TH85808A - Mixtures containing 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene - Google Patents

Abstract

DC60 (23/08/49) disclosed herein is a mixture. 3,3,4,4,5,4,6,6,6-nonafluoro-1-hexene for Use in refrigeration and air conditioning systems Especially in the centrifugal compressor system was also disclosed as 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with bromo Fluorocarbon, ketone, alcohol, chlorocarbon, ether, esters, 4-chloro-1,1,2,3,3,4-hexa. Fluorobutene, N- (DIfluoromethyl) -N, N-dimethylamine at least one type or a mixture of substances These, which are aciotropes, or near the azotropes. Disclosed herein is a mixture 3,3,4,4,5,4,6,6,6-nonafluoro-1-hexene for Use in refrigeration and air conditioning systems Especially in the centrifugal compressor system was also disclosed as 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with bromo Fluorocarbon, ketone, alcohol, chlorocarbon, ether, ester, 4-chloro-1,1,2,3,3,4-hexa. Fluorobutene, N- (DIfluoromethyl) -N, N-dimethylamine at least one type or a mixture of substances These, which are aciotropes, or near the azotropes.

Claims (31)

1. A refrigerant or heat-transferring fluid mixture containing 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and at least one compound selected from the group containing 4-bromo-3,3,4,4-tetrafluorobutane, 2-bromo-1,1,1,3,4,4,4-heptafluorobutane, 3-bromo-1,1,1,2,4,4-5,5,5-nonafluorobutene, 1-bromo-3,3,4,4,4-pentafluorobutene, 2-bromo-3,3,4,4,4-pentafluorobutene, acetone, and 2-chloro-1,1,1,4,4,5,5,5-octafluoro-2-(trifluoromethyl)-3-pentanone. 1,1,1-2,2,5,5,5-octafluoro-4-(trifluoromethyl)-3-pentanone, methanol, ethanol, n-propanol, isopropanol, 2,2,2-trifluoroethanol, 2,2,3,3,3-pentafluoropropanol, 2,2,3,3-tetrafluoropropanol, hexafluoroisopropanol, 1,1-dichloroethane, cis-1,2-dichloroethylene, trans-1,2-dichloroethylene, diisopropyl ether, 1,2-dimethoxyethane, dimethoxymethane, methyl-tert-butyl ether, methyl acetate, methyl formate, ethyl acetate, ethyl formate 4-chloro-1,1,2,3,3,4-hexafluorobutene N-(difluoromethyl)-N,N-dimethylamine 2. Refrigerant or heat-transmitting fluid mixture as per Requisition 1, where the mixture is selectable from the group containing: PFBE and 4-bromo-3,3,4,4-tetrafluorobutane; PFBE and 2-bromo-1,1,1,3,4,4,4-heptafluorobutane; PFBE and 3-bromo-1,1,1,2,4,4-5,5,5-nonafluorobutane; PFBE and 1-bromo-3,3,4,4,4-pentafluorobutane; PFBE and 2-bromo-3,3,4,4,4-pentafluorobutane; PFBE and acetone; PFBE and 2-chloro-1,1,1,4,4,5,5,5-octafluoro-2-(trifluoromethyl)-3-pentanone; PFBE and 1,1,1-2,2,5,5,5-octafluoro-4-(trifluoromethyl)-3-pentanone; PFBE and methanol; PFBE and ethanol; PFBE and n-propanol; PFBE and isopropanol; PFBE and 2,2,2-trifluoroethanol; PFBE and 2,2,3,3,3-pentafluoropropanol; PFBE and 2,2,3,3-tetrafluoropropanol; PFBE and hexafluoroisopropanol; PFBE and 1,1-dichloroethane; PFBE and cis-1,2-dichloroethylene; PFBE and trans-1,2-dichloroethylene; PFBE and diisopropyl ether; PFBE and 1,2-dimethoxyethane; PFBE and dimethoxymethane; PFBE and methyl-tert-butyl ether; PFBE and methyl acetate; PFBE and methyl formate; PFBE and ethyl acetate; PFBE and ethyl formate; PFBE and 4-chloro-1,1,2,3,3,4-hexafluorobutene; and PFBE and N-(difluoromethyl)-N,N-dimethylamine. 3. Refrigerant or heat-transmitting fluid mixture as per Reservion 1, where the mixture is an azeotrope or near-azeotrope mixture of selectable groups; approximately 28 to 76 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 24 to 72 percent by weight of 4-bromo-3,3,4,4-tetrafluorobutene; approximately 1 to 99 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 99 percent by weight of 2-bromo-1,1,1,3,4,4,4-heptafluorobutene; Percentages by weight of approximately 1 to 99 of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentages by weight of approximately 1 to 99 of 3-bromo-1,1,1,2,4,4,5,5,5-nonafluorobutene; percentages by weight of approximately 1 to 85 of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentages by weight of approximately 15 to 99 of 1-bromo-3,3,4,4-pentafluorobutene; percentages by weight of approximately 54 to 89 of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentages by weight of approximately 11 to 46 of acetone; Percentage by weight of approximately 1 to 99 of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight of approximately 1 to 99 of 2-chloro-1,1,1,4,4,5,5,5-octafluoro-2-(trifluoromethyl)-3-pentanone; percentage by weight of approximately 1 to 99 of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight of approximately 1 to 99 of 1,1,1,2,2,5,5,5-octafluoro-4-(trifluoromethyl)-3-pentanone; The percentage by weight is approximately 77 to 96 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 4 to 23 percent of methanol; the percentage by weight is approximately 76 to 97 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 3 to 24 percent of ethanol; the percentage by weight is approximately 76 to 98 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 2 to 24 percent of n-propanol; the percentage by weight is approximately 73 to 97 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 