TW201130932A - Infrared-reflective paint and infrared-reflective resin composition - Google Patents
Infrared-reflective paint and infrared-reflective resin composition Download PDFInfo
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- TW201130932A TW201130932A TW99135962A TW99135962A TW201130932A TW 201130932 A TW201130932 A TW 201130932A TW 99135962 A TW99135962 A TW 99135962A TW 99135962 A TW99135962 A TW 99135962A TW 201130932 A TW201130932 A TW 201130932A
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- resin
- infrared
- pigment
- leather
- coating
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
- C14C11/006—Surface finishing of leather using macromolecular compounds using polymeric products of isocyanates (or isothiocyanates) with compounds having active hydrogen
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- Chemical Kinetics & Catalysis (AREA)
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- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
201130932 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種反射太陽光等所含有之紅外線的紅 外線反射塗料及紅外線反射樹脂組成物。尤其，有關一種 具有紅外線反射功能之天然皮革用及人工皮革用的塗料、 與使用此之皮革製品、以及具有紅外線反射功能之樹脂組 成物及使用該樹脂組成物之樹脂成型品。 【先前技術】 近年，從對省能源或都市部之熱島現象的對策，硏究 於道路、建築物之屋頂或外壁等塗佈紅外線反射塗料以抑 制蓄熱，防止溫度上昇（參照專利文獻1、2)。 在夏季日中之汽車或建物的室內溫度係急劇上昇，曝 露於如此之環境下之室內的物品表面例如汽車安全帶、方 向盤、沙發等之皮革製品、儀錶板、行李箱、家倶、家電 製品等之樹脂成型品等的表面溫度亦上昇。若皮膚直接接 觸其等，感覺不愉快。 然而，至今在皮革製品或樹脂成型品中之紅外線反射 材料的硏究係不太實施。尤其皮革製品係易引起熱劣化， 尤其，天然皮革中係長期間曝露於日光之環境下，很難保 持特有的手感或美觀。 又，以往被硏究之紅外線反射塗料之大半係被設計於 屋外用之塗料，未對應於皮革製品或樹脂成型品。 先前技術文獻 -5- 201130932 專利文獻 專利文獻1 :特開2006-273985號公報 專利文獻2 :特開2007-217540號公報 【發明內容】 [發明欲解決之課題] 本發明之目的在於提出一種具有反射太陽光等所含有 之紅外線的紅外線反射功能之天然皮革用及人工皮革用的 塗料、與使用此之皮革製品、以及具有紅外線反射功能之 樹脂組成物及使用該樹脂組成物之樹脂成型品。 [用以解決課題之手段] 本發明之具有紅外線反射功能之天然皮革用及人工皮 革用塗料，係於構成伸度3 0%以上之塗料固形成分的玻璃 轉移溫度爲-30 °C〜90 °C之樹脂成分中，含有在波長 7 5〇11111〜2 60〇11111區域中具有10%以上之反射率譜峯的紅外線 反射顏料0.1〜5 0重Μ %。 又一種具有紅外線反射功能之紅外線反射樹脂組成物 ’其係於可熱成型之熱塑性樹脂成分中，含有在波長 750nm〜2600nm區域中具有10%以上之反射率譜峯的紅外 線反射顔料0 · 0 5 ~ 7 0重量％。 [發明之效果] 若依本發明，可提供一種具有反射太陽光等所含有之 -6- 201130932 紅外線的紅外線反射功能之天然皮革用及人工皮革用的塗 料、與使用此之皮革製品、以及具有紅外線反射功能之樹 脂組成物及使用該樹脂組成物之樹脂成型品。 藉本發明，可抑制表面溫度上昇，得到保持手感或美 觀之皮革製品及樹脂成型品。 [用以實施發明之形態] (天然皮革用及人工皮革用塗料） 本發明之具有紅外線反射功能之天然皮革用及人工 皮革用塗料，係於構成伸度3 0 %以上之塗料固形成分的玻 璃轉移溫度爲-30 °C〜90 °C之樹脂成分中，含有在波長 75〇nm〜26〇〇nm區域中具有1 〇%以上之反射率譜峯的紅外線 反射顏料0 . 1 ~ 5 0重量％。 前述之樹脂成分爲由聚胺基甲酸酯樹脂、（甲基）丙 烯酸樹脂、聚酯樹脂、乙烯基酯樹脂、醇酸樹脂、聚矽氧 樹脂、硝基纖維素樹脂、纖維素酯系樹脂、酪蛋白所選出 之1種或2種以上所構成的樹脂、或可塑劑被混合於此者。 由前述樹脂、或於前述樹脂中混合可塑劑者所構成之 樹脂成分，成爲在具有本發明之紅外線反射功能的天然皮 革用及人工皮革用塗料中之塗料固形分。 本發明之天然皮革用及人工皮革用塗料中係此塗料固 形分之伸度成爲30%以上。塗料固形分之伸度未達30%時 ’塗佈有本發明之塗料的皮革彎曲時，恐於塗膜產生破損 或龜裂。因塗料固形分之伸度爲30%以上，故本發明之塗 201130932 料可發揮良好的耐彎曲性與密著性。 如前述般，樹脂成分之玻璃轉移溫度爲-30 °C〜90。(：。 玻璃轉移溫度超過90 °C時，塗膜硬，且變脆而損及塗佈有 本發明之塗料的皮革表面的手感，或於彎曲時破損，或剝 離。另外，玻璃轉移溫度未達-30 °C時，係於皮革表面易 產生沾黏，重疊塗料塗佈後之皮革製品時，互相貼黏，或 附著塵埃，而很難處理。從如此之觀點，前述樹脂成分更 佳之玻璃轉移溫度爲-15°C〜70°C。 此處所敘述之玻璃轉移溫度係單獨使用上述樹脂時， 不僅其玻璃轉移溫度在於-3 0 °C ~ 9 0 °C之範圍內時，組合前 述樹脂之複數者、或單獨使用之前述樹脂中混合可塑劑者 、或組合前述樹脂之複數者中混合可塑劑者所構成之樹脂 成分的玻璃轉移溫度在於-30 °C〜90 °C之範圍內。 亦即，在上述複數的樹脂中組合玻璃轉移溫度高的樹 脂與低的樹脂，或添加可塑劑，俾構成塗料固形分之前述 的樹脂成分之玻璃轉移溫度被限制於-3CTC〜90°C之特定玻 璃轉移溫度範圍內即可》 在本發明之塗料可使用的可塑劑之具體例，係可舉例 如二甲基酞酸酯、二乙基酞酸酯、二丁基酞酸酯、雙（2-乙基己基）酞酸酯、丁基苯甲基、二異癸基酞酸酯等之酞 酸酯系可塑劑、二甲基己二酸酯、二丁基己二酸酯、二異 丁基己二酸酯、雙（2-乙基己基）己二酸酯、二異癸基己 二酸酯等之己二酸酯、磷酸酯、蓖麻醇酸酯、聚酯、蔥麻 油、礦物油等。此等之可塑劑係可組合二種以上而使用。 -8- 201130932 可使用於具有本發明之紅外線反射功能的天然皮革用 及人工皮革用塗料之紅外線反射顔料，爲提高紅外線反射 效率，宜爲紅外線區域之反射率高於碳黑顏料者。就在如 此之紅外線區域可發揮高的反射率者，宜使用在波長 75〇11111〜260〇11111區域中具有1〇°/。以上之反射率譜峯的紅外線 反射顏料。 具有在前述波長75〇nm〜2600nm區域中具有1〇%以上 之反射率譜峯的紅外線反射顏料係可例示含有二種以上之 金屬元素的複合氧化物系黑色顏料、偶氮甲亞胺系黑色顏 料、無機白色顏料、干涉顏料。在本發明中，係可使用從 此等之中選出的一種或二種以上。 無機白色顏料可舉例如氧化鈦、氧化鋅、氧化銷、氧 化鋁、二氧化矽、硫酸鋇等。若考量耐水性、耐藥品性等 ，宜爲金紅石型氧化鈦、氧化鋅。 干涉顏料係只要於顏料表面單層或層合塗佈由折射率 相異之材料所構成的薄膜之顔料，產生光干涉現象者即可 〇 含有二種以上之金屬元素的複合氧化物系黑色顏料， 可舉例如鐵、銅、銘、鉍、錳、鈷、釔、鋁、鎂、鈣、鈦 、錫、鋅等選出二種以上之金屬元素的複合氧化物系顔料 。使用含有如此之二種以上之金屬元素的複合氧化物系黑 色顏料時’宜平均粒徑爲5〇nm~2()()()nm。 偶氮甲亞胺系黑色顔料亦宜平均粒徑爲50nm〜2000nm 201130932 任一者之情形，平均粒徑超過2000nm時，係塗膜表面 之平滑性或保存安定性變差。平均粒徑未達5 〇nm時，有時 塗膜之隱蔽性變弱，於塗料之分散變困難。從如此之觀點 ，含有前述二種以上之金屬元素的複合氧化物系黑色顏料 、及偶氮甲亞胺系黑色顏料更佳之平均粒徑爲 1 OOnm〜1 OOOnm 〇 在具有本發明之紅外線反射功能的天然皮革用及人工 皮革用塗料中，於前述樹脂成分所含有之前述紅外線反射 顔料爲前述樹脂成分之0.1〜5 0重量％。 若超過50重量％而含有，易引起紅外線反射顏料之凝 集或沉澱，故不佳。另外，若含量少於0.1重量％，無法得 到充分的熱線反射效果，故不佳。從如此之觀點，更佳之 含量係相對於前述樹脂成分爲1 ~3 0重Μ %。 在具有本發明之紅外線反射功能的天然皮革用及人工 皮革用塗料中，爲提昇塗膜之耐摩耗性或耐熱性，可使用 交聯劑。可使用例如異氰酸酯化合物、氮丙啶、環氧化合 物等。又，若增加交聯劑之比例，塗膜之耐摩耗性或耐熱 性提昇，但若交聯劑之比率太多，塗膜變硬，有損手感。 因此，前述之樹脂成分與交聯劑、例如異氛酸酯化合物之 調配比係宜設定成交聯劑例如異氛酸酯化合物爲7 0重量％ 以下。 又，在無損本發明之目的的範圍，依需要亦可添加各 種之著色劑、分散劑、消泡劑、紫外線吸收劑、抗氧化劑 等。 -10- 201130932 在具有本發明之紅外線反射功能的天然皮革用及人工 皮革用塗料，可依一般之要領進行製造。 例如，可賦予剪斷力之攪拌機或使用分散機而混合前 述之構成成分來製造。又，在無損本發明之目的的範圍， 依需要而添加顏料分散劑或潤濕劑等而調製顏料之分散情 形。 又，前述之構成成分中，樹脂成分係宜使用加工成乳 液、有機溶劑溶液等之形態者。 又，前述之構成成分中，紅外線反射顔料係亦可直接 加入於其他之構成成分中，亦可預先分散於水或有機溶劑 而使用。 從如此做法所製造之本發明的塗料分離除去異物或凝 集粒子時，係使用濾紙或濾布而進行此等之分離除去。 又’可賦予剪斷力之攪拌機或分散機係可使用例如熔 融棒、均質機、漢歇爾混合機、球磨機、油漆振盪機、輥 輪、噴磨機、超音波分散裝置等。 有關具有本發明之紅外線反射功能的天然皮革用及人 工皮革用塗料之塗佈法係爲任意且亦可採用既知方法、例 如輥輪塗佈法、噴塗法或噴霧法等任一者的方法。 依需要，在無損本發明之目的的範圍，可適當調配顏 料、增黏劑、塡充劑、蠟、交聯劑、紫外線吸收劑等。 形成於皮革表面之塗料層係單層或複層。塗膜之膜厚 宜爲薄者，但無法以單層得到充分的紅外線反射效果時， 或，對於如皮革之表面的粗皮革係亦可以數次之塗佈形成 -11 - 201130932 數層。 本發明之塗料的被塗佈體並特別限制，但宜爲皮革製 品，亦可爲天然皮革、人工皮革的任一者。亦即，若依本 發明，可提供一種塗佈有具有本發明之紅外線反射功能的 天然皮革用及人工皮革用塗料之天然或人工皮革用製品。 天然皮革可舉例如牛皮、馬皮、羊皮、山羊皮、豬皮 等，並無特別限制，但宜爲具有牛皮、馬皮等平滑的表面 者。又，使用此等之皮革時，亦可進行耐熱、制革步驟等 之必須的前處理。人工皮革可舉例如氯化乙烯皮革、胺基 甲酸酯皮革、乙烯皮革等。 (紅外線反射樹脂組成物） 具有本發明之紅外線反射功能的紅外線反射樹脂組成 物係於可熱成型之熱塑性樹脂成分中，含有在波長75 Onm ~ 2600nm區域中具有10%以上之反射率譜峯的紅外線反射 顏料0.0 5 ~ 7 0重量％。 於本發明之紅外線反射樹脂組成物所使用的樹脂係加 上熱只要爲可塑化之樹脂，亦即熱塑性樹脂即可’並無特 別限制。可舉例如聚乙烯、聚丙烯、聚甲基戊烯、聚丁二 烯等之聚烯烴樹脂、聚甲基丙烯酸甲酯、聚甲基丙Μ酸酯 等之丙烯酸樹脂、聚對苯二甲酸乙二酯、聚對苯二甲酸丁 二酯等之聚酯樹脂、聚碳酸酯、聚苯乙烯、苯乙烯丁二嫌 樹脂、丙烯腈苯乙烯樹脂、聚氯化乙烯、聚醋酸醋' 聚偏氯乙烯、丁縮醛樹脂、乙烯醋酸乙烯酯共聚物' @2* -12- 201130932 醛、聚醯胺、聚醯亞胺、聚苯醚、醋酸纖維素、胺基甲酸 酯樹脂、ABS樹脂、AAS樹脂、ACS樹脂、AES樹脂、烯烴 共聚合系彈性體、各種聚合物合膠等。可使用從此等之中 選出之一種或複數種。 於具有本發明之紅外線反射功能之紅外線反射樹脂組 成物所使用的紅外線反射顏料，係可使用與前述之具有本 發明之紅外線反射功能之天然皮革用及人工皮革用塗料所 使用的紅外線反射顏料相同者》 亦即可使用於具有本發明之紅外線反射功能的紅外線 反射樹脂組成物之紅外線反射顏料，爲提高紅外線反射效 率，宜爲紅外線區域之反射率高於碳黑顏料者。就在如此 之紅外線區域可發揮高的反射率者，宜使用在波長 7 50nm〜2600nm區域中具有1 〇%以上之反射率譜峯的紅外線 反射顏料。 具有在前述波長75〇nm〜2600nm區域中具有10%以上 之反射率譜峯的紅外線反射顔料係可例示含有二種以上之 金屬元素的複合氧化物系黑色顏料、偶氮甲亞胺系黑色顏 料、無機白色顏料、干涉顏料。在本發明中，係可使用從 此等之中選出的一種或二種以上。 無機白色顏料可舉例如氧化鈦、氧化鋅、氧化锆、氧 化鋁、二氧化砍、硫酸鋇等。若考量耐水性、耐藥品性等 ，宜爲金紅石型氧化鈦、氧化鲜。 干涉顏料係只要於顏料表面單層或層合塗佈由折射率 相異之材料所構成的薄膜之顏料，產生光干涉現象者即可 -13- 201130932 含有二種以上之金屬元素的複合氧化物系黑色顏料， 可舉例如鐵、銅、鉻、鉍、錳、鈷、釔、鋁、鎂、鈣 '鈦 、錫、鋅等選出二種以上之金屬元素的複合氧化物系顏料 。使用含有如此之二種以上之金屬元素的複合氧化物系黑 色顔料時，宜平均粒徑爲50nm〜2000nm* 偶氮甲亞胺系黑色顏料亦宜平均粒徑爲50nm~2 0 0 0nm 〇 任一者之情形，平均粒徑超過2000ηίη時或未達50nm 時，係有時於樹脂之分散變困難。從如此之觀點，更佳之 平均粒徑爲l〇〇nm〜lOOOnm。 在具有本發明之紅外線反射功能的紅外線反射樹脂組 成物中，於可使前述之紅外線反射顏料熱成型的熱塑性樹 脂成分含有的比率爲0.05〜70重量％。若超過70重量％而含 有，紅外線反射顏料之分散性降低，故不佳。