201217162 六、發明說明： 【發明所屬之技術領域】 [0001]本發明係為有關於一種具有環保水性樹脂的透濕防水抗 黏性加工布的製造方法’尤指利用水性樹脂塗佈織物表 面二層候，再進行織物的表層抗黏劑的塗佈，以替代溶 劑型樹脂的塗佈，合乎環保性與具有抗黏的特性。 【先前技術】 [〇〇〇2] —般傳統型的樹脂塗佈加工布，係利用溶劑型樹脂直接 塗佈於織物表層為主完成一種透濕防水產品，單以水性 PU樹脂直接塗佈於布主，其透濕度與耐水性較差，而表 層使用溶劑型PU樹脂對於近年環保意識加強，溶劑型樹 脂塗佈於表層後織物透濕性、耐磨性及防水性與親水性 水性樹脂塗佈於表層後織物之物性比較較差，所以一般 傳統型織物不具有環保性與織物物性的優異性，另以加 工方法而言，其織物經由塗佈後往往會造成捲取時造成 織物與織物之間產生黏著現象，本發明南J對上述之缺失 改進而發明一種『具有環保水性樹脂籩濕防水加工布及 其方法』’為一種創新發明乏塗佈加工，主要係於不同 成份之底層上利用親水性樹脂作為三層塗佈，為具有環 保性的水性樹脂作為織物的塗佈加工，而所經由塗佈之 織物具有高透濕度及高耐水壓及抗黏的產品，在於市場 上的應用極廣例如；衣料用布（衣服、褲子）、醫療用布（ 床單、枕碩套及防水貼膜）及休閒用布（帳蓬、睡袋、鞋 子、巾自子、皮帶、尿布及手套）。 【發明内容】 099136296 表單編號ΑΟίοι 第4頁/共14頁 0992063459-0 201217162 #發明主要目的’係要出—種具有環保水性樹脂的透濕 布的製造方法專利中請，主要是利用第 到刀塗佈環保水性樹脂為底層(第-層)塗佈經過一次 ’再利用第—刮刀塗佈中間層（第二層）水性樹脂 、&過第供相後’再利用第二刮刀進行表層（第三層）塗 佈再左過一次烘箱的烘乾使織物具有增加高透濕度與 k黏隹’與傳統型利用溶劑型樹脂進行塗佈比較具有優 γ的手感耐水屋與抗點特性，因此，為了使塗佈水性 樹的織物_第—棋箱另織物再塗佈抗黏劑是為了 〇 ，布與布之間不會造絲著現象，並為傳統使用溶劑型 樹月曰進订塗佈加卫布的缺失改善，使本發明的產品除了 ‘ *有織物優良特性兼具環保意識觀念增進產業上之價質 感。 【實施方式】 _本發B月係為—種『具有環保水性樹脂透濕防水抗黏性加 工布的製造方法』’請參閱圖1與圖2所示，其中圖1為本 發明之加工製造方法流程圖；首先以15Dxl5D耐隆平織規 〇 格布經由退漿、精練、染色及預定型後，並經過壓光處 理’以10(TC〜12(TC溫度進行烘乾其烘乾時間為45秒~1 分完成。上述前處理過之耐隆平織物a之底層（第一層）A1 經·過刮刀塗佈c進行親水性PU(POLYURETHANE)樹脂b(選 自勝暉公司的商品）的塗佈量為70~200g/m2，經過烘箱 N〇. l(d)80°C〜100°Cxl分完成具有底層A1的織物e，其 中第二刮刀塗佈與烘箱N0. 2無作用狀態為第一步驟。 [0005] 請參閱圖1所示的第二步驟：將塗佈具有底層A1的耐隆平 099136296 表單編號A0101 第5頁/共14頁 0992063459-0 201217162 織物e進仃親水性ρϋ樹脂f的塗佈〇㈣添加入增稍劑# 經過第—到刀2以70〜200仏2塗佈量塗佈，再經過棋箱。 N〇. lh 8GC〜1G(rCxl分完成具有底層Α1與中間層Α2的 織物i，織物i再利用抑水性樹脂jl〇〇%添加入架橋船 ~5%、抗黏劑卜3%及增稠飢5〜1%，再利用第二刮 佈7〇’Og/m2塗佈後，再經過烘箱N〇 2 18〇。〔 xl刀即π成具有表層A3的織物m具有水壓5咖_ Η 上料濕度5_^細以上之高材水壓與高透濕= 產品。 _6] 4參閱圖2與圖3所轉為本發明織物塗佈結構分解圖， 織物a作為基材，先以pu水性樹脂作為底層ai塗佈， 以水性樹脂添加_劑再塗佈中間層A2 ,捲取後的織物& 再塗佈添加有黏_、抗黏劑及架橋劑在於表層Μ，因a 此H七述加工方法可以取的織物a表層為三層結構a 1 A2，A3。 ’ [0007] 【實施例1】 ：'._ 卜. :ί Γ :.. . ；..i； ' _取耐隆平織物經退漿L;染色及預定型而進行壓光 處理，爾來以110X：的溫度進行供乾其乾燥時間為5〇秒。 对隆布（15DX15D)作為塗佈加工布，以下列之塗佈液對。 織物進行底層第-次塗佈，而塗制樹脂為聚尿醋（p〇 -LYURETHANE)樹脂，塗佈量為75 g/m2，以乾燥8〇以 分鐘進行烘乾，再以浮游心㈤士⑽仏）之塗伟加 工方法進行表層塗佈之親水性塗佈加I，塗佈量i5〇 g/m2隨後進人烘箱進行啊χ1分鐘及15代小㈣秒之 熱處理工程，即得一透濕防水加工布 0992063459-0 099136296 表單編號A0101 第6頁/共丨4頁 201217162 其所使用塗佈加工液如下： 底層塗佈加工液： 聚尿酯樹脂100% 〇 闺又，塗佈液對織物進行第二次塗佈進行中間層的塗佈， 而塗佈用樹脂為聚尿醋樹脂，再以第一刮刀之塗佈加工 方法進行表層塗佈之親水性塗佈加工塗佈量15{^、2，並 以第一烘箱乾燥80°Cxl分鐘進行烘乾，隨後進入第二刮 刀之塗佈加工方法進行表層塗佈親水性pu樹脂的塗佈加 工塗佈量150g/m2 ’以第二烘箱乾燥8(rcxl分鐘進行烘 乾’即得一透濕防水防黏性的加工布。 選自如下塗佈液一 [0010] 中間層塗佈加工液 PU樹脂100% 增稠劑0. 5% [0011] 表層塗佈加工液： PU樹脂100% 〇201217162 VI. Description of the Invention: [Technical Field of the Invention] [0001] The present invention relates to a method for producing a moisture-permeable waterproof and anti-adhesive processing cloth having an environmentally-friendly water-based resin, in particular, a surface of a fabric coated with an aqueous resin. At the same time, the surface layer of the fabric is coated with an anti-adhesive agent to replace the solvent-based resin, which is environmentally friendly and has anti-stick properties. [Prior Art] [〇〇〇2] The