TW200930564A - Material for kitchen panel, method for production of material for kitchen panel, and kitchen panel - Google Patents
Material for kitchen panel, method for production of material for kitchen panel, and kitchen panel Download PDFInfo
- Publication number
- TW200930564A TW200930564A TW97144493A TW97144493A TW200930564A TW 200930564 A TW200930564 A TW 200930564A TW 97144493 A TW97144493 A TW 97144493A TW 97144493 A TW97144493 A TW 97144493A TW 200930564 A TW200930564 A TW 200930564A
- Authority
- TW
- Taiwan
- Prior art keywords
- metal plate
- organic resin
- kitchen
- panel
- layer
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
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- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B96/00—Details of cabinets, racks or shelf units not covered by a single one of groups A47B43/00 - A47B95/00; General details of furniture
- A47B96/20—Furniture panels or like furniture elements
- A47B96/205—Composite panels, comprising several elements joined together
- A47B96/206—Composite panels, comprising several elements joined together with laminates comprising planar, continuous or separate layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B13/00—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material
- B32B13/04—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B13/06—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/043—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/283—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysiloxanes
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/041—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/4026—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
- E04F2290/045—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against fire
- E04F2290/046—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against fire with a facing or top layer for fire insulation
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Laminated Bodies (AREA)
- Finishing Walls (AREA)
Abstract
Description
200930564 六、發明說明: 【發明所屬之技術領域】 發明領域 本發明係有關於廚房面板用材料、廚房面板用材料之 5 製造方法及廚房面板,詳言之,係有關在廚房使用之廚房 面板用材料、廚房面板用材料之製造方法,及以該廚房面 板用材料所製成之廚房面板。又,廚房面板用材料,除供 用於厨房面板外’例如亦可適用於衛生用的面板。 【先前技術;j !〇 發明背景 傳統以來’廚房面板用材料’由於在使用煙火之廚房 内使用,故必須具有耐火性或耐熱性;又,在面板的面須 能表現令人喜愛的顏色或花紋之新式樣性。 作為该類之廁房面板用材料之一例,已知在由碎酸在弓 15 板等無機材料構成之厚度約數毫米之薄板上,積層有内部 添加有氧化鈦,且已印刷之裝飾板,再以胺酯樹脂浸潰之 構造物(專利文獻1)。 再者,已在專利文獻2中揭示,雖非廚房面板用材料, 已有用於各種家俱類或建築用内裝材料等之裝飾板。該裝 20 飾板,係具有在金屬板、木質板、或石膏板等單獨使用之 基板上,以裝飾板積層用印刷樹脂薄膜所積層之構造。 專利文獻1 :特開平6-143484號公報 專利文獻2:國際公開W001/015901號小冊 【發明内容3 200930564 發明揭示 發明欲解決之問題 即便’廚房面板用材料係搬運至各家庭,配合各家庭 之廚房以載斷使用情形為多,當然要讓内裝專業人員甚至 5 般豕庭的個人亦易於處理,故搬運或截斷加工之容易 性,亦不可或缺。 在專利文獻1揭示之傳統廯房面板用材料,由於基板係 由無機材料構成之薄板,質量雖輕但受到外力則有易於 破裂的問題。因此,廚房面板用材料之搬運或截斷加工時, 馨 10 必須予以相當的注意。 再者,在專利文獻2揭示之裝飾板中,基板為金屬板之 情形時’由於有過重不易搬運,且亦不易截斷加工之問題。 - 金屬板單薄,财與傳統的廚房面板用材料相同的強度& 一 低之問題。X ’基板為木質板的情形時,有防火性劣差的 15問題。再者,基板為石膏板的情形時,則有與傳統的廚房 面板用材料相同的易破裂(成為粉碎狀)之問題。 本發明係鑑於相關的傳統例之問題點所創作者,目的 〇 在於提供強度高且易於搬運或截斷加工,更具有優良耐火 性之厨房面板用材料,其製造方法及廚房面板。 20 用以欲解決問題之手段 根據本發明之一觀點’係提供一種廚房面板用材料, 特徵在於具有由無機物為主成分之不燃性材料構成之基 板,形成於前述基板上之金屬板,以及形成於前述金屬板 上之有機樹脂層。 基板係無機物為主成分之不燃性材料,例如石膏板、 4 25 200930564 矽酸鈣板、水泥浪板氧化鎂板、矽酸鎂板、石棉成型板、 氫氧化鋁板、火山性玻璃質複層板、陶瓷紙、或由使用該 等之至少2種以上所積層者、故耐火性優良。 再者由於金屬板形成於基板上,雖令金屬板的厚度 '二翠4仍可維持高強度之同時’在基板使用石膏板等易 破4材料之情形時,藉金屬板不會引起破裂亦可截斷加 。又,由於可令金屬板之厚度較為單薄,可輕量化 於搬運。 金屬板之厚度宜令成為0.1〜0·5毫米,則可謀求材料之 10 輕量化 ^ ,更令金屬板之厚度成為0.1〜0.3毫米,則材料 於截斷加工。 易 15BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a kitchen panel material, a kitchen panel material manufacturing method, and a kitchen panel, and more particularly to a kitchen panel for use in a kitchen. A material, a method of manufacturing a material for a kitchen panel, and a kitchen panel made of the material for the kitchen panel. Further, the material for the kitchen panel can be applied to a sanitary panel, for example, in addition to being used for a kitchen panel. [Prior Art; j! 〇Invention Background] Since the 'kitchen panel material' has to be fire-resistant or heat-resistant because it is used in a kitchen using fireworks; in addition, the surface of the panel must be able to express a favorite color or The new style of the pattern. As an example of the material for the urinal panel of this type, it is known that a thin plate having a thickness of about several millimeters made of an inorganic material such as a bow 15 plate is used to laminate a decorative plate in which titanium oxide is added and printed. A structure impregnated with an amine ester resin (Patent Document 1). Further, as disclosed in Patent Document 2, a material for a kitchen panel has been used as a decorative sheet for various furniture or architectural interior materials. The 20-piece plaque has a structure in which a decorative resin film is laminated on a substrate which is used alone, such as a metal plate, a wooden board, or a gypsum board. Patent Document 1: Japanese Laid-Open Patent Publication No. Hei 6-143484. Patent Document 2: International Publication No. W001/015901. [Invention Summary 3 200930564 The invention discloses a problem to be solved by the invention. Even if the material for the kitchen panel is transported to each household, the family is coordinated. The kitchen has a lot of load-breaking conditions. Of course, it is easy for the interior professionals to even handle the individual, so the ease of handling or cutting is indispensable. In the material for a conventional mortuary panel disclosed in Patent Document 1, since the substrate is a thin plate made of an inorganic material, the quality is light, but the external force is liable to be broken. Therefore, when handling or cutting off the materials used in kitchen panels, Xin 10 must pay considerable attention. Further, in the decorative panel disclosed in Patent Document 2, when the substrate is a metal plate, the problem is that it is difficult to carry due to excessive weight, and the processing is not easily cut off. - Metal sheets are thin, and the same strength and < a low problem with the traditional kitchen panels. When the X' substrate is a wooden board, there is a problem of poor fire resistance. Further, in the case where the substrate is a gypsum board, there is a problem that it is easily broken (becomes pulverized) as in the case of the conventional kitchen panel material. The present invention has been made in view of the problems of the related conventional examples, and aims to provide a kitchen panel material, a manufacturing method thereof and a kitchen panel which are high in strength, easy to handle or cut off, and have excellent fire resistance. 20 means for solving the problem according to the aspect of the invention' is a material for a kitchen panel characterized by a substrate comprising a non-combustible material mainly composed of an inorganic substance, a metal plate formed on the substrate, and formed An organic resin layer on the aforementioned metal plate. The substrate is an incombustible material mainly composed of inorganic materials, such as gypsum board, 4 25 200930564 calcium silicate board, cement wave board magnesium oxide board, magnesium silicate board, asbestos forming board, aluminum hydroxide board, volcanic glass composite board, Ceramic paper, or a laminate of at least two or more of these, is excellent in fire resistance. In addition, since the metal plate is formed on the substrate, the thickness of the metal plate can be maintained at the same time as the thickness of the metal plate, and the metal plate does not cause cracking when the substrate is made of a material such as gypsum board. Can be truncated plus. Moreover, since the thickness of the metal plate can be made thin, it can be lightened and transported. The thickness of the metal plate should be 0.1 to 0.5 mm, and the weight of the material can be reduced. If the thickness of the metal plate is 0.1 to 0.3 mm, the material can be cut off. Easy 15