另外，若含 S少於0.05重量％，無法得到充分的熱線反射效果，故不 佳。從如此之觀點，更佳之含量相對於前述樹脂成分爲 0.1〜50重量％。 具有本發明之紅外線反射功能的紅外線反射樹脂組成 物係可使用前述之構成成分而以以往公知之方法製造。 例如，可使熱塑性樹脂與紅外線反射顏料直接混練或 熔融混練而得到紅外線反射樹脂組成物。又，使紅外線反 射顏料分散於有機溶劑後，亦可與熱塑性樹脂混練而得到 紅外線反射樹脂組成物。 -14- 201130932 上述混練時，只要使用一般之樹 例如射出成形機、輥磨機、押出機等 歇爾混合機、Banbary混合機、捏合 之後，以押出機等進行混練等。 又，依需要而在無損本發明之目 各種之著色劑、分散劑、可塑劑、紫 劑等。 從具有本發明之紅外線反射功能 成物所得到的成型品之對象係無特別 內外裝品、纖維、家電製品外裝品、 家倶、遊戲機等。此等係使前述之構 押出而以單獨希望之形態成形。 亦即，可從上述之本發明的紅外 行熱成型而形成本發明之成型樹脂製 又，亦可採用預先使本發明之成 品而裝塡於模具內後，注入熔融樹脂 而得到一體複合品之插入模鑄成型》[Technical Field] The present invention relates to an infrared reflective paint and an infrared reflective resin composition which reflect infrared rays contained in sunlight or the like. In particular, it relates to a coating for natural leather and artificial leather having an infrared reflection function, a leather composition using the same, a resin composition having an infrared reflection function, and a resin molded article using the resin composition. [Prior Art] In recent years, the countermeasures against the heat island phenomenon of the Ministry of Energy and the Ministry of the City are applied to the roof, the roof of the building, or the outer wall to suppress the heat storage and prevent the temperature from rising (see Patent Documents 1 and 2). ). In the summer day, the indoor temperature of cars or buildings rises sharply, and the surface of articles exposed to such environments, such as car seat belts, steering wheels, sofas, leather goods, dashboards, luggage, furniture, home appliances, etc. The surface temperature of the resin molded article or the like also rises. If the skin is directly in contact with it, it feels unpleasant. However, the research on infrared reflective materials in leather products or resin molded articles has not been implemented so far. In particular, leather products are liable to cause thermal deterioration. In particular, natural leather is exposed to sunlight in a long period of time, and it is difficult to maintain a unique touch or appearance. In addition, most of the infrared reflective coatings that have been studied in the past are designed for use in exterior coatings, and do not correspond to leather products or resin molded articles. CITATION LIST OF THE INVENTION PROBLEMS TO BE SOLVED BY THE INVENTION [Problem to be Solved by the Invention] The object of the present invention is to provide a A paint for natural leather and artificial leather that reflects infrared rays reflected in sunlight or the like, a leather product using the same, a resin composition having an infrared reflection function, and a resin molded article using the resin composition. [Means for Solving the Problem] The natural leather and artificial leather coating having the infrared reflection function of the present invention is a glass transition temperature of -30 ° C to 90 ° which is a solid content of a coating which constitutes a stretch of 30% or more. The resin component of C contains 0.1 to 50% by weight of an infrared reflective pigment having a reflectance peak of 10% or more in a wavelength range of 75 〇 11111 〜 2 60 〇 11111. Further, an infrared reflective resin composition having an infrared reflection function is attached to a thermoformable thermoplastic resin component and contains an infrared reflective pigment having a reflectance peak of 10% or more in a wavelength range of 750 nm to 2600 nm. ~ 70% by weight. [Effects of the Invention] According to the present invention, it is possible to provide a coating for natural leather and artificial leather having an infrared reflection function of -6-201130932 infrared rays contained in sunlight, and the like, and a leather product using the same, and A resin composition of an infrared reflection function and a resin molded article using the resin composition. According to the present invention, it is possible to suppress the rise in the surface temperature and obtain a leather product and a resin molded article which are kept in a hand or a beautiful appearance. [Formation for Carrying Out the Invention] (Coating for Natural Leather and Artificial Leather) The natural leather and artificial leather coating having the infrared reflection function of the present invention is a glass which constitutes a solid content of a coating having an elongation of 30% or more. In the resin component having a transfer temperature of -30 ° C to 90 ° C, the infrared reflective pigment having a reflectance peak of 1 〇 % or more in a region of a wavelength of 75 〇 nm to 26 〇〇 nm is 0.1 to 500 weight. %. The aforementioned resin component is composed of a polyurethane resin, a (meth)acrylic resin, a polyester resin, a vinyl ester resin, an alkyd resin, a polyoxyxylene resin, a nitrocellulose resin, or a cellulose ester resin. A resin or a plasticizer composed of one or more selected from casein is mixed therewith. The resin component composed of the above-mentioned resin or a plasticizer mixed with the above-mentioned resin is a coating solid content in the coating for natural leather and artificial leather having the infrared reflection function of the present invention. In the coating for natural leather and artificial leather of the present invention, the elongation of the coating is 30% or more. When the elongation of the solid content of the coating is less than 30%, when the leather coated with the coating of the present invention is bent, the coating film may be damaged or cracked. Since the elongation of the solid content of the coating is 30% or more, the coating of the present invention, 201130932, exhibits good bending resistance and adhesion. As described above, the glass transition temperature of the resin component is -30 ° C to 90 °. (: When the glass transition temperature exceeds 90 °C, the coating film is hard and becomes brittle to damage the surface of the leather coated with the coating of the present invention, or breakage or peeling during bending. In addition, the glass transition temperature is not When the temperature reaches -30 °C, it is easy to cause sticking on the surface of the leather. When the leather products coated with the overlapping coatings adhere to each other, or adhere to dust, it is difficult to handle. From this point of view, the glass with better resin composition is better. The transfer temperature is -15 ° C to 70 ° C. The glass