general-purpose resin-coated fabric is directly coated on the surface of the fabric with a solvent-based resin to complete a moisture-permeable waterproof product, which is directly coated with an aqueous PU resin. The main body of the cloth has poor moisture permeability and water resistance, and the solvent-based PU resin on the surface layer is more environmentally conscious in recent years. The solvent-based resin is coated on the surface layer, and the moisture permeability, abrasion resistance and water repellency of the fabric are coated with the hydrophilic water-based resin. The physical properties of the fabric after the surface layer are relatively poor, so the conventional fabric is generally not environmentally friendly and has excellent fabric properties. In addition, in terms of processing methods, the fabric is often coated between the fabric and the fabric after being wound. In the present invention, South J has improved the above-mentioned defects and invented a "green water-repellent resin dampness waterproof processing cloth and method thereof" as an innovative invention of the lack of coating processing, mainly on the bottom layer of different components to utilize hydrophilic As a three-layer coating, the resin is coated with an environmentally-friendly water-based resin as a fabric, and the coated fabric has a high permeability. The high degree of water pressure resistance and anti-adhesive products are widely used in the market, such as cloth for clothes (clothes, pants), medical cloth (sheets, pillows and waterproof films) and casual cloth (tents, Sleeping bags, shoes, towels, belts, diapers and gloves). SUMMARY OF THE INVENTION 099136296 Form No. ΑΟίοι Page 4 of 14 Page 0992063459-0 201217162 #Main purpose of the invention is to produce a kind of moisture-permeable cloth with environmentally-friendly water-based resin. In the patent, please use the first knife. Applying the environmentally-friendly water-based resin to the bottom layer (the first layer) is applied once through the 'reuse of the first-blade coating intermediate layer (the second layer) of the aqueous resin, & after the first supply phase, and then using the second scraper to perform the surface layer ( The third layer) coating and drying in the left oven once makes the fabric have high moisture permeability and k-sticking. Compared with the conventional coating with solvent-based resin, it has excellent γ-like hand-resistance and water resistance resistance. In order to make the fabric coated with water-based tree _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The lack of improvement of Bujiaweibu makes the product of the present invention not only have the excellent characteristics of fabrics, but also the concept of environmental awareness to enhance the quality of the industry. [Embodiment] _ This issue is a "manufacturing method of environmentally-friendly water-based resin moisture-permeable waterproof and anti-adhesive processing cloth" as shown in Fig. 1 and Fig. 2, wherein Fig. 1 is a manufacturing process of the present invention. Method flow chart; firstly, the 15Dxl5D Nylon-flat woven fabric is desiccated, scoured, dyed and pre-formed, and then calendered to '10 (TC~12 (TC temperature drying its drying time is 45) It is completed in seconds to 1 minute. The bottom layer (first layer) A1 of the above-mentioned pretreated treated endurance fabric a is coated with a hydrophilic PU (POLYURETHANE) resin b (a product selected from Shenghui Co., Ltd.). The fabric having the bottom layer A1, wherein the second blade coating and the oven N0. 2 have no effect state, the drying agent N. l (d) 80 ° C ~ 100 ° C x l minutes to complete the fabric e with the bottom layer A1, wherein the second blade coating and the oven N0. [0005] Please refer to the second step shown in FIG. 1 : The coating with the bottom layer A1 will be coated with the flat layer 099136296 Form No. A0101 Page 5 / Total 14 pages 0992063459-0 201217162 Fabric e into the hydrophilic ρ ϋ resin f Coating 〇 (4) added to the addition agent # After the first - to the knife 2 coated with 70~200 仏 2 coating, and then Chess box. N〇. lh 8GC~1G (rCxl finished fabric i with bottom layer Α1 and intermediate layer Α2, fabric i reused water-repellent resin jl〇〇% added to bridge boat ~5%, anti-adhesive agent 3% And thickening hunger 5~1%, and then coating with the second scraping cloth 7〇'Og/m2, and then passing through the oven N〇2 18〇. [xl knife is π into the fabric with surface layer A3 with water pressure 5 Coffee _ Η Feeding humidity 5_^ above the high material water pressure and high moisture permeability = product. _6] 4 Refer to Figure 2 and Figure 3 to turn into the exploded view of the fabric coating structure of the present invention, fabric a as a substrate, first The pu water-based resin is used as the bottom layer ai coating, the water-based resin is added with the agent and the intermediate layer A2 is applied, and the wound fabric is added. The coating is added with the adhesive, the anti-adhesive agent and the bridging agent in the surface layer, because a The surface layer of the fabric a which can be taken by this H-seven processing method is a three-layer structure a 1 A2, A3. [Example 1] : '._ Bu. : Γ Γ :.. . ;..i; ' _ Take the Nylon flat fabric by desizing L; dyeing and pre-formed and calendering, and then dry at 110X: The drying time is 5 〇 seconds. For Longbu (15DX15D) as a coated fabric, With the following The coating liquid is subjected to the first coating of the bottom layer, and the resin is a polyacetal (p〇-LYURETHANE) resin, and the coating amount is 75 g/m2, and drying is performed for 8 minutes