20 _再者,以在有機樹脂層上,形成有保制之構成為佳。 =層係堅硬且具有難祕。例如丙騎樹脂、丙稀酸變 :樹脂、氟樹脂、二氧切、或二氧切與選自於該等 用之至少1種以上的樹脂之混合物為佳。因此,廚房面板 用材料,可具備優良之柄染性、耐熱性、耐磨耗性。 再者,無機物為主成分之不燃性材料,係以氫氧化铭 ^或含有丙雜樹脂及紙漿之前述氫氧化缺為佳。由 ,可謀得材料之輕量化易於搬運材料。 再者 ,金屬板係以含有強魏材料為佳,因此,由於 :在廚房面板上固定磁鐵、或附有磁鐵之夾子等,故在廚 房面板上,可易於裝上料理用切或調理用器且。 再者,有機樹脂層係以由有機樹脂之塗料構成之皮 膜,或有機樹脂薄膜為佳。因此,可切房面板用材料具 5 200930564 備優良之耐污染性。 再者,有機樹脂薄膜,係單層時在其下側’或多層時 在其層間,以設有印㈣騎。騎,有麟脂層係以含 有顏料為佳。由此,可令具備優良之新式樣性。 根據本發明之另-觀點而言,提供一鑛房面板用材 '之製造方法,係以無機物為主成分之㈣性材料作為基 Γ用’將有機樹脂積層於金屬板之-面後,在有機樹脂 未積層之金屬板表面,藉黏合_層該不燃性材料。 5 10 15 因此’由於可製成由無機物為主成分之不燃性材料構 成之基板及域於基板上之金屬板,以及形成於金屬板 上的有機樹脂層之廚房面板畴料,可提供-種除具有5 強度外,易於搬運及截斷加工,且耐火性優之蔚房面板。 再者’基板由於使用無機物為主成分之不燃性材料, 例如石膏板、㈣触、水泥浪板、氧化純、㈣錢板、 石棉成1板、氫氧化銘板、火山性破璃質複層板、陶曼紙、 或由該等之至少2種以±積層構成者、故可具備優良之耐火 I·生特别於使用氫氧化銘板之情形時,可謀得材料全體之 輕量化。 金屬板之厚度宜令成為01〜05毫卡則可謀得材料之 &量化又’金屬板之厚度令成為0.1〜〇·3毫米,則可易於 截斷加工。 、 再者以令保護層形成於有機樹脂層上為佳。保護層 係堅硬且具有難燃性,例如丙稀酸樹脂、丙烯酸變性石夕档十 月曰氟樹月曰、二氧化石夕、或二氧化石夕與選自於該等樹脂之 200930564 至少1種以上的樹脂之混合物為佳。由此,厨房面板用材 料’可具備優良的耐污染性、耐熱性、耐磨耗性。 5 ❹ 10 15 20 再者,金屬板係以含有強磁性材料為佳,因此,由於 可在廚房面板上固定磁鐵、或附有磁鐵之夾子等,故在廚 房面板上,可易於裝上料理用食譜或調理用器具。 再者有機樹脂層係以由有機樹脂之塗料構成之皮 膜’或有機樹脂_為佳。由此,可令料面㈣材料具 備優良之财污染性。 再者,有機樹脂薄膜,係在單層時在其下側,或多層 時在其層間’以設有印刷層為佳。又,有機樹脂層係以含 有顏料為佳。因此,可令其具備優良之新式樣性。 根據本發明之另一觀點而言,提供一種廚房面板,係 以月I』述廚房面板用材料,或前述廚房面板用材料之製 法製成。 因此,提供一種除有強度高之外,易於搬運或截斷加 工’且優良耐火性之蔚房面板。 發明效果 根據本發明,由於具有由無機物為主成分之不燃性材 料構成之基板,及形成於基板上之金屬板,以及形成於金 屬板上之有機樹脂層,故可提供強度高,且易於搬運或截 斷加工,更有優良耐火性之廚房面板用材料、廚房面板用 材料之製造方法與廚房面板。又,廚房面板用材料,除用 於厨房面板外,例如亦適用於衛生面板。 圖式簡單說明 7 200930564 第1圖係顯示有關於本發明第丨實施形態的廚房面板用 材料之截面圖。 第2圖係顯示有關於本發明第2實施形態的廚房面板用 材料之截面圖。 第3圖係有關於本發明第i及第2實施形態的廚房面板 用材料之性能比較調查結果的顯示圖。 【實施方式1 用以實施發明之最佳形態 (本發明之概要) ίο 纟中請案之發明人,為要獲得強度高且易於截斷加工 或搬運,更具有優良耐火性之特性,χ,除具該等之特性 之外,增加新式樣性、耐污染性、耐熱性及耐磨耗性之中 之至少任1個之優良特性的厨房面板用材料,經專心檢討。 結果,發現可提供在於單薄的金屬層之片面上形成有 15機樹脂層,或更於有機樹脂層上形成保護層,藉由^金屬 板之另-面,設置由無機物為主成分的不燃性材料構成之 基板以支持金屬板,不僅具備新式樣性或耐污染性 性、财磨耗性,除強度高之外,易於搬運或_加工^ 2。:Γ火一板用材料,該材料製成· 關於截斷加工之容易性, 毫米之情形時效果顯著;關於搬運之容n 2=0.3 厚度為〇.Μ)·3毫米之情形時,或 ^別金屬板 材料為輕量的氫氧化銘之情形時效果顯著。刀之不燃性 200930564 Μ雜,特別於令有機樹 時’或在有機樹腊薄膜之下側,或在由多:::料等情形 樹脂薄膜之層間,設有印刷層之情形時效果數t成之有機 關於耐污_、耐錢及耐聽性, 層、而保護層之材料堅硬、具有難燃性之__设有保護 酸變性_旨、氟樹脂、二氧_或二氧化♦與 樹脂之至少1種以上的樹脂之混合物之情形時 再者,使用含有強磁性材料之金屬 = 有下述樣之便利。即,可在魅· π 帛房面板則 10 15 之类+ I# 射面板固定磁鐵或附有磁鐵 2子’可藉磁鐵在廯房面板,或以夾子㈣料理用食譜, 了邊閱讀食譜邊料理。又,可藉 ° 子固定調則器具。了藉磁鐵在厨房面板,或以央 以下,有關本發明根據實施形態更詳細說明。 (第1實施形態) (Α)廚房面板用材料 第1圖係顯示有關於本發明第#施形態的厨房面板用 材料101之截面圖。 -有關於第1實施形態⑽房面㈣㈣⑼, 不,係由無機物為域分之不難材料構成之基板1 、形成 於基板i上之金屬板2、形成於金屬板2上之有機樹脂層3、 及形成於有機樹脂層3上之保護層4構成。有機樹脂層3可用 有機樹脂塗料或有機樹脂薄媒。保護層係以使用堅硬且具 難燃性為佳。對於硬度及難燃性未要求之情形時,亦可無 保護層。圖上雖未顯示,在金屬板2與有機樹脂層3之界面, 9 200930564 亦可塗布黏合劑。 以下,詳細說明有關廚房面板用材料101之各構成要素。 (基板) 基板1,係用於以金屬板2為主以對抗外力使之不易變 5 形,雖未特別限制,重要的是令基板1本體成為對抗外力不 易變形之厚度。 構成基板1之無機物為主成分之不燃性材料,可使用石 膏板、矽酸鈣板、水泥浪板、氧化鎂板、矽酸鎂板、石棉 成型板、氫氧化鋁板、火山性玻璃質複層板、陶瓷紙、或 10 由該等之至少2種以上所積層者。陶瓷紙係含有陶瓷纖維 (Al2〇3:40〜60%SiO2:60〜40%)95%以上,其他則含有丙烯酸 酯、丙烯酸系樹脂、苯乙烯系樹脂及硫酸鋁者,可適宜使 用。特別於使用氫氧化鋁板之情形時,可謀求材料全體之 輕量化。更由於令氫氧化鋁板中含有丙烯酸樹脂及紙漿, 15 重量更輕,可謀得材料全體更為輕量化。以積層2層以上作 成基板之情形時,在層間藉黏合劑適宜使用。又,以氫氧 化鋁作為主成分,亦可適用於含有石棉、補強劑及黏合劑 之陶瓷系纖維氈毛。例如,期望的成分為含有氫氧化鋁 65〜75%、石棉15〜20%、補強劑及黏合劑5〜10%之陶瓷系纖 20 維氈毛。又,以硫酸鋁為主成分,添加有石臘及丙稀酸系 樹脂之陶瓷纖維板,亦可適宜使用。 (金屬板) ⑴材料 金屬板2可適當地使用公認之不銹鋼板、表面處理鋼 200930564 板、鋁板或鋁合金板等。不銹鋼板以JIS G4305中規定之材 料、SUS304所代表之18-8不銹鋼、或SUS430所代表之鉻18 不錄鋼,由於加工性良好適於使用。銘板或銘合金板,可 使用JISH4000中規定之材料等。 5 表面處理鋼板,包含以鋅、鋅中添加鎳、鐵、銘、錢 等之1種以上之辞合金、錫、鉻、銅、鋁、鋁合金或鎳等所 鍍覆之鋼板。 鍵覆鋼板之鍍覆方法,有電鍍方法、熔融鍍覆法、蒸 〇 鍵方法等可適用。該等之鍍覆進行後,亦可實施公認之化 10 成處理。公認之化成處理,包含有鉻酸鹽處理、磷酸鹽處 理、有機矽烷偶合劑處理、Zr處理等。使用表面處理鋼板 - 之情形時,可藉由磁鐵易將記錄紙或調理用器具固定於廚 - 房面板。 本發明之廚房面板用材料之金屬板2,厚度雖未特予限 15制,從材料輕量化的觀點,期望是0.5毫米以下。 仁疋本發明之庚房面板用材料,以木工用手提式圓 IS施作為截斷加工用途之情形時,以使用厚度q i〜〇 3毫米 且薄金屬板為佳。厚度小於0.1毫米,則必須實施數次之壓 延步驟’又由於成品率不佳,故在製造成本之點會有問題。 20又’金屬板之厚度小於0.1毫米,則在工業上,線圈狀之表 面不易將有機樹脂薄膜連續地積層。相反的,金屬板厚度 大於0.3毫米,則以手提式祕喊斷方法之情形時,截斷 加工困難且對於截斷後之形狀精加工不佳。 ⑼對金屬板的基板之積層方法 11 200930564 5 10 15 如以下方式進彳亍,將在後面詳細說明的有 層之金屬板2,在_则3未積層_板2之表曰面曰,藉 黏者積層基板丨。基板〗之材麵板2之 材料^令該等之積層,受外力仍不易破裂之組合為Γ 首先,預先於基板1或金屬板2之表面塗布黏合劑,將 基板1黏著於金屬板2。基板认金她黏著後,進行加献 等以提高《力。在此種情料,金編係_面已預 先使用有機樹脂層3積層者。 黏合劑之種類,可適當地使用胺醋樹脂系、石夕變性樹 脂、尿素樹脂系、乙酸乙婦乳劑系、環氧樹脂系、三聚氮胺樹脂系、祕樹脂系、烯烴樹脂、丙稀酸乳劑系、氯丁 二稀系、丁腈橡膠系、苯乙稀_丁二稀橡膠系氰基丙稀酸酷 系等之公認黏合劑。 (有機樹脂層) 有機樹脂層3,可藉由有機樹脂塗料塗布於金屬板2上 製作,或可預先製作有機樹脂薄膜而得到。 ⑴材料20 _ Further, it is preferable to form a protective structure on the organic resin layer. = The layer is hard and difficult to secret. For example, it is preferred that the resin is a resin, a fluororesin, a dioxo, or a mixture of at least one selected from the group consisting of a resin. Therefore, the material for the kitchen panel can have excellent handle dyeability, heat resistance and wear resistance. Further, the incombustible material containing the inorganic component as a main component is preferably the above-mentioned hydroxide deficiency of the hydroxide or the acrylic resin and the pulp. By making it possible to reduce the weight of materials, it is easy to carry materials. Furthermore, it is preferable that the metal plate contains a strong Wei material. Therefore, since the magnet or the clip with the magnet is fixed on the kitchen panel, the kitchen cutting panel can be easily mounted with a cutting or conditioning device. And. Further, the organic resin layer is preferably a film composed of a coating material of an organic resin or an organic resin film. Therefore, the material for the panel can be cut to provide excellent stain resistance. Further, the organic resin film is a single layer in which the lower side or the plurality of layers are provided between the layers to provide a printing (four) riding. Riding, there is a layer of linseed with a pigment. Therefore, it is possible to have a good new style. According to another aspect of the present invention, a method for producing a mine panel material is provided by using a (four) material having an inorganic component as a base material, and then laminating the organic resin on the surface of the metal sheet, in organic The surface of the metal plate on which the resin is not laminated is bonded to the non-combustible material. 5 10 15 Therefore, it is possible to provide a kitchen panel material which can be made of a non-combustible material mainly composed of an inorganic substance and a metal plate on the substrate, and an organic resin layer formed on the metal plate. In addition to the 5 strength, it is easy to handle and cut off, and has excellent fire resistance. Furthermore, the substrate is a non-combustible material mainly composed of inorganic materials, such as gypsum board, (4) touch, cement wave board, oxidized pure, (4) money board, asbestos into 1 board, hydroxide nameplate, volcanic glazed laminated board, When the ceramics or the at least two kinds of these are composed of ± layers, it is possible to provide excellent fire resistance, and it is possible to reduce the weight of the entire material. The thickness of the metal plate should be such that it can be made from 01 to 05 mcal, and the thickness of the metal plate can be easily cut off by making the thickness of the metal plate 0.1 to 〇3 mm. Further, it is preferred that the protective layer be formed on the organic resin layer. The protective layer is hard and flame retardant, such as acrylic acid resin, acrylic acid modified Shishi file, October fluorinated tree, sulphur dioxide, or sulphur dioxide, and at least one selected from the resin of 200930564 A mixture of the above resins is preferred. Therefore, the kitchen panel material ' can have excellent stain resistance, heat resistance, and abrasion resistance. 