transition temperature described herein is the same when the above resin is used alone, not only when the glass transition temperature is in the range of -3 0 ° C to 90 ° C, the resin is combined. The glass transition temperature of the resin component composed of a plurality of the above-mentioned resins, or a mixture of the above-mentioned resins, or a combination of the above-mentioned resins, is in the range of -30 ° C to 90 ° C. That is, in combination with a resin having a high glass transition temperature and a low resin or a plasticizer added to the above plurality of resins, the glass transition temperature of the above-mentioned resin component constituting the solid content of the coating is limited to -3 CTC to 9 Specific examples of the plasticizer which can be used in the coating of the present invention are, for example, dimethyl phthalate, diethyl phthalate, dibutyl decanoic acid. a phthalate-based plasticizer such as an ester, bis(2-ethylhexyl) phthalate, butylbenzyl or diisodecyl phthalate, dimethyl adipate, dibutyl adipate Adipate, phosphate, ricinoleate, polyester such as ester, diisobutyl adipate, bis(2-ethylhexyl) adipate, diisodecyl adipate , scallion oil, mineral oil, etc. These plasticizers can be used in combination of two or more. -8- 201130932 It can be used for infrared reflective pigments for natural leather and artificial leather coatings having the infrared reflection function of the present invention, In order to improve the infrared reflection efficiency, it is preferable that the reflectance of the infrared region is higher than that of the carbon black pigment. In such an infrared region, a high reflectance can be used, and it is preferable to use a wavelength of 75〇11111 to 260〇11111. °/. The above-mentioned reflectance peak of the infrared reflective pigment. The infrared-reflecting pigment having a reflectance peak of 1% by weight or more in the region of 75 Å to 2,600 nm in length may be a composite oxide black pigment containing two or more kinds of metal elements, an azomethine-based black pigment, or inorganic In the present invention, one or two or more selected from the group may be used. The inorganic white pigment may, for example, be titanium oxide, zinc oxide, oxidized pin, alumina, cerium oxide or barium sulfate. Etc. If considering water resistance, chemical resistance, etc., it is preferably rutile-type titanium oxide or zinc oxide. The interference pigment is a single-layer or laminar coating of a pigment composed of a material having a different refractive index on the surface of the pigment. A composite oxide black pigment containing two or more kinds of metal elements, such as iron, copper, indium, lanthanum, manganese, cobalt, lanthanum, aluminum, magnesium, calcium, titanium, tin, may be produced by the phenomenon of light interference. A composite oxide pigment in which two or more metal elements are selected from zinc or the like. When a composite oxide black pigment containing two or more kinds of metal elements is used, the average particle diameter is 5 〇 nm 2 () () (nm). The azomethine-based black pigment preferably has an average particle diameter of 50 nm to 2000 nm. In the case of any of the above, when the average particle diameter exceeds 2000 nm, the smoothness or storage stability of the surface of the coating film is deteriorated. When the average particle diameter is less than 5 〇 nm, the concealing property of the coating film may be weak, and dispersion of the coating may become difficult. From such a viewpoint, the composite oxide black pigment containing the above two or more metal elements and the azomethine black pigment preferably have an average particle diameter of 100 nm to 1 OOO nm, and have the infrared reflection function of the present invention. In the natural leather and artificial leather paint, the infrared reflective pigment contained in the resin component is 0.1 to 50% by weight of the resin component. If it is contained in an amount of more than 50% by weight, aggregation or precipitation of the infrared reflective pigment is liable to occur, which is not preferable. On the other hand, if the content is less than 0.1% by weight, a sufficient heat ray reflection effect cannot be obtained, which is not preferable. From such a viewpoint, a more preferable content is 1 to 30% by weight based on the above resin component. In the coating for natural leather and artificial leather having the infrared reflection function of the present invention, a crosslinking agent can be used to improve the abrasion resistance and heat resistance of the coating film. For example, an isocyanate compound, aziridine, an epoxide or the like can be used. Further, when the ratio of the crosslinking agent is increased, the abrasion resistance and heat resistance of the coating film are improved. However, if the ratio of the crosslinking agent is too large, the coating film becomes hard and the hand feel is impaired. Therefore, the compounding ratio of the above-mentioned resin component to a crosslinking agent, for example, an isocyanate compound is preferably set to be 70% by weight or less of a crosslinking agent such as an isocyanate compound. Further, various coloring agents, dispersing agents, antifoaming agents, ultraviolet absorbers, antioxidants, and the like may be added as needed within the scope of the object of the present invention. -10- 201130932 A natural leather and artificial leather paint having the infrared reflection function of the present invention can be produced in accordance with a general method. For example, it can be produced by blending the above-mentioned constituent components with a blender capable of imparting shearing force or by using a disperser. Further, in the range which does not impair the object of the present invention, a pigment dispersant or a wetting agent or the like is added as needed to prepare a dispersion of the pigment. Further, among the above-mentioned constituent components, the resin component is preferably used in the form of an emulsion or an organic solvent solution. Further, among the above-mentioned constituent components, the infrared reflective pigment may be directly added to other constituent components, or may be used by being dispersed in water or an organic solvent in advance. When the foreign