TW201214045A - Coloring composition, color filter, and display element - Google Patents

Abstract

The present invention provides a coloring composition having excellent heat-resistance and comprising coloring agent. The coloring composition comprises (A) coloring agent, (B) binder resin and (c) cross-linking agent. The coloring composition comprises coloring agent represented by following formula (1) as (A) coloring agent. X+Z- (1) [In formula (1), X+ represents cationic chromophore, Z- represents conjugated base of organic acid having halogenated hydrocarbon group.]

Description

201214045 VI. Description of the Invention: [Technical Field] The present invention relates to a coloring composition, a color filter, and a display element, and more particularly to a color suitable for use in a transmissive or reflective type. a liquid crystal display element, a solid-state imaging element, an organic EL display, a color filter of a color filter such as an electronic paper, a coloring composition containing the coloring agent, a color light-emitting sheet including a coloring layer containing the coloring agent, And a display element having the color filter. [Prior Art] When a color filter is produced using a coloring-sensitive radioactive composition, a method (Patent Documents 1 to 2) is known, which is dried by applying a pigment-dispersed color-sensitive radioactive composition on a substrate. Thereafter, the dried coating film is irradiated (hereinafter referred to as "exposure") with radiation to obtain a desired pattern and developed to obtain pixels of respective colors. Further, a method (Patent Document 3) is known in which a black matrix is formed by using a photopolymerizable composition obtained by dispersing carbon black. Further, there is also known a method (Patent Document 4) which obtains pixels of respective colors by an ink jet method using a pigment dispersion type coloring resin composition. In order to achieve high brightness of the display element, high color purity, or high definition of the solid-state imaging element, it is known that it is effective to use a dye as a colorant. For example, Patent Document 5 proposes to disclose a triarylmethane dye using a specific structure. [PATENT DOCUMENT] [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei No. Hei. No. Hei. No. Hei. No. Hei. [Problems to be Solved by the Invention] However, the triaryl decane-based dye disclosed in Patent Document 5 is disclosed in JP-A-2008-304766. The heat resistance is insufficient, and the superiority of the chromaticity characteristics of the pigment disappears after a step of heating (post-baking) higher than 20 (r exposure), and it is strongly required to develop a kind due to the above responsibilities. A dye having excellent heat resistance / ^ Therefore, the object of the present invention is to provide a coloring composition containing a coloring agent which is excellent in heat resistance. Further, the object of the present invention is to provide a coloring layer formed using the coloring composition. The color filter and the display element including the color filter. [Means for Solving the Problem] As a result of intensive studies by the inventors, it has been found that the problem is solved by including the test dye 'month b'. The dye is a co-base having an acidity stronger than that of a normal sulfonic acid as an anion. That is, the present invention provides a coloring composition containing (A) a colorant and (B) a binder. The colored composition of the resin and (c) a crosslinking agent, wherein the coloring agent represented by the following formula (1) (hereinafter also referred to as "the present coloring agent") is contained as the coloring agent (A). Χ+Ζ· (1) · 匕 (1) 'Χ + indicates a cationic chromophore, and ζ• indicates a total test of the organic acid of the chemical base.] 1 The present invention is represented by the following formula (la) An anion or an anion represented by the following formula Ub) is preferred. (la) 201214045 R1—so- [in formula (la), ri 矣 _ ^ Λ ^ ', clothing may also have eyebrows &, + R2—so2^ containing carbon atoms, hydrogen atoms and prime atoms Linkage group i-hydrocarbyl].

Ob) [In the formula (lb), Han 2 in the $ ^ ^ n 糸 independently of each other may also have carbon atoms

The ruthenium atom and the methine group of the atomic group of the atom other than M '1 may be mutually known to form a ring. Further, the present invention is intended to provide a color layer formed by using the above-mentioned coloring composition, _, y. / color light film, and having the color filter. Pieces. Here, the "color layer of the sleeve n m" means a color, a black matrix, a black spacer, or the like, which is used for color filter. [Effect of the Invention] The heat is very excellent. The coloring layer containing the coloring agent of the present invention can be formed into a coloring layer which maintains the chromaticity characteristics of the granules of the present invention even when subjected to a high-temperature heating step. Therefore, *, 士*·** a 3 makes the coloring composition of Fengshui toner very suitable for the color filter for color separation of color liquid crystal display elements and solid-state shadow 7G parts. Various color filters including color filters for organic EL display elements and color filters for electronic papers. This colorant is also suitable for coloring of plastic molded articles, coloring agents for inkjet inks, and private colors. A coloring agent for carbon powder (c〇l〇rt〇ner), a coloring agent for an electric display element, and the like. [Embodiment] [Mode for Carrying Out the Invention] Hereinafter, the present invention will be described in detail. The halogen R2 is also used for the coloring of the film. Swim 201214045 [Coloring composition] Hereinafter, the constituent components of the coloring composition of the present invention will be described in detail. - (A) Coloring agent - The coloring composition of the present invention is characterized in that the coloring agent represented by the above formula (1) is used as the coloring agent (A). The present colorant is a compound having a maximum molar absorption coefficient in the visible light region (38 〇 nm to 78 〇 nm) of usually 3, _ or more and a triaryl group known as a photoacid generator which generates an acid by absorbing ultraviolet rays. The 铳 is equal. <Dish First, Z· in the formula (1) will be described. As long as the Z system has a toothed Meiqi _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _S〇3H), continued imiline (_s〇2Nhs〇2_) and the like. It is presumed that the inventors of the present invention can enhance the heat resistance by introducing a light base having a higher acidity as an anion portion by a coloring agent which is colored as a chromophore. mix water with clay,,,. Specific examples of the force-k-to-knit toner Z- can be exemplified by the lower formula, (b), +, hopper, W 1 U, Μ + 八 (1 a) Indicates anion and the like. (la) r2-s〇2-n_-S02sR2 (lb) Next, 2 illustrates the definition of the symbols in the formula (la) and the formula (lb). R and R are examples of a tetrahydrogen atom and a dentate hydrocarbon group which may have an atom other than a carbon atom. For example, the meat α which is a skeleton of the yam and the yttrium may be, for example, an aliphatic hydrocarbon (1). 3) having an alicyclic hydrocarbon group as () an aliphatic hydrocarbon group as a substituent, an aliphatic hydrocarbon group as a substituent (hereinafter referred to as 201214045 2-ring type halogen-substituted aliphatic nicotine group), and (4) an aromatic nicotyl group having an aliphatic hydrocarbon group as a substitution The base family furnace defeats the earthy aromatic hydrocarbon group (hereinafter referred to as "fat moon base"), and (6) has an aromatic hydrocarbon group as a substituent smoke group (hereinafter (4) "aromatic hydrocarbon substituted aliphatic hydrocarbon group" The solution: The hydrocarbon group of the skeleton constituting the structure is preferably the following characteristic group from the viewpoint of the bathing property to the organic solvent. That is, in the case of the above (1) aliphatic hydrocarbon group, an alkyl group is preferred, and a hydrazine r is preferably 1 2 fluorene, particularly preferably 1 to 8. Further, in the case of the above (2) lipid bis group, an alicyclic saturated hydrocarbon group is preferred, and the carbon number is preferably ,: preferably 3 to 12. Further, the above (3) alicyclic hydrocarbon is substituted for the ruthenium aliphatic hydrocarbon group, and the alicyclic saturated hydrocarbon is preferably substituted for the alkyl group. The straight total carbon: preferably 4 to 20, and 6 to Μ Very good. Further, in the above (4); the hydrocarbon group and the s, the carbon number is 6 to 14 (more preferably, the carbon number is 6 to oxime), and the = group is particularly preferred. Further, the above (5) aliphatic hydrocarbon-substituted aromatic smog group is preferably an alkyl-substituted phenyl group, and the total carbon number is preferably 7 to 30%, and particularly preferably 20 or 20. Further, the above aromatic hydrocarbon is substituted for the aliphatic hydrocarbon. The aralkyl group is preferred, and the total carbon number is preferably 7 to 3 Å, and particularly preferably 720. Further, the alkyl group in this paragraph may be linear or branched. In the case of the hydrocarbon group of the skeleton of the crumb 2 and the crumb, the aliphatic hydrocarbon group is replaced by (3) an alicyclic hydrocarbon, (4) an aromatic = a hydrocarbon group, and (5) a fat. The hydrocarbon-substituted aromatic hydrocarbon group or the (6) aromatic hydrocarbon is preferably substituted for the sulphur-free hydrocarbon-free group, and the alkyl group, the alicyclic saturated hydrocarbon is substituted for the alkyl group, the phenylalkyl group is substituted with the strepyl group, and the aralkyl group is more preferably. It is particularly preferred to use an alkyl group. Further, in the formula (1b), R2 may be bonded to each other to form a divalent hydrocarbon group. 201214045 'Improved from the organic acid colored as a substituent, and the total R1 and R2 of the carbon moiety, the so-called carbon moiety, and the base of the acid formation are again, and in R1 and R2, _

The viewpoint of the heat resistance of the halogen in the G-based group is determined by IA by selecting fluorine, because the anionic portion of the toner becomes a stronger acidity (4), which is considered to be capable of forming an ion bonding force. The heat of the salt. Now, 'in Ri and R2', a linking group containing a carbon atom or an atom other than an atomic atom can be exemplified by _〇_, _s_-C.OO-, -CONH-, _SfK stem-C·^S 〇2-4. Further, in the preceding paragraph, the number of carbons after removing the carbon number constituting the linking group is shown. In the present invention, from the viewpoint of heat resistance of the coloring agent, it is preferably a group represented by the following formula (丨-^ or ^^), and the following formula of the conjugate base of the organic acid having higher degree of properties is preferable. (丨_丨) is particularly good.

(1-1) [In the formula (1-1) ' represents a hydrogen atom, a fluorine atom, an alkyl group, a fluorinated alkyl group, an alicyclic hydrocarbon group, an alkoxy group, a fluorinated alkoxy group, R2〇C〇〇 R21_ or K2()C00R21CFH_(R2() is an alkyl group, an alicyclic hydrocarbon group, a heteroaryl group or a substituted or unsubstituted aryl group, R21 represents a methylene group or an alkylene group), and η represents the above integer , "*" indicates the dangling key]

(1-2) 201214045 [In the formula (1_2), Rl4 to Rl8 independently represent a hydrogen atom, a fluorine atom, a trans group, an alkyl group, a fluorinated alkyl group or an alkoxy group, and "*" means a dangling bond' However, at least i of R14 to R18 is a fluorine atom or a fluorinated alkyl group]. In the formula U-1), in the case of R19, it is a gas atom, a gasification base, a fat king coat; a base, a fluoride oxy group, a r2〇c〇〇r21 or a r2〇c〇〇R21CFH- Preferably, it is particularly preferably a fluorine atom, an alicyclic hydrocarbon group, a perfluoroalkoxy group, R20COOCH2CH2- or R20CO〇CH2CH2CFH-. R20 represents an alkyl group, an alicyclic hydrocarbon group, a heteroaryl group or a substituted or unsubstituted aryl group, and the alkyl group may be a linear chain or a branched chain, and the carbon number of the alkyl group is more Jia is 丨 ~ 8) is better. The alicyclic hydrocarbon group is preferably a 2 to 4 ring crosslinked alicyclic hydrocarbon group, and the alicyclic hydrocarbon group preferably has a carbon number of 3 to 20 (more preferably 3 to 12). The heteroaryl group is preferably a group consisting of an aromatic heterocyclic ring containing 5 to 10 members of a hetero atom selected from a nitrogen atom, an oxygen atom and a sulfur atom. In the case of an aryl group, an aryl group having a carbon number of 6 to 14 (more preferably a carbon number of 6 to 10) is preferred, and a stupid group is particularly preferred. Further, examples of the substituent include an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a halogen atom or a trifluoromethyl group, and the position and number of the substituent are arbitrary 'having 2 In the case of more than one substituent, the substituents may be the same or different. Further, R21 represents a methylene group or an alkylene group, and is preferably an anthracene group or an alkylene group having 2 to 6 carbon atoms. In terms of ease of production, it is particularly preferable to extend ethyl groups. Further, the upper limit of η is preferably 10, and more preferably 8. Further, in the formula (Bu 2), at least 3 of R14 to Ri8 is preferably a fluorine atom or an iodine group. Further, it is also preferable to form a vaporized stretching group by bonding with each other between the formulas (2) and R2, particularly to form a perfluoroalkylene group. In the case of the representative example of the anion represented by the above formula (丨-^ or (1-2), for example, an anion represented by the following compound group a and the compound group b can be given. [Compound group a]

CF3SO3" C4F9SO3' C8F17S03· C2F5OC2F4SO3· F3C iPVcFa όμΎ% όβΎ%

CF2, CF strict 3·

〇3S

F F CF2CF2S〇3'

0-Π〇ί2^25

F

•〇3S O~cf3 -10- 201214045 [Compound group b]

The X + is not particularly limited as long as it is a cationic chromophore, that is, a cation which forms a basic coloring agent in the form of Χ + Ζ ·, and examples thereof include a triaryl arsenic chromophore and a sulfhydryl group ( Methine) is a chromophore, an azo chromophore, a diarylmethane chromophore, a quinone imine chromophore, a quinone chromophore, a phthalocyanine chromophore, a dibenzopyran (X anthene) is a chromophore and the like. The above triaryl chromophore is preferably represented by the following formula (2). The cation system represented by the following formula (2) has various resonance structures -11 - 201214045

When the cation represented by each formula is used in the specification, it is considered to be equivalent to the cation represented by the formula. /,, (2) [In the formula (7), the hydrazine hydrocarbon ring of the 'r3' and the r4 are mutually independent of each other, and represent the chlorine atom or the alkyl group of the number 8, and the chlorine atoms and the slave numbers i to 8 are independently expressed by the heart. The alkyl group or the phenyl 'R7 group represents a hydrogen atom or a carbon number: a group: C〇〇R: (R' represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms) or a gas source 2 and 8 ^ is an alkyl group independently representing a hydrogen atom or a carbon number of 丨8, or a sulfur atom, and an R" The hydrogen atom, the carbon number of 1 to 8 are independently indicated, and the gas atom is represented by a hydrogen atom or a group represented by the following formula (3).

R

N (3) 13

R

[In the formula (3) 'R1R" is a hydrogen atom or an alkyl group having a carbon number independently of each other. The aromatic hydrocarbon ring of the fluorene is preferably an aromatic hydrocarbon ring having 6 to 20 carbon atoms (more preferably 6 to 10 carbon atoms), and specific examples thereof include a benzene ring, a naphthalene ring, a biphenyl ring and an anthracene ring. R to R丨丨 of the above formula (2) (R containing _c〇〇R of R7), and an alkyl group of 8 and 2 of the above formula (3) For example, -12-201214045 can be used to give methyl, ethyl, propyl, isopropyl, butyl, t-butyl-butyl, isobutyl, decyl, tert-pentyl, hexyl, g. Base, octyl: isooctyl, trioctyl, 2-ethylhexyl and the like. In the present invention, the viewpoint of the degree of lift and color purity in the % ion of the above formula (2) is particularly good as the cation represented by the following formula _ ( (4) 〇

R3 [In the formula (4)', R3, Μ, R5, R6, Ru and Rl3 are synonymous with R3, R4, R5, R6' R12 and Rl3 of the above formulas (2) and (3). In the above (4)', in the case of R3, R4, R2, and the ruler 3, an alkyl group having a carbon number of 8 (more preferably, a carbon number of i to 6) is preferable, and in the case of R5, Preferably, the alkyl group or the phenyl group having a carbon number of 1 to 8 (more preferably, the carbon number is 6) is an alkyl group having a number of 1 to 8 (more preferably a carbon number of -6 to 6). Hydrogen atoms are preferred. In the representative example of the cation represented by the above formula (2), for example, a cation represented by the following compound group c and the compound group d is present, and "the compound C2, the compound c3, and the compound" are preferable. .