5 ❹ 10 15 20 Furthermore, the metal plate is preferably made of a ferromagnetic material. Therefore, since the magnet can be fixed on the kitchen panel or a clip with a magnet, it can be easily mounted on the kitchen panel. Recipe or conditioning equipment. Further, the organic resin layer is preferably a film formed of a coating material of an organic resin or an organic resin. As a result, the material of the material (4) can be made to have excellent financial pollution. Further, the organic resin film is preferably provided on the lower side thereof in the case of a single layer or in the interlayer layer in the case of a plurality of layers. Further, the organic resin layer is preferably a pigment. Therefore, it can be made to have a good new style. According to another aspect of the present invention, a kitchen panel is provided which is manufactured by using a material for a kitchen panel or a material for the kitchen panel. Therefore, there is provided a ventilated panel which is easy to handle or cut off and has excellent fire resistance in addition to high strength. Advantageous Effects of Invention According to the present invention, since a substrate comprising a non-combustible material containing an inorganic component as a main component, a metal plate formed on the substrate, and an organic resin layer formed on the metal plate can provide high strength and easy handling Or a kitchen panel material that is excellent in fire resistance, a method of manufacturing a kitchen panel, and a kitchen panel. Further, the material for the kitchen panel, in addition to the kitchen panel, is also applicable to a sanitary panel, for example. BRIEF DESCRIPTION OF THE DRAWINGS 7 200930564 Fig. 1 is a cross-sectional view showing a material for a kitchen panel according to a third embodiment of the present invention. Fig. 2 is a cross-sectional view showing a material for a kitchen panel according to a second embodiment of the present invention. Fig. 3 is a view showing the results of a comparison study on the performance of materials for kitchen panels according to the first and second embodiments of the present invention. [Embodiment 1] The best mode for carrying out the invention (summary of the present invention) ίο The inventor of the present invention has the characteristics of high strength, easy cutting and handling, and superior fire resistance. In addition to these characteristics, materials for kitchen panels that add excellent characteristics such as new ones, stain resistance, heat resistance, and abrasion resistance have been carefully reviewed. As a result, it has been found that a 15 resin layer is formed on the sheet surface of the thin metal layer, or a protective layer is formed on the organic resin layer, and the incombustibility of the inorganic component is mainly provided by the other surface of the metal plate. The substrate made of the material supports the metal plate, and has not only new style, pollution resistance, and wear resistance, but also has high strength and is easy to handle or process. : bonfire plate material, made of this material · With regard to the ease of cutting, the effect is significant in the case of millimeters; when the capacity of handling is n 2 = 0.3, the thickness is 〇.Μ)·3 mm, or ^ The effect is remarkable when the metal sheet material is lightly oxidized. Non-combustibility of the knife 200930564 Noisy, especially when the organic tree is used, or on the underside of the organic wax film, or in the case where a printed layer is provided between the layers of the resin film in the case of a multi::: material, etc. It is organically resistant to pollution _, resistant to money and hearing resistance, and the material of the protective layer is hard and flame retardant. __Protected acid denaturation _ purpose, fluororesin, dioxin _ or dioxide ♦ In the case of a mixture of at least one resin of at least one resin, the use of a metal containing a ferromagnetic material = the following convenience. That is, you can use the charm π 帛 room panel 10 15 or the like + I# shot panel fixed magnet or attached magnet 2 sub-can borrow magnets in the boudoir panel, or use clips (four) to cook recipes, while reading recipes Cuisine. In addition, you can use the ° to fix the adjustment device. The present invention will be described in more detail with reference to the embodiments of the present invention. (First Embodiment) (Α) A material for a kitchen panel Fig. 1 is a cross-sectional view showing a material 101 for a kitchen panel according to a first embodiment of the present invention. - In the first embodiment (10), the floor surface (4), (4), (9), the substrate 1 made of an inorganic material, and the metal plate 2 formed on the substrate 2, and the organic resin layer 3 formed on the metal plate 2 And a protective layer 4 formed on the organic resin layer 3. The organic resin layer 3 may be an organic resin coating or an organic resin thinner. The protective layer is preferably hard and inflammable. In the case where hardness and flame retardancy are not required, there is no protective layer. Although not shown in the figure, at the interface between the metal plate 2 and the organic resin layer 3, 9 200930564 may also be coated with a binder. Hereinafter, each component of the kitchen panel material 101 will be described in detail. (Substrate) The substrate 1 is mainly used for the metal plate 2 to resist external force and is not easily deformed into a 5-shape. Although it is not particularly limited, it is important that the substrate 1 has a thickness which is not easily deformed against external force. As the non-combustible material which constitutes the inorganic component of the substrate 1 as a main component, a gypsum board, a calcium silicate board, a cement wave board, a magnesium oxide board, a magnesium niobate board, an asbestos-formed board, an aluminum hydroxide board, a volcanic glass multi-layer board can be used. , ceramic paper, or 10 layers of at least two or more of these. The ceramic paper contains 95% or more of ceramic fibers (Al2〇3: 40 to 60% SiO2: 60 to 40%), and others may contain acrylate, acrylic resin, styrene resin, and aluminum sulfate, and may be suitably used. In particular, in the case of using an aluminum hydroxide plate, it is possible to reduce the weight of the entire material. Further, since the aluminum hydroxide plate contains acrylic resin and pulp, the weight of 15 is lighter, and the entire material can be made lighter. In the case where two or more layers are formed as a substrate, it is preferable to use a binder between the layers. Further, aluminum hydroxide as a main component can also be applied to ceramic fiber felts containing asbestos, a reinforcing agent and a binder. For example, the desired composition is a ceramic-based 20-dimensional felt comprising 65 to 75% of aluminum hydroxide, 15 to 20% of asbestos, and 5 to 10% of a reinforcing agent and a binder. Further, a ceramic fiber board containing a paraffin wax and an acrylic resin as a main component of aluminum sulfate may be suitably used. (Metal plate) (1) Material The metal plate 2 can be suitably used with a recognized stainless steel plate, surface treated steel 200930564 plate, aluminum plate or aluminum alloy plate. The stainless steel plate is made of the material specified in JIS G4305, 18-8 stainless steel represented by SUS304, or chrome 18 represented by SUS430, and is suitable for use because of its good workability. For the nameplate or the alloy plate, the materials specified in JISH4000 can be used. (5) The surface-treated steel sheet contains a steel sheet coated with one or more of nickel, iron, iron, and nickel, zinc, zinc, copper, aluminum, aluminum alloy, or nickel. The plating method of the key-coated steel sheet may be applied by an electroplating method, a hot-dip plating method, or a steaming method. After the plating is carried out, it can also be subjected to a recognized treatment. The recognized chemical conversion treatment includes chromate treatment, phosphate treatment, organic decane coupling agent treatment, Zr treatment and the like. When a surface treated steel sheet is used, the recording paper or the conditioning material can be easily fixed to the kitchen-housing panel by the magnet. The metal plate 2 of the material for a kitchen panel of the present invention is not particularly limited in thickness, and is desirably 0.5 mm or less from the viewpoint of weight reduction of the material. In the case where the material for the gem chamber panel of the present invention is used for the purpose of cutting processing for the hand-held circular IS for woodworking, it is preferable to use a thin metal plate having a thickness q i to 〇 3 mm. If the thickness is less than 0.1 mm, it is necessary to carry out the rolling step several times. In addition, since the yield is not good, there is a problem at the point of manufacturing cost. When the thickness of the metal plate is less than 0.1 mm, it is industrially difficult to continuously laminate the organic resin