TW201434652A - Separator connecting device for electric appliance and electric appliance and joining method thereof - Google Patents
Separator connecting device for electric appliance and electric appliance and joining method thereof Download PDFInfo
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- TW201434652A TW201434652A TW102144642A TW102144642A TW201434652A TW 201434652 A TW201434652 A TW 201434652A TW 102144642 A TW102144642 A TW 102144642A TW 102144642 A TW102144642 A TW 102144642A TW 201434652 A TW201434652 A TW 201434652A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0404—Machines for assembling batteries
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K31/00—Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by any single one of main groups B23K1/00 - B23K28/00
- B23K31/02—Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by any single one of main groups B23K1/00 - B23K28/00 relating to soldering or welding
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0436—Small-sized flat cells or batteries for portable equipment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0468—Compression means for stacks of electrodes and separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
- H01M50/451—Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Cell Separators (AREA)
- Secondary Cells (AREA)
- Laminated Bodies (AREA)
Abstract
[課題]提供即便振動或受到衝擊,是可以防止分隔件(30)的耐熱材(32)的飛散之電器(1)。還有,提供於分隔件接合裝置內,可以防止分隔件(30)的耐熱材(32)飛散之電器(1)之分隔件接合裝置(100)及其之接合方法。[解決課題之手段]電器係具有發電元件(60)。發電元件,為介隔著分隔件層積第1電極(正極10)、以及與第1電極極性相異之第2電極(負極20)。分隔件,為包含熔融材(31)、以及僅層積在熔融材的單面且比熔融材的熔融溫度還要高的耐熱材(32)。鄰接的分隔件彼此,係使耐熱材彼此對面而接合。[Problem] An electric appliance (1) capable of preventing scattering of the heat-resistant material (32) of the separator (30) even if it is vibrated or subjected to an impact. Further, the separator joining device (100) of the electric appliance (1) which can be prevented from scattering the heat-resistant material (32) of the partition member (30) and the joining method thereof are provided in the partition joining device. [Means for Solving the Problem] The electric appliance has a power generating element (60). In the power generating element, a first electrode (positive electrode 10) and a second electrode (negative electrode 20) having a polarity different from that of the first electrode are laminated via a separator. The separator is a heat-resistant material (32) including a molten material (31) and a single layer laminated on the molten material and higher than the melting temperature of the molten material. The adjacent separators are joined to each other such that the heat resistant materials are opposed to each other.
Description
本發明,係有關電器、電器之分隔件接合裝置及其之接合方法。 The present invention relates to a separator joining device for an electric appliance and an electric appliance, and a joining method thereof.
以往,例如二次電池這樣的電器,是以外部件材料來密封進行充放電的發電元件。發電元件,係層積電極與分隔件而構成。分隔件一加熱的話就容易收縮。分隔件收縮的話,會發生局部的電性的短路,電器的輸出會下降。 Conventionally, an electric appliance such as a secondary battery is a power generating element that is sealed and charged and discharged by a member material. The power generating element is composed of a laminated electrode and a separator. The separator is easily shrunk as soon as it is heated. If the separator shrinks, a local electrical short circuit will occur and the output of the appliance will drop.
在此,使用分隔件,該分隔件於具有耐熱性之耐熱層配置具有比該耐熱層的熔點還要低的熔點之熱熔融層,構成即便在加熱了該分隔件的情況下也可以防止收縮之層積式電池。層積式電池的分隔件的熱熔融層彼此,係藉由熱熔著而固定(例如,參閱專利文獻1。)。 Here, a separator is used which is provided with a heat-melting layer having a melting point lower than the melting point of the heat-resistant layer in a heat-resistant heat-resistant layer, and is configured to prevent shrinkage even when the separator is heated. The laminated battery. The heat-melting layers of the separator of the laminated battery are fixed to each other by heat fusion (for example, refer to Patent Document 1).
順便一說,作為層積電極與分隔件的裝置,揭示有第1及第2分隔件原材料是隨著吸附滾筒的轉動而被抽出,吸附滾筒在轉一圈的期間用分隔件把電極予以袋裝而成形之構成(例如,參閱專利文獻2。)。還有,揭 示有藉由連續分隔件的接著把電極板的周圍予以包圍,並防止該電極板的位置錯誤之構成(例如,參閱專利文獻3。)。 By the way, as a means for laminating the electrode and the separator, it is revealed that the first and second separator raw materials are taken out in accordance with the rotation of the adsorption roller, and the adsorption roller is used to pack the electrode with the separator during one rotation. The structure which is formed and formed (for example, refer to Patent Document 2). Also, reveal A configuration in which the periphery of the electrode plate is surrounded by the continuous separator and the position of the electrode plate is prevented from being erroneous is shown (for example, refer to Patent Document 3).
[專利文獻1]日本特開2011-210524號專利公報(參閱圖14、圖15) [Patent Document 1] Japanese Laid-Open Patent Publication No. 2011-210524 (see Figs. 14 and 15)
[專利文獻2]日本特開2011-003381號專利公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2011-003381
[專利文獻3]日本特開2009-009919號專利公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2009-009919
但是,在上述專利文獻1的構成中,如圖14及圖15所示般,在層積體的兩端的最外部面分別露出分隔件的耐熱層。還有,也在各分隔件的兩端部,露出耐熱層。 However, in the configuration of Patent Document 1, as shown in FIGS. 14 and 15 , the heat-resistant layers of the separator are exposed on the outermost surfaces of both ends of the laminate. Further, a heat-resistant layer is also exposed at both end portions of each separator.
在這樣的狀態下,於層積式電池振動或受到衝擊的情況下,分隔件的耐熱材飛散,是有電性的特性下降之虞。尚且,於上述專利文獻1的圖3所示的分隔件,乃是在耐熱層的兩面設有熱熔融層之結構,所以耐熱材不會飛散,但分隔件的層厚卻變得很厚。 In such a state, when the laminated battery vibrates or is subjected to an impact, the heat-resistant material of the separator scatters, and the electrical properties are degraded. Further, in the separator shown in FIG. 3 of Patent Document 1, since the heat-melting layer is provided on both surfaces of the heat-resistant layer, the heat-resistant material does not scatter, but the layer thickness of the separator becomes thick.
更進一步,也在任一上述專利文獻2及3中,並沒有考慮到:在搬送層積耐熱材與熔融材而形成的 分隔件之際不使容易飛散的耐熱材飛散之構成。 Furthermore, in any of the above-mentioned Patent Documents 2 and 3, it is not considered that the heat-dissipating material and the molten material are laminated and formed. When the separator is used, the heat-resistant material which is easy to scatter is not scattered.
在這樣的構成下,於使用層積耐熱材與熔融材而形成之分隔件的情況下,分隔件的耐熱材,是有飛散在分隔件接合裝置內之虞。 In such a configuration, when a separator formed by laminating a heat-resistant material and a molten material is used, the heat-resistant material of the separator is scattered in the separator joining device.
本發明為了解決上述課題,其目的為提供既使是振動或受到衝擊也可以防止分隔件的耐熱材飛散之電器。 In order to solve the above problems, an object of the present invention is to provide an electric appliance which can prevent scattering of a heat-resistant material of a separator even if it is vibrated or impacted.
還有,本發明為了解決上述課題,其目的為提供在分隔件接合裝置內,可以防止分隔件的耐熱材飛散之電器的分隔件接合裝置及其之接合方法。 In order to solve the above problems, an object of the present invention is to provide a separator joining device for an electric appliance capable of preventing scattering of a heat-resistant material of a separator in a separator joining device, and a joining method therefor.
有關達成上述目的之本發明的電器,是具有發電元件。發電元件,為介隔著分隔件層積第1電極、以及與第1電極極性相異之第2電極。分隔件,為包含熔融材、以及僅層積在熔融材的單面且比熔融材的熔融溫度還要高的耐熱材。鄰接的分隔件彼此,係使耐熱材彼此對面而接合。 The electric appliance of the present invention for achieving the above object has a power generating element. The power generating element has a first electrode laminated with a separator and a second electrode having a polarity different from that of the first electrode. The separator is a heat-resistant material containing a molten material and a single layer which is laminated only on one side of the molten material and higher than the melting temperature of the molten material. The adjacent separators are joined to each other such that the heat resistant materials are opposed to each other.