S -13- 201214045 [Compound group c ]

Compound c3

[Compound group d]

-14- 201214045

(5-1) The above-mentioned methine chromophore is preferably represented by the following formula (5_1} to (5_3). r36 Ra

(5-2) (5-3) [In the formulae (5-1) to (5-3), R31 represents a hydrogen atom or a _ atom, and R33, R34 and R35 represent carbon numbers independently of each other]~ 6 alkyl, R36 represents a substituted or unsubstituted burnt number of 1 to 6, a lanthanide -CH = CH-, -CH = CH-NR37- (R37 hydrogen atom or a carbon number 1-6 alkyl) , /CH=N-NR37- (R37 is synonymous with the above) or -N=N-NR37- (R37 is synonymous with the foregoing), and Ra is a substituted or unsubstituted aromatic hydrocarbon group or substituted or unsubstituted Heterocyclic group]. In the case of Ra, it is preferred to use a group represented by the following formulas (5a) to (5g).

[In the formulae (5a) to (5g), R38 and R45 each independently represent a carbon number of the alkyl group] R39 represents a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, and R42 • 15 - 201214045, R43 And R44 independently of each other represent a hydrogen atom or a carbon number of 1' and R46 which independently represent a hydrogen atom, a dentate atom, an alkoxy group, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, a nitrate or a cyano group. ]. The substituent of the above alkyl group may, for example, be a halogen or a trans group. The cation represented by the above formula (5-1) to (5-3) may be a cation represented by the following compound group e. a group of -6, R41, a carbon number of 1 to 6, a hydroxyl group, an atom, a cyano group, for example, -16 - 201214045 [compound group e]

Cl

Compound el compound e2 compound e3

^C2H5 c2h4cn

Compound e7 compound e8

Compound elO

Compound el5

17 201214045 The above azo chromophore is preferably represented by the following formulas (6-1) to (6-6).

[In the formulae (6-1) to (6-6), R51, R52, R53, R54, R55 and R57 each independently represent a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, and R56 and R6Q are each other. Independently, it represents a hydrogen atom, a halogen atom, a C1-C6 alkyl group, a C1-C6 alkoxy group, a nitro group, a hydroxyl group or a cyano group, and R58 represents an alkyl group having 1 to 6 carbon atoms, and R59 represents A 4-stage ammonium group is formed, and Rb represents a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted heterocyclic group]. In the above R59, -NRHCmHhN + RWR^R6, !!! is an integer of 1 to 5, and R61 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and R62, R63 and R64 are independently represented by each other. Alkyl group having 1 to 6 carbon atoms, -COCmH2mN + R62R63R64 (r, R62, R63 and R64 are synonymous with the above) -18- 201214045, _CmH2mN (NH2)R74R75 (m is synonymous with the foregoing, ruler" and R system are mutually Independently representing an alkyl group having 1 to 6 carbon atoms, or a formula (6-i) or (6-fluorene)

The basis of the table is good D

[In the formulae (6_i) and (6-ii), R61 and m are synonymous with the above]. The above 11 is preferably a substituted or unsubstituted stupid group represented by the following formulas (6a) to (6e).

Base

[In the formulae (6a) to (6d)', R65 represents a hydrogen atom, an alkyl group having a carbon number of 6, a phenyl group, or a benzyl group, and R06 represents a hydrogen atom or a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms. R67 is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a phenyl group, R68 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and R69 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. R to R73 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having a carbon number, a nitro group, a hydroxyl group or a cyano group. -19-201214045 The substituent of the above alkyl group may, for example, be a halogen atom, a hydroxyl group, a cyano group or a -conh2 group. The substituent of the phenyl group may, for example, be a halogen atom, a carbon group having 1 to 6 carbon atoms, a oxy group having 1 to 6 carbon atoms, a trans group, a cyano group or a nitro group. Representative examples of the cation represented by the above (6-1) to (6-6) include, for example, a cation represented by the following compound group f or compound g. -20- 201214045 [Compound group f]

Compound ill

C2H4OH

Compound f!3

Compound f!8 201214045

[Compound group g] (H3C}, NH2CC0-<Q>-IS

y-NHC2H4CNbi (H3C)3*NH2CC〇-^ n=n—^ nhc2h4cn (h3c)3*nh2cco-^^-n= c2h4cn (H3C)3+NH2CCO^Qy-N=N^^_N|C2H5 c2h5 ( H3c)3+nh2cco^^h

O2r*

Ci 02h

Cl o2n

/=\ c2H5 N fc2H4N+{CH3)3 p2^5 C2H4N+(CH3)2 nh2 p2^5 si fc2H4N+(CH3)3

02

O^1 xy- p2^s ^ )~N ^ fc2H4N+(CH3)3 /=\ P2h5 N C2H4N+(CH3)3

M=N

P2H5 sl C2H4N+(CH3)3 Compound gl Compound g2 Compound g3 Compound g4 Compound g5 Compound g6 Compound g7 Compound g8 Compound g9 Compound glO Compound gll Compound gl2 Compound gl3 22- 201214045 For the above diaryl chromophore, the following It is preferred that the expression (7-1) or (7-2) is expressed.

(7-1), 86

'R' R 88 ,89 [In the formulae (7-1) and (7-2), R81, R82 and R89 are mutually independent of each other to represent the carbon number] to 6 alkyl groups, r85, R9〇 and R9! The representative example of the cation represented by the above formula (7_υ to (7-2)), which is a hydrogen atom or a carbon number of the carbon number W, is exemplified by the group of compounds h shown below. Group h]

The above quinone imine chromophore is preferably represented by the following formula (8-1) to (8_3)\. . R101

R Ν' 111 112 -23- 201214045

[In equations (8-1) to (8-3), R101, R1. 2, R1. 3, R104, R105, R

R108, R109, R110, Rl11, R114, R1 丨5, R116, R117& R are each independently a hydrogen atom, a substituted or unsubstituted carbon number of 1 to 6, and an alkoxy group having 1 to 6 carbon atoms. , phenyl or benzyl, R 1 () 7 and R 113 each independently represent an alkyl group having 1 to 6 carbon atoms or an aryl group having 6 to 20 carbon atoms, and R 112 卞 111191112 () (11119 and 1112 () are independent of each other. The ground represents an alkane having a carbon number of 1 to 6, a hydroxyl group, a nitro group or a cyano group, and Q represents an oxygen atom or a sulfur atom. Examples of the substituent of the above alkyl group include a halogen atom, a hydroxyl group, and a cyano group. Representative examples of the cation represented by the above formulas (8-1) to (8-3) include, for example, a cation represented by the following compound group i. 1 06 118 Burning phase system base -24- 201214045 [Compound group i]

Ν^α

Compound i4 c2h4cn

C2nr

Compound i7 Compound i8 The above oxime chromophore is preferably represented by the following formula (9-1) or (9-2). 0 NHR131 Ο NHR135

25- 201214045 [In the formulae (9-1) and (9-2), Rm, r135 and r136 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, or a substituted or not Substituted phenyl, R132, R133, Rl34, Rl38, Rl3^Ri4. The alkyl group having 1 to 6 is independently represented by each other, and R1" represents a methylene group or a substituted or unsubstituted alkylene group. The substituent of the above-mentioned alkyl group or phenyl group is exemplified by a carbon number of 1 to And a halogen group, a halogen atom, a hydroxyl group, a cyano group, etc. Further, the substituent of the above-mentioned extended group may be a hydroxyl group, a cyano group or a nitro group, etc., and the above formula (9-1) or (9) -2) Representative examples of the cations indicated are, for example, cations represented by the following compound groups. [Compound group j]

The phthalocyanine chromophore is preferably represented by the following formula (1 〇).

CuPC-T (10) [In the formula (10)', the CuPc system represents a copper phthalocyanine residue, and the T system represents a group represented by the following formula (10a) or (10). -26- 201214045 R151 —(cmH2mN+CmH2mN+R153R15V55 )

\ ^152 /P (10a)·——^S02NHCmH2mN+R156R157R158 ), (10b) [In the formulas (10a) and (10b), R1", R152, R153, R154, R155, Ri56, R15 7 and R15 8 are mutually The hydrogen atom, the alkyl group having 1 to 6 carbon atoms, or the phenyl 'p group independently of each other represent an integer of 2 to 8, and the m system is synonymous with the above.] A representative example of the cation represented by the above (10) For example, a cation represented by the following compound group k can be mentioned. [Compound group k] ch3

CuPC-[ CH2N+C3H6N+(CH3)3 ] 2 2C1' CuPC-j~S02NH+C3H6N+(CH3)3 jp. p'Cl. CH3 p,=2-3 compound k2 compound kl on the above one In the case of a chromophore, it is preferred to be represented by the following formula (1 1 ).

[In formula (11), R159, R16. Further, 1^61 and Rl62 each independently represent a hydrogen atom, -R1 66 or an aromatic hydrocarbon group having 6 to 10 carbon atoms. However, the hydrogen atom contained in the aromatic hydrocarbon group may be substituted by a halogen atom, -Ri66, _〇H, -OR166, -S03H, -S03M, -C02H, -C02R166, -S03R166, -so2nhr167 or -so2nr167r168. . -27- 201214045 R163 and R164 each independently represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms. R165 represents -so3h, -so3m, -C02H, -co2r166, -so3r166, -so2nhr167 or -S02NR167R168. • q is an integer from 0 to 5. When q is an integer of 2 or more, the plural R165 systems may be the same or different. R166 represents a saturated hydrocarbon group having a carbon number of 1 to 1 Torr. However, the hydrogen atom contained in the saturated hydrocarbon group may be substituted by a halogen atom, and the methylene group contained in the saturated hydrocarbon group may be substituted by an oxygen atom, a carbonyl group or -NR166-. R167 and R168 independently of each other represent a linear or branched alkyl group having a carbon number of 1 to 1 Å, a cycloalkyl group having a carbon number of 3 to 30 or -Q, or a combination of R167 and R168, which are bonded to each other. A heterocyclic group having 1 to 10 carbon atoms. However, the hydrogen atom contained in the alkyl group and the cycloalkyl group may be substituted by a radical, a halogen atom, _q, _CH=C Η 2 or -CH=CHR166, and the alkyl or naphthene may be substituted. The fluorene group contained in the group may be substituted by an oxygen atom, a carbonyl group or _NR166-, and the hydrogen atom contained in the heterocyclic group may be substituted by -r166, _〇H or -Q. The lanthanide represents a sodium atom or an unloading atom. The Q system represents an aromatic hydroxyl group having 6 to 10 turns or an aromatic heterocyclic group having 5 to 1 carbon atoms. However, the hydrogen atom contained in the aromatic hydrocarbon group and the aromatic heterocyclic group may be substituted by _〇H, r166, -〇r166, _n〇2, _ch = CH2, -CtKHR166 or a halogen atom]. The saturated hydrocarbon group in R166 may have any of a carbon number of 丨~(7), a linear chain, a branched chain, and a cyclic chain, and may have a crosslinked structure. Specific examples thereof include mercapto, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, hexyl, heptyl, octyl, 2-ethylhexylfluorene Base, sulfhydryl-specific base, %•pentyl, cyclohexyl, cycloheptane-28 * 201214045 base, . The naphthyl atom of the saturated -NR atom group may be a cycloalkyl group such as a carbonyl pentyloxy group, a carbonyl group, an ethyl propyl group or a cyclyl group, a tricyclodecyl group or the like. The hydrogen atom system contained in the crosslinked alicyclic hydrocarbon group-saturated hydrocarbon group may be substituted by a γ atom, and examples of the phenol atom include a fluorine atom, a chlorine atom, and a filling atom. The methylene group contained in π and the hydrocarbon group may be substituted by an oxygen atom, a carbonyl group or a hydrazine. For example, a group in which a methylene group contained in a saturated hydrocarbon group is substituted with oxygen may, for example, be a methoxypropyl group, an ethoxypropyl hexyloxypropyl group, a methoxyhexyl group or an ethoxy propyl group. Base. The aromatic hydrocarbon group of R1", RIW, R..., R162 & Q is not particularly limited as long as it has a carbon number of 6 to 10, and examples thereof include a phenyl group and the like. Further, a substituent of the aromatic hydrocarbon group is used. Examples of the dentate cited include a fluorine atom, a chlorine atom, a bromine atom, etc., and R165-so3r166.

Just at R 159

R 1 60

R 16 1

R 1 62 曱 醯 、, ethanesulfonyl, hexyl sulfonyl, sulfonyl sulfhydryl, etc., in the case of R159, R16〇, RWi, Rl 62 1 65 ^ Dl66^ R162 and R165 _C02R166 Methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, isopropoxy, butoxycarbonyl, isobutoxycarbonyl, pentyloxycarbonyl, heteroyl, neopentyloxycarbonyl, cyclopentyloxy Carbocarbonyl, hexyloxycarbonylcyclohexyloxy, heptyloxycarbonyl, cycloheptyloxycarbonyl, octyloxy, 2-ethylhexyloxycarbonyl, cyclooctyloxycarbonyl, decyloxycarbonyloxy Carbocarbonyl, tricyclodecyloxycarbonyl, methoxypropoxycarbonyloxypropoxycarbonyl, hexyloxypropoxycarbonyl, 2-ethylhexyloxycarbonyl, nonyloxyhexyloxycarbonyl, etc. . In the case of R159, Ri6〇, Rm, Rl62 and Rl652_s〇2NHRl67, sulfonamide, methanesulfonyl, ethanesulfonyl, propanesulfonyl, isopropanylsulfonyl, butane Aminesulfonyl, isobutane-29· 201214045 Aminesulfonyl, pentamaminesulfonyl, isoamylamine sulfonyl, neopentylsulfonyl, cyclopentylamine sulfonyl, hexane Aminesulfonyl, cyclohexylamine, heptylamine, heptanesulfonyl, cycloheptylamine, octylamine sulfonyl, 2-ethylhexylsulfonyl, 1,5 - Methylhexylsulfonyl, cyclooctylamine sulfonyl, decylamine sulfonyl, decylamine sulfonyl, tricyclodecylamine sulfonyl, decyloxypropanyl sulfonyl, B Oxylamine sulfonyl, propoxyamine sulfonyl, isopropoxyamine sulfonyl, hexyloxysulfonyl, 2-ethylhexyloxysulfonyl, methoxyhexaneamine Sulfonyl, 3-phenyl-1-methylpropanamine sulfonyl and the like. Just at R159 and R16. Further, Ri61, R丨62, and R丨65-S02NHR丨67 and -sc^NR1 Mr1 68 may further include a group represented by the following substituent group a to the substituent group U. Group a] III NIH.Qn« NJi-I.Qn. NH<502

[substituent group b]

-30- 201214045 [Substituent group C] γ NHS〇2

^^nhso2 nhso2

,0' NHS〇2 [substituent group d]

HO ^\^NHS02

OH

Nhso2

, NHSO HO〆 2

HO

NHSO 2

HO ^^/\^nhs°2 ho

Nhso2 OH nhso2

OH

HO

NHS02 χ1 production, /NHS02 X1

Nhso2

I I 1 I CF3CH2NHS02 CF3(CF2)7CH2NHS02 In the above substituent group d, X1 represents a halogen atom. The halogen atom of X1 may, for example, be a fluorine atom, a chlorine atom or a bromine atom. -31 - 201214045 [Substituent group e] I MeO—NHS02

Nhso2 /0

Nhso2 〇, NHS〇2

Nhso2

Nhso2 nhso2 [substituent group f]

I I I I ^N\^^/NHS〇2 [Substituent group g]

X I x H NHS02 X I MeO NHS02 nhso2 NHSOo NC NHSO 2

NHSO 2 -32- 201214045 [Substituent group h]

O2n nhso2

NOc

In the above substituent group h, X3 represents an alkyl group having 1 to 3 carbon atoms or an alkoxy group having 1 to 3 carbon atoms, and the hydrogen atom of the alkyl group and the alkoxy group may be substituted by a halogen atom. Examples of the alkyl group having 1 to 3 carbon atoms include a mercapto group, an ethyl group, a propyl group, an isopropyl group and the like. The alkyl group having 1 to 3 carbon atoms substituted by a halogen atom can be exemplified. Fluoromethyl and the like. Examples of the alkoxy group having 1 to 3 carbon atoms include a decyloxy group, an ethoxy group, a propoxy group and the like. -33- 201214045 [Substituting group i]

[substituent group j]

201214045 [Substituting group 1]

In the above substituent group 1, X2 represents an alkyl group having 1 to 3 carbon atoms, an alkoxy group having 1 to 3 carbon atoms, a halogen atom or a nitro group, and the hydrogen atom of the alkyl group and the alkoxy group may be halogen. Atomic substitution. The halogen atom is the same as the above X1, and the alkyl group having 1 to 3 carbon atoms or the alkoxy group having 1 to 3 carbon atoms which may be substituted by a halogen atom may, for example, be The above X3 is the same. [substituent group m]

NHS〇2

-35- 201214045 [Substituent group η], N S02

, Ν S02

'N S02

[Substituent group P]

-36- 201214045 [Substituent group q ]

In the above substituent group q, the X2 system is synonymous with the above. [substituent group r]

37- 201214045 [Substituting group s]

Nhso2, nhso2

Nhso2 nhso2 ho^s^nhso2 /〇\^nhso2 I nhso2

H0/^/0^^^NHS0〇 HO’ 丫, NHS〇2

OH

[substituent group t]

NHSO Q.