film on the surface of the coil. On the contrary, when the thickness of the metal plate is more than 0.3 mm, the cutting process is difficult and the shape after the truncation is poorly finished in the case of the portable secret shouting method. (9) Method for laminating a substrate of a metal plate 11 200930564 5 10 15 In the following manner, a layered metal plate 2, which will be described in detail later, is immersed in the surface of the _ 3 unstacked _ plate 2 Adhesive laminate substrate 丨. The material of the panel 2 of the substrate is such that the laminate of these layers is not easily broken by the external force. First, the adhesive is applied to the surface of the substrate 1 or the metal plate 2 in advance, and the substrate 1 is adhered to the metal plate 2. After the substrate is put on the gold, she adds it to enhance the force. In this case, the gold-based system has previously used the organic resin layer 3 to laminate. As the type of the binder, an amine vinegar resin, a stone varnish resin, a urea resin, an acetic acid emulsion, an epoxy resin, a trisamine resin, a secret resin, an olefin resin, or propylene can be suitably used. A well-known adhesive such as an acid emulsion system, a chloroprene system, a nitrile rubber system, or a styrene-butadiene rubber-based cyanoacrylic acid. (Organic Resin Layer) The organic resin layer 3 can be obtained by coating an organic resin coating on the metal plate 2 or by preparing an organic resin film in advance. (1) Materials
20 (a)有機樹脂塗料 有機樹脂塗料,可使用熱硬化性或熱可塑性之樹脂塗 料’例如麟、環氧塗料,尿素、環氧塗料,胺基、環氧 塗料’環氧、醋塗料等之變性環氧塗料,例如使用氣乙烯_ 乙酸乙稀共聚物、氣乙稀_乙酸乙烯共聚物部分驗化物、氣 乙豨-乙酸⑽無水順丁稀二酸共聚物等之乙稀塗料,例如 環氧變性.乙烯_旨塗料、環氧胺魏{烯樹脂塗料、環氧 12 200930564 盼酸變性·乙烯樹脂塗料等變性乙_脂塗料,丙烤酸樹脂 系塗料’油性塗料,醇酸樹脂塗料,聚酯塗料,苯乙烯_丁 二烯共聚物等合成橡膠系塗料等。 從耐姓性及經濟性之觀點而言,塗布量為 1〜200mg/dm2,而以1〇〜1〇〇mg/dm2為佳。 (b)有機樹脂薄膜 ❹ 10 1520 (a) Organic resin coatings Organic resin coatings, which can be used with thermosetting or thermoplastic resin coatings such as Lin, epoxy coatings, urea, epoxy coatings, amine based, epoxy coatings, epoxy, vinegar coatings, etc. a denatured epoxy coating, for example, a vinyl coating such as ethylene ethylene-ethylene acetate copolymer, ethylene ethylene-vinyl acetate copolymer partial acid, gas acetonitrile-acetic acid (10) anhydrous cis-butyl dicarboxylic acid copolymer, such as a ring Oxygen denaturation. Ethylene _ coating, epoxy amine wei ene resin coating, epoxy 12 200930564 tempering denaturation · vinyl resin coating and other denatured B-lip coating, acrylic acid resin coating 'oily coating, alkyd coating, Polyester coatings, synthetic rubber coatings such as styrene-butadiene copolymers. The coating amount is from 1 to 200 mg/dm 2 from the viewpoint of resistance to the surname and economy, and preferably from 1 〇 to 1 〇〇 mg/dm 2 . (b) Organic resin film ❹ 10 15
20 有機樹脂薄膜之材料,可適當地使用聚對苯二甲酸乙 一酯’聚對苯二甲酸丁二酯,聚萘乙二酯,對苯二甲酸乙 二酯、異對苯二甲酸乙二酯聚合物,對苯二甲酸丁二酯、 異對苯一甲酸丁二酯聚合物等之聚酯樹脂,或該等之聚酯 樹脂之2種類以上混合之樹脂,聚乙二醇,聚丙烯,乙稀、 丙稀聚合物,及該等以順丁稀二酸變性者,乙稀、乙酸乙稀 聚合物,乙烯、丙烯酸聚合物等之聚烯烴樹脂,6-尼龍,6, 6尼龍6 1〇_尼龍等聚胺樹脂,聚碳睃酯,聚甲基戊稀, 更有前述之聚S旨樹脂及離子鍵聚合物混合者,皆可適用。 有機樹脂薄膜,係使用前述材料中之任1種類製成之單 層所構成,或使用前述材料之2種類以上製作之複數層所構 成。有機樹脂薄膜之厚度,從有機樹脂薄_層作業之容 易度、有機劃旨薄膜之黏著強度、耐祕及經濟性錢= 而言,以10〜100微米為佳。 ‘ 有機樹脂薄膜,亦可含有公認之顏料。例如可適㈣ 使用氧化鈦、辞白、鉛白、紅色氧化鐵、群青,碳黑: 墨等公認之無機顏料’絲青、n、料系、対咬、 沃丘紅(watchungred)、二噁烷紫等公認之有機顏料。 13 200930564 有機樹脂薄膜,係以前述材料構成之樹脂粒加熱熔 融,將其從擠壓機之T台壓出,而藉由製膜製作所期望的厚 度之薄膜。在此種情形時,將樹脂粒加熱熔融,將其從擠 5 10 15 20 壓機之T台直接對基板卜例如藉由壓出、積層於前述鑛錫 鋼板上製作亦可。 (ii)對有機樹脂薄膜的金屬板之積層方法 第1之方法如前述,將樹脂粒加熱熔融,將其從擠壓機20 organic resin film material, suitable for the use of polyethylene terephthalate 'polybutylene terephthalate, polyethylene naphthalate, ethylene terephthalate, ethylene terephthalate a polymer, a polyester resin such as butylene terephthalate or a butylene terephthalate polymer, or a resin of two or more kinds of the polyester resins, polyethylene glycol, polypropylene, Ethylene, propylene polymer, and those modified with cis-succinic acid, ethylene, ethylene glycol polymer, polyolefin resin such as ethylene, acrylic polymer, 6-nylon, 6, 6 nylon 6 1 〇_Nylon, such as nylon, polycarboester, polymethyl pentene, and the above-mentioned poly-S resin and ionomer mixture can be used. The organic resin film is composed of a single layer made of any one of the above materials, or a plurality of layers made of two or more types of the above materials. The thickness of the organic resin film is preferably from 10 to 100 μm in terms of the ease of operation of the organic resin, the adhesion of the organic film, the adhesion resistance, and the economical cost. ‘ Organic resin film can also contain recognized pigments. For example, it is suitable for (4) use of titanium oxide, white, white, red iron oxide, ultramarine, carbon black: inks and other recognized inorganic pigments 'silk, n, material system, bite, watchungred, dioxins A recognized organic pigment such as alkane violet. 13 200930564 The organic resin film is heated and melted by resin pellets of the above-mentioned materials, and is extruded from the T stage of the extruder to form a film of a desired thickness by film formation. In this case, the resin pellets may be heated and melted, and may be directly formed on the substrate from the T stage of the press 5 10 15 20 press, for example, by extrusion and lamination on the above-mentioned tinplate. (ii) Lamination method of metal plate for organic resin film First method As described above, resin pellet is heated and melted, and it is taken from an extruder
之T台直接對基板卜例如壓出於前述賴鋼板上而積層於 金屬板2上之方法。 第2之方法,使用熱黏著法以形成於金屬板2上之方 法。熱黏著法中,係將有機樹脂薄膜加熱至可黏著的溫度 範圍内之金屬板2,與有機樹脂薄膜對接,以!對之親失住 加壓、壓接。The T-stage directly laminates the substrate onto the metal plate 2, for example, by pressing on the steel sheet. The second method is a method of forming a metal plate 2 by a thermal bonding method. In the thermal bonding method, the organic resin film is heated to a metal plate 2 in a temperature range which can be adhered, and is bonded to the organic resin film to be! For the loss of the pro, the pressure, pressure connection.
再者W熱黏著法將有機樹脂薄膜,熱黏著於鑛錫 板(金屬板)2之情形時,必須注意以下各點。即當孰黏 未以比踢的融點相當低之溫度進行,則無法獲得優良的 機樹脂薄膜與链錫鋼板之黏著強度。另__方面,在有機 脂薄膜之1轴方向,或縱橫2軸方向實_伸加工之情 t加工後之熱固疋’必須在樹脂之融點以上的高 實施。因此’對有機樹脂薄膜實施延伸加工,或不實施 情形下,適當地選擇所使用之樹脂為要。 匕即’有機樹脂薄媒實施延伸加工之情形時,所使用 樹脂之融點必須低於錫之融點。另—方面,延伸加工不 施之情形時,由於延伸加工後之熱固定不用實施, 14 200930564 黏: 予考慮,而可在比錫的融點相當低之溫度進行熱 5 ❹ 10 15 20 第3之方法,係以黏合劑黏著有機樹脂薄膜3及金屬板2 之方法纟此種情形時,在有機樹脂薄膜3與金屬板2之界 面二:在有機樹脂薄膜埃金屬板2的化成處理層之界面, 、 之黏口別塗布、黏著。黏合劑以使用乙酸乙烯樹脂 、烯醋酸乙稀酿樹脂(ethylene vinylacetate resin)系、 尿素樹H㈣旨樹脂系等之乳劑型黏合劑為佳。由於任 何1種皆具有效於防止火災,無臭且價格便宜。 (保護層) ⑴材料 保護層4係期望在廚房面板用材料,可具有耐污染性、 耐熱性、耐磨耗性為佳。_之材料以堅硬且具難燃性之 丙:酸樹脂、丙烯酸變性矽樹脂、氟樹脂或二氧化矽,可 適宜使用。二氧化耗單體謂、或可使用在二氧化石夕中 以丙稀酸㈣、丙騎變性顿脂或氟細旨等之黏合劑凝 固者。厚度射是5〜30微米。小於5微米則過於單薄,在对 污染性、耐熱性或耐祕性之點,未能顯示充分之效果。 另-方面,大於30微米舰厚且效果飽和,*符合經濟性。 (11)對保護層的有機樹脂薄膜之積層方法 保護層4,係在積層有有機樹脂層3的金屬板2之有機樹 脂層3之上塗布。塗布方法使用輥式塗布法、旋轉塗布法、 喷霧塗布法' 或幕式塗布料公認紐進行。然後,在保 護層4未塗布側之金屬板2表面,藉黏合劑積層基板卜 15 200930564 (B)厨房面板 前述厨房面板用材料,係預先藉由配合規格尺寸截斷 加工,或將廚房面板用材料搬運至作業現場,在現場藉由 配合需求進行設置之廚房牆壁、其他需要使用的場所之尺 5 寸截斷加工,可作為廚房面板使用。 諸如前述,根據本發明之第丨實施形態的廚房面板用材 料及廚房面板,由於在基板丨上形成有金屬板2,金屬板2之 厚度,雖單薄仍可保持高強度,同時雖在基板丨使用石膏板 等易破裂材料之情形時,亦可藉由金屬板2不引起破裂而截 1〇 斷加工。又,由於金屬板2之厚度可作成單薄,故可成為輕 量化且易於搬運。 因此,廚房面板用材料易於搬運至作業現場,且可在 現場易於截斷加工。又,一般家庭的個人,可在郊外之專 業商店等購買而易於搬運至自宅,個人配合廚房的情況而 15 加工容易。 再者’基板1係由於使用無機物為主之不燃性材料, 例如石膏板、矽酸鈣板、水泥浪板、氧化鎂板、矽酸鎂板、 石棉成型板、氫氧化鋁板、火山性玻璃質複層板、陶瓷紙、 或由該等之至少2種以上所積層者,故耐火性優良。陶瓷紙 係含有陶究纖維(Al2O3:40〜60%SiO2:60〜40%)95%以上,其 他則含有丙烯酸酯 、丙烯酸系樹脂、苯乙烯系樹脂及硫酸 18者’可適宜使用。特別於使用氫氧化鋁之情形時,由於 可謀求廣房面板用材料全體之輕量化,故材料易於搬運。以 積層2層以上作成基板之情形時,在層間藉黏合劑適宜使用。 16 200930564 再者,有機樹脂層3中令藉由含有顏料 之新式樣性。因此,適用於廣房或可造出在腐房=二 所喜愛的環境。 