 (ru) | 1973-11-23 | 1973-11-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU645528A3 true SU645528A3 (ru) | 1979-01-30 |
Family
ID=9128184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU742078930A SU645528A3 (ru) | 1973-11-23 | 1974-11-22 | Катализатор дл гидрориформинга углеводородов |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3974097A (ru) |
| JP (1) | JPS5645652B2 (ru) |
| BE (1) | BE822403A (ru) |
| CA (1) | CA1032968A (ru) |
| CH (1) | CH602179A5 (ru) |
| DE (1) | DE2455375C3 (ru) |
| FR (1) | FR2252394B1 (ru) |
| GB (1) | GB1464931A (ru) |
| IT (1) | IT1025934B (ru) |
| NL (1) | NL7415191A (ru) |
| SE (1) | SE406868B (ru) |
| SU (1) | SU645528A3 (ru) |
| ZA (1) | ZA747350B (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2377066C1 (ru) * | 2008-12-08 | 2009-12-27 | Александр Адольфович Ламберов | Катализатор для дегидрирования изопентана и изопентанизоамиленовых фракций и способ его получения |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2312552A2 (fr) * | 1975-05-28 | 1976-12-24 | Raffinage Cie Francaise | Catalyseurs d'hydrotraitement d'hydrocarbures et procede de preparation desdits catalyseurs |
| US3966790A (en) * | 1973-12-10 | 1976-06-29 | Engelhard Minerals & Chemicals Corporation | Compositions and methods for high temperature stable catalysts |
| CA1094533A (en) * | 1976-08-23 | 1981-01-27 | Paul W. Tamm | Reforming catalyst and a hydrocarbon catalytic reforming process using the catalyst |
| US4174271A (en) * | 1977-11-03 | 1979-11-13 | Cosden Technology, Inc. | High severity reforming |
| FR2427844A1 (fr) * | 1978-06-05 | 1980-01-04 | Raffinage Cie Francaise | Procede pour deposer du zirconium et/ou du titane sur un support de catalyseur |
| DE4013074A1 (de) * | 1990-04-25 | 1991-10-31 | Ego Elektro Blanc & Fischer | Einstellbares geraet, insbesondere elektrisches schalt-, steuer- oder regelgeraet |
| US5496467A (en) * | 1992-12-04 | 1996-03-05 | Degussa Aktiengesellschaft | Method for the catalytic reforming of naphtha |
| DE4240862C2 (de) * | 1992-12-04 | 1995-01-19 | Degussa | Verwendung eines Katalysators zur Herstellung von BTX-Aromaten |
| DE4240863C2 (de) * | 1992-12-04 | 1995-05-24 | Degussa | Verwendung eines Katalysators zum katalytischen Reformieren von Naphtha mit hoher Ausbeute an BTX-Automaten |
| CN1039917C (zh) * | 1995-11-14 | 1998-09-23 | 中国石油化工总公司 | 一种铂－锡－钛多金属重整催化剂 |
| US6110862A (en) * | 1998-05-07 | 2000-08-29 | Engelhard Corporation | Catalytic material having improved conversion performance |
| RU2594482C1 (ru) * | 2015-11-16 | 2016-08-20 | Публичное акционерное общество "Научно-производственное предприятие Нефтехим" (ПАО "НПП Нефтехим") | Катализатор для риформинга бензиновых фракций |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2957819A (en) * | 1958-05-19 | 1960-10-25 | Universal Oil Prod Co | Reforming process and catalyst therefor |
| US3002920A (en) * | 1958-12-10 | 1961-10-03 | Exxon Research Engineering Co | Hydroforming catalyst and process |
| FR2031984A5 (ru) * | 1969-02-14 | 1970-11-20 | Raffinage Cie Francaise | |
| GB1347475A (en) * | 1970-04-10 | 1974-02-20 | Shell Int Research | Process for increasing the activity of supported catalysts |
| GB1401002A (en) * | 1971-06-16 | 1975-07-16 | Johnson Matthey Co Ltd | Platinumrhodium supported catalysts |
| BE787953A (fr) * | 1971-08-26 | 1973-02-26 | Franc De Comp | Procede de regulation de la teneur en halogene des catalyseurs de conversion des hydrocarbures |
| US3806446A (en) * | 1972-01-10 | 1974-04-23 | Universal Oil Prod Co | Reforming of hydrocarbons with a platinum-tungsten-germanium catalyst |
-
1973
- 1973-11-23 FR FR7341827A patent/FR2252394B1/fr not_active Expired
-
1974
- 1974-11-15 ZA ZA00747350A patent/ZA747350B/xx unknown
- 1974-11-15 CH CH1527674A patent/CH602179A5/xx not_active IP Right Cessation
- 1974-11-20 BE BE150688A patent/BE822403A/xx not_active IP Right Cessation
- 1974-11-20 US US05/525,675 patent/US3974097A/en not_active Expired - Lifetime
- 1974-11-21 SE SE7414652A patent/SE406868B/xx unknown
- 1974-11-21 NL NL7415191A patent/NL7415191A/xx not_active Application Discontinuation
- 1974-11-22 DE DE2455375A patent/DE2455375C3/de not_active Expired
- 1974-11-22 IT IT29737/74A patent/IT1025934B/it active
- 1974-11-22 GB GB5072174A patent/GB1464931A/en not_active Expired
- 1974-11-22 SU SU742078930A patent/SU645528A3/ru active
- 1974-11-25 JP JP13442374A patent/JPS5645652B2/ja not_active Expired
- 1974-11-25 CA CA214,595A patent/CA1032968A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2377066C1 (ru) * | 2008-12-08 | 2009-12-27 | Александр Адольфович Ламберов | Катализатор для дегидрирования изопентана и изопентанизоамиленовых фракций и способ его получения |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2252394B1 (ru) | 1977-06-10 |
| AU7561274A (en) | 1976-06-24 |
| CA1032968A (en) | 1978-06-13 |
| CH602179A5 (ru) | 1978-07-31 |
| GB1464931A (en) | 1977-02-16 |
| DE2455375B2 (de) | 1978-10-05 |
| ZA747350B (en) | 1975-11-26 |
| DE2455375A1 (de) | 1975-05-28 |
| NL7415191A (nl) | 1975-05-27 |
| SE7414652L (ru) | 1975-05-26 |
| BE822403A (fr) | 1975-05-20 |
| JPS5645652B2 (ru) | 1981-10-28 |
| IT1025934B (it) | 1978-08-30 |
| JPS5084488A (ru) | 1975-07-08 |
| SE406868B (sv) | 1979-03-05 |
| US3974097A (en) | 1976-08-10 |
| DE2455375C3 (de) | 1979-08-16 |
| FR2252394A1 (ru) | 1975-06-20 |
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