Me 2 nhso2 nhso2 [substituent group u]

02 _HS N-

-NHSO,

OMe In the above substituent group u, the X3 system is synonymous with the above. In the above-mentioned R167 and R168 of -S02NHR167 and -S02NR167R168, a branched alkyl group having 6 to 8 carbon atoms, an alicyclic hydrocarbon group having 5 to 7 carbon atoms, an allyl group, and a carbon number of 8 to 10 are used. An aralkyl group, a hydroxyl group-containing hydroxyl group of -38-201214045, an alkyl group having an alkoxy group having 2 to 8 carbon atoms, preferably an aryl group, and having a branched carbon number of 6 to 8 The base is more preferred, and 2-ethylhexyl is particularly preferred. The substituent of the aromatic hydrocarbon group having 6 to 10 carbon atoms of R, R, Rm and R162 is an alkyl group, an aryl group, an alkyl-substituted phenyl group or a -S03R丨66 having a carbon number of i to 4 or -S02NHR 丨67 is preferred, and ethyl, propyl, dimethylphenyl, -S03R166 or -S02NHR167 is more preferred. Specific examples of the aromatic hydrocarbon group having a carbon number of 6 to 1 具有 having a substituent of 11159, 11^, 1^1, and 1^2 include a nonylphenyl group, a dimethylphenyl group, and a second group. Methylphenyl, ethylphenyl, hexylphenyl, nonylphenyl, fluorophenyl, chlorophenyl, bromophenyl, hydroxyphenyl, nonyloxyphenyl, dimethoxyphenyl, ethoxy Phenylphenyl, hexyloxyphenyl, nonyloxyphenyl 'trifluoromethylphenyl, and the like. At least one of R 59 and R160 or at least Hg of R!6! and R162 is preferably an alkyl group having 1 to 10 carbon atoms or an aromatic hydrocarbon group having 6 to 10 carbon atoms which may be substituted. It is more preferable that at least one of R159 and R160 and at least one of the ribs 16 and R of 62 have an aromatic hydrocarbon group having 6 to 10 carbon atoms which may be substituted.

Rl65 is a carbonyl group, an ethoxycarbonyl group, a thioxyl group, a 2-ethylhexyloxypropanolsulfonyl group, a dimethyl dimethyl sulfonyl sulfonyl group, a 3-hydroxy group Methylpropenolamine hydrazino or isopropoxy propyl amide is preferred. The cation represented by the above (1 1) is preferably a cation represented by the following formula (1 1 -1) U 1·2), (1 1_3) or (1 1-4). -39- 201214045

RlS9a p161a p160a R162a (Il-1) p165b p165a [In the formula (1 1-1), R159a, R160a, 1613 and 111623 independently represent a hydrogen atom, -R166 or an aromatic hydrocarbon group having 6 to 10 carbon atoms; The hydrogen atom contained in the aromatic hydrocarbon group may be substituted by a halogen atom, -R166, -OH, -OR166, -S03H, -S03Na, -C02H, -C02R166, -S03R166, -so2nhr167 or -so2nr167r168. R165a means -S03H, -S02NHR167 or -S02NR167R168. Ruler 16515 represents a hydrogen atom, -S03H, -S02NHR167 or -S02NR167R168. R166, R167 and R168 are synonymous with the above]. R159b r160< p161b p162b p163b

P164b (11-2) {r165c) q [In the formula (1 1-2), 'R159b, R160b, 1116115 and ruler 1621) independently represent a hydrogen atom, -R166b or an aromatic hydrocarbon group having 6 to 10 carbon atoms. The hydrogen atom contained in the aromatic hydrocarbon group may be substituted by a halogen atom, -R166b, -OH, -OR166b, -S03-, -S03Na, -C02H, -C02R166b, -S03H, -S03R166b or -S02NHR178. -40- 201214045 R163b and R164b represent a hydrogen atom or a carbon number of 1 to 8 independently of each other. R165e means -S03Na, -C02H, -C〇2RU6b, _8〇3^ or S02NHR178. R16 6 b represents a saturated fe group having a carbon number of 1 to 10, and the hydrogen atom contained in the saturated nicotine group may be substituted by -OR166b or a halogen atom. R178 is a hydrogen atom, -R166b, -C02R166b or an aromatic hydrocarbon group having 6 to 10 carbon atoms, and the hydrogen atom contained in the aromatic hydrocarbon group may be substituted by -R166b4_OR166b. q is synonymous with the above]

R159iN\/^s^Q

(Π-3) |^165e [In the formula (11-3), R159e and R1 61 e each independently represent a phenyl group, and the hydrogen atom contained in the phenyl group may be a halogen atom, -R166b, - OR166b, -C02R166b, _s〇3R166I^_s〇2NhR178 are substituted.

Rl65d is -S02NHR178.

Rl651 represents a hydrogen atom or -S02NHR178. R1661 R178 is synonymous with the above]. ϊ Η I |

(11-4) -41 - 201214045 [In the formula (11-4), r] 59^r丨chuan is a phenyl group independently of each other, and the hydrogen atom contained in the phenyl group may be _Rl66b, or _ s〇2NhR1" is substituted. R165f is -S02NHR178. R1661 R178 is synonymous with the above.] Representative examples of the cation represented by the above formula (1 1) include, for example, the following compound group m and compound group. a cation represented by η. [Compound group m]

-42- 201214045 x The cationic chromophore which is represented by the following formula, for example, the cation represented by the following compound 雔J ^ D kiss group p. [Compound group P]

Compound m 1

C〇CH2N+(CH3)3 4 Compound m 2 This colorant can be produced by a known method using the same bis as in the examples of JP-A-2003-20641. When the coloring agent is produced by the Frangipani reaction in the example of JP-A-2003-20641, the salt of the anion represented by the above formula (lb) represented by the above formula (u) is essential, In the case of the salt, the product can be used as the product, and the method can be used as described in the paragraphs [〇149] to [〇m] of the JP-A-2008-741 公报. Further, in the case of the publication of JP-A No. 2〇〇3_2〇6415, the anionic material, that is, the dye (4), the dye is used as a starting material for the di-alkali parent to change the reaction to produce the coloring agent, the Jingyou is further improved: the coloring agent In terms of heat resistance? It is preferred that the halogen ions are not left as much as possible (10)'. The present colorant obtained in this manner is soluble in various organic solvents including ketones such as ketones, and X has excellent properties. Further, in order to further improve heat resistance, it is preferable that the halogen ions contained in the colored color of the present invention are as small as possible. That is, the other components described in 4 are preferably as small as possible using a halogen ion. The present invention can be used singly or in combination of two or more. ―, the coloring agent is, for example, χ+ is a triarylmethane chromophore, because it is blue to red in an organic solvent, so by using the coloring agent alone or

S-43-201214045 is used by suitably mixing with other colorants, and can be applied, for example, to a colored composition for forming blue pixels, red pixels, and black colored layers. For the coloring agent other than the coloring agent, color and material can be appropriately selected according to the use. Specifically, any of pigments, dyes, and pigments can be used as the coloring agent other than the coloring agent, and the coloring layer constituting the color filter is required to have high color purity, brightness, contrast, and light blocking properties. It is preferred to use pigments and/or dyes. In the case of the above pigments, 'any of the organic pigments or inorganic pigments: Yes, in the case of organic pigments', for example, may be mentioned in color; by the Society of Colorists and Colorists (The SQeiety. £_ _nsts) a compound classified as a pigment. Specifically, a color index (c.i.) named as follows can be cited. C.I. Pigment Yellow 12, c I Wanzulong 1, Pigment Yellow 17, C.I. Pigment Yellow 2〇Vc L C I. Pigment Page 14, C·1 ‘, CI Pigment. Pigment Yellow 24, Pigment Yellow 31. ==.1. Pigment yellow...丄Pigment yellow--pigment:, two=...pigment yellow (3),. ·1. Pigment (4) C.I. 枓 枓 page 150, c 丄 pigment yellow 153,

Pigment Yellow 155, CI Pigment Yellow 166, c-pigment t 2 / CL 180, CI·Pigment Yellow 211; ^, 丄 Pigment Yellow C.1. Pigment Dial 5, C.I_Pigment Dial 13, c〗 镫24 , C.1. Pigment dial 34, C丄 pigment dial 36: c and, C.1. Yan C丄 pigment dial 40, ^• pigment orange 43, cj =, pigment orange 38' 49, CI · pigment dial 61, c ..., beans, CI · pigment orange. Upper. Pigment lamp 6 4, c Ϊ cobalt coarse by m pigment orange (9), c 丄 pigment orange 71, c · · Yan Yanke "8, c 丄, CI pigment orange 74; ...,, plate 72, CI. Pigment Orange 73 -44 - 201214045 C. I · Pigment Red 1, CI Pigment Red 2, CI Pigment Red 5, C. I · Pigment Red 1 7, CI Pigment Red 3 1, CI Pigment Red 3 2, C · I. Pigment Red 4 1 , CI Pigment Red 122, CI Pigment Red 123, CI Pigment Red 144, CI Pigment Red 149, CI Pigment Red 166, CI Pigment Red 168, CI Pigment Red 170, CI Pigment Red 171, CI Pigment Red 175, CI Pigment Red 176, CI Pigment Red 177, CI Pigment Red 178, CI Pigment Red 179, CI Pigment Red 180, CI Pigment Red 185, CI Pigment Red 187, CI Pigment Red 202, CI Pigment Red 206, CI Pigment Red 207, CI Pigment Red 2 09, CI Pigment Red 214, CI Pigment Red 220, CI Pigment Red 221, CI Pigment Red 224, CI Pigment Red 242, CI Pigment Red 243, CI Pigment Red 254, CI Pigment Red 25 5 'CI Pigment Red 262, CI Pigment Red 264, CI Pigment Red 272 » CI Pigment Violet 1, CI Pigment Violet 19, CI Pigment Violet 23, CI Pigment Violet 29, CI Pigment Violet 32, CI Pigment Violet 36, CI Pigment Violet 38; CI·Pigment Blue 1, CI Pigment Blue 15, CI Pigment Blue 15 : 3, CI Pigment Blue 15 : 4, CI Pigment Blue 15 : 6, CI·Pigment Blue 60, CI Pigment Blue 80; CI Pigment Green 7, CI Pigment Green 3 6, CI Pigment Green 5 8 ; CI pigment brown 2 3, CI pigment brown 2 5 ; CI pigment black 1, CI pigment black 7. Further, examples of the inorganic pigment include titanium oxide, barium sulfate, carbonic acid #5, and zinc white. , sulfuric acid wrong, yellow wrong, zinc yellow, iron oxide red (red iron oxide (III)), cadmium red, ultramarine blue, indigo, chrome oxide green, cobalt green, amber, titanium black, synthetic iron black, and carbon black. -45-201214045 In the present invention, the pigment can be used by using a recrystallization method, a reprecipitation method, a refrigerant washing method, a sublimation method, a vacuum heating method, or the like. Further, the pigment may be used by modifying the surface of the particles with a resin. The resin for modifying the surface of the particles of the pigment can be, for example, a vehicle liquid resin described in JP-A-Kaki 7 or a resin for dispersing various pigments. As a resin of the surface of the carbon black, for example, the method described in the Japanese Patent Laid-Open No. 9 95625, No. 1, 733, JP-A-5-725, No. Hei. It is preferable to use the so-called salt mill to use the primary particles 彳 & As a salt mill, the square γ 7 person position U refines - (1) bulletin; for example, it can be used in the special Kaiping and 'the above-mentioned slanting; J. direct dye, acid (four) two enough from a variety of oil-soluble dyes, For example, it may be appropriately selected from the following: the yellow agent yellow 24, the CL solvent yellow 82 2 \ 14 ' C · 1 · the solvent yellow 15 , the C 丄 dissolved CI solvent yellow 1 C. · Solvent yellow = yellow (four) ^ C ·!. Solvent red 45, C: I·1. Solvent yellow 179; > gluten red 49; C 丨 solvent orange 2, C ·!, solvent dial 7, c " dial I5 , cu container lamp 26, CI solvent dial 56 〆 -, CU container CJ solvent blue 35, CI. Solvent.

Solvent Blue 67; L·1·♦ Indigo 59, CJ C.I. Acid Yellow 17, c τ舻 Bu Wai

Acid yellow 76; 丄^ is more 29' C.I. Acid yellow 40, c.L 2. Acid red 91, c 丄 acid red 92.