matter or the aggregated particles are separated and removed from the coating material of the present invention produced in this manner, the separation and removal are carried out using a filter paper or a filter cloth. Further, for example, a melting rod, a homogenizer, a Hanschel mixer, a ball mill, a paint shaker, a roller, a jet mill, an ultrasonic dispersing device, or the like can be used as the agitator or dispersing machine which can impart shearing force. The coating method for the natural leather and the artificial leather coating having the infrared reflection function of the present invention is arbitrary, and any of known methods such as a roll coating method, a spray method, or a spray method may be employed. The pigment, the tackifier, the chelating agent, the wax, the crosslinking agent, the ultraviolet absorber, and the like can be appropriately formulated as needed within the scope of the object of the present invention. The coating layer formed on the surface of the leather is a single layer or a composite layer. The film thickness of the coating film is preferably thin, but when a sufficient infrared reflection effect cannot be obtained in a single layer, or a thick leather system such as a leather surface may be applied several times to form a number of layers -11 - 201130932. The coated body of the coating material of the present invention is particularly limited, but it is preferably a leather product, and may be either natural leather or artificial leather. That is, according to the present invention, it is possible to provide a product for natural or artificial leather coated with a coating for natural leather and artificial leather having the infrared reflection function of the present invention. The natural leather may, for example, be cowhide, horse skin, sheepskin, goat skin, pig skin or the like, and is not particularly limited, but is preferably a smooth surface such as cowhide or horse skin. Further, when such leather is used, it is also possible to perform pretreatment such as heat resistance and tanning step. The artificial leather may, for example, be vinyl chloride leather, urethane leather, vinyl leather or the like. (Infrared Reflective Resin Composition) The infrared reflective resin composition having the infrared reflection function of the present invention is contained in a thermoformable thermoplastic resin component and contains a reflectance peak having a reflectance peak of 10% or more in a wavelength range of 75 nm to 2600 nm. The infrared reflective pigment is 0.0 5 to 70% by weight. The resin to be used in the infrared-reflective resin composition of the present invention is not particularly limited as long as it is a plasticizable resin, that is, a thermoplastic resin. For example, a polyolefin resin such as polyethylene, polypropylene, polymethylpentene or polybutadiene, an acrylic resin such as polymethyl methacrylate or polymethyl phthalate, or polyethylene terephthalate Polyester resin such as diester or polybutylene terephthalate, polycarbonate, polystyrene, styrene butadiene resin, acrylonitrile styrene resin, polyvinyl chloride, polyvinyl acetate vinegar Ethylene, butyral resin, ethylene vinyl acetate copolymer ' @2* -12- 201130932 Aldehyde, polyamine, polyimide, polyphenylene ether, cellulose acetate, urethane resin, ABS resin, AAS resin, ACS resin, AES resin, olefin copolymerized elastomer, various polymer glues, and the like. One or a plurality selected from among these may be used. The infrared reflective pigment used in the infrared reflective resin composition having the infrared reflection function of the present invention can be used in the same manner as the infrared reflective pigment used in the above-mentioned natural leather and artificial leather coatings having the infrared reflection function of the present invention. The infrared reflective pigment having the infrared reflective resin composition having the infrared reflection function of the present invention can also be used. In order to improve the infrared reflection efficiency, it is preferable that the reflectance of the infrared region is higher than that of the carbon black pigment. In the case where such a high-intensity reflectance can be exhibited in such an infrared region, it is preferable to use an infrared reflective pigment having a reflectance peak of 1% or more in a wavelength range of from 50 to 2600 nm. The infrared reflective pigment having a reflectance peak of 10% or more in the region of the wavelength of 75 〇 nm to 2600 nm is exemplified by a composite oxide black pigment or an azomethine black pigment containing two or more metal elements. , inorganic white pigments, interference pigments. In the present invention, one or more selected from the above may be used. The inorganic white pigment may, for example, be titanium oxide, zinc oxide, zirconium oxide, aluminum oxide, cerium oxide or barium sulfate. When considering water resistance, chemical resistance, etc., it is preferably rutile-type titanium oxide and fresh oxide. The interference pigment system is a composite film containing two or more kinds of metal elements as long as the pigment of the film composed of a material having a different refractive index is applied to the surface of the pigment layer by lamination or lamination, and the light interference phenomenon occurs. 13-201130932 The black pigment may, for example, be a composite oxide pigment in which two or more metal elements are selected, such as iron, copper, chromium, ruthenium, manganese, cobalt, rhodium, aluminum, magnesium, calcium, titanium, tin, or zinc. When a composite oxide black pigment containing two or more kinds of metal elements is used, the average particle diameter is preferably from 50 nm to 2000 nm*, and the azomethine-based black pigment preferably has an average particle diameter of 50 nm to 200 nm. In the case of one, when the average particle diameter exceeds 2,000 η η or when it is less than 50 nm, it may be difficult to disperse in the resin. From such a viewpoint, a more preferable average particle diameter is l〇〇nm~lOOOnm. In the infrared reflective resin composition having the infrared reflection function of the present invention, the ratio of the thermoplastic resin component which can be thermoformed to the infrared reflective