SU654175A3 - Способ получени катализатора полимеризации и сополимеризации с -с -альфаолефинов - Google Patents

Способ получени катализатора полимеризации и сополимеризации с -с -альфаолефинов

Info

Publication number: SU654175A3
Authority: SU; USSR - Soviet Union
Prior art keywords: polymerization; compound; reaction; catalyst; titanium
Prior art date: 1974-09-03

Application number

SU752170532A

Other languages

English (en)

Russian (ru)

Inventor

Тойото Акинори

Одавара Киеси

Касива Норио

Original Assignee

Мицуи Петрокемикал Индастриз, Лтд. (Фирма)

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-09-03

Filing date

1975-09-02

Publication date

1979-03-25

1975-09-02 Application filed by Мицуи Петрокемикал Индастриз, Лтд. (Фирма) filed Critical Мицуи Петрокемикал Индастриз, Лтд. (Фирма)

1979-03-25 Application granted granted Critical

1979-03-25 Publication of SU654175A3 publication Critical patent/SU654175A3/ru

Links

238000006116 polymerization reaction Methods 0.000 title claims description 20
239000003054 catalyst Substances 0.000 title claims description 19
238000007334 copolymerization reaction Methods 0.000 title claims description 4
239000004711 α-olefin Substances 0.000 title claims description 3
238000000034 method Methods 0.000 title description 8
239000007787 solid Substances 0.000 claims description 25
238000006243 chemical reaction Methods 0.000 claims description 17
150000003609 titanium compounds Chemical class 0.000 claims description 12
-1 aromatic monocarboxylic acids Chemical class 0.000 claims description 11
150000002148 esters Chemical class 0.000 claims description 11
229910052749 magnesium Inorganic materials 0.000 claims description 11
239000011777 magnesium Substances 0.000 claims description 11
229910052751 metal Inorganic materials 0.000 claims description 11
239000002184 metal Substances 0.000 claims description 11
230000000737 periodic effect Effects 0.000 claims description 10
150000002902 organometallic compounds Chemical class 0.000 claims description 9
239000000047 product Substances 0.000 claims description 9
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
239000002244 precipitate Substances 0.000 claims description 7
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
238000000926 separation method Methods 0.000 claims description 4
229910052719 titanium Inorganic materials 0.000 claims description 4
239000010936 titanium Substances 0.000 claims description 4
230000000694 effects Effects 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims description 2
238000005406 washing Methods 0.000 claims description 2
239000004215 Carbon black (E152) Substances 0.000 claims 1
239000013256 coordination polymer Substances 0.000 claims 1
229930195733 hydrocarbon Natural products 0.000 claims 1
150000002430 hydrocarbons Chemical class 0.000 claims 1
150000001875 compounds Chemical class 0.000 description 16
239000007795 chemical reaction product Substances 0.000 description 14
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
239000012442 inert solvent Substances 0.000 description 12
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 10
239000003350 kerosene Substances 0.000 description 10
239000000203 mixture Substances 0.000 description 10
230000003197 catalytic effect Effects 0.000 description 8
229920000642 polymer Polymers 0.000 description 7
239000000725 suspension Substances 0.000 description 7
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
150000001336 alkenes Chemical class 0.000 description 5
239000007789 gas Substances 0.000 description 5
239000012071 phase Substances 0.000 description 5
150000002681 magnesium compounds Chemical class 0.000 description 4
239000002904 solvent Substances 0.000 description 4
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
230000003993 interaction Effects 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000007791 liquid phase Substances 0.000 description 3
150000007524 organic acids Chemical class 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000009835 boiling Methods 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
238000000605 extraction Methods 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
235000005985 organic acids Nutrition 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000001273 butane Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000010908 decantation Methods 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
238000000227 grinding Methods 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
239000000178 monomer Substances 0.000 description 1
150000002899 organoaluminium compounds Chemical class 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000010408 sweeping Methods 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

SU752170532A 1974-09-03 1975-09-02 Способ получени катализатора полимеризации и сополимеризации с -с -альфаолефинов SU654175A3 (ru)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP10055374A JPS5128189A (ja)	1974-09-03	1974-09-03	Koketsushoseihoriorefuin no kokatsuseijugohoho

Publications (1)

Publication Number	Publication Date
SU654175A3 true SU654175A3 (ru)	1979-03-25

Family

ID=14277120

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU752170532A SU654175A3 (ru)	1974-09-03	1975-09-02	Способ получени катализатора полимеризации и сополимеризации с -с -альфаолефинов

Country Status (7)

