TW200906302A - Method of pest and/or disease control - Google Patents
Method of pest and/or disease control Download PDFInfo
- Publication number
- TW200906302A TW200906302A TW97111946A TW97111946A TW200906302A TW 200906302 A TW200906302 A TW 200906302A TW 97111946 A TW97111946 A TW 97111946A TW 97111946 A TW97111946 A TW 97111946A TW 200906302 A TW200906302 A TW 200906302A
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- Taiwan
- Prior art keywords
- growth medium
- fungicide
- plant
- particles
- granules
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
200906302 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種疾病及/或有害生物控制的方法,及 更具體地,關於一種藉由添加殺蟲劑顆粒至生長培養美 以控制植物之疾病及/或有害生物的方法。其也關於本身含 有殺蟲劑顆粒之生長培養基。 【先前技術】 有害生物及疾病對植物生長係麻煩事,因為它們可以 傷害及殺死植物、降低作物產量、及減損植物的視覺外觀。 用於有害生物及疾病控制的殺蟲劑係常常藉由葉子噴夜 根部浸液或施用至或生長培養基表面土壤的液態混和物或 顆粒之方式施詩植物,作^療措施,以反應被特定疾 病或有害生物感染的襲擊。‘然而,這些調配物中無—係理 想的m和及施用該調配物的人具有暴露至該殺 的風險。 因此,對可造成操作者較少暴露至殺蟲劑可較安全的 殺蟲劑調配物、或殺蟲劑的遞送機制存在需求。進—步, 對可以被施用作為預防性抖 v 、 r生措%,以停止或延遲植物中疾症 或有害生物的襲擊,而不a ,,. 疋作為治療措施的殺蟲劑調配 物,存在需求。 j % 殺蟲劑之顆粒調配物 S ’顆粒殺蟲劑調配物係 (例如’高爾夫場地), 係已知。在草皮工業上,舉例而 方便於殺蟲劑之快速散佈至草皮 其對操作者具有最低的暴露。散 200906302 布後茅頁粒留在草地的表面上,及直到殺蟲劑被釋放至 土壤,通常在與水接觸之後。 含有肥料顆粒之生長培養基係亦已知。典型上’肥料 係在數週或月的期間,由顆粒被漸漸地釋放,以提供長 間的肥料作用。 一 然而,以顆粒的形式添加殺蟲劑(如殺真菌劑)至植 物生長心養基中係未知。令人舒異地,已經發現,以顆粒 的形式添加殺蟲劑至生長培養基本身,對播種及生長於此 之植物,可以提供良好的有害生物及/或疾病控制。因此, 此係有用於作為用於延遲栽種於生長培養基的植物,疾病 與有害生物之侵襲的預防性處理。 、 【發明内容】 因此,根據本發明,提供了控制植物中疾病及/或有害 生物的方法,#包含添加含有至少一種殺蟲劑之顆粒至: 長培養基中,及種植植物於該生長培養基中。 本發明亦提供控制植物中疾病及/或有害生物的方法, 其包含種植植物於含有包含至少一種殺蟲劑之顆粒的 培養基。 I發明亦提供製造會給予生長於此之植物對疾病及/或 有害生物的抗性的生長培養基的方法,其包含添加含有至 少一種殺蟲劑之顆粒至生長培養基申。 岡彙控制”意指預防及治療兩者。舉例而士,其包 括預防疾病或有害生物侵擾、保護植物遠離疾病^有 200906302 及對付或殺死 物仅擾、減緩疾病或有害生物侵擾之襲擊 疾病及/或有害生物。 生長培養基”係使用於㈣植物的物質。在本發明 ’其包括任何植物可以被種植的合適培養基。生長培養 二:3有夕於一種之成分,舉例而言,無機物質,如石 :朱石蛭石、沙、泥沙及黏土及/或有機物質,如泥 皮、肥土、椰子纖維。生長培養基係常常被調配自 二加工物質的混合物,以達到用於植物生長的空氣及 水为保持容積的正確平衡。 使用於此之字彙,,顆粒,,包括任何形狀或尺寸之顆粒, 就舉例的範圍而言’由非常小之顆粒(其類似粉末或灰塵) :大顆粒(其類似錠劑)。適合地,顆粒之直徑係在範圍 '认5mm到2_0mm,更適合地從〇.5mm到1.5mm。適合 地,顆粒係近乎相同形狀及尺寸,以幫助在生長培養基中 的良好散佈。200906302 IX. Description of the Invention: [Technical Field] The present invention relates to a method for controlling diseases and/or pests, and more particularly to a method for controlling plants by adding insecticide particles to growth and beauty Methods of disease and/or pests. It also relates to growth media which themselves contain insecticidal particles. [Prior Art] Pests and diseases are troublesome for plant growth because they can damage and kill plants, reduce crop yield, and detract from the visual appearance of plants. Pesticides for pests and disease control are often applied to the poultry by means of leaf immersion in the roots or liquid mixture or granules applied to the soil on the surface of the medium. Attack of disease or pest infection. ‘However, none of these formulations are desirable and the person administering the formulation has a risk of exposure to the kill. Therefore, there is a need for a delivery mechanism for insecticide formulations, or insecticides, which can result in less exposure of the operator to the pesticide. Step-by-step, which can be administered as a preventive shaker, to reduce or delay the attack of a disease or pest in the plant, without a, ,. 杀 as a therapeutic measure of the pesticide formulation, There is a demand. j % Pesticide particle formulation S 'granular insecticide formulation system (e.g., 'golf course') is known. In the turf industry, for example, it is convenient to spread the insecticide quickly to the turf which has the lowest exposure to the operator.散 200906302 The saplings remain on the surface of the grass and until the pesticide is released into the soil, usually after contact with water. Growth medium containing fertilizer granules is also known. Typically, the fertilizer is gradually released from the granules over a period of weeks or months to provide a long-term fertilizer action. However, the addition of insecticides (e.g., fungicides) to the growth of the plant in the form of granules is unknown. Surprisingly, it has been found that the addition of pesticides to the growth medium itself in the form of granules provides good pest and/or disease control for plants that are sown and grown there. Therefore, this has been used as a preventive treatment for delaying the invasion of diseases and pests of plants grown in a growth medium. SUMMARY OF THE INVENTION Accordingly, in accordance with the present invention, there is provided a method of controlling diseases and/or pests in a plant, #include adding particles containing at least one insecticide to: a long medium, and planting the plants in the growth medium . The invention also provides a method of controlling diseases and/or pests in a plant comprising growing a plant in a medium comprising granules comprising at least one insecticide. The invention also provides a method of making a growth medium which will confer resistance to diseases and/or pests to plants grown thereon, which comprises adding particles containing at least one insecticide to the growth medium. "Okaye Control" means both prevention and treatment. For example, it includes prevention of disease or pest infestation, protection of plants away from disease ^200906302 and attacking or killing only disturbing, slowing down diseases or pests And/or pests. Growth medium" is used in (iv) plant matter. In the present invention, it includes any suitable medium in which any plant can be planted. Growth and culture 2:3 In the case of a composition, for example, inorganic substances, such as stone: vermiculite, sand, silt and clay and / or organic matter, such as mud, loam, coconut fiber. Growth medium is often formulated from a mixture of two processing materials to achieve the correct balance of air and water for plant growth to maintain volume. As used herein, granules, including particles of any shape or size, are by way of example 'by very small particles (which are similar to powder or dust): large particles (which are similar to tablets). Suitably, the diameter of the particles is in the range '5 mm to 2_0 mm, more suitably from 〇5 mm to 1.5 mm. Suitably, the granules are nearly identical in shape and size to aid in good dispersion in the growth medium.
顆粒係存在於生長培養基,而不是簡單地分佈於表面。 、&地顆粒係散佈於生長培養基中。顆粒可以藉由手工 或機械被散佈於生長培養基中。每公升生長培養^所加入 員粒之數目係基於所需活性成分之劑量、及顆粒之尺寸來 典型上’每公升生長培養基係加入1〇〇及1000之 貝粒在一具體實例中’顆粒係在種植前被加至加入 生長培養基中’其幫助完全地混和’及因此有助於確定顆 板係散佈於整個生長培養基中。 在本發明之一具體實例中,多於一種殺蟲劑係使用於 200906302 分開的顆粒,用於以適當量共同混和至生長培養基,以達 到需要的劑量比例。適合地,顆粒係在尺寸上相似,以確 保適當的混和及散佈。如此一來,生長培養基可以殺蟲劑 顆粒混和物訂製改造,以合適特殊植物物種及被使用之生 長環境。在進一步具體實例中,每一個別顆粒可以含有多 於-種殺蟲劑,舉例而言,殺真菌劑及殺昆蟲劑,或兩種 不同的殺真菌劑。後者可有用於在抗性處理上作為有效工 具’以及改善疾病控制之範圍及效力。 顆粒可以被加入到任何適合於生長植物之生長培養 基。典型上,生長培養基會係超過一種組分之混合物。舉 例而言,對於觀賞植物,生長培養基可以包括一或多種以 下組分:淺色泥煤、暗色泥煤、珍珠岩、虫至石、樹皮、沙、 泥沙、黏土及椰子纖維。生長培養基之精確組成取決於欲 生長之植物物種。舉例而言,對於花壇植物,生長培養基 可以具有60%肥土,30%石棉及2〇%沙。生長培養基可以 係少土混和(不含有任何沙、泥沙或黏土),或含土之混 和。較佳地,顆粒係混合到’及完全散佈遍及於生長培= 基,以確保活性成分之良好分佈(當其被釋放時)。。 本發明使用之顆粒調配物包括擠壓appiei沖^製物及 相對粗輕的顆粒。除了殺蟲劑之外,通常地,顆粒可以包 括填充劑(亦稱為載劑)、表面活性劑(此詞囊可以包= 分散劑及潤濕劑)及助劑就如黏結劑、安定劑及緩衝^。 填充劑可以係惰性的’或可以提供生物性功能,例如作 為肥料。填充劑,以及其他組分’在顆粒製備或長時間儲 200906302 存或在田野間使用時, 熟悉該項技藝者可以容 等準則。 較佳地應不會降解殺蟲 易地挑選適當顆粒組分 活性物質。 ,以符合此 用於顆粒调配物之业开丨恭亦丨勹 < 一坦载劑包括肥料、沙、石灰石、 漂白土、鎮紹海泡石黏土、 〜工微晶咼嶺土、蛭石、珍 珠岩、碳酸鈣、磚塊、浮石、 一 果嘴石、同嶺土、白雲石、 灰泥、木粉、玉米穗粉、花 王成物糖、氯化鈉、硫酸納、 矽酸鈉、硼酸鈉、氧化餻、承 礼化鎬、雲母、氧化鐵、氧化鋅、氧化 鈦、氧化銻、冰晶石、石膏、 ^ 臼垩粕、沸石、方解石、石夕 漠土、硫酸4弓及其他有機或益拖私妨 负俄次無機物為,其吸收殺蟲劑,或 其可以被殺蟲劑所包覆。The granules are present in the growth medium rather than being simply distributed on the surface. , & granules are dispersed in the growth medium. The particles can be dispersed in the growth medium by hand or mechanically. The number of granules added per liter of growth culture is based on the dose of the active ingredient required, and the size of the granules. Typically, '1 liter and 1000 lbs of granules per liter of growth medium are added to a specific example. It is added to the growth medium before planting, which helps to completely mix and thus helps to determine that the plate is dispersed throughout the growth medium. In one embodiment of the invention, more than one insecticide is used in 200906302 separate granules for co-mixing to the growth medium in an appropriate amount to achieve the desired dosage ratio. Suitably, the granules are similar in size to ensure proper mixing and spreading. In this way, the growth medium can be tailored to the insecticide particle mixture to suit the particular plant species and the environment in which it is used. In further embodiments, each individual particle may contain more than one insecticide, for example, a fungicide and an insecticide, or two different fungicides. The latter can be used as an effective tool in resistance treatment' and to improve the scope and effectiveness of disease control. The granules can be added to any growth medium suitable for growing plants. Typically, the growth medium will be a mixture of more than one component. For example, for ornamental plants, the growth medium may include one or more of the following components: light peat, dark peat, perlite, worm to stone, bark, sand, sediment, clay, and coconut fiber. The precise composition of the growth medium depends on the plant species to be grown. For example, for flower bed plants, the growth medium may have 60% loam, 30% asbestos and 2% sand. The growth medium can be mixed with less soil (without any sand, silt or clay) or mixed with soil. Preferably, the granules are mixed to ' and completely dispersed throughout the growth medium to ensure a good distribution of the active ingredient when it is released. . The granule formulations used in the present invention include extruded appiei and relatively coarse particles. In addition to insecticides, in general, the granules may include fillers (also known as carriers), surfactants (which can be included as a dispersant and a wetting agent), and auxiliaries such as binders, stabilizers. And buffer ^. The filler may be inert or may provide biological function, for example as a fertilizer. Fillers, as well as other components, can be tolerated by those skilled in the art when preparing for particle preparation or long-term storage in 200906302 or when used in the field. Preferably, the appropriate particulate component active material should be readily selected without degrading the insecticide. In order to comply with this industry for the preparation of granules, Gong Yiyi also has a carrier including fertilizer, sand, limestone, bleaching earth, Zhenshao sepiolite clay, , perlite, calcium carbonate, brick, pumice, a fruit, stone, dolomite, dolomite, stucco, wood flour, corn ear powder, Kaocheng sugar, sodium chloride, sodium sulphate, sodium citrate, Sodium borate, cerium oxide, cerium oxide, mica, iron oxide, zinc oxide, titanium oxide, cerium oxide, cryolite, gypsum, lanthanum, zeolite, calcite, Shixia desert, sulfuric acid 4 bow and other organic Or the benefit of the Russian private minerals, which absorb insecticides, or they can be coated with insecticides.