in a dry state, and then dried. The hydrophilic coating of the surface coating was carried out by the coating method of the floating heart (five) (10) 仏 (10) ,), and the coating amount i5〇g/m2 was then carried into the oven for χ 1 minute and 15 generations of small (four) seconds heat treatment project. , that is, a moisture-permeable waterproof processing cloth 0992063459-0 099136296 Form No. A0101 Page 6 / Total 4 pages 201217162 The coating processing liquid used is as follows: The bottom coating processing liquid: Polyurethane resin 100% 〇闺 again, The coating liquid is applied to the fabric for the second time to apply the intermediate layer, and the coating resin is a polyurethane resin, and the surface coating is applied by the first doctor blade coating method. The amount of cloth is 15{^, 2, and dried by drying in a first oven at 80 ° C for 1 minute, and then into a coating method of the second doctor blade to apply a coating coating amount of surface-coated hydrophilic pu resin of 150 g/m 2 . 'Drying in a second oven 8 (drying in rcxl minutes) gives a moisture-permeable waterproof Sticky cloth processing. The coating liquid is selected from the following: [0010] Intermediate layer coating processing liquid PU resin 100% thickener 0. 5% [0011] Surface coating processing liquid: PU resin 100% 〇
三聚氰胺架橋劑5% [0012] 抗黏劑3% [0013] 增稠劑 0.3% [0014] 經過實施過程以穫得如下超輕薄量化布（i5D)的物性（透 濕度、耐水壓及防黏性）特性— [0015] 表一、超輕薄量化布物性測試結果： —--- --『.. ___ [0016] ϋ度 透濕度 耐水壓 塗佈量 099136296 表單編號Α0101 第7頁/共14頁 0992063459-0 201217162 物性 g/m2. D g/m2. D "~~- _2〇 -----1 g/m2 顏色 (JIS L (ASTM E- (JIS (布 1099A1法 96 BW 法 L1 092 法） + f i lin) ) ) 黑色 2602 3080 ~~——--- --- 2583 33 + 20 (15D)色 布 黑色布三 2160 4245 2157 ---~~—^ 33 + 20 次水洗後 白色布 2551 m\i 1927 -一 33 + 20 (15D) 白色布三 2309 4083 1410 --—-一 33 + 20 次水洗後 傳統非超 1600 2500 —----- 1300 ~ —— 68 + 25 輕薄布 (70D) !-主山An _ 上表指出超輕薄量化布（1 5D)與非超輕薄布（ 度與耐水壓的相互比較，超輕薄量化布（15D)優於非超輕 薄布（70D)例如；以ASTM E-96 BW法測得黑色布（15D)其 透濕度g/m2_ D為3080則傳統型布（70D)其透濕度g/ m .D為2500得知超輕薄量化布（i5D)較優。 [0017] 表二、超輕薄布防黏性比較結果: 樣品 物性 第一刀塗佈製程表 面粘性 第二刀塗佈製程表 面枯性 90°剥離強度 —------ 0. 70 kgf 0.21 kgf — 表單編號A0101 第8頁/共14頁 0992063459-0 099136296 201217162 (in) (JISZ0237)Melamine bridging agent 5% [0012] Anti-adhesive agent 3% [0013] Thickener 0.3% [0014] After the implementation process to obtain the following ultra-lightweight quantitative cloth (i5D) physical properties (humidity, water pressure and anti-adhesive) Characteristics - [0015] Table 1, ultra-thin and quantitative fabric test results: —--- --『.. ___ [0016] 透 degree moisture and moisture resistance coating amount 099136296 Form No. 1010101 Page 7 / Total 14 Page 0992063459 -0 201217162 Physical property g/m2. D g/m2. D "~~- _2〇-----1 g/m2 Color (JIS L (ASTM E- (JIS (cloth 1099A1 method 96 BW method L1 092 method) ) + fi lin) ) ) Black 2602 3080 ~~——--- --- 2583 33 + 20 (15D) Color cloth black cloth three 2160 4245 2157 ---~~—^ 33 + 20 times washed white cloth 2551 m\i 1927 - a 33 + 20 (15D) white cloth three 2309 4083 1410 --- a 33 + 20 wash after the traditional non-super 1600 2500 —----- 1300 ~ —— 68 + 25 light cloth (70D) !