pigment described above is 0.05 to 70% by weight. If it exceeds 70% by weight, the dispersibility of the infrared reflective pigment is lowered, which is not preferable. Further, if S is contained in the amount of less than 0.05% by weight, a sufficient heat ray reflection effect cannot be obtained, which is not preferable. From such a viewpoint, a more preferable content is 0.1 to 50% by weight based on the above resin component. The infrared reflective resin composition having the infrared reflection function of the present invention can be produced by a conventionally known method using the above-described constituent components. For example, the thermoplastic resin and the infrared reflective pigment may be directly kneaded or melt-kneaded to obtain an infrared reflective resin composition. Further, after dispersing the infrared reflective pigment in an organic solvent, it may be kneaded with a thermoplastic resin to obtain an infrared reflective resin composition. -14- 201130932 In the above-mentioned kneading, a general-purpose tree, such as an injection molding machine, a roll mill, an extruder, or the like, a Baner mixer, a kneading machine, and kneading are used, and kneading is performed by an extruder or the like. Further, various coloring agents, dispersing agents, plasticizers, and purifying agents, etc., which are the object of the present invention, are not impaired as needed. The object of the molded article obtained by the infrared reflecting functional product of the present invention is not particularly suitable for interior and exterior articles, fibers, home furnishings, furniture, furniture, and the like. These are configured to be formed in a form that is desired as desired. In other words, the molding resin of the present invention can be formed by the infrared hot-melting of the present invention described above, or the molten resin can be injected into the mold after the finished product of the present invention is preliminarily attached to the mold to obtain an integrated composite. Insert molding
料的薄板、薄片、薄膜等重疊二片以 等。 亦即，可形成一種樹脂成形品， 的紅外線反射樹脂組成物進行熱成型 樹脂製品、與如丙烯酸樹脂製品的其 亦即，未具備熱線反射功能之合成樹 脂混練機即可，可舉 進行混練之方法、漢 機、Brabender等混合 的的範圍，亦可添加 外線吸收劑、抗氧化 之紅外線反射樹脂組 限制。可舉例如汽車 薄片、薄膜、容器、 成成分混練後，直接 線反射樹脂組成物進 品。 型樹脂製品作爲插入 而包圍插入品以固化 進一步，亦可採用在 一種或二種以上之材 上而黏著之積層加工 其係由上述之本發明 而成之本發明的成型 他之合成樹脂製品（ 脂製品）一體化之複 -15- 201130932 合品所構成者。或，可形成一種樹脂成形品，其係由上述 之本發明的紅外線反射樹脂組成物進行熱成型而成之本發 明的成型樹脂製品被層合於如丙烯酸樹脂製品的其他之合 成樹脂製品（亦即，未具備熱反射功能之合成樹脂製品） 之表面的複合品所構成之樹脂成形品。 圖3、圖4係說明如此之實施形態的一例者。圖3係說 明於如板或片狀之丙烯酸樹脂製品的合成樹脂成型物，張 貼本發明的紅外線反射樹脂組成物進行熱成型而成之本發 明的成型樹脂製品而成之複合品的一例者。圖3中，表示 爲下側之樹脂成型品的部分未具備如板或片狀之丙烯酸樹 脂製品的熱線反射功能之合成樹脂成型物。表示爲上側之 紅外線反射樹脂組成物的部分爲本發明之成型樹脂製品。 若圖3之上側的部分形成於太陽光等照射之表面側，可抑 制表面溫度上昇。 圖4係說明從具有凹凸之丙烯酸樹脂製品之合成樹脂 成型物與本發明之紅外線反射樹脂組成物熱成型而成之本 發明之成型樹脂製品一體化的複合品之一例者。圖4中， 表示爲下側之樹脂成型品的部分未具備如丙烯酸樹脂製品 的熱線反射功能之合成樹脂成型物。表示爲上側之紅外線 反射樹脂組成物的部分爲本發明之成型樹脂製品。若圖4 之上側的部分形成於太陽光等照射之表面側，可抑制表面 溫度上昇。 藉由如此做法，而使未具備熱線反射功能之丙烯酸板 或合成樹脂成型品形成具有紅外線反射功能之合成樹脂的 -16- 201130932 複合品。 【實施方式】 實施例 1 (具有紅外線反射功能之天然皮革用及人工皮革用塗料） 使用以下之構成成分而製造具有本發明之紅外線反射 功能之天然皮革用及人工皮革用塗料。 〈所使用之樹脂成分〉The sheets, sheets, films, and the like of the material are overlapped by two sheets. In other words, the infrared-reflective resin composition which can form a resin molded article can be a thermoformed resin product, and a synthetic resin kneading machine which does not have a heat-ray reflecting function, such as an acrylic resin product, can be kneaded. The method, the range of the Han machine, Brabender, etc., may also be limited by the addition of an external absorbent and an anti-oxidation infrared reflective resin group. For example, a car sheet, a film, a container, and a component are kneaded, and a direct line reflection resin composition is introduced. The resin product is surrounded by the insert to be cured for further insertion, and the synthetic resin product of the present invention obtained by the above-described invention may be processed by laminating one or more materials. The product of the integration of the fat product) -15- 201130932. Alternatively, a resin molded article obtained by thermoforming the infrared reflective resin composition of the present invention described above may be laminated to other synthetic resin products such as acrylic resin products (also In other words, a resin molded article comprising a composite of the surface of a synthetic resin product having no heat reflecting function. 3 and 4 illustrate an example of such an embodiment. Fig. 3 is a view showing an example of a composite product of the molded resin article of the present invention in which the infrared reflective resin composition of the present invention is thermoformed, which is a synthetic resin molded article of a plate or sheet-like acrylic resin product. In Fig. 3, a portion of the resin molded article of the lower side is a synthetic resin molded article which does not have a heat ray reflecting function such as a plate or a sheet of acrylic resin product. The portion of the infrared reflective resin composition indicated as the upper side is the molded resin article of the present invention. When the upper portion of Fig. 3 is formed on the surface side irradiated with sunlight or the like, the surface temperature rise can be suppressed. Fig. 4 is a view showing an example of a composite product in which a molded resin article of the present invention obtained by thermoforming a synthetic resin molded article having an uneven acrylic resin product and the infrared reflective resin composition of the present invention. In Fig. 4, a portion of the resin molded article of the lower side is not provided with a synthetic resin molded article having a heat ray reflecting function as an acrylic resin product. The portion indicated as the upper infrared reflective resin composition is the molded resin article of the present invention. When the upper portion of Fig. 4 is formed on the surface side irradiated with sunlight or the like, the surface temperature rise can be suppressed. By doing so, the acrylic plate or the synthetic resin molded article which does not have the heat reflecting function is formed into a composite resin having a synthetic resin having an infrared reflecting function. [Embodiment] Example 1 (Cointing material for natural leather and artificial leather having infrared reflection function) A coating material for natural leather and artificial leather having the infrared reflection function of the present invention was produced by using the following constituent components. <Resin component used>