Coffee ".acidic (four)....acid red 15i;,.,,U-46- 201214045 CI acid dial 5 1 C · I. Acid blue 8 〇CI acid green 9, sex green 27; ci·acid orange 63; C·1·Acid Blue 83, CI Acid Blue 90; C.1. Acid Green 16, C.I_ Acid Green 25, and CI Acid are used in the present invention. The toner system can be used alone or in combination of two

In the present invention, when the X + # A agent and the green other chromophore are used, it is preferred to use the colored product in combination. At this time, 1 is used as a green coloring agent for green pixel formation. The green coloring agent is a green coloring agent for the coloring agent, which is 'CT 4d., and is selected from CI pigment 7, c.l_pig 36 CI·枓The group consisting of 58 is Tejiaping, at least one of which is preferred, and the CI pigment 58 coloring agent and the red other... southern chromophore (4) are used in combination with the original color composition or the combination of the two: as the red pixel formation. The blue color pixel forms H and blue other colorants, and the bamboo "π color composition is better. Xin forms H death: the colorant and the red other colorant are made into a red color composition, ... The reddish organic pigment of the red coloring agent is preferably red, and the group of C 丄 pigment red 16 < . (7), pigment red (2) ... ^ yan: 254 is at least good. t * ^ ^ ^ ^ ^ + ^ ^3< Use cm * % of quality is better. Also, at this time, _ can be more pigment yellow N38, CI pigment yellow i39, C. 〇, ci 枓 yellow 38 and other yellow and light colors -47- 201214045 When using this coloring agent together with the blue I color pixel forming color composition, it is = For the coloring agent which is blue, it is blue organic: material: blue of coloring agent is CI pigment blue, c丄 pigment or organic dye is preferred, cl pigment blue 〇, CI pigment Blue 〗 4, Blue 3, C 丄 Pigment Blue 9 Pigment Blue 15:6, c I 铕 at least 丄 Pigment Blue 15:3, C j 丄 枓 62 62, ci alkaline blue LI · at least j type is better, and CI alkaline blue u is widely used, and the content ratio of the coloring agent is good. The mass % is better, preferably 3 to 5 % by mass. Also, the color is 3 to 70 A purple coloring agent such as ci pigment violet 23 is used. In this case, a black matrix of pixels having high luminance and excellent color purity can be formed, and the solid content of the f6 ” or the excellent light-shielding property is 5 mass%. To W. Mass color: The solid component is a component other than the solvent described later. Further, in the present invention, when a pigment is used as the coloring agent, a dispersing agent or a dispersing aid can be used as needed. As the dispersing agent, for example, a dispersing agent such as a cationic system, an anionic system or a nonionic system can be used, and a polymer dispersant is preferred. Specific examples thereof include an amine phthalate dispersant, a polyethyleneimine dispersant, a polyoxyethylene alkyl ether dispersant, a polyoxyethylene alkyl phenyl ether dispersant, and a polyethylene glycol diester system. A dispersing agent, a sorbitan fatty acid ester dispersing agent, a polyester dispersing agent, an acrylic dispersing agent, or the like. Such a dispersant can be obtained commercially. For example, in the case of an acrylic dispersant, Disperbyk-2000, Disperbyk-2001, BYK-LPN6919, BYK-LPN21116 'BYK-LPN21324 (above 201214045, BYK-Chemie (BYK) (Company system); Examples of the urethane-based dispersant include Disperbyk-161, Disperbyk_162, Disperbyk-165, Disperbyk_167, Disperbyk-170, and Disperbyk-182 (above, BYK-Chemie (BYK)) SOLSPERSE 76500 (manufactured by LUBRIZOL Co., Ltd.); SOLSIPERSE 2400 (manufactured by LUBRIZOL Co., Ltd.) for the polyethyleneimine dispersant; AJISPER PB821 for the polyester dispersant AJISPER PB822, AJISPER PB880 - AJISPER PB 8 81 (manufactured by AJINOMOTO FINE TECHNO Co., Ltd.), and the like. In addition, the above-mentioned dispersing aid may, for example, be a pigment derivative, and specifically, a copper ugly cyanine, a dioxime 17 to 11 and 11 pirin, a quinophthalone sulfonic acid derivative, etc. . Further, the oxime containing the dispersing agent and the dispersing aid can be appropriately determined within the range not impairing the object of the present invention. - (B) Binder Resin _ The coloring composition of the present invention contains (Β) binder resin. Thereby, the developability of the coloring composition and the adhesion to the substrate can be improved. The binder resin is not particularly limited, and a resin having an acidic functional group such as a cation group or a phenolic hydroxyl group is preferred. Among them, a polymer having a retardation group (the following & "man, >, the lower handle is a thiol-containing polymer") is preferable, and (for example, one or more kinds of impurities may be mentioned) 7 α The carboxyl group of the ethylenically unsaturated monomer (referred to as - 'unsaturated monomer (bl)) 盥 他 麫 麫 麫 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似 似Ethylene] a copolymer called unsaturated precursor (b2)") is attached to an unsaturated single vessel (k > acid, maleene 1 (called έ, for example, (methyl) propyl ^ page H, cis decene: acid anhydride, succinic acid mono [2_(methyl), -49- 201214045 ene methoxyethyl ester], ω-carboxy polycaprolactone mono(indenyl) acrylate, p-vinyl benzene The unsaturated monomer (bi) may be used singly or in combination of two or more. The unsaturated monomer (b2) may, for example, be N-phenyl-butenene. N-position of maleimide, 1-cyclohexanimide, substituted maleimide, styrene, nonyl styrene, phenyl styrene Ethylene propyl group An aromatic vinyl compound of ether or terpene; such as methyl (meth) acrylate, n-butyl (meth) acrylate, (mercapto) acrylic acid 2-ethylhexyl vinegar, (meth) propylene Acid _2. base ethyl vinegar, (meth) acrylic acid allyl vinegar, (meth) acrylate, cool, polyethylene glycol (tetra) ~ dimercapto ether (meth) acrylate cool 'polypropylene glycol (nyq acrylic vinegar, Polyethylene glycol (n = 2~1〇) single (methionan β r 哔 (2 1U) early (meth) acrylate, polydimethylene n = 2~10) mono (meth) propylene (four), (a Alkyl hexanoic acid acrylate, (acrylic acid iso-, tricyclo[5·2· U26] oxime I-based (methyl) 久久曰, dicyclopentenyl (meth) acrylate, Glycerol mono (methyl hydrazine), 4, phenyl (meth) acrylate vinegar, p-cumyl benzene: <院 modified (meth)acrylic acid vinegar, (methyl) propyl acrylate propylene vinegar , base bis-butyric acid, epoxidized cyclohexan vinegar, Μ Μ 产 产 ) ) 氧基 氧基 氧基 氧基 oxymethyl] _3_ ethyl oxonium (meth) acrylate; -: 乂 乂 乂 、 、, 莰 莰 趟 趟, 三 三 [ [ [ 2. -3-Ethylene sorrow I B (tetra), 3-(vinyloxyethyl ketone hexacyclohexane vinyl ether; -50- 201214045 in ♦ styrene, poly(decyl) decyl acrylate, poly (Mercapto) acrylic acid n-butyl S, poly-stone oxygen burning flat, _ A 5 molecular bond end has a single (meth) acrylonitrile-based macromonomers, etc. The copolymerization ratio of the '4 unsaturated monomer (M) in the copolymer of the body (bl) and the unsaturated monomer (b2) is preferably 5 to 5 % by mass, and is preferably 1 to 40% by weight. It is preferable that the unsaturated monomer (b 1) is copolymerized in such a range to obtain a coloring composition excellent in basic developability and storage stability. Specific examples of the copolymer of the unsaturated monomer (b1) and the unsaturated monomer (10) are disclosed in Japanese Laid-Open Patent Publication No. Hei 7-14-654, No. Hei 8-259876, and No. Hei. Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Copolymer. In the case of the present invention, for example, Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. A carboxyl group-containing polymer having a polymerizable unsaturated bond such as a (fluorenyl) fluorenyl group in a side chain, as disclosed in Japanese Unexamined Patent Publication No. Hei. Used as a binder resin. The weight average molecular weight (Mw) of the converted polystyrene measured by GPC (eluent solvent: tetrahydrofuran) in the adhesive resin of the present invention is usually 1,000 to 100,000, preferably 3,000 to 50,000. When the Mw is too small, the residual film rate of the obtained film is lowered, or the pattern shape, heat resistance, and the like are impaired, and the electrical characteristics are also deteriorated. On the other hand, the resolution of the time is too low, Or the shape of the pattern is impaired, and there is a possibility that dry foreign matter is likely to be generated when coated by the slit nozzle method. Further, the ratio (Mw/Mn) of the weight average molecular weight (Mw) of the binder resin in the present invention to the number average molecular weight (?n) of the converted polystyrene measured by GPC (eluent solvent: tetrahydrofuran) is 1.0~5.0 is better, with 1. .〇~3.〇 is better. The binder resin in the present invention can be produced by a known method, and can be used, for example, in Japanese Laid-Open Patent Publication No. Hei. No. 2006-259680, and International Publication No. 2/7/29. In the method disclosed in the booklet or the like, the structure and the Mw are controlled. In the present invention, the binder resin may be used singly or in combination of two or more. In the present invention, the content of the binder resin is usually 10 to 10,000 parts by mass, preferably 2 to 5 parts by mass, per part by mass of the (A) coloring agent. When the content of the binder resin is too small, for example, there is a decrease in the visibility of the testability, the possibility that the preservation stability of the obtained coloring composition is low, :: aspect: too much, because the concentration of the colorant is relatively low, there is It is difficult to achieve the possibility of being a target color density of the film. - (c) Crosslinking agent - In the present invention, the compound (C) can be used as a compound of B:& Examples of the polymerizable group include a compound in which the 'unsaturated group, the epoxy group, and the oxyhetero ring are in the present invention, and the (2) crosslinking agent is a di(2-)(meth)acryl fluorenyl group or A compound having two or more n _ -52- 201214045 alkoxyfluorenylamino groups is preferred, particularly a compound having two or more (fluorenyl) acrylonitrile groups and having two or more N-house oxygens It is preferred to use a combination of a sulfhydryl group-based compound. Specific examples of the compound having two or more (meth) acrylonitrile groups can be exemplified by a polyfunctional (fluorenyl) propyl group obtained by reacting an aliphatic polyhydroxy compound with (mercapto) acrylic acid. Dilutate ester, caprolactone-modified polyfunctional (meth) acrylate, alkylene oxide-modified polyfunctional (fluorenyl) acrylate, (hydroxyl) acrylate having hydroxyl group and polyfunctional A polyfunctional amine phthalate (meth) acrylate obtained by reacting an isocyanate, a polyfunctional (meth) acrylate having a carboxyl group obtained by reacting a (fluorenyl) acrylate having a hydroxyl group with an acid anhydride, or the like. Here, as the above aliphatic polyhydroxy compound, for example, a binary aliphatic polyhydroxy compound such as ethylene glycol, propylene glycol, polyethylene glycol or polypropylene glycol; for example, glycerin or trihydroxydecylpropane, a ternary aliphatic polyhydroxy compound of pentaerythritol or dipentaerythritol; and as the above-mentioned (meth) acrylate having a trans group, for example, (meth)acrylic acid-2-thiophene Cool, trimethylolpropane (meth) acrylate, neopentyl diol di(mercapto) acrylate, dipentaerythritol penta (meth) acrylate, glycerol dimethacrylate. The polyfunctional isocyanate may, for example, be toluene diisocyanate, hexamethylene diisocyanate, diphenylmethylene diisocyanate or isophorone diisocyanate. Examples of the acid anhydride include acid anhydrides of dibasic acids such as succinic anhydride, maleic anhydride, glutaric anhydride, itaconic acid liver, phthalic anhydride, and hexahydrophthalic anhydride; for example, pyrocalcic liver, biphenyl Tetracarboxylic acid anhydride of tetracarboxylic dianhydride and diphenyl ketone tetracarboxylic dianhydride-53-201214045 Further, the above-mentioned caprolactone-modified polyfunctional (fluorenyl) acrylate is exemplified by The compound described in paragraphs [0015] to [0018] of JP-A-44955. Examples of the above polyalkylene oxide-modified polyfunctional (meth) acrylate include ethylene oxide and/or propylene oxide-modified di(meth)acrylate of bisphenol A, and iso-three. Ethylene oxide and/or propylene oxide modified tri(meth)acrylate of polycyanic acid, ethylene oxide and/or propylene oxide modified tris(decyl)acrylic acid of trimethylolpropane Ethylene oxide and/or propylene oxide modified tetra(methyl) of ester, neopentyl alcohol ethylene oxide and/or propylene oxide modified tris(fluorenyl) acrylate 'nepentaerythritol Ethylene acrylate and dipentaerythritol ethylene oxide and/or propylene oxide modified penta (meth) acrylate, dipentaerythritol ethylene oxide and / or propylene oxide modified Hexa(meth)acrylate and the like. Further, the compound having two or more N-alkoxyguanidinoamine groups may, for example, be a compound having a melamine structure, a benzoguanamine structure or a urea structure. Further, the melamine structure and the benzoguanamine structure refer to a chemical structure in which one or more triacyl rings or a phenyl-substituted triterpene ring are used as a basic skeleton, and also includes melamine, benzoguanamine or the like. The concept. Specific examples of the compound having two or more N-alkoxymethylamino groups include n, n, n,, n', n, n, and - six (homoyloxyf group) melamine , n, n, n', n, -tetrakis(alkoxymethyl)benzoguanamine, n, n, n, n, -tetrakis(alkoxymethyl) glycoluril, and the like. Among these polyfunctional monomers, a polyfunctional (mercapto) acrylate obtained by reacting a trivalent or higher aliphatic polyhydroxy compound with (meth)acrylic acid, and a polycaprolactone-modified polyfunctional (A) Acrylate, polyfunctional urethane (mercapto) acrylate, polyfunctional (methyl) with carboxyl group -54- 201214045 acrylate, n, n, n', n', n, ', n, Preferably, hexa(alkoxymethyl)melamine, n,n,n,,n,-tetra(alkoxymethyl)benzoguanamine is preferred. Among the polyfunctional (meth) acrylates obtained by reacting a trihydric or higher aliphatic polyhydroxy compound with (mercapto)acrylic acid, trimethylolpropane triacrylate, neopentyl alcohol triacrylate, and two new ' Pentaerythritol pentaacrylate, dipentaerythritol hexaacrylate; a compound obtained by reacting pentaerythritol triacrylate with succinic anhydride among polyfunctional (fluorenyl) acrylates having a carboxyl group, The compound obtained by the reaction of pentaerythritol pentaacrylate succinic anhydride is excellent in the strength of the colored layer and the surface smoothness of the colored layer, and is less likely to cause contamination, residual film, etc. on the unexposed portion of the substrate and the light shielding layer. It is especially good. In the present invention, the (C) crosslinking agent may be used singly or in combination of two or more. In the case of + (I), the content of the parent-linked agent is relative to the mass of the bismuth (A), to! 〇~〗, 〇〇〇 mass parts are better than 2 〇 ~ 5 〇〇 mass parts is particularly good. At this time, when the polyfunctional retention μ u θ month b |·the raw monomer contains too little 1, there is no sufficient hardenability ♦ ^ ρ θ 虞 on the other hand, if the polyfunctional monomer is contained

In the case of imparting alkali developability to the coloring composition of Chu A 4 L 3 of the present invention, the basic developing property is low, and it is easy to be on the substrate of the unexposed portion and the light shielding layer. There is a tendency to cause pollution, residual film, and the like. - (D) Photopolymerization initiator _ # The color composition of the present month, which can be made to contain (D) photopolymerization initiation 斛 estimated Γ L % is sufficient to impart a linearity to the coloring composition. (D) Guangping human +-Μ, φ φ 2 AD initiator used in the present invention is exposed by radiation such as visible light, ultraviolet light, far green, electron start, ^. , x-ray, etc. The aforementioned (c) crosslinking agent will start to polymerize to illuminate the compound which produces the active species.