人貝 再者,在最上層’為令具有丙烯酸樹脂、丙稀 石夕樹脂、氟樹脂、二氧切、或二氧㈣與 樹 種Μ的樹脂之混合物構成之保護層4,因= =提—房面板之狀染性;又,廚房面板亦可具^Further, when the organic resin film is thermally adhered to the tinplate (metal plate) 2 by the W-adhesive method, the following points must be noted. That is, when the crucible is not carried out at a temperature which is considerably lower than the melting point of the kick, the adhesion strength between the excellent resin film and the chain tin steel sheet cannot be obtained. On the other hand, in the case of the organic fat film in the one-axis direction, or in the longitudinal and transverse directions, the heat-solid 疋' after processing is required to be higher than the melting point of the resin. Therefore, when the organic resin film is subjected to elongation processing or not, the resin to be used is appropriately selected. In the case where the organic resin thin film is subjected to the elongation processing, the melting point of the resin used must be lower than the melting point of the tin. On the other hand, when the extension processing is not applied, the heat fixation after the extension processing is not carried out, 14 200930564 Adhesive: Considering the heat at a temperature lower than the melting point of tin 5 ❹ 10 15 20 3 In the case where the organic resin film 3 and the metal plate 2 are adhered by a binder, in the case of the interface between the organic resin film 3 and the metal plate 2: in the chemical conversion treatment layer of the organic resin film The interface, and the adhesive are not coated or adhered. As the binder, an emulsion type binder such as a vinyl acetate resin, an ethylene vinylacetate resin, or a urea tree H (four) resin is preferably used. Since any one of them has the effect of preventing fire, it is odorless and inexpensive. (Protective layer) (1) Material The protective layer 4 is preferably a material for a kitchen panel, and is preferably stain-resistant, heat-resistant, and abrasion-resistant. The material of _ is hard and inflammable. C: acid resin, acrylic styrene resin, fluororesin or cerium oxide, which can be suitably used. The dioxide-consuming monomer is said to be used, or it can be used in the presence of an acrylic acid (tetra), a propylene-denatured or a fluorine-based adhesive. The thickness is 5 to 30 microns. If it is less than 5 μm, it is too thin, and it does not show sufficient effects at the point of contamination, heat resistance or seizure resistance. On the other hand, the ship is thicker than 30 microns and the effect is saturated, * is economical. (11) Method of laminating an organic resin film for a protective layer The protective layer 4 is applied on the organic resin layer 3 of the metal plate 2 on which the organic resin layer 3 is laminated. The coating method is carried out using a roll coating method, a spin coating method, a spray coating method, or a curtain coating material. Then, on the surface of the metal plate 2 on the uncoated side of the protective layer 4, the substrate is laminated by the adhesive. 15 200930564 (B) The kitchen panel material for the kitchen panel is previously cut by the size of the specification, or the material for the kitchen panel is used. It can be transported to the job site and can be used as a kitchen panel on the site by means of a 5 inch cut-off process for the kitchen wall and other places to be used. As described above, according to the kitchen panel material and the kitchen panel according to the third embodiment of the present invention, since the metal plate 2 is formed on the substrate raft, the thickness of the metal plate 2 can be kept high while being thin, and at the same time, the substrate 丨When a rupturable material such as a gypsum board is used, the metal sheet 2 can be cut and cut without causing cracking. Further, since the thickness of the metal plate 2 can be made thin, it can be made lightweight and easy to handle. Therefore, the materials for the kitchen panel are easy to transport to the job site and can be easily cut off at the site. In addition, the average family can purchase it in a professional store in the suburbs, and it is easy to carry it to the house, and the individual can cooperate with the kitchen. Furthermore, 'substrate 1 is a non-combustible material mainly composed of inorganic materials, such as gypsum board, calcium silicate board, cement wave board, magnesium oxide board, magnesium silicate board, asbestos-formed board, aluminum hydroxide board, volcanic glass complex The laminate, ceramic paper, or at least two or more of these layers are laminated, so that the fire resistance is excellent. The ceramic paper contains 95% or more of ceramic fiber (Al2O3: 40 to 60% SiO2: 60 to 40%), and others containing acrylate, acrylic resin, styrene resin, and sulfuric acid can be suitably used. In particular, when aluminum hydroxide is used, since the entire material for a wide-area panel can be made lighter, the material can be easily handled. In the case where two or more layers are formed as a substrate, an adhesive is preferably used between the layers. 16 200930564 Furthermore, the organic resin layer 3 is made to contain a new form of pigment. Therefore, it can be applied to a wide room or can be created in a corrupt room = two favorite environments. In addition, in the uppermost layer, the protective layer 4 is composed of a mixture of resin having acrylic resin, acrylonitrile resin, fluororesin, dioxo, or dioxane (tetra) and tree species, because == The staining of the roof panel; in addition, the kitchen panel can also have ^
15 Ο 20 ,、.、性、耐磨耗性。因此, 耐 房板本體之*命保持長,且 可保持清潔。又,不設置保護層4之情形時, 有機樹脂層3,可具備有優良之耐污染性。 屬板Π,藉由使用含有表面處理鋼板等強磁性材料之金 ίΓ磁ΓΓ細㈣定磁鐵,或附有磁鐵之夹子, 食藉:=房面板,或藉夹子於廚房面板以固定料理用 失二=料理。I藉磁鐵於廚房面板,或藉 处于於廚房面板固定調理用器具。 (第2實施形態) (Α)廚房面板用材料 第2圖係顯示有關於第2實施形態的厨房面板用 之戴面圖。 _有關於第2實施形態的厨房面板用材料1〇2,如第2圖顯 不,在無機物為主之不燃性材料構成之基板丨上,從下依 序,有金屬板2、印刷廣5、有機樹脂層3、保護層4所積層: 與有關於第1實施形態㈣房面板用材料101之相異,在於 金屬板2與有機樹脂層3之間介有印刷層5之點。印刷層% 17 200930564 設在接觸於金屬板2之表面 再者’作為有機樹脂層3, 層5 機樹脂薄膜之情形時,亦可^用2層以上的複數層有 心 脂薄膜3之間形成印刷 5 10 15 印刷層5,例如將表現樹紋、 紋、右妗^ ^ 石紋、天然皮革之表面花 、,文布紋、抽象化紋等圖樣之 具借古+ _茱印刷層,令圖案印刷層 具備有基義色之同時,可由騎鋪料膜推15 Ο 20 , ,., sex, wear resistance. Therefore, the life of the house-resistant body remains long and can be kept clean. Further, when the protective layer 4 is not provided, the organic resin layer 3 can have excellent stain resistance. It is a slab, by using a magnetic material containing a ferromagnetic material such as a surface-treated steel sheet, or a magnet with a magnet attached to it, or by using a clip on the kitchen panel to fix the cooking loss. Two = cuisine. I use a magnet on the kitchen panel or a fixed conditioning device on the kitchen panel. (Second embodiment) (Α) Kitchen panel material Fig. 2 is a perspective view showing a kitchen panel according to a second embodiment. The kitchen panel material 1〇2 according to the second embodiment is shown in Fig. 2, and the substrate is composed of a non-combustible material mainly composed of inorganic materials. The organic resin layer 3 and the protective layer 4 are laminated. The difference between the metal plate 2 and the organic resin layer 3 is that the printed layer 5 is interposed between the metal plate 2 and the organic resin layer 3 in the first embodiment (fourth). Printing layer % 17 200930564 When the surface of the metal plate 2 is contacted with the resin film of the organic resin layer 3 or the layer 5, it is also possible to form a printing between the plurality of layers of the core film 3 with two or more layers. 5 10 15 Printed layer 5, for example, will display the pattern of tree, grain, right 妗^^ stone, surface of natural leather, embossed pattern, abstract pattern, etc. The printed layer has a basic color and can be pushed by the film.
熱黏著之㈣刷層構成。在有機樹脂層薄膜3之表面,從_; 依圖案印刷層及约刷層之順序形成。形成印刷層5之油墨 之展色劑(溶劑、樹脂及石臘等之現合物),例如雖可使用續 化纖維素、乙酸纖維素等纖維素衍生物、聚㈣醋樹脂等 公認者,其中’從密著性及熱黏合性之兩觀點而言,以碎 化纖維素-醇酸樹脂系油墨為佳。 (對有機樹脂薄膜之印刷層的製作方法) 印刷層5,係在有機樹脂薄膜3及金屬板2積層之前,依 以下方式形成。The heat-adhesive (four) brush layer is formed. The surface of the organic resin layer film 3 is formed in the order of the pattern printed layer and the approximate brush layer. For example, a toner exhibiting an ink (a solvent, a resin, or a waxy wax) of the printing layer 5 can be used, for example, a cellulose derivative such as a continuation cellulose or a cellulose acetate, or a poly(tetra) vinegar resin. Among them, from the viewpoint of adhesion and thermal adhesion, it is preferred to use a cellulose-alkyd resin. (Method for Producing Printed Layer of Organic Resin Film) The printed layer 5 is formed as follows before the organic resin film 3 and the metal plate 2 are laminated.
