TW200829162A - Improvement of the biological action of agrochemical compositions on application to the culture substrate, suitable formulations and their use - Google Patents

Abstract

In soil applications, the action of crop protection compositions comprising active compounds from the classes of the insecticidal phthalic acid diamides can be improved by adjuvants. The present invention describes corresponding methods and suitable compositions.

Description

200829162 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to an improvement in the role of agrochemical compositions in soil application, an agrochemical composition suitable for such application, and its use for controlling harmful insects. [Prior Art] Agrochemically active compounds can be administered by different methods for controlling pests. In addition to leaf treatment, the culture substrate can also be treated, which can be soil, but can also be especially peat moss, cocoa fiber, stone wool (such as Grodan®), pumice, bentonite (such as Lecaton®). Or Lecadan®), clay granules (such as seramis®), foamed plastics (such as Baystrat), vermiculite, perlite, synthetic soil (such as Hygromull®) or a combination of such substrates as a special substrate. In the following, all of these 15 culture matrices are referred to as soil. The herbicidal organism is contacted with the active compound by applying the active compound to the soil or on the surface, and the root absorbs the systemically active compound. Many adjuvants for improving the action of agriculturally active compounds in leaf treatment are known. These include, for example, penetrants which promote penetration of active compounds into plants (e.g., WO 03/000053). 20 For the application of insecticides and fungicides, the corresponding adjuvants have not been described so far. Known is the effect of accelerating the penetration of irrigation water into the soil into the dry soil (eg Agri-Prep® CS from Northwest Agricultural Products). The surfactant is also known as Permethrin. ) Distribution in soil 5 200829162 has influence (Howell, McMullan, RM· (ed·) 1998, adjuvant for agrochemicals, minutes of the 5th International Symposium on Adjuvants for Agrochemicals, Memphis, USA Page 247_253). The improvement of the herbicidal composition by the optimum formulation has also been described (Chung et al., Pesticide Science, 1993, 38(2_3), pp. 250-252). SUMMARY OF THE INVENTION Surprisingly, it has now been found that when the insecticidal composition comprises an adjuvant, its biological action in soil application can be improved. Here, the adjuvant may be one of the components of the concentrated formulation (canned formulation), or it may be added during the preparation of the ready-to-use pesticide solution (tank mixed application). The improved effect is significant in controlling soil organisms and in controlling leaf pests or leaf diseases controlled by systemically active compounds. In this manner, the use of the composition according to the present invention can reduce the amount of active compound applied or achieve an improved effect at a fixed application rate. Therefore, the consumption of water can be reduced to a minimum. Accordingly, the present invention provides an adjuvant for improving the agrochemical composition in soil application (eg, by spraying to soil, watering, side application, leaching, overhead perfusion, or application using an irrigation system (drip irrigation)) use. [Embodiment] The present invention now provides a novel suspension concentrate for such application comprising: ', at least one from the insecticide-based bismuth citrate group at room temperature at 6 200829162 Active compound, - at least " adjuvant. In addition to concentrated formulations, the present invention also provides a ready-to-use composition that is diluted. The present invention further provides the use of such compositions for controlling pests in the soil and larvae. In the present invention, the adjuvant is a substance which improves the action of the organism in the following test system: 10 15 20 The corn young plant is planted in a 1 liter container containing soil (sand loam, humidity % by weight, pH 6.7). Plants are grown for 3 or 12 days in a greenhouse at 2 °c (until they violate the 2- or 3-leaf stage) and then watered. During the watering, 0.25 mg or 0.5 mg of the insecticidal active compound (S)-3-chloro-N1-{2-mercapto-4-[ 1,2,2,2-tetrafluoro· 1 _ (three Air oxime) ethyl]phenyl} grab (1_mercapto-2-methylsulfinylethyl) acetaminophen (known from WO 06/22225) and 6 gram of potential adjuvant in 6 liters = volume. On days 1, 3, 7 or 14 after flooding, the mortality of the plants and the larvae of the puppies of the autumn stage of the Spodoptera frugiperda were measured 7 days later. The same = ' again - no potential adjuvant was added as a control group. When using the adjuvant according to the invention, this test showed an increased mortality compared to the control group. Here, death = 3 does not necessarily increase, it may also be an adjuvant according to the invention only in the initial active or long-lived embodiments, in particular the following (1) D dioctyl succinyl, commercially available, for example Product series 7 200829162

Geropon®, (1-2) a composition comprising sodium dioctylsulfosuccinate and sodium benzoate, commercially available, for example, from the product line Aerosol®; dioctylsulfosylsuccinate: benzoquinone Preferably, the weight of the sodium salt is from 5:1 to 6:1, 5 (1-3) end-capped alkoxylated fatty alcohols and terminally capped alkoxylated linear alcohols, commercially available, for example. The product range Plurafac® ; is preferably an ethoxylated and/or butoxylated fatty alcohol and a terminally capped ethoxylated and/or butoxylated linear alcohol, (1-4) 10 to 15 EO units of tributylphenol polymerized glyceryl ether (where EO means oxirane), commercially available, for example, from the product line

Sapogenat®, (1-5) polyalkylene oxide modified polymethyl oxiranes, commercially available, for example, from the product line Silwet®, (1-6) formula CH3-(CH2)rCH2-0-(-CH2 -CH2_0-)uH branched alkane 15 alcohol alkoxide, wherein t represents a number from 9 to 10.5 and u represents a number from 6 to 25 (preferably from 8 to 12), and t and u are average values, commercial It can be obtained, for example, from the product line Lutensol®, (1-7) betaine, (1-8) polyoxylated triglyceride, in which triglyceride is preferably a plant source, commercially available For example, the product line Crovol®, (1-9) alkoxylated fatty amines, commercially available, for example, from the product line Armoblen®, (1-10) sodium lauryl ether ether, commercially available, for example, from the product line Genapol® , 8 200829162 (I-ll) PEG-10 coconut alcohol, commercially available, for example, from the product line Genapol®, (1-12) comprising corn syrup, thiolated soybean oil and nonionic emulsifier, commercial For example, the product line Superb® is available. The quinone imine of formula (II) is known to have an insecticidal action. This applies to the racemic form of the compound (EP-A 1 006 107) or even the mirror image isomer of the (S)-configuration (WO 06/22225).

So2ch3 κτ八 10

Hal represents chlorine, bromine or iodine, * represents a carbon atom in the R- or S-configuration, preferably an S-configuration. Formula (II) comprises the following preferred active compounds:

(II-l): (S)-3-iododecyl-4-[l,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl}-Ν2-(1· Mercapto-2-mercaptosulfonylethyl)decylamine 9 200829162

