TR200000665T2 - Çift metalli kompleksler ve bunlardan elde edilen polimerizasyon katalizatörler. - Google Patents

Çift metalli kompleksler ve bunlardan elde edilen polimerizasyon katalizatörler.

Info

Publication number
TR200000665T2
TR200000665T2 TR2000/00665T TR200000665T TR200000665T2 TR 200000665 T2 TR200000665 T2 TR 200000665T2 TR 2000/00665 T TR2000/00665 T TR 2000/00665T TR 200000665 T TR200000665 T TR 200000665T TR 200000665 T2 TR200000665 T2 TR 200000665T2
Authority
TR
Turkey
Prior art keywords
metal complexes
obtained therefrom
polymerization catalysts
catalysts obtained
dual metal
Prior art date
Application number
TR2000/00665T
Other languages
English (en)
Inventor
T. Patton Jasson
J.Marks Tobin
Li Liting
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Publication of TR200000665T2 publication Critical patent/TR200000665T2/tr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Mevcut bulus, iki metal merkezi içeren Grup 3-6 veya latanid kompleksler, bunlarin, güçlü lewis asitleri, Bronsted asit tuzlari ve bir katyonik oksidizassyon aracisi içeren tuzlar ile birlestirilmeden elde edilen veya uygun, koordine olmayan atil anyonlarin varliginda kütle elektrolizine maruz kalan katalizatörler, ve olefinleri, diolefinleri ve/veya asetik olarak doymamis monomerleri polimerize etmek için bu tür katalizörlerin kullanimi ile ilgilidir.
TR2000/00665T 1997-09-15 1998-08-28 Çift metalli kompleksler ve bunlardan elde edilen polimerizasyon katalizatörler. TR200000665T2 (tr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6071297P 1997-09-15 1997-09-15
US9229498P 1998-07-10 1998-07-10

Publications (1)

Publication Number Publication Date
TR200000665T2 true TR200000665T2 (tr) 2000-09-21

Family

ID=26740275

Family Applications (1)

Application Number Title Priority Date Filing Date
TR2000/00665T TR200000665T2 (tr) 1997-09-15 1998-08-28 Çift metalli kompleksler ve bunlardan elde edilen polimerizasyon katalizatörler.

Country Status (14)

