TR200200546T2 - Metanol karbonilasyon işlemi için rodyum/inorganik iyodid katalizatör sistemi - Google Patents
Metanol karbonilasyon işlemi için rodyum/inorganik iyodid katalizatör sistemiInfo
- Publication number
- TR200200546T2 TR200200546T2 TR2002/00546T TR200200546T TR200200546T2 TR 200200546 T2 TR200200546 T2 TR 200200546T2 TR 2002/00546 T TR2002/00546 T TR 2002/00546T TR 200200546 T TR200200546 T TR 200200546T TR 200200546 T2 TR200200546 T2 TR 200200546T2
- Authority
- TR
- Turkey
- Prior art keywords
- methanol carbonylation
- rhodium
- catalyst system
- iodide catalyst
- inorganic iodide
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract 9
- 238000005810 carbonylation reaction Methods 0.000 title abstract 3
- 230000006315 carbonylation Effects 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 229910001505 inorganic iodide Inorganic materials 0.000 title 1
- 229910052703 rhodium Inorganic materials 0.000 title 1
- 239000010948 rhodium Substances 0.000 title 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 2
- 239000012535 impurity Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- IQGZCSXWIRBTRW-ZZXKWVIFSA-N (2E)-2-ethyl-2-butenal Chemical compound CC\C(=C/C)C=O IQGZCSXWIRBTRW-ZZXKWVIFSA-N 0.000 abstract 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 abstract 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 abstract 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Mevcut bulusun yöntemi karbonil katisiklarinin üretimini önemli ölçüde azaltarak önceki teknolojiye ait olan metanol karbonilasyon yöntemleri üzerinde bir ilerleme saglar. Reaksiyonun ilerleyisi sirasinda reaksiyon ortami içerisindeki metil iyodinin agirlikça yaklasik %5 ya da düsük bir oranda tutulmasi vasitasiyla metanol karbonilasyon reaksiyonlarinda karbonil katisiklarinin, özellikle asetaldehit'in, krotonaldehit'in ve 2-etil krotonaldehit'in üretiminin azaltildigi bulunmustur.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/386,561 US6323364B1 (en) | 1999-08-31 | 1999-08-31 | Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TR200200546T2 true TR200200546T2 (tr) | 2002-06-21 |
Family
ID=23526114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TR2002/00546T TR200200546T2 (tr) | 1999-08-31 | 2000-08-07 | Metanol karbonilasyon işlemi için rodyum/inorganik iyodid katalizatör sistemi |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US6323364B1 (tr) |
| EP (1) | EP1208072B1 (tr) |
| JP (1) | JP4693320B2 (tr) |
| KR (1) | KR100718422B1 (tr) |
| CN (1) | CN1183080C (tr) |
| AR (1) | AR025311A1 (tr) |
| AT (1) | ATE299855T1 (tr) |
| AU (1) | AU777960B2 (tr) |
| BR (1) | BR0013681B1 (tr) |
| CA (1) | CA2391720C (tr) |
| CZ (1) | CZ301625B6 (tr) |
| DE (1) | DE60021392T2 (tr) |
| ES (1) | ES2243289T3 (tr) |
| GC (1) | GC0000346A (tr) |
| MX (1) | MXPA02002260A (tr) |
| MY (1) | MY121879A (tr) |
| NO (1) | NO327990B1 (tr) |
| PL (1) | PL199389B1 (tr) |
| RS (1) | RS50147B (tr) |
| RU (1) | RU2217411C1 (tr) |
| TR (1) | TR200200546T2 (tr) |
| TW (1) | TWI227710B (tr) |
| UA (1) | UA69481C2 (tr) |
| WO (1) | WO2001016069A1 (tr) |
| ZA (1) | ZA200201045B (tr) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0427821D0 (en) * | 2004-12-17 | 2005-01-19 | Bp Chem Int Ltd | Catalyst and process |
| DE12007339T8 (de) * | 2006-04-14 | 2014-01-09 | Celanese International Corporation | Verfahren zur Reduktion von Aldehydkonzentration in einem Targetstrom |
| US7524988B2 (en) * | 2006-08-01 | 2009-04-28 | Lyondell Chemical Technology, L.P. | Preparation of acetic acid |
| US7208625B1 (en) | 2006-08-04 | 2007-04-24 | Lyondell Chemical Technology, L.P. | Removing permanganate-reducing impurities from acetic acid |
| US7485749B2 (en) * | 2006-08-22 | 2009-02-03 | Lyondell Chemical Technology, L.P. | Preparation of acetic acid |
| DE102009001765A1 (de) | 2009-03-23 | 2010-09-30 | Walter Ag | PVD beschichtetes Werkzeug |
| WO2011159268A1 (en) | 2010-06-14 | 2011-12-22 | Celanese Internaltional Corporation | Carbonylation process |
| US8785684B2 (en) | 2010-06-14 | 2014-07-22 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst, an iodide salt and a metallic co-catalyst selected from transition metals, indium, strontium, barium, zinc, tin and heteropoly acids |
| US8835681B2 (en) | 2010-06-14 | 2014-09-16 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst and a lanthanide metal co-catalyst |
| US8916727B2 (en) | 2011-12-16 | 2014-12-23 | Celanese International Corporation | Production of acetic acid with enhanced catalyst stability |
| US9340481B1 (en) * | 2014-11-14 | 2016-05-17 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
| CN107108431B (zh) | 2014-11-14 | 2023-02-03 | 国际人造丝公司 | 通过引入锂化合物生产乙酸的方法 |
| US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3769329A (en) | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
| DE3170215D1 (en) | 1980-12-29 | 1985-05-30 | Monsanto Co | Carbonylation process employing a catalyst stabilised in soluble form |
| US5281751A (en) * | 1983-12-02 | 1994-01-25 | Union Carbide Chemicals And Plastics Company Inc. | Synergistic production of carboxylic acids from alcohols |
| CA1231965A (en) * | 1983-12-02 | 1988-01-26 | David J. Schreck | Synergistic production of carboxylic acids from alcohols |
| CA1228867A (en) | 1984-05-03 | 1987-11-03 | Celanese Corporation | Methanol carbonylation process |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5026908A (en) | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
| GB9120902D0 (en) * | 1991-10-02 | 1991-11-13 | Bp Chem Int Ltd | Purification process |
| US5258751A (en) | 1991-11-04 | 1993-11-02 | Motorola, Inc. | Method of presenting messages for a selective call receiver |
| JP3244351B2 (ja) * | 1993-07-08 | 2002-01-07 | ダイセル化学工業株式会社 | 高純度酢酸の製造方法 |
| EP0759022B1 (fr) * | 1994-05-13 | 2000-01-26 | Acetex Chimie | Procede de preparation d'acides carboxyliques ou des esters correspondants en presence d'un catalyseur a base d'iridium et d'iodures sous forme soluble |
| JP3306227B2 (ja) * | 1994-07-06 | 2002-07-24 | ダイセル化学工業株式会社 | 酢酸および/または無水酢酸の製造法 |
| JP3244385B2 (ja) * | 1994-06-15 | 2002-01-07 | ダイセル化学工業株式会社 | 高純度酢酸の製造方法 |
| GB9512427D0 (en) * | 1995-06-19 | 1995-08-23 | Bp Chem Int Ltd | Process |
| US5817869A (en) * | 1995-10-03 | 1998-10-06 | Quantum Chemical Corporation | Use of pentavalent Group VA oxides in acetic acid processing |
| US6031129A (en) * | 1995-10-03 | 2000-02-29 | Quantum Chemical Corporation | Use of pentavalent group VA oxides in acetic acid processing |
| GB9521501D0 (en) * | 1995-10-20 | 1995-12-20 | Bp Chem Int Ltd | Process |
-
1999
- 1999-08-31 US US09/386,561 patent/US6323364B1/en not_active Expired - Lifetime
-
2000
- 2000-07-08 UA UA2002021704A patent/UA69481C2/uk unknown
- 2000-08-07 PL PL354052A patent/PL199389B1/pl not_active IP Right Cessation
- 2000-08-07 DE DE60021392T patent/DE60021392T2/de not_active Expired - Lifetime
- 2000-08-07 CZ CZ20020754A patent/CZ301625B6/cs not_active IP Right Cessation
- 2000-08-07 AU AU65276/00A patent/AU777960B2/en not_active Ceased
- 2000-08-07 RU RU2002108001/04A patent/RU2217411C1/ru not_active IP Right Cessation
- 2000-08-07 CA CA002391720A patent/CA2391720C/en not_active Expired - Fee Related
- 2000-08-07 CN CNB008121362A patent/CN1183080C/zh not_active Expired - Fee Related
- 2000-08-07 TR TR2002/00546T patent/TR200200546T2/tr unknown
- 2000-08-07 ES ES00952610T patent/ES2243289T3/es not_active Expired - Lifetime
- 2000-08-07 KR KR1020027002661A patent/KR100718422B1/ko not_active Expired - Fee Related
- 2000-08-07 RS YUP-116/02A patent/RS50147B/sr unknown
- 2000-08-07 MX MXPA02002260A patent/MXPA02002260A/es active IP Right Grant
- 2000-08-07 JP JP2001519639A patent/JP4693320B2/ja not_active Expired - Fee Related
- 2000-08-07 WO PCT/US2000/021561 patent/WO2001016069A1/en not_active Ceased
- 2000-08-07 BR BRPI0013681-6A patent/BR0013681B1/pt not_active IP Right Cessation
- 2000-08-07 EP EP00952610A patent/EP1208072B1/en not_active Expired - Lifetime
- 2000-08-07 AT AT00952610T patent/ATE299855T1/de active
- 2000-08-17 AR ARP000104258A patent/AR025311A1/es active IP Right Grant
- 2000-08-29 TW TW089117494A patent/TWI227710B/zh not_active IP Right Cessation
- 2000-08-29 MY MYPI20003981A patent/MY121879A/en unknown
- 2000-08-29 GC GCP2000883 patent/GC0000346A/en active
-
2002
- 2002-02-06 ZA ZA200201045A patent/ZA200201045B/xx unknown
- 2002-02-27 NO NO20020962A patent/NO327990B1/no not_active IP Right Cessation
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