(II-2): (S)_3-gas-nM2-methyl-4-[l,2,2,2-tetrafluoro-i-(trifluoromethyl)ethyl]phenyl bene N2-(l -Methyl-2-mercaptosulfonylethyl)decylamine (II-3): (S)-3-bromo-N1-^ mercapto-4-[l,2,2,2-tetrafluoro 1-(trifluoromethyl)ethyl]phenyl}-indole 2-(1-methyl-2-methylsulfonylethyl)decylamine, in addition to at least one active compound and at least one adjuvant, The composition according to the invention preferably further comprises other formulation adjuvants: to v kinds of nonionic surfactants and / or at least one anionic surfactant, - one or more additives selected from antifreeze agents, defoamers In the group of preservatives, antioxidants, θ spreaders, colorants and/or thickeners. Examples of other ingredients of the formulations according to the invention which may be mentioned are in particular the following: Suitable nonionic surfactants are all such compounds which are generally used in agrochemical compositions. Mention may be made of polyethylene oxide-poly, propylene and copolymers, polyethylene glycol ethers of linear alcohols, fatty acid and ring, ethylbenzene and/or epoxy propylene. Polyvinyl alcohol, polymethyl ketone ketone, polyethylene glycol and polyethylene sulfonium. a mixed polymer, a mixed polymer of ethylene oxide and polyethylene, and a copolymer of (a 200829162) acrylic acid and (meth) acrylate, and an alkyl ethoxylate and an alkyl aryl group. Ethoxide (which can be selectively phosphorylated and optionally neutralized with a base), a polyoxylamine derivative, and a nonylphenol ethoxylate. Suitable anionic surfactants are all such materials commonly used in agrochemical compositions 5. Preferred are the metal salts of the base acid or the aryl aryl tartaric acid and the soil test metal salt. Another preferred anionic surfactant or dispersant group is a salt of polystyrenesulfonic acid, a salt of polyvinylsulfonic acid, a salt of a naphthalenesulfonic acid/furfural condensate, a naphthalenesulfonic acid, a phenolsulfonic acid And salts of furfural condensates and salts of woody 10 acid. Suitable antifreeze agents are all such materials commonly used in agrochemical compositions. Preferred are urea, glycerin, polymeric glycerol and polymeric glycerin derivatives, propylene glycol and propylene glycol. Suitable antifoams are those which are commonly used in agrochemical compositions for this purpose 15 . Preferred are Shixi oxygen oil and magnesium stearate. Suitable preservatives are all materials which are normally used in such agrochemical compositions for this purpose. Examples that may be mentioned are Preventol® (from Bayer AG) and Proxel®. Suitable antioxidants are those which are normally used in this agrochemical composition for this purpose. Examples which may be mentioned are: propyl gallate, octyl gallate, lauryl gallate, butylated hydroxyanisole, propyl p-hydroxybenzoate, sodium benzoate, dihydrogen reduction Cunchinic acid and butylated hydroxyindole. Preferred is butylated hydroxyindole (2,6-di-t-butyl-4-mercaptopurine, BHT) 〇11 200829162 Suitable for spreading agents for all commonly used agrochemical compositions Substances used for this purpose. Preferred are polyether- or organic-modified polyoxyalkylenes. Suitable colorants are all materials commonly used in agrochemical compositions for this purpose. Mention may be made, by way of example, of titanium dioxide, pigment grade carbon 5 black, zinc oxide and blue pigments, and permanent red FGR. Suitable thickeners are all materials commonly used in agrochemical compositions for this purpose. Preferred are, for example, a sulphate (such as Attagel® 50 from Engelhard) or xanthan gum (such as Kelzane® S from Kelko). The concentrated formulations according to the present invention are prepared by mixing the components of the specific desired ratio with each other. The ingredients can be mixed with one another in any order. Appropriately, the solid components are used in an extremely finely ground state. However, it is also possible to subject the suspension formed after the mixing of the components to coarse grinding and then finely grinding to have an average particle diameter of less than 20 μm. Preferred suspension concentrates are those in which the solid particles have an average particle size of from 1 to 10 microns. 15 When carrying out the method according to the invention, the temperature can be varied within a certain range. Generally, the process is carried out at temperatures between 10 ° C and 60 ° C, preferably between 15 ° C and 40 ° C. Suitable mixers and grinders for the manufacture of agrochemical formulations are suitable for carrying out the process according to the invention. 20 The composition according to the present invention is a formulation which is stable even after long-term storage at a warm or cold condition, since no crystal growth is observed. By diluting with water, they can be converted into a uniform spray. The rate of application of the compositions according to the invention can vary over a wide range. It depends on the agrochemically active compound used and the composition of the composition 12 (200829162 content. The composition according to the invention comprises: - at least one active compound from the insecticide bismuth citrate and - At least one adjuvant. In a preferred embodiment, the composition according to the invention comprises: - at least one activity selected from the group consisting of (II-1), (II-2) and (II-3) a compound and at least one adjuvant. In a particularly preferred embodiment, the composition according to the invention comprises: - at least one selected from the group consisting of (11-1), (H-2) and (II-3) The active compound - and at least one selected from the group consisting of (M) to (1 - 12). The composition according to the invention comprises (if they are concentrated formulations): often by 1 Up to 60% by weight of the agrochemically active compound may be used according to the invention, preferably from 5 to 5% by weight, particularly preferably from 10 to 30% by weight, usually from at most 5% to 5% by weight. An adjuvant according to the invention, preferably 2 to 3 % by weight, particularly preferably 5 to 2 % by weight, = At least 1 to 20 weights of a nonionic surfactant and/or an anionic surfactant, preferably from 25 to 25, usually from 1 to 20% by weight; an agent, preferably from 5 to 15 by weight. 13 200829162 %, - usually from 0. 1 to 20% by weight of additives, preferably from 0.1 to 15% by weight. The compositions according to the invention usually comprise (if they are ready-to-use type 5 - for watering) The solution is 0.05 to 10 g / liter, preferably 0.1 to 8 g / liter, particularly preferably 0.1 to 5 g / liter of adjuvant. Excellent concentrated formulation for soil application comprises: - from 1 to 60% by weight At least one active compound selected from the group consisting of (ΙΙ-1), (ΙΙ-2), and (ΙΙ-3), ίο - at least one between 1 and 50% by weight selected from the group consisting of (1- 1) to (M2) the substance or composition in the group, from 1 to 20% by weight of at least one nonionic surfactant and/or anionic surfactant, from 1 to 20% by weight of the anti-beam Agent, is - from 0.1 to 20% by weight of an additive selected from the group consisting of antifoaming agents, preservatives, antioxidants, spreading agents, colorants and/or thickeners In general, some combinations of the active compounds and adjuvants listed in the table below are preferred, wherein each composition is preferably: y Zc ...:::... : ί, ^ ^ - Γ ^ ^ > - * «*, Λ , r -3⁄4. j; ' 丨 ( 1 (II-1) Dioctylsulfosuccinate 2 (IM) Composition comprising sodium dioctylsulfosuccinate and sodium benzoate 3 (II-1) End-capped alkoxylated fatty alcohol and terminally capped alkoxylated linear alcohol 4 (II-1) Tributyl-terminated polymeric glycerol scales having 10 to 15 units of fluorene 14 200829162

:#德德価 I polyalkylene oxide-modified polymethyloxane 6 (Π-1) a branched alkanol alkoxide of the formula CHr(CH2)rCH2-CK-CHrCHr〇-)uH, where t represents Numbers from 9 to 10.5 and u represent numbers from 6 to 7 7 betaine polyalkoxylated triglycerides 9 alkoxylated fatty amines 10 11 12 13 14 15 16 17 18 19 22 23 (II-l) Sodium lauryl ether sulfate PEG-10 coconut alcohol contains corn syrup, thiolated soybean oil and nonionic emulsified product. Dioctyl base number έ acid steel (Π-2) contains sodium dioctyl sulfosuccinate and benzoquinone Sodium composition (Π-2) Blocked alkoxylated fatty alcohol ^ 氪 氪 龥 龥 ΙΙ ΙΙ ΙΙ ΙΙ ΙΙ 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有2) (Π-2) (Π-2) (Π-2) (Π-2) (II-2) (ΙΙ-2) Polyalkylene oxide-modified polymethyloxane type CHr(CH2) a branched alkanol alkoxide of t-CHrO7CHrCHra)uH where t represents a number from 9 to 1 〇·5 and u represents a number from 6 to 25 of betaine polyalkoxylated triglyceride alkoxy Fatty amine----_ sodium lauryl ether ether PEG-10 coconut alcohol 15 200829162 (Π-2) Contains corn syrup, Thiolated soybean oil and nonionic emulsified composition 舲25 (II-3) sodium dioctylsulfosuccinate 26 (II-3) composition comprising sodium dioctyl succinate and sodium benzoate 27 (Π-3) blocked alkoxylated fatty alcohol and blocked alkoxylated linear alcohol 28 tributylphenol polymerized glycerol with 10 to 15 EO units _ 29 (Π-3) polyalkylene oxide - modified polyfluorenyl oxane 30 (II-3) a branched calcined oxide of the formula CHr(CH2)t-CHrO-(-CHrCHrO-)uH, where t represents a number from 9 to 10.5 and u Representative from 6 to 25 of 31 (Π-3) betaine