有機樹脂薄膜為單層之情形時,預先設置成有機樹月旨 薄膜3之片面。然後’如同印刷層5接觸於金屬板2樣,而將 有機樹脂薄膜3積層於金屬板2。此種情形時,期望金屬板2 20 與印刷層5之間介有黏合劑。 再者,當有機樹脂薄膜3,由2種類以上的材料製作之 複數層構成之情形時’亦可設置於有機樹脂薄膜3之層間, 或亦可在接觸於金屬板2之有機樹脂薄膜3之表面,設置印 刷層5。 18 200930564 在有機樹脂薄膜3之層間設置印刷層5之情形時,在具有 印刷層5之層,與未設有印刷層之層,期望是藉黏合劑積層。 在有機樹脂薄膜印刷之方法,可使用凸版印刷法、凹 版印刷法、平板印刷法或絹絲印刷法。 5 (B)廚房面板 相同於第1實施形態,前述廚房面板用材料係預先藉 由⑽規格尺寸截斷加工,或將廚房面板用材料搬運到作 O f現場’就在現場藉*配合《置之廚騎壁、其他使用 1〇場所之尺寸截斷加工,故可供用為廚房面板。 ° 諸如前述,根據相關於第2實施形態的厨房面板用材料 ' ⑽及厨房面板,由於除具有相關於第1實施形態的厨房面 , 板用材料韻之構成外,增有印刷層5,故除有第丨實施形態 的特性外,更具備有新式樣性。因此,適用於蔚房,或為 15要營造厨房作業人員嗜好之環境,其選擇幅度可更為寬廣。 (有關本發明實施形態的廚房面板用材料之性能比較) ^ 其次,基於前述之構造,說明如實施例卜5製作之廚房 面板用材料之性能比較調查及其結果。 (實施例1) 2〇 $備作為由無機物為主成分之不燃性材料構成的基板 1之石膏板。作為金屬板2,準備經以下處理的板厚0.2毫米 之鋼板。即,在鋼板的兩面實施鑛鋅l〇g/m2,更於其表面 實施路酸鹽處理,以路作為鉻酸鹽處理皮膜實施被覆 gm。又作為有機樹脂層3,準備由含有氧化欽質 量%、厚度5〇微米之聚對二甲酸丁KPBT)構成之有機樹 19 200930564 脂薄膜。 /其次’在金屬板2之鉻酸鹽處理表面,塗布聚賴系黏合劑 後,加熱金屬板2 ’將有機樹脂薄膜3形成於金屬板2之片面。 其次’在與積層有有機樹脂薄膜3側之反對側的金屬板 2表面’以㈣系黏合劑塗布令乾燥後之厚度成為13〇微 米,再將石膏板(基板U積層於金屬板2表面,令石膏板淡 金屬板2黏著。 、 再者’在有機樹脂薄膜3上,作為保護層4係以丙稀酸 變性矽樹脂塗布令乾燥後之厚度成為2〇微米。 _ 如此-來’在金屬板2之片面,積層有機樹脂薄膜认 保護層4,在另一側之面,獲得由石膏板構成之基板i積層 之廚房面板用材料101。 (實施例2) 準備作為由無機物為主成分的不燃性材料構成的基板 1之石夕酸妈板。又,作為金屬板2,準備經以下之處理的板 厚0.2毫米之鋼板。即,在鋼板的兩面實施鑛鋅1〇咖2,更 、;其表面實施鉻酸鹽處理’以鉻作為鉻酸鹽處理皮膜魏 ⑬ 被覆25g/m2。又’作為有機樹脂層3,準備由含氧化鈦質 量/〇、厚度50微米之聚對二甲酸丁二醋(pBT)構成之有機樹 脂薄祺。 ,其次,在金屬板2之鉻酸鹽處理表面,塗布聚醋系黏合劑 後加熱金屬板2,將有機樹脂薄膜3形成於金屬板2之片面。 其次,在與積層有有機樹脂薄骐3側之反對側的金屬板 2表面’以㈣系黏合劑塗布令乾燥後之厚度成為13〇微 20 200930564 米,再將矽酸鈣板(基板)1積層於金屬板2表面,令矽酸鈣板 1與金屬板2黏著。 再者,在有機樹脂薄膜3上,作為保護層4係以氟樹脂 塗布令乾燥後之厚度成為15微米。 5 ❹ 10 15 ❹ 20 如此一來,在金屬板2之片面,積層有機樹脂薄膜3及 保濩層4,在另一側之面,獲得由矽酸鈣板構成之基板1積 層之廚房面板用材料101。 (實施例3) 準備作為由無機物為主成分的不燃性材料構成的基板 1之石膏板。又,作為金屬板2,準備經以下處理的板厚〇 2 毫米之鋼板。即,在鋼板的兩面實施鑛鋅10g/m2,更於其 表面實施鉻酸鹽處理,以鉻作為鉻酸鹽處理皮膜實施被覆 5g/m。又,作為有機樹脂層3 ’準備由含氧化欽20質量%、 P刷層4形成的厚度5〇微米之聚對二曱酸丁二酯(pBT)構成 之有機樹脂薄膜3。 其次,在金屬板2之鉻酸鹽處理表面,塗布聚酯系黏合 齊J後,加熱金屬板2,將前述有機樹脂薄膜3,如同印刷層4 接觸於金屬板2樣地積層於金屬板2之片面。 其次,在與積層有有機樹脂薄膜3側的反對側之金屬板 表面以胺酯系黏合劑塗布令乾燥後之厚度成為120微 米再將石膏板(基板)1積層於金屬板2表面,將石膏板1與 金屬板2黏著。 再者,在有機樹脂薄膜3上,作為保護層4係以丙烯酸 變性石夕樹脂塗布令錢後之厚度成為職米。 21 200930564 如此一來,在金屬板2之片面,積層有機樹脂薄膜3及 保護層4 ’在另-側之面,獲得由石膏板構成之基板1積層 之廚房面板用材料102。 (實施例4) 5 帛備作為由無機物為主成分的不燃性材料構成的基板 1之陶:是紙。又,作為金屬板2,準備經以下之處理的板厚 〇.2毫米之鋼板。即,在鋼板的兩面實施鐘鋅lOg/m2,更於 其表面實施鉻酸鹽處理,以鉻作為路酸鹽處理皮膜實施被 覆25g/m2。X,作為有機樹脂層3,準備由含有氧化欽加質 1〇量/〇、厚度50微米之聚對二甲酸丁κρΒτ)構成之有麵 脂薄膜。 其次,在金屬板2之鉻酸鹽處理表面,塗布聚醋系黏合劑 後,加熱金屬板2 ’將有機樹脂薄膜3積層於金屬板2之片面。 15 20When the organic resin film is a single layer, it is previously provided as a one-sided film of the organic tree. Then, the organic resin film 3 is laminated on the metal plate 2 as if the printing layer 5 is in contact with the metal plate 2. In this case, it is desirable to have a binder interposed between the metal plate 2 20 and the printed layer 5. Further, when the organic resin film 3 is composed of a plurality of layers made of two or more kinds of materials, it may be disposed between the layers of the organic resin film 3 or may be in contact with the organic resin film 3 of the metal plate 2. The surface is provided with a printed layer 5. 18 200930564 In the case where the printing layer 5 is provided between the layers of the organic resin film 3, it is desirable to laminate the layer having the printing layer 5 and the layer not provided with the printing layer by the adhesive. In the method of printing an organic resin film, a relief printing method, a gravure printing method, a lithography method or a twist printing method can be used. 5 (B) The kitchen panel is the same as the first embodiment, and the material for the kitchen panel is cut off by the size of (10) in advance, or the material for the kitchen panel is transported to the site of Of. The kitchen is used as a kitchen panel because it is cut off by the size of the other one. In the kitchen panel material (10) and the kitchen panel according to the second embodiment, the printing layer 5 is added in addition to the kitchen surface of the first embodiment and the material of the panel. In addition to the characteristics of the third embodiment, it has a new style. Therefore, it can be applied to Weifang, or to create an environment where kitchen workers are hobby, and the choice can be wider. (Comparison of performance of materials for kitchen panels according to the embodiment of the present invention) ^ Next, based on the above-described structure, a comparative performance survey of the materials for kitchen panels produced in Example 5 and the results thereof will be described. (Example 1) A gypsum board of a substrate 1 made of a non-combustible material mainly composed of an inorganic substance. As the metal plate 2, a steel plate having a thickness of 0.2 mm which was subjected to the following treatment was prepared. That is, the mineral zinc l〇g/m2 was applied to both surfaces of the steel sheet, and the surface acid treatment was carried out on the surface thereof, and the coated gm was applied as a chromate-treated film. Further, as the organic resin layer 3, an organic tree 19 200930564 lipid film composed of polybutylene dicarboxylate KPBT containing oxidized % and 5 μm thick was prepared. Next, after the poly-based adhesive is applied to the chromate-treated surface of the metal plate 2, the metal plate 2' is heated to form the organic resin film 3 on the sheet surface of the metal plate 2. Next, 'the surface of the metal plate 2 on the opposite side to the laminated organic resin film 3 side' is coated with a (4) adhesive to make the thickness after drying to 13 μm, and then the gypsum board (the substrate U is laminated on the surface of the metal plate 2, The gypsum board is adhered to the light metal plate 2. Further, on the organic resin film 3, the protective layer 4 is coated with acrylic acid denatured enamel resin to make the thickness after drying to 2 μm. _ So-to' in the metal On the one side of the board 2, the organic resin film is covered with the protective layer 4, and on the other side, the material for the kitchen panel 101 in which the substrate i composed of the gypsum board is laminated is obtained. (Example 2) Prepared as an inorganic component-based material A steel plate having a thickness of 0.2 mm which is processed by the following processing is prepared as the metal plate 2, that is, a mineral zinc is applied to both sides of the steel plate. The surface is chromate-treated with chromium as a chromate-treated film Wei 13 coated with 25 g/m2. Also as an organic resin layer 3, prepared from a polytetramethylene dicarboxylate containing titanium oxide mass/〇, thickness 50 μm Divine vinegar (pBT) Next, the metal plate 2 is coated on the chromate-treated surface of the metal plate 2, and the organic resin film 3 is formed on the sheet surface of the metal plate 2. Next, the organic layer 3 is formed on the surface of the metal plate 2. The surface of the metal plate 2 on the opposite side of the resin thin crucible 3 is coated with (4) adhesive to make the thickness after drying to 13 〇 micro 20 200930564 m, and then the calcium silicate plate (substrate) 1 is laminated on the surface of the metal plate 2, The calcium silicate board 1 is adhered to the metal plate 2. Further, on the organic resin film 3, the protective layer 4 is coated with a fluororesin to have a thickness of 15 μm after drying. 5 ❹ 10 15 ❹ 20 As a result, On the one side of the metal plate 2, the organic resin film 3 and the protective layer 4 are laminated, and on the other side, the kitchen panel material 101 in which the substrate 1 composed of the calcium silicate plate is laminated is obtained. (Example 3) A gypsum board of the substrate 1 made of a non-combustible material containing an inorganic component as a main component. Further, as the metal plate 2, a steel plate having a thickness of 2 mm as follows is prepared. That is, 10 g/m 2 of zinc ore is applied to both surfaces of the steel sheet. More chromate treatment on the surface A coating of 5 g/m was carried out with chromium as a chromate treatment film. Further, as an organic resin layer 3', a polybutylene dimercaptoate having a thickness of 5 μm and a thickness of 20% by mass of the P brush layer 4 was prepared. (pBT) The organic resin film 3 is formed. Next, after the polyester-based bonding is applied to the chromate-treated surface of the metal plate 2, the metal plate 2 is heated, and the organic resin film 3 is brought into contact with the printing layer 4 as The metal plate is laminated on the one side of the metal plate 2. Next, the surface of the metal plate opposite to the side on which the organic resin film 3 is laminated is coated with an amine ester-based adhesive so that the thickness after drying is 120 μm and the gypsum board is (Substrate) 1 is laminated on the surface of the metal plate 2, and the gypsum board 1 and the metal plate 2 are adhered. Further, in the organic resin film 3, the thickness of the protective layer 4 after the coating of the acrylic denatured resin is used. 21 200930564 In this manner, on the one side of the metal plate 2, the organic resin film 3 and the protective layer 4' are laminated on the other side, and the kitchen panel material 102 in which the substrate 1 made of the gypsum board is laminated is obtained. (Example 4) 5 A substrate made of a non-combustible material containing an inorganic substance as a main component 1 is a paper. Further, as the metal plate 2, a steel plate having a thickness of 2. 2 mm which was subjected to the following treatment was prepared. Namely, the bell zinc lOg/m2 was applied to both surfaces of the steel sheet, and the surface was subjected to chromate treatment, and the coating was applied with 25 g/m2 of chromium as the acid salt treatment film. X, as the organic resin layer 3, a dough film comprising a poly(p-dicarboxylic acid butyl κ Β 含有 含有 含有 含有 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Next, after the polyester-based adhesive is applied to the chromate-treated surface of the metal plate 2, the metal plate 2' is heated to laminate the organic resin film 3 on the sheet surface of the metal plate 2. 15 20
其次,在與積層有有機樹脂薄膜3側的反對側之金屬板 2表面,以㈣系黏合劑塗布令乾燥後之厚度成為13〇微 米’再將喊紙(基板)1積層,將^紙1與金屬板2黏著。Next, on the surface of the metal plate 2 on the opposite side to the side on which the organic resin film 3 is laminated, the thickness after drying is (4)-bonded so that the thickness after drying becomes 13 〇 micrometers, and then the paper (substrate) 1 is laminated, and the paper 1 is laminated. Adhered to the metal plate 2.