聚胺基甲酸酯樹脂：黏結劑RBPolyurethane Resin: Adhesive RB
(五常產業製乳化樹脂固形分 30% )玻璃轉移溫度：約l〇°C 丙烯酸樹脂A :黏結劑S A (五常產業（股）製乳化樹脂固形 分30%)玻璃轉移溫度：約-1〇t 硝化綿漆：乾式透明 (五常產業（股）製硝化綿樹脂溶液 固形分13%)玻璃轉移溫度：1〇〇<t 以上 〈所使用之紅外線反射顏料〉 紅外線反射黑色顔料A Bi-Cu系複合氧化物 紅外線反射黑色顏料B偶氮甲亞胺系化合物 無機白色顔料 JR-1000(Teika製） -17- 201130932(Five-factory emulsified resin solid content 30%) Glass transfer temperature: about l〇 °C Acrylic resin A: Adhesive agent SA (Five-component industry (stock) emulsified resin solid content 30%) Glass transfer temperature: about -1 〇t Nitrifying varnish: dry transparent (five percent of nitrocellulose resin solution produced by Wuchang Industry Co., Ltd.) glass transition temperature: 1 〇〇 <t or more <infrared reflective pigment used> infrared reflective black pigment A Bi-Cu Composite oxide infrared reflection black pigment B azomethine compound inorganic white pigment JR-1000 (made by Teika) -17- 201130932
干涉顔料 黑色顏料AInterference pigment black pigment A
黑色顔料BBlack pigment B
紅色著色顏料A 黃色著色顏料BRed coloring pigment A yellow coloring pigment B
Solar flair 8 75(Merck) CP黑色（五常產業（股）製碳黑 ) 碳黑（c. I. Name Pigment Black 7) TAROX R-516-L(鈦工業製） TAROX LL-XLO(鈦工業製） 在所使用之紅外線反射顏料的平均粒徑、波長75 Onm〜 2 600nm中之反射率譜峯的數値係如以下之表1。 [表1] 平均粒徑 反射率 紅外線反射黑色顏料A 0.7 μ m 60% (1500nm) 紅外線反射黑色顏料B 0.3 μ τη 60% (1500nm) 無機白色顔料 一 88% (1500nm) 干涉顔料 — 85% (1500nm) 黑色顔料A — 未達5% (ΙδΟΟηιη) 黑色顏料B — 未達5% (1500nm) 紅色著色顔料A — 70% (1300nm) 黃色著色顔料B — 75% (1300nm) 〈所使用之可塑劑、交聯劑〉 可塑劑 DOA (二辛基己二酸酯） 交聯劑 Elastron BN-1 1 (第一工業製藥製） 使上述原料，依據下述表2所示之各材料的調配比率 ，以全量成爲100重量％之方式’調製於不銹鋼製容器。再 -18- 201130932 以攪拌溶解棒（3 OOrpm )攪拌1小時後，以吉野紙過濾， 得到紅外線反射皮革塗料1〜4。 又’在紅外線反射皮革塗料3中係使用於硝化綿漆（ 玻璃轉移溫度：100°C以上）混合可塑劑（DOA )者作爲 樹脂成分。此玻璃轉移溫度約爲7(TC。 又，僅將材料變更成如下述表2所示般，其他係同一 做法’準備進行比較.硏究之比較塗料1、2。 [表2] 塗料1 塗料2 塗料3 塗料4 比較塗料1 比較塗料2 聚胺基甲酸酯樹脂 60 45 60 60 丙烯酸樹脂 20 硝·漆 30 30 紅外線反射黑色顔料A 5 4 4 5 4 無機白色顔料 2 1 1 黑色顏料A 5 水 35 35 15 35 醋酸乙酯 40 40 醋酸丁酯 20 25 DOA 5 交聯劑 20 實施例2 (具有紅外線反射功能之紅外線反射樹脂組成物） 使用以下之構成成分而製造具有本發明之紅外線反射 功能之紅外線反射樹脂組成物。 〈所使用之樹脂成分〉 ABS樹脂：TM 30(UMC. ABS 製） 聚丙烯樹脂：Novatech MA 3 (日本Polypro製） -19- 201130932 丙烯酸樹脂B : Delpet 60N (旭化成Chemicals製） 氯化乙烯樹脂：MT 1100 ( Vtech製）Solar flair 8 75 (Merck) CP black (French black carbon industry) carbon black (c. I. Name Pigment Black 7) TAROX R-516-L (titanium industrial) TAROX LL-XLO (titanium industrial system The average particle diameter of the infrared reflective pigment used and the number of reflectance peaks in the wavelength of 75 Onm to 2 600 nm are as shown in Table 1 below. [Table 1] Average particle size reflectance Infrared reflection Black pigment A 0.7 μ m 60% (1500 nm) Infrared reflection black pigment B 0.3 μ τη 60% (1500 nm) Inorganic white pigment 88% (1500 nm) Interference pigment - 85% ( 1500nm) Black pigment A — less than 5% (ΙδΟΟηιη) Black pigment B — less than 5% (1500nm) Red pigment A — 70% (1300nm) Yellow pigment B — 75% (1300nm) <Plastic used , cross-linking agent > plasticizer DOA (dioctyl adipate) cross-linking agent Elastron BN-1 1 (manufactured by Daiichi Kogyo Co., Ltd.) The above raw materials are prepared according to the ratio of each material shown in Table 2 below. It was prepared in a stainless steel container so that the total amount became 100% by weight. Further, -18-201130932 was stirred for 1 hour with a stirring dissolving rod (300 rpm), and then filtered with Yoshino paper to obtain infrared reflective leather coatings 1 to 4. Further, in the infrared reflective leather coating 3, a plasticizer (DOA) is used as a resin component in a nitrocellulose varnish (glass transition temperature: 100 ° C or higher). The glass transition temperature is about 7 (TC. Further, only the material is changed as shown in Table 2 below, and the other is the same procedure 'prepare for comparison. Compare the coatings 1 and 2. [Table 2] Coating 1 Coating 2 Coating 3 Coating 4 Comparison Coating 1 Comparison Coating 2 Polyurethane Resin 60 45 60 60 Acrylic Resin 20 Nitrole Paint 30 30 Infrared Reflecting Black Pigment A 5 4 4 5 4 Inorganic White Pigment 2 1 1 Black Pigment A 5 Water 35 35 15 35 Ethyl acetate 40 40 Butyl acetate 20 25 DOA 5 Crosslinking agent 20 Example 2 (Infrared reflecting resin composition having infrared reflection function) The infrared reflecting function of the present invention was produced by using the following constituent components. Infrared reflective resin composition. <Resin component used> ABS resin: TM 30 (manufactured by UMC. ABS) Polypropylene resin: Novatech MA 3 (manufactured by Polypro, Japan) -19- 201130932 Acrylic resin B: Delpet 60N (Asahi Kasei Chemicals) Vinyl chloride resin: MT 1100 (made by Vtech)
〈所使用之紅外線反射顏料 紅外線反射黑色顏料A 紅外線反射黑色顏料B 無機白色顏料 干涉顏料 黑色顏料A<Infrared Reflective Pigment Used Infrared Reflective Black Pigment A Infrared Reflective Black Pigment B Inorganic White Pigment Interference Pigment Black Pigment A
黑色顏料BBlack pigment B
紅色著色顏料A 黃色著色顔料B >Red coloring pigment A yellow coloring pigment B >
Bi-Cu系複合氧化物 偶氮甲亞胺系化合物 JR-1000 ( Teika製）Bi-Cu composite oxide azomethine compound JR-1000 (made by Teika)
Solar flair 8 7 5 ( Merck) CP黑色（五常產業（股）製碳黑 ) 碳黑（C. I. Name Pigment Black 7) TAROX R-516-L(鈦工業製） TAROX LL-XLO(鈦工業製） 在所使用之紅外線反射顔料的平均粒徑、波長75 Onm ~ 260 0nm中之反射率譜峯的數値係如以下之表3。 [表3] 平均粒徑 反射率 紅外線反射黑色顏料A 0.7 μ m 60% (1500nm) 紅外線反射黑色顔料B 0.3 μ m 60% (1500nm) 無機白色顏料 _ 88% (1500nm) 干涉顔料 — 85% (1500iun) 黑色顔料A 一 未達 5% (1500mn) 黑色顔料B _ 未達5% (1500nm) 紅色著色顔料A — 70% (I300nm) 黃色著色顔料B — 75% (1300nm) -20- 201130932 〈所使用之可塑劑、交聯劑〉 可塑劑 DOA (二辛基己二酸酯） 交聯劑 Elastr〇n BN-11 (第一工業製藥製） 使上述原料’依據下述表4所示之各材料的調配比率 ，以全量成爲100重量％之方式進行調整，使用押出機以 2 1 0 °C進行混練處理，製作紅外線反射樹脂卜4。又，僅將 材料變更成如下述表4所示般，其他係同一做法，準備進 行比較•硏究之比較樹脂1。 [表4] 樹脂1 樹脂2 樹脂3 樹脂4 比較樹脂1 ABS樹脂 70 70 聚丙烯樹脂 70 丙烯酸樹脂 78 氣化乙烯樹脂 80 紅外線反射黑色顔料A 30 25 紅外線反射黑色顔料B 20 白色無機顔料 5 干涉顔料 20 黒色顔料B 30 紅色著色顔料A 1 黃色著色顔料B 1 〈比較•硏究試驗〉 (試驗片之製作） 使塗料1〜4及比較塗料1、2噴塗塗裝於牛革（鉻制革 '尺寸1 Ocmxl 0cm )而製作試驗片。乾燥後之膜厚爲30μιη 。以樹脂1〜4及比較樹脂1所製作之樹脂組成物以沖壓機進 -21 - 201130932 行熱沖壓，製作試驗片。 (表面溫度測定） 從離試驗片30cm之處，照射紅外線燈（1 00V · 200W )，藉輻射溫度計（股份公司Custom製IR-3 03 )而測定試 驗片之表面溫度變化。