Plants and plant organs, increase harvest yield, "stay 4 plant brakes _, especially in agriculture = sexual species and for all or part of the two == 16 200829162 兹目 (毛益目), such as Niu Yuyi (Pamalinia Genus, Haematopinus, Linognathus, Pediculus, Trichodectes. Arachnida, such as Acarus siro, orange 5 Aceria sheldoni, Aculops, Aculus, Amblyomma, Argas, Boophilus, Brevipalpus Genus, Bryobia praetiosa, 'Chorioptes genus, Dermanyssus gallinae, Eote-tranychus genus, Epitrimerus pyri, brown leafhopper (Eute_tranychus) genus, genus Eriophyes, Hemitarsonemus, Hyalomma, Ixodes, Latrodectus mactans, Metatetranychus ) genus, Oligonychus genus, genus Ornithodoros, spider mites Is (Panonychus) genus, phyllocoptruta oleivora, Polyphagotarso nemus latus, Psoroptes genus, Rhipicephalus genus, Rhizoglyphus genus, genus Sarcoptes genus, Scorpio maurus, Stenotarsonemus genus, Tarsonemus genus, Tetranychus genus, Vasates lycopersici 〇 bivalve ' A genus of the genus Dreissena. For example, the genus Geophilus is a genus of the genus Geophilus and the genus Scutigera. Coleoptera ', such as the genus Acanthoscelides obtectus, the genus Adoretus, and the blue-hip hip. Agelastica alni, stag beetle 17 200829162 (Agriotes) genus, potato giant tortoise (Amphimallonsolstitialis), furniture mites (Anobium punctatum), Anoplophora genus, cotton boll weevil (Anthonomus) genus, skin stupid (Anthrenus) genus, Apogonia genus, Atomaria genus, Attgenus genus, 5 soybean genus (Bruchidius obtectus), Bean genus (Bruchus) genus, Turtle (Ceuthorhynchus) genus, Cleonus mendicus, Conoderus, Cosmopolites, Costelytrazealandica, Curculio, Cryptorhynchus lapathi, Pichia (Cryptorhynchus lapathi) Dermestes), 曱 ίο (Diabrotica), Ladybug (Epilachna) genus, fauna (Faustinus cubae), Gibbium psylloides, Heter-onyclius arator, flash Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus, Lachnosterna is consanguinea, Leptinotarsa decemlineata, rice Lisorhoptrus oryzophilus, Lyxus, Lyctus, Meligethes aeneus, Melolontha melolontha, Migdolus, Black beetle Monochamus), fruit tree weevil (Naup-2〇actus xanthographus), yellow spider mites (Niptus hololeucus), rhinoceros tortoise (Oryctes rhinoceros), sawhorax powder flat (Oryzaephilus surinamensis), Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, Phyllo- phaga genus, Japanese chafer 18 200829162 (Popilliajaponica ), genus premn〇trypes, Psylliodes chrysocephala, Ptinus, Rhizobius ventralis, Rhizopertha dominica, Sitophilus genus, elephant Sphenophorus, Sternechus, Symphyletes, Tenebriomolitor, Tribolium, Trogoderma, Tychius Genus, Xylotrechus genus, from the genus Zabrus. The tail of the bullet, such as the insect nematode (Onychiurus armatus). Ίο The genus of the genus, such as the Forficula auricularia 倍, such as the Blaniulus guttulatus. Diptera, such as the genus Aedes, the genus Anopheles, the bibio hortulanus, the Calliphora erythrocephala, the Ceratitis capitata, the Chrysomyia genus, Cochliomyia, Cordylobia anthropophaga, Culex, Cutrebra, Dacus oleae, Dermatobia hominis, fruit rope (Droso-phila) genus, genus of Fannia, genus of Gastrophilus, genus of Hyl- emyia, genus Hyppobosca, genus Hypoderma, plaque Liriomyza, Lilium, Luca, Muzara, Nezara, Oestrus, Swedish sci_neua frit, Pegomyia hyoscyami), Phorbia, Stomoxys, Tabanus, Tannia, Tipula 19 200829162 paludosa, Wohlfahrtia. Gastropods, such as Arion, Biomphalaria, Bulinus, Deroceras, Galba, Lymnaea, The genus Oncomelania and the genus Succinea. Spirulina, such as Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma, Ascaris lubricoides, Ascaris , Brugia malayi, Brugia timori, Bunostomum, Chabertia, Clonorchis, Cooperia, trematode (Dicrocoelium) genus, Dictyocaulus filarial, Diphyllobothrium latum, Dracunculus 15 medinensis, Echinococcus granulosus, multi-atrial stag beetle (Echinococcus multilocularis) Enterobius vermicularis, Faciola genus, Haemonchus genus, Heterakis genus, Hymenolepis nana, Hyostrongulus genus, Luo Aphid (Loa 2〇Loa), Nematodirus, Neso-phagostomum, and liver worm (Opisthorchi) s) genus, Onchocerca volvulus, Ostertagia, Para-gonimus, Schistosomen, Strongyloides fuelleborni, Strongyloides stercoralis ), Intestinal 20 200829162 Aphid (Stronyloides), Taeniasaginata, Taenia solium, Trichinella spiralis, Trichinella native, Trichinella spiralis (Trichinella britovi), Trichinella nelsoni, Trichinella pseudo-5 opsiralis, Trichostrongulus genus, Trichuris trichuria, Wuchereria bancrofti. It further controls protozoa, such as Eimeria. Heteroptera, such as Anasa tristis, Antestiopsis, Blissus, Calocoris 10, Campylomma livida, Cavelerius, bed bugs (Anasa tristis), Antestiopsis genus, Blissus genus, Calocoris 10 genus, Campylomma livida Cimex) genus, Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus genus, Euschis genus, scutellaria Eurygaster), Heliopeltis genus, 15 plant bug (Horcias nobilellus), genus Leptocorisa, Leptoglossus phyllopus, Lygus genus, Macropes excavatus, Miridae, Nezara, Oebalus, Pentomidae, Piesema quadrata, Piezodorus, Psallus seriatus , lace bed bug (Pseudacysta persea), Rhodonis genus, Sahlbergella singularis, Scotinophora genus, Stephanitis nashi ), Tibraca genus, Triatoma genus 200821 200829162 Homoptera, such as the genus Acyrthosipon, the genus Aeneolamia, the genus Agonoscena, the mealworm (Aleurodes) genus, Aleurolobus barodensis, genus Aleurothrixus, Amrasca genus, Anuraphis 5 cardui, Aonidiella genus, pear worm Aphanostigma piri), Aphis genus, Arboridia apicalis, Aspi-diella genus, Aspidiotus genus, Atanus genus, potato wealth Aulacorthum solani), Bemisia genus, Brachycaudus helichrysii, Brachycolus genus, Bravicoryne brassicae, Calligypona margi-nata, Carneocephala fulgida , Ceratova- cuna lanigera, Cercopidae, Ceroplastes, Chaetosiphon fragaefolii, Chiona- spis tegalensi s), tea small green 15 (Chlorita onukii), walnut black spotted (Chromaphis juglandicola), brown round scale insect (Chrysomphalus ficus), leafhopper (Cicadulina mbila), Coccomytilus halli, genus Coccus genus, Cryptomyzus ribis, Dalbulus, Dialeurodes, Diaphorina, Diaspis 2, Doralis, Paramecium Drosicha), Dysaphis, Dysmicoccus, Empo-asca, Eriosoma, Erythroneura, and bilobote Euscelis bilobatus), Geococcus coffeae, Homalodisca coagulate, Hyalo pterus 22 200829162 arundinis, Icerya genus, Idiocerus genus, The genus Idyoscopus, Laodelphax stria-tellus, Lecanium, Lepidosaphes, Lipaphiserysimi, Macrosiphum, 5 Mahanarva fimbriolata, Melanaphis sacchari, Metcalfiella genus, Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus genus, lettuce aphid (Naso- Novia ribisnigri), Nephotettix genus, Nilaparvata lugens, Oncometopia, Orthezia praelonga, Parabemisia myricae, Paratrioza Genus, genus Parlatoria, Pemph-igus, Peregrinus maidis, Phena-coccus, Phloeomyzus passerinii, finger worm is (Phorodon humuli), Phylloxera genus, Pinnaspis aspidistrae, Planococcus genus, Protopulvinaria pyriformis, Pseudaulacaspispentagona, powder Pseudococcus genus, Psylla genus, Pteromalus genus, Pyrilla genus, 2 avocado round scale insects (Q Eudraspidiotus), Quesada gigas, Rastrococcus genus, Rhopalosiphum, Saissetia, Scaphoides titanus, Schizaphis graminum, thorn shield (Selenaspidus articulatus), genus Sogata, Sogatella furcifera, floating dust 23 200829162 ((Sogatodes) genus, Stictocephala festina, Tenalaphara mala-yensis, Tinocallis caryaefoliae, genus Tomaspis, The genus Toxoptera, Trialeurodes vaporari-orum, Trioza, Typhlocyba, Unaspis, Vineus vitifolii ). Hymenoptera, such as the genus Diprion, the genus Hoplocampa, the genus Lasius, the genus Monomoriumpharaonis, and the genus Vespa. Isopods, such as Armadillidium vulgare, Oniscus asellus, Porcellio scaber, etc., such as the genus Reticulitermes and the genus Odonto-termes . Lepidoptera, such as Acronicta major, Aedialeucomelas, Agrotis genus, Alabama argillacea, Anticarsia genus, cabbage night Moth (Barathra brassicae), Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulana, Carpocapsa pomonella, Cheimatobia bmmata, Chilo ), genus Choristoneura fumi-ferana, Clysia ambiguella, Cnaphalocerus genus, Earias insulana, Ephestia kuehn-iella, brown-tailed moth (Euproctis chrysorrhoea), Euzoa genus, Feltia genus, Galleria mellonella, Helicoverpa genus, 24 200829162 Heliconia, Hewlettium genus, Hofmannophila pseudospretella, tea Homona magnanima, Hyponomeuta padella, Laphygma genus, Lithocolletis blancardella, Lithohane antennata Loxagrotis albicosta, 5 genus Lymantria, Malacosoma neustria, Mamestra brassicae, Mocis repanda, Mythimna separate, Oria genus, Oulema Oryzae), Panolis flammea, Pectinophora gossypiella, Phyllocnistis citrella, Pieris genus, Plutella xylostella, Prodenia Genus, Pseudaletia genus, Pseudoplusia includens, Pyrausta nubilalis, Spodoptera genus, Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortox viri_ is dana, Trichoplusia. Orthoptera, such as Acheta domesticus, Blata orientalis, Blattella germanica, Gryllo talpa, Florida (Leucophaea maderae), and Luxus (Locusta) , genus Melanoplus, Periplaneta Americana, Schistocerca gregaria, scorpion, such as Ceratophyllus, Xenopsylla cheopis 0, Symphyla, For example, Scutigerella 25 200829162 immaculate is of the order Thunderoptera, such as Baliothrips biformis, Enneothrips flavens, Franldiniella, Heliothrips, Hercinothrips femoralis , Kakothrips genus, Rhipiphorothrips cruentatus, Scirto-thrips genus, Taeniothrips cardamoni, Thrips genus. The total tail, such as Lepisma saccharina. Plant-parasitic nematodes, including, for example, the genus Anguina, the genus Aphelenchoides, the genus Belenoaimus, the genus Bursaphelenchus, the genus Ditylenchus dipsaci, and the genus Globodera. Genus, Heliocotylenchus, Hetero- dera, Longidorus, Meloidogyne, Pratylenclius, Rado-pholus similes, spiral The genus Rotylenchus, the genus Tri- chodorus, the genus Tylenchorhynchus, the genus Tylenchulus, the genus Tylenchulus semipenetrans, and the genus Xiphinema. If appropriate, the compositions according to the invention may also be used as herbicides, safeners, growth regulators or medicaments at certain concentrations or application rates of 20 to improve properties, or as microbicides, for example as fungicides, Antifungal agents, bactericides, viricides (including antiviral agents) or as agents against MLO (mycoplasma) and RLO (like rickettsia) 0 26 200829162 Compositions of the invention In addition to the above agrochemically active compounds, other active compounds are also included as a mixing admixture, such as insecticides, attractants, bacteriostats, bactericides, acaricides, nematicides, fungicides, growth regulating substances, Herbicides, safeners, fertilizers or chemical messaging substances. Particularly desirable blending materials are, for example, the following: fungicides: inhibitors of nucleic acid synthesis: benalaxyl, bunda _M, bupirimate, chiralaxyl, klekang ( Ci〇Zyiacon), dimethirimol, ethirim〇l, furai_ axyl, hymexazol, mefenoxam, metalaxyl , killing Ning-m, ofurace, oxadixyl, oxolinic acid, mitosis and cell division inhibitors, benomyl, carbendazim , dietofencarb, ethaboxam, fuberi-dazole, pencycuron, thiabendazole, thiophanat-methyl, oxazamide (zoxamide) inhibitor of respiratory chain complex I, diflumetorim, inhibitor of respiratory chain complex, boscalid, carboxin, fenfu_ ram, fudoline (flutolanil), Fulakou ratio (furametpyr), Maogu 27 200829162 Le (furmecyclox ), mepr〇nil, oxycar-boxin, penthiopyrad, cyanofluoride (1:111; 〇117 & 1111(16) respiratory chain complex III Inhibitors of azoxystrobin, cyazofamid, dimoxystrobin, enestrobin, famo-xadone, fenamidone ), Fluoxa-strobin, kresoxim-methyl, metom-inostrobin, orysastrobin, pyraclo-strobin , picoxystrobin, trifloxy-10 strobin decoupling agent dinocap, fluazinam ATP inhibitor Fentin acetate, triphenyl Tintin 15 chloride, fentin hydroxide, silthiofam Amino acid biosynthesis and protein biosynthesis inhibitor anilino sneeze (andoprim), insurance Blastindin (S), cyprodinil, kasugamycin, carnitrol 2 Hydrogen hydrate, mepanipyrim, pyrim-ethanil information transfer inhibitor fenpiclonil, fludioxonil, quinoxyfen 28 200829162 Lipid and membrane synthesis The inhibitors are chlozolinate, iprodione, pro-cymidone, vinclozolin, ampropylfos, potassium-anthraquinone, edifen- 5 phos), etridiazole, iprobenfos (IBP), isoprothiolane, pyrazophos, biphenyl iodocarb, propamo -carb), plucker hydrochloride, pluck-ethyl phosphonate ergosterol biosynthesis inhibitor ίο cyclohexamid, azaconazole, bitertanol , bro·muconazole, cyproconazole, diclobutrazole, difenoconazole, dini-conazole, sulphate-M, fluorocyclic guanidine Epoxiconazole, is etaconazole, fenarimol, funk Fenbu-conazole, fluquinconazole, flurpri-midole, flusilazole, flutriafol, furconazole, protective sputum - Chuan page type, hexaco-nazole, imazalil, acesulfame sulfate, imibenconazole, ipconazole, metco-nazole, Myclobutanil, nuarimol, umami. Oxpoconazole, paclobutrazole, penconazole, pefurazoate, pro- chloraz, prokly 29 200829162 (propiconazole), prothio-conazole ), pyrifenox, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triflu-5 mizole ), triforine, triticonazole, uniconazole, voriconazole, viniconazole, aldimorph, dodemorph , diuron acetate, fenpropidin, fenpropimorph, 10 spiroxamine, tridemorph, naftifine, pyributicarb , terbinafine (terbinafine) cell wall synthesis inhibitors Benzovalicarb, bialaphos, dimethomoi^ph, flumorph, propyl ( Ipro_ valicarb), dipropionin ( Mandipropamid), polyoxins, polyoxorim, validamycin A, melanin biosynthesis inhibitors 2 carpropamid, chloramphenicol (diclocymet), fenoxanil, phthalide, pyroquilon, tricyclazole, resistance-inducing substance, benzo sigma II (&0. 112〇1&;1>_8-11161:11;71),扑杀热(口1#(^611- 30 (200829162 azole), tiadinil multisite (Multisite) tetrachlor (captafol), Gap Captan, chloro-thalonil, copper salt (such as: copper hydroxide, copper naphthalate, oxychlorinated copper, copper sulphate, copper oxide, oxine-copper) And Bordeaux mixture), dichlofluanid, dithianon, dodine, polyglycine free base, ferbate, folpet, fluoro Fluoro-folpet, guazatine, gram-heat acetate, diinxin 10 amine (iminoctadine), gram heat Burning besylate, bis-octylamine triacetate, mancopper, zinc I Mancozeb, maneb, mantram, free of zinc, methyl zinc (propineb), sulfur and sulfur preparations containing calcium polysulfide, thiram, tolylfluanid, zineb, ziram, other fungicides, abromo Amibromdol), benzene mouth plug. Sitting (benthiazol), bethoxazin, capsimycin, carv-one, qinomethionat, chloropicrin, copper cufraneb , cyflufenamid, cymoxanil, dazomet, debacarb, diclomezine, dichlorophen, dicloran, benzene Difenzoquat, benzoic acid sulfate, diphenylamine, ferimzone, fluxetover, husband 31 200829162 flusulphamide, fluopicolide, Fluoroimide, fosetyl-aluminium, triethylphosphonate-calcium, triethylphosphonate-sodium, hexabenzene, 8-hydroxy-indole sulfate, irumamycin , methasulfocarb, metrafenone, isothiocyanate, mildiomycin, natamycin, dimercaptodithiocarbamic acid nickel, Nitrothal-isopropyl, octyl ketone, oxamocarb, oroxyxan Oxyfenthiin), pentachlorophenol and salt, 2-phenyl sulfonate, piperalin, propanosine-sodium, proquinazid, pyribencarb, Pyrrolnitrin, quintozene, tecloftalam, tecnazene, triazoxide, trichlamide, Valiphenal, zarilamid, 2-(2-{[6-(3-chloro-2-indolylphenoxy)-5-fluoroindole-4-yl]oxy} Phenyl-2-(nonyloxyiminomercaptoacetamide, 2[[[[Η[(Η)]]]]]]]]]]]]]]]]]]]]]曱 亚 亚 - - - a a 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 Heptanol, Η(4-decyloxyphenoxy)indolyl]_2,2-dimethylpropyl-1Η-imidazole-1-decanoic acid, 2,3,5,6-tetrachloro-4-( Mercaptosulfonyl)pyridine, 2-butoxy-6-bromo-3-propylbenzothiamethane-4-S, 32 200829162 2-Chloro-N_(2,3-dihydro-1, 1,3-tridecyl _ih-$-4-yl)-3-acridiniumamine, 3,4,5-trichloro-2,6-oxime. Dicarbonitrile, 3,4-dichloro-(2-cyanophenyl)isothiazole _5-decylamine (isotianil), 3-[5-(4-gas-based) )_2,3-_曱基异口号Wow. Ding-3-yl] mouth bite, 5-chloro-6_(2,4,6-trifluorophenyl)-N-[(1R)_1,2,2-trimercaptopropyl]-[1, 2,4]三峻和[l,5-a]Bite -7-amine, 5-chloro-7-(4-mercaptohexahydropyridine small group)_6_(2,4,6-trifluorophenyl ) ίο [1,2,4]·Triazolo[l,5-a]pyrimidine, 5-chloro-N-[(1R)-1,2-dimercaptopropyl]_6_(2,4,6 _Trifluorophenyl) [1,2,4]trimetic [l,5-a> sessile-7-amine, 2-[[[cyclopropyl[(4- methoxyphenyl)imine] Ethyl]thiol]thiol]-α-(decyloxyindenyl) phenylacetate, is 1-(2,3-dihydro-2,2-diindenyl)-1Η- Imidazole-5-carboxylic acid decyl ester, Ν_(3',4'-dichloro-5-fluorobiphenylindyl) winter (difluorodecyl) small methyl formamide, N-(3-ethyl-3 ,5,5-trimethylcyclohexyl)-3-indenyl-2-hydroxy 20 benzoguanamine, N-(4-Gas-2-nitrophenyl)-N-ethyl-4- Nonylbenzylamine N'N-(4-chlorobenzyl)-3-[3-decyloxy-4-(prop-2-yn-1-yloxy)phenyl]propanamine, N -[(4-Phenylphenyl)(cyano)indolyl]-3-[3-methoxy-Kprop-2-yn-1-37 200829162 oxy)phenyl]propanamine, Ν- (5 chloropyridyl) fluorenyl]_2,4_di-nicotinamide It is called 1-(5-bromo-3-chloropyridin-2-yl)ethyl]_2,4-dichloronicotinium amide, (2S)-N-[2[4-[[3_(4 phenyl) _2•propynyl]oxy]oxomethoxybenzene5-yl]ethyl]fluorenyl_2_[(methylsulfonyl)amino]butanamine, N-{(Z)-[(cyclopropyl) Alkyloxy)imino][6-(difluorodecyloxy)-2,3-difluorophenyl]indolyl 2-phenylethylamine, Ν-{2-[1,1·-bis( Cyclopropyl)-2-yl]phenyl-3-(difluorodecyloxy)-1-indenyl-1H-indole. -4--4-甲胺胺, ίο N_{2-〇chloro-5-(trifluoromethyl)acridin-2-yl]ethyl b 2_(trifluoromethyl)benzamide, N-ethyl _N-fluorenyl_N'-{2-mercapto-5-(trifluoromethyl)-4-[3-(trimethylsulfanyl)propoxy]phenyl}aryleneamine hydrazine Amine, 0-[1-[(4-decyloxyphenoxy)indolyl]_2,2-dimercaptopropyl]-1H- 15 imidazolium thiocyanate, 2-amino-4-indenyl -N-phenyl-5-喧σ-sodium citrate, 2,4-dihydro-5-nonyloxy-2-methyl-4-[[[[1-[3-(trifluoromethyl))] Ethylene]amino]amino]oxy]indolyl]phenyl]-3Η-1,2,4-tris-s--3-anthracene (CAS No. 185336-79-2), 2〇Ν-(6 - 曱oxy-3-batch base) propyl acetoin. Bactericides: bronopol (bronopol), dichlorophenol, tris-pyridinyl (5) trapydn), - fluorenyl-monothiol decanoic acid, the most philanthropic, xin 嗔 g, 吱 竣 竣, tetracycline, chlorpyrifos, streptomycin, gram rot, copper sulphate and 34 200829162 other copper preparations. Insecticides/Acaricides/Nematicidal Agents AChE inhibitors, such as alanycarb, aldicarb, aldoxycarb, AilyXyCarb, aminocarb, bendiocarb, benfuracarb, bufencarb, butacarb, butocar·boxim, Ding Weitong Butoxycarboxim, carbaryl, carbofuran, carbosulphan, cloethocarb, dimetilaan, ethiofen-carb, diced Fenobucarb, fenthiocarb, formetanate, furathiocarb, iso-procarb, metam-sodium, chlorpyrifos Methicarb, methomyl, metolcarb, oxamyl, pirimicarb, prome- carb, propoxur, sulphur Thiodicarb, thiofanox, trimethacarb, XMC, lexica Ylcarb), triazamate organophosphates such as acephate, azamethiphos, azinphos (-mercapto, -ethyl), bromophos -ethyl, bromfenvinfos (-mercapto), chlorhexidine 35 200829162 (butathiofos) cadusafos, carbophenothion, chl〇rethoxyfos, fenfen Chlorfenvinphos, chl〇rmephos, chlorpyrifos (-mercapto/-ethyl), coumaph〇s, 5 cyanofenphos, cyanazine (Cyan 〇phos), chlorfenvinphos, dimeton-S-methyl, dimeton-S_methyl sulphon, dialifos, diazinon, diclofenac (dichlofenthion), dichlorvos/DDVP, dicrotophos, dimethoate, dimethylvinphos, dioxabenzofos, disulphoton, EPN, ethion, etho-prophos, etrimfos, Famphur, fenamiphos, fenitrothion, fensul_fothion, fenthion, σ flupyrazofos, fonofos, Formothion, f-sulphur dish (f〇s-methilan), fosthiazate, hepte-nophos, iodofenphos, ipro-benfos ), isazofos, isofenphos, iso- 2 propyl hydrazine-salicylate, isoxathion, mala-thion, mecarbam, extinction Mesacrifos, methamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, oxydemeton - 36 200829162 methyl), parathion (_曱基Λethyl), phenthoate, phorate, phosalone, phosmet, blessing Phosphadon, phosphocarb, phoxim, pirimiphos (-methyl/_ethyl , profenofos, propa-phos, propetamphos, pr〇thiofos, protlioate, pyraclofos, pyri-daphenthion ), pyridathion, qUi-nalphos, sebufos, sulfotep, sulprofos, tebupirimfos, abbott (tern-ephos), terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon, vamidothion sodium channel modulators /potential-dependent sodium channel blockers pyrethroids, such as acrinathrin, allethrin (d-cis-trans-d-trans), beta-saiconin (beta-cyfluthrin), bifen-thrin, bioallethrin, bioarylene, cyclopentyl-isomer, biopterin (bi〇ethanomethrin), biopermethrin , bioresmethrin, clovaporthrin, cis-saidingin (cy Permethrin), cis-column-Ning, cis-Bai-Ning, clocythrin, CyCi〇pr〇thrin, Saifuning, Cyhalothrin赛赛宁(α·,β-,θ-,ζ·), 37 200829162 cyphenothrin, deltamethrin, empenthrin (lR-isomer), Yihua Esfenvalerate, etofenprox, fenfluthrin, fenpropathrin, fen_pyridin, fenvalerate, fluflurin - cyhrinate), flucythrinate, flufen_prox, flumethrin, fluvalinate, fubenprox, gamma-cyhalothrin ), imiprothrin, kadethrin, lambda-cyhalothrin, metofluthrin, huntin (chuanchuan-, trans-), phenothrin (1R-trans-isomer), prallethrin, profluthrin, prot-rifenbute, pirixon (p Yresmethrin), ruining (5111 heart thrin), RU-15525, silafluofen, tauflu-15 valinate, tefluthrin, terallethrin,