S-55-201214045 Such a photopolymerization initiator may, for example, be thioxanthone, phenylethyl group I compound, disigmow methane compound, trimorphic compound, orthoquinone system. A compound, a rust salt compound, a benzoin compound, a diphenylketone compound, an α-diketone compound, a polynuclear benzoquinone compound, a diazo compound, an imidosulfonate compound, or the like. In the present invention, the photopolymerization initiator may be used alone or in combination of two or more. In the case of a photopolymerization initiator, it is selected from the group consisting of a 9-oxosulfuryl 4 σ star compound, an acetophenone compound, and a biimidazole compound. At least one of the group consisting of a triterpenoid compound and a 0-lanthanoid compound is preferred. Among the preferred photopolymerization initiators of the invention are 9-oxosulfur. Specific examples of the hawthorn-based compound include 9-oxothione and 2-azone 9-oxosulfur. Hawthorn, 2-mercapto 9-oxosulfate, hawthorn, 2-isopropyl 9-oxosulfide. Mountain 17!·, 4-isopropyl 9-oxo sulfur σ山p star, 2,4 -.—murine 9-oxosulfonate mountain star, 2,4-dimercapto 9-lactide. Mountain, 2,4 _diethyl 9-lactosulfur, 2,4-diisopropyl 9-oxosulfide. Mountain σ star and so on. Further, specific examples of the acetophenone-based compound include 2-mercapto-1-[4-(methylthio)phenyl]-2-indole-Miso-propyl-1-pyrene, 2-block group -2-dimethylamino-1-(4:indole-pyridylphenyl)butan-1-one, 2-(4-methylbenzyl)-2-(diguanylamino)-1 - (4 -N - flavor ° Lin phenyl) Ding Shao-1 - 嗣 and so on. Further, specific examples of the biimidazole-based compound include 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2 , 2'-bis(2,4-diphenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2,'2'-bis (2,4, 6-trisylphenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole. Further, when a biimidazole-based compound is used as a photopolymerization initiator, it is preferred to use a hydrogen donor in combination for improving the sensitivity. Here, "hydrogen donor" means a compound capable of imparting a hydrogen atom to a radical generated from a biimidazole compound by exposure. Examples of the hydrogen donor include a thiol-based hydrogen donor such as 2-hydrothiobenzothiazole or 2-sulfonylbenzoxazole, and 4,4'-bis(dimethylamino)diphenyl ketone. An amine-based hydrogen donor such as 4,4'-bis(diethylamino)diphenyl ketone. In the present invention, the hydrogen donor can be used singly or in combination of two or more kinds, and it is preferable to use one or more kinds of thiol-based hydrogen donors and one or more amine-based hydrogen donors in combination. . Further, specific examples of the above-mentioned three-tillage compound include 2,4,6-paraxyl (trimethylsulfonyl)-s-triterpene and 2-methyl-4,6-bis(trichloro). Methyl)-s-. Mountain, 2-[2-(5-fluorenylfuran-2-yl)ethenyl]-4,6-bis(trichloromethyl)-3-tri <1 well, 2-[2-(°夫喃-2-yl)ethenyl]-4,6-bis(trichloromethyl)-8-trimethyl, 2-[2-(4-diethylamino-2-methylphenyl)vinyl ]-4,6-bis(trimethylmethyl)-8-trimorphine, 2-[2-(3,4-dimethoxyphenyl)vinyl]-4,6-bis (trimethylmethyl) -s-triterpene, 2-(4-methoxyphenyl)-4,6-bis(trichloromethyl)-s-triterpene, 2-(4-ethoxyphenyl)-4, 6-bis(trishydrazinyl)-s-triphthyl, 2-(4-n-butoxyphenyl)-4,6-bis(trichloroindenyl)-s-triphthyl, etc. Triterpenoid compounds. Further, specific examples of the 0-lanthanoid compound include 1-[4-(phenylthio)phenyl]-1,2-octanedione-2-(0-benzoquinone). ), 1-·[9-ethyl-6-(2-mercaptophenyl)yl-9-oxazol-3-yl]-ethanone-1-(0-acetamidine), 1-[ 9-Ethyl-6-(2-methyl-4-tetrahydrofuranyloxyphenyl fluorenyl)-9H-indazol-3-yl]-ethanone-1-(0-acetamidine), 1 -[9-ethyl-6-{2-fluorenyl-4·(2,2-dimercapto-1,3-dioxolanyl)nonyloxyphenylhydrazino}-9H-carbazole -3-yl]-ethanone-1-(0-acetamidine) and the like. -57-201214045 In the present invention, when a photo-radical generator other than the biimidazole-based compound such as an acetophenone-based compound is used, a sensitizer may be used in combination. Such a sensitizer may, for example, be 4,4 '-bis(dimethylamino)diphenyl ketone, 4,4,-bis(diethylamino)diphenyl ketone or 4-diethylamino benzene. Ethyl ketone, 4-dimethylaminopropiophenone, ethyl 4-dimethylaminobenzoate, 2-dimethylaminobenzoic acid 2-ethylhexanoic acid, 2,5-bis(4-diethylamino) Benzylene)cyclohexanone, 7-diethylamino_3_(4-ethylaminobenzyl) coumarin, 4-(diethylamino)chalcone, and the like. In the present invention, the content of the photopolymerization initiator is usually 0.01 to 120 parts by mass, preferably 1 to 1 part by mass, per 100 parts by mass of the (c) crosslinking agent. In this case, when the content of the photopolymerization initiator is too small, there is a possibility that the curing is insufficient by exposure: in the case of too much, the coloring layer formed tends to fall off from the substrate. _ Solvent · Coloring of the present invention Other morphological compositions which are arbitrarily added. When the solvent component or the additive component is volatile, the solvent may, for example, be ethylene glycol monomethyl ether, ethylene glycol mono-n-ethylene glycol monoethyl ether, mono-n-butyl ether or tri-ether ether. The propylene glycol monomethyl composition is contained in the above-mentioned group J, and the singularity of the singularity of the singularity of the above-mentioned group J is usually 5, and it is not suitable for the selection. Ethyl ether diethylene glycol diethylene glycol oxime ketone ketone ketone ketone monoethyl ketone shouting, propylene glycol monoethyl (A) ~ (C) component, and solvent to prepare liquid solution or dispersion (A) ~(C) Sub-reaction with appropriate scream, ethylene glycol mono-n-propyl alcohol monomethyl ether, di-extension ether, diethylene glycol, tri-ethylene glycol monoethyl sulfonate, propylene glycol mono-n-propyl-58 - 201214045 base ether, propylene glycol mono-n-butyl ether, di-n-propylene glycol monodecyl ether, di-n-ethylene glycol monoethyl ether, di-n-glycol mono-n-propyl ether, di-n-ethylene glycol Butyl ether, tri-propanol monomethyl ether, triple extension a (poly)alkylene glycol monoalkyl ether such as propylene glycol monoethyl ether; an alkyl lactate such as decyl lactate or ethyl lactate; sterol, ethanol, propanol, butanol, isopropyl (cyclo)alkanols such as alcohol, isobutanol, tert-butanol, octanol, 2-ethylhexanol, cyclohexanol; keto alcohols such as diacetone alcohol; ethylene glycol monomethyl ether Acid ester, ethylene glycol monoethyl ether acetate, diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, propylene glycol monodecyl ether acetate, propylene glycol (poly)alkylene glycol monoalkyl ether acetate such as monoethyl ether acetate, 3-decyloxybutyl acetate, 3-mercapto-3-indolyl butyl acetate Other ethers such as diethylene glycol didecyl ether, diethylene glycol decyl ethyl ether, diethylene glycol diethyl ether, tetrahydrofuran, etc.; mercapto ethyl ketone, cyclohexanone, a ketone such as 2-heptanone or 3-heptanone; a diacetate such as propylene glycol diacetate, 1,3-butylene glycol diacetate or 1,6-hexanediol diacetate; Methyl 3-methoxypropionate, ethyl 3-methoxyoxypropionate, 3-ethoxypropionic acid Alkoxycarboxylates such as methyl ester, ethyl 3-ethoxypropionate, ethyl ethoxyacetate, 3-methyl-3-decyloxybutylpropionate; ethyl acetate, acetic acid N-propyl ester, isopropyl acetate, n-butyl acetate, isobutyl acetate, n-amyl formate, isoamyl acetate, n-butyl propionate, ethyl butyrate, n-propyl butyrate, isopropyl butyrate Ester, n-butyl butyrate, decyl pyruvate, ethyl pyruvate, n-propyl pyruvate, methyl acetate, ethyl acetate, 2-ethyloxybutyrate and other esters ;

Q -59- 201214045 Aromatic hydrocarbons such as benzene and diphenylbenzene; hydrazines such as N,N-dimercaptoamine, hydrazine, hydrazine-dimethylacetamide, and N-decylpyrrolidone Amine or indoleamines, etc. Among these solvents, propylene glycol monodecyl ether, propylene glycol monoethyl ether, ethylene glycol monomethyl ether acetate, and propylene glycol monomethyl ether B are used from the viewpoints of solubility, pigment dispersibility, and coatability. Acid ester, propylene glycol monoethyl ether acetate, 3-methoxybutyl acetate, diethylene glycol dimethyl ether, diethylene glycol decyl ethyl ether, cyclohexanone, 2- Heptone, 3-heptanone, 1,3-butanediol diacetate, 1,6-hexanediol diacetate, ethyl lactate, ethyl 3-methoxypropionate, 3-ethoxy Ethyl propyl propionate, ethyl 3-ethoxypropionate, 3-methyl-3-decyloxybutyl propionate, n-butyl acetate, isobutyl acetate, n-amyl decanoate, acetic acid Amyl ester, n-butyl propionate, ethyl butyrate, isopropyl butyrate, n-butyl butyrate, ethyl pyruvate and the like are preferred. In the present invention, the solvent may be used singly or in combination of two or more kinds, and the content of the hydrazine solvent is not particularly limited, and the solvent is removed from the coloring composition from the viewpoints of coatability and stability of the obtained coloring composition. The total concentration of the components is usually 5 to 50% by weight. It is particularly good in an amount of 10 to 40% by weight. - Additive - The coloring composition of the present invention may contain various additives as necessary. Examples of the additive include a filler such as glass or oxidized metal; a polymer compound such as polyvinyl alcohol or poly(fluoroalkyl acrylate); a surfactant such as a fluorine-based surfactant or a ray-based surfactant; ;乙浠-60- 201214045 base trimethoxy decane, vinyl triethoxy decane, vinyl ginseng (2 methoxy ethoxy), sulphur, N-(2-aminoethyl) _3 amine Internal group methyl dimethoxy decane, N-(2-aminoethyl)-3 aminopropyl trimethoxy hydroxy, 3-aminopropyl triethoxy decane, 3-glycidoxypropyl trimethyl Oxydecane, 3•glycidoxypropylmethyldimethoxymethane, 2—(3,4·ethoxycyclohexyl)ethylmethoxycarbonyl, 3-cyclopropylmethyldi a adhesion promoter such as methoxydecane, 3-cyclopropyltris-oxydecane, 3-methylpropenyloxypropyltrimethoxydecane, 3-hydrothiopropyltrimethoxydecane; 2_Antioxidant such as thiobis(4-methyl-6-tert-butylphenol), 2,6-di-t-butylphenol, etc.; 2-(3-third-based _5-methyl _ 2_ by stupid base) _5_chlorobenzotriazine, alkoxydiphenyl ketones, etc. Absorbent; anti-agglomerating agent such as sodium polyacrylate; malonic acid, adipic acid, itaconic acid, citraconic acid, antibutanic acid, mesaconic acid, 2-aminoethanol, 3-amino group| Residue improver of alcohol, % amino-1-pentanol, 3-amino+2·propanediol, 2-amino-1)3-propanediol, 4·amino-1,2-butanediol, etc.; Take acid mono [2_(methyl) propylene methoxy ethoxy vinegar], citric acid mono [2 · (methyl) propyl oxime ethoxylate], polycaprolactone mono (indenyl) acrylate, etc. A developer improving agent; a siloxane oxide oligomer having a reactive functional group disclosed in, for example, JP-A-H08-242078. The coloring composition of the present invention can be prepared by an appropriate method, and the method of the present invention is disclosed in Japanese Laid-Open Patent Publication No. 2008-58642, No. 2G1G-132874, and the like. method. When both the coloring agent and the like are used as the coloring agent, as disclosed in Japanese Laid-Open No.-mm, it is possible to pass the dye solution containing the coloring agent or the like after passing through the first transition device. Preferably, the dye solution is mixed with a separately prepared pigment dispersion or the like, and the obtained colored composition is prepared by passing through the second filter. Further, the dye containing the coloring agent or the like, the components (B) to (C), and the component (D) and the additive component as necessary are dissolved in the solvent (e), and the obtained solution is passed through the first filtration. After the apparatus, a method in which the solution having passed through the first filter is mixed with a separately prepared pigment, dispersion, or the like, and the obtained colored composition is prepared by a second filter is also preferable. Further, after the dye solution containing the coloring agent or the like is passed through the first filter, the dye solution that has passed through the first filter, the components (B) to (c), and (D) as necessary are added. (E) component and additive component are mixed and dissolved, and the obtained solution is passed through the second filter, and the second teardropper/liquid mixture is mixed with the separately prepared pigment dispersion liquid, and the obtained solution is obtained. The method of modulating the colored composition by the third filter is also preferable. [Color filter and method of manufacturing the same] The color filter of the present invention is provided with a coloring layer containing the coloring agent as a color filter for coloring, and a square of the present invention: On the surface, 'blue enamel containing the present colorant is applied as necessary to form a pixel: line = coating film. Next, through the reticle pair: = the formation liquid is developed and the unexposed portion of the coating film is dissolved and removed so that the pixel array &amp; is arranged in a pre-arranged arrangement of the blue pixel pattern - 62 · 201214045 'Using each of the coloring sense radiation groups of green or red, pre-baking, exposing, developing, and post-baking each of the coloring sensitizing radiation compositions, and forming green pixels in the same order in the same manner as described above Array and red pixel array. Thereby, an image of the three primary colors arranged in red, green, and blue is obtained. However, in the present invention, the formation of pixels of respective colors is not limited to the above. Further, the black matrix can be formed by a lithography method using a metal thin film formed by sputtering or vapor deposition, but it is also possible to use a color ray which is dispersed with a black coloring agent. The composition was formed in the same manner as in the case of forming the above-described pixels. The colored composition of the present invention can also be suitably formed into a matrix. Examples of the substrate used in forming the color filter include glass, ruthenium, polycarbonate, polyester, aromatic polyamide, polyimide, polyimine, and the like. The slab|plate system can also be preliminarily subjected to appropriate pretreatment such as drug treatment using a name agent, lightning forging, i i electropolymerization, ion plating, sputtering reaction, vacuum evaporation, and the like. When the substrate is coated with a color-sensing radioactive composition, it can be used for the Li mist method, the I-Kun coating method, the hot wire method, the coating method (spin coating method), the slit mold method, and the rod coating method. -