/顆粒基質物質可以係上述提及之典型載劑之一及/或可 以係肥料物質,如尿素/甲搭肥料、尿素、卸化合物(如疏 酸鉀、石肖酸鉀、氣化鉀、氧化鉀、偏磷酸卸)、錢化合物 (如確酸銨、硫酸銨、磷酸幻、碟化合#(如賴)、 硫磺、相似之植物營養素及微量營養素及其混和或組合 物。殺蟲劑可以被均勻地分佈遍及顆粒、在顆粒形成後喷 灑浸潰或吸收於顆粒基質上、或包覆於顆粒表面上。 黏結劑可以被使用於凝聚顆粒之組分。當其存在時, 黏結劑典型地可以以重量計最多至大約顆粒組成物(乾 重)百分之20,更典型地以重量計大約介於百分之2至2〇 之量使m结劑黏、结成分至顆粒基質,其抵抗磨損及不 會被快速地降解’及因此在處理時實質上維持顆粒尺寸。 合適黏結劑之例子包括啤酒濃縮可溶物(brewers c〇ndensed 200906302 solubles )、木質纖維素、碳酸鈉木質素、甘蔗糖蜜、甜菜 糖聚、甜菜糖蜜、去糖甜菜糖蜜、乳聚、澱粉、大豆可溶 物與甘蔗糖蜜或類似物、水解膠原蛋白、胺基酸溶液、纖 維素何生物、或以纖維素為基之聚合物黏結劑。其他與(舉 例而言)啤酒濃縮可溶物具有相同的特性的可溶於水之黏 結劑,亦可以被使用。 另外的輔助劑(如界面活性劑、分散劑、崩解劑、潤 濕劑及類似物)可以被添加至需求處,以改變顆粒的特性。 本發明之顆粒調配物可以包含從大約〇〇1%至大約 99%之殺蟲劑。合適地,顆粒調配物可以包含從大約〇 〇1% 至大約1 0%之殺蟲劑。更合適地,顆粒調配物可以包含從 大、0 _ 0 1 /〇至大約1 %之殺蟲劑。更合適地,顆粒調配物可 以包含從大約0.04°/。至大約0.5%之殺蟲劑。舉例而言,當 顆粒中之殺蟲劑係赛洛寧(lambda cyhal〇thrin ),大約 0.045%之殺蟲劑可以被使用。當顆粒中之殺蟲劑係赛速安 (thiamethoxam) ’大約 0.22%、大約 〇·33% 或大約 0.5% 之殺蟲劑可以被使用。當顆粒中之殺蟲劑係亞托敏 (azoxystrobin) ’大約〇 3 1〇/〇之殺蟲劑可以被使用。 另外的活性成分亦可以存在於調配物中,其包括表面 活性劑,如重芳烴石油腦、煤油及其他石油餾分、或植物 油;及/或黏著劑,如糊精、黏膠或合成樹脂。 任何合適的顆粒技術可以被使用於本發明。舉例而言, 在一段時期中’由生長培養基中的顆粒逐步釋放殺蟲劑可 月b係需要的。或者,在相同情況下,由顆粒快速釋放殺蟲 10 200906302 劑至生長培養基中可能係需要的。 受控制釋放或緩慢藉# η心u Γ 粒’隨著時間逐步地釋放 ”又蟲幻至生長培養基中,因此確保 連續供應之殺蟲劑" 長於此處之植物有 配物重複施用夕" 除對傳統喷灌殺蟲劑調 制。典型上顆粒提供至少 =生物之控 合地至彡3個月,#、南人山 ^地至少1個月,更適 年的m * 6個月,最適合地至少1 3 :=月的=明之一個具體實例中,顆 提供從大約二6J。在本發明之另一個具體實例中,顆粒 捉仏攸大約3到6個月的控制。在 H t » μ μ ^ j- 备月之進一步具體實 進一步且靜眚 月的控制。在本發明之 步/、體貫例中,顆粒提供從大 ^ ^ m # ϋ 2ί ^ 12到u個月的控制。 不士明係特別有用於提供季 本發明# a 拴制在—具體實例中, μ月之方法包括在生長培養基令添 的釋放速率特性f n 4 + # ,其具有不同 疋午将性(砘如受控制釋放、及 但其包含相同殺蟲劑,以確 、、釋放顆粒), 之連續釋放。兴— 早在特別長的時期中,殺蟲劑 連價釋& I例而言,快速釋放顆粒可 1至6他ιβ、ι2ρ: 期釋放(如 至6個月)及長期釋放(就如6至 較佳地,且有不π經 月)顆粒施用。 提供相對-致的殺蟲劑釋放。U施用,隨著時間 顆粒之釋放速率可藉由熟悉 法控制,如經由Λ筏蟄者已知之各種方 戈,、-_k由不同調配物組分之使 應用。考岸刭J:仙或聚合物包覆的 會在何時及多枰孜特性、及該殺蟲劑 夕長時間被釋放’存在於每-種顆粒中之殺蟲 200906302 劑量可以被調整’以確保所需比例的殺蟲劑被遞送。不同 種類顆粒的比例可以被調整,以達到所需的持續時間及殺 蟲劑之釋放特性。顆粒可以係分開販售或於單一包裝中預 一種受控制釋放顆粒技術係稱為熔融擠製。舉例而言, 受控制釋放顆粒可以含有以重量計G.G1_99%2殺蟲㈣混 和殺蟲劑、以重量計0-70%之惰性載劑、以重量計〇_5〇% 之一或多種有機及無機添加物、及以重量計2請%之熱塑 聚合物之組合,到以重量計總共1〇〇%。混和物可以被擠 製形成熔解物,及擠製物被顆粒化。 快速釋放顆粒與水(如灌凝水或降雨)接觸後,快速 崩解。合適地,顆粒載劑本身係水可溶的,以幫助快速瓦 解及殺蟲劑快速釋放。顆粒載劑可以包含交聯聚合物,其 造成水的快速吸收,製造靜水壓力’其物理性破裂顆粒了 顆粒載劑亦可以包含-或多種沸騰劑或分散劑以幫助殺蟲 劑快速釋放。由顆粒釋放後,殺蟲劑可以被生長於生長培 養基之植物所吸收,以提供疾病及/或有害生物保護。 雖然不限定於任何特殊尺寸,本發明之顆粒通常具有 平均顆粒尺寸範圍由大約〇」至大約1〇 mm,較佳地由大 約0.25至大約5 mm,更佳地由大約〇 5至大約3 ,雖 然此範圍以外的尺寸也可以被使用。 顆粒貫際上可以係任何所需形狀,舉例而言,球形、 圓柱狀、橢圓开’、桿狀、圓錐形、針狀、及不規則形。理 想地’顆粒係近乎球形及具有平滑表面,其提供散裝形式 12 200906302 的顆粒所需之流動特徵。 主製備顆粒調配物有三種基本方法:擠製、包覆、及浸 T °顆粒可經由擠製程序製備’舉例而言,藉由在相對高 壓下(通常超過100psi),擠製殺蟲劑及其他成分的預混 和物’及裁剪形成的擠製物至短的長度。形成的顆粒可以 接者被乾燥。包覆性顆粒可藉由使用膠黏劑 末,劑至載劑顆粒之外表而製造。浸潰顆粒可藉= 以wj為基之殺蟲劑溶液至吸收載劑而製備。在每—案例 中,形成的顆粒可以合成樹脂或聚合物喷灌包覆,以控制 殺蟲劑在施用後之釋放速率。 顆粒亦可藉由混和成分(視情況地包括殺蟲劑)以形 /。I·生私末’及磨製其等以提供所需顆粒尺寸,接著产 後使粉末形成顆粒(藉由 思 i猎由夕種技術,包括附聚、喷乾、 /、他方法就如盤式造粒)而製備。 一 顆粒可藉由混和及诰 別組分製備,及混和可以在 相對低的剪應力下姑—士 甘 几成,以避免降解個別組分。 以使用常見的造粒設備來&士 l + τ "成,如造粒盤及轉鼓造粒機。 形成的顆粒,呈顆粒狀, 如认 逋㊉接者破乾燥以移除多於水分。 在缺乏殺蟲劑下,藉由擠製 斤取矛序製備之顆粒,可以接荖w 溶液(其會黏附至顆粒)喷灑。 使用於本發明之f g # + 、A 、亦可以包含一或多種有機或盔機 與Μ %丨貝使用於擠製技術之輔助劑, 舉例來說潤滑劑,通常是 旦彡 今 ,衫響—或多種活性成分之釋 放的添加物’舉例而言,Α 單 水洛性無機鹽’如氣化鈉、硫酸 13 200906302 鈉及硫酸鈣;穩定一或多種活性成份之緩衝液,如擰檬酸 及聚天冬氨酸;溶劑;及通常使用於殺蟲劑調配技術之類 型的表面活性劑及分散劑,其可以係非離子性、陽離子及/ 或陰離子’具有良好乳化、分散或濕潤特性。 任何殺蟲劑皆可以根據本發明使用。合適地,殺蟲劑 係選自由殺昆蟲劑、殺真菌劑、除草劑、防黴劑、殺蟎劑、 殺藻劑、殺軟體動物劑及植物生長調節劑所組成之族群 中。適合活性成分之完整名單可以於殺蟲劑手冊(Pesticide Manual ’ 14th版,英國作物保護諮議會(British Cr〇p/Particle matrix material may be one of the typical carriers mentioned above and / or may be a fertilizer material, such as urea / fertilizer, urea, unloading compounds (such as potassium sulphate, potassium silicate, potassium hydride, oxidation Potassium, metaphosphoric acid unloading), money compounds (such as ammonium sulphate, ammonium sulphate, phosphoric acid syrup, dish compound # (such as Lai), sulfur, similar phytonutrients and micronutrients and their mixtures or compositions. Insecticides can be Uniformly distributed throughout the particles, sprayed or absorbed onto the particulate substrate after particle formation, or coated on the surface of the particles. Adhesives can be used in the components of the agglomerated particles. When present, the binder typically The m-clay may be adhered to the particulate substrate by weight up to about 20 percent by weight of the particulate composition (dry weight), more typically about 2 to 2 percent by weight. It resists abrasion and does not degrade rapidly' and thus maintains particle size substantially during processing. Examples of suitable binders include beer concentrates (brewers c〇ndensed 200906302 solubles), lignocellulose, sodium carbonate Quality, sugar cane molasses, beet sugar poly, beet molasses, sugar beet molasses, milk poly, starch, soy solubles and sugar cane molasses or the like, hydrolyzed collagen, amino acid solution, cellulose, or fiber A base-based polymer binder. Other water-soluble binders having the same characteristics as, for example, beer-concentrated solubles, can also be used. Additional adjuvants (such as surfactants, dispersion) Agents, disintegrants, wetting agents, and the like) may be added to the requirements to modify the characteristics of the particles. The particle formulation of the present invention may comprise from about 1% to about 99% of the pesticide. The particulate formulation may comprise from about 1% to about 10% of the pesticide. More suitably, the particulate formulation may comprise from about 0 _0 1 /〇 to about 1% of the pesticide. More suitably, the granule formulation may comprise from about 0.04 deg. to about 0.5% of the insecticide. For example, when the pesticide in the granule is lambda cyhal〇thrin, about 0.045% Insecticides can be used. The insecticide in the granule is thiamethoxam 'about 0.22%, about 〇33% or about 0.5% of the pesticide can be used. When the pesticide in the granule is azoxystrobin' An insecticide of about 〇3 1〇/〇 may be used. Additional active ingredients may also be present in the formulation, including surfactants such as heavy aromatic petroleum naphtha, kerosene and other petroleum fractions, or vegetable oils; Or an adhesive such as dextrin, viscose or synthetic resin. Any suitable particle technique can be used in the present invention. For example, the gradual release of the pesticide from the particles in the growth medium can be used for a period of time. Alternatively, or in the same case, rapid release of the insecticidal 10 200906302 agent into the growth medium may be required. Controlled release or slow borrowing # 心心u Γ granules 'gradually released over time' and worms into the growth medium, thus ensuring continuous supply of pesticides " plants longer than the plants here have repeated application eve " In addition to the modulation of traditional sprinkler insecticides, the typical granules provide at least = control of the organism to 彡 3 months, #, Nanrenshan ^ at least 1 month, more suitable for m * 6 months, most Suitably at least 1 3 :=month = in a specific example, the particles are provided from about two 6 J. In another embodiment of the invention, the particles are captured for about 3 to 6 months of control. At H t » μ μ ^ j- further details of the preparation of the month and the control of the moon. In the step / body example of the present invention, the particles provide control from a large ^ ^ m # ϋ 2ί ^ 12 to u months. The sylvestre system is particularly useful for providing the present invention. # a 拴 In the specific example, the method of μ month includes the release rate characteristic fn 4 + # in the growth medium, which has different noon properties (such as Controlled release, and it contains the same pesticide to confirm, release particles ), continuous release. Xing - As early as in a particularly long period of time, insecticides release * & I case, rapid release particles can be 1 to 6 he ιβ, ι2ρ: period release (such as to 6 months) And long-term release (as in 6 to preferably, and not π menstrual) granule application. Provides relative release of insecticide. U application, the release rate of particles over time can be controlled by familiar methods, such as Through the various squares known to the latter, -_k is applied by different formulation components. When and how many properties, and the pesticide, will be coated The release of the insecticidal 200906302 dose present in each particle can be adjusted to ensure that the desired proportion of pesticide is delivered. The proportion of different types of particles can be adjusted to achieve the desired duration. And the release characteristics of the insecticide. The particles may be sold separately or in a single package, and a controlled release particle technique is called melt extrusion. For example, the controlled release particles may contain G.G1_99% by weight. 2 insecticide (four) mixed with pesticides, with weight 0-70% by weight of inert carrier, 〇5〇% by weight of one or more organic and inorganic additives, and 2% by weight of thermoplastic polymer combination, to a total of 1〇 by weight 〇%. The mixture can be extruded to form a melt, and the extrudate is granulated. The fast release particles quickly disintegrate after contact with water (such as condensed water or rainfall). Suitably, the granule carrier itself is water. Soluble to help rapid disintegration and rapid release of pesticides. Granular carriers can contain cross-linked polymers that cause rapid absorption of water, making hydrostatic pressure 'the physical rupture of particles. The particulate carrier can also contain - Or a variety of boiling agents or dispersing agents to aid in the rapid release of the pesticide. After release from the granules, the pesticide can be absorbed by the plant grown on the growth medium to provide disease and/or pest protection. While not limited to any particular size, the particles of the present invention typically have an average particle size ranging from about 〇" to about 1 mm, preferably from about 0.25 to about 5 mm, more preferably from about 5 to about 3, Although dimensions outside this range can also be used. The particles may be of any desired shape, for example, spherical, cylindrical, elliptical, rod-shaped, conical, needle-like, and irregular. Ideally, the particle system is nearly spherical and has a smooth surface that provides the desired flow characteristics of the particles in bulk form 12 200906302. There are three basic methods for preparing a master particle formulation: extrusion, coating, and immersion of T ° particles can be prepared via an extrusion procedure' by way of example, by extruding the insecticide at relatively high pressure (typically over 100 psi). Premixes of other ingredients' and tailored extrudates to short lengths. The formed granules can be dried by the receiver. The coated particles can be produced by using an adhesive agent, an agent to the surface of the carrier particles. The impregnated granules can be prepared by using a wj-based insecticide solution to absorb the carrier. In each case, the formed granules can be sprinkled with a synthetic resin or polymer to control the rate of release of the pesticide after application. The granules may also be formed by mixing the ingredients (optionally including insecticides). I. raw end and 'grinding' and so on to provide the required particle size, and then post-production to make the powder into granules (by thinking of i-hunting technology, including agglomeration, spray drying, /, his method is like a plate Prepared by granulation). A granule can be prepared by mixing and discriminating the components, and the mixing can be carried out under relatively low shear stress to avoid degradation of the individual components. Use common granulation equipment to & l + τ " into, such as granulation trays and drum granulators. The granules formed are in the form of granules, such as those that are broken and dried to remove more moisture. In the absence of an insecticide, the granules prepared by the extrusion process can be sprayed with a solution of w (which adheres to the granules). The fg #+, A used in the present invention may also contain one or more organic or helmets and Μ% mussels used in the extrusion technology as an adjuvant, for example, a lubricant, usually a denim, a shirt ringing - Or an additive for the release of a plurality of active ingredients', for example, Α monohydrate inorganic salts such as sodium carbonate, sulfuric acid 13 200906302 sodium and calcium sulfate; buffers for stabilizing one or more active ingredients, such as citric acid and Polyaspartic acid; solvent; and surfactants and dispersing agents of the type commonly used in pesticide formulation techniques, which may be nonionic, cationic and/or anionic' having good emulsifying, dispersing or wetting characteristics. Any pesticide can be used in accordance with the present invention. Suitably, the insecticide is selected from the group consisting of insecticides, fungicides, herbicides, mildewcides, acaricides, algicides, molluscicides, and plant growth regulators. A complete list of suitable active ingredients can be found in the Pesticides Manual (Pesticide Manual ' 14th Edition, UK Crop Protection Advisory Council (British Cr〇p)
Protection Council) ,ed.C.D.S. Tomlin)中找到。 舉例而言本發明包括一或多種下列殺蟲劑或殺線蟲劑 之使用·阿巴 >丁( abamectin )、亞滅培(acetamiprid)、 蘇雲金桿菌(Bacillus thuringiensis )產物、免扶克 (benfuracarb )、免速達(bensultap )、貝他賽扶寧 (cyfluthrin ) 、丁基加保扶(carbosulfan )、 chloranthraniliprole、可尼丁 ( clothianidin )、氰亞氨 (cyanoimine )、赛滅寧(Cypermethrin)、賽諾嗎嗪 (cyromazin )、丁鍵腺(diafenthiuron )、大利松(diazinon )、 呋蟲胺(dinotefuran)、乙拌填(disulphoton)、醚菊酯 (etofenprox )、芬諾克(fenoxycarb )、芬普尼(fipronil )、 fluxofenime、吱線威(furathiocarb )、益達胺(imidacloprid )、 賽洛寧(lambda cyhalothrin )、祿芬隆(lufenuron )、稀 °定蟲胺(nitenpyram )、硝基亞甲基(nitromethylene )、 氯菊醋(permethrin )、丙漠-破(profenofos )、丙蟲磷 14 200906302 (propaphos ) 、α比財顧](pymetrozine )、百利普芬 (pyripfoxyfen )、多殺菌素(spinosad )、氟胺氰菊西旨 (tau-fluvalinate )、七氟菊醋(tefluthrin )、售蟲琳 (thiacloprid)、賽速安及硫敵克(thiodicarb)。尤其較 佳地殺蟲劑或線蟲殺蟲劑之活性成分包.括阿巴汀、亞滅 培、貝他賽扶寧' chloranthraniliprole、可尼丁、氰亞氨、 呋蟲胺、芬普尼、益達胺、賽洛寧、烯啶蟲胺、硝基亞甲 基、七氟菊酯、噻蟲啉、賽速安及硫敵克。尤其合適地係 阿巴汀、芬普尼、賽洛寧、益達胺及賽速安。 舉例而言本發明包括一或多種下列殺真菌劑之使用: 亞托敏、比多農三泰隆(bitertanol )、萎錄靈(carboxin )、 加普胺(carpropamid ) 、Cu20、克絕(cymoxanil )、環 克座(cyproconazole )、赛普洛(Cypr〇dinil )、益發靈 (dichlofluamid )、雙氯氰菌胺(diclocymet )、待克利 (difenoconazole )、達克矛4 ( diniconazole )、依普座 (epoxiconazole )、拌種咯(fenpiclonil )、護汰寧 (fludioxonil )、氟0^ 菌醋(fluoxastrobin )、敗喧 °坐 (fluquiconazole )、護矽得(flusilazole )、護汰芬 (flutriafol )、吱霜靈(furalaxyl )、福拉比(furametpyr )、 克熱淨(guazatin )、菲克利(hexaconazole )、殺紋寧 (hymexazol )、依滅列(imazalil )、易胺座 (imibenconazole )、種菌。坐(ipconazole )、亞賜圃 (isoprothiolone)、克收欣(kresoxim-methyl)、鋅猛乃 浦 (mancozeb )、右滅達樂 (mefenoxam )、滅達樂 15 200906302 (metalaxyl )、滅特座(metconazole )、邁克尼 (myclobutanil )、肟醚菌胺(orysastrobin )、毆殺斯 (oxadixyl)、披扶座(pefurazoate)、平克座(penconazole )、 賓克隆(pencycuron )、撲殺熱(probenazole )、撲克拉 (prochloraz )、普克利(propiconazole )、百快隆 (pyroquilone)、(土)順式-1 - ( 4-氣苯基)-2_ ( 1 Η-1,2,4_ 二0坐-1 -基)環庚醇、Spiroxarnin、得克利(tebuconazole )、 腐絕(thiabendazole )、賽氟滅(thifluzamide ) 、°塞醯菌 月女(tiadinil) 、tolifluamide、〇坐菌唤(triazoxide )、三泰 务(triadimefon )、三泰隆(triadimenol )、三氟敏 (trifloxystrobin )、賽福座(triflumizole )、滅菌喻 (triticonazole)、單克素(uniconazole)、式 I 之化合物Found in the Protection Council), ed.C.D.S. Tomlin). For example, the invention includes the use of one or more of the following insecticides or nematicides: abamectin, acetamiprid, Bacillus thuringiensis product, benfuracarb , benzultap, cyfluthrin, carbosulfan, chloranthraniliprole, clothianidin, cyanoimine, Cypermethrin, Sino Cyromazin, diafenthiuron, diazinon, dinotefuran, disulphoton, etofenprox, fenoxycarb, fentanyl (fipronil), fluxofenime, furathiocarb, imidacloprid, lambda cyhalothrin, lufenuron, nitenpyram, nitromethylene ( Nitromethylene ), permethrin, profenofos, chlorpyrifos 14 200906302 (propaphos ), alpha ratio