如此一來,在金屬板2之片面積層有機樹脂薄膜3,在 另一側之面,獲得由喊紙構成之基板1積層之廚房面板用 (實施例5) 作為由無機物為域分的獨性㈣構成的基板i,準 備含有丙稀酸職及㈣之氫氧化叫,。又 板2,準備經以下之處理的板厚〇,毫米之鋼板。即,在鋼 板的兩面實賴辞丨⑽2,更於其表面實施鉻酸鹽處理, 22 200930564In this way, in the sheet metal layer of the metal sheet 2, the organic resin film 3 is obtained on the other side, and the kitchen panel in which the substrate 1 made of shouting paper is laminated (Example 5) is used as the domain of the inorganic material. (4) The substrate i to be formed is prepared to contain the acrylic acid and (4) the hydroxide. In addition, the plate 2 is prepared by the following processing of the plate thickness 〇, the millimeter steel plate. That is, the two sides of the steel plate rely on the word (10) 2, and the chromate treatment is applied to the surface thereof, 22 200930564
10 15 以鉻作為鉻酸鹽處理皮膜實施被覆25g/m2。又,作為有機 樹月曰層3 ’準備由木紋花樣之圖案印刷及yS印刷層之2層構 成之印刷層4所形成的厚度50微米之聚對二甲酸丁二醋 (PBT)所成之有機樹脂薄膜。 其次,在金屬板2之鉻酸鹽處理表面,塗布聚酯系黏合 劑後,加熱金屬板2後,將前述有機樹脂薄膜3,如同印刷層 4中之/5印刷層接觸於金屬板2樣地,積層於金屬板2之片面。 其次,在與積層有有機樹脂薄膜3侧的反對側之金屬板 2表面,以胺醋系黏合劑塗布令乾燥後之厚度成為12〇微 米,再將前述氫氧化鋁板(基板)丨積層。 再者,在有機樹脂薄膜3之上’作為賴層4係以丙稀 酸變性销脂塗布令乾雜之厚度成為職米。 如此-來,在金屬板2之片面,積層有機樹腊薄膜认 保護層4,在另,之面,獲得由含有丙烯酸樹脂及紙漿之 風氧化純構成之基板i積層之蔚房面板用材料繼。 (比較例1)10 15 Coating with 25 g/m2 was carried out using chromium as a chromate treatment film. Further, as the organic tree moon layer 3', a 50-micron thick polybutylene diacetate (PBT) formed by the printing layer 4 composed of two layers of a pattern printing of a wood grain pattern and a yS printing layer is prepared. Organic resin film. Next, after coating the polyester-based adhesive on the chromate-treated surface of the metal plate 2, after heating the metal plate 2, the organic resin film 3 is brought into contact with the metal plate 2 as in the printed layer 4 Ground, laminated on one side of the metal plate 2. Then, the surface of the metal plate 2 on the side opposite to the side on which the organic resin film 3 was laminated was coated with an amine vinegar-based adhesive so that the thickness after drying was 12 μm, and the aluminum hydroxide plate (substrate) was deposited. Further, on the organic resin film 3, the thickness of the dry layer 4 as a layer 4 of the lyophilized resin was used to make the thickness of the dry rice. In this way, on the one side of the metal plate 2, the organic tree wax film is covered with the protective layer 4, and on the other hand, the material for the yufang panel which is composed of the substrate i composed of the oxidized pure resin containing acrylic resin and pulp is obtained. . (Comparative Example 1)
20 準備作為無機物為主成分的不燃性材料構成的基板之 ,板又作為準備金屬板,準備經以下處理的板厚 毫米之鋼板1 ’在鋼板的兩面實施鑛鋅iQg/m2,更於其表面實施鉻酸鹽處理,以鉻作為鉻酸鹽處理皮膜實施被覆 25g/m2 ° 其次,在金屬板2之鉻酸鹽處理表面,以賴系黏合劑 堂布令乾燥後之厚度成為13〇 M U微未,再將石膏板(基板)積 層,將石貧板與金屬板黏著。 23 200930564 如此一來,在金屬板之片面,獲得由石膏板構成之基 板積層之廚房面板用材料。 (比較例2) 準備作為由無機物為主成分的不燃性材料構成的基板 5之石貧板。又,準備由含有氧化鈦20質量%,且由實施例3 同樣的/3印刷層形成之厚度5〇微米之聚對二甲酸丁二酯 (PBT)構成之有機樹脂薄臈。 在石膏板(基板)表面塗布胺酯系黏合劑後,藉胺酯黏合 劑於石膏板上’將前述有機樹赌薄膜,如$印刷層與石t 0 板接觸樣地積層,然後,加熱石膏板,將前述有機樹脂薄 膜積層於石膏板之片面。 其次,在有機樹脂薄膜之上,作為保護層係以丙騎 . 變性销脂㈣令錢後之厚度絲1G财。 · 如此來,在由石膏板構成的基板之片面獲得有機 15樹脂薄膜及保護層積層讀房面板用材料。 (性能評價) 有關於實施例1〜5及比較例i〜2製作之廚房面板用材 ❿ 料’對於耐/可染性、容易截斷性及耐破裂性實施評價。 (耐污染性) 2〇 销房面板用材料的最表層之樹脂薄膜面,以黑色之 託毛_卿)塗緣、放置24小時後,以含浸有乙醇之布片捧 清,以肉眼觀察殘存於樹脂薄膜面上之魅毛程度根射 述之基準評價。 ◎記號:完全無法認定範毛 24 200930564 〇記號:認定為實用性無問題程度之極少氈毛殘存。 △記號:認定為實用性無問題程度之略有氈毛殘存。 X記號:認定有相當程度之熟毛殘存。 (容易截斷性) 5 使用手提式圓鋸之截斷方法實施截斷加工,評價截斷 後之截斷面的形狀。在金屬板之截斷面,顯呈彎曲或顯著 翅曲皆無者作為良好(第3圖之表中,以〇記號表示);在金 屬板之截斷面’顯呈彎曲或顯著翅曲之情形,或完全無法 〇 截斷之情形者作為不良(第3圖之表中,以乂記號表示)。 10 (耐破裂性) • 將廚房面板用材料彎曲加工成90。後,基板破裂令基板 從廚房面板用材料切離之情形作為不良(第3圖之表中,以χ 記號表示);基板未破裂而與廚房面板用材料密切連接狀態 之情形作為良好(第3圖之表中,以〇記號表示)。 15 根據如同以上之性能比較調查,得到顯示於第3圖之表 〇 的結果。根據其結果,實施例1〜5之廚房面板用材料,具優 良之耐污染性’且以手提式圓鋸易於戴斷。金屬板之厚度, 特別了解到當以廚房面板用材料,供用為木工用手提式圓 1 呂戴斷加工時’作為基板而使用厚度0.1〜0_3毫米且單薄金 屬板時,則使用木工用手提式圓鋁易於截斷,且由於截斷 面成為精加工之良好狀態,故尺寸等微調整容易。 再者’表中雖未見表示,從輕量化的觀點而言,了解 到金屬板之厚度期望是〇5毫米以下。因此,視情形亦可擴 大超過0.1〜0.3毫米之範圍,亦可為0.1〜0.5毫米之範圍。板 25 200930564 厚雖超過0.5毫米,雖亦可製造’在輕量化或經濟性之點會 有問題。 再者,實施例1~3之廚房面板用材料’了解到由於表層 具有保護層,故優於耐受傷痕性或耐磨耗性,而在基板上 5 積層有金屬板,故外加壓力之情形下不易破裂(不易成為粉 碎狀)。 相對於此,比較例1由於金屬板之板厚較厚,手提式圓 鋸無法截斷,且未具有有機樹脂層及保護層,故耐污染性 劣差。又,比較例2由於無金屬板之積層,故耐破裂性不佳, 10 基板破裂成粉碎狀。 以上,雖根據實施形態詳細說明本發明,本發明之範圍 不受前述實施形態之顯示具體例限制,在不脫離本發明之要 旨範圍的前述實施形態之變更,均包括於本發明之範圍。 產業之可利用性 15 20 本發明之廚房面板用材料及廚房面板,對於外力不易 破裂,且使用手提式_我斷方法,可易於截斷加工, 截斷後的截斷面之形狀亦良好。由於輕量化而易於搬運。 又,具有優良之新式樣性,可給㈣房美㈣外觀。又, 具有财污·、耐驗、耐磨耗性,_面板的壽命可長 久保持’骗房可經常㈣於清潔。更藉磁鐵或附磁鐵之 夾子,可固定料理用食譜或調則器具。 如此’本發明之廚房面板用材料及廚房面板,可利用 例20 Prepare a substrate made of a non-combustible material containing inorganic substances as the main component. The plate is prepared as a metal plate. The steel plate 1 mm thick is prepared for the following treatment. The mineral zinc iQg/m2 is applied to both surfaces of the steel plate. The chromate treatment was carried out, and the coating of 25 g/m 2 ° was carried out with chromium as a chromate treatment film. Next, on the chromate treated surface of the metal plate 2, the thickness of the coating was dried and the thickness was 13 〇 MU micro. Then, the gypsum board (substrate) is laminated, and the stone lean board is adhered to the metal board. 23 200930564 In this way, a material for a kitchen panel in which a base plate composed of a gypsum board is laminated is obtained on one side of a metal plate. (Comparative Example 2) A stone-lean plate of a substrate 5 composed of a non-combustible material containing an inorganic substance as a main component was prepared. Further, an organic resin thin film composed of polybutylene terephthalate (PBT) having a thickness of 5 μm which is formed of 20% by mass of titanium oxide and having the same /3 printing layer as in Example 3 was prepared. After coating the surface of the gypsum board (substrate) with the amine ester-based adhesive, the melamine adhesive is applied to the gypsum board to deposit the aforementioned organic tree gambling film, such as the printed layer and the stone t 0 plate, and then heat the gypsum. In the plate, the aforementioned organic resin film is laminated on one side of the gypsum board. Secondly, on the organic resin film, as a protective layer, it is a C-ride. The transesterified pin (4) makes the thickness of the wire 1G. In this way, an organic 15 resin film and a protective layer laminated material for a house panel are obtained on a sheet surface of a substrate made of a gypsum board. (Performance evaluation) The materials for kitchen panel materials produced in Examples 1 to 5 and Comparative Examples i to 2 were evaluated for resistance/dyeability, easy cut-off property, and crack resistance. (Stain resistance) 2 The outermost layer of the resin film surface of the floor panel material is coated with black bristles _ qing, placed for 24 hours, then covered with a cloth impregnated with ethanol, and observed by the naked eye. The benchmark evaluation of the degree of glamour on the surface of the resin film. ◎ mark: Fan Mao can not be identified at all 24 200930564 〇 : : : : : : : : : : : 2009 : : : : : : : : : : : : : △ mark: It is considered to be practical and has no problem. X mark: It is determined that there is a considerable degree of maturity remaining. (Easy to be cut off) 5 The cutting process was carried out using the cutting method of the portable circular saw, and the shape of the cut section after the cut was evaluated. In the section of the metal plate, the curved or significant wing is not good as well (in the table of Fig. 3, indicated by the 〇 mark); in the section of the metal plate, the curved section is markedly curved or significantly winged, or Those who are completely unable to cut off are not good (in the table of Figure 3, indicated by 乂 marks). 