Tetramethrin (1R isomer), tralome-thrin, transfluthrin, ZXI 8901, pyreth-thrins or pyrethrum 5 DDT 2〇吟二ϋ井Oxadiazines, such as indoxacarb, semi-calendar, such as metaflumizone (BAS3201), acetylcholine receptor potentiator/antagonist 38 200829162 gas in the test, such as sub-killing ( Acetamiprid), clothianidin, dinotefuran, imidacloprid, niten-Pyram, nithiazine, thiacloprid, speed 5 amps (thiamethoxam) nicotine, bensultap, cartap, amphibious receptor modulator, spinosyns, such as spinosad 10 GAB from controlled chloride Channel antagonists organochlorines, such as camphechlor, chlordane, endosulphan, γ-HCH, HCH, heptachlor, lindane, helium oxygen Methoxychlor 15 is not a generic (fiprols) such as acetoprole, love Ethiprole, fippron, pyrafluprole, pyripolle, vaniliprole, juvenile hormone mimics such as diofenolan, eprefene (epofenonane), fenoxycarb, hydroprene, ldnoprene, metheprene, pyriproxyfen, triprene, dermatone Activating agent/destroying agent 39 200829162 Diterpenoids such as chromafenozide, hafenofozide, methoxyfenozide, tebufenozide, chitinogenic synthesis inhibitor, benzoic acid, urea For example, bistrifluron, chlorfluazuron, diflubenzuron, fluazuron, flucyc-loxuron, flufenoxuron, hexaflu Hexaflumuron), lufenuron, novaluron, noviflu-muron, penfluron, teflubenzuron, triflumuron (buprofezin) cyromazine Oxidative phosphorylation inhibitor, ATP breaker diafenthiuron organotin compounds, such as azocyclotin, cyhexatin, fenbutatin oxide by interference Η-proton gradient oxidation Sexual phosphorylation decoupling azoles, such as chlorfenapyr dinitrophenols, such as binapacryl, dinobuton, white powder gram 200829162 (dinocap), DNOC, methyl white powder Site-I electron transport inhibitors METIs, such as fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tofinenpyrad ) Hydramethylnone dicofol site-II electron transport inhibitor squid squid-III electron transport inhibitor acequinocyl, fluacrypyrim insect microtubule destruction Bacillus thuringiensis strain lipid synthesis inhibitor season @ tetronic acid (tetronic acid), such as spirodiclofen (spirodiclofen), spiromesifen (spiromesifen) Tetramic acids, such as spirotetramate, cis-3-(2,5-dimethylphenyl X-hydroxy-8-methoxy-1-azaspiro[4.5]indole-3- Isobutyramines, for example, fl〇nicamid, octopaminergic synergists such as amitraz 41 200829162 Magnesium-irritating ATPase inhibitors, Oscar Propargite Nereistoxin analogues, such as thiocyclam hydrogen oxalate, thiosultap-sodium Rryanodine receptor potentiator benzomethamine, for example II flubendiamide anthranilamide such as rynapypyr (3-bromo{4_chloro-2·indolyl-6-[(decylamino)) ano] - 本基} -1 -(3-Gas ratio 0-but-2-yl)-1 Η-ϋ ϋ -5-5-nonylamine) Biological substance, hormone or pheromopurtin (azadirachtin) , Bacillus subtilis, Beauveria, codlemone, green genus, Paecilomyces, sulindac, Verticillium genus with unknown or non-specific mechanism of action , example Obstacles, sulfhydryl bromide, sulfur fluoride antifeedants, such as cryolite, flonicamid, pymetrozine cochlear growth inhibitors, such as clofentezine, kill. (etoxazole), 赛赛42 200829162 (hexythiazox) acid amine amidoflumet, benclothiaz, benzoximate, bifenazate, new bromopro- pylate ), buprofezin, chinomethionate, chlordimeform, chlorobenzilate > chloropicrin, clothiazoben, cycloprene ), cyflumetofen, dicyclanil, fenoxacrim, fentrifanil, flubenzimine, flufenerim, flutanin (flutenzin), hexadecyl ester (g0ssy- plure), hydramethylnone, japonilure, metoxadiazone, petroleum, sunflower-based butoxide, potassium oleate, bicali ( Pyridalyl), sulfluramid, tetra-15 difon, tetrasul, triarathene, verbutin. Mixtures with other known active compounds, such as herbicides, fertilizers, growth regulators, safeners, chemical signaling materials, or mixtures with improved plant traits are also possible. 20 When used as an insecticide, the compositions according to the invention may additionally be present as a mixture with their commercially available formulations or in a form of use (and thus prepared from such formulations) and a co-agent. The synergistic agent added to the compound which increases the effect of the active compound present in the composition according to the invention itself is not necessarily active. 43 200829162