3 to 27 percent of isopropanol; The percentage by weight is approximately 58 to 93 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 7 to 42 percent of 2,2,2-trifluoroethanol; the percentage by weight is approximately 50 to 91 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 9 to 50 percent of 2,2,3,3,3-pentafluoropropanol; the percentage by weight is approximately 60 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 40 percent of 2,2,3,3-tetrafluoropropanol; The percentage by weight is approximately 28 to 86 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 14 to 72 percent of hexafluoroisopropanol; the percentage by weight is approximately 39 to 84 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 16 to 61 percent of 1,1-dichloroethane; the percentage by weight is approximately 35 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 65 percent of cis-1,2-dichloroethylene; The percentage by weight is approximately 22 to 79 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 21 to 78 percent of trans-1,2-dichloroethylene; the percentage by weight is approximately 1 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 99 percent of diisopropyl ether; the percentage by weight is approximately 64 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 36 percent of 1,2-dimethoxyethane; Percentage by weight approximately 1 to 81 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight approximately 19 to 99 percent of dimethoxymethane; percentage by weight approximately 1 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight approximately 1 to 99 percent of methyl tert-butyl ether; percentage by weight approximately 49 to 87 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight approximately 13 to 51 percent of methyl acetate; The percentage by weight is approximately 37 to 83 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 17 to 63 percent of methyl formate; the percentage by weight is approximately 58 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 42 percent of ethyl acetate; the percentage by weight is approximately 46 to 86 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 14 to 54 percent of ethyl formate; Percentage by weight of approximately 1 to 99 of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight of approximately 1 to 99 of 4-chloro-1,1,2,3,3,4-hexafluorobutene; and percentage by weight of approximately 1 to 99 of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight of approximately 1 to 99 of N-(difluoromethyl)-N,N-dimethylamine. 4. Refrigerant or heat-transmitting fluid mixture as per claim 1, where the mixture is an azeotrope or near-azeotrope mixture of selectable groups containing approximately 40 to 70 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 30 to 60 percent by weight of 4-bromo-3,3,4,4-tetrafluorobutene; approximately 40 to 99 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 60 percent by weight of 2-bromo-1,1,1,3,4,4,4-heptafluorobutene; The percentage by weight is approximately 40 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 60 percent of 3-bromo-1,1,1,2,4,4,5,5,5-nonafluorobutene; the percentage by weight is approximately 40 to 85 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 15 to 60 percent of 1-bromo-3,3,4,4,4-pentafluorobutene; Percentage by weight approximately 40 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight approximately 1 to 60 percent of 2-bromo-3,3,4,4,4-pentafluorobutene; percentage by weight approximately 60 to 89 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight approximately 1 to 40 percent of acetone; percentage by weight approximately 40 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and percentage by weight approximately 1 to 60 percent of 2-chloro-1,1,1,4,4,5,5,5-octafluoro-2-(trifluoromethyl)-3-pentanone; The percentage by weight is approximately 40 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 60 percent of 1,1,1,2,2,5,5,5-octafluoro-4-(trifluoromethyl)-3-pentanone; the percentage by weight is approximately 80 to 96 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 4 to 20 percent of methanol; the percentage by weight is approximately 80 to 97 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 3 to 20 percent of ethanol. The percentage by weight is approximately 80 to 98 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 2 to 20 percent of n-propanol; the percentage by weight is approximately 80 to 97 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 3 to 20 percent of isopropanol; the percentage by weight is approximately 60 to 93 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 7 to 40 percent of 2,2,2-trifluoroethanol; The percentage by weight is approximately 60 to 91 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 9 to 40 percent of 2,2,3,3,3-pentafluoropropanol; approximately 70 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 30 percent of 2,2,3,3-tetrafluoropropanol; approximately 40 to 86 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 14 to 60 percent of hexafluoroisopropanol. The percentage by weight