10 (Fracture resistance) • Bend the kitchen panel material to 90. After that, the substrate was broken, and the substrate was cut off from the kitchen panel material (as indicated by the χ mark in the table of Fig. 3); the substrate was not broken and was closely connected to the kitchen panel material. In the table of the figure, it is indicated by a 〇 mark. 15 Based on the performance comparison survey above, the results shown in Table 3 of Figure 3 are obtained. According to the results, the materials for kitchen panels of Examples 1 to 5 have excellent stain resistance, and the portable circular saw is easy to break. For the thickness of the metal plate, it is especially known that when the material for the kitchen panel is used for the portable circular type 1 for woodworking, when the thickness is 0.1 to 0 mm 3 and the thin metal plate is used as the substrate, the portable type for woodworking is used. The round aluminum is easy to be cut, and since the cross-section is in a good state of finishing, it is easy to finely adjust the size and the like. Further, although not shown in the table, from the viewpoint of weight reduction, it is understood that the thickness of the metal plate is desirably 〇 5 mm or less. Therefore, it may be expanded by more than 0.1 to 0.3 mm as the case may be, or may be in the range of 0.1 to 0.5 mm. Plate 25 200930564 Although the thickness is more than 0.5 mm, it can be manufactured. 'There will be problems in terms of weight reduction or economy. Furthermore, the materials for kitchen panels of Examples 1 to 3 are understood to have better protection against scratches or abrasion resistance due to the protective layer on the surface layer, and there are metal sheets on the substrate, so the pressure is applied. It is not easy to break under (it is not easy to be pulverized). On the other hand, in Comparative Example 1, since the thickness of the metal plate was thick, the portable circular saw could not be cut, and the organic resin layer and the protective layer were not provided, so that the stain resistance was inferior. Further, in Comparative Example 2, since there was no lamination of the metal plate, the crack resistance was poor, and the 10 substrate was broken into a pulverized shape. The present invention is not limited by the specific embodiments of the present invention, and the scope of the present invention is not limited by the above-described embodiments, and modifications of the embodiments described above are intended to be included within the scope of the present invention. Industrial Applicability 15 20 The kitchen panel material and the kitchen panel of the present invention are not easily broken by an external force, and the hand-held method can be easily cut off, and the shape of the cross-section after cutting is also good. Easy to handle due to weight reduction. In addition, it has a good new style and can give (4) the appearance of the room (four). In addition, it has the characteristics of pollution, durability, and wear resistance. The life of the panel can be maintained for a long time. The recipe for cooking or the adjustment device can be fixed by a magnet or a clip attached to the magnet. Thus, the kitchen panel material and the kitchen panel of the present invention can be utilized.
〇 於廚房:途上。又’廚房面板用材料,除廚房面板外, 如亦可適用於衛生用面板。 26 200930564 【圖式簡單說明3 第1圖係顯示有關於本發明第1實施形態的廚房面板用 材料之截面圖。 第2圖係顯示有關於本發明第2實施形態的廚房面板用 5 材料之截面圖。 第3圖係有關於本發明第1及第2實施形態的廚房面板 用材料之性能比較調查結果的顯示圖。 【主要元件符號說明】 1…基板 2…金屬板 3…有機樹脂層 4…保護層 - 5…印刷層 101、102…廚房面板用材料 27〇 In the kitchen: on the way. In addition, the kitchen panel material can be applied to sanitary panels in addition to the kitchen panel. [Brief Description of the Drawings] Fig. 1 is a cross-sectional view showing a material for a kitchen panel according to a first embodiment of the present invention. Fig. 2 is a cross-sectional view showing a material for a kitchen panel according to a second embodiment of the present invention. Fig. 3 is a view showing the results of a comparison study on the performance of materials for kitchen panels according to the first and second embodiments of the present invention. [Description of main component symbols] 1...substrate 2...metal plate 3...organic resin layer 4...protective layer - 5...printing layer 101,102...material for kitchen panel 27
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| JP2007308660 | 2007-11-29 |
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| JP (1) | JPWO2009069464A1 (en) |
| KR (1) | KR20100087703A (en) |
| CN (1) | CN101855073B (en) |
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| WO (1) | WO2009069464A1 (en) |
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| EP2412891A3 (en) * | 2010-07-27 | 2013-10-23 | IBL UG haftungsbeschränkt | Fire-retardant architectural panel |
| CN102514310A (en) * | 2011-12-07 | 2012-06-27 | 常熟市东涛金属复合材料有限公司 | Clad metal sheet |
| JP6048042B2 (en) * | 2012-09-28 | 2016-12-21 | 凸版印刷株式会社 | Incombustible decorative board |
| EP2843129B2 (en) * | 2013-08-30 | 2023-06-07 | Saint-Gobain Placo | Reinforced gypsum board having improved fire resistance |
| WO2017173407A1 (en) * | 2016-04-01 | 2017-10-05 | Certainteed Gypsum, Inc. | Building board and method of forming the building board |
| KR102137997B1 (en) | 2017-05-02 | 2020-07-29 | 김홍집 | Kitchen installation kitchen panel for easy removal of contaminated protective film |
| CN111886132B (en) * | 2018-03-29 | 2022-12-06 | 日本制铁株式会社 | Covered metal plate and joining material having the covered metal plate |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH09125562A (en) * | 1995-11-01 | 1997-05-13 | Toyo Polymer Kk | Non-combustible kitchen panel |
| JP2000129821A (en) * | 1998-10-23 | 2000-05-09 | Sekisui Chem Co Ltd | Semi-combustible panel material |
| JP2000301682A (en) * | 1999-04-22 | 2000-10-31 | Toppan Printing Co Ltd | Decorative sheet |
| JP4344055B2 (en) * | 1999-12-24 | 2009-10-14 | 株式会社エーアンドエーマテリアル | Mirror surface decorative plate manufacturing method |
| JP2002052678A (en) * | 2000-08-07 | 2002-02-19 | Dainippon Printing Co Ltd | Method of manufacturing cosmetic material and cosmetic material |
| JP2004090298A (en) * | 2002-08-30 | 2004-03-25 | Dainippon Printing Co Ltd | Cosmetic material |
| JP2007045135A (en) * | 2005-08-11 | 2007-02-22 | Kohjin Shoji Kk | Non-flammable metal panel |
| CN2855727Y (en) * | 2005-11-24 | 2007-01-10 | 程子斌 | Aluminium cladding nonmetallic material structure |
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| CN101855073A (en) | 2010-10-06 |
| WO2009069464A1 (en) | 2009-06-04 |
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