還有,有關達成上述目的之本發明的電器,是具有發電元件。發電元件,為介隔著分隔件層積第1電極、以及與第1電極極性相異之第2電極。分隔件,為包含熔融材、以及層積在熔融材的單面且比熔融材的熔融溫度還要高的耐熱材。藉由搬送裝置保持分隔件的熔融材的一側並進行搬送,把使鄰接的分隔件的耐熱材彼此對面並 鄰接的分隔件彼此予以接合。 Further, the electric appliance of the present invention for achieving the above object has a power generating element. The power generating element has a first electrode laminated with a separator and a second electrode having a polarity different from that of the first electrode. The separator is a heat-resistant material containing a molten material and a single layer laminated on the molten material and higher than the melting temperature of the molten material. The side of the molten material of the separator is held by the conveying device and conveyed, and the heat-resistant materials of the adjacent separators are opposed to each other. Adjacent spacers are joined to each other.
有關達成上述目的之本發明的電器的分隔件接合裝置,乃是把交互層積第1電極以及與第1電極的極性相異之第2電極的分隔件彼此予以接合之接合裝置。使用包含熔融材、以及僅層積在熔融材的單面且比熔融材的熔融溫度還要高的耐熱材之分隔件。在此,藉由搬送裝置保持分隔件的熔融材的一側並進行搬送,把使鄰接的分隔件的耐熱材彼此對面並鄰接的分隔件彼此予以接合。 The separator joining device for an electric appliance according to the present invention which achieves the above object is a joining device in which a first electrode and a separator of a second electrode which are different in polarity from the first electrode are joined to each other. A separator containing a molten material and a heat-resistant material laminated only on one side of the molten material and higher than the melting temperature of the molten material is used. Here, the side of the molten material of the separator is held by the conveying device and conveyed, and the separators that face the adjacent heat-resistant members of the separators and are adjacent to each other are joined to each other.
還有,有關達成上述目的之本發明的電器的分隔件接合方法,乃是把交互層積第1電極以及與第1電極的極性相異之第2電極的分隔件彼此予以接合之接合方法。使用包含熔融材、以及僅層積在熔融材的單面且比熔融材的熔融溫度還要高的耐熱材之分隔件。在此,保持分隔件的熔融材的一側並進行搬送,把使鄰接的分隔件的耐熱材彼此對面並鄰接的分隔件彼此予以接合。 Further, the separator joining method of the electric appliance according to the present invention for achieving the above object is a joining method in which the first electrode and the separator of the second electrode which are different in polarity from the first electrode are joined to each other. A separator containing a molten material and a heat-resistant material laminated only on one side of the molten material and higher than the melting temperature of the molten material is used. Here, one side of the molten material of the separator is held and conveyed, and the separators that face the adjacent heat-resistant members of the separators and are adjacent to each other are joined to each other.
1‧‧‧電器 1‧‧‧Electrical appliances
10‧‧‧正極(第1電極) 10‧‧‧ positive electrode (first electrode)
11‧‧‧正極集電體 11‧‧‧ positive current collector
11a‧‧‧正極電極端子 11a‧‧‧positive electrode terminal
12‧‧‧正極活性物質 12‧‧‧ positive active material
20‧‧‧負極(第2電極) 20‧‧‧Negative electrode (2nd electrode)
21‧‧‧負極集電體 21‧‧‧Negative current collector
21a‧‧‧負極電極端子 21a‧‧‧Negative electrode terminal
22‧‧‧負極活性物質 22‧‧‧Negative active material
30‧‧‧分隔件 30‧‧‧Parts
31‧‧‧熔融材 31‧‧‧ molten material
32‧‧‧耐熱材 32‧‧‧Heat-resistant materials
40‧‧‧外部件材料 40‧‧‧External component materials
41、42‧‧‧層板片 41, 42‧‧‧ layers
50、70‧‧‧袋裝電極 50, 70‧‧‧ bagged electrodes
60‧‧‧發電元件 60‧‧‧Power generation components
100‧‧‧分隔件接合裝置 100‧‧‧Parts jointing device
210‧‧‧正極捲繞滾子 210‧‧‧ positive winding roller
220‧‧‧搬送滾子 220‧‧‧Transport roller
310‧‧‧吸入式輸送機(搬送裝置) 310‧‧‧Sucking conveyor (transporting device)
320‧‧‧旋轉滾子 320‧‧‧Rotating roller
410、420、430、440‧‧‧切斷構件 410, 420, 430, 440‧‧‧cutting members
510、610‧‧‧分隔件捲繞滾子 510, 610‧‧‧Parts winding roller
520、620‧‧‧加壓滾子 520, 620‧‧‧ Pressurized roller
530、630‧‧‧夾持滾子 530, 630‧‧‧Clamping roller
540、640‧‧‧真空吸引搬送滾筒(搬送裝置) 540, 640‧‧‧ Vacuum suction conveyor roller (transporting device)
710‧‧‧加熱加壓構件 710‧‧‧heating and pressing members
810‧‧‧袋裝電極吸附墊(搬送裝置) 810‧‧‧Bag electrode adsorption pad (transport device)
820‧‧‧伸縮部 820‧‧‧Flexing Department
830‧‧‧支撐構件 830‧‧‧Support members
840‧‧‧軌條 840‧‧‧ rails
850‧‧‧載置台 850‧‧‧mounting table
[圖1]為表示有關第1實施型態的電器之立體圖。 Fig. 1 is a perspective view showing an electric appliance according to a first embodiment.
[圖2]為表示有關第1實施型態的電器之爆炸圖。 Fig. 2 is an exploded view showing an electric appliance according to the first embodiment.
[圖3]為表示分別在用一對分隔件袋裝有關第1實施型態的正極而形成之袋裝電極的兩端,層積負極的狀態之立體圖。 3 is a perspective view showing a state in which a negative electrode is laminated on both ends of a packaged electrode formed by attaching a positive electrode according to the first embodiment to a pair of separators.
[圖4]為表示有關第1實施型態的圖3之4-4線之剖 視圖。 Fig. 4 is a cross-sectional view taken along line 4-4 of Fig. 3 showing the first embodiment. view.
[圖5]為表示接合有關第1實施型態的電器的分隔件之分隔件接合裝置的立體圖。 Fig. 5 is a perspective view showing a separator joining device for joining a separator of the electric appliance according to the first embodiment.
[圖6]為表示接合有關第1實施型態的電器的分隔件之分隔件接合裝置的真空吸引搬送滾筒近旁的側視圖。 Fig. 6 is a side view showing the vacuum suction conveyance roller of the separator joining device for joining the separator of the electric device according to the first embodiment.
[圖7]為表示接合有關第1實施型態的電器的分隔件之分隔件接合裝置的吸入式輸送機近旁的側視圖。 Fig. 7 is a side view showing the vicinity of a suction conveyor in which a separator joining device for a separator of an electric appliance according to the first embodiment is joined.
[圖8]為表示接合有關第1實施型態的電器的分隔件之分隔件接合裝置的袋裝電極吸附墊近旁的側視圖。 Fig. 8 is a side view showing the vicinity of a pocket electrode adsorption pad of a separator joining device for joining a separator of an electric appliance according to the first embodiment.
[圖9]為表示接合有關第1實施型態的電器的分隔件之分隔件接合裝置的加熱加壓構件近旁的立體圖。 Fig. 9 is a perspective view showing the vicinity of a heating and pressurizing member of a separator joining device for joining a separator of an electric appliance according to the first embodiment.
[圖10]為有關第1實施型態的圖9之10-10線之剖視圖。 Fig. 10 is a cross-sectional view taken along line 10-10 of Fig. 9 of the first embodiment.
[圖11]為表示分別在用一對分隔件袋裝有關第2實施型態的負極而形成之袋裝電極的兩端,層積正極的狀態之電器的一部分之剖視圖。 [Fig. 11] Fig. 11 is a cross-sectional view showing a part of an electric appliance in a state in which a positive electrode is laminated on both ends of a pocket electrode formed by sandwiching a negative electrode of a second embodiment with a pair of separators.
以下,一邊參閱添附的圖面,一邊說明本發明之實施型態。有關圖面的說明方面,於同一的元件賦予同一之元件符號並省略重複說明。圖面之各構件的大小或比例,是為了配合說明而誇大,是有與實際的大小或比例相異之情況。 Hereinafter, the embodiment of the present invention will be described with reference to the attached drawings. In the description of the drawings, the same components are denoted by the same reference numerals, and the repeated description is omitted. The size or proportion of each member of the drawing is exaggerated for the sake of explanation, and may be different from the actual size or ratio.
首先,有關藉由有關第1實施型態之分隔件接合裝置100使分隔件30彼此接合之電器1的構成,一邊參閱圖1~圖4一邊說明之。 First, the configuration of the electric appliance 1 in which the separators 30 are joined to each other by the separator joining device 100 according to the first embodiment will be described with reference to Figs. 1 to 4 .