Country Link
US (1) US6153776A (tr)
EP (1) EP1015462B1 (tr)
JP (1) JP2001516762A (tr)
KR (1) KR20010024020A (tr)
CN (1) CN1270596A (tr)
AR (1) AR017104A1 (tr)
AT (1) ATE222917T1 (tr)
AU (1) AU9037598A (tr)
BR (1) BR9812308A (tr)
CA (1) CA2303519A1 (tr)
DE (1) DE69807506T2 (tr)
NO (1) NO20001306D0 (tr)
TR (1) TR200000665T2 (tr)
WO (1) WO1999014222A1 (tr)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6284698B1 (en) * 1997-09-15 2001-09-04 The Dow Chemical Company Highly activated bimetallic complexes and polymerization process
US6228790B1 (en) * 1998-06-29 2001-05-08 Industrial Technology Research Institute Dinuclear metallocene catalyst for preparing high molecular weight olefin polymer
EP1097161A1 (en) * 1998-07-10 2001-05-09 Exxon Chemical Patents Inc. Tethered monocyclopentadienyl polymerization catalysts
AU2001229571A1 (en) * 2000-02-11 2001-08-20 The Dow Chemical Company Dinuclear group 4 metal boron or aluminum bridge containing ansa-complexes
KR100455713B1 (ko) * 2001-01-29 2004-11-06 호남석유화학 주식회사 올레핀 중합용 다중핵 메탈로센 촉매 및 이를 이용한중합방법
DE10114345A1 (de) * 2001-03-23 2002-09-26 Bayer Ag Katalysator mit einer Donor-Akzeptor-Wechselwirkung
US6642400B2 (en) 2001-09-26 2003-11-04 Univation Technologies, Llc Linked metallocene complexes, catalyst systems, and olefin polymerization processes using same
CN1691979A (zh) * 2001-11-30 2005-11-02 埃克森美孚化学专利公司 具有高活性的双金属催化剂
KR100576971B1 (ko) * 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US7172987B2 (en) * 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
WO2004112301A2 (en) * 2003-06-11 2004-12-23 Wtviii, Inc. Mark up language authoring system
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7276567B2 (en) * 2004-04-16 2007-10-02 Exxonmobil Chemical Patents Inc. Heterocyclic substituted metallocene compounds for olefin polymerization
DE102004025938A1 (de) * 2004-05-27 2005-12-22 Bayer Ag Dinukleare Übergangsmetallkomplexe
CN102321201B (zh) 2004-06-16 2013-06-26 陶氏环球技术有限责任公司 选择聚合改性剂的方法
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
WO2007078134A1 (en) * 2005-12-30 2007-07-12 Lg Chem. Ltd. Transition metal complexes and preparation methods thereof
KR100874032B1 (ko) * 2006-02-01 2008-12-17 주식회사 엘지화학 전이 금속 화합물을 포함하는 촉매 조성물 및 이를 이용한올레핀 중합
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
ES2446294T3 (es) 2007-06-04 2014-03-07 Exxonmobil Chemical Patents Inc. Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución
US7863210B2 (en) 2007-12-28 2011-01-04 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US8012900B2 (en) * 2007-12-28 2011-09-06 Chevron Phillips Chemical Company, L.P. Nano-linked metallocene catalyst compositions and their polymer products
US8080681B2 (en) * 2007-12-28 2011-12-20 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US7812104B2 (en) * 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US7919639B2 (en) * 2009-06-23 2011-04-05 Chevron Phillips Chemical Company Lp Nano-linked heteronuclear metallocene catalyst compositions and their polymer products
WO2013040276A1 (en) * 2011-09-13 2013-03-21 California Institute Of Technology Multi-metallic organometallic complexes, and related polymers, compositions, methods and systems
CN105308059B (zh) 2013-06-25 2018-05-18 株式会社Lg化学 催化剂组合物、其制备方法及使用其制备聚烯烃的方法
KR101600583B1 (ko) 2013-06-25 2016-03-08 주식회사 엘지화학 이핵 메탈로센 화합물, 및 이의 제조방법
KR20170036713A (ko) * 2014-07-17 2017-04-03 메르크 파텐트 게엠베하 바이메소젠성 화합물 및 메소젠성 매질
CN105273010B (zh) * 2015-10-29 2018-07-13 中国石油天然气股份有限公司 一种限制构型双核茂金属化合物及其制备方法与应用
CN105273000B (zh) * 2015-10-29 2018-07-10 中国石油天然气股份有限公司 不对称限制构型双核茂金属化合物及其制备方法与应用
KR101918484B1 (ko) 2017-11-15 2019-01-31 금호폴리켐 주식회사 탄성 공중합체 제조용 촉매 조성물 및 이를 이용한 에틸렌 및 알파-올레핀 또는 에틸렌, 알파-올레핀 및 비공액 디엔을 포함하는 탄성 공중합체의 제조 방법
CN111741961B (zh) 2018-02-19 2024-01-12 埃克森美孚化学专利公司 催化剂、催化剂体系和使用它们的方法
JP7495880B2 (ja) 2018-03-30 2024-06-05 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合のための助触媒としての高溶解性アルキル置換ホウ酸カルベニウム
US12037440B2 (en) 2018-03-30 2024-07-16 Dow Global Technologies Llc Highly soluble bis-borate as binuclear co-catalysts for olefin polymerization
JP7304880B2 (ja) 2018-03-30 2023-07-07 ダウ グローバル テクノロジーズ エルエルシー 二核オレフィン重合活性化剤
CN112703208B (zh) * 2018-09-18 2023-02-24 阿朗新科荷兰有限公司 催化剂混合物
US11802170B2 (en) 2021-04-29 2023-10-31 Exxonmobil Chemical Patents Inc. Polyolefins prepared with binuclear metallocene catalysts
CN117624221A (zh) * 2022-08-17 2024-03-01 中化学科学技术研究有限公司 一类氮杂双核大体积阴阳离子型配合物及其制备方法和应用
CN117903208A (zh) * 2022-10-11 2024-04-19 中国石油化工股份有限公司 膦-酚后过渡金属配合物及其制备方法和应用
CN116284514A (zh) * 2023-02-28 2023-06-23 天津科技大学 限制几何构型的阳离子茂金属催化剂、及其合成方法和应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242099A (en) * 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
PL166690B1 (pl) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
EP0739897A1 (de) * 1995-04-27 1996-10-30 Hoechst Aktiengesellschaft Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator
DE19546501A1 (de) * 1995-12-13 1997-06-19 Hoechst Ag Metallocenverbindung