pymetrozine , pyripfoxyfen , Spinosad, tau-fluvalinate, tefluthrin, thiacloprid, acesulfan and thiodicarb. Particularly preferred active ingredients for insecticides or nematode insecticides include abatatin, arbutin, beta chloramphenicol chloranthraniliprole, cotinine, cyanamide, dinotefuramide, fentanyl, Yidaamine, Xeronine, nitenpyram, nitromethylene, tefluthrin, thiacloprid, acesulfan and sulfur enemy. Particularly suitable are Abatin, Fenopney, Xeronine, Idamine and Sai Su An. For example, the invention includes the use of one or more of the following fungicides: Atmomin, bitertanol, carboxin, carpropamid, Cu20, cymoxanil , cyproconazole, Cypr〇dinil, dichlofluamid, diclocymet, difenoconazole, diniconazole, Epp ( Epoxiconazole ), fenpiclonil, fludioxonil, fluoxastrobin, fluquiconazole, flusilazole, flurifaol, arsenic Furalaxyl, furametpyr, guazatin, hexaconazole, hymexazol, imazalil, imibenconazole, inoculum. Sit (ipconazole), isoprothiolone, kresoxim-methyl, mangzeb, mefenoxam, metander 15 200906302 (metalaxyl ), extant ( Metconazole ), myclobutanil, oressastrobin, oxadixyl, pefurazoate, penconazole, pencycuron, probenazole, Prochloraz, propiconazole, pyroquilone, (soil) cis-1 - (4-phenylene)-2_ (1 Η-1,2,4_2 0 sitting-1 -yl)cycloheptanol, Spiroxarnin, tebuconazole, thiabendazole, thifluzamide, tiadinil, tolifluamide, triazoxide, three Thai Triadimefon, triadimenol, trifloxystrobin, triflumizole, triticonazole, uniconazole, compounds of formula I
16 (II)。 200906302 尤其較佳地殺真菌地活性藥劑包括亞托敏、赛普洛、待克 利、濩汰争、氟嘧菌酯、右滅達樂、滅達樂、邁克尼、得 克利、腐絕、二氟敏、滅菌唑、式〗之化合物及式Η之化 合物。尤其合適的係亞托敏、待克利、護汰寧及右滅達樂。 進一步’本發明包括使用其他活性成分,如植物生長 調節劑及植物活化劑。合適的植物生長調節劑包括多效唑 (paclobutrazol )及抗倒酯(trinexapac_ethyi )。合適的 植物活化劑包括阿拉酸式苯_s_甲基(acibenz〇lar_s_ methyl )。這些活性成分可以改善植物的健康,因此使其 對疾病及/或有害生物較不敏感。因此,在本發明之範圍十了 這些活性成分亦被認為係殺蟲劑。 在一具體實例中,使用於本發明之殺蟲劑係由赛速安、 右滅達樂、濩汰寧、亞托敏、多效唑及阿拉酸式苯甲基 所組成之清單中挑選。合適地,活性成分係、赛速安。活二 成分係右滅達樂。合適地,活性成分係護汰寧。合適地, 活性成分係亞托敏。合適地,活性成分係多效唑。合適地, 活性成分係阿拉酸式苯_ s _甲基。 在本發明之一具體實例中,殺蟲劑係殺真菌劑。合適 地,殺真菌劑係由亞托敏、赛普》、待克利、護汰寧:氟 嘧菌酯、右滅達樂、滅達樂、邁克尼、得克利、腐絕、三 氟敏、滅菌唑、式I之化合物及式π之化合物所組成之清 單中挑選。合適地,殺真菌劑係由亞托敏、待克利、護汰 寧及右滅達樂所組成之清單中挑選。合適地,殺真菌 亞托敏。 17 200906302 在進步,、體實例中,殺蟲劑顆粒可以包含多於一種 之活性成分。布I ^ λ ' 八―,匕έ不同殺蟲劑之顆粒混和物可以被 。口、丨,殺蟲劑顆粒包含殺真菌劑及至少一種進一 步的活性成分。更合適地,殺真菌劑係亞托敏。 在進-步實例中’殺蟲劑係水溶性,或基本上水溶性。 水溶性殺蟲劑在室溫具有超過〇.5g/1之水中溶解度,及在 η-辛醇及水之間之分配係數κ^ρ係、2或更多。適合之 水〉谷性活性成分包括赛速安及右滅達樂。本發明包括系統 性及非糸統性之活性成分。f、統性活性成分可以透過根吸 收及^輪到整個植物中,而非系、統性活性成分係有用於(舉 例而言)控制土壤衍生性有害生物及疾病。較佳而言,殺 蟲劑係系統性。 ,當殺蟲劑係、系統性時’本發明係特別地有用。殺蟲劑 顆粒係散佈人種子或幼小植物所生長之生長培養基中。在 Λ蟲幻已、’·二由顆粒被釋放後,其被植物根部所吸收。植物 可以接著被移植入不含有殺蟲劑顆粒的新鮮生長培養基, 但決定於植物種類及殺蟲劑的選擇’植物將保留殺蟲劑顆 ;:(八存在於原來的生長培養基中)所授與之對疾病及/或 有。生物的保護作用。盆栽及花壇植物之種植者可以利用 本發明’以在殺蟲劑的存在下,種植健康的植物或栽種穴 盤田,及為了後續賣給消費者,移植其等到不含殺蟲劑之 生長培養基。 在本發明之一具體實例中,包括了種植無疾病的植物 方法其包含栽種種子或幼苗於含有一或多種殺嘉劑顆 18 200906302 粒的生長培養基中,及種植該植物。視情況地,方法進一 步包含移植該幼苗或植物至不含有殺蟲劑顆粒生長培養 基,以預防或最小化殺蟲劑暴露至消費者。移植的步驟可 以敖生於任何合適的時間,但將典型上會發生於數天或週 後,以允許種子有足夠的時間發芽,及/或讓幼苗或植物攝 取殺蟲劑。 很像本發明 _〜八I八 徂柳王仅I丞,具包含含 有至少一種殺蟲劑之顆粒。在-具體實例中,顆粒係散佈 於整個培養基。在另-個進—步的具想實例中,顆=: 栽種前加入培養基。 植物生長培養基的組成物可以被調節以增強殺蟲劑的 釋放及/或其對植物的遞送。舉例而言,泥煤結合某些活性 成分,及因此泥煤在組成物中的4可以被增加以增強 劑受控制的釋放。16 (II). 200906302 Particularly preferred fungicidal active agents include Atomin, Saiplow, Klein, 濩 、, fluoxastrobin, dextromethorphan, chlorhexidine, dextran, dexke, rot, two Fluorine, sterilized azole, a compound of the formula and a compound of the formula. Particularly suitable are Atomin, Klee, Ting Ning and Right DeTaol. Further, the invention encompasses the use of other active ingredients such as plant growth regulators and plant activators. Suitable plant growth regulators include paclobutrazol and trinexapac_ethyi. Suitable plant activators include phenyl-s-methyl (acibenz〇lar_s_methyl). These active ingredients can improve the health of the plant and therefore make it less susceptible to diseases and/or pests. Thus, within the scope of the invention, these active ingredients are also considered to be insecticides. In one embodiment, the insecticide used in the present invention is selected from the list consisting of Saskatchewan, dextromethorphan, ruthenium, atoreno, paclobutrazol and benzyl arsenate. Suitably, the active ingredient is Syracuse. The second component is the right halal. Suitably, the active ingredient is a protective base. Suitably, the active ingredient is atramine. Suitably, the active ingredient is paclobutrazol. Suitably, the active ingredient is phenyl s_methyl. In one embodiment of the invention, the insecticide is a fungicide. Suitably, the fungicide is from Atomin, Saip, to Klee, Ting Ning: fluoxastrobin, dextromethorphan, chlordane, dextran, dextran, rot, trifluoro-sensitive, A list consisting of sterilized azole, a compound of formula I, and a compound of formula π is selected. Suitably, the fungicide is selected from the list consisting of Atomin, Pakli, Ting Ning and Kendall. Suitably, the fungicidal atornamine. 17 200906302 In an advanced embodiment, the pesticide granules may comprise more than one active ingredient. Cloth I ^ λ ' 八 --, a mixture of granules of different insecticides can be used. The mouth, cockroach, insecticide granules comprise a fungicide and at least one further active ingredient. More suitably, the fungicide is atomin. In the further examples, the insecticide is water soluble or substantially water soluble. The water-soluble insecticide has a solubility in water of more than 0.5 g/1 at room temperature, and a partition coefficient κ^ρ system, 2 or more between η-octanol and water. Suitable for water > gluten active ingredients including Sai Su An and Zuo Hu Dal. The present invention encompasses both systemic and non-biological active ingredients. f. The active ingredient can be absorbed through the roots and the whole plant, and the non-systemic and active ingredients are used to control, for example, soil-derived pests and diseases. Preferably, the insecticide is systemic. The invention is particularly useful when the insecticide is systemic. Insecticides Granules are dispersed in growth media in which human seeds or young plants are grown. After the mites have been released, the granules are released by the roots of the plants. Plants can then be transplanted into fresh growth medium without pesticide particles, but depending on the choice of plant species and pesticides 'plants will retain pesticides;: (eight present in the original growth medium) With the disease and / or have. Biological protection. Planters of potted plants and flowerbed plants can use the present invention to grow healthy plants or plant potted fields in the presence of insecticides, and to subsequently sell them to consumers, transplant them to growth media without pesticides. . In one embodiment of the invention, a method of planting a disease-free plant comprising planting seeds or seedlings in a growth medium containing one or more killer granules 18 200906302 granules, and planting the plant is included. Optionally, the method further comprises transplanting the seedling or plant to a pest free granule growth medium to prevent or minimize exposure of the pesticide to the consumer. The step of transplantation can occur at any suitable time, but will typically occur several days or weeks to allow the seed to have sufficient time to germinate and/or allow the seedling or plant to take the pesticide. Much like the present invention _~八一八 徂柳王 I丞 only, containing particles containing at least one insecticide. In a specific example, the granules are dispersed throughout the medium. In another example of the further step, the particle =: The medium is added before planting. The composition of the plant growth medium can be adjusted to enhance the release of the pesticide and/or its delivery to the plant. For example, peat combined with certain active ingredients, and thus peat 4 in the composition, can be increased to achieve controlled release of the enhancer.