表面溫度之測定結果表示於表5中 [表5] 表面溫度 試驗時間 (分） 塗料1 塗料2 塗料3 塗料4 樹脂1 樹脂2 樹脂3 樹脂4 比較 塗料 1 比較 塗料 2 比較 樹脂 X 0 25.9 26.1 26.0 26.7 25.0 25.4 26.0 25.4 26.5 25.7 24.0 1 39.0 37.1 35.8 38.0 34.0 33.4 29.0 28.4 58.0 36.0 47.5 2 44.1 42.5 44.0 45.0 42.0 44.0 38.1 37.5 70.2 43.5 50.5 3 50.7 61.6 50.3 49,5 52.3 52.0 45.9 43.1 80.6 50.4 65.7 4 54.0 52.3 54.0 55.4 55.7 68.0 50.1 48.0 85.1 53.1 65.9 5 68.9 65.4 57.0 58.7 59.8 62.0 52.4 61.4 88.5 56.7 73.4 10 61.5 58.0 60.2 61.4 60.7 65.4 58.7 57.1 90.5 59.4 83-4 30 64.0 63.5 63.5 65.0 64.0 68.0 65,0 62.0 91.8 62.4 88.7 60 70.0 66.7 69.9 69.4 70.0 71.5 70.8 69.5 93.0 68.0 90.0 (彎曲性試驗） 依JIS K6545 (革之耐_曲性試驗方法），試驗紅外 線反射皮革塗料之耐彎曲性。於塗膜以目視無法確認裂開 或龜裂者評估爲〇（合格），以目視可確認裂開或龜裂者 評估爲X (不合格）。 (密著性試驗） 依JIS K5 60 0-5 -6 (交叉切割法），試驗紅外線反射皮 •22- 201130932 革塗料之密著性。 彎曲性試驗、密著性試驗之結果如以下之表6 [表6] 彎曲性及密著性試驗結果 塗料1 塗料2 塗料3 塗料4 比較塗料1 比較塗料2 彎曲性 〇 〇 〇 〇 〇 ·—— . X 密著性 分類0 分類0 分類。 分類0 分類。 ~~ϋ"5 密著性試驗之評估（分類0~分類5 )係如以下。 分類0 切割之邊緣完全平滑，任一格子眼均無剝離。 分類1 在切割之交差點中的塗膜小之剝離。 在交叉切割部分受到影響係未明確地超過5%。 分類2 塗膜沿著切割之邊緣，及/或在交差點中剝離。 在交叉切割部分受到影響係雖明確地超過5%，但 未超過1 5 % ^ 分類3 塗膜沿著切割之邊緣，部分或全面地產生大剝離 ，及/或眼的各種部分於部分或全面地剝離。 在交叉切割部分受到影響係雖明確地超過1 5 %， 但未超過3 5 %。 分類4 塗膜沿著切割之邊緣，部分或全面地產生大剝離 ，及/或數處之眼部分或全面地剝離。在交叉切 割部分受到影響係明確地未超過3 5%。 分類5 於分類4亦無法分類之剝離程度的任一者。 如上述般，本發明之紅外線反射皮革塗料1與比較塗 -23- 201130932 料1係塗料1使用紅外線反射黑色顏料A，比較塗: 用黑色顏料A之點相異。兩者係於表5、表6之試 顯可知，在物理上的物性（表6)中無很大的相 關表面溫度之降低（表5 )係顯示很大的相異。 紅外線反射皮革塗料1者明顯地顯示表面溫度的1¾ 以上，說明本發明較佳之實施形態、實施例 明係不限定於如此之實施形態、實施例，從申請 之記載所把握的技術範圍中可變更成各種的形態 【圖式簡單說明】 圖1係表示對於本發明之塗料及比較例之塗 紅外線燈而進行之表面溫度變化的結果之圖表。 圖2係表示對於本發明之樹脂組成物及比較 組成物而照射紅外線燈而進行之表面溫度變化的 表。 圖3係說明於板或薄片狀之丙烯酸樹脂製品 發明之成型樹脂製品而成之複合品的一例之圖。 圖4係說明具有凹凸之丙烯酸樹脂製品、與 成型樹脂製品一體化的複合品之一例的圖。 斗1只在使 驗結果明 異，但有 本發明之 低。 ，但本發 專利範圍 料而照射 例之樹脂 結果之圖 ，張貼本 本發明之 -24-Solar flair 8 7 5 ( Merck) CP black (Cichang Industrial Co., Ltd.) carbon black (CI Name Pigment Black 7) TAROX R-516-L (manufactured by Titanium Industry) TAROX LL-XLO (titanium industrial system) The average particle diameter of the infrared reflective pigment used and the number of reflectance peaks in the wavelength range of 75 Onm to 260 0 nm are shown in Table 3 below. [Table 3] Average particle size reflectance Infrared reflection Black pigment A 0.7 μm 60% (1500 nm) Infrared reflection black pigment B 0.3 μm 60% (1500 nm) Inorganic white pigment _ 88% (1500 nm) Interference pigment - 85% ( 1500iun) Black pigment A less than 5% (1500mn) Black pigment B _ less than 5% (1500nm) Red pigment A - 70% (I300nm) Yellow pigment B - 75% (1300nm) -20- 201130932 Plasticizers and crosslinkers used> Plasticizer DOA (dioctyl adipate) Crosslinker Elastr〇n BN-11 (manufactured by Daiichi Kogyo Co., Ltd.) The above raw materials are made according to the following Table 4 The mixing ratio of the materials was adjusted so that the total amount became 100% by weight, and the mixture was subjected to kneading treatment at 2 1 0 °C using an extruder to prepare an infrared reflective resin. In addition, only the materials were changed as shown in Table 4 below, and the other methods were the same, and the comparison resin 1 was prepared for comparison. [Table 4] Resin 1 Resin 2 Resin 3 Resin 4 Comparative resin 1 ABS resin 70 70 Polypropylene resin 70 Acrylic resin 78 Gasified vinyl resin 80 Infrared reflection black pigment A 30 25 Infrared reflection black pigment B 20 White inorganic pigment 5 Interference pigment 20 颜料Color pigment B 30 Red coloring pigment A 1 Yellow coloring pigment B 1 <Comparison • Studying test> (Production of test piece) Spray coatings 1 to 4 and comparative paints 1 and 2 on cow leather (chrome leather size) A test piece was prepared by 1 Ocmxl 0 cm). The film thickness after drying was 30 μm. The resin composition prepared from the resins 1 to 4 and the comparative resin 1 was hot-pressed in a press machine at -21 - 201130932 to prepare a test piece. (Measurement of surface temperature) From the place where the test piece was 30 cm, an infrared lamp (100 V · 200 W) was irradiated, and the surface temperature change of the test piece was measured by a radiation thermometer (IR-3 03 manufactured by the company). The surface temperature measurement results are shown in Table 5 [Table 5] Surface temperature test time (minutes) Coating 1 Coating 2 Coating 3 Coating 4 Resin 1 Resin 2 Resin 3 Resin 4 Comparative Coating 1 Comparative Coating 2 Comparative Resin X 0 25.9 26.1 26.0 26.7 25.0 25.4 26.0 25.4 26.5 25.7 24.0 1 39.0 37.1 35.8 38.0 34.0 33.4 29.0 28.4 58.0 36.0 47.5 2 44.1 42.5 44.0 45.0 42.0 44.0 38.1 37.5 70.2 43.5 50.5 3 50.7 61.6 50.3 49,5 52.3 52.0 45.9 43.1 80.6 50.4 65.7 4 54.0 52.3 54.0 55.4 55.7 68.0 50.1 48.0 85.1 53.1 65.9 5 68.9 65.4 57.0 58.7 59.8 62.0 52.4 61.4 88.5 56.7 73.4 10 61.5 58.0 60.2 61.4 60.7 65.4 58.7 57.1 90.5 59.4 83-4 30 64.0 63.5 63.5 65.0 64.0 68.0 65,0 62.0 91.8 62.4 88.7 60 70.0 66.7 69.9 69.4 70.0 71.5 70.8 69.5 93.0 68.0 90.0 (Flexibility test) The bending resistance of the infrared reflective leather coating was tested in accordance with JIS K6545 (Resistance test method for leather resistance). The coating film was visually incapable of confirming cracking or cracking and was evaluated as 〇 (passed), and visually confirmed that cracking or cracking was evaluated as X (failed). (Adhesion test) According to JIS K5 60 0-5 -6 (cross-cut method), test infrared reflective skin • 22- 201130932 The adhesion of leather paint. The results of the bending test and the adhesion test are shown in Table 6 below [Table 6] Bending and adhesion test results Coating 1 Coating 2 Coating 3 Coating 4 Comparison Coating 1 Comparison Coating 2 Flexibility 〇〇〇〇〇 · — . X Adhesive Classification 0 Classification 0 Classification. Category 0 classification. ~~ϋ"5 The evaluation of the adhesion test (category 0 to category 5) is as follows. Category 0 The edges of the cut are completely smooth and there is no peeling of any of the grid eyes. Classification 1 Small peeling of the coating film in the intersection of the cuts. The affected part in the cross-cutting section did not explicitly exceed 5%. Classification 2 The film is peeled off along the edge of the cut and/or at the intersection. Although the affected part in the cross-cutting part is clearly more than 5%, but not more than 15% ^ Classification 3 The coating film along the edge of the cut, partially or comprehensively produces large peeling, and/or various parts of the eye are partially or comprehensively Stripping. The affected part in the cross-cutting section is clearly more than 15%, but not more than 35%. Classification 4 The film is partially or fully produced along the edge of the cut, and/or the eye is partially or fully