The coating method of k field is preferably a spin coating die coating method. Buckle-burning soil 帀C pre-baking system is used as the eucalyptus wood and the mouth is dried under reduced pressure and heated to dry. The dry olefin system usually enters the rod # # -i ^ ^ reaches 5〇~200Pa. Further, the heating member is suspended at 70 to 1 1 〇 &gt; C for about 1 to 1 minute. The composition of the cloth and the substrate can be colored and filmed, and the case can be placed in a black form, and the film can be sprayed and coated in a gas phase. The strip thickness is -63-201214045. The coating thickness is usually 0.6 to 8 〇 μ m ', preferably 1.2 to 5.0 μm, based on the film thickness after drying. For the light source of the radiation used in forming the pixel and/or the black matrix, for example, a xenon lamp, a tooth lamp, a tungsten lamp, a high pressure mercury lamp, a super-pressure mercury lamp, a gel metal lamp, a medium pressure mercury lamp, and a low pressure mercury lamp are mentioned. Other light sources such as argon ion lasers, Yag lasers, XeC1 excimer lasers, and nitrogen lasers, etc., preferably have radiation in the range of 19 〇 to 45 〇 nm. The exposure amount of the radiation is usually 1 〇 to 1 〇, and 〇〇〇 J/m 2 is preferred. Further, in the case of the above alkaline developing solution, for example, sodium carbonate, sodium hydroxide, potassium hydroxide, tetraammonium hydroxide, choline, 1,8-diazabi[5. 4. 〇] An aqueous solution of -7-undecene, iota, 5-diazabicyclo_[4 3 〇]_5_pinene or the like is preferred. The above-mentioned test imaging liquid can also be added with an appropriate amount of, for example, methanol, an ethanol water-soluble organic solvent, a surfactant, or the like. In addition, after the alkali imaging, the conventional imaging processing method is used to capture the Chuanbei Pu, the sputum, and the mist of the mouth in the i-dip imaging method, the immersion (PUddle) imaging method, and the like. Development conditions The book temperature is preferably 5 to 300 seconds. The condition of the left bell is to be baked. The temperature f is 10 to 60 24 in the 120 to 28 generations (TC is preferably used for the heat resistance of the coloring agent after the baking, and is preferably 23 or less. It is particularly preferable that m, the thickness of the pixel formed, is usually 〇.5~5·0 1 ·〇~3·〇// m is better. -64 - 201214045 again &gt; 7- 3 1 8723 shows the use of an inkjet method in which a substrate is first pre-baked in a liquid layer of a coloring composition, and a solvent is post-baked to subsequently use a green sample. In accordance with the invention of the red pixel pattern and the blue three primary colors, the respective colors of the partition walls are separated into the compartments. Therefore, the partition wall usually forms a color 光 'light and J pre- Bake and post-bake the same as 0. Do the same for the 13⁄4 degree of the 153⁄4 wall. After the film is applied, after the splash is used, In addition, it is also possible to use a color-sensitive filter, which is generally used in a color filter, and to provide a partition wall on the surface of each color pixel, for example, by using an inkjet evaporation method. Then, the coloring order of blue or red is formed on the same substrate according to the hardening of it. Thus, the order of the color filter pixels capable of obtaining the pixel pattern is not tied, not only the shading function coloring composition is not mixed. The method and conditions for baking the substrate used in the black matrix used in the black matrix are formed by the ink jet method. The obtained pixel pattern is formed by bonding a transparent conductive film to form a spacer to form a radial composition. In the method, it is possible to adopt a method disclosed in Japanese Patent Publication No. WO 60. The color pattern is formed after the blue device containing the coloring agent in the partition wall having the light-shielding function is discharged. 'The red and green light patterns are arranged in the same green pixel pattern as above. However, it is limited to the above. 'Because it is also achieved The function is such that the film thickness is thicker and formed by the composition. The light source of the radiation and the thickness of the pixel of the first method are formed as necessary. The transparent conductive film is formed as a color light-emitting sheet. Interstitial, but can also be -65- 201214045 with a light-shielding spacer (black spacer). In this case, the color-sensing radiation composition which disperses the black coloring agent can be used. The coloring composition of the present invention is also suitably used for forming such a black spacer. The color filter of the present invention obtained in this manner is very useful in color liquid crystal display elements, color image sensor elements, color sensors, organic EL display elements, electronic paper, etc. because of its high brightness and color purity. [Display Element] The display element of the present invention is provided with the color filter of the present invention. Examples of the display element include a color liquid crystal display element, an organic EL display element, and electronic paper. The color liquid crystal display element having the color filter of the present invention can adopt an appropriate structure. For example, it is possible to adopt a configuration in which a color filter is formed on a substrate different from a substrate on which a thin film transistor (TFT) is mounted, and a substrate on which the color filter is formed and a substrate on which the color filter is formed are transmitted through the liquid crystal layer, and The substrate in which the color filter is formed on the surface on which the thin film transistor (TFT) driving substrate is disposed and the substrate on which the ITO (tin-doped indium oxide) electrode is formed may be opposed to each other through the liquid crystal layer. . The latter structure has the advantage of being able to significantly increase the aperture ratio and to obtain a bright and high-definition liquid crystal display element. The color liquid crystal display element having the color filter of the present invention may be provided with a backlight module having a white LED as a light source in addition to a cold cathode fluorescent tube (CCF) L: Cold Cathode Fluorescent Lamp. In the case of a white LED, for example, a white LED-66-201214045 which uses a red LED having an independent spectrum, a green LED, and a blue LED to obtain white light can be cited; by combining a red LED, a green LED, and a blue LED And color mixing to obtain a white light white LED; by combining blue LED, red LED and green phosphor to obtain a white light white LED; by blue LED, red light fluorescent body and green light The phosphors are combined and mixed to obtain a white LED of white light; a white LED is obtained by mixing a blue LED and a YAG-based luminescent phosphor; and the blue LED and the luminescent phosphor are A green light-emitting phosphor is combined and mixed to obtain a white light white LED; a white light white LED is obtained by combining an ultraviolet LED, a red light-emitting phosphor, a green light-emitting phosphor, and a blue light-emitting phosphor. Wait. The color liquid crystal display element having the color filter of the present invention can be applied to TN (Twisted Nematic; Twisted Nematic) type, sTN (Super)

Suitable liquid crystal modes such as Twisted Nematic, Ips (In_pianes Switching), VA (Vertical Alignment), and OCB (Optically Compensated Birefringence). In addition, the organic EL display element having the color filter of the present invention can be suitably configured, and the structure disclosed in Japanese Laid-Open Patent Publication No. Hei. Further, the electronic paper having the color filter of the present invention can adopt a suitable structure, and for example, a structure disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. [Embodiment 1] Hereinafter, the embodiment of the present invention will be described in more detail with reference to the embodiments, but the present invention is not limited by the following examples. -67- 201214045 &lt;Synthesis and Evaluation of the Colorant 1. Synthesis of the Colorant

Colorant Synthesis Example ^NH

CF3SO3K Basic Blue 7

O3S-CF3 Add 4 g (2 72 mm 〇i) c 丄 basic blue 7 (C1-salt of compound c2 of the above compound group c), 0.768 g (4. 〇 8 mmo 在) to the screw into the stirrer Potassium trifluoromethanesulfonate (manufactured by Wako Pure Chemical Industries, Ltd.), 20 mL of gas and 10 ml of water were stirred at room temperature for 7 hours. After the aqueous layer was separated and evaporated, the organic layer was washed twice and concentrated under reduced pressure, and the obtained solid was dried under reduced pressure to give a white solid (yield: 80.2%). This was designated as Compound A. The 1H-NMR (solvent: deuterated gas) spectrum of the compound A was confirmed to be the target compound as follows. 4-丽11』8.25((1,1H), 7.18-7.51(m,8H), 6.75(brs, 4H), 6.65(d, 1H), 3.60(q, 2H), 3.55(q, 8H), 1.46 (t, 3H), 1.30 (t, 12H) Colorant Synthesis Example 2 In the colorant synthesis example i', except for the use of nonafluorobutyric acid (manufactured by Wako Pure Chemical Industries, Ltd.) instead of potassium trifluoromethanesulfonate' The coloring agent was synthesized in the same manner as the coloring agent synthesis example 1 and was measured by 1H-NMR (solvent: deuterated gas), and it was confirmed to be a target compound. This was used as the compound B. The 1H-NMR spectrum of the compound B is as follows -68- 201214045 1H-NMR: 88.26 (d, 1H), 7.15-7.55 (m, 8H), 6.75 (brs, 4H), 6.65 (d, 1H), 3.60 (q, 2H), 3.55 (q, 8H), 1.47(t, 3H), 1.30(t, 12H) Colorant Synthesis Example 3 In the colorant synthesis example 1, except that bis(trifluoromethanesulfonyl) sulfinium imide was used instead of trifluoromethanesulfonic acid. In the same manner as in the case of the coloring agent synthesis example 1, the coloring agent was synthesized, and the target compound was confirmed by 'H-NMR (solvent: deuterated chloroform). This was used as the compound C. 1 Η - NMR of the compound C The spectrum is as follows. ^-ΝΜΚιδδ.Ο^ά, 1H), 7.16-7.52(m, 7H), 6.75(brs, 4H), 6.68(d, 1H), 6.19(t, 1H), 3.55(q, 10H), 1.45(t, 3H), 1.30(t, 12H) Colorant Synthesis Example 4 In the colorant synthesis example, except for the use of CI base Sex blue 1 1 (C sulfonium salt of the compound C4 of the above compound group c) was synthesized in the same manner as in the colorant synthesis example 1 except that c. I. basic blue 7 was synthesized by 〗 〖H_NMR (solvent: 氘The gas was measured and confirmed to be the target compound. Colorant Synthesis Example 5 The colorant synthesis example was carried out in the same manner as in the colorant synthesis example except that C_I. basic violet 16 (Cl. salt of the compound e2 of the above compound group e) was used instead of the cI basic blue 7. The synthetic color former was confirmed to be the target compound by iH_NMR (solvent: deuterated chloroform). Colorant Synthesis Example 6 In Colorant Synthesis Example 1, except that d basic blue 41 (methane sulfate of the compound Π3 of the above compound group f) was used instead of CI. Basic blue 7 was -69-201214045 except for the coloring agent. In Synthesis Example 1, the coloring agent was synthesized in the same manner, and it was confirmed by H-NMR (solvent: deuterated chloroform) to confirm that it was the target compound. Colorant Synthesis Example 7 In the colorant synthesis example 1, except that C. 〗 Basic Blue 3 (Cl. salt of the compound i4 of the above compound group i) was used instead of the basic blue 7, the coloring agent was synthesized. The coloring agent was synthesized in the same manner, and it was confirmed to be a target compound by 1 h_nmr (solvent: deuterated gas). Colorant Synthesis Example 8 In the same manner as the colorant synthesis example 1, except that d•basic blue 22 (cr salt of the compound j1 of the above compound group j) was used instead of CI basic blue 7 in the colorant synthesis example 1′ The synthetic color former was confirmed to be the target compound by ih_NMr (solvent: deuterated gas). Colorant Synthesis Example 9 In the colorant synthesis example 1, except that CI·basic red 13 (C1_salt of the compound e 1 of the above compound group e) was used instead of c. I·inspective blue 7 and bis (trifluoro) was used. In the same manner as the coloring agent synthesis example 1, the coloring agent was synthesized in the same manner as the coloring agent synthesis example 1 except that the trimethoprim group was replaced with the trifluoroanthracene group I, and the target was confirmed by j-NMR (solvent: gasification gas simulation). Compound. Colorant Synthesis Example 10 In the colorant synthesis example, c. I. Basic Yellow 2 5 (C1 'salt of Compound fl of the above compound group f) was used instead of cI Basic Blue 7 and bis (trifluoromethyl) was used. In the same manner as in the coloring matter synthesis example 1, the chrome-based imidazole was synthesized in the same manner as in the coloring matter synthesis example 1, and the target compound was confirmed by W-NMR (solvent: gasification gas simulation). -70-201214045 Colorant Synthesis Example 1 1 In Colorant Synthesis Example 1, except that CI•Basic Yellow 2 (C1-salt of Compound h2 of the above compound group h) was used instead of CJ Basic Blue 7 and double (three) was used. In the same manner as the coloring agent synthesis example 1, the coloring agent was synthesized in the same manner as in the coloring agent synthesis example 1 except that the potassium fluoromethanesulfonyl) sulfinium imide was used to determine the target by the 1 H_NMR (solvent: gasification). Compound. Colorant Synthesis Example 1 2 In Colorant Synthesis Example 1, except that CI Basic Red 2 (C1·s salt of Compound il of Compound Group 1 above) was used instead of cI Basic Blue 7 and bis(trifluoromethyl fluorenyl) was used. In the same manner as the coloring agent synthesis example 1, the coloring agent was synthesized in the same manner as in the coloring agent synthesis example 1, and it was confirmed by the 1H_NMR (solvent: deuterated chloroform) to confirm that it was the target compound. Colorant Synthesis Example 1 3 In the colorant synthesis example, in addition to CI Basic Orange 24 (Cl. salt of Compound g3 of the above compound group g), instead of cI Basic Blue 7, and using bis(trifluoromethane) In the same manner as the coloring agent synthesis example 1, the coloring agent was synthesized in the same manner as in the coloring agent synthesis example 1, and the target compound was confirmed by 1H_NMR (solvent: deuterated chloroform). Colorant Synthesis Example 1 4 In the colorant synthesis example 1 'except. Use (: _; [. Basic yellow 21 (C1 · salt of compound e9 of the above compound group e) instead of c.; [• Basic blue 7 Further, a coloring agent was synthesized in the same manner as in the coloring matter synthesis example 1 except that bis(trifluoromethylsulfonium) quinone imide potassium was used instead of potassium trifluoromethanesulfonate, and the mixture was synthesized by 1H NMR (solvent: deuterated chloroform). 'Confirmed to be the target compound. This is taken as the compound E. The 1H-NMR spectrum of the compound E is as follows. -71 - 201214045 lH-NMR: 8-78 (d, 1H), 7.70 (d, 1H), 7.67 (m) 1H), 7.28-7.57(m, 8H), 6.24(d, 1H), 5.1 9 (quintet, 1H), 3.89(s 3H), 3.66(q, 1H), 3.01(d, 1H), 1.88(s , 3H), 1.82 (s, 3H), 1.52 (d, 3H) Colorant Synthesis Example 1 5 Add 1.3 g (2.71 mmol) of CI-indicating red represented by the following formula to a screw inserted into a stirrer 1. 0.766 g (4.07 mmol) of potassium trifluoroantimonate (manufactured by Wako Pure Chemical Industries, Ltd.), 20 μL of chloroform and 1 〇m 1 of water, and stirred at room temperature for 7 hours. After separating and removing the aqueous layer, The organic layer was washed twice with water and concentrated under reduced pressure, and dried under reduced pressure. To give 1.6 lg blue-black solid (yield 72%) The 1H-NMR as the compound G. G which compound (solvent: deuterated imitation gas) spectra were as follows, identified as the title compound.

'H-NMRiS^SCdd, 1H), 7.87(m, 2H), 7.70(t, 2H), 7.47(dd, 1H), 6.94(d, 3H), 6.81(s, 2H), 3.95(q, 2H) ), 3.50 (quintet, 4H), 2.1〇(s, 6H), 1.27(t, 6H), 〇.85(t, 3H,) Colorant Synthesis Example 1 6 In Colorant Synthesis Example 5, except for use Potassium nonafluorobutanesulfonate (manufactured by Wako Pure Chemical Industries, Ltd.) was synthesized in the same manner as in the colorant synthesis example 15 except that potassium hexafluorobutanesulfonate (manufactured by Wako Pure Chemical Industries, Ltd.) was synthesized by 1H-NMR (solvent: deuterated chloroform) , confirmed to be the target compound. This was used as a compound hydrazine. The 1H-NMR spectrum of the compound is as follows. -72- 201214045 1H-NMR: 8.32 (d, 1 H), 7.7 8 (m, 2H), 7.2 8 (dd, 1H), 6.81 (d, 2H), 6.76 (s, 2H), 6.68 (s, 2H), 4.04 (q, 2H), 3.51 (quintet, 4H), 2.18 (s, 6H), 1.38 (t, 6H), 1.00 (t, 3H,) Colorant Synthesis Example 1 7 In Colorant Synthesis Example 1 5, a coloring agent was synthesized in the same manner as in the coloring matter synthesis example 15 except that potassium bis(trifluoromethanesulfonyl) phthalimide was used instead of potassium trifluoromethanesulfonate, and j-NMR (solvent: The sample was confirmed to be the target compound. This was designated as Compound I. The 1 H-NMR spectrum of Compound I is as follows. 11-Li 11: 8.33 ((1,1H), 7.79 (m, 2H), 7.28 (dd, 1H), 6.81 (d, 2H), 6.76 (d, 2H), 5.94 (d, 2H), 4.04 (q, 2H), 3.50 (quintet, 4H), 2.15 (s, 6H), 1.39 (t, 6H), 1.01 (t, 3H,) Colorant Synthesis Example 1 8 In the colorant synthesis example 15, except The coloring agent was synthesized in the same manner as in the coloring matter synthesis example 15 except that the CI basic red 1:1 was used instead of the CI basic red 1, and the target compound was confirmed by W-NMR (solvent: deuterated chloroform). This is taken as the compound J. The 1 H-NMR spectrum of the compound J is as follows. 4- Leg 11: 8.33 ((1,1H), 7.80 (m 2H), 7.28 (d, 1H), 6.77 (d, 4H), 5.95(t, 2H), 3.66(s 3H), 3.49(quintet, 4H), 2.13(s, 6H), 1.38(t, 6H) Colorant Synthesis Example 1 9 In Colorant Synthesis Example 17, except for use In the same manner as the coloring agent synthesis example, the coloring agent was synthesized in the same manner as the coloring agent synthesis example 1 7 except that the CI-acceptable violet 1 represented by the above formula was used instead of C · I · basic red 1, by j-NMR (solvent: deuterated chloroform) - 73-201214045 It was confirmed that it was a target compound, and it was made into the compound κ. The 1 H-NMR spectrum of the compound κ is as follows.