圖1,為表示藉由分隔件接合裝置100接合分隔件30之電器1之立體圖。圖2,為表示藉由分隔件接合裝置100接合分隔件30之電器1之爆炸圖。圖3為表示藉由分隔件接合裝置100分別在用一對分隔件30袋裝正極10而形成之袋裝電極50的兩端,層積負極20的狀態之立體圖。圖4為表示在圖3之4-4線之剖視圖。 1 is a perspective view showing the electric appliance 1 in which the separator 30 is joined by the spacer joining device 100. 2 is an exploded view showing the electric appliance 1 in which the partition member 30 is joined by the spacer joining device 100. 3 is a perspective view showing a state in which the negative electrode 20 is laminated on both ends of the packaged electrode 50 formed by sandwiching the positive electrode 10 with a pair of separators 30 by the separator bonding apparatus 100. Figure 4 is a cross-sectional view taken along line 4-4 of Figure 3.
電器1,係如圖1所表示,相當於例如鋰離子二次電池、聚合物鋰電池、鎳-氫電池、鎳-鎘電池。電器1,係如圖2所表示,以外部件材料40密封進行充放電的發電元件60。發電元件60,係交互層積以下而構成:以一對的分隔件30挾持正極10而接合之袋裝電極50、以及負極20。 The electric appliance 1 is as shown in FIG. 1, and corresponds to, for example, a lithium ion secondary battery, a polymer lithium battery, a nickel-hydrogen battery, or a nickel-cadmium battery. The electric appliance 1 is shown in Fig. 2, and the external component material 40 seals the power generating element 60 that is charged and discharged. The power generating element 60 is configured by alternately laminating the packaged electrode 50 and the negative electrode 20 which are sandwiched between the positive electrode 10 by a pair of separators 30.
正極10相當於第1電極,如圖2所表示,在乃是導電體之正極集電體11的兩面結合正極活性物質12而形成。取出電力的正極電極端子11a,係延伸存在自正極集電體11的其中一端的一部分而形成。複數層積了正極10的正極電極端子11a,係藉由熔接或是接著而相互地固定。 The positive electrode 10 corresponds to the first electrode, and is formed by bonding the positive electrode active material 12 to both surfaces of the positive electrode current collector 11 of the conductor as shown in FIG. 2 . The positive electrode terminal 11a from which electric power is taken out is formed by extending a part of one end of the positive electrode current collector 11. The positive electrode terminal 11a of the positive electrode 10 is laminated in plural, and is fixed to each other by welding or subsequent.
於正極10的正極集電體11的材料方面,使用例如鋁製多孔金屬、鋁製網狀織物、或是鋁製沖孔金 屬。於正極10的正極活性物質12的材料方面,在電器1為鋰離子二次電池的情況下,使用種種的氧化物(LiMn2O4類的鋰錳氧化物、二氧化錳、LiNiO2類的鋰鎳氧化物、LiCoO2類的鋰鈷氧化物、含鋰的鎳鈷氧化物、含鋰的非晶質五氧化二釩)或是硫屬化合物(二硫化鈦、二硫化鉬)等。 For the material of the positive electrode current collector 11 of the positive electrode 10, for example, a porous metal made of aluminum, a mesh fabric made of aluminum, or a punched metal made of aluminum is used. In the case of the material of the positive electrode active material 12 of the positive electrode 10, when the electric device 1 is a lithium ion secondary battery, various oxides (LiMn 2 O 4 lithium manganese oxide, manganese dioxide, LiNiO 2 type) are used. Lithium nickel oxide, LiCoO 2 type lithium cobalt oxide, lithium-containing nickel cobalt oxide, lithium-containing amorphous vanadium pentoxide, or a chalcogen compound (titanium disulfide or molybdenum disulfide).
負極20相當於與第1電極(正極10)相異之第2電極,如圖2所表示,在乃是導電體之負極集電體21的兩面結合負極活性物質22而形成。負極電極端子21a,係延伸存在自負極集電體21的其中一端的一部分而形成,使得不與形成在正極10的正極電極端子11a重疊。負極20的長邊方向的長度,比正極10的長邊方向的長度還要長。負極20的短邊方向的長度,與正極10的短邊方向的長度同樣。複數層積了負極20的負極電極端子21a,係藉由熔接或是接著而相互地固定。 The negative electrode 20 corresponds to a second electrode different from the first electrode (positive electrode 10), and is formed by bonding the negative electrode active material 22 to both surfaces of the negative electrode current collector 21 of the conductor as shown in FIG. 2 . The negative electrode terminal 21a is formed to extend from a part of one end of the negative electrode current collector 21 so as not to overlap with the positive electrode terminal 11a formed on the positive electrode 10. The length of the negative electrode 20 in the longitudinal direction is longer than the length of the positive electrode 10 in the longitudinal direction. The length of the negative electrode 20 in the short-side direction is the same as the length of the positive electrode 10 in the short-side direction. The negative electrode terminal 21a of the negative electrode 20 is laminated in plural, and is fixed to each other by welding or subsequent.
於負極20的負極集電體21的材料方面,使用例如銅製多孔金屬、銅製網狀織物、或是銅製沖孔金屬。負極20的負極活性物質22的材料方面,在電器1為鋰離子二次電池的情況下,使用吸留並放出鋰離子的碳材料。於這樣的碳材料方面,使用例如:天然石墨、人造石墨、碳煙、活性碳、碳纖維、焦炭、或是在非活性環境氣體中熱處理有機先驅物(酚樹脂、聚丙烯腈、或是纖維素)而合成的碳。 For the material of the negative electrode current collector 21 of the negative electrode 20, for example, a porous metal made of copper, a mesh fabric made of copper, or a punched metal made of copper is used. In the case of the material of the negative electrode active material 22 of the negative electrode 20, in the case where the electric device 1 is a lithium ion secondary battery, a carbon material that occludes and discharges lithium ions is used. For such carbon materials, for example, natural graphite, artificial graphite, soot, activated carbon, carbon fiber, coke, or heat treatment of organic precursors (phenolic resin, polyacrylonitrile, or cellulose) in an inert environmental atmosphere ) and the synthesis of carbon.
分隔件30,係如圖2所表示,是設在正極10 與負極20之間,並電性的隔離該正極10與負極20。分隔件30,係把電解液保持在正極10與負極20之間,擔保離子的傳導性。分隔件30形成為矩形形狀。分隔件30的長邊方向的長度,比扣掉負極電極端子21a的部分之負極20的長邊方向的長度還要長。 The separator 30, as shown in FIG. 2, is disposed on the positive electrode 10 The positive electrode 10 and the negative electrode 20 are electrically isolated from the negative electrode 20. The separator 30 holds the electrolyte between the positive electrode 10 and the negative electrode 20 to ensure the conductivity of the ions. The separator 30 is formed in a rectangular shape. The length of the separator 30 in the longitudinal direction is longer than the length of the negative electrode 20 of the portion where the negative electrode terminal 21a is buckled.
該分隔件30,係如圖4所表示,例如,層積熔融材31與耐熱材32而形成。耐熱材32比起熔融材31,其熔融溫度更高。鄰接的分隔件30,係在耐熱材32彼此已對面的狀態下進行接合。因此,耐熱材32,例如,即便是塗布到熔融材31後使其乾燥後易飛散的粉狀體,是可以密封侷限在鄰接了該粉狀體之分隔件30的內部。亦即,即便電器1振動或受到衝擊,於該電器1內,是可以防止分隔件30的耐熱材32的飛散。 The separator 30 is formed as shown in FIG. 4, for example, by laminating a molten material 31 and a heat-resistant material 32. The heat resistant material 32 has a higher melting temperature than the molten material 31. The adjacent separators 30 are joined in a state in which the heat-resistant materials 32 are opposed to each other. Therefore, the heat-resistant material 32 can be sealed to the inside of the separator 30 adjacent to the powder even if it is applied to the molten material 31 and dried and then scatters. That is, even if the electric appliance 1 vibrates or is subjected to an impact, in the electric appliance 1, the scattering of the heat-resistant material 32 of the partition member 30 can be prevented.