peeled off. The affected part of the cross-cutting section clearly did not exceed 35%. Category 5 Any of the degree of divestiture that cannot be classified in Category 4. As described above, the infrared-reflective leather coating 1 of the present invention and the comparative coating -23-201130932 material 1-based coating 1 use infrared-reflecting black pigment A, and are comparatively coated: the points of the black pigment A are different. Both of them are shown in Tables 5 and 6. It is known that there is no significant decrease in the relative surface temperature (Table 5) in the physical properties (Table 6) which shows a large difference. The infrared reflective leather coating material clearly shows a surface temperature of 13⁄4 or more, and the preferred embodiments and examples of the present invention are not limited to the embodiments and examples, and may be changed from the technical scope of the application. Various forms [Simplified description of the drawings] Fig. 1 is a graph showing the results of surface temperature changes of the paints of the present invention and the coated infrared lamps of Comparative Examples. Fig. 2 is a table showing changes in surface temperature by irradiation of an infrared lamp with respect to the resin composition and the comparative composition of the present invention. Fig. 3 is a view showing an example of a composite product of a molded resin product of the invention of a sheet or a sheet of an acrylic resin product. Fig. 4 is a view showing an example of a composite product having an uneven acrylic resin product and a molded resin product. Bucket 1 only shows the results of the test, but it is low in the present invention. , but the scope of the patent and the results of the resin of the illuminating example, the present invention -24-
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| JP (1) | JPWO2011048913A1 (en) |
| CN (1) | CN102575128A (en) |
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| TWI586858B (en) * | 2015-05-29 | 2017-06-11 | 台虹科技股份有限公司 | Infrared reflective fiber and infrared reflective fiber manufacturing method |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2013006897A (en) * | 2011-06-22 | 2013-01-10 | Agc Coat-Tech Co Ltd | Heat ray highly reflective paint composition, kit for preparing heat ray highly reflective paint composition, heat ray highly reflective coated article, and coating method of heat ray highly reflective coated article |
| JP2013006898A (en) * | 2011-06-22 | 2013-01-10 | Agc Coat-Tech Co Ltd | Heat ray highly reflective paint composition, kit for preparing heat ray highly reflective paint composition, heat ray highly reflective coated article, and production method of heat ray highly reflective coated article |
| JP5687155B2 (en) * | 2011-08-11 | 2015-03-18 | 神東塗料株式会社 | Quick-drying thermal barrier coating composition |
| JP6267016B2 (en) * | 2014-03-07 | 2018-01-24 | 東洋紡株式会社 | Synthetic leather |
| JP6346873B2 (en) * | 2015-06-08 | 2018-06-20 | 株式会社クラレ | Artificial leather |
| CN106283708A (en) * | 2016-09-12 | 2017-01-04 | 福建华阳超纤有限公司 | A kind of production technology of the refrigerant superfine fiber chemical leather of aqueous |
| CN106755626A (en) * | 2016-11-30 | 2017-05-31 | 海宁森德皮革有限公司 | A kind of automotive leather production technology for having infrared heat reflection cooling function |
| EP3578613B1 (en) * | 2018-05-17 | 2025-11-26 | Canon Kabushiki Kaisha | Article including film, optical apparatus, coating material, and method for producing article |
| WO2020008341A1 (en) * | 2018-07-03 | 2020-01-09 | 3M Innovative Properties Company | Infrared reflective wrap film |
| CN110028776A (en) * | 2019-04-23 | 2019-07-19 | 福建宝利特科技股份有限公司 | A kind of antifouling solvent-free artificial leather |
| CN112604522A (en) * | 2020-11-27 | 2021-04-06 | 邢台职业技术学院 | Preparation device and preparation method of energy-saving environment-friendly building material |
| JP7610469B2 (en) * | 2021-06-04 | 2025-01-08 | 株式会社クラレ | Leather-like sheet |
| CN118773924A (en) * | 2023-04-10 | 2024-10-15 | 北京车和家汽车科技有限公司 | Surface material, artificial leather, vehicle component, vehicle and method for producing artificial leather |
| CN118910900B (en) * | 2024-08-22 | 2025-08-08 | 思嘉环保材料科技（上海）有限公司 | A near-infrared high-reflection PVC material and its preparation method |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3180230B2 (en) * | 1992-05-14 | 2001-06-25 | セーレン株式会社 | Method for producing colored suede-like synthetic leather |
| JP3180238B2 (en) * | 1993-07-26 | 2001-06-25 | セーレン株式会社 | Leather-like sheet |
| JP3464822B2 (en) * | 1994-05-31 | 2003-11-10 | 三洋化成工業株式会社 | Aqueous resin dispersion composition and method for producing synthetic leather |
| JP3441253B2 (en) * | 1995-08-21 | 2003-08-25 | 株式会社クラレ | Artificial leather with a black grain surface layer with little stuffiness |
| JPH10279879A (en) * | 1997-04-10 | 1998-10-20 | Kanegafuchi Chem Ind Co Ltd | Aqueous matting agent composition |
| JP2001122044A (en) * | 1999-10-22 | 2001-05-08 | T S Tec Kk | Interior lining for vehicle |
| EP1127926A1 (en) * | 2000-02-22 | 2001-08-29 | Nippon Paint Co., Ltd. | Heat radiation shield coating composition |
| JP3513149B1 (en) * | 2000-02-22 | 2004-03-31 | 日本ペイント株式会社 | Heat shield |
| DE10038381A1 (en) * | 2000-08-07 | 2002-02-28 | Gerd Hugo | Flat arrangement with dark surface and low solar absorption |
| AU2002307625A1 (en) * | 2002-03-08 | 2003-09-22 | Cueros Industrializados Del Bajio | Method of incorporating heat-stable particles into leather |
| JP4040895B2 (en) * | 2002-03-27 | 2008-01-30 | アキレス株式会社 | Polyurethane urea foam sheet and synthetic leather using the sheet |
| JP4203267B2 (en) * | 2002-06-11 | 2008-12-24 | 日本ペイント株式会社 | Heat shielding paint and coating film forming method using the same |
| JP2005097462A (en) * | 2003-09-26 | 2005-04-14 | Kansai Paint Co Ltd | Coloring paint having heat blocking property and method of forming coating film |
| JP3767826B2 (en) * | 2004-02-26 | 2006-04-19 | 大日本インキ化学工業株式会社 | Leather-like sheet manufacturing method |
| JP2008184603A (en) * | 2007-01-31 | 2008-08-14 | Soft99 Corporation | Coating composition for leather |
| JP5285307B2 (en) * | 2008-03-07 | 2013-09-11 | 石原産業株式会社 | Black pigment and method for producing the same |
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