Country	Link
JP (1)	JPS5128189A (de)
AT (1)	AT335730B (de)
GB (1)	GB1502886A (de)
HU (1)	HU173365B (de)
PL (1)	PL102871B1 (de)
RO (1)	RO71808A (de)
SU (1)	SU654175A3 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5812888B2 (ja) *	1976-08-27	1983-03-10	三井化学株式会社	ポリオレフインの製造方法
JPS53109587A (en) *	1977-03-07	1978-09-25	Mitsui Petrochem Ind Ltd	Polymerization of olefin
LU77489A1 (de) *	1977-06-06	1979-01-19
JPS5426891A (en) *	1977-08-02	1979-02-28	Mitsui Petrochem Ind Ltd	Preparation of olefin copolymer
IT1092448B (it) *	1978-02-09	1985-07-12	Montedison Spa	Catalizzatori per la polimerizzazione delle alfa-olefine
DE2839136A1 (de) *	1978-09-08	1980-03-20	Bayer Ag	Katalysator auf einem festen traeger zur polymerisation von alpha -olefinen
JPS6037804B2 (ja)	1979-04-11	1985-08-28	三井化学株式会社	オレフイン重合触媒用担体の製法
JPS5611908A (en) *	1979-07-11	1981-02-05	Mitsui Petrochem Ind Ltd	Preparation of olefin polymer
JPS56118340A (en) *	1980-02-25	1981-09-17	Hitachi Ltd	Pattern formation device by laser
JPS5770104A (en) *	1980-10-17	1982-04-30	Toa Nenryo Kogyo Kk	Catalytic component for alpha-olefin polymerization and its use
KR100341040B1 (ko)	1994-08-18	2002-11-23	칫소가부시키가이샤	고강성프로필렌-에틸렌블록공중합체조성물및이의제조방법
JP3355864B2 (ja) *	1995-04-24	2002-12-09	チッソ株式会社	高剛性プロピレン・エチレンブロック共重合体の連続製造法
KR100334163B1 (ko)	1998-12-04	2002-10-25	삼성종합화학주식회사	올레핀중합또는공중합방법
EP3564346A4 (de)	2016-12-27	2020-09-02	Mitsui Chemicals, Inc.	Schmierölzusammensetzung, viskositätsmodifikator für schmieröl und additivzusammensetzung für schmieröl
EP4023737A4 (de)	2019-08-29	2023-08-30	Mitsui Chemicals, Inc.	Schmierölzusammensetzung

1974
- 1974-09-03 JP JP10055374A patent/JPS5128189A/ja active Granted
1975
- 1975-09-01 RO RO7583298A patent/RO71808A/ro unknown
- 1975-09-02 HU HU75MI591A patent/HU173365B/hu unknown
- 1975-09-02 SU SU752170532A patent/SU654175A3/ru active
- 1975-09-03 PL PL18308475A patent/PL102871B1/pl unknown
- 1975-09-03 GB GB3629375A patent/GB1502886A/en not_active Expired
- 1975-09-03 AT AT679875A patent/AT335730B/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
AT335730B (de)	1977-03-25
GB1502886A (en)	1978-03-08
ATA679875A (de)	1976-07-15
RO71808A (ro)	1982-05-10
PL102871B1 (pl)	1979-04-30
HU173365B (hu)	1979-04-28
JPS565403B2 (de)	1981-02-04
JPS5128189A (ja)	1976-03-09

Publication	Publication Date	Title
US4400302A (en)	1983-08-23	Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
KR930008452B1 (ko)	1993-09-04	분자량 분포가 좁은 입체규칙성 중합체의 제조방법
JP2557054B2 (ja)	1996-11-27	アルフア−オレフイン重合用触媒組成物
US3969332A (en)	1976-07-13	Polymerization of ethylene
JPS6330328B2 (de)	1988-06-17
EP0133783B1 (de)	1989-04-26	Trägerkatalysator für die Polymerisation von Äthylen bei hoher Temperatur
US4543389A (en)	1985-09-24	Copolymerization catalyst and process for polymerizing impact resistant ethylene-propylene polymers
US4520163A (en)	1985-05-28	Process of sequentially copolymerizing propylene-ethylene copolymers and catalyst therefor
JPS6015410A (ja)	1985-01-26	アルフア−オレフイン類の重合体類製造のための溶液法
US4303769A (en)	1981-12-01	Process for preparing substantially gel-free cis-1,4-polybutadiene
KR0137775B1 (ko)	1998-05-01	알파-올레핀의 입체특이적 중합법과 중합용 촉매
US4208304A (en)	1980-06-17	Catalyst system for producing ethylene polymers
US4007133A (en)	1977-02-08	Process for the manufacture of a catalyst
JP3340730B2 (ja)	2002-11-05	α−オレフィンの重合方法
US4316975A (en)	1982-02-23	Titanium trichloride catalytic component and method for homo- or copolymerization of α-olefin
US3944529A (en)	1976-03-16	Process for the preparation of polybutene-1
US3634384A (en)	1972-01-11	Polymerization catalysts
EP0576413B1 (de)	1999-01-13	Elektrondonor zur verbesserten Olefinpolymerisation
US4420417A (en)	1983-12-13	Ethylene polymerization catalyst and a process for its preparation
JPS6211705A (ja)	1987-01-20	プロピレン重合体の製造法
JPS6072903A (ja)	1985-04-25	α−オレフィンの重合法
EP0031213B1 (de)	1985-05-15	1-Olefinpolymerisation und Katalysator für die 1-Olefinpolymerisation
US4981928A (en)	1991-01-01	Supported polyolefin catalyst for polymerization of ethylene under high temperatures
US4626519A (en)	1986-12-02	Supported polyolefin catalyst components and methods of making and using same
JPH0680092B2 (ja)	1994-10-12	オレフイン重合用触媒成分の調製法