is approximately 40 to 80 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 20 to 60 percent of 1,1-dichloroethane; the percentage by weight is approximately 40 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 60 percent of cis-1,2-dichloroethylene; the percentage by weight is approximately 30 to 79 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 21 to 70 percent of trans-1,2-dichloroethylene; The percentage by weight is approximately 40 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 60 percent of diisopropyl ether; approximately 70 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 30 percent of 1,2-dimethoxyethane; approximately 20 to 81 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 19 to 80 percent of dimethoxymethane; The percentage by weight is approximately 40 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 60 percent of methyl tert-butyl ether; the percentage by weight is approximately 60 to 87 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 13 to 40 percent of methyl acetate; the percentage by weight is approximately 40 to 87 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 13 to 60 percent of methyl formate; The percentage by weight is approximately 60 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 40 percent of ethyl acetate; the percentage by weight is approximately 50 to 86 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 14 to 50 percent of ethyl formate; the percentage by weight is approximately 40 to 99 percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 60 percent of 4-chloro-1,1,2,3,3,4-hexafluorobutene; And approximately 40 to 99 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and approximately 1 to 60 percent by weight of n-(difluoromethyl)-N,N-dimethylamine. 5. The refrigerant or heat-transmitting fluid mixture as described in Reservation 1, where the mixture is an azeotrope or near-azeotrope mixture of selectable groups consisting of: 51.6 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 48.4 percent by weight of 4-bromo-3,3,4,4-tetrafluorobutene with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 39.1 °C; 57.7 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 42.3 percent by weight of 1-bromo-3,3,4,4,4-pentafluorobutene. With a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 49.8 °C; 55.3 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 44.7 percent by weight of 2-bromo-3,3,4,4-pentafluorobutene with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 56.9 °C; 76.0 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 24.0 percent by weight of acetone with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 41.5 °C; 91.9 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 8.1 percent by weight of methanol with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 44.2 °C; 93.2 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 6.8 percent by weight of ethanol with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 49.4 °C; 95.9 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 4.1 percent by weight of n-propanol with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 54.2 °C; 92.7 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 7.3 percent by weight of isopropanol with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 50.9 °C; 84.7 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 15.3 percent by weight of 2,2,2-trifluoroethanol. With a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 48.6 °C; 82.5 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 17.5 percent by weight of 2,2,3,3,3,-pentafluoropropanol with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 51.2 °C; 93.3 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 6.7 percent by weight of 3,3,3,3-tetrafluoropropanol with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 57.1 °C; 55.9 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 44.1 percent by weight of hexafluoroisopropanol at a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 48.8 °C; 63.9 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 36.1 percent by weight of 1,1-dichloroethane at a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 44.5 °C; 66.1 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 33.9 percent by weight of cis-1,2-dichloroethylene. With a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 50.4 °C; 52.8 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 47.2 percent by weight of trans-1,2-dichloroethylene with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 41.3 °C; 92.7 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 7.3 percent by weight of 1,2-dimethoxyethane with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 58.1 °C; 53.7 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 46.3 percent by weight of dimethoxymethane with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 40.6 °C; 69.5 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 30.5 percent by weight of methyl tert-butyl ether with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 57.2 °C; 72.4 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 