V 視情況地,殺蟲劑顆粒可以植物生長培養基本身之組 分之形式提供。舉例而言,殺蟲劑可以被喷灑至或浸潰入 玉米芯、珍珠岩、高嶺土、肥料或通常地被包含於植物生 長培養基中的相似載劑物質,如同上述。 合適地’植物生長培養基中的殺蟲劑係挑選自由殺昆 以丨、殺真菌劑、除草劑、防黴劑、殺蟎劑、減藻劑, 軟體動物劑及植物生長調節劑所組成之族群。更又 殺蟲劑係水溶的。更合適地,殺蟲劑係系統性,所以盆可 = 專送貫穿植物’以在所有的植物部分提供良好的疾病 .生物控制。在一具體實例中,殺蟲劑係挑選自由賽 19 200906302 速女、右滅達樂、護汰寧、亞托敏、多效唾及阿拉酸式笨 s-甲基所組成之族群。合適地,殺蟲_亞托敏。 視選擇的殺蟲劑而定,本發明可以被使用於控制大範 圍的植物有害生物及疾疡兴 王物及疾病。舉例而言,其可以被使用於對 付昆蟲有害生物’就如介殼蟲、壁益、莉馬科害蟲(制⑷、 網蝽(lacebug)、水蠟蟲、蚜蟲、粉蝨(whitefiy)、蕈 蚊、水蠅、毛蟲、虫皇蟲、甲蟲、潛葉蟲 '象鼻蟲及虹蟲。 植物(如觀賞植物)之常見昆蟲有害生物之例子包括蚜蟲 屬(薔薇蚜(儿r⑽ae)、棉蚜(Agossypii)、黑豆蚜(Α· fabae) ) ^ ^ ( Bemisia spp.) ( ^ ( B.tabaci)). 蕈蚊屬(5〜办spp.)、蠟蚧屬spp )、 舞蛾屬(C/20spp.)(蘋果舞蛾(c.户謂·細))、 介殼蟲屬(Coccw spp.)(扁堅介殼蟲(C. 心謂))、V Optionally, the pesticide granules may be provided in the form of a component of the plant growth medium itself. For example, the pesticide can be sprayed or impregnated into corn cobs, perlite, kaolin, fertilizer or similar carrier materials typically contained in plant growth medium, as described above. Suitably the insecticides in the plant growth medium are selected from the group consisting of cockroaches, fungicides, herbicides, fungicides, acaricides, algicides, molluscs and plant growth regulators. . More insecticides are water soluble. More suitably, the insecticide is systemic, so the pot can be delivered to the plant to provide good disease in all plant parts. Biological control. In one specific example, the insecticides are selected from the group consisting of speed females, right-handed darlings, defensive linings, atorenos, multi-effect saliva, and arsenic acid stupid s-methyl groups. Suitably, the insecticidal _Atomin. Depending on the insecticide selected, the present invention can be used to control a wide range of plant pests and diseases and diseases. For example, it can be used against insect pests such as scale insects, wall yi, lima pests (4), lacebug, water wax insects, mites, whitefiy, cockroaches , water flies, caterpillars, worms, beetles, leaf miners 'weeks and rainbow worms. Examples of common insect pests of plants (such as ornamental plants) include locusts (Rose 蚜 儿 (儿 r (10) ae), cotton aphid ( Agossypii), black bean Α(Α· fabae) ) ^ ^ ( Bemisia spp.) ( ^ ( B.tabaci)). 蕈 ( (5~办spp.), 蚧 s spp ), genus Moth (C/ 20spp.) (Apple moth (c. household, fine)), Coccw spp. (C. sinensis (C. heart)),
網蝽屬(Coryi/zMc/za spp.)(懸鈴木方翅網蝽(c c出)、 C*. cydonicis ' 斗樂多罔 ( C. ο,νcuatq ) 、 c· pcrgcmdci ' C paliipes、C. pruni、C. celtadis)、M 蚧慝(Diaspis spp.)、 圍盾纷殼蟲屬(spp.)(茶圍盾蛉(F· ))、 花薊馬屬(Fr⑽spp.)(西方花薊馬(F. occ/i/eWa/b) ) 、Gargaphia 屬(G.tiliae)、財屬(Myzws spp )(桃財(M. joerhcae ))、象曱屬(spp.)、 象鼻蟲屬(Otiorhynchus spp.)(葡萄黑象鼻蟲(〇. sulcatus ))、盔输屬(Parthenolecaniurn )、蛾屬 (Phytonemus spp.X P_ paHidus)、粉介殼螽屣(Planococcus spp.)(柑桔粉介殼蟲(八 dW))、細蟎屬 20 200906302 (Polyhagotarsonemus spp.)(茶、名田璃(p. latus ))、金 龜屬(spp.)(日本金龜(八y叩))、粉介 殼蟲屬(尸sewi/ococcws spp.)(擬長尾粉介殼蟲(尸 /o/igkpz’nwi))、蠟介殼蟲屬(尸w/Wwariaspp.) 、Scatella 屬、Sciarra屬、網培屬(Siep/za5 spp.)(杜鸦網堵($ rhododendri )、杜鵑冠網蝽(*S_ ργζ·〇 )、樟冠網培($ takeyai ))、葉蜗屬(spp.)(二點葉螨(7 urticae )、硃砂葉蟎(Γ. ciwwMarbMi ))、白粉兹屬 (Trialeurodes spp.)及矢尖蚧屬(spp.)。較佳 地’本發明係使用於控制蚜蟲、粉蝨、黑蛀象鼻蟲、潛葉 蟲、介殼蟲、及/或蕈蚊。 進一步’本發明可以被使用於對付真菌疾病,例如, 但不限於,植物炭疽病(anthracnose )(辣椒炭疽病黴 (Colletotrichum coccodes))、木栓化或褐腐根腐病(木 栓化根腐病黴(々rwcoc/zaeia /ycopem.cO )、露菌病(downy mildew )及晚疫病(late blight )(馬鈴薯晚疫病黴 i Phytopthora infestans ))、年爽病Q螯茄年疫病氤 (Alternaria solani))、鐮孢菌腐病(fusarium crown rot ) (尖孢鐮刀菌(Fusarium oxysporum))、鐮孢黴枯萎病 (Fusarium wilt)(尖孢鐮刀菌)、灰色葉斑病(茄匍柄 ’飯 i Stemphylium solani))、灰黴病(灰黴菌(Bo/ry沿 c kerfl ))、瓜類蔓枯病(gUmmy stem blight )(甜瓜蔓 括病菌(Didymella bryoniae))、葉黴病(fuhiafilva)、 點腐病(phoma rot )(毀滅莖點徽菌(尸办心以rMCyva ))、 21 200906302 白粉病(powdery mildew )(辣椒白粉病(ZeveH/w/a taurica ))、銹病菌屬(尸wcc/m’a spp.)(葉錢病菌(/> recondita)、小麥條鏽菌(P. wWz/ormb)、大麥葉錢菌 (P. hordei))、稻瘦菌屬(i^rz'cw/ar/a spp·)、瘡癌或 流膠病(黃瓜黑星病菌(C/adovoriwm ))、 菌核莖腐病(sclerotinia stem rot )(油菜菌核病菌 (Mkoiz.owm )) ' 葉斑枯病(septoria leaf sp〇t ) (番茄斑枯菌(《Sepiorz.a /少coperhca ))、紋枯病(sheath blight)(立枯絲核菌(Rhizoct〇nia solani )),煤污病(S00ty blotch )(蘋果煤污病菌(G/oeode·? ))及數種 果貫腐病、及其他真菌疾病。較佳地,本發明係使用於控 制炭疽病黴(Colletotricum )、鐮刀菌屬、疫病菌屬、草 苗立炫菌屬(PW/n.Mm )、絲核菌屬、及/或核病菌屬。最 佳地,本發明係使用於控制疫病菌屬或草苗立炫菌屬。 根據本發明之方法及/或生長培養基可以被使用於與任 何合適的植物連結’舉例而言觀賞植物、育苗植物、花壇 植物、盆栽植物、蔬菜植物、花卉植物、灌木、闊葉樹種、 長青植物及類似物。舉例而言本發明可以被使用於任何下 列觀賞物種:藿香薊屬(spp_ )、假面花屬(4/0如⑽ spp·)、銀蓮花屬(h㈣_spp.)、扶桑屬㈠⑴ SPP.)(儿)、黃爾屬(Spp.)、金房 草屬(Antirrhinum spp.)、秋海棠屬(spp.)(麗 秋海棠〔B· elatior )、四李狄海棠 Q β. sβίηρβΙ^〇Γβηί;)、 B. tubdreux))、雛菊屬(Beilis spp·)、九重葛屬(Bougajnv⑴ea 22 200906302 spp.)、五色菊屬(5rac/2ycome spp.)、荷包花屬(Ca/ceo/ar/a spp_)、蓮焦花屬(Ca關aspp.)、歲檢屬(Capi/cMmspp.) (M ( C. anuum))、長春花屬 Q Catharanthus spp.) i 長春化 Q C _ roseus、)、家射屬 Q Chrysanthemum sw .、、 瓜葉菊凰 i Cineraria spp.) {銀色瓜葉菊 I c. maritime)、、 肉葉草 i Crassula sw.)(滿堂紅{ C. coccinea))、 萼距花魇(Cuphea sw.) {雪茄花Q c. ignea)) '石竹 屬(Dianthus spp.)(康乃馨(carnation))、荷包牡丹 屬(Dicewira spp. )( # 汔农分(D.aeckW山))、d〇r〇theantus .、洋枯梗 Μι l Eustoma spp.乂 洋枯梗Q ε· grandiflorum、')、 連翹亀(Forsythia sw·、、金鐘亀 Q Fuchsia svv·、、天竺 葵屣(Geranium spip. ) i G. gnaphalium )、千日紅屬 l Gomphrena s抑{千曰紅{ g. gl〇b〇sa))、向曰葵琢 (Helianthus sPp·)、天芥菜餍 QHeli〇tr〇pium spv )、木 槿餍{Hibiscus s仲.、、繡球花亀、H〇rtensia svv、、搶 刀藥 M Uiypoestes sVV.)(紅點草phyllostachya))、 鳳仙花亀、Impatiens s仰.、{非洲鳳仙花{1 waUeriana))、 紅木香亀 iIresinessVV、)' 長壽花亀 LKalanchoes仰·、、 馬櫻丹餍{Lantana sVV.) {馬櫻丹camara)、、花 葵戛 Uavatera sVVJ {裂葉花葵 u trimestris)、、獅 子尾嘎{Leonotis sVV.) U師耳花{L, leonurus))、百合 屬(Lilium spp.)日1f7 化屬{ Mesembryanthemum s 抑' 溝酸漿琢 iMimulus sVV.)、龍面花亀{Nemesia 、 煙草亀{Nicotinia sVV,)、%%後蜘BrassUa、酢漿草屬 23 200906302 (Oxalis spp.)、爬山虎屬 Q p aythenocis sus sw{五葉 爬山虎、P. quinquefolia )、藤本植物爬山虎{ P. tricuspidata))、天竺葵屣 Q Pelarg〇nium spp ) {盾葉天 竺葵(P. peitatum)、馬蹄紋天竺葵Q P · zonale ))、接 牽牛亀(Petunias抑·、'香茶菜戛仰.)、 聖誕紅魇 iP〇insettiasVV·、、報春花亀 iPrimulas1?vr)、 毛苠屬(Ranunculus 邛p.)、杜鵑屣(Rh〇d〇(Jendr〇n spv )、 #癡屬(如wspp.)(玫魂)、葳名罩屬Ua/Waspp.)、 草海洞 i Scaevola sVV.) { S. aem〇la、、蝴蝶花爆 iSchizanthus i 蝴蝶花wiset〇nensis)、、茄爆 (心/α«謂 spp.)、如r/z.m.a spp·、毐壽荔屬(rizggie5 spp.)、 萬奇菊餍{ Tagetes sw.、、馬鞭草琢、Verbena 、 直茗屬(Ho/aspp.)(三色蓳)、歹沒荔屬(z/_/flspp_) 及其他花壇植物。在此觀賞植物作物種類中,較佳地係教 弟桌屬、包括來自插條)、趙邊、0#屬(包 括來自種子及插條)、,#壤在屬、屢必在屬、#㈣、堂 契愈屬、mhw (包括盆栽植物及來自插條)、 良尾草屬反菫菜屬。 進一步,本發明可以被使用於下列任何灌木及樹木: 銀樅i Abies alba)、槭軚Aeer 、歐洲七葉m細_似 hipp〇castanum)、赤揚(Alder)' 普通赤揚{Ainus"此⑽以)、 蘋果、椁木、山毛櫸、毛#屬(細_ spp.)、白禅、黑 雲衫、黑刺李、黃楊木、角樹、全念# 刃j鬥树盃‘化、鼠李、辟漁皐屬 (Buddleia啊)、錦熟黃揚{Buxus ㈣、歐 24 200906302 洲鵠耳櫪l Carpinus betulus、、歐洲板栗{Yi genus (Coryi/zMc/za spp.) (P. sylvestris) (C), C*. cydonicis ' C. ο, νcuatq, c· pcrgcmdci ' C paliipes, C. pruni , C. celtadis), M 蚧慝 (Diaspis spp.), Shield genus (spp.) (Tea Shield (F· )), 蓟 蓟 (Fr(10)spp.) (Western 蓟 ( ( F. occ/i/eWa/b)), Gargaphia genus (G.tiliae), genus (Myzws spp) (M. joerhcae), genus genus (spp.), weevil (Otiorhynchus) Spp.) (V. sulcatus), Parthenolecaniurn, Phytonemus spp.X P_ paHidus, Planococcus spp. (Citrus powder scale insect ( Eight dW)), genus 20 200906302 (Polyhagotarsonemus spp.) (tea, famous glass (p. latus)), genus (spp.) (Japanese golden tortoise (eight y叩)), powder scale insect genus (corpse) Sewi/ococcws spp.) (Pseudo-tailed powder scale insect (corpse/o/igkpz'nwi)), wax-scale insect genus (corpse w/Wwariaspp.), Scatella genus, Sciarra genus, net genus (Siep/za5 spp. ) (Rrow net plug ($ rhododendri), cuckoo crown net 蝽 (*S_ ργζ·〇) , take冠网培 ($takeyai), snail (spp.) (2 urticae, cinnabar leaf (ciwwMarbMi)), genus Trialeurodes spp. Genus (spp.). Preferably, the invention is used to control aphids, whiteflies, black weevil, leaf miners, scale insects, and/or aphids. Further, the present invention can be used against fungal diseases such as, but not limited to, anthracnose (Colletotrichum coccodes), cork or brown root rot (wood root rot) Mildew (々rwcoc/zaeia /ycopem.cO), downy mildew and late blight (Potato Phytophthora infestans), Alternaria solani )), Fusarium crown rot (Fusarium oxysporum), Fusarium wilt (Fusarium wilt), Fusarium oxysporum, Gray leaf spot i Stemphylium solani)), gray mold (Bo/ry along c kerfl), gUmmy stem blight (Didymella bryoniae), leaf fly disease (fuhiafilva), Point rot (phoma rot) (destroyed stems of the bacterium (rMCyva)), 21 200906302 powdery mildew (ZewH/w/a taurica), rust genus (corpse wcc) /m'a spp.) (Lepidoptera (/> recondita), wheat stripe rust ( P. wWz/ormb), P. hordei, rice genus (i^rz'cw/ar/a spp.), sore or gum disease (cucumber black spot (C/) Adovoriwm )), sclerotinia stem rot (Mkoiz.owm) 'septoria leaf sp〇t (P. oleracea (Sepiorz.a / less coperhca) )), sheath blight (Rhizoct〇nia solani), coal fouling disease (S00ty blotch) (apple coal germ disease (G/oeode·?)) and several kinds of fruit rot Disease, and other fungal diseases. Preferably, the present invention is used for controlling Colletotricum, Fusarium, Phytophthora, Phytophthora (PW/n.Mm), Rhizoctonia, and/or Nuclear genus . Most preferably, the invention is used to control the genus Bacillus or the genus. The method according to the invention and/or the growth medium can be used in connection with any suitable plant 'for example ornamental plants, nursery plants, flower beds, potted plants, vegetable plants, flower plants, shrubs, broadleaf species, evergreen plants And similar. For example, the present invention can be applied to any of the following ornamental species: genus (spp_), genus (4/0 such as (10) spp.), anemone (h (four) _spp.), genus (1) (1) SPP. (child), genus (Spp.), genus (Antirrhinum spp.), genus Begonia (spp.) (B. elatior), four Lidi 棠 Q β. sβίηρβΙ^〇Γβηί;) , B. tubdreux)), daisy (Beilis spp.), bougainvillea (Bougajnv (1) ea 22 200906302 spp.), genus (5rac/2ycome spp.), genus (Ca/ceo/ar/a spp_) , Lilium genus (Ca off aspp.), genus (Capi/cMmspp.) (M (C. anuum), vinca Q Qharharanthus spp.) i vinca QC _ roseus,), family genus Q Chrysanthemum sw.,, Citrusia spp.) {Silver cucurbit I c. maritime), I Crassula sw.) (C. coccinea), Cuphea sw. ) {cigar flower Q c. ignea)) 'Dianthus spp. (carnation), Dicewira spp. (#汔农分(D.aeckW山)), d〇r〇 Theantus . l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l l Amaranth l Gomphrena s = {千曰红{ g. gl〇b〇sa)), 曰 琢 (Helianthus sPp·), 芥天芥菜餍QHeli〇tr〇pium spv ), 槿餍{Hibiscus szhong. , Hydrangea, H〇rtensia svv, M Uiypoestes sVV.) (Pygmyphylla phyllostachya), Impatiens sinensis, Impatiens s., {1 waUeriana), mahogany iIresinessVV,) 'Longevity flower 亀 LKalanchoes Yang,, 马 餍 餍 {Lantana sVV.) {马樱丹camara), 花花戛 Uavatera sVVJ {裂叶花葵 u trimestris), 狮子尾嘎{Leonotis sVV.) L, leonurus)), Lilium spp., 1f7 genus { Mesembryanthemum s ' 沟 酸 琢 M iMimulus sVV.), Longan flower 亀 {Nemesia, tobacco 亀 {Nicotinia sVV,), %% after the spider BrassUa , sorrel 23 200906302 (Oxalis spp.), Parthenocissus Q p aythenocis sus sw {五叶Parthenocissus, P. quinquefolia, vines {P. tricuspidata), geranium 屣Q Pelarg〇nium spp {P. peitatum, horseshoe geranium QP · zonale), Petunias ·, '香茶菜戛仰.), Christmas red 魇 iP〇insettiasVV·, primrose 亀iPrimulas1?vr), Ranunculus 邛p., Rhododendron (Jendr〇n spv ), #痴属(如wspp.)(玫魂),葳名罩Ua/Waspp.), 草海洞i Scaevola sVV.) { S. aem〇la,, 蝴蝶 burst iSchizanthus i pansy wiset〇 Nensis), eggplant blast (heart/α« spp.), such as r/zma spp·, 毐 荔 ( (rizggie5 spp.), 奇奇菊餍 { Tagetes sw., verbena, Verbena, straight茗 (Ho/aspp.) (three-color 蓳), 歹 荔 (z/_/flspp_) and other flower beds. Among the ornamental plant crop species, it is preferred to teach the genus of the genus, including from the cuttings, Zhaobian, 0# genus (including from seeds and cuttings), #土在属, repeatedly in the genus, # (4), the genus of the church, mhw (including potted plants and from cuttings), and the genus Amaranthus. Further, the present invention can be applied to any of the following shrubs and trees: silver 枞 i Abies alba), maple 軚 Aeer, eucalyptus m fine _ like hipp 〇 castanum), 赤扬 (Alder) '普通赤扬 {Ainus" (10)), apple, eucalyptus, beech, hair# genus (fine _ spp.), white zen, black cloud blouse, black thorn, boxwood, horn tree, full mind #刃j斗树杯', rat Li, Buddleia (Buddleia ah), Jinshu Huangyang {Buxus (four), Europe 24 200906302 鹄 鹄 枥 carpinus betulus, European chestnut {
Castanea sativa) ' 美桃屬(Cherry spp.)、鐵線蓮爆(Clematis spip.、、歐 洲紅 ί而木{ Cornus sanguinea)、榛木{ Corylus、、藥方 莉立、山禮屬(Crafaegus spp.)、金雀兒{ Cytisus scoparius )、桂葉瑞香 q Daphne laureola)、山系 1、接 月木 知[先 '歐洲衛矛、Euonymus europaeus、、歐洲山 毛櫸、Fagus sylvatica)、敬表、歐鼠李 Q Frangula (2111118)、 、\h 痕、% 春藤、中國沙棘夂 Hippophae rhamnoides')、 冬月、忍冬、七葉樹、銳碑冬#( a《wzyb//«m )、杜松、 金鍊化屬{ Laburnum sipp .)、歐洲落葉松 Q Larix decidua、、 月桂樹、#遠女肩、紫丁香、菩提 树、忍冬屬(Lom.ceror spp.)、廣果(Μα/wi )、Castanea sativa) 'Cherry spp., Clematis spip., European red and green { Cornus sanguinea, Elm { Corylus, Pharmacy Lili, Crafaegus spp. ), Jintiser { Cytisus scoparius ), Guiye Ruixiang q Daphne laureola), Mountain System 1, Jiu Muzhi [First 'European Euonymus, Euonymus europaeus, European Beech, Fagus sylvatica), Jing Table, O'Reilly Q Frangula (2111118), , \h mark,% ivy, Chinese sea buckthorn 夂Hippophae rhamnoides'), winter moon, honeysuckle, horse chestnut, ruin winter # ( a "wzyb / / «m ), juniper, golden chain genus {Laburnum sipp.), European larch Q Larix decidua, laurel, #远女肩, lilac, linden, Lom.ceror spp., 广α/wi
楓樹、歐洲雲杉、鐵線蓮、柳樹、洋梨樹、##屬(Pz.cea 各 ' 松 Mi i Pinus sw.)、二球懸鈴木{ Platanus X /njpam’ea)、洋李、揚屬(/>0pW/⑽Spp·)、水堪樹、奏屬 、Prunus s於.、、西洋梨Q Pyrus communis、、標木氣(Q uercus SVV.、、藥鼠李{ Rhamnus cathartica')、在儀、刺槐{Robinia pseudoacacia)、薔薇屬(R0sasvp.)、炎紙、柳餍(Salix SPP·)、西事接爱术(iSawZjwews )、沙棘、雲杉、在 #屬(Sorh·? spp.)、雪漿果、甜栗、美國梧桐、歐砷歹 香(Syringa vulgaris) '曼地亞紅豆杉{ Taxus baccata、、 椴樹Μ C Tilia sipp.)、第議葉鐵象蓮、光输Q ulmus glabra)、 荚 4f 屬(spp.)、胡桃樹、白面子樹(whitebeam )、 wild Ulex、柳木及紫杉。 25 200906302 進一步’本發明可以被使用於下列任何蔬菜:彥屬 (Allium spp.)〔大蒜(A. sativum)、洋惠(A. cepa)、 A. oschcminii)、韭蒽(A. porrum)、小葱(a. ascalon icum )、 大蔥 i A. fistulosumB ' 細菜香芹{ Anthriscus cerefolium、、 塊根芹菜i Apium graveolus)、蘆筍{ Asparagus officinalis)、 、.工葉甜米 Qbetavulgarus、、油采屬 QBrassica wp.Q 彩 葉甘藍、B· Oleracea)、大白菜B· pekinensis、、白菜 型油采、B. rapa))、辣椒、Capsicum (171711111171)、鷹嘴 五 Q Cicer arietinum)、縮采萬苣 C Cichorium endivia~) ' Cichorum sw.(菊苣{ C. intybus) 、C. endivia)、西瓜 〈Citrillus lanatus、、甜瓜屬 Q Cucumis spY(資名(C. sativus、、甜瓜〔C. melo))、南瓜屬 Q Cucurbita sw·、 、義大利南瓜 k C.pepo、、筒瓜 Q C, maxima') ) 、Cyanara SPP· ( C. scolymus ' C. cardunculus )、胡蘿蔔、Daucus carota)、甜茴香{ Foeniculum vulgare)、萵苣{ Lactuca sativa)、番茄慝{ Lycopersicon s仰.X 番茄{ L. esculentum)、 番兹 C L. lycopersicum)) ' 羅勒 Q Ocimum basilicum)、 香芹(Petroselinum crispum)、菜豆屬(Phaseolus spp.) (四季豆(P. vulgaris)、花豆(p. coccineUs))、婉豆 { Pisum sativum)、濱蘿蔔{ Raphanus sativus )、山大黃 (Rheum rhaponticum )、鵪惠(Scorzonera hispanica )、 -ψ- { Solanum melongena )、蔽菜(Spinacea oleracea)、 绳草屬 i Valerianella spp.) {萵苣顧草{ V. locusta) 、V. eriocarpa) 蠶豆(Vicia fab a)。 26 200906302 本發明係特別地有興趣於使用亞托敏的在觀賞植物上 ;::性疾:控制’合適地’本發明係使用於白粉病的控 1牛例而5在冑牛花上。使用亞托敏顆粒於牵牛花植物 生長之生長培養基可以提供長時間保護,對抗真菌性疾 病,如白粉病。 、 據本發明,提供了栽培及種植種子之改善方法其 匕3栽。種子田比鄰至少一種殺蟲劑顆粒,以確保其可以在 無疾病及/或有害生物的環境中發芽。該方法確保由開端保 j種子’及係有用於使由疾病及/或有害生物感染造成之幼 員失降到最低。視情況地,殺蟲劑顆粒亦含有肥料,豆 可以提供營養以改善種子的發芽及形成幼苗之生長。當種 子係以一或多«子被栽培於播種盤之每一小財,一或 多個殺蟲劑顆粒可以被放置於小洞中,靠攏種子。殺蟲劑 顆粒數目由活性成分的所欲速率決定,及會根據殺蟲劑的 4擇而改變。合適地,自!至1〇個殺蟲劑顆粒會被放置 於每一小洞。更合適地’由1至5個殺蟲劑顆粒會被放置 於每一小洞。 【實施方式】 實施例 實施例1 -亞托敏顆粒 亞托敏顆粒(調配物A)係如下製造: 0.3 1%亞托敏Maple, European spruce, clematis, willow, pear tree, ## genus (Pz.cea each 'song Mi i Pinus sw.), two ball sycamore { Platanus X /njpam'ea), plum, genus (/>0pW/(10)Spp·), Shui Keshu, Actinomy, Prunus s.,, Pear Q Pyrus communis, and Quercus SVV., Rhamnus cathartica' Instrument, Robinia {Robinia pseudoacacia), Rose (R0sasvp.), Yan paper, Salix SPP, Western-speaking love (iSawZjwews), Seabuckthorn, Spruce, in the genus (Sorh·? spp.) , snow berry, sweet chestnut, sycamore, arsenic arsenic (Syringa vulgaris) 'Mandia yew { Taxus baccata, eucalyptus Μ C Tilia sipp.), the first leaf iron lotus, light loss Q ulmus glabra ), pod 4f genus (spp.), walnut tree, white-faced tree (whitebeam), wild Ulex, willow and yew. 25 200906302 Further 'the invention can be used for any of the following vegetables: Allium spp. (A. sativum, A. cepa, A. oschcminii), A. porrum, Scallion (a. ascalon icum), Scallion i A. fistulosumB 'Anthriscus cerefolium, jasmine i Apium graveolus, Asparagus officinalis, ., sweet potato Qbetavulgarus, QBrassica wp .Q, Cabbage, B. Oleracea, Chinese cabbage B. pekinensis, Brassica oil, B. rapa), Pepper, Capsicum (171711111171), Cicri arietinum, Cichorium endivia ~) ' Cichorum sw. (C. intybus), C. endivia), watermelon <Citrillus lanatus, Q Cucumis spY (C. sativus, C. melo), Cucurbita Q Cucurbita sw·, , Italian pumpkin k C. pepo, QC, maxima') ), Cyanara SPP· ( C. scolymus ' C. cardunculus ), carrot, Daucus carota, sweet fennel { Foeniculum vulgare ), lettuce { Lactuca sativa), tomato 慝 { Lycopersi Con s Yang.X Tomato { L. esculentum), F. C. lycopersicum)) Basil Q Ocimum basilicum, Petroselinum crispum, Phaseolus spp. (P. vulgaris) Bean (p. coccine Us), Bean { Pisum sativum), Radish Raphanus sativus, Rheum rhaponticum, Scorzonera hispanica, -ψ- { Solanum melongena ), Spincea oleracea ), Valerianella spp.) {V. locusta, V. eriocarpa) Vicia fab a. 26 200906302 The present invention is particularly interested in the use of Atomin on ornamental plants;:: Sexually transmitted diseases: Control 'properly' The present invention is used for control of powdery mildew and 5 on yak flowers. The growth medium using the atomolone granules in the growth of morning glory plants can provide long-term protection against fungal diseases such as powdery mildew. According to the present invention, there is provided an improved method for cultivating and growing seeds. The seed field is adjacent to at least one insecticide granule to ensure that it can germinate in an environment free of disease and/or harmful organisms. This method ensures that the seed is kept from the beginning and is used to minimize the loss of the infant caused by the disease and/or pest infection. Depending on the case, the pesticide granules also contain fertilizer, which can provide nutrients to improve seed germination and seedling growth. When the seed is cultivated in one or more seeds on each seed of the seeding tray, one or more pesticide particles can be placed in the small hole to close the seed. The number of insecticide particles is determined by the desired rate of the active ingredient and will vary depending on the choice of insecticide. Suitably, from! Up to 1 insecticide particle will be placed in each hole. More suitably, from 1 to 5 insecticide particles will be placed in each small hole. EXAMPLES Example 1 - Atoximin Particles Atomin particles (Formulation A) were produced as follows: 0.3 1% Atomin
0.5%具有16莫耳EO之三笨乙烯基苯酚(s〇pr〇ph〇rTM 27 200906302 BSU) 0.5%石粦酸二苯乙稀基苯盼聚乙氧基自旨(Soprophor TM 3D33 ) 3_69%碳酸伸丙酯(&£€3〇1頂八0-15 55 ) 95% DG Lite™ 150 顆粒具有平均直徑1 ·5 mm。顆粒係手工地混合於培養 土(包含6 5 %泥煤、2 〇 %珍珠岩及1 5 %虫至石)中。表1顯 示實施例2、3及5中,使用於評估觀賞植物疾病控制的 處理。 表1 :處理 處理編號 處理描述 比例(g產物/m3 除非說明) 每培養土之亞托 敏量(me ) 1 未經處理對 照組(非經 接種) 0 0 2 未經處理對 照組(經接 種) 0 0 3 調配物A 1108 -----—_ 0.68 4 調配物A 2770 1.69 5 調配物A 5540 ---- 3.39 6 Heritage 50 WG* 0.9 oz 產物/100 gal 0.84 ----- *表面浸液25 mL/植物 實施例2-於金魚草中的絲核菌 28 200906302 〆、重複之/、週大金魚草,cv_ “ Montego Sunset”穴盤 田係轉植至3x3培養土(包含Fafard培養土混和物# 2, 以3種比例之亞托敏顆粒(調配物a)修改)。對於經接 種及非經接種對照組兩者、及標準處理(Heritage⑧WG被 施用作為浸液),穴盤苗係轉植至不含有殺蟲劑顆粒之培 養土混和物。表面浸液係在兩天後被施用至標準處理(處 理6)。植物係在轉植三天後接種絲核菌,及絲核菌之發 生率係於固定時間間隔評估。結果係顯示於表2。 在金魚草的發生率(%感染) 處理編號 9DAT 3 15DAT J卿木 J 22DAT 29DAT 6DAI] 4 12DAI1 19DAI 7DAI2 1 0 b 0 b 0 b 2 100 a 100 a 100 a 67 a 3 0 b 0 b 0 b 0 -—— b 4 0 b 0 b 0 b 0 b 5 0 b 0 b 0 b 0 b 6 0 b 0 b 0 b 0 •—-- b 3轉植後天數 4接種後天數 a、b在所有的數據表格中,具有相同字母之結果係統計上 有意義的。 絲核菌接種一週後,六個經接種金魚草對照組(處理 2 )被感染及枯萎。所有經亞托敏處理的植物(處理3至6 ) 係健康的。移植三週後,植物(4-5”高)被再次接種,使 29 200906302 用先前的非經接種對照作為經接種對照。一週後(轉植至 經修改培養土混和物之—伽n、 犯矛物之個月後),六個經接種對照組中 有四個被感染。所有經處理的植物依然健康。 實施例3 -於天竺赛中的腐霉筠 八重複之二週大天竺葵,cv “Ring〇 2〇〇〇 vi〇let”穴 i田係轉植至3 χ 3培養土(包含Fafard培養土混和物# 2, 乂 3種比例之亞托敏顆粒(調配物a)修改)。對於經接 種及非經接種對照組兩者、及標準處理(Heritage@ WG被 施用作為浸液),穴盤苗係轉植至不含有殺蟲劑顆粒之培 養土混和物。表面浸液係在兩天後被施用至標準處理(處 理6)。植物係在轉植三天後接種經腐霉菌感染之裸麥穀 粒’植物高度及植物葉面寬度係於固定間隔評估,及結果 係顯不於表3。 二.天,葵植物南度及葉面寬度 處理編號 植物高度 (英寸) 最寬葉面寬度 〔英寸) --- 22DA T 29DA1 15DAT3 22DAT 29DAT 1 — 2.63 a 3.38 a 1.88 a 2.17 a 2.42 a 2 --—^ 1.79 b 2.06 c 1.33 cd 1.54 be 1.55 b 3 1.92 b 2.42 be 1.13 d 1.38 c 1.58 b 4 2.46 ab 3 ab 1.58 abc 1.88 ab 2.25 a 5 2.46 ab 3.25 a 1.54 be 1.92 ab 2.29 a 6 ----— 2.83 a 3.33 a 1.79 ab 2.04 a 2.38 a 轉植後天數 30 200906302 轉植-個月後,經腐霉菌感染之植物係發育不良的及 與未經感染植物相較具有較小的葉片。處理4至6 (亞托 敏顆粒(調配物A))於中及高比例,及此一⑽腦 作為浸液),造成植物與非經接種對照有相等高度及葉面 寬度。 ' 結論,亞托敏顆粒可以成功地併入至Fafard培養土混 和物# 2,以控制於金魚草中的絲核菌及於天竺葵中的腐 霉菌。 實施例4 -錄核酋於百日草比例的發現研究 兩週大百日草,cv. “Envy”係轉植至Fafard# 2培養 土混和物(具有及不具有亞托敏顆粒(調配物A))。植 物係在三天後接種。被感染植物係在轉植九及二十天後 (DAT )計算。結果係顯示於表4。 表4:絲核菌於百日草之發生肩 P ( %威染) 處理編號 處理 比例 單位 9DA^ -3 20DA1 1 非經接種對照 n/a n/a 0 b 0 b 2 經接種對照 n/a n/a 83 a 83 a 3 A14912A 277 g prod/m3 67 a 67 a 4 A14912A 554 g prod/m3 67 a 67 a 5 A14912A 1108 g prod/m3 0 b 0 b 6 A14912A 2770 g prod/m3 0 b 0 b 7 Heritage WG 0.9 oz prod/100 gal 0 b 0 b 3轉植後天數 31 200906302 結論’保護兩週大百日草幼苗對抗絲核菌所需要之亞 托敏比例(以顆粒調配物A施用)係介於每一立方公尺554 及1108 g之亞托敏。 實施例5-白粉病於牵牛花 一十六天大之牽牛花’ cv. “Celebrity Blue”係轉植至 培養土培養基(具有或不具有亞托敏顆粒(調配物A))。 使用於此5式驗之亞托敏顆粒比例係每立方公尺培養土混和 物1 108 ’ 2770,及554〇g產物。作為標準,在轉植兩天後, 將Heritage® WG施用作為浸液至處理6。兩週後,試驗被 暴露至白粉病。t其等變成生根滿盆時,植物被轉植入6 圓形的培養土。白粉病感染之發生率及嚴重性係在固定 時間間隔評估。結果係顯示於表5。 重性0.5% tris-vinylphenol with 16 moles of EO (s〇pr〇ph〇rTM 27 200906302 BSU) 0.5% diphenylethylene phenyl phthalate polyethoxylate (Soprophor TM 3D33 ) 3_69% Propyl carbonate (& £3〇1 top eight 0-15 55) 95% DG LiteTM 150 particles have an average diameter of 1 · 5 mm. The granules were manually mixed into the culture soil (containing 65% peat, 2% % perlite and 15% worm to stone). Table 1 shows the treatments used in the evaluation of ornamental plant disease control in Examples 2, 3 and 5. Table 1: Treatment treatment number treatment Description ratio (g product/m3 unless otherwise stated) Sub- sensitization amount per culture soil (me) 1 Untreated control group (non-inoculated) 0 0 2 Untreated control group (inoculated 0 0 3 Formulation A 1108 ------_ 0.68 4 Formulation A 2770 1.69 5 Formulation A 5540 ---- 3.39 6 Heritage 50 WG* 0.9 oz Product / 100 gal 0.84 ----- * Surface infusion 25 mL / Plant Example 2 - Rhizoctonia in Snapdragon 28 200906302 〆, repeated /, gilt carp, cv_ " Montego Sunset" turf field transferred to 3x3 culture soil (including Fafard Culture soil mixture # 2, modified with 3 ratios of azotropine particles (formulation a)). For both the inoculated and non-inoculated control groups, and the standard treatment (Heritage 8WG was applied as the infusion), the plug seedlings were transferred to a culture soil mixture containing no pesticide particles. The surface immersion liquid was applied to standard treatment two days later (Process 6). The plant line was inoculated with Rhizoctonia after three days of planting, and the incidence of Rhizoctonia was assessed at fixed time intervals. The results are shown in Table 2. Incidence in Snapdragon (% infection) Treatment number 9DAT 3 15DAT J Qingmu J 22DAT 29DAT 6DAI] 4 12DAI1 19DAI 7DAI2 1 0 b 0 b 0 b 2 100 a 100 a 100 a 67 a 3 0 b 0 b 0 b 0 -—— b 4 0 b 0 b 0 b 0 b 5 0 b 0 b 0 b 0 b 6 0 b 0 b 0 b 0 •—-- b 3 days after transplanting 4 days after inoculation a, b at all In the data table, the results of the same letter are systematically meaningful. One week after the inoculation of Rhizoctonia, six inoculated Snapdragon control groups (Treatment 2) were infected and withered. All Atomin-treated plants (Treatment 3 to 6) are healthy. Three weeks after transplantation, the plants (4-5" high) were vaccinated again, using 29 200906302 with the previous non-inoculated control as the inoculated control. One week later (transplanted to the modified culture soil mixture - gamma, guilty Four months after the spears, four of the six vaccinated controls were infected. All treated plants remained healthy. Example 3 - Pythium sinensis in the scorpio race, two weeks of geranium, cv The "Ring〇2〇〇〇vi〇let" ai field was transferred to 3 χ 3 culture soil (including Fafard culture soil mixture # 2, 乂 3 ratios of azotropine particles (formulation a) modified). For both inoculated and non-inoculated control groups, and standard treatment (Heritage@ WG was applied as an infusion), the plug seedlings were transferred to a culture soil mixture containing no pesticide particles. The surface infusion was Two days later, it was applied to standard treatment (treatment 6). The plant line was inoculated with Pythium-infected rye grain after planting for three days, and the plant height and plant leaf width were evaluated at regular intervals, and the results were not observed. In Table 3. II. Day, sunflower