201217584 [0001] [0002] Ο ο 099136680 發明說明： 【發明所屬之技術領域】 本發明係與水電解裝置有關，尤指一種具有可選擇 製出氧氣、臭氧水或臭氧之水電解裝置。 【先前技術】 按，臭氧（0 3)係為一種安全、乾淨以及強效的 氧化劑，目前已被廣泛運用製消毒或解毒用途上，其應 用範圍廣及個人口腔衛生、居家清潔與洗滌，乃至於工 業加工和廢水處理。 然而傳統用於快速製造臭氧的方式大致可分為紫外 線法、無聲放電法以及尖端放電法，其中： 紫外線法係利用紫外線對空氣中的氧分子（0 2 ) 作用而產生微量的臭氧，其是由一個氧分子（0 2)和 氧原子（0)結合成三氧原子的物質（Ο 3 )。 無聲放電法則是利用石英玻璃管、耐熱玻璃、陶瓷 、不鏽鋼等誘電體，當直流高壓高頻電流通過時，與接 地電極產生放電電暈現象，以電擊通過之空氣而產生分 解反應，將氧分子（Ο 2 )之鏈鍵擊潰形成氧原子（從 302成為203)以得到臭氧。 尖端放電法則是利用電子變壓器產生高壓，並利用 多根金屬針以尖端放電形成如同閃電電擊之電離作用， 將氧分子（0 2)之鏈鍵擊潰形成帶負電的氧原子（0 )，而氧原子再與空氣中的氧分子結合即可得臭氧（03卜 惟，不論採用上述何種方式產生臭氧，其共通點就 是利用空氣中的氧分子為原料，來作為電擊分解成帶負 表單編號Α0101 第3頁/共17頁 0992064101-0 201217584 電的氧原子，然而空氣中除氧氣外，另有大量之氮氣存 在，因此在電擊解離作用過程中，也會電擊到空氣中的 氮氣而產生氮氧化合物（NOX )，而其再與空氣中的 濕氣結合後即會形成對人體有害的亞硝酸類物質。 據此，如何改進上述問題並提供一種具有多用途之 水電解裝置，即為本發明之首要課題，因此本案發明人 乃經過不斷苦思及試作後，才終於有本發明之產生。 【發明内容】 [0003] [0004] [0005] [0006] [0007] 本發明目的之一，係在於提供一種水電解裝置，其 係具有可選擇製出氧氣、臭氧水或臭氧，以達到多用途 之功效者。 本發明目的之二，係在於提供一種水電解裝置，其 係利用質子交換膜電解方式，將純水中的氫氧分離進而 產生氫氣及氧氣，再藉由電化學的原理使臭氧產生，並 由於是在純水中進行的，因此不會有任何氮氧化合物產 生，而可確保所產出之臭氧或臭氧水均是安全無害的。 為達前述之目的，本發明係提供一種水電解裝置， 其包含有： 一進水端，係供輸入純水； 一儲水桶，係經一第一連接管路而與該進水端相接 ，且於該第一連接管路中係設有一可控制純水進入該儲 水桶之第一控制閥，並於該儲水桶底部接設有一可對純 水進行電解動作以解離出氫氣及氧氣之氫氧解離器，且 經該氫氧解離器解離出之氫氣係可作為一氣電再生器之 099136680 表單編號A0101 第4頁/共17頁 0992064101-0 201217584 燃料以產生電力，而經解離後之氧氣與純水則經一回收 管路回流至該儲水桶中，且解離出之氧氣再由該儲水桶 頂部之一第一排出管路釋出； [0008] —臭氧產生器，係經一第二連接管路而與該進水端 相接，並於該連接管路中設有一第二控制閥，且當關閉 該第一控制閥並令該第二控制閥開啟時，該臭氧產生器 即可對由該第二連接管路所輸入之純水進行電解以製成 臭氧水，且於其電解過程所產生之氫氣係同樣可被分離 Λ 出作為該氣電再生器之燃料，而所製成之臭氧水則經一 〇 出水管路排出； [0009] 一水氣分離器，係可進一步將該臭氧產生器所製成 之臭氧水中之臭氧分離並經一第二排出管路釋出，且由 該水氣分離器作用後之液體部分則再次回流至該臭氧產 生器中以構成一循環迴路，並於該循環迴路中係設有一 決定該臭氧產生器所製成之臭氧水是否可進入該水氣分 離器中之第三控制閥。 Ο [0010] 而本發明之上述目的與優點，不難從下述所選用實 施例之詳細說明與附圖中，獲得深入了解。 [0011] 當然，本發明在某些另件上，或另件之安排上容許 有所不同，但所選用之實施例，則於本說明書中，予以 詳細說明。 【實施方式】 [0012] 請搭配參閱第1圖，本發明係提供一種專門用以對 純水進行電解動作之水電解裝置，其主要係由一進水端 099136680 表單編號Α0101 第5頁/共17頁 0992064101-0 201217584 [0013] [0014] [0015] 099136680 1 1、一儲水桶12、一氫氧解離器14、一 益2 1以及一水氣分離器3 1所構成，其中·· 該進水端1 1 ’係可供輸入純水； 該儲水桶1 2，係經一第一連接管路2 3而與該進 水端1 1相接，且於該第一連接管路丄3中係設有一可 控制純水進入s亥儲水桶1 2之第一控制閥1 3 1，並於 該儲水桶1 2底部接設該氫氧解離器i 4，而該氫氧解 離器14係採用質子交換膜電解方式以對純水進行電解 動作以解離出氫氣及氧氣，且解離出之氫氣係可作為一 氣電再生器1 5之燃料以產生電力，並可利用該氣電再 生器15所產生之電力以供應本發明水電解裝置其控制 面板1 6上之LED (圖中未示）產生照明光源，而經 解離後之氧氣與純水則經一回收管路i 7回流至該儲水 桶1 2中，且解離出之氧氣再由該儲水桶i 2頂部之一 第一排出管路1 8釋出，另於緣第一排串管路1 8中更 設有一混合裝置1 9，該混合裝置1 9係由一文氏管丄 9 1與一空氣泵浦1 9 2構成，以使氧氣釋出前，係須 先經混合裝置1 9混合與調壓後，方可由該第一排出管 路1 8向外釋出。 該臭氧產生器2 1，係同樣採用質子交換膜電解方 式’而可將純水中的氫氡分離進而產生氫氣及氧氣，並 再藉由電化學的原理使臭氧產生，該臭氧產生器2工係 經一第二連接管路2 2而與該進水端1 1相接，並於該 第二連接管路2 2中設有-第二控制閥2 2 !，且當關 閉该第—控制閥1 3 1並令該第二控制閥2 2 1開啟時 表單編號Λ0101 « R ' 臭氧產生 0992064101-0 201217584 [0016] Ο [0017] Ο ，該臭氧產生器2 1即可對由該第二連接管路2 2所輪 入之純水進行電解以製成臭氧水，且於其電解過程所產 生之氫氣係同樣可被分離出作為該氣電再生器丄5之燃 料，而所製成之臭氧水則經一出水管路2 3排出，並於 該出水管路2 3申係設有一出水控制閥2 3 1。 該水氣分離器3 1，係可進一步將該臭氧產生器2 1所裝成之臭乳水中之臭氧分離並經一第二排出管路3 2釋出，且由該水氣分離器3 1作用後之液體部分則再 次回流至該臭氧產生器2 1中以構成一循環迴路3 3， 並於該循環迴路3 3中係設有一決定該臭氧產生器2工 所製成之臭氧水是否可進入該水氣分離器3丄中之第三 控制閥3 3 1 » , 而本發明之水電解褒置於實際使用時，如第2圖所 示，當開啟該第一控制閥1 3 1並令該第二控制閥2 2 1處於關閉狀態時，該氫氧解離器1 4即可對由該儲水 桶1 2輸入之純水進行一轉離作用，以解離出氧氣與氫 氣’接著經該氫氧解離器1 4所解離出之氧氣與純水係 經該回收管路1 7回流至該儲水桶1 2中，且解離出之 氧氣再由該第一排出管路1 8釋出並受該混合裝置工9 作用後，而排出至一吸氧器（圖中未示）以供使用，並 藉此即可構成一氧氣生成模式。 [0018] 而當關閉該第一控制閥1 3 1並令該第二控制閥2 2 1與該出水控制閥2 3 1處於開啟狀態時，如第3圖 所示，則由該進水端1 1輸入之純水即可經該第二連接 管路2 2而進入於該臭氡產生器2 1中以製成臭氡水， 099136680 表單編號A0101 第7頁/共17頁 0992064101-0 201217584 此時並令各該第三控制閥3 3丄處於關閉狀態，而使由 °亥臭乳產生11 2 1所製成之臭氧水可由該出水管路2 3 輪出以供使用，並藉此即可構成—臭氧水生成模式。 [0019] [0020] [0021] 者如第4圖所示，當關閉該第一控制閥1 3 1 與"亥出水控制閥2 3 1 ’並令該第二控制閥2 2 1與各 該第三控制閥3 3 1處於開啟狀態時，由該臭氧產生器 2 1所製成之臭氧水即可經該循環迴路3 3而進入於該 水氣分離器3 1中，以可將臭氧水中之臭氧分離後在經 由该第二排出管路3 2釋m氧空氣機（圖中未示 ^中’且由該水氣分離器31作用後之液體部分則會經 ，循環迴路3 3而再次進人至該臭氧產生器2 i中並 藉此即可構成一臭氧生成模式。 經由上述構件所組成之本發明水電解裝置係可具有 以下優點： 、 .本發明之水電解裝置係可籍該等控制閥以選擇製 成氧氣臭氧水或臭氧， Hi:此诀本發明之水電解 裝置係可具有多用途之士妓:。 2. 本發明係採用質子交換膜電解方式，將純水中的氯 氧分離進而產生氫氣及氧氣，並再藉由電化學的原 理使臭氧產生，且由於是在純水中進行的，因此並 不會有任何氮氧化合物產生，而可確保由本發明水 電解裝置所產出之臭氧或臭氧水均是安全無害的。 3. 本發明更可利用純水於電解過程中所產生之氫氣作 為該氣電再生器之燃料，並進而達到節能省電之功 效。 099136680 表單編號A0101 第8頁/共17頁 0992064101-0 201217584 准以上所述實施例之揭示係用以說明本發明，並 非用以限制本發明，故舉凡數值之變更或等效元件之置 換仍應隸屬本創作之範嘴。 [0023] 紅上所述，係可使熟知本項技藝者明瞭本發明的確 可達成前述目的，實已符合專利法之規定，故本案發明 人菱俊法提出申請。 【圖式簡單說明】 [0024] 第1圖係本發明之結構方塊示意圖 〇 [0025]第2圖係本發明於進行氧氣生成模式時之作動流程示意 園 [0026] 第3圖係本發明於進行臭氧水生成模式時之作動流程示 意圖 [0027] 第4圖係本發明於進行臭氧生成模式時之作動流程示意 圖 【主要元件符號說明】 [0028] 進水端1 1 儲水桶1 2 [0029] 第二連接管路13 第一控制閥131 [0030] 氫氧解離器1 4 氣電再生器15 [0031] 控制面板16 回收管路17 [0032] 第一排出管路18 混合裝置19 [0033] 文氏管1 9 1 空氣泵浦1 9 2 [0034] 臭氧產生器2 1 第一連接管路2 2 表單編號A0101 第9頁/共17頁 〇 099136680 0992064101-0 201217584 [0035] 第二控制閥2 2 1 [0036] 出水控制閥2 3 1 [0037] 第二排出管路3 2 [0038] 第三控制閥3 3 1 出水管路2 3 水氣分離器3 1 循環迴路3 3 099136680 表單編號A0101 第10頁/共17頁 0992064101-0201217584 [0001] [0001] [0002] 0002 ο 099136680 Description of the Invention: [Technical Field] The present invention relates to a water electrolysis device, and more particularly to a water electrolysis device having an alternative process for producing oxygen, ozone water or ozone. [Prior Art] According to ozone, ozone (0 3) is a safe, clean and potent oxidant. It has been widely used in disinfection or detoxification applications. It has a wide range of applications and personal oral hygiene, home cleaning and washing, and even For industrial processing and wastewater treatment. However, the conventional methods for rapidly producing ozone can be roughly classified into an ultraviolet method, a silent discharge method, and a tip discharge method, in which: the ultraviolet method uses ultraviolet rays to act on oxygen molecules (0 2 ) in the air to generate trace amounts of ozone, which is A substance (Ο 3 ) which combines into a three oxygen atom by an oxygen molecule (0 2) and an oxygen atom (0). The silent discharge method utilizes a quartz glass tube, a heat-resistant glass, a ceramic, a stainless steel or the like. When a DC high-voltage high-frequency current passes, a discharge corona phenomenon is generated with the ground electrode, and a decomposition reaction is generated by the air passing through the electric shock, and the oxygen molecule is generated. The chain bond of (Ο 2 ) collapses to form an oxygen atom (from 302 to 203) to obtain ozone. The tip discharge method uses an electronic transformer to generate high voltage, and uses a plurality of metal needles to form a ionization effect