When used as an insecticide, the compositions according to the invention may additionally be in the form of their commercially available formulations or in the form of use (and thus the preparation of the preparations) and in the plant environment, in the plant parts After the surface or after use in the plant weaving, the formulation which reduces the decomposition of the agrochemically active compound present is present as a mixture. The person in the form of the active compound in the form of the use of the commercially available formulation can be varied within a wide range. The concentration of the active compound in use and the weight of the C-active compound is from 〇〇〇〇〇〇〇〇1 to %%, preferably from about 0.00Ό01 to 1% by weight. The compound can be applied in a conventional manner in which the form of use is appropriate. All plants and plant parts can be treated in accordance with the invention. In this context, a plant means all plants and plant groups, such as desired and non-priced 5 stomach wild plants or crop plants (including naturally occurring crop plants = , which can be traditionally planted and optimized or borrowed by biotechnology and Plants obtained by a combination of these methods, including the base W box and the plants that can or cannot be protected by the variety rights, are poor, trees, roots, and roots. , needle apple, two trunks, flowers, fruit bodies, fruits, seeds, roots: straight: local also includes post-harvest materials and no. Such as seedlings, tubers, roots, cities and seeds. Inventive composition treatment = application: or by means of the traditional treatment method, ^ ^, can be directly "hair, micronized, spread, brush, injection, for 44 200829162 body or storage space to implement, and Seeds) may also be applied by single or multiple coatings (especially as described above in the 'Processing & Parts according to the invention. In the preferred embodiment, the plants of Yin and their species' or those borrowing from traditional organisms Breeding object And the plant-derived) and some of the crosses or protoplasts have been genetically engineered for specific purposes, and are responsible for the treatment of plant and plant varieties (genetic madness obtained by genetic law)" And parts of them. "Some parts of the community" and "plant parts," have been explained in the previous section. Plants can be obtained from the market or in the plant varieties used in the (four) Shikang treatment. The meaning has been borrowed: hunting mutants or plants grown by recombinant DNA technology ("characteristics"). They may be cultivars, biotypes and genotypes. 15 20 r = plant species or plant varieties, According to the region and the growing environment (soil, sputum: climatology, growth period, nutrition), the treatment according to the present invention can also be used to reduce the application rate. The extension/and/or increase of the month of the object can be used according to the invention to reduce the activity of the substance, to increase the plant growth, to increase the height or to receive:, to increase the force = =1 to the drought or water The content or soil salt content on the ancient Khan 1 匕 behavior, easier harvest, accelerated maturity, comparison: the higher quality of the harvested product and the higher nutrient price of the georgo than the actual storage of the pre-m Sex and/or processability may exceed 45 200829162 Plants or plant varieties (ie, those who receive the money) include all plants that are particularly beneficial and useful for plants such as 闵 闵 + = =; Low severity combined with drought or water or soil salt content = rate, easy release of harvest, accelerated maturity, higher yield of higher yields and / or higher nutritional value, harvest yield plus &quot ; 'Sex. Others of these characteristics and special 10 15 20 Another week's example is the plant defense against animal and microbial harmful substances (such as resistance to t, butterfly, phytopathogenic fungi, bacteria and / or viruses)柒 , and increase the tolerance of plants to specific active herbicidal substances. Examples of genetically modified plants that may be mentioned are important crop plants, such as cereals (wheat, ΐί), corn, soybeans, potatoes, beets, tomatoes, bowls. Beans and other vegetable varieties, cotton, tobacco, rapeseed and fruit plants (fruits such as apples, pears, citrus fruits and grapes) with special emphasis on corn, soybeans, potatoes, cotton, tobacco and rapeseed. Sexuality is the formation of toxins in plants by plants (especially those derived from S. cerevisiae, such as the genes CrylA(a), CrylA(b), CrylA(c), CryllA, CrylllA, CryIIIB2. Cry9c Cry2Ab, Cry3Bb and

The combination of CrylF and their combination in plants (hereinafter referred to as "Bt plants,") is resistant to insects, arachnids, nematodes, mites and snails. Increasing plant-induced disease resistance (SAR), systemin, plant antibiotics, inducing factors and resistance genes, and the resulting proteins and toxins of plants 46 200829162 Resistance to mold, bacteria and viruses Other special emphasis is on the increased resistance of plants to certain herbicidal compounds, such as imidazolium, sulfonylurea, carbofuran or phosphino-tricin (eg "PAT" genes). The genes that confer the desired characteristics may also be present in combination with each other in the genetically transformed plants. "Bt plants," examples of which are corn varieties, cotton varieties, soybean varieties, and potato varieties, may be mentioned. The trade names are YIELD GARD® (eg corn, cotton, soybeans), KnockOut® (eg 10 15 20 such as corn), StarLink® (eg corn), Bollgard® (cotton), Nuc Otn® (cotton) and NewLeaf® (potato). Mention may be made of herbicide-tolerant plants in the form of corn, cotton and soybean varieties, which are sold under the trade name Roundup Ready® (tolerant to Jiaphos, such as corn, cotton, soybeans), Liberty Link® (tolerant to grass, such as rapeseed), IMI® (tolerant to imidazolinone), and STS8 (tolerant to sulfonylurea, such as corn). Examples of herbicide resistant plants (plants traditionally grown for herbicide tolerance) which may be mentioned include those sold under the trade name Clearfield® (e.g., corn). Of course, these statements also apply to plant varieties with such genetic traits or genetic traits developed in the future, which will be developed and/or sold in the future. According to the invention, in a particularly advantageous manner, it is possible to use s. The above preferred ranges are also applicable to the plants. The 4 inch emphasis is on the use of plants in this article. Send = 47 200829162 Internal parasites, such as hard palate, soft palate, beast, leafhopper, fly (bite and cockroach) parasitic fly larvae, feathers, head lice and fleas. Such parasites include: Insects such as Haematopinus, Linognathus, Pediculus, Phtirus, and Solenopotes 5 genera. From the order of the genus and the obtuse and the suborders, such as the genus Trimenopon, the genus Menopon, the genus Trinoton, the genus Bovi cola, the genus Werneckiella, and the genus Lepikentron , the genus Damalina, the genus Trichodectes, and the genus Felicola 10 . Diptera and Nematocerina and Brachy-Cerina, such as the genus Aedes, the genus Anopheles, the genus Culex, the genus Simulium, true Eusimulium, Phlebotomus, Lutzomyia, 15 Culicoides, Chrysops, Hybomitra, Yellow Cattle (Atylotus) ) genus, genus Tabanus, genus Haematopota, Philipomyia, Braula, Musca, Hydrotaea, Stomoxys, horn The genus Haematobia, the genus Morellia, the genus Fannia, the genus Glossina, the genus Calliphora, the genus Lucilia, the genus Chrysomyia, Wool-fahrtia, Sarcophaga, Oestrus, Hypoderma, Gasterophilus, Hippo-bosca, Merlot Genus (Lipoptena), genus Melophagus. 48 200829162 蚤目, for example, the genus Pulex, the genus Ctenocephalides, the genus Xenopsylla, and the genus Ceratophyllus. Heteropterida, such as the genus Cimex, the genus Tri-atoma, the genus Rhodius, and the genus Panstrongylus. From the order of the eye, for example, Blatta orientalis, Peri- planeta americana, Blattella germanica, Supella. Metanal and post-and-middle Mesos-tigmata, such as the genus Argas, the genus Ornithodorus, the ear mites (Otobius) ), genus, Ixodes, Ambl- yomma, Boophilus, Dermacentor, Jemo Ha (Haemophysalis), Hyaloma, genus Rhinopis genus, Dermanyssus, Raillietia, Pneumonyssus, Sternostoma, and Varroa. Radix suborders (formerly valve suborders) and whitefly suborders (no valve suborders), such as Acarapis, Aphid (Cheyletiella), Ornithocheyletia, Myobia, Psorergates , Demodex genus, Trimombia genus, Listrophorus, Acarus genus, Tyrophagus genus, Caloglyphus genus, Hypodectes genus , Pterolichus, Psoroptes, Choriopteres, Otodectes, Sar-coptes, Notoedres 49 200829162 Genus, knee (Knemidocoptes) genus, (Laminosioptes) genus. The sheath of the genus Cytodites is also suitable for use in accordance with the composition of the present invention: Π: Π: cattle, sheep, goats, horses, pigs, donkeys, turkeys, turkeys, ducks, cranes and bees), other pets (such as Dogs, dragonbirds and aquarium fish, and arthropods on so-called test animals (such as stagnation, squirrel and stinging). By controlling these limbs, it can alleviate the easy death and productivity (for meat, milk, hair, skin, eggs, 10 15 20 , = ', etc.) ▲ reduce 'by making the daily composition of the hair Animal husbandry that is more/back and easier. The composition according to the present invention is used in the veterinary industry and in the animal husbandry industry in a conventional manner, and can be, for example, in the form of tablets, capsules, drinks, veterinary syrup, f-tablets, paste t, bolus, and penetration method. The suppository form is administered by the intestine, and is administered by a peripheral agent, for example, by injection (intramuscular, subcutaneous, intravenous, abdominal, internal, etc.), graft, by nasal application, for example by soaking or bathing, spraying , pour and rub, wash and smear in the form of a skin and application by means of a molded article comprising an active compound, such as a collar, ear tag, tail tag, limb bandage, reins, marking device, and the like. When used in livestock, poultry, pets, etc., the composition of formula (1) may comprise a formulation (for example, a powder, an emulsion, a free-flowing composition) in an amount of from 1 to 80% by weight of the active compound, either directly or at 1 〇〇. They are used after 1 〇〇 (8) dilution, or they can be used as chemical baths. It has further been found that the composition according to the present invention also has a strong insecticidal activity against insects which destroy industrial substances. 50 200829162 The following insects can be mentioned as examples and are preferred (but without any limitation): Bees, such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, 5 Xestobium Rufo- villosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctusbrunneus, Lyctusafricanus, Lyctus planicollis, Lyctus Linearis), Lyctus pubescens, Trogoxylon aequale, Minthes 10 rugicollis, Xyleborus, Tryptodendron, Apate mona_chus, Bostrychus capucins, Heterobostrychus brunneus ), Sinoxylon genus, Dinoderus minutus; Hymenopterons, such as Sirex i5 juvencus, Urocerus gigas, Tailikou big tree bee ( Urocerus gigas taignus), tree bee (Urocerus augur); termites, such as the European wood termite (Kalotermes flavicollis) , Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes 2〇 santo- nensis, Reticulitermes lucifugus,

Mastot- ennes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus, Bristletails, such as Lepisma saccharina o Industrial substances described herein should be understood as non-living substances, such as 51 200829162 ( Preferably, plastics, adhesives, coatings, paper and board, leather, wool and processed wool products and coating compositions. The splitting composition may additionally comprise an insecticide and, if appropriate, one or more fungicides, as appropriate. 5 Regarding other additives of "^, the above-mentioned insecticides and fungicides can be mentioned. Compositions in accordance with the present invention can also be used to protect objects (especially shells, screens, nets, buildings, moorings, and semaphore systems) that are in contact with saline or brackish water from fouling. The composition according to the present invention, alone or in combination with other active compounds, can be used as an antifouling agent. For the protection of home, sanitation and storage items, the composition is also suitable for controlling animal pests, especially insects and arachnids in confined spaces (eg residential, factory corridors, office to, car trunks, etc.) . 15 They may also be used in household insecticidal products to control such pests, either alone or in combination with other active compounds and adjuvants. They are sensitive to and resistant to species and active to all stages of growth. Such pests include: Moths such as Buthus occitanus. Walls 13⁄4 mesh' such as Argas persicus, Argas 2〇reflexus, Bryobia genus, Dermanyssus gallinae, Glyciphagus domesticus, Ornitho- Dorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, powder 52 200829162 Dermato- phagoides forinae 〇 知 知 , , , (Aviculariidae), gold test (Araneidae) genus. Blind spiders, such as Pseudoscorpiones chelifer, Pseu- doscorpiones cheiridium, Obilis phalanxgium °, such as the genus Oniscus asellus, Porcellio scaber o For example, Blancoi guttulatus and Poly-desmus belong to the genus Ligustrum, such as the genus Geophilus, such as the genus Ctenolepisma and the squid. (Lepisma saccharina), Lepismodes inquilinus, for example, Blatta orientalis, Blat_ tella germanica, Blattella asahinai, Leucophaea maderae , the genus Panchlora, the genus Parcoblatta, the Periplaneta australlasiae, the Periplaneta Americana, the Periplaneta brunnea, the Periplaneta 2〇fuliginosa, Supella longipalpa 〇 Jumping suborders, such as Acheta domesticus. Genus, such as Forficula auricularia. Isoptera, such as the genus Kalotermes and the genus Reticulitermes. 53 200829162 Oral insects such as the genus Lepinatus and the genus Liposcelis. Coleoptera 'for example, the genus Anthrenus, the genus Attagenus, the genus Dermestes, the Latheticusoryzae, the genus Necrobia, the genus Ptinus, the glutinous rice (Rhizopertha 5 dominica), Sitophilus granaries, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum, Diptera, such as Aedes aegypti, white lines Aedes albopictus, Aedes taeniorhynchus, Anoph- eles, Calliphora erythrocephala,

Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila genus, Fannia canicularis, Musca domestica, Phlebotomus, Sarcophaga i5 camaria, Simum genus, Stomoxys genus, Stomoxys calcitrans, Tipulapaludosa 〇 Lepidoptera, for example small Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella For example, enocephalides canis, enocepha-lides felis, Pulex irritans, Tunga pene-trans, Xenopsylla cheopis. Hymenoptera, such as Camponotusherculeanus, Black Grass 54 200829162 r Ant (Lasius fuliginosus), Black Garden Ant (Lasius niger), Male Ant (Lasius umbratus), Monomorium pharaonis, Paravespula Genus, paving Tetramorium caespitum o Insects such as Pediculus humanus capitis, Pediculus humanus corporis, Pemphigus genus, Phylloera vastatrix, Phthirus pubis o Heteroptera, such as tropical bugs (Cimex) Hemipterus), Cimex lectularius, Rhodinus prolixus, Triatoma infestans o 10 In the field of household insecticides, they may be used alone or in combination with other suitable active compounds, such as phosphates, urethanes Classes, pyrethroids, novels, growth regulators, or combinations of active compounds derived from other known classes of insecticides are used. According to SR Colby, Weeds 15 (1967), 20-22, the expected effect of a particular composition of two active compounds can be calculated as follows: If X is used at a rate of ΠΙ_g/ha or at a concentration of ppm The lethality at the time of active compound A, expressed as % of the untreated control group, 20 Y is the lethal rate when the active compound B is applied at an application rate of SL g/ha or at a concentration of n ppm, as % of the untreated control group Indicates that E is the lethal rate when the active compounds A and B are used at an application rate of 2 L and g/ha or at concentrations of _ and n ppm, expressed as % of the untreated control group, 55 200829162 then Ε = Χ + Υ - ΧΎ 100 If the actual lethality exceeds the calculated value, the effect of the composition is superadditive, that is, there is a synergistic effect. In this case, the actual observed lethality must exceed the value calculated using the above formula for the expected lethality (Ε). [Implementation content]

Example A Spodoptera frugiperda test To make a suitable product solution, 1 part by weight of the formulated product is (SC 120) was diluted with water to the desired concentration. Add a defined amount of the desired adjuvant and confuse it. The corn plants (Zea wa; ^) are washed with a product solution of a desired concentration and infected with the larvae of the army worm (Autumn worm). After the desired time, the % effect was measured. 100% means that all hairs are killed; 〇% means that no caterpillars are killed. Bring the measured lethality into