27.6 percent by weight of methyl formate with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 41.9 °C; 57.2 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 42.8 percent by weight of methyl formate with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 26.0 °C; 87.3 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 12.7 percent by weight of ethyl acetate with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 56.8 °C; 68.8 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 31.2 percent by weight of ethyl formate with a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 40.4 °C; 44.2 percent by weight of 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and 55.8 percent by weight of N-(difluoromethyl)-N,N-dimethylamine at a vapor pressure of approximately 14.7 psia (101 kPa) at a temperature of approximately 46.8 °C; 6. The cooling process involves evaporating the substance, cooling the heat transfer mixture of claim 1 in the vicinity of the cooled unit, and subsequently condensing the mixture. 7. The process for generating heat, which involves condensing the refrigerant or heat transfer mixture of claim 1 in the vicinity of the heated unit and subsequently evaporating the mixture. 8. The process for heat transfer, which involves the transfer of the mixture of claim 1 from the heat source to the heat sink. 9. The mixtures under Reputation 1 also contain select lubricants from a group consisting of mineral oil, paraffin, naphthene, synthetic paraffin, alkylbenzene, poly-alpha-olefin, polyalkylene glycol, polyvinyl ether, polyoxide and mixtures thereof. 10. A mixture as described in Reservation 1, which also contains at least one selectable ultraviolet fluorescent dye from the group consisting of naphthalimide, perylene, coumarin, anthrazine, phenathrazine, xanthine, thiosanthine, naphthoxanthine, fluorescein, derivatives of such dyes, and combinations of such dyes. 11. The mixtures described in Reservation 10 also contain at least one selectable solute from the hydrocarbon, dimethyl ether, polyalkylene glycol ether, amide, ketone, nitrile, chlorocarbon, ester, lactone, aryl ether, hydrofluoroether, and 1,1,1-trifluoroalkane groups; and where the coolant and solute are not the same compound. 12. A mixture according to claim 11 where such solvent is selectable from a group consisting of (a) polyoxyalkylene glycol ethers denoted by the structural formula R1[(OR2)xOR3]y, where x is an integer from 1 to 3; y is an integer from 1 to 4; R1 is selectable from hydrogen and aliphatic hydrocarbon radicals with 1 to 6 carbon atoms and the side bonded to y; R2 is selectable from aliphatic hydrocarbon radicals with 2 to 4 carbon atoms; R3 is selectable from hydrogen and aliphatic and alicyclic hydrocarbon radicals with 1 to 6 carbon atoms; at least one group of R1 and R3 is selectable from such hydrocarbon radicals, and where polyoxyalkylene (b) Amides represented by the structural formula R1C(O)NR2R3 and cyclo-[R4CN(R5)-], where R1, R2, R3 and R5 are freely selective from aliphatic and alicyclic hydrocarbon radicals with 1 to 12 carbon atoms and at most 1 aromatic radical with 6 to 12 carbon atoms; R4 is selective from aliphatic hydrocarbon radicals with 3 to 12 carbon atoms, and where such amides have molecular weights of atomic masses from approximately 100 to approximately 300 units; (c) Ketones represented by the structural formula R1C(O)R2, where R1 and R2 are freely selective. (d) Nitriles represented by the structural formula R1CN, where R1 is chosen from aliphatic, alicyclic, or aryl hydrocarbons radically containing 1 to 12 carbon atoms, and where such ketones have a molecular weight with an atomic mass of approximately 70 to approximately 300 units; (e) Chlorocarbons represented by the structural formula RCIx, where; x is 1 or 2; R is chosen from aliphatic and alicyclic hydrocarbons radically containing 1 to 12 carbon atoms, and where such chlorocarbons have a molecular weight with an atomic mass of approximately 100 to approximately 200 units; (f) aryl ethers represented by the structural formula R1OR2, where R1 is chosen from aryl Radical hydrocarbons with 6 to 12 carbon atoms; R2 is selective from aliphatic radical hydrocarbons with 1 to 4 carbon atoms; and where such aryl ethers have a molecular weight of approximately 100 to approximately 150 atomic mass units (g); 1,1,1-trifluoroalkanes represented by the structural formula CF3R1, where R1 is selective from aliphatic and alicyclic radical hydrocarbons with approximately 5 to approximately 15 carbon atoms (h); fluoroethers represented by the structural formula R1OCF2CF2H, where R1 is selective from aliphatic and alicyclic radical hydrocarbons with approximately 5 to approximately 15 carbon atoms; Or where such fluoroethers are derived from fluoroolefins and polyols, where such fluoroolefins are of the type CF2=CXY, where X is hydrogen, chlorine, or fluorine, and Y is chlorine, fluorine, CF3, or ORf, where Rf is CF3, C2F5, or C3F7; and such polyols are straight-chain or branched, where such straight-chain polyols are of the type