plant south and leaf width treatment Plant height (inches) Maximum leaf width (inches) --- 22DA T 29DA1 15DAT3 22DAT 29DAT 1 — 2.63 a 3.38 a 1.88 a 2.17 a 2.42 a 2 ---^ 1.79 b 2.06 c 1.33 cd 1.54 be 1.55 b 3 1.92 b 2.42 be 1.13 d 1.38 c 1.58 b 4 2.46 ab 3 ab 1.58 abc 1.88 ab 2.25 a 5 2.46 ab 3.25 a 1.54 be 1.92 ab 2.29 a 6 ----- 2.83 a 3.33 a 1.79 ab 2.04 a 2.38 a turn Days after planting 30 200906302 After planting-months, plants infected with Pythium have dysplasia and have smaller leaves compared to uninfected plants. Treatments 4 to 6 (Atomin particles (Formulation A) ) The medium to high ratio, and the one (10) brain as the infusion), resulted in plants of equal height and leaf width as the non-inoculated control. ' Conclusion, the Atomin particles can be successfully incorporated into the Fafard culture soil mixture. # 2, to control the Rhizoctonia in the Snapdragon and the Pythium in the geranium. Example 4 - Recording the discovery of the ratio of the emirate to the genus Zinnia. Two weeks of the big zinnia, cv. "Envy" Planted to Fafard # 2 culture soil mixture (with and without Atomin particles (mixed (DAT) is calculated after A)). Three days after plant inoculation line. Lines were infected plants transplanted nine and twenty days. The results are shown in Table 4. Table 4: Generation of Rhizoctonia solani in Z. sinensis P (% smear) Treatment number treatment ratio unit 9DA^ -3 20DA1 1 Non-inoculated control n/an/a 0 b 0 b 2 Inoculated control n/an /a 83 a 83 a 3 A14912A 277 g prod/m3 67 a 67 a 4 A14912A 554 g prod/m3 67 a 67 a 5 A14912A 1108 g prod/m3 0 b 0 b 6 A14912A 2770 g prod/m3 0 b 0 b 7 Heritage WG 0.9 oz prod/100 gal 0 b 0 b 3 days after replanting 31 200906302 Conclusion 'Protection of the ratio of azotoxin required to protect two-week-old zinnia seedlings against Rhizoctonia (administered as granule formulation A) Attorney between 554 and 1108 g per cubic meter. Example 5 - Powdery mildew in morning glory 16-day-old morning glory 'cv. 'Celebrity Blue' was transferred to culture medium (with or without atramine particles (formulation A)). The ratio of the azotropine particles used in this type 5 test was 1 108 ' 2770, and 554 〇g of product per cubic meter of soil mixture. As a standard, Heritage® WG was applied as an infusion to Treatment 6 after two days of planting. Two weeks later, the test was exposed to powdery mildew. When the plants become rooted and filled, the plants are transferred into 6 round culture soils. The incidence and severity of powdery mildew infections are assessed at fixed time intervals. The results are shown in Table 5. Severity
0=未被感染,1=被感染 %被涵蓋之葉片面積(5片葉片之平均) 32 200906302 白粉病係在暴露十八天後,於未經處理對照組中首次 被觀察到,但經處理之植物(處理3至6 )未顯示任何感 染的跡象。所有經亞托敏-處理之植物在處理十一週後(6〇 天),依然未患病。 實施例6-赛速安顆粒 二種不同之受控制釋放赛速安顆粒調配物係經由熔融 擠製製備’如同顯示於下列之表6 : 表6 :赛速安顆粒調配物(% w/w ) 調配物B 調配物C 調配物D 赛速安 5% 5% 0.5% 褐煤躐(Montan-wax )甘油 酯(LicolubTM WE4P ) 5% 5% 5% 石夕酸銘(Kaolin ) 3 0% 3 0% 4.5% 聚醋酸乙烯酯(SynthomerTM M50) 60% - 醋酸乙烯酯,與乙烯的聚合物 (Coathylene™ CL 3547-1 ) - 2% 39.7& 聚乙烯吡咯烷酮醋酸乙烯共聚 物(AgrimerTM VA6) - 5 8% 40.3% 擰檬酸 _ - 10% 這些顆粒調配物可以根據本發明被添加至植物生長培 養基中。 【圖式簡單說明】 33 200906302 無 【主要元件符號說明 無0 = not infected, 1 = leaf area covered by infection % (average of 5 leaves) 32 200906302 The powdery mildew system was first observed in the untreated control group after 18 days of exposure, but was treated The plants (treatments 3 to 6) did not show any signs of infection. All of the Atomin-treated plants remained unaffected after 11 weeks of treatment (6 days). Example 6 - Sai'an'an Particles Two different controlled release Sai'an Granule formulations were prepared by melt extrusion as shown in Table 6 below: Table 6: Sai Suan Granule Formulation (% w/w Formulation B Formulation C Formulation D 赛速安5% 5% 0.5% Montan-wax glyceride (LicolubTM WE4P) 5% 5% 5% Oscar Yuen (Kaolin) 3 0% 3 0 % 4.5% Polyvinyl acetate (SynthomerTM M50) 60% - Vinyl Acetate, Polymer with Ethylene (CoathyleneTM CL 3547-1 ) - 2% 39.7& Polyvinylpyrrolidone Vinyl Acetate Copolymer (AgrimerTM VA6) - 5 8% 40.3% citric acid _ - 10% These granule formulations can be added to plant growth media in accordance with the present invention. [Simple description of the diagram] 33 200906302 None [Main component symbol description
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0706665A GB0706665D0 (en) | 2007-04-04 | 2007-04-04 | Method of pest and fungal control |
| US95354907P | 2007-08-02 | 2007-08-02 |
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| TW200906302A true TW200906302A (en) | 2009-02-16 |
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| TW97111955A TW200911114A (en) | 2007-04-04 | 2008-04-02 | Method of pest and fungal control |
| TW97111946A TW200906302A (en) | 2007-04-04 | 2008-04-02 | Method of pest and/or disease control |
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| TW97111955A TW200911114A (en) | 2007-04-04 | 2008-04-02 | Method of pest and fungal control |
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| GB (1) | GB0706665D0 (en) |
| TW (2) | TW200911114A (en) |
| WO (2) | WO2008122763A1 (en) |
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| CN102845419B (en) * | 2012-03-29 | 2013-11-06 | 广东中迅农科股份有限公司 | Cyprodinil water dispersible granule and preparation method thereof |
| KR101409081B1 (en) | 2012-09-12 | 2014-06-17 | 이두천 | Peach chronic treatment solution using natural ingredients and method of manufacturing the same |
| US9351487B2 (en) * | 2012-11-09 | 2016-05-31 | Rachel Dove | Polymeric film for agricultural product storage, containers made therefrom and related methods of agricultural product storage |
| CN113994959A (en) * | 2021-11-23 | 2022-02-01 | 合肥康来生态农业有限公司 | Pomegranate tree pesticide and preparation method thereof |
| CN114668024B (en) * | 2022-05-05 | 2022-09-27 | 山东农业大学 | A kind of bactericidal composition containing boscalid and honeysuckle essential oil |
| TWI871984B (en) * | 2023-08-24 | 2025-02-01 | 皇基股份有限公司 | Insect-resistant cultivation medium and insect-resistant method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1543626A (en) * | 1976-09-21 | 1979-04-04 | Fisons Ltd | Plant growth medium |
| JPS5470931A (en) * | 1977-11-09 | 1979-06-07 | Kureha Chemical Ind Co Ltd | Granular cultivating soil for growing plant |
| US5645843A (en) * | 1986-11-24 | 1997-07-08 | American Cyanamid Company | Safened pesticidal resin compositions for controlling soil borne pests and process for the preparation thereof |
| DE4343176A1 (en) * | 1993-12-17 | 1995-06-22 | Basf Ag | Fungicidal mixture |
| US5882689A (en) * | 1997-12-23 | 1999-03-16 | Church & Dwight Co., Inc. | Control of soilborne fungi in cultivated crops |
| US6541425B1 (en) * | 1998-04-30 | 2003-04-01 | Basf Aktiengesellschaft | Retarding formulations of active substances used for plant protection |
| DK1102533T3 (en) * | 1998-08-05 | 2004-04-05 | Basf Ag | Soil granules with controlled release of active substance (CR soil granules) |
| WO2000028816A1 (en) * | 1998-11-12 | 2000-05-25 | Basf Aktiengesellschaft | Plant protection agents in tablet form |
| US20040259736A1 (en) * | 2001-09-28 | 2004-12-23 | Reinhold Dieing | Biodegradable solid preparation of a phytopathologicalagent with delayed active substance release |
| JP4159789B2 (en) * | 2002-03-01 | 2008-10-01 | 三井化学株式会社 | Improved process for producing pesticide granules |
| KR20060062673A (en) * | 2004-12-06 | 2006-06-12 | 신젠타코리아 주식회사 | New mat composition for water and manufacturing method thereof |
| GB0520654D0 (en) * | 2005-10-11 | 2005-11-16 | Syngenta Participations Ag | Method of pest and fungal control |
-
2007
- 2007-04-04 GB GB0706665A patent/GB0706665D0/en not_active Ceased
-
2008
- 2008-04-01 WO PCT/GB2008/001166 patent/WO2008122763A1/en not_active Ceased
- 2008-04-01 WO PCT/GB2008/001194 patent/WO2008122782A1/en not_active Ceased
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| WO2008122782A8 (en) | 2009-10-15 |
| WO2008122763A1 (en) | 2008-10-16 |
| GB0706665D0 (en) | 2007-05-16 |
| WO2008122782A1 (en) | 2008-10-16 |
| TW200911114A (en) | 2009-03-16 |
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