-Main Mountain An _ The above table indicates that the ultra-lightweight quantitative cloth (1 5D) and the non-ultra-light cloth (the degree and the water pressure resistance are compared with each other, the ultra-lightweight quantitative cloth (15D) is superior to the non-ultra-light cloth. 70D) For example; the black cloth (15D) measured by the ASTM E-96 BW method has a moisture permeability g/m2_D of 3080, and the conventional type cloth (70D) has a moisture permeability g/m. D is 2500 to obtain an ultra-lightweight quantitative cloth. (i5D) is superior. [0017] Table 2, super light fabric anti-sticking comparison results: sample physical properties first knife coating process surface viscosity second knife coating process surface dryness 90 ° peel strength ------- 0. 70 kgf 0.21 kgf — Form No. A0101 Page 8 of 14 0992063459-0 099136296 201217162 (in) (JISZ0237)
_ --- 5. 〇 cm J----- 12. 0cm 短表示越粘，傳統型布僅作第一刀塗佈，而超輕薄布（15 要經過第—刀塗佈與第二刀的塗佈，在於表面黏性 方面超輕薄布（15D)優於傳統型布。_ --- 5. 〇cm J----- 12. 0cm short means more sticky, traditional cloth is only used for the first knife coating, and ultra-light cloth (15 is subject to the first knife coating and the second knife The coating is superior to the conventional fabric in terms of surface stickiness in ultra-thin cloth (15D).
[0019] [0020] [0021] [0022][0020] [0022] [0022]
[0023] 本發明係為-種具有環保水性樹脂透濕防水抗黏性加工 布及其方法’已符合專利要件’妥依法提出專利申請。 【圖式簡單說明】 圖1係為本發明之加工方法流程圖。 圖2係為本發明之織物*佈錄構分解齡。 圖3係為本發明之織物塗佈示意圖。 【主要元件符號說明1 a，e，i，m 織物 [0024] A1 底層 [0025] A 2中間層 [0026] A 3 表層 [Q027] b，f PU樹脂[0028] c，g 第一刮刀 099136296 *單編號A0101 第9頁/共14頁 0992063459-0 201217162 [0029] k第二刮刀 [0030] d，h 烘箱 NO.l [0031] 1 烘箱NO. 2 0992063459-0 099136296 表單編號A0101 第10頁/共14頁[0023] The present invention is a kind of environmentally-friendly water-based resin moisture-permeable waterproof and anti-adhesive processing cloth and its method 'has met the patent requirements' and legally filed a patent application. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flow chart of a processing method of the present invention. Fig. 2 is a view showing the decomposition age of the fabric * fabric of the present invention. Figure 3 is a schematic view of the coating of the fabric of the present invention. [Main component symbol description 1 a, e, i, m fabric [0024] A1 underlayer [0025] A 2 intermediate layer [0026] A 3 surface layer [Q027] b, f PU resin [0028] c, g first scraper 099136296 *单编号A0101 Page 9/14 pages 0992063459-0 201217162 [0029] k second scraper [0030] d, h oven NO.l [0031] 1 oven NO. 2 0992063459-0 099136296 Form No. A0101 Page 10 / Total 14 pages