like a lightning shock with a tip discharge, and the oxygen chain (0 2) is broken to form a negatively charged oxygen atom (0), and oxygen is used. The atom can be combined with the oxygen molecules in the air to obtain ozone (03, except that the above method is used to generate ozone, the common point is to use the oxygen molecules in the air as raw materials to be decomposed into electric shocks into negative form numbers Α0101 Page 3 of 17 0992064101-0 201217584 Electric oxygen atoms, however, in addition to oxygen in the air, there is a large amount of nitrogen, so in the process of electric shock dissociation, it will also hit the nitrogen in the air to produce nitrogen and oxygen. The compound (NOX), which is combined with the moisture in the air, forms a nitrous acid which is harmful to the human body. Accordingly, how to improve the above problem and provide a multipurpose water electrolysis device, namely the present invention As a primary issue, the inventor of the present invention has finally developed the present invention after continually thinking and trying. [Abstract] [0003] [0004] [0007] [0007] [0007] One of the objects of the present invention is to provide a water electrolysis device having the function of selectively producing oxygen, ozone water or ozone to achieve multi-purpose effects. The invention provides a water electrolysis device which uses a proton exchange membrane electrolysis method to separate hydrogen and oxygen in pure water to generate hydrogen gas and oxygen gas, and then generates ozone by electrochemical principle, and since it is in pure water. Therefore, there is no nitrous oxide production, and it is ensured that the ozone or ozone water produced is safe and harmless. For the purpose of the foregoing, the present invention provides a water electrolysis device comprising: The water inlet end is for inputting pure water; a water storage bucket is connected to the water inlet end via a first connecting pipeline, and a controllable pure water is connected to the first connecting pipeline The first control valve of the water bucket is connected with a hydrogen oxygen dissociator capable of decomposing hydrogen and oxygen from the bottom of the water storage tank, and the hydrogen gas dissociated by the hydrogen oxygen dissociator can be used as a gas. 099136680 regenerator Form No. A0101 Page 4 of 17 0992064101-0 201217584 Fuel to generate electricity, and dissociated oxygen and pure water are returned to the storage tank through a recovery line, and the oxygen is dissociated And being discharged from the first discharge line of one of the tops of the water storage tank; [0008] an ozone generator connected to the water inlet end via a second connecting line, and a gas line is disposed in the connecting line a second control valve, and when the first control valve is closed and the second control valve is opened, the ozone generator can electrolyze the pure water input by the second connecting pipe to form ozone water. And the hydrogen gas generated in the electrolysis