在此,抵接分隔件30的耐熱材32、與正極10的正極活性物質12。在該耐熱材32與正極活性物質12之間,產生摩擦力。因此,即便電器1振動或受到衝擊的話,在用分隔件30袋裝了正極10的袋裝電極50內,可以抑制正極10的移動。亦即,在電器1內,經由抑制正極10的層積偏差,防止電器1的損傷,可以維持電性的特性。 Here, the heat-resistant material 32 of the separator 30 and the positive electrode active material 12 of the positive electrode 10 are abutted. A frictional force is generated between the heat resistant material 32 and the positive electrode active material 12. Therefore, even if the electric appliance 1 vibrates or is subjected to an impact, the movement of the positive electrode 10 can be suppressed in the pouch electrode 50 in which the positive electrode 10 is packed by the separator 30. In other words, in the electric appliance 1, by suppressing the variation in the lamination of the positive electrode 10, damage of the electric appliance 1 is prevented, and electrical characteristics can be maintained.
於分隔件30的熔融材31的材料方面,例如,使用聚丙烯。於熔融材31方面,使其含浸到藉由溶解電解質到非水性溶劑的方式所調製出的非水性電解液中。為了維持非水性電解液,使其含有聚合物。分隔件 30的耐熱材32的材料方面,例如,使用以高溫成形無機化合物之陶瓷。陶瓷是利用經由氧化矽、氧化鋁、鋯氧化物、鈦氧化物等的陶瓷粒子與結合劑的結合所形成的多孔質來構成。耐熱材32的材料,並沒有限定在陶瓷,只要是比起熔融材31熔融溫度還要高的就可以。 As the material of the molten material 31 of the separator 30, for example, polypropylene is used. The molten material 31 is impregnated into a non-aqueous electrolyte solution prepared by dissolving an electrolyte to a non-aqueous solvent. In order to maintain the non-aqueous electrolyte, it contains a polymer. Separator In the material of the heat-resistant material 32 of 30, for example, a ceramic in which an inorganic compound is formed at a high temperature is used. The ceramic is formed by a porous material formed by bonding ceramic particles such as cerium oxide, aluminum oxide, zirconium oxide, or titanium oxide to a binder. The material of the heat-resistant material 32 is not limited to ceramics, and may be higher than the melting temperature of the molten material 31.
外部件材料40,係如圖2所表示,例如,利用在內部具備金屬板的層板片41及42來構成,由兩側被覆發電元件60並密封。於以層板片41及42密封發電元件60之際,開放該層板片41及42的周圍的一部分,藉由熱熔著等密封其他的周圍。從層板片41及42的開放部分注入電解液,使電解液含浸到分隔件30等。由層板片41及42的開放部減壓內部的方式來一邊抽出空氣,並熱熔接該開放部來完全密封。 The outer member material 40 is formed by, for example, the laminate sheets 41 and 42 having a metal plate inside, and is covered with the power generating element 60 on both sides and sealed. When the power generating element 60 is sealed by the laminate sheets 41 and 42, a part of the periphery of the laminated sheets 41 and 42 is opened, and the other periphery is sealed by heat fusion or the like. The electrolyte is injected from the open portions of the laminate sheets 41 and 42 to impregnate the separator 30 and the like. Air is extracted while the open portions of the laminate sheets 41 and 42 are decompressed inside, and the open portion is thermally welded to be completely sealed.
層板片41及42的材料方面,例如,使用層積了3種類的材料。具體而言,鄰接到負極20的第1層的熱熔接性樹脂的材料方面,例如,使用聚乙烯(PE)、離子性聚合物、或是乙烯/醋酸乙烯酯(EVA)。第2層的金屬箔方面,例如,使用Al箔或是Ni箔。第3層的樹脂膜方面,例如,使用具有剛性之聚對苯二甲酸乙酯(PET)或是尼龍。 For the material of the laminate sheets 41 and 42, for example, three types of materials are laminated. Specifically, for the material of the heat-fusible resin of the first layer adjacent to the negative electrode 20, for example, polyethylene (PE), an ionic polymer, or ethylene/vinyl acetate (EVA) is used. As the metal foil of the second layer, for example, an Al foil or a Ni foil is used. As the resin film of the third layer, for example, rigid polyethylene terephthalate (PET) or nylon is used.
根據藉由有關上述的本實施型態之分隔件接合裝置100接合分隔件30彼此之電器1,發揮以下的作用效果。 According to the electric appliance 1 in which the separators 30 are joined to each other by the separator joining device 100 of the present embodiment described above, the following operational effects are exhibited.
電器1具有發電元件60。發電元件60,為介 隔著分隔件30層積第1電極(正極10)、以及與第1電極(正極10)極性相異之第2電極(負極20)。分隔件30,為包含熔融材31、以及僅層積在熔融材31的單面且比熔融材31的熔融溫度還要高的耐熱材32。鄰接的分隔件30,係使耐熱材32彼此對面而接合。 The electric appliance 1 has a power generating element 60. Power generation component 60 The first electrode (positive electrode 10) and the second electrode (negative electrode 20) having a polarity different from that of the first electrode (positive electrode 10) are laminated via the separator 30. The separator 30 is a heat-resistant material 32 including the molten material 31 and only one side of the molten material 31 and higher than the melting temperature of the molten material 31. Adjacent spacers 30 are joined to each other such that the heat-resistant materials 32 face each other.
根據如此所構成的電器1,可以密封侷限鄰接了耐熱材32的分隔件30的內部。因此,電器1即便振動或受到衝擊,是可以防止分隔件30的耐熱材32的飛散。因此,可以維持電器1的電性的特性。 According to the electric appliance 1 thus constituted, the inside of the partition member 30 adjacent to the heat-resistant material 32 can be sealed. Therefore, even if the electric appliance 1 vibrates or is subjected to an impact, scattering of the heat-resistant material 32 of the partition member 30 can be prevented. Therefore, the electrical characteristics of the electric appliance 1 can be maintained.
更進一步,根據電器1,亦可構成:第1電極(正極10)與第2電極(負極20)中,以鄰接到與耐熱材32的摩擦力為相對高的一方的電極之分隔件30來挾持並接合。 Further, according to the electric appliance 1, the first electrode (positive electrode 10) and the second electrode (negative electrode 20) may be formed by a separator 30 that is adjacent to the electrode having a relatively high frictional force with the heat-resistant material 32. Hold and join.
根據如此構成之電器1,例如,抵接分隔件30的耐熱材32與正極10的正極活性物質12而產生摩擦力。因此,即便電器1振動或受到衝擊的話,在用分隔件30袋裝了正極10的袋裝電極50內,可以抑制正極10的移動。亦即,在電器1內,經由抑制正極10的層積偏差,防止電器1的損傷,可以維持電性的特性。 According to the electric appliance 1 thus constituted, for example, the heat-resistant material 32 of the separator 30 and the positive electrode active material 12 of the positive electrode 10 are abutted to generate a frictional force. Therefore, even if the electric appliance 1 vibrates or is subjected to an impact, the movement of the positive electrode 10 can be suppressed in the pouch electrode 50 in which the positive electrode 10 is packed by the separator 30. In other words, in the electric appliance 1, by suppressing the variation in the lamination of the positive electrode 10, damage of the electric appliance 1 is prevented, and electrical characteristics can be maintained.
更進一步,根據電器1,耐熱材32,亦可為包含塗布到熔融材31而乾燥之粉狀體之構成。 Further, according to the electric appliance 1, the heat-resistant material 32 may be configured to include a powder which is applied to the molten material 31 and dried.
根據如此所構成的電器1,耐熱材32為特別是即便像粉狀體般容易飛散的粉狀體,是可以密封侷限鄰接了該粉狀體的分隔件30的內部。亦即,即便電器1振 動或受到衝擊,於該電器1內,用分隔件30的熔融材31,可以有效果地遮蔽因粉狀體所構成的耐熱材32的飛散。 According to the electric appliance 1 thus constituted, the heat-resistant material 32 is a powder-like body which is particularly likely to scatter like a powder, and can seal the inside of the separator 30 which is adjacent to the powder. That is, even if the appliance is vibrating In the electric appliance 1, the molten material 31 of the separator 30 can effectively shield the scattering of the heat-resistant material 32 composed of the powder.
更進一步,根據電器1,也可以用陶瓷來形成粉狀體。 Further, according to the electric appliance 1, ceramics can also be used to form a powder.
根據如此所構成的電器1,耐熱材32為特別是即便像以高溫所成形的無機化合物之陶瓷般容易飛散的多孔質,是可以密封侷限鄰接了該陶瓷的分隔件30的內部。亦即,即便電器1振動或受到衝擊,於該電器1內,用分隔件30的熔融材31,可以有效果地遮蔽因經由粒子與結合劑的結合所形成的多孔質的陶瓷所構成的耐熱材32的飛散。 According to the electric appliance 1 thus constituted, the heat-resistant material 32 is a porous material which is particularly likely to scatter even like a ceramic of an inorganic compound formed at a high temperature, and can seal the inside of the separator 30 which is adjacent to the ceramic. That is, even if the electric appliance 1 vibrates or is subjected to an impact, in the electric appliance 1, the molten material 31 of the separator 30 can effectively shield the heat resistance caused by the porous ceramic formed by the combination of the particles and the binder. The scattering of the material 32.
接著,有關接合電器1的分隔件30彼此之接合方法,以及具體化該接合方法的分隔件接合裝置100,一邊參閱圖5~圖10說明之。 Next, a method of joining the separators 30 of the bonding apparatus 1 to each other, and a separator bonding apparatus 100 embodying the bonding method will be described with reference to FIGS. 5 to 10.
圖5為表示接合電器1的分隔件30之分隔件接合裝置100的立體圖。圖6為表示接合電器1的分隔件30之分隔件接合裝置100的真空吸引搬送滾筒540近旁的側視圖。圖7為表示接合電器1的分隔件30之分隔件接合裝置100的吸入式輸送機310近旁的側視圖。圖8為表示接合電器1的分隔件30之分隔件接合裝置100的袋裝電極吸附墊810近旁的側視圖。圖9為表示接合電器1的分隔件30之分隔件接合裝置100的加熱加壓構件710近旁的立體圖。圖10為表示在圖9之10-10線之剖視 圖。 FIG. 5 is a perspective view showing the separator joining device 100 of the separator 30 of the bonding apparatus 1. FIG. 6 is a side view showing the vicinity of the vacuum suction conveyance roller 540 of the separator joining device 100 of the separator 30 of the bonding apparatus 1. Fig. 7 is a side view showing the vicinity of the suction conveyor 310 of the separator joining device 100 of the separator 30 of the joining device 1. FIG. 8 is a side view showing the vicinity of the bagged electrode adsorption pad 810 of the separator joining device 100 of the separator 30 of the bonding apparatus 1. FIG. 9 is a perspective view showing the vicinity of the heating and pressing member 710 of the separator joining device 100 of the separator 30 of the bonding apparatus 1. Figure 10 is a cross-sectional view taken on line 10-10 of Figure 9. Figure.
在此,亦可用加熱加壓構件710一邊加壓分隔件30彼此一邊加熱的方式使其相互地接合後,插入正極10到該一對的分隔件30之間。但是,從量產性或品質的觀點來看,說明藉由用加熱加壓構件710一邊加熱並加壓挾持了正極10之分隔件30彼此的方式來相互地接合之構成。 Here, the heating and pressing member 710 may be joined to each other while the pressure-receiving separators 30 are heated to each other, and then the positive electrode 10 may be inserted between the pair of separators 30. However, from the viewpoint of mass productivity and quality, the configuration in which the separators 30 of the positive electrode 10 are held and heated by the heating and pressing member 710 is bonded to each other.
如圖5所表示,分隔件接合裝置100中,正極10,係捲繞保持在正極捲繞滾子210成捲筒狀。正極捲繞滾子210,係由圓柱形狀所構成,從動於後述的吸入式輸送機310的旋轉,旋轉在順時針方向。從正極捲繞滾子210所搬出的正極10,係介隔著搬送滾子220,朝向後述的真空吸引搬送滾筒540及640的方向進行搬送。 As shown in FIG. 5, in the separator joining device 100, the positive electrode 10 is wound and held in a roll shape of the positive electrode winding roller 210. The positive electrode winding roller 210 is formed of a cylindrical shape and is driven to rotate in the clockwise direction by the rotation of the suction conveyor 310 to be described later. The positive electrode 10 carried out from the positive electrode winding roller 210 is conveyed in the direction of the vacuum suction conveyance rollers 540 and 640, which will be described later, via the transport roller 220.
相當於搬送裝置的吸入式輸送機310,係利用無端狀的皮帶所構成,複數設置有吸引口在表面。於吸入式輸送機310的內周面,設有複數個旋轉滾子320。複數個旋轉滾子320中,一個為設有動力之驅動滾子,其他為從動滾子。以複數個旋轉滾子320順時針方向旋轉之吸入式輸送機310,係例如,於比起真空吸引搬送滾筒540及640還要更靠近正極10的搬送方向下游側與上游側處,各配設有2組。 The suction conveyor 310 corresponding to the conveying device is constituted by an endless belt, and a plurality of suction ports are provided on the surface. A plurality of rotating rollers 320 are provided on the inner peripheral surface of the suction conveyor 310. One of the plurality of rotating rollers 320 is a driving roller with power, and the other is a driven roller. The suction conveyor 310 that rotates in the clockwise direction by the plurality of rotating rollers 320 is disposed closer to the downstream side and the upstream side in the conveying direction of the positive electrode 10 than the vacuum suction conveying rollers 540 and 640, for example. There are 2 groups.
切斷正極10的切斷構件410及420,係配設在2組吸入式輸送機310之間,該2組吸入式輸送機310是配設在比真空吸引搬送滾筒540及640還要更靠近正極 10的搬送方向下游側。切斷構件410,係在前端設有直線狀之銳利的切斷刃,來切斷連續之正極10的其中一端。切斷構件420,係在前端設有已曲折之銳利的切斷刃,來切斷緊接著已切斷其中一端之正極10的另一端。切斷構件420之已曲折之切斷刃的形狀,係對應到正極電極端子11a的形狀。 The cutting members 410 and 420 that cut off the positive electrode 10 are disposed between two sets of suction conveyors 310 that are disposed closer to the vacuum suction conveying rollers 540 and 640. positive electrode The downstream direction of the transport direction of 10. The cutting member 410 is provided with a linear sharp cutting edge at the tip end to cut one end of the continuous positive electrode 10. The cutting member 420 is provided with a sharply cut cutting edge at the front end to cut the other end of the positive electrode 10 which has been cut at one end. The shape of the meandering cutting blade of the cutting member 420 corresponds to the shape of the positive electrode terminal 11a.
一對的分隔件30中之一個的分隔件30,係捲繞保持在分隔件捲繞滾子510成捲筒狀。於分隔件捲繞滾子510的軸心,抵接著一個分隔件30的熔融材31側。分隔件捲繞滾子510,係由圓柱形狀所構成,從動於相當於搬送裝置之真空吸引搬送滾筒540的旋轉,旋轉在逆時針方向。一個分隔件30,係被加壓滾子520與夾持滾子530挾持,在具有一定的張力的狀態下被搬送,在被真空吸附於真空吸引搬送滾筒540的狀態下逆時針方向旋轉。真空吸引搬送滾筒540,係由圓柱形狀所構成,複數設置有吸引口。一個分隔件30,係設在接近於真空吸引搬送滾筒540,藉由在前端設有銳利的切斷刃之切斷構件430,以一定的寬度而被切斷。 The separator 30 of one of the pair of separators 30 is wound and held in a roll shape of the separator winding roller 510. The core of the roller winding member 510 is wound against the side of the molten material 31 of one partition member 30. The separator winding roller 510 is formed of a cylindrical shape and is driven by the rotation of the vacuum suction conveyance roller 540 corresponding to the conveying device, and the rotation is in the counterclockwise direction. The separator 30 is held by the pressure roller 520 and the pinch roller 530, and is conveyed while having a constant tension, and is rotated counterclockwise in a state of being vacuum-adsorbed to the vacuum suction conveyance roller 540. The vacuum suction conveyance roller 540 is formed by a cylindrical shape, and a plurality of suction ports are provided in plural. One separator 30 is provided close to the vacuum suction conveyance roller 540, and is cut at a constant width by a cutting member 430 having a sharp cutting edge at its tip end.
同樣地,一對的分隔件30中之另一個的分隔件30,係捲繞保持在分隔件捲繞滾子610成捲筒狀。於分隔件捲繞滾子610的軸心,抵接著另一個分隔件30的熔融材31側。分隔件捲繞滾子610,係由圓柱形狀所構成,從動於相當於搬送裝置之真空吸引搬送滾筒640的旋轉,旋轉在順時針方向。另一個分隔件30,係被加壓滾 子620與夾持滾子630挾持,在具有一定的張力的狀態下被搬送,在被真空吸附於真空吸引搬送滾筒640的狀態下順時針方向旋轉。真空吸引搬送滾筒640,係由圓柱形狀所構成,複數設置有吸引口。另一個分隔件30,係設在接近於真空吸引搬送滾筒640,藉由在前端設有銳利的切斷刃之切斷構件440,以一定的寬度而被切斷。 Similarly, the separator 30 of the other of the pair of separators 30 is wound and held in a roll shape of the separator winding roller 610. The axial center of the separator winding roller 610 is abutted against the side of the molten material 31 of the other separator 30. The separator winding roller 610 is formed of a cylindrical shape and is driven by the rotation of the vacuum suction conveyance roller 640 corresponding to the conveying device, and the rotation is in the clockwise direction. Another partition 30 is pressurized The sub-620 is held by the pinch roller 630, and is conveyed while having a constant tension, and is rotated clockwise in a state where it is vacuum-adsorbed to the vacuum suction conveyance roller 640. The vacuum suction conveyance roller 640 is formed by a cylindrical shape, and a plurality of suction ports are provided. The other separator 30 is provided close to the vacuum suction conveyance roller 640, and is cut at a constant width by a cutting member 440 having a sharp cutting edge at its tip end.
在真空吸引搬送滾筒540及640的間隙的部位,如同一對分隔件30挾持正極10般,在層積了一個分隔件30、正極10、及另一個分隔件30的狀態下進行搬送。 At a portion where the gap between the transfer rollers 540 and 640 is suctioned by the vacuum, as in the case where the pair of separators 30 hold the positive electrode 10, the separator 30, the positive electrode 10, and the other separator 30 are stacked and transported.
如圖9所表示,加熱加壓構件710,係配設在一對分隔件30的長邊方向之兩端的上方及下方,上下移動使得從夾入該一對分隔件30後開始離開。尚且,於圖9中,本來,圖示為在層積了一個分隔件30、正極10、及另一個分隔件30的狀態,但在此為使其離開之狀態。挾持了正極10之一對分隔件30,係被相互地接合,形成袋裝電極50。一對分隔件30,係配設成耐熱材32相互地對面。加熱加壓構件710,係例如,利用不鏽材料或銅所構成,形成為長方體形狀。加熱加壓構件710,係藉由未圖示的驅動部上下移動。加熱加壓構件710,係例如,利用電熱線或加熱燈泡來進行加熱。 As shown in FIG. 9, the heating and pressing member 710 is disposed above and below both ends of the pair of separators 30 in the longitudinal direction, and moves up and down so as to start to separate from the pair of separators 30. Further, in Fig. 9, originally, a state in which one separator 30, the positive electrode 10, and the other separator 30 are laminated is shown, but here, it is in a state of being separated. One of the separators 30 of the positive electrode 10 is held and joined to each other to form the pocket electrode 50. The pair of separators 30 are disposed such that the heat-resistant members 32 face each other. The heating and pressing member 710 is formed of, for example, a stainless material or copper, and is formed in a rectangular parallelepiped shape. The heating and pressing member 710 is moved up and down by a driving unit (not shown). The heating and pressing member 710 is heated by, for example, a heating wire or a heating bulb.
如圖10(a)所表示,配設複數個加熱加壓構件710,使得一對分隔件30的長邊方向的兩端從上下方向夾入。在圖10(a)以剖視圖所表示之構成,係相當於 在圖9以立體圖所表示之構成。尚且,於圖10(a)中,本來,圖示為在層積了一個分隔件30、正極10、及另一個分隔件30的狀態,但在此為使其離開之狀態。 As shown in Fig. 10 (a), a plurality of heating and pressing members 710 are disposed such that both ends of the pair of separators 30 in the longitudinal direction are sandwiched from the vertical direction. The configuration shown in cross section in Fig. 10(a) is equivalent to This is shown in a perspective view in Fig. 9. Further, in Fig. 10(a), originally, a state in which one separator 30, the positive electrode 10, and the other separator 30 are laminated is shown, but here, it is in a state of being separated.
如圖10(b)所表示,經由驅動複數個加熱加壓構件710在表示於圖中的P1的方向的方式,加熱加壓構件710自上下方向挾持一對分隔件30的長邊方向的兩端後,接合該一對分隔件30。此時,一對分隔件30,係藉由加熱加壓構件710被加熱及加壓,進行接合。 As shown in FIG. 10(b), the heating and pressing member 710 holds two of the longitudinal directions of the pair of separators 30 from the upper and lower directions by driving the plurality of heating and pressing members 710 in the direction indicated by P1 in the drawing. After the end, the pair of separators 30 are joined. At this time, the pair of separators 30 are heated and pressurized by the heating and pressing member 710 to be joined.
如圖10(c)所表示,複數個加熱加壓構件710,係驅動在圖中的P2所表示的方向,從接合完的一對分隔件30進行離開。一邊參閱圖11及圖10,在上述的分隔件接合方法中,加熱加壓構件710為一邊加熱挾持了正極10之一對分隔件30並加壓,來接合該一對分隔件30。這樣的一對分隔件30之接合製程,係相當於從量產性或品質的面來看為優秀之所謂形成袋裝電極50之製程。 As shown in FIG. 10(c), a plurality of heating and pressing members 710 are driven in a direction indicated by P2 in the drawing, and are separated from the joined pair of separators 30. Referring to Fig. 11 and Fig. 10, in the above-described separator joining method, the heating and pressing member 710 is heated and held by one of the positive electrodes 10 against the separator 30 and pressurized to join the pair of separators 30. The joining process of such a pair of separators 30 corresponds to a process of forming the bagged electrode 50 which is excellent in terms of mass productivity or quality.
相當於搬送裝置之袋裝電極吸附墊810,係暫時載置已完成的袋裝電極50到指定的載置台850。袋裝電極吸附墊810,係由板狀所構成,在與袋裝電極50抵接的面複數設有吸引口。袋裝電極吸附墊810,係例如把未圖示的空氣壓縮機等作為動力,連結到自由伸縮的伸縮部820之其中一端。伸縮部820之另一端,係連結到板狀的支撐構件830。支撐構件830,係利用例如未圖示之轉動馬達,沿著一對的軌條840往復運動。如此,袋裝電極 吸附墊810,係藉由伸縮部820、支撐構件830、及一對的軌條840,吸引並移動用吸入式輸送機310所搬送過之袋裝電極50,載置到載置台850。 The bagged electrode adsorption pad 810 corresponding to the transfer device temporarily mounts the completed packaged electrode 50 to the designated mounting table 850. The bagged electrode adsorption pad 810 is formed of a plate shape, and a plurality of suction ports are provided on a surface that is in contact with the bagged electrode 50. The bagged electrode adsorption pad 810 is connected to one end of the freely stretchable stretchable portion 820 by using, for example, an air compressor (not shown) as a power. The other end of the expansion and contraction portion 820 is coupled to a plate-shaped support member 830. The support member 830 reciprocates along the pair of rails 840 by, for example, a turning motor (not shown). So, the bagged electrode The adsorption pad 810 sucks and moves the bagged electrode 50 conveyed by the suction conveyor 310 by the expansion and contraction portion 820, the support member 830, and the pair of rails 840, and places it on the mounting table 850.
分別於圖6、圖7、及圖8所表示之真空吸引搬送滾筒540、吸入式輸送機310、及袋裝電極吸附墊810,係相當於以分別吸附了分隔件30之狀態下進行搬送之搬送裝置。在此,分隔件30的熔融材31,係例如,利用聚丙烯所構成,是不會飛散。另一方面,分隔件30的耐熱材32,係例如,利用以高溫成形無機化合物之陶瓷所構成,容易變成粉狀體而飛散。因此,真空吸引搬送滾筒540、吸入式輸送機310、及袋裝電極吸附墊810,係構成為不是吸引分隔件30的耐熱材32,而是吸引分隔件30的熔融材31側。根據如此所構成之電器1,因為吸引分隔件30之難以飛散的熔融材31側而進行搬送的緣故,在分隔件接合裝置100內,可以防止分隔件30的耐熱材32飛散。 The vacuum suction conveyance roller 540, the suction conveyor 310, and the bagged electrode adsorption pad 810 shown in FIG. 6, FIG. 7, and FIG. 8 are equivalent to being conveyed in a state in which the separator 30 is adsorbed, respectively. Transfer device. Here, the molten material 31 of the separator 30 is made of, for example, polypropylene, and does not scatter. On the other hand, the heat-resistant material 32 of the separator 30 is made of, for example, a ceramic in which an inorganic compound is molded at a high temperature, and is easily scattered into a powder. Therefore, the vacuum suction conveyance roller 540, the suction conveyor 310, and the bagged electrode adsorption pad 810 are configured not to attract the heat-resistant material 32 of the separator 30 but to attract the side of the molten material 31 of the separator 30. According to the electric appliance 1 configured as described above, the heat transfer material 32 of the separator 30 can be prevented from scattering in the separator joining device 100 by sucking the side of the molten material 31 which is difficult to scatter the separator 30.
更進一步,真空吸引搬送滾筒540、吸入式輸送機310、及袋裝電極吸附墊810之各搬送裝置,係吸引分隔件30之不飛散的熔融材31側而進行搬送的緣故,可以一定地保持該吸引力。因各搬送裝置所致的分隔件30的吸引力保持在一定的話,可以讓該分隔件30的進給尺寸一定。更進一步,各搬送裝置,係因為沒有吸引容易飛散的耐熱材32側的緣故,沒有該耐熱材32飛散之情事。為此,在各搬送裝置的周邊,沒有必要設有清掃去除飛散 的粉狀體等之機構。因此,可以小型化分隔件接合裝置100的結構,且抑制成本。更進一步,各搬送裝置,係不吸引飛散且容易剝離的耐熱材32側的緣故,可以防止該耐熱材32從熔融材31剝離,或產生吸引傷痕、或是接觸傷痕。更進一步,各搬送裝置,係因為沒有吸引容易飛散的耐熱材32側的緣故,所以不會因粉狀體而堵塞,沒有必要於該各搬送裝置內設有去除粉狀體用的過濾器等並定期地交換清掃。 Further, each of the conveyance devices of the vacuum suction conveyance roller 540, the suction conveyor 310, and the bagged electrode adsorption pad 810 can be held while being sucked by the side of the molten material 31 which is not scattered by the separator 30. The attraction. Since the suction force of the partition member 30 by each conveying device is kept constant, the feeding size of the partitioning member 30 can be made constant. Further, in each of the conveying apparatuses, since the side of the heat-resistant material 32 which is easy to scatter is not attracted, the heat-resistant material 32 does not scatter. Therefore, it is not necessary to have a cleaning and removal scattering around the respective conveying devices. The body of the powder, etc. Therefore, the structure of the spacer joining device 100 can be miniaturized, and the cost can be suppressed. Further, each of the conveying devices can prevent the heat-resistant material 32 from being peeled off from the molten material 31, or attracting scratches or contact flaws, without attracting the side of the heat-resistant material 32 which is scattered and easily peeled off. Further, since each of the conveying devices does not attract the side of the heat-resistant material 32 which is easily scattered, it is not clogged by the powder, and it is not necessary to provide a filter for removing the powder in each of the conveying devices. And cleanly exchanged regularly.
根據上述之電器1的分隔件30彼此之接合方法,以及具體化該接合方法的分隔件接合裝置100,發揮有以下的作用效果。 According to the above-described method of joining the separators 30 of the electric appliance 1 and the separator joining device 100 embodying the joining method, the following effects are exhibited.
電器1的分隔件接合方法、以及具體化該接合方法之分隔件接合裝置100,乃是針對把第1電極(正極10)、以及與第1電極(正極10)極性相異之第2電極(負極20)予以交互層積之分離30彼此進行接合之裝置。使用包含熔融材31、以及僅層積在熔融材31的單面且比熔融材31的熔融溫度還要高的耐熱材32之分隔件30。在此,保持分隔件30的熔融材31的一側並進行搬送,把使鄰接的分隔件30的耐熱材32彼此對面並鄰接的分隔件30彼此予以接合。 The separator joining method of the electric appliance 1 and the separator joining device 100 embodying the joining method are for the first electrode (positive electrode 10) and the second electrode having the same polarity as the first electrode (positive electrode 10) ( The negative electrode 20) is a device in which the separations 30 of the alternately stacked layers are joined to each other. The separator 30 including the molten material 31 and the heat-resistant material 32 which is laminated only on one side of the molten material 31 and higher than the melting temperature of the molten material 31 is used. Here, one side of the molten material 31 of the separator 30 is held and conveyed, and the separators 30 which are adjacent to each other and adjacent to the heat-resistant material 32 of the adjacent separator 30 are joined to each other.
根據如此所構成之電器1的分隔件接合方法、及其之分隔件接合裝置100,因為藉由搬送裝置保持分隔件30之難以飛散的熔融材31側而進行搬送的緣故,在分隔件接合裝置100內,可以防止分隔件30的耐熱材 32飛散。因此,可以保持分隔件接合裝置100內清淨,而且,可以維持已接合分隔件30之電器1的電性的特性。 In the separator joining method of the electric appliance 1 configured as described above, and the separator joining device 100, the conveying device holds the side of the molten material 31 which is difficult to scatter by the separator 30, and the separator is joined by the separator. 100, the heat-resistant material of the partition member 30 can be prevented 32 scattered. Therefore, it is possible to keep the inside of the separator joining device 100 clean, and it is possible to maintain the electrical characteristics of the electric appliance 1 to which the separator 30 has been joined.
更進一步,真空吸引搬送滾筒540、吸入式輸送機310、及袋裝電極吸附墊810之各搬送裝置,係吸引分隔件30之不飛散的熔融材31側而進行搬送的緣故,可以一定地保持該吸引力。因各搬送裝置所致的分隔件30的吸引力保持在一定的話,可以讓該分隔件30的進給尺寸一定。 Further, each of the conveyance devices of the vacuum suction conveyance roller 540, the suction conveyor 310, and the bagged electrode adsorption pad 810 can be held while being sucked by the side of the molten material 31 which is not scattered by the separator 30. The attraction. Since the suction force of the partition member 30 by each conveying device is kept constant, the feeding size of the partitioning member 30 can be made constant.
更進一步,各搬送裝置,係因為沒有吸引容易飛散的耐熱材32側的緣故,沒有該耐熱材32飛散之情事。為此,在各搬送裝置的周邊,沒有必要設有清掃去除飛散的粉狀體等之機構。因此,可以小型化分隔件接合裝置100的結構,且抑制成本。 Further, in each of the conveying apparatuses, since the side of the heat-resistant material 32 which is easy to scatter is not attracted, the heat-resistant material 32 does not scatter. Therefore, it is not necessary to provide a mechanism for cleaning and removing the scattered powder or the like around the respective conveying devices. Therefore, the structure of the spacer joining device 100 can be miniaturized, and the cost can be suppressed.
更進一步,各搬送裝置,係不吸引飛散且容易剝離的耐熱材32側的緣故,可以防止該耐熱材32從熔融材31剝離,或產生吸引傷痕、或是接觸傷痕。 Further, each of the conveying devices can prevent the heat-resistant material 32 from being peeled off from the molten material 31, or attracting scratches or contact flaws, without attracting the side of the heat-resistant material 32 which is scattered and easily peeled off.
更進一步,各搬送裝置,係因為沒有吸引容易飛散的耐熱材32側的緣故,所以不會因粉狀體而堵塞,沒有必要於該各搬送裝置內設有去除粉狀體用的過濾器等並定期地交換清掃。因此,可以削減有關清掃之工時。 Further, since each of the conveying devices does not attract the side of the heat-resistant material 32 which is easily scattered, it is not clogged by the powder, and it is not necessary to provide a filter for removing the powder in each of the conveying devices. And cleanly exchanged regularly. Therefore, it is possible to reduce the working hours related to cleaning.
更進一步,在電器1的分離30之接合中,進行接合的分隔件30的耐熱材32方面,亦可使用塗布在熔 融材31並使其乾燥之粉狀體。 Further, in the joining of the separator 30 of the electric appliance 1, in terms of the heat-resistant material 32 of the joined separator 30, it is also possible to use the coating in the fusion. The powder 31 is melted and dried.
如此構成的話,耐熱材32,特別是,即便為如粉狀體般容易飛散的粉狀體,在分隔件接合裝置100內,也是可以有效果地防止分隔件30的耐熱材32飛散。還有,各搬送裝置,因為不吸引粉狀體的緣故,所以沒有因該粉狀體而堵塞之情事。 According to this configuration, the heat-resistant material 32 is particularly effective in preventing the heat-resistant material 32 of the separator 30 from scattering even in the separator bonding apparatus 100 even if it is a powdery body which is easily scattered like a powder. Further, since each conveying device does not attract the powder, there is no clogging due to the powder.
更進一步,在電器1的分離30之接合中,進行接合的分隔件30的耐熱材32方面,亦可使用陶瓷。 Further, in the joining of the separator 30 of the electric appliance 1, ceramics may be used in terms of the heat-resistant material 32 of the joined separator 30.
如此構成的話,耐熱材32,特別是,即便為如以高溫成形無機化合物之陶瓷般容易飛散的多孔質,在分隔件接合裝置100內,也是可以有效果地防止分隔件30的耐熱材32飛散。還有,各搬送裝置,因為不吸引陶瓷的緣故,所以沒有因該陶瓷而堵塞之情事。 In such a configuration, the heat-resistant material 32 is particularly porous in the separator joining device 100, and the heat-resistant material 32 of the separator 30 can be effectively prevented from scattering even in the case of a porous material which is easily scattered like a ceramic in which an inorganic compound is molded at a high temperature. . Further, since each of the transporting devices does not attract ceramics, there is no clogging due to the ceramics.
在有關第2實施型態之電器中,一邊參閱圖11說明之。 In the electric appliance relating to the second embodiment, it will be explained with reference to Fig. 11 .
在第2實施型態中,有關與第1實施型態同樣的構成,使用相同的符號,並省略前述說明。 In the second embodiment, the same components as those in the first embodiment are denoted by the same reference numerals, and the description thereof will be omitted.
圖11為表示分別在用一對分隔件30袋裝負極20而形成之袋裝電極70的兩端,層積正極10的狀態之電器的一部分之剖視圖。 FIG. 11 is a cross-sectional view showing a part of the electric appliance in a state in which the positive electrode 10 is laminated on both ends of the pouch electrode 70 formed by enclosing the negative electrode 20 with a pair of separators 30.
抵接分隔件30的耐熱材32、與負極20的負極活性物質22,並產生摩擦力。因此,即便電器振動或 受到衝擊的話,在用分隔件30袋裝了負極20的袋裝電極50內,可以抑制負極20的移動。亦即,在電器內,經由抑制負極20的層積偏差,防止電器的損傷,可以維持電性的特性。 The heat resistant material 32 of the separator 30 and the negative electrode active material 22 of the negative electrode 20 are abutted to generate a frictional force. So even if the appliance vibrates or When the impact is applied, the movement of the negative electrode 20 can be suppressed in the pocket electrode 50 in which the negative electrode 20 is packed by the separator 30. That is, in the electric appliance, by suppressing variations in the lamination of the negative electrode 20, damage to the electric appliance is prevented, and electrical characteristics can be maintained.
有關上述第2實施型態之電器,係產生在耐熱材32與負極20的負極活性物質22之間的摩擦力,比起產生在耐熱材32與正極10的正極活性物質12之間的摩擦力,在較大的場合是有效的。 In the electric appliance according to the second embodiment, the friction between the heat-resistant material 32 and the negative electrode active material 22 of the negative electrode 20 is generated, and the friction between the heat-resistant material 32 and the positive electrode active material 12 of the positive electrode 10 is generated. It is effective on larger occasions.
其他,本發明,係根據記載於申請專利範圍的結構可以做各式各樣的改變,該些改變亦為本發明之範疇。 In addition, the present invention can be variously modified according to the structure described in the patent application, and such modifications are also within the scope of the invention.
在第1實施型態中,作為其中一例,說明了用搬送裝置(真空吸引搬送滾筒540、吸入式輸送機310、以及袋裝電極吸附墊810)吸引分隔件30的熔融材31側並進行搬送之構成,但並不限定於這樣的構成。例如,也作為藉由搬送裝置挾持分隔件30的熔融材31側而搬送,或是藉由搬送裝置載置分隔件30的熔融材31側而搬送之構成,是可以密封侷限鄰接了耐熱材32之分隔件30的內部。 In the first embodiment, the conveyance device (the vacuum suction conveyance roller 540, the suction conveyor 310, and the bagged electrode adsorption pad 810) is sucked and conveyed on the side of the molten material 31 of the separator 30. The configuration is not limited to such a configuration. For example, it is configured to be transported while holding the side of the molten material 31 of the separator 30 by the transport device, or by transporting the side of the molten material 31 of the separator 30 by the transport device, and it is possible to seal the adjacent heat-resistant material 32. The interior of the divider 30.
還有,在實施型態中,作為其中一例,說明了藉由分隔件接合裝置100用一對分隔件30袋裝正極10之構成,但並不限定於這樣的構成。例如,亦可作為藉由分隔件接合裝置100用一對分隔件30袋裝負極20之構成。這樣的構成,係產生在耐熱材32與負極20的負極活 性物質22之間的摩擦力,比起產生在耐熱材32與正極10的正極活性物質12之間的摩擦力,在較大的場合是有效的。 In the embodiment, the configuration in which the positive electrode 10 is packaged by the pair of separators 30 by the separator bonding apparatus 100 is described as an example. However, the configuration is not limited thereto. For example, it is also possible to form the negative electrode 20 by a pair of separators 30 by the separator joining device 100. Such a configuration is generated in the negative electrode of the heat-resistant material 32 and the negative electrode 20 The frictional force between the sex substances 22 is effective in a larger case than the frictional force generated between the heat-resistant material 32 and the positive electrode active material 12 of the positive electrode 10.
本申請案,係根據2012年12月28日申請之日本專利申請案號2012-286988號案以及2012年12月28日申請之日本專利申請案號2012-286993號案;作為整體,其揭示內容被參閱、編入。 The present application is based on the Japanese Patent Application No. 2012-286988 filed on Dec. 28, 2012, and the Japanese Patent Application No. 2012-286993 filed on Dec. 28, 2012; Be referred to and programmed.
10‧‧‧正極(第1電極) 10‧‧‧ positive electrode (first electrode)
11‧‧‧正極集電體 11‧‧‧ positive current collector
12‧‧‧正極活性物質 12‧‧‧ positive active material
20‧‧‧負極(第2電極) 20‧‧‧Negative electrode (2nd electrode)
21‧‧‧負極集電體 21‧‧‧Negative current collector
22‧‧‧負極活性物質 22‧‧‧Negative active material
30‧‧‧分隔件 30‧‧‧Parts
31‧‧‧熔融材 31‧‧‧ molten material
32‧‧‧耐熱材 32‧‧‧Heat-resistant materials
50‧‧‧袋裝電極 50‧‧‧Bagged electrode
Claims (10)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| JP2012286993 | 2012-12-28 | ||
| JP2012286988 | 2012-12-28 |
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| TW201434652A true TW201434652A (en) | 2014-09-16 |
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| TW102144642A TW201434652A (en) | 2012-12-28 | 2013-12-05 | Separator connecting device for electric appliance and electric appliance and joining method thereof |
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| US (1) | US9799910B2 (en) |
| EP (1) | EP2940775B1 (en) |
| JP (1) | JP5994866B2 (en) |
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| CN (2) | CN110071250A (en) |
| TW (1) | TW201434652A (en) |
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| KR101730318B1 (en) | 2014-07-07 | 2017-05-11 | 주식회사 엘지화학 | Battery Cell Having Separation Film of Suppressed Thermal Shrinkage |
| KR102165333B1 (en) * | 2014-08-01 | 2020-10-13 | 삼성에스디아이 주식회사 | Device for winding electrode plate |
| JP6292081B2 (en) * | 2014-08-21 | 2018-03-14 | 日産自動車株式会社 | Separator molding equipment |
| JP6511693B6 (en) * | 2014-11-27 | 2019-06-12 | 株式会社エンビジョンAescエナジーデバイス | battery |
| CN111769241A (en) | 2015-02-17 | 2020-10-13 | 株式会社杰士汤浅国际 | Power storage element, power storage device, and automobile |
| KR102540142B1 (en) * | 2015-11-10 | 2023-06-05 | 삼성에스디아이 주식회사 | Apparatus for Winding Electrode Assembly |
| JPWO2018154777A1 (en) * | 2017-02-27 | 2019-07-11 | 日産自動車株式会社 | Method of manufacturing monocell |
| CN108807809A (en) * | 2017-05-04 | 2018-11-13 | 宁德新能源科技有限公司 | Battery core and energy storage device |
| DE102017216209A1 (en) * | 2017-09-13 | 2019-03-14 | Robert Bosch Gmbh | Method for producing an electrode stack for a battery cell and battery cell |
| KR102864919B1 (en) * | 2021-02-05 | 2025-09-26 | 주식회사 엘지에너지솔루션 | Cutting and Fusing Device for Separator |
| KR20220127094A (en) * | 2021-03-10 | 2022-09-19 | 주식회사 엘지에너지솔루션 | Electrode assembly and manufacturing method thereof |
| WO2022204981A1 (en) * | 2021-03-30 | 2022-10-06 | 宁德新能源科技有限公司 | Electrochemical apparatus and electrical device |
| KR20260014856A (en) * | 2024-07-24 | 2026-02-02 | 삼성에스디아이 주식회사 | Electrode assembly and secondary battery |
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| US9799910B2 (en) | 2017-10-24 |
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