(c2h5)2n λ ί(02η5)2 ^-NMRiS.lSCd, 1H), 7.77(t, 1H), 7.69(t, 1H), 7.26(dd, 2H), 7.02(d, 2H), 6.76-6.83 (m 4H), 5.95 (t, 2H), 3.58 (q, 8H), 1.30 (t, 12H) Colorant Synthesis Example 20 In the colorant synthesis Example 1 7 'except that c. I is represented by the following formula In the same manner as the coloring agent synthesis example, the coloring agent was synthesized in the same manner as the coloring agent synthesis example 1 7 except that the test violet 1 1 : 1 was used, and it was confirmed by W-NMR (solvent: deuterated gas) that it was the target compound. . This was designated as Compound L. The 1H-NMR spectrum of the compound L is as follows.

(C2H5)2N λ ...:2Η5)2 'H-NMRiS.SICd, 1H), 7.77(dt, 2H), 7.30(m, 1H), 7.06(m 2H), 6.83(d, 4H), 3.68(s 3H), 3.60 (q, 8H), 1.32 (t, 12H) Colorant Synthesis Example 2 1 In the colorant synthesis example, the 7' system is represented by the following formula: c. I. Verification red 3 instead of cI· In the same manner as in the case of the coloring agent Synthesis Example 17, the coloring agent was synthesized in the same manner as in the case of the coloring agent 1 and was determined to be the target compound by iH-NMR (solvent: deuterated chloroform). • 74· 201214045

In the colorant synthesis example, the coloring agent was synthesized in the same manner as the coloring agent synthesis example 17 except that CI basic red 4 represented by the following formula was used instead of CI basic red 1, and the coloring agent was synthesized. The compound was identified as a target compound by 1H-NMR (solvent: deuterated gas).

In the colorant synthesis example 17, a coloring agent was synthesized in the same manner as the coloring agent synthesis example 1 except that CI basic violet 1 1 represented by the following formula was used instead of CI basic red 1 by iH-NMR. (Solvent: deuterated chloroform) The measurement was confirmed to be the target compound.

2. Evaluation of the coloring agent The compound A obtained in the coloring agent Synthesis Example 1 was dissolved in 10% by mass or more of cyclohexanone, and the solution was blue. Any of the color formers obtained in the colorant synthesis examples 2 to 2 3 was dissolved in cyclohexanone by 10% by mass or more. Further, in the coloring agent synthesis examples 1 to 23, the 5% by mass reduction temperature based on the thermogravimetric-differential heat simultaneous measurement and analysis of the coloring agent was 25 °C or higher. On the other hand, CI-Basic Blue 7, CI Basic Blue 1 1 , (: 1. Basic Purple 16, CI Basic Blue 41, CI Basic Blue 3, CI Basic Blue 22, CI Basic Red 13, CI alkaline yellow 25, CI alkaline yellow 2, CI alkaline red 2, CI alkaline orange 24, CI alkaline yellow 21, CI alkaline red 1, CI alkaline red 1: 1, CI alkaline red 3, CI alkaline red 4, CI alkaline purple 10, CI alkaline purple 1 1, CI alkaline purple 1 1 : 1 based on thermal weight - differential heat simultaneous determination of the analysis of the 5% mass reduction temperature system It is less than 200 ° C. &lt;Preparation of Pigment Dispersion&gt; Preparation Example 1 Using 5 parts by mass of CI Pigment Blue 1 5 ··6 as a colorant, 12.5 parts by mass as a dispersing agent (solid content concentration = 40) (% by mass) BYK-LPN21 1 16 (manufactured by BYK-Chemie (BYK)), 7 2.5 parts by mass of propylene glycol monodecyl ether acetate as a solvent, and treated with a bead mill to prepare a pigment dispersant (A-1) Preparation Example 2 A pigment dispersant (A-2) was prepared in the same manner as in Preparation Example 1 except that CI Pigment Violet 23 as a coloring agent was used instead of CI Pigment Blue 1 5 : 6. Preparation Example 3 In addition to use as a coloring The pigment dispersant (A-3) was prepared in the same manner as in Preparation Example 1 except that CI Pigment Blue 58 was used instead of CI Pigment Blue 1 5: 6. -76- 201214045 Modification Example 4 In addition to the use as a coloring agent, C. The pigment yellow 150 was prepared in the same manner as in the preparation example except that the pigment yellow 150 was used in the same manner as in the preparation example. The preparation example 5 used 15 parts by mass of C j. Pigment Red 177 as a coloring agent. 12.5 parts by mass (solid content concentration = 40% by mass) BYK_LPN21 1 16 (manufactured by BYK-Chemie (BYK)), 72.5 parts by mass of propylene glycol monomethyl ether acetate as a solvent, and a bead mill were used as a dispersing agent. The pigment dispersant (A-5) was prepared by the treatment of the pigment dispersant (A-5). The preparation of the pigment dispersant (A) was carried out in the same manner as in Preparation Example 5 except that c is a coloring agent, and pigment red 254 was used instead of ci·pigment 1 77. -6) &lt;Preparation of Dye Solution&gt; Preparation Example 7 Five kinds of compound VIII were used as a coloring agent and mixed as a solvent.

Modulation example 8

Acetate to modulate dye solution A. B and mixing as a solvent to prepare a dye solution B Modification Example 9

95 Compound C and mixed as a solvent ester to prepare a dye solution c. -77- 201214045 Preparation Example 1 ο The dye was prepared by using 5 parts by mass of Basic Blue 7 as 9 θ J of the colored Nanxun and mixing as a solvent <mussel 3: part propylene glycol (1),,, y-flat T-ether. Solution D 〇1 Example 1 1 A dye solution e was prepared by using 5 parts by mass of a human 95 danthene GD as a coloring agent and mixing propylene glycol monomethyl as a solvent and preparing an oxime acetate. . Use as a coloring sword

95 parts by mass of n ^ of the agent was inspected and mixed as a solution. Alcohol early methyl ether acetate to prepare a dye solution F. Preparation Example 1 3 Using a mass fraction of propylene glycol monochromate as a colorant tanning agent and mixing as a solvent preparation example 14 Dye solution G. The dye solution H was prepared by using 80 parts by mass of propylene glycol (^) as a coloring agent and using the same as a solvent early methyl ether. Example 1 5 A dye solution I was prepared by using 20 parts by mass of the compound I as a coloring agent and mixing 80 parts by mass of propylene glycol as a tempering agent. Withdrawal Example 1 6 The dye solution J was prepared by using a chelating compound J as a coloring agent and mixing 80% by mass of the propylene glycol monoester of the mixture. Preparation Example 17 π &amp; π The dye solution K was prepared by using 20 parts by mass of the compound oxime as a coloring agent and mixing propylene glycol monodecyl ether as A, 'Bai Lizhi 乍 as / mixture'. -78- 201214045 Preparation Example 1 8 Using 2 parts by mass of compound B as the second generation of the product, and mixing 80 parts by mass of mono-nonyl ether as a solvent to prepare the dye solution. L·. 20 parts by mass of C.I. Basic Red 1 was used as a chromic propylene dimer as a coloring agent and 80 mass of methyl ether was mixed as a solvent to prepare a dye <Synthesis of a binder resin>. Glycol ί Ϊ : Add 100 parts by mass of propylene to the flask of the tube and the mixer: "Heart vinegar acetate and replace with nitrogen. Heat to 8 (TC and drop 100 parts by mass of propylene glycol in 1 hr. 2〇ff ^ ψ Λ ^ Premature methyl ether acetate s day, olefin...: acid, 1 part by mass of styrene, 5 parts by mass of methyl propyl &quot;&quot; 5 parts by mass of 2-hydroxy methacrylate Ethyl ester, 23 parts by mass of f-based acrylic acid · 2 · ethyl hexanoic acid, 12 parts by mass of N · stupid butadiene di-branched, 15 temporary θ, succinic acid monosuccinate (2-propylene oxyethyl) a mixed solution of vinegar and 6 parts by mass of 2,2=-even^bis(2,4-diindenylcarbonitrile), which is kept at this temperature for 2 hours. Then the temperature of the reaction solution is raised to 1 〇〇 ° C 'further polymerization for 1 hour to obtain a binder resin solution (solid content concentration 33 minus 〇 / 〇). The obtained binder resin is Mw = 12,200, 6'5 〇〇 ° The resin was used as the "adhesive resin (B 1 )". &lt;Preparation and evaluation of coloring composition&gt; Example 1 13.6 parts by mass of pigment dispersion liquid (A·1), 27.2 parts by mass of dye solution A 1 6.1 parts by mass of the binder resin (B 1 ) as the binder resin, 5.5 parts by mass of the parent-agent, m-402 (a neopentyl alcohol hexaacrylate and dipentaerythritol 5) Mix of acrylate -79- 201214045) and 2 ·4 parts by mass of M+V-3〇 by CHEMICAL Co., Ltd. (Yiyi:^',:^',&gt;1",:^"- Hexa(alkoxymethyl)melamine as a main component, a weight average degree of polymerization of 1.3), 2.2 parts by mass as a photopolymerization initiator, 2-carbyl-2 -monoamido-1-(4-indole- Flavor #· phenyl phenyl butyl ketone - (CIBA SPECIALTY CHEMICALS company, trade name IRGACURE 369), and propylene glycol monomethyl-acetic acid as a solvent are mixed to prepare a color component having a solid concentration of 20% by mass (cr) 1) After coating the colored composition (CR1) on a glass substrate using a spin coater, prebaking was performed for 1 minute using a hot plate at 80 ° C to form a coating film. By changing the number of revolutions of the spin coater The same operation was performed to form three coating films of different film thicknesses. Then the substrates were cooled. After the room temperature, the radiation of each wavelength containing 3 65 nm, 405 nm, and 436 nm was exposed to an exposure amount of 2,000 J/m 2 for each coating film without using a high-pressure mercury lamp. Then, by using the substrate, A developing solution containing 0.04 mass of a hydrogen peroxide solution at 23 ° C was spouted at a developing pressure of 1] cgf/cm 2 (nozzle diameter: 1 mm) to carry out shower development for 90 seconds. Subsequently, the substrate was washed with ultrapure water and air-dried, and then baked in a clean oven at 203 ° C for 3 minutes to form a cured film for evaluation. A color analyzer (MCPD2000 manufactured by Otsuka Electronics Co., Ltd.) was used for the obtained three cured films, and the chromaticity coordinate value (X, y) and the stimulus value of the cie color system were measured by a C light source and a 2 degree field of view. (Y). Further, the film thickness of the obtained cured film was measured using Alpha-Step IQ manufactured by KLA-Tencor. From the measurement results, the chromaticity coordinate value y, 刺激_〇8〇, the chromaticity coordinate value χ, the stimulus value (Υ), and the film thickness were obtained. The evaluation results are shown in Table 1. The more the stimulus value (γ) is displayed -80-201214045, the higher the light transmittance (brightness), and the thinner the film thickness, the more the tinting strength is. The substrate on which the cured film was formed was sandwiched between two deflecting plates, and the polarizing plate (wavelength range: 380 to 780 nm) was used to illuminate the front side of the deflecting plate from the back side, and the brightness meter LS-1〇 was used. 〇 (MIN〇LTA (manufactured by the company)) to measure the maximum and minimum values of the transmitted light intensity. Further, the value obtained by dividing the maximum value by the minimum value for each of the cured films is used as a comparison. The comparison between the chromaticity coordinate values y=〇_〇8〇 is obtained from the measurement results. The evaluation results are shown in Table 1. Example 2 15.5 parts by mass of a pigment dispersion liquid (Ai), 24.3 parts by mass of a dye solution B, 1 6.1 parts by mass of a binder resin (b丨) as a binder resin, and 5.5 mass parts of East Asia Synthetic Co., Ltd. as a parent-linked agent Co., Ltd. made μ·402 (a mixture of dipentaerythritol hexaacrylate and dipentaerythritol pentaacrylate) and 2.4 篁 二 和 and CHMICAL Co., Ltd. mw_30 (with N, N, N, N ', N', N,, _ hexa(alkoxy fluorenyl) melamine as a main component, weight average degree of polymerization is 1.3), 2.2 parts by mass as a photopolymerization initiator, 2-benzyl-2-dimethyl Amino-l-(4-N-carbolinylphenyl)butane-indole-one (manufactured by CIBA SPECIALTY CHEMICALS, trade name IRGACURE 369), and propylene glycol monomethyl ether acetate as a solvent are mixed to prepare a solid component. A coloring composition (CR2) having a concentration of 20% by mass. The evaluation was carried out in the same manner as in Example 1 except that the coloring composition (CR2) was used instead of the coloring composition (CR1)a. The evaluation results are shown in Table-81 - 201214045. Example 3 12 5 parts by mass of the pigment dispersion liquid (α·1), 28.3 parts by mass of the dye solution C, and 1 6 _ 1 part by mass of the binder as the binder resin Resin (β 1 ), 5.5 parts by mass of a cross-linking agent, μ_4〇2 (a mixture of dipentaerythritol hexaacrylate and dipentaerythritol pentaacrylate) and 2.4 mass-injured m\V-30 (using N, N, N, N, N, N-hexa(oxyalkyl) melamine as a main component, weight average degree of polymerization of 1.3) as a photopolymerization 2 parts by mass of 2 -benzyl-2-dimethylamino-1-(4-indole- phenylphenyl)butane- ketone (manufactured by CIBA SPECIALTY CHEMICALS, trade name IRGACURE 369), and The propylene glycol monothiol group as a solvent was mixed with acetic acid to prepare a coloring composition (cr 3) having a solid content concentration of 20% by mass. Evaluation was carried out in the same manner as in Example 1 except that the coloring composition (CR3) was used instead of the coloring composition (CR1). The evaluation results are shown in Table 1 ° Comparative Example 1 18.1 parts by mass of the pigment dispersion liquid (A-丨), 45 parts by mass of the pigment dispersion liquid (A-2), and 6.1 parts by mass of the binder resin as the binder resin ( b 1) 5 parts by mass as a crosslinking agent Μ-402 and 2.4 parts by mass of MW-30 manufactured by Sanhe Chemical Co., Ltd., 2.2 parts by mass as a photopolymerization initiator 2- Benzyl-2-dimethylamino-1-(4-indole-phenyl-phenyl)butane-indole-one (manufactured by ciBA SPECIALTY CHEMICALS, trade name IRGaCURE 369), and propylene glycol monomethyl ether as a solvent The acetate was mixed to prepare a coloring composition (CR4) having a solid content concentration of 20% by mass. -82-201214045 Evaluation was carried out in the same manner as in Example 1 except that the coloring composition (CR4) was used instead of the coloring composition (CR1). The evaluation results are shown in Table 1 ° Comparative Example 2 8.1 ZiLi pigment dispersion (8_1), 24.2 parts by mass of dye solution as binder resin 16.1 parts by mass of binder resin (Β1), 5.5 as a parent agent Manufactured by Toago Seisakusho Co., Ltd. 4〇2 Quality 1 Injury 2 and mW-30 manufactured by CHEMICAL Co., Ltd., 22 parts by mass of 2-benzyl-2-dimethylamino-1 as a photopolymerization initiator 4_Temicinylphenyl)butan-1-one (manufactured by CIBA SPECIALTY CHEMICALS, trade name IRGACURE 369), and propylene glycol monomethyl ketone acetate as a solvent to prepare a solid content concentration of 2% by mass Coloring composition (CR5).