Colby formula (see Table 1). In this test, for example, the following compositions of the active compound and the adjuvant according to the present application exhibit synergistic enhancing activity compared to the active compound administered alone: 56 200829162 Table A1 Plant Insect Insect Autumn Runner Test, The concentration of active compound after infection for 3 days after application of drip irrigation, in milligrams per hectare or the mortality rate 7 days after infection, in terms of product per liter of soil (II-2) 0.5 0 0.25 0 Aerosol8 OT-B 1000 0 ( 11-2)+ found value 1 calculated value 2 Aerosol® OT-B 0.5 + 1000 94 0 According to the invention 0.25 + 1000 83 0 GenapofLRO paste 1000 0 (Π-2)+ found value 1 calculated value 2 GenapofLRO paste 0.5 + 1000 88 0 According to the invention Plurafac 8 LF 132 1000 0 (Π-2)+ found value 1 calculated value 2 Plurafac® LF 132 0.5+1000 95 0 According to the invention 0.25+1000 93 0 Plurafac8 LF 231 1000 0 (Π- 2)+ found value 1 calculated value 2 Plurafac 8 LF 231 0.5+1000 93 0 According to the invention 0.25+1000 45 0 57 1 Found value = found activity 2 5 2 calculated value == activity calculated using Colby formula 200829162 Table A2 Plant damaging insect autumn In the army insect test, the concentration of the active compound after 7 days of application after drip irrigation, in the case of grams per hectare or the mortality rate 7 days after infection, in terms of product per liter of soil (ΙΙ·2) 0.5 0.25 25 25 ammonium sulfate 1000 0 (11-2)+ Sulfate according to the invention 0.5 + 1000 0.25 + 1000 Found value * Calculated value ** 80 25 70 25 Amulsol® PSA 81 A 1000 0 (11-2) + Amulsol® PSA 81 A According to the present Invention 0.5 + 1000 Found value * Calculated value ** 95 25 Betaine 1000 0 (11-2) + Betaine According to the invention 0.5+1000 Found value * Calculated value ** 94 25 Crowol® CR 70 G 1000 0 (Π- 2) + Crowol® CR 70 G According to the invention 0.5+1000 found value* calculated value** 89 25 dioctylsulfosuccinate 1000 0 (Π-2)+ dioctylsulfolyl hydrochloride Invention 0.5 +1000 0.25 + 1000 Found value * Calculated value** 95 25 95 25 58 200829162 Active compound concentration in mg/ha or % of death 7 days after infection Genapol® C 100 per liter of soil product 1000 0 (Π-2)+ Genapol® C 100 According to the invention 0.5 + 1000 found value 1 calculated value 2 88 25 Lutensol® TO 10 1000 0 (Π-2)+ Lutensol® TO 10 According to the invention 0.5 + 1000 0.25 + 1000 found value 1 calculated value 2 97 25 90 25 Lutensol® TO 20 1000 0 (11-2) + Lutensol® TO 20 0.5 + according to the invention 1000 0.25 + 1000 found value 1 calculated value 2 78 25 45 25 Sapoginat® T 130 1000 0 (11-2) + Sapoginat8 T 130 According to the invention 0.5 + 1000 0.25 +1000 found value 1 calculated value 2 98 25 94 25 Sapoginat® T 500 1000 0 (Π-2)+ Sapoginat® T 500 According to the invention 0.5 + 1000 found value 1 calculated value 2 85 25 59 1 found value = found activity 2 calculated value = activity calculated using Colby formula 200829162 Table A3 plant Insect-resistant insects in the autumn army insect test, the concentration of active compound after infection for 14 days after drip irrigation, in milligrams per hectare or the mortality rate in 7 days after infection, in terms of product per liter of soil (II-2) 0.5 0.25 60 55 Armoblem 615 1000 0 (11-2) + Armoblem 615 According to the invention 0.5 + 1000 0.25 + 1000 Found 1 Calculated value 2 88 60 70 55 Soy lecithin 1000 0 (Π-2) + soy lecithin 0.5 according to the invention + 1000 found value 1 calculated value 2 95 60 Superb (HC) MSO 1000 0 (Π -2) + Superb (HC) MSO According to the invention 0.5+1000 0.25+1000 found value 1 calculated value 2 93 60 90 55 Silwett L77 1000 0 (11-2) + Silwett L77 Found according to the invention 0.5+1000 0.25+1000 Value 1 calculated value 2 98 60 95 55 60 1 Found value = found activity 2 5 2 calculated value = activity calculated using Colby's formula 200829162 Table A4 Plant-damaging insects autumn marching insect test, infection 3 days after administration Compound concentration, in mg/ha or % of death 7 days after infection, based on product per liter of soil (II-1) 1.0 0.5 20 7 Aerosol 8 OT-B 2000 0 (Π-1) + Aerosol® OT -B According to the invention 1.0 + 2000 0.5 + 2000 found value * calculated value ** 100 20 83 7 Agrimul® RSO1503 2000 0 (II_1) + Agrimul® RSO 1503 According to the invention 1.0 + 2000 found value * calculated value ** 63 20 Emulan® HE 50 2000 0 (11-1)+ Emulan® HE 50 According to the invention 1.0+2000 found value* calculated value** 47 20 Plurafac® LF 231 2000 20 (11-1)+ Plurafac® LF 231 according to the invention 1.0 + 2000 0.5 + 2000 Found value * Calculated value ** 36 98 25.6 Silwett L77 2000 0 61 200829162 Active compound Concentration in milligrams per hectare or % of death 7 days after infection in terms of product per liter of soil (11-1) + Silwett L77 According to the invention 1.0 + 2000 0.5 + 2000 found value 1 calculated value 2 93 20 67 7 Surfynol® TG 2000 0 (11-1)+ Surfynol® TG According to the invention 1.0 + 2000 0.5 + 2000 Found 1 Calculated value 2 65 20 60 7 Witconol® NS 500 LQ 2000 0 (11-1)+ Witconol8 NS 500 LQ According to the invention 1.0 + 2000 found value 1 calculated value 2 83 20 62 1 found value = found activity 2 calculated value = activity calculated using Colby formula 200829162 Table A5 Plant damaging insect autumn marching insect test, after drip irrigation application Ingredient concentration of active compound for 5 days, in mg/ha or % of death after 4 days of infection, based on product per liter of soil (II-1) 1.0 70 0.5 33 Imbentin® AG S 90 2000 17 (11-1) + found value * calculated value ** Imbentin® AG S 90 1.0 + 2000 99 75.1 0.5 + 2000 65 44.39 according to the invention * found value = activity found 5 ** calculated value = activity calculated using the Colby formula 63

Claims (1)

200829162 X. Patent application scope: 1. A method for controlling animal pests or phytopathogenic fungi by applying an agrochemical composition comprising at least one agrochemical active compound selected from the group consisting of insecticidal bismuth citrate to plants The culture medium is characterized in that it is characterized by applying a composition comprising at least one adjuvant. 2. The method according to item 1 of the patent application, characterized in that the adjuvant is selected from the group consisting of sodium dioctylsulfosuccinate, - comprising sodium dioctylsulfosuccinate and benzoquinone a composition of sodium, a 10-blocked alkoxylated fatty alcohol and a blocked alkoxylated linear alcohol, a tributylphenol polymerized glyceryl ether having 10 to 15 EO units (where EO means Ethylene oxide), a polyalkylene oxide modified polyfluorenyl phthalate, a branched alkanol is a calcined oxide of the formula CH3-(CH2)rCH2-CK-CH2-CH2-〇-)uH, wherein t represents The number from 9 to 10.5 and u represent from 6 to 25, - beet test, - polyoxylated triglyceride, - alkoxylated fatty amine, sodium 20-sodium lauryl ether, - PEG-10 coconut alcohol, And - a composition comprising corn syrup, thiolated soybean oil and a nonionic emulsifier. 3. An agrochemical composition for use in soil comprising: 64 200829162 - at least one agrochemically active compound, - at least one adjuvant selected from the group consisting of sodium dioctyl sulfosuccinate, a composition comprising sodium dioctylsulfosuccinate and sodium benzoate, a 5-blocked alkoxylated fatty alcohol and a blocked alkoxylated linear alcohol, having from 10 to 15 EO units Tributyl phenol polymerized glyceryl ether (where EO means ethylene oxide), polyoxyalkylene modified polyfluorenyl oxa oxide, -CH3_(CH2)t-CH2-CK-CH2-CH2-0-) a branched alkane of uH, wherein a t represents a number from 9 to 10.5 and u represents a number from 6 to 25, a betaine, a polyoxyalkylated triglyceride, an alkoxylated fatty amine , 15 - sodium lauryl ether sulfate, - PEG-10 coconut alcohol, and - a composition comprising corn syrup, thiolated soybean oil, and a nonionic emulsifier. 4. The composition according to item 3 of the patent application, comprising 20 - at least one nonionic surfactant and / or at least one anionic surfactant, - one or more additives selected from the group consisting of anti-beaming agents, antifoaming agents, preservation a group of agents, antioxidants, spreading agents, colorants, and/or bulking agents. 5. According to the composition of claim 3 or 4, comprising 65 200829162 kinds of agrochemical active compounds from insecticidal bismuth citrate from 1 to 60% by weight of at least monthly females, 'from 1 to 50 weight % at least one adjuvant, _% by weight of a nonionic surfactant and/or 1 ionic surfactant, from 1 to 20% by weight of antifreeze, and 6.1 to 20% by weight An additive selected from the group consisting of antifoaming agents, preservatives, antioxidants, spreading agents, colorants, and/or thickeners. The composition of any of items 3 to 5 of the scope of the patent application is that it comprises at least one active compound selected from the group consisting of (1) 2 and (II-3): (U_2) (Π4.) 66 15 200829162 7. The composition according to item 6 of the scope of the patent application, comprising at least one active compound selected from the group consisting of (IM) and (II-2) according to item 6 of the patent application. 8. The use of an adjuvant for improving the action of crop protection agents in soil application. 9. Use according to item 8 of the scope of the patent application, characterized in that at least 10 adjuvants selected from the group consisting of: - sodium dioctylsulfosuccinate, - comprising dioctylsulfosuccinium, are used. a composition of sodium and sodium benzoate, a blocked alkoxylated fatty alcohol and a blocked alkoxylated linear alcohol, a tributylphenol polymeric glyceryl ether having from 10 to 15 EO units ( Its 15 EO means ethylene oxide), - polyalkylene oxide modified polydecyl methoxyalkane, - branched CH3_(CH2)rCH2-0-(-CH2-CH2-0-)uH And t represents a number from 9 to 10.5 and u represents a number from 6 to 25, 20 - beet test, - polyoxyalkylated triglyceride, 67 200829162 - alkoxylated fatty amine, - lauryl ether Sodium sulfate, -PEG-10 coconut alcohol, and - a composition comprising corn syrup, methylated soybean oil, and a nonionic emulsifier. 68 200829162 VII. Designation of representative representatives: (1) The representative representative of the case is: (No). (2) Simple description of the symbol of the representative figure: None 10 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None 4