Also Published As

Publication number Publication date
US6153776A (en) 2000-11-28
BR9812308A (pt) 2000-09-05
WO1999014222A1 (en) 1999-03-25
DE69807506T2 (de) 2003-05-28
NO20001306L (no) 2000-03-14
KR20010024020A (ko) 2001-03-26
EP1015462B1 (en) 2002-08-28
CN1270596A (zh) 2000-10-18
JP2001516762A (ja) 2001-10-02
CA2303519A1 (en) 1999-03-25
ATE222917T1 (de) 2002-09-15
EP1015462A1 (en) 2000-07-05
AR017104A1 (es) 2001-08-22
DE69807506D1 (de) 2002-10-02
AU9037598A (en) 1999-04-05
NO20001306D0 (no) 2000-03-14

Similar Documents

Publication Publication Date Title
TR200000665T2 (tr) Çift metalli kompleksler ve bunlardan elde edilen polimerizasyon katalizatörler.
AU5637899A (en) Polymerisation catalyst
TR200000688T2 (tr) Tadil edilmiş alümoksan katalizör aktivatörü.
TR200000533T2 (tr) Olefinlerin polimerizasyonu.
ES2155127T3 (es) Catalizador para la oxidacion en fase vapor de hidrocarbonos alcanos.
TR200001539T2 (tr) Esterleşme katalizörleri
CY1111199T1 (el) Μικτες ενωσεων ή θειϊκες μεταλλικες ενωσεις, ως συνδετικες ουσιες φωσφορικων
FI981718A0 (fi) Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö
FI955734A0 (fi) Olefiinien polymerointiin tarkoitetut komponentit ja katalysaattorit
GB2369120A (en) Metal complexes comprising a 2,6-diacylpyridine-ligand and their use in the polymerization of ethylene
DE60114599D1 (de) Adehyde enthaltende polymere als nassfestmittel
BR9813196A (pt) Processo para preparação de complexos metálicos de fulvenos
EA199800628A1 (ru) Диспергируемые в воде порошки пленкообразующих полимеров, полученных из этиленоненасыщенных мономеров
TR199903150T2 (tr) Zvitteryonlu katalizör etkinlestirici.
ES2127573T3 (es) Procedimiento para la obtencion de terpolimeros.
MY117253A (en) Novel colloid dispersion mixtures as protective colloid for aqueous emulsion polymerization, processes for preparing them and their use
Kramer Rescuing Boris.
KR920002368A (ko) 시이트, 호일 또는 웹 형태의 오프셋-인쇄판 제조용 지지물질, 이의 제조방법 및 이의 용도
ATE288935T1 (de) Gemischte dialkalimetallsalze von schwefelsäure die zumindest ein cesiumäquivalent enthalten als polymerisationskatalysatoren
CN107722172A (zh) 离子型复合纤维素及制备方法
Ouchi et al. Vinyl Polymerization. 377. Polymerization of Methyl Methacrylate by the System of Lysozyme, Copper (II) Ion, and Water
BR9909291A (pt) Catalisadores de polimerização e processos para obtê-los
AU4609497A (en) Process for the preparation of N-hydrocarbyl-substituted amides such as Tert-butylacrylamide via the Ritter reaction using solid heteropolyacid catalyst
ATE111348T1 (de) Kosmetische zusammensetzung auf der basis von chromo-carboxylaten.
ES536301A0 (es) Un procedimiento para preparar un catalizador para la polimerizacion o copolimerizacion de olefinas