The evaluation was carried out in the same manner as in Example 1 except that the coloring composition (CR5) was used instead of the coloring composition (CR1). The evaluation results are shown in Table 1 ° Example 4 12.3 parts by mass of the pigment dispersion liquid (a-3), 31.3 parts by mass of the dye solution E, and 6 parts by mass of the binder resin (B丨) as the binder resin. 5.5 parts by mass of a crosslinking agent M-402 manufactured by Toagosei Co., Ltd. and 2.4 parts by mass of MW-30 manufactured by Sanhe Chemical Co., Ltd., and 2.2 parts by mass of 2-benzyl-2-diindole as a photopolymerization initiator Amino-M4-N-tylinylphenyl)butane-1_one (manufactured by CIBA SPECIALTY CHEMICALS, trade name IRGACURE 369), and propylene glycol monodecyl ether acetate as a solvent are mixed to prepare a solid concentration of 20% by mass. % colored composition (CR6). • 83-201214045 Evaluation was carried out in the same manner as in Example 1 except that the coloring composition (CR6) was used instead of the coloring composition (CR1). However, at this time, the chromaticity coordinate value x, the stimulus value (Y), the film thickness, and the contrast at the chromaticity coordinate value y = 590.590 are obtained. The evaluation results are shown in Table i. Comparative Example 3 12.1 parts by mass of the pigment dispersion liquid (A_3), 32 parts by mass of the pigment dispersion liquid (A-4), 16 parts by mass of the binder resin (B1) as a binder resin, and 5 5 as a crosslinking agent. M-402 and 2_4 parts by mass of Sanwa Chemical Co., Ltd. MW-30, manufactured by Toagosei Co., Ltd., and 2 2 parts by mass of 2-benzyl-2-diguanidinyl-1 as photopolymerization initiator -(4-Ν-tyrosolinylphenyl)butane-anthracene ketone (manufactured by CIBA SPECIALTY CHEMICALS, trade name IRGACURE 369), and propylene glycol monodecyl ether acetate as a solvent to prepare a solid content concentration of 20 % of the color composition. Evaluation was carried out in the same manner as in Example 4 except that the coloring composition (CR7) was used instead of the coloring composition (CR6). The evaluation results are shown in Table 1 ° Comparative Example 4 12.1 parts by mass of the pigment dispersion liquid (A_3), 3 parts by mass of the dye solution F, 16.1 parts by mass of the binder resin (B1) as the binder resin, as the parent compounding agent 5.5 parts by mass of m-402 manufactured by Toagosei Co., Ltd. and 2.4 parts by mass of MW-30 manufactured by Sanhe Chemical Co., Ltd., and 2.2 parts by mass of 2-benzyl-2-diguanylamino group as a photopolymerization initiator 1-(4-Ν-咮琳基基基)butane-anthracene-ketone^ is prepared by mixing with eight SPECIALTY CHEMICALS company, trade name IRGACURE 369), and solvent propylene glycol-84-201214045 monomethyl ether acetate vinegar. A coloring composition (CR8) having a solid content concentration of 2% by mass. The evaluation was carried out in the same manner as in Example 4 except that the coloring composition (CR8) was used instead of the coloring composition (CR6), and the evaluation results were shown in Table Example 5. 25.6 parts by mass of the pigment dispersion liquid (A_5), 26 mass Part of the pigment dispersion (A-6), 2.2 parts by mass of the dye solution (3, 16 as a binder resin), a straight-line binder resin (B 1 ), 5.5 parts by mass as a crosslinking agent, manufactured by Toagosei Co., Ltd. M-402, 2 parts by mass as a photopolymerization initiator, 2-benzyl-2-diguanylamino-indole-...zurryloylphenyl)butanone (manufactured by CIBA SPECIALTY CHEMICALS, trade name) IRGACURE 3 6 9) A coloring composition (cr9) having a solid content concentration of 20% by mass was prepared by mixing AFACF_554 as a fluorine-based surfactant enamel company and as a solvent. Evaluation was carried out in the same manner as in Example 1 except that the coloring composition (CR9) was used instead of the coloring composition (CRi). However, at this time, the chromaticity coordinate value y and the stimulating value at the chromaticity coordinate value x = 0.655 were obtained (contrast. The evaluation results are shown in Table 1. ' Further Example 6 23.6 parts by mass of the pigment dispersion liquid (A_5), 2 〃 〇 〇 份 颜料 颜料 颜料 颜料 ( ( ( ( ( ( ( ( ( ( ( 3.2 3.2 3.2 3.2 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料Co., Ltd. made Μ-402, as a light poly a button such as ° ^ ~ χ 〇 〇 始 始 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 Base) butane-1-1 -85- 201214045 (CIBA SPECIALTY CHEMICALS company, trade name

IRGACURE3 6 9), as a fluorine-based surfactant, 2 parts by mass of MEGAFAC F-554 manufactured by DIC Co., Ltd., and a mixture of solvents as a solvent to prepare a colored component (CR1〇) having a solid concentration of 20% by mass. The evaluation was carried out in the same manner as in Example 5 except that the coloring composition (CR10) was used instead of the coloring composition (CR9). The evaluation results are shown in Table 1. Example 7 22.3 parts by mass of the pigment dispersion liquid (A_5), the mass parts of the pigment dispersion liquid (A-6), 1.2 parts by mass of the dye solution, and the i6 i mass parts as the binder resin were bonded. Resin (B 1 ), 5 parts by mass as a crosslinking agent, M-402, manufactured by Toagosei Co., Ltd., and 2·2 parts by mass as a photopolymerization initiator, 2-benzyl-2-diguanamine hydrazine啉 笨 笨) Butane ketone (trade name, CIBA SPECIALTY CHEMICALS)

IRGACURE 369), as a fluorine-based surfactant, 2 parts by mass of MEGAFAC F_554, manufactured by dic Co., Ltd., and cyclohexane as a solvent, to prepare a color composition having a solid concentration of 2% by mass (cri: in addition to the use of &amp; The composition (CR11) was evaluated in the same manner as in Example 5 except for the coloring composition (cr9). The evaluation results are shown in Table 10. Example 8 Leaf knife powder (A·5) 2.6 parts by mass of pigment dispersion (A-6), 1.3 parts by mass of dye solution meter J 忭 horse binder resin 1 6 · 1 201214045 parts by mass of binder resin (Bl), as a crosslinking agent 5.5 parts by mass of East Asia Synthetic Co., Ltd. M-402 2-benzyl-2-dimethylamino-1-(4_N_imilinyl)-butane-butanone (manufactured by CIBA SPECIALTY CHEMICALS, trade name 0.2) The cyclohexanone composition (CR12) of the DIC solvent (CR12) IRGACURE3 69), the MEGAFAC F-554 manufactured by Co., Ltd. as a fluorine-based surfactant, and the coloring of the solid component concentration of 20% by mass as a mixture, in addition to the coloring composition (CR12) instead of coloring composition (CR9 The evaluation was carried out in the same manner as in Example 5. The evaluation results are shown in Table 1. Example 9 22.6 parts by mass of the pigment dispersion liquid (A_5), 56 parts by mass of the pigment dispersion liquid (A-6), 3.2 mass a dye solution ruler, a binder resin (B1) as a binder resin, a binder resin (B1) as a binder, 55 mass parts of M_4〇2 as a crosslinking agent, and a mass of 2 2 as a photopolymerization initiator 2-mercapto-2-dimethylamino group W4_N_morpholinyl phenyl)butane ketone (manufactured by CIBA SPECIALTY CHEMICALS, trade name IRGACURE 3 6 9), as a fluorine-based surfactant 〇·2 MEGAFAC ?_554 manufactured by DIC Co., Ltd. and a cyclohexane as a solvent to prepare a colored composition (cri3) having a solid concentration of 2% by mass. In addition to using a coloring composition (CR13) instead of a coloring composition (cr9) Evaluation was carried out in the same manner as in Example 5 except for the above. The evaluation results are shown in Table 1. -87- 201214045 Example 1 ο 24.2 parts by mass of pigment dispersion liquid (Α_5), 46 parts by mass of pigment dispersion liquid (Α-6), 2_2 Beiley dye solution L, and 丨6" parts by mass of binder resin Binder resin (B1), 5 parts by mass as a crosslinking agent, M-402, manufactured by Toagosei Co., Ltd., as a photopolymerization initiator, 2 parts by mass of 2-...-dimethylamino-[N-... = (manufactured by CIBA SPECIALTY CHEMICALS, trade name: IRGACURE3 6 9), as a fluorine-based surfactant, 2 parts by mass of MEGAFAC F-554 manufactured by DIC Co., Ltd., and cyclohexanone as a solvent to prepare a solid content concentration of 2〇 The color % composition (CR14) was evaluated in the same manner as in Example 5 except that the coloring composition (CR14) was used instead of the coloring composition (CR9). The evaluation results are shown in Table 1. Comparative Example 5 22.1 parts by mass of the pigment dispersion liquid (A_5), 4 parts by mass of the pigment dispersion liquid (A_6), and 6.1 parts by mass of the binder resin (B 1) as the binder resin, and 5.5 parts by mass as the crosslinking agent. M_402 manufactured by Toagosei Co., Ltd. and 2.4 parts by mass of MW-30 manufactured by Sanhe Chemical Co., Ltd. as a photopolymerization initiator 2 2 parts by mass of 2·benzyl 2 dioxin-l-(4_Ν味琳基Butyl-based butane-1-one (manufactured by CIBA SPECIALTY CHEMICALS, trade name IRGACURE 369), 0.2 parts by mass of fluorochemical surfactant MEGAFAC F-554, and propylene glycol monomethyl ether B as solvent The acid ester was mixed to prepare a colored composition (CR15) having a solid concentration of 2% by mass. -88-201214045 Evaluation was carried out in the same manner as in Example 5 except that the coloring composition (CR15) was used instead of the coloring composition (CR9). The evaluation results are shown in Table 1. 〇Comparative Example 6 24.1 parts by mass of the pigment dispersion liquid, 4.6 parts by mass of the pigment dispersion liquid (Α-6), 2.2 parts by mass of the dye solution μ, and 6 parts by mass of the binder resin The binder resin (B1), 5.5 parts by mass of M-402 as a crosslinking agent, and 2.4 parts by mass of MW-30 manufactured by Sanhe Chemical Co., Ltd., and 2.2 parts by mass as a photopolymerization initiator 2 -Benzyl-2-dimethylamino-1.(4·Ν-味琳基基基)丁丁-丨-ketone (manufactured by CIBA SPECIALTY CHEMICALS, trade name IRgaCURE369), as a surfactant of 0.2 A mass composition (CR丨6) having a solid content concentration of 20% by mass was prepared by mixing MEGAFAC F-554 manufactured by DIC Co., Ltd. and cyclohexanone as a solvent. The evaluation was carried out in the same manner as in Example 5 except that the coloring composition (CR16) was used instead of the coloring composition (CR9). The evaluation results are shown in Table 1. -89-201214045 [Table 1] Coloring composition coloring 剤X y Y Film thickness (μηι) Comparative Example 1 CR1 B15:6/Compound A 0.140 0.080 9.55 2.0 14800 Example 2 CR2 B 15:6/Compound B 0.140 0.080 9.38 2.0 15200 Example 3 CR3 B15:6/Compound C 0.140 0.080 9.47 2.0 14400 Example 4 CR6 G58/Compound E 0.300 0.590 63.2 2.0 13500 Example 5 CR9 R254/R177/Compound G 0.655 0.327 20.2 2.2 9800 Example 6 CR10 R254/R177/Compound Η 0.655 0.327 19.9 2.2 9500 Example 7 CR11 R254/R177/Compound I 0.655 0.327 20.0 2.2 9300 Example 8 CR12 R254/R177/Compound J 0.655 0.327 20.1 2.2 9500 Example 9 CR13 R254/R177/Compound Κ 0.655 0.327 19.8 2.2 9600 Example 10 CR14 R254/R177 / Compound L 0.655 0.327 19.9 2.2 9400 Comparative Example 1 CR4 B15: 6/V-23 0.140 0.080 8.34 2.1 8900 Comparative Example 2 CR5 Β15:6/ΒΒ-7 Faded and Comparative Example 3 as a light-colored brown color Comparative Example 3 CR7 G58/Y150 0.300 0.590 61.2 2.1 13000 Comparative Example 4 CR8 G58/BY-21 Cured film which faded and became pale coke brown Comparative Example 5 CR15 R254/R177 0.655 0.327 19.2 2.2 9300 Comparative Example 6 CR16 R254/R177 /BR1 0.655 0.327 15.2 2.2 9200 In Table 1, the meanings are as follows. "B15: 6" is CI Pigment Blue 15: 6, "G58" is CI Pigment Green 58. "V-23" is CI Pigment Violet 23, "BB-7" is CI Basic Blue 7, and "Y150" is CI·Pigment Yellow 150. The so-called "BY-21" is a CI-acceptable yellow 21, so-called " R254" is CI Pigment Red 254, "R177" is CI Pigment Red 177, and "BR1" is CI Basic Red 1. [Simple description of the diagram] None. [Main component symbol description] No 0 -90-

Claims (2)

201214045 VII. Patent application scope: 1 · A coloring composition comprising a coloring composition of (A) a coloring agent, (B) a binder resin, and (C) a crosslinking agent, wherein the coloring composition contains the following formula (1) The coloring agent represented is (A) a coloring agent, X+Z-(1) [In the formula (1), X + represents a cationic chromophore, and z- represents a conjugated base of an organic acid having a halogenated hydrocarbon group. ]. 2. The coloring composition according to claim 1, wherein the z is an anion represented by the following formula (la) or an anion represented by the following formula (lb) [in the formula (la), Ri represents The halogenated hydrocarbon group R—S〇2—Nws〇2—r2 (10) having a linking group of a carbon atom, a hydrogen atom, a halogen atom, and a halogen atom may also have an independent representation of each other in the formula (lb). , hydrogen atom and tooth xin © do not, there are anti-atomic long-term atomic ruthenium atomic linker, R2 can also be mutually # ^ _ hydrocarbyl 3, J J is bonded to each other to form a ring]. Shen π patent range! Or a coloring composition of two, a hydrocarbon group based on a fluorinated hydrocarbon group. /, 中中画画 4' If the patent application scope is the coloring composition of the following formula, the basis of the above-mentioned heart, or the following formula (Μ (1'1) -91- 201214045 [In the formula R19, it represents fj milk atom, fluorine atom, alkyl group, fluorinated alkyl group, alicyclic hydrocarbon group, gas-burning alkoxy group, fluorinated alkoxy group, r2Qc〇or21 - or r20coor21cfh-(r20俜泸甘^ Your pit base, alicyclic hydrocarbon group, heteroaryl group or substituted or unsubstituted aryl group, R21 system represents anthracene or alkylene group) η It means an integer of 1 or more, and the total car-Pudu k Μ Ί *" is not a dangling key], (J-2) [In the formula (1-2) 'R丨4-R丨8 each independently represents a hydrogen atom, a fluorine atom, a hydroxyl group, an alkyl group, a fluorinated alkyl 'alkoxy group or an alkanesulfonyl group "*" indicates a dangling bond, but at least i of the RU to R 8 is a fluorine atom or a fluorinated alkyl group]. 5. The coloring composition of claim 1 or 2, wherein the bismuth + diaryl arsenic chromophore, methine chromophore, azo chromophore, An aryl decane chromophore, a quinone imine chromophore 蒽S Kun chromophore or a stupid and xanthene chromophore. 6. The colored composition of claim 1 or 2, which further comprises (D) a photopolymerization initiator. A color filter comprising a color former formed using the colored composition according to any one of claims 1 to 6. 8. A display element' having a color calender as in claim 7 of the patent application. -92- 201214045 IV. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: None 0. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: