I991t Λ6 B6 經濟部中央標準局員工消费合作社印*·'农 五、發明説明（1 ) 本發明乃關於氧氣產生方法及裝置，.尤指一種使用者 可在室內簡便實施之醫療、.保健用氧氣之產生方法及實施 此方法之裝置。 查氧氣除了在工業上大量傲爲原料使用之外.，.在醫療 、保.健及璦保上亦是相當重要的物質。以往製備氧氣之方 法有：(ι>液態空氣蒸餾法，⑵空氣吸附分離法，⑶水的電 解.法及⑷化學法。前三種方法適合工業上大量生產’且都 需用電源，裝置也較複雜，不適合家庭、醫院之用；至於 化學法適合少量的生產，惟如利甩過硼酸鈉的分解則需要 熱源。但經硏究使用過碳酸鈉逆在催化劑的催化作用下分 解製造氧氣，其過程中不需外加電源或熟源’設1備亦簡單 ，操作使用簡便，而可應用於一般醫療或家庭須用氧的場 合0 發明人對如何提供一種人人均能使周的簡便製氧方法 ，並致力硏究最佳而安全的催化劑之選擇，催化反應過程 的彭響因素，以及應用條件，遂完成本發明簡便而安全之 製氧方法及裝置。 按過碳酸鈉（Sodium Percarbonate簡稱SPC )爲 Na2C03和H202的加成化合物，有兩種結構形式是Na2C03 .1 . 5 H202，二是2Na 2C03 . 3H202爲白色結晶粉末，性不 穩定，遇重佥屬離子，易分解成Na2C03，仏0和〇2，其化 學反應式爲： 2Na2C03· 3H202-^2Na 2C03 + 3H20 + i-|-〇2 | 過碳酸鈉中的活性氧的理論含量爲15.3%與30% H202 (^-之，；;χώ?ρ^再塡寫本頁) -裝- *1T. 本纸張义度適用中國國家標準（CNS>甲4 %格（210 X 297公釐） 2 - 81.9.20,000 19911.3 Λ6 Bfi 經濟部中央標準局員工消费合作社印-¾ 五'發明説明（2) 水溶液等效，因此稱固體雙氧水。一般工業品活性氧含量 爲13 %以上。將固定過碳酸鈉裝入聚乙烯袋，室溫下保存 —年，分解率小於3 %，若原來的含氧量爲14 %，則保存 2〜3年時間，其有效含氧量仍有13 %左右。 過碳酸鈉在水中和催化劑的作用下容易分解，作爲過 碳酸鈉分解的催化，主要有重金屬離子，無機活性材料及 有機物等。爲了獲得高純度的可供醫用的呼吸氧氣，經過 種種試驗，得知選用硫酸錳（MnS04 )及二氧化錳（Μη02〕 兩種爲最佳的催化劑。因爲硫駿錳易溶於水，無毒旦可做 « fiS飼料添加劑’在常溫下 2Na 2 CO 3 · 3H, 0 ,+2MnSO +~>2Na 2 SO + +2VfiiC0：ji^"3H20+T 2MnS0,+O2+2Na 2C03->2Mn0,+2Na 2S0, + 2C02 T 其反應生成物對氣體不汚染，而且第二式中生成的活性二 氧化錳（Μη02 )又可進一步起催化作用·，其反應式如下： 2Na2C03 ·3Η202 2 2Na 2 CO 3+3Η 2 0+ly02 | 二氧化錳不溶於水，在分解反應中，不發生變化。 〔實驗例1〕 將粉末狀的硫酸錳（MnSC^ )在常溫常壓下直接投入 過碳駿鈉（SPC )水溶液中，在幾秒鐘卽可產生氧氣，經 過不同配比的試驗，其中如齒線圖1所示者是將過碳酸鈉 60g置於直徑100 mm且溶釋爲500 的廣口瓶中，並加入 20〇11^之水和7〇11^硫酸錳，所產生的氧氣流量\^(//1^11) 與時間t ( min )的關係。放.出的氧氣流量用轉子流量計 和濕式流量計測定。 ΐ U|J 1'ί: \ίυI991t Λ6 B6 Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperative Printed * · 'Agriculture V. Description of Invention (1) The present invention relates to an oxygen generation method and device, especially a medical and health care service that can be easily implemented indoors by users Oxygen generation method and device implementing this method. In addition to using a large amount of pride as a raw material in the industry, check oxygen is also a very important substance in medical treatment, health care and health care. Previous methods for preparing oxygen include: (ι> liquid air distillation method, ⑵ air adsorption separation method, ⑶ water electrolysis method and ⑷ chemical method. The first three methods are suitable for industrial mass production and all require power supply, and the device is relatively Complex, not suitable for family and hospital use; as for the chemical method suitable for a small amount of production, but if the decomposition of sodium borate is required, a heat source is required. However, the use of sodium percarbonate to decompose under the catalytic action of the catalyst to produce oxygen No external power supply or cooked source is needed during the process. The equipment is also simple, easy to use and operate, and can be used in general medical or family occasions where oxygen is needed. 0 The inventor has how to provide a simple oxygen production for everyone. Method, and strive to study the selection of the best and safe catalyst, the Peng Xiang factor of the catalytic reaction process, and the application conditions, and then complete the simple and safe oxygen production method and device of the present invention. According to Sodium Percarbonate (SPC) ) Is an addition compound of Na2C03 and H202, there are two structural forms of Na2C03. 1. 5 H202, the second is 2Na 2C03. 3H202 is a white crystalline powder, the sex is not It is determined that in the event of heavy ions belonging to the genus, it can be easily decomposed into Na2C03, 〇0 and 〇2, the chemical reaction formula is: 2Na2C03 · 3H202- ^ 2Na 2C03 + 3H20 + i- | -〇2 | active oxygen in sodium percarbonate Theoretical content is 15.3% and 30% H202 (^-之 ， ;; χώ? Ρ ^ Where to write this page) -installed- * 1T. The meaning of this paper is applicable to the Chinese national standard (CNS> A 4% grid (210 X 297 Mm) 2-81.9.20,000 19911.3 Λ6 Bfi Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-¾ Five 'Invention Description (2) The aqueous solution is equivalent, so it is called solid hydrogen peroxide. The active oxygen content of general industrial products is more than 13%. The fixed sodium percarbonate is packed in a polyethylene bag and stored at room temperature for one year. The decomposition rate is less than 3%. If the original oxygen content is 14%, it will be stored for 2 to 3 years, and its effective oxygen content is still 13% Sodium percarbonate is easy to decompose under the action of water and catalyst. As the catalyst for sodium percarbonate decomposition, there are mainly heavy metal ions, inorganic active materials and organic matter. In order to obtain high-purity breathable oxygen for medical use, various Test, knowing the choice of manganese sulfate (MnS04) and manganese dioxide (Mn0) 2] The two are the best catalysts. Thiomanganese is easily soluble in water and non-toxic can be used as «fiS feed additive '2Na 2 CO 3 · 3H, 0, + 2MnSO + ~> 2Na 2 SO + at room temperature + 2VfiiC0: ji ^ " 3H20 + T 2MnS0, + O2 + 2Na 2C03- > 2Mn0, + 2Na 2S0, + 2C02 T The reaction product does not pollute the gas, and the active manganese dioxide produced in the second formula ( Μη02) can further play a catalytic role, and its reaction formula is as follows: 2Na2C03 · 3Η202 2 2Na 2 CO 3 + 3Η 2 0 + ly02 | Manganese dioxide is insoluble in water and does not change during the decomposition reaction. [Experimental Example 1] Powdered manganese sulfate (MnSC ^) was directly put into the sodium percarbonate (SPC) aqueous solution at normal temperature and pressure, and oxygen can be generated in a few seconds. After experiments with different ratios, such as The tooth line shown in Figure 1 is that 60g of sodium percarbonate is placed in a wide-mouthed bottle with a diameter of 100 mm and a dissolution rate of 500, and 20〇11 ^ water and 7〇11 ^ manganese sulfate are added. The resulting oxygen flow The relationship between \ ^ (// 1 ^ 11) and time t (min). The flow rate of released oxygen is measured by rotameter and wet flowmeter. Ι U | J 1'ί: \ ίυ
Μ- m 衣 TS 裝 訂 本紙張又度適用中國园家標準（CMS)甲4現格（210 X 297公货） 81.9.20,000 199113 Λ6 B6 經濟部中央標準局S工消费合作社印製 五、發明説明（3 ) 〔實驗例2〕 採用粉末狀的活性二氧化錳（Μη02 )爲催化劑，同樣 經過不同的配比的.試驗，其中如曲線圖2所示者爲用240g 過碳酸鈉置於直徑爲14 Omm，溶釋爲2500 m2 .的小口瓶中， 加入1000 mZ之水和15g二氧化錳，所產生的氧氣流量V (β/miii )與時間t ( min )的關係_。 〔實驗例3〕 由曲線圖1及2，可見使用硫酸錳爲催化劑時其前期 的氧氣流量大，而用二氧化錳爲催化劑時，則在後期的氧 氣流量大，所以採用該兩種之混合催化劑，相互補匱°曲 線圖3表示用100 g過碳發鈉置於1 00 X 80 mm2的1公升 塑膠瓶中，加〇.1 g硫酸錳和2g二氧化錳，所產生的氧 氣流量V ( Z /min )與時間t( min)的關係。 將以上所得氣體中氧的含量採用銅氨溶液吸收法、紅 外綫c〇2分析儀測定c〇2 ，用空分矽膠吸收H20，其結杲 如下： 0 2 : 9 9.7 % C02 :< 1〇〇 ppm H20 : 18.31〜26.36 s/V (爲反應溫度下的飽和濕含量） 不含其他有害氣體，符合醫用氧氣之規格要求。 將以上在各種條件下進行試驗的結杲，可知使用混合催化 劑硫酸錳與二氧化錳相互補償能使氧氣產生量均匀，且對 系統內沒有汚染；過碳酸鈉的分解速度可由選擇二種催化 劑之配比而適當調節；根據各種應用場合的需要，如醫用 (-t'"、-'!-!i面之：;it'"項再填寫本頁) 丨裝· 本紙張疋度適用中國國家標準（CNS)甲4岘格（210 X 297公釐> —4 81.9.20,000 199113 Λ 6 ____B(i 五、發明説明（4 ) 呼吸氧氣的流量爲1〜2 </mi n，空氣補充給氧0.5〜1^/inin 等，可以經過調整催化劑之配比而滿足要求。 本發明又提供一種能在室內簡便使用之實施上述方法 的安全且小巧之氧氣產生裝.置。如圖3及圖4所示，此裝 置係由：一包括器體1 a及蓋體1 b而內部做爲反應室a 的容器1，一可裝卸地蓋於容器1的加料口 11之高突周緣 的加料口蓋2，一可卸下地嵌置於加料口蓋2頂面凹座20 的以通常爲有機玻璃之透明材質製成而作爲淨化室b兼視 窗的圓筒3，一可裝卸地介以密封垫圏41封羞於圓筒3上 方開口的淨化室蓋4，及一在不用時可蓋於容器1之頂部 開口頸部12而將加料口羞2、圓筒3及淨化室蓋4等組合 裝置羞起來以防塵埃侵入的量杯5所構成。當然’此量杯 5亦可免去不用，或以—般量杯替代。 容器1之器體1a與羞體1b係在接合處呈氣密狀連 接固定，加料口羞2之中央突設一升_氣管_21進入圓筒3中 央，淨化室蓋4之底面則設有周圍及下方留以間隙c罩於 升氣管21之罩筒42，另淨化室蓋4之頂面—側設有—將淨. 化室b內部空間與外界連通的氧氣出口管嘴43，此管嘴可 供連接端末設有氧氣罩或鼻塞之氧氣導管（均未圖示）以 洪吸用；又，容器1頂面設有二環耳13以便穿繫背帶；又 ，透明圓筒3之外面設有一圏水位指示線3】°此外’覗必 要可在容器1之加料口 11內設—過瀘兼除濕杯6，藉加料 口蓋2與加料口 11之口緣夾持該杯6之突緣61而固定°逼 盧除濕杯6底面開設許多小孔62，杯內可放置過慮材、除 本纸張又度適用中國國家標準（CNS)甲4规格（210 X 297公— 5 — ' 81.9.20,〇〇^ ' 丨裝. -:¾ · 經濟部中央標準局員工消费合作社印製 199113 Α6 Β6 經濟部中央標準局員工消费合作社印製 五、發明說明（5 ) 濕劑、芳香劑或淨化劑63等之一種或一種以上，則可除去 氣體中所含反應所生之飽和水氣，並使放出之氧氣帶有清 新、芳香之效果，甚至具有淨化、消毒之作用。 使用本裝置時，先取下量杯5，打開加料口蓋2，則 . · 淨化室構件3、4與加料口蓋2 —起被取下，取出除濕杯 6 (如果有的話），周量杯量取所定量之清水倒入容器1 C反應室a )內。繼之，打開淨化室蓋4，加水入圓筒3 (淨化室b )內，並注視圓筒3至水位昇至指示線31爲止 之後，蓋上淨化室蓋4。將所定量的製氧劑C過碳酸鈉） 及催化劑倒入反應室a內，並將除濕杯6 C如果有的話） 掛於加料口 11內，兹蓋上附载淨化裝置之加料口蓋2，之 後，立卽可從圓筒3看見氣泡通過淨化室b開始供氧，反 應終了時，只有少量斷斷績續的氣泡發生，氣泡完全停止 之後，打開加料口蓋2，取出除濕杯6，倒出反應室及淨 化室內之剩留溶液，卽可供下次使用。 〔實驗例4〕 稱取一般工業用品過碳酸鈉280 g ’二氧化錳2 g， 硫酸錳0.4 g置於上述裝置之具有長2〇〇mnx寬l〇〇_x 高140mm，內容積爲3 Θ的容器反應室中，加清潔水1,000 m/，立卽產生氧氣，其產生率爲1〜1·5 //miη，產生氧 的總量爲3 ，給氧時間爲20〜30 mi η。 本發明因如上述可使用小巧携帶方便的裝置在常溫、 常壓下，用催化劑分解製氧劑水溶液，而可控制且以大致一 定的流量，連績發生高純度的氧氣，供醫用或家庭室內、 ----------I — l·---^-------裝—丨----’玎------- (^%:'»1..ν!ί*之;±念事項再填寫本頁) 本紙張尺度適用中因國家標準（CNS)甲4規格（21〇 X 297公釐 —6 81.9.20,000 19911¾ A6 ΒΓ, 五、發明説明（6 ) 會議室等補充氧氣之用。同時，過碳酸鈉及催化劑均可加 以穩定化處理及定量包裝而確保長期的保存及使用上之方 便。又，氧氣產生過程簡便、安全且迅速，不，僅可作爲家 庭中之氧源，亦可使患有慢性氣管性疾病者或緊急需用氧 氣者及時得到治療或急救之用，堪稱一極具價値之發明。 圖式說明： 圖1係表示依本發明方法第一實施例產生氧氣時其流 量與時間的關係之曲線圖； 圖2係表示依本發明方法第二實施例產生氧氣時其流 量與時間的關係之囲線圖； 圖3係表示依本發明方法第三實施例產生氧氣時其流 量與時間的關係之曲線圖； 圖4係依本發明之氧氣產生裝置一具證實施例之局部 剖面正視圖； 圖5係圖4所示裝置之縱剖面側視圖。 ----------:------|-------裝--------訂 (淆1"4"而之注念"項再填寫本頁) 經濟部中央標準局0工消費合作社印皱 參紙張疋度適用中國國家標準（CNS)甲4規格（210 X 297公發） —7 一 81.9.20,000Μ-m clothing TS bound paper is again applicable to the Chinese Gardener Standard (CMS) A4 cash (210 X 297 public goods) 81.9.20,000 199113 Λ6 B6 Printed by the S Industry and Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy (3) [Experimental Example 2] Using powdered active manganese dioxide (Μη02) as a catalyst, also through different ratios. The test, where the curve shown in Figure 2 is 240g sodium percarbonate placed in a diameter of 14 Omm, a small-mouthed bottle with a dissolution rate of 2500 m2. Add 1000 mZ of water and 15 g of manganese dioxide. The relationship between the generated oxygen flow V (β / miii) and the time t (min). [Experimental Example 3] From the graphs 1 and 2, it can be seen that when manganese sulfate is used as a catalyst, the oxygen flow rate in the early stage is large, and when manganese dioxide is used as the catalyst, the oxygen flow rate in the late stage is large, so the mixture of the two is used. Catalyst, complementary phase diagram. Figure 3 shows the oxygen flow rate generated by using 100 g of sodium percarbonate in a 1 liter plastic bottle of 100 X 80 mm2 and adding 0.1 g of manganese sulfate and 2 g of manganese dioxide. The relationship between (Z / min) and time t (min). The content of oxygen in the gas obtained above was measured using a copper ammonia solution absorption method, an infrared c〇2 analyzer, and H20 was absorbed by air separation silica gel. The results were as follows: 0 2: 9 9.7% C02: < 1〇 〇ppm H20: 18.31 ~ 26.36 s / V (saturated moisture content at reaction temperature) does not contain other harmful gases, and meets the requirements of medical oxygen specifications. According to the results of the above tests under various conditions, it can be seen that the use of mixed catalysts such as manganese sulfate and manganese dioxide to compensate each other can make the amount of oxygen produced uniform and no pollution to the system; the decomposition rate of sodium percarbonate can be selected from two catalysts Proportioning and appropriate adjustment; according to the needs of various applications, such as medical (-t '",-'!-!I-face:; it '" item and then fill out this page) Applicable to Chinese National Standard (CNS) A 4 Dange (210 X 297 mm> — 4 81.9.20,000 199113 Λ 6 ____B (i V. Description of the invention (4) The flow rate of breathing oxygen is 1 ~ 2 < / mi n , Air supplementation of oxygen 0.5 ~ 1 ^ / inin, etc., can be adjusted to meet the requirements of the catalyst. The present invention also provides a safe and compact oxygen generation device that can be used indoors to implement the above method. As shown in FIGS. 3 and 4, this device is composed of: a container 1 including a container body 1 a and a cover body 1 b with the interior serving as the reaction chamber a, and a high protrusion that removably covers the feeding port 11 of the container 1 The feed port cover 2 at the periphery is detachably embedded in the recess 20 on the top surface of the feed port cover 2 Of a cylinder 3 made of a transparent material usually made of plexiglass and serving as a clean room b and a window, a removable clean room cover 4 sealed with a gasket 41 on the opening above the cylinder 3, and a When not in use, it can be covered on the top opening neck 12 of the container 1 and the combination device such as the feeding port 2, the cylinder 3 and the clean room cover 4 can be constructed with a measuring cup 5 in which dust penetrates. Of course, this measuring cup 5 can also be Don't use it, or replace it with a general measuring cup. The container 1a and container 1b of container 1 are connected and fixed in a gas-tight manner at the joint. The center of feeding port 2 is protruded with a liter_trachea_21 into cylinder 3 In the center, the bottom surface of the clean room cover 4 is provided with a cover c around the bottom of the riser 21 with a gap c, and the top surface of the clean room cover 4-side is provided with-will be clean. Oxygen outlet nozzle 43 connected to the outside world. This nozzle can be used for oxygen suction (not shown) with an oxygen hood or a nasal congestion at the end of the connection end for flooding. In addition, the top surface of the container 1 is provided with two ring ears 13 for wearing Wear a strap; in addition, a transparent water level indicator line 3 is provided on the outer surface of the transparent cylinder 3] ° In addition, the 覗 necessary can be in the container 1 is equipped with a feeding port 11-passing through the dehumidifying and dehumidifying cup 6, by the feeding port cover 2 and the edge of the feeding port 11 is clamped by the flange 61 of the cup 6 and fixed ° forced Lu dehumidifying cup 6 at the bottom of the opening many holes 62, The cup can be filled with materials, except for this paper, and it is also applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 male-5 — '81.9.20, 〇〇 ^' 丨 installed.-: ¾ · Ministry of Economic Affairs Printed by the Staff Consumer Cooperative of the Bureau of Standards 199113 Α6 Β6 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (5) One or more of the wet agent, fragrance or purifier 63, etc., can be removed from the gas The saturated water vapor produced by the reaction, and the released oxygen gas has a refreshing and aromatic effect, and even has the effect of purification and disinfection. When using this device, first remove the measuring cup 5 and open the filler cap 2. Then the clean room components 3, 4 and the filler cap 2 are removed together, take out the dehumidifying cup 6 (if any), and take the measuring cup A certain amount of clean water is poured into the container 1 C reaction chamber a). Next, the clean room cover 4 is opened, water is added into the cylinder 3 (clean room b), and after the cylinder 3 is watched until the water level rises to the indicating line 31, the clean room cover 4 is closed. Pour the quantified oxygen-generating agent C sodium percarbonate) and the catalyst into the reaction chamber a, and hang the dehumidifying cup 6 C (if any) in the feeding port 11, and close the feeding port cover 2 with the purification device attached. After that, Li can see the bubbles from the cylinder 3 through the clean room b to start oxygen supply. At the end of the reaction, only a small amount of intermittent bubbles occur. After the bubbles have completely stopped, open the feeding port cover 2, take out the dehumidifying cup 6, and pour out the reaction The remaining solution in the room and purification room can be used for the next time. [Experimental Example 4] Weighed 280 g of sodium percarbonate, 2 g of manganese dioxide, and 0.4 g of manganese sulfate, which were placed in the above-mentioned device and had a length of 200 mmx, a width of 100 mm, and a height of 140 mm, and the internal volume was 3 In the vessel reaction chamber of Θ, add 1,000 m / of clean water to generate oxygen, and the generation rate is 1 ~ 1.5 · miη, the total amount of generated oxygen is 3, and the oxygen supply time is 20 ~ 30 mi η. The present invention can use a compact and convenient device as described above to decompose an aqueous solution of an oxygen-generating agent with a catalyst at room temperature and normal pressure, and can control and generate high-purity oxygen at a substantially constant flow rate for medical or family use. Indoor, ---------- I — l · --- ^ ------- installed-- 丨 ---- '玎 ------- (^%:' »1 ..ν! ί * 之; ± Thoughts and then fill out this page) This paper scale is applicable to the China National Standard (CNS) A 4 specifications (21〇X 297 mm-6 81.9.20,000 19911¾ A6 ΒΓ, V. Description of the invention (6) The use of supplementary oxygen in conference rooms, etc. At the same time, sodium percarbonate and catalyst can be stabilized and quantitatively packed to ensure long-term storage and ease of use. In addition, the oxygen generation process is simple, safe and rapid, not It can only be used as a source of oxygen in the family, and it can also be used by people with chronic tracheal diseases or those in urgent need of oxygen to receive treatment or first aid in a timely manner, which can be called a very valuable invention. A graph showing the relationship between the flow rate and time when oxygen is generated according to the first embodiment of the method of the present invention; FIG. 2 shows the method according to the present invention The second embodiment is a graph of the relationship between the flow rate and time when generating oxygen; FIG. 3 is a graph showing the relationship between the flow rate and time when generating oxygen according to the third embodiment of the method of the present invention; FIG. 4 is a graph according to the present invention A partial sectional front view of a certified embodiment of the oxygen generating device; Figure 5 is a longitudinal side view of the device shown in Figure 4. ----------: ------ | ---- --- installed -------- ordered (to confuse 1 " 4 " and fill in this item and fill in this page again) Central Bureau of Standards, Ministry of Economic Affairs, China Industrial and Commercial Cooperative, Printing and Wrinkling Ginseng Paper, the degree of application is in line with Chinese national standards (CNS) A 4 specifications (210 X 297 public)-7 a 81.9.20,000