HOCH2(CHOH)x(CRR')yCH2OH, where R and R7 are hydrogen, CH3, or C2H5, x is an integer from 0-4, y is an integer from 0-3, and z is 0 or 1, and such branched polyols are of the type... C(OH)t(R)t(R)u(CH2OH)y[(CH2)mCH2OH]w, where R may be hydrogen, CH3 or C2H5m are integers from 0 to 3, t and u are 0 or 1, v and w are integers from 0 to 4 and also where t+u+v+w= 4; and (i) lactone can be represented by structures [B],[C], and [D]: (chemical formula) [A] (chemical formula) [B] (chemical formula) [C] where R1 to R8 are freely selectable from hydrogen, saturated and unsaturated radical hydrocarbide, cyclic, bicyclic, straight-chain, branched; and the molecular weight of the atomic mass is from approximately 100 to approximately 300 units; and (j) esters that can be represented by the general structural formula R1CO2R2 in which R1 and R2 are freely selectable from saturated and unsaturated alkyl and aryl radicals, straight-chain and cyclic, and in which such esters have molecular weights with atomic masses ranging from approximately 80 to approximately 550 units. 13. A method for measuring the mixture of claim 10 in a compressive cooling or air conditioning device, which includes the preparation of such mixture for the use of the device and the preparation of appropriate equipment for measuring such mixture at the leak point or in an approximate quantity within the device. 14. The method of inducing cooling in claim 6 where the cooling agent or heat transfer mixture also contains at least one violet fluorescent dye of choice from the group comprising naphthalimide, perylene, coumarin, anthrazine, phenanthrazine, xanthene, thioxanthene, naphthoxanthene, fluorescein, derivatives of such dyes and combinations of these. 15. Methods of heat production as per claim 7 where the coolant or heat transfer mixture also contains at least one ultraviolet dye of choice from a group consisting of naphthalimide, perylene, coumarin, anthrazine, phenanthrazine, xanthene, thiosanthene, naphthoxanthene, fluorescein, derivatives of such dyes and combinations of these. 16. The mixtures as described in Claim 1 that also contain stabilizers, dehydrators, or odor enhancers. 17. Mixtures as per claim 16 where such stabilizers are selectable from a group consisting of nitromethanes, barrier phenols, hydroxylamides, thiols, phosphites and lactones. 18. The method in claim 6 where such method involves causing cooling in a refrigeration unit or air conditioning unit that uses a multi-stage centrifugal compressor. 19. The method described in claim 18 where a multi-stage centrifugal compressor is used is a two-stage centrifugal compressor. 20. The method described in claim 7, where such method involves the production of heat in a refrigeration unit using a multi-stage centrifugal compressor. 21. The method specified in claim 20 where a multi-stage centrifugal compressor is used is a two-stage centrifugal compressor. 22. The mixture as described in claim 16 where the dehydrating agent is an ester hormone. 23. The method in claim 6 where such method involves the production of cooling or air conditioning using a mini-centrifugal compressor powered by a turbine driven in an engine by used gas. 24. The method in claim 6 where such method involves the production of cooling or air conditioning using a mini-centrifugal compressor powered by a proportional gear drive component with a proportional belt drive. 25. Refrigeration, air conditioning or heat pumps containing the refrigerant mixture referred to in claim 1. 26. The equipment as specified in claim 25 where such equipment uses a multi-stage centrifugal compressor. 27. The equipment referred to in claim 26, where such multi-stage centrifugal compressor is a 2-stage centrifugal compressor. 28. Procedures for removing residues from surfaces containing: (a) surface contact with an aceotrope or aceotrope-like mixture containing perfluorobutylethylene (3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene (PFBE)) and at least one hydrofluorocarbon of choice from a group containing: 4-bromo-3,3,4,4-tetrafluorobutane, 2-bromo-1,1,1,3,4,4,4-heptafluorobutane, 3-bromo-1,1,1,2,4,4-5,5,5-nonafluorobutene, 1-bromo-3,3,4,4,4-pentafluorobutene. 2-Bromo-3,3,4,4,4-pentafluorobutene, acetone, 2-chloro-1,1,1,4,4,5,5,5-octafluoro-2-(trifluoromethyl)-3-pentanone, 1,1,1-2,2,5,5,5-octafluoro-4-(trifluoromethyl)-3-pentanone, methanol, ethanol, n-propanol, isopropanol, 2,2,2-trifluoroethanol, 2,2,3,3,3-pentafluoropropanol, 2,2,3,3-tetrafluoropropanol, hexafluoroisopropanol, 1,1-dichloroethane, cis-1,2-dichloroethylene, trans-1,2-dichloroethylene Diisopropyl ether 1,2-dimethoxyethane dimethoxymethane methyl-tert-butyl ether methyl acetate methyl formate ethyl acetate ethyl formate 4-chloro-1,1,2,3,3,4-hexafluorobutene N-(difluoromethyl)-N,N-dimethylamine (b) Surface removal from the mixture 29. The process as outlined in claim 28 where the said residue contains oil. 30. The process as described in claim 28 where the said residue contains rosin flux. 31. The process as described in claim 28 where the surface is an integrated circuit device.