process can also be separated and discharged as the fuel of the gas electric regenerator, and the ozone water produced is discharged through a water outlet pipe; [0009] a water gas separator, The ozone in the ozone water produced by the ozone generator can be further separated and released through a second discharge line, and the liquid portion after the water separator is returned to the ozone generator again. Form a loop and Circulation circuit is provided with a system to decide whether the ozone water made of the ozone generator may enter the water vapor separation vessel of the third control valve. The above objects and advantages of the present invention will be readily understood from the following detailed description of the embodiments of the invention. [0011] Of course, the present invention may be different in some of the components, or the arrangement of the components, but the selected embodiments are described in detail in the present specification. [Embodiment] [0012] Please refer to Fig. 1, the present invention provides a water electrolysis device specially used for electrolysis of pure water, which is mainly composed of a water inlet end 099136680 Form No. Α 0101 Page 5 / Total 17 pages 0992064101-0 201217584 [0013] [0015] 099136680 1 1. A water storage tank 12, a hydrogen oxygen dissociator 14, a Yi 2 1 and a water gas separator 3 1 , wherein The water inlet end 1 1 ' is for inputting pure water; the water storage tank 12 is connected to the water inlet end 1 1 via a first connecting line 2 3 , and in the first connecting line 丄 3 The middle system is provided with a first control valve 133 for controlling the passage of pure water into the s-water storage tank 12, and the hydrogen-oxygen dissolver i4 is connected to the bottom of the water storage tank 12, and the oxyhydrolyzer is 14 Proton exchange membrane electrolysis is used to perform electrolysis on pure water to dissociate hydrogen and oxygen, and the dissociated hydrogen gas can be used as a fuel for a gas regenerator 15 to generate electricity, and the gas regenerator 15 can be utilized. The generated electric power is supplied to the LED (not shown) on the control panel 16 of the water electrolysis device of the present invention. a light source, and the dissociated oxygen and pure water are returned to the water storage tank 12 through a recovery line i 7 , and the dissociated oxygen is again discharged from the top of the water storage tank i 2 by a first discharge line 1 8 is released, and a mixing device 1 9 is further disposed in the first row of the pipe 18, and the mixing device 19 is composed of a venturi 9 1 and an air pump 192 to make oxygen Before being released, the system must be mixed and adjusted by the mixing device 19 before being released from the first discharge line 18. The ozone generator 2 1 is also a proton exchange membrane electrolysis method, and the hydroquinone in pure water can be separated to generate hydrogen and oxygen, and the ozone is generated by an electrochemical principle. Connected to the water inlet end 1 1 via a second connecting line 2 2 , and a second control valve 2 2 ! in the second connecting line 2 2 , and when the first control is turned off Valve 1 3 1 and when the second control valve 2 2 1 is opened, the form number Λ0101 « R ' ozone generation 0992064101-0 201217584 [0016] Ο [0017] Ο , the ozone generator 2 1 can be used by the second The pure water rotated in the connecting line 2 2 is electrolyzed to make ozone water, and the hydrogen gas generated in the electrolysis process can also be separated as the fuel of the gas electric regenerator crucible 5, and is produced. The ozone water is discharged through a water outlet pipe 23, and an outlet water control valve 213 is provided in the water outlet pipe 23. The water gas separator 3 1 can further separate the ozone in the odorous milk water filled by the ozone generator 21 and release it through a second discharge line 3 2 , and the water gas separator 3 1 The liquid portion after the action is again returned to the ozone generator 2 1 to form a circulation loop 33, and in the circulation loop 33, whether or not the ozone water produced by the ozone generator 2 is determined can be Entering the third control valve 3 3 1 » in the water separator 3丄, and the water electrolysis crucible of the present invention is placed in actual use, as shown in FIG. 2, when the first control valve 1 3 1 is opened and When the second control valve 2 2 1 is in the closed state, the hydrogen oxygen dissociator 14 can perform a rotation of the pure water input from the water storage tank 12 to dissociate oxygen and hydrogen. The oxygen and pure water dissociated from the hydrogen oxygen dissociator 14 are returned to the water storage tank 12 through the recovery line 107, and the dissociated oxygen is released from the first discharge line 18 and subjected to After the mixing device 9 is actuated, it is discharged to an oxygen absorber (not shown) for use, and thereby an oxygen can be formed. Into a pattern. [0018] When the first control valve 13 1 is closed and the second control valve 2 2 1 and the water outlet control valve 23 1 are in an open state, as shown in FIG. 3, the water inlet end is 1 1 input pure water can enter the skunk generator 2 1 through the second connecting line 2 2 to make skunk water, 099136680 Form No. A0101 Page 7 / Total 17 Page 0992064101-0 201217584 At this time, the third control valve 3 3 丄 is in a closed state, and the ozone water produced by the sulphur emulsion 11 1 1 can be rotated by the water outlet pipe 2 3 for use. It can be constructed - the ozone water generation mode. [0020] [0021] As shown in FIG. 4, when the first control valve 1 3 1 and the "Hai water control valve 2 3 1 ' are closed and the second control valve 2 2 1 and each When the third control valve 331 is in an open state, the ozone water prepared by the ozone generator 21 can enter the water gas separator 3 1 through the circulation circuit 3 3 to After the ozone in the water is separated, the m oxygen air machine (not shown in the figure) and the liquid portion after the action of the water gas separator 31 passes through the second exhaust line 3, and the circulation circuit 3 3 The ozone generator 2 i can be reintroduced into the ozone generator 2 i to form an ozone generation mode. The water electrolysis device of the present invention comprising the above components can have the following advantages: The water electrolysis device of the present invention can be used. The control valves are selectively made into oxygen ozone water or ozone. Hi: The water electrolysis device of the present invention can have a multi-purpose gem: 2. The present invention uses a proton exchange membrane electrolysis method to purify pure water. The separation of chlorine and oxygen generates hydrogen and oxygen, and the ozone is generated by the principle of electrochemistry. Moreover, since it is carried out in pure water, there is no generation of nitrogen oxides, and it is ensured that the ozone or ozone water produced by the water electrolysis device of the present invention is safe and harmless. 3. The present invention is more usable. The hydrogen produced by the pure water in the electrolysis process is used as the fuel of the gas electric regenerator, and further achieves the effect of energy saving and power saving. 099136680 Form No. A0101 Page 8 of 17 0992064101-0 201217584 The disclosure is intended to be illustrative of the present invention and is not intended to limit the invention, so any change in value or replacement of equivalent elements should still be exemplified by the present invention. [0023] As described above, it is possible to familiarize the art with this technique. It is clear that the present invention can achieve the above-mentioned objectives, and has already met the requirements of the Patent Law. Therefore, the inventor of the present invention applied for the application of the method. [Comparative Description of the Drawings] [0024] Figure 1 is a block diagram of the structure of the present invention [0025] Fig. 2 is a schematic flow diagram of the operation flow of the present invention in the oxygen generation mode. [0026] Fig. 3 is a schematic diagram of the operation flow of the present invention in the ozone water generation mode [0027] Schematic diagram of the operation flow of the present invention in the ozone generation mode [Description of main components] [0028] Inlet end 1 1 Water storage tank 1 2 [0029] Second connecting line 13 First control valve 131 [0030] Hydrogen and oxygen Dissociator 1 4 gas electric regenerator 15 [0031] control panel 16 recovery line 17 [0032] first discharge line 18 mixing device 19 [0033] venturi 1 9 1 air pump 1 9 2 [0034] ozone Generator 2 1 First connecting line 2 2 Form No. A0101 Page 9 / Total 17 pages 〇 099136680 0992064101-0 201217584 [0035] Second control valve 2 2 1 [0036] Outlet control valve 2 3 1 [0037] Second discharge line 3 2 [0038] Third control valve 3 3 1 Water outlet line 2 3 Water gas separator 3 1 Cycle circuit 3 3 099136680 Form number A0101 Page 10 of 17 0992064101-0