TW201716355A - Ceramic material and production method thereof, and eluted functional water - Google Patents

Abstract

A ceramic material is provided which contains a beneficial mineral component and which is easier to handle than a liquid. This ceramic material contains a mineral component derived from mineral functional water and immobilized in an elutable manner. In said ceramic material, the mineral component is immobilized in an elutable manner, and the immobilized mineral component can be eluted through contact with an extraction solvent.

Description

Ceramic material, its manufacturing method, and electrolyte water

The present invention is based on the Japanese Patent Application No. 2015-173941, the entire disclosure of which is incorporated herein by reference.

The present invention relates to a ceramic material in which a beneficial mineral component is immobilized in a soluble state, a method for producing the same, and a soluble functional water containing a mineral component eluted from the ceramic material.

In water containing mineral components, there is a possibility of effects such as soil modification, plant growth, decomposition of harmful chemicals, deodorization, air purification, etc. In the past, various mineral-containing waters and Mineral water manufacturing equipment was developed.

The inventors of the present invention have developed a mineral-containing water producing apparatus (A) including a conductive wire coated with an insulator and a mineral-imparting material (A) immersed in water to conduct a direct current to the conductive wire. The water around the conductive wire generates a water flow in the same direction as the DC current, and imparts ultrasonic vibration to the water to form a raw material mineral aqueous solution. (A) means, and a far-infrared ray generating means for forming a mineral-containing water (A) by irradiating far-infrared rays to the formed raw material mineral aqueous solution (A) (see Patent Document 1).

Further, the inventors of the present invention have also developed a mineral water manufacturing facility comprising a mineral water-containing water producing device (A) and a mineral-containing water producing device (B), and the mineral water-containing water producing device (B) And a plurality of water-passing containers filled with mineral material-imparting materials (B) having different types; and a water-feeding path in which a plurality of the water-passing containers are connected in series; and in a state in which a plurality of the water-passing containers are juxtaposed a bypass water passage connected to the water supply path; and a water flow switching valve provided in a branching portion of the water supply path and the bypass water passage (refer to Patent Document 2). Further, it is described that when the mineral water-producing equipment is used, it is possible to produce mineral functional water (far-infrared-generated water) having a function of generating far-infrared rays having a characteristic wavelength.

In addition, in the apparatus described in Patent Document 2, the types and blending ratios of the raw materials (mineral imparting materials) used in the mineral-containing water producing apparatuses (A) and (B) are complicated. In the meantime, it is not possible to know which kind of mineral-based material to be used, and it is possible to obtain mineral-functional water which has an effect. However, the inventors of the present invention used the mineral-functional water-making apparatus disclosed in Patent Document 2, As a result of the review, the mineral functional water produced under certain conditions has excellent control effects on single-celled organisms and viruses (Patent Document 3) and body activation. (Patent Document 4), combustion promotion of hydrocarbons (patent text) 5), antioxidant effects (Patent Document 6) and the like.

[Previous Technical Literature] [Patent Document]

[Patent Document 1] Japanese Patent No. 4817817

[Patent Document 2] Japanese Laid-Open Patent Publication No. 2011-56366

[Patent Document 3] WO2016/043213

[Patent Document 4] WO2016/043214

[Patent Document 5] PCT/JP2016/058141

[Patent Document 6] PCT/JP2016/058362

The mineral functional water described in the patent documents 3 to 6 and the like has a specific effective effect, but since it is a liquid, there is room for improvement in the convenience surface such as storage property and transportability.

Under the circumstances, an object of the present invention is to provide a ceramic material which can be immobilized (maintained) by elution of a beneficial mineral component, which can be easily handled compared to a liquid, and a method for producing the same.

As a result of intensive studies to solve the above problems, the inventors of the present invention have found that the following invention has been completed in accordance with the above objects.

That is, the present invention is the invention described below.

<1> A ceramic material comprising a mineral component that is immobilized and is a source of mineral water.

The ceramic material according to the above <1>, wherein the ceramic material is a cement hardened body containing a mineral component or a ceramic porous body in which a mineral component is supported in a pore.

(3) The ceramic material according to the above <1>, wherein the mineral functional water is contained in a ratio of 1:5 to 1:20 (weight ratio) by the following process (1) The mineral water (A) formed, and the mineral water containing the mineral water (B) formed by the following process (2), process (1): a conductive wire covered with an insulator, And a plant material consisting of a plant material consisting of a plant of the family Asteraceae and a plant of the family Rosaceae, and a woody plant material consisting of one or more woody plants selected from maple, birch, pine and cedar. The substance-imparting material (A) is immersed in water to conduct a direct current to the conductive wire, and a water flow in the same direction as the direct current is generated in the water around the conductive wire, and ultrasonic vibration is applied to the water to form a raw material mineral aqueous solution. (A) Next, the raw mineral aqueous solution (A) is irradiated with far infrared rays (wavelength: 6 to 14 μm) to form a process containing mineral water (A), wherein the amount of the mineral-imparting material (A) added to the water is 10~15% by weight, current value and voltage value of direct current flowing through the foregoing conductive line Do is 0.05 ~ 0.1A, and the 8000 ~ 8600V Scope; Process (2): a process for forming mineral-containing water (B) containing mineral water (B) through six water-passing containers, wherein the six water-passing containers are filled with inorganic substances of different kinds The first water-passing container to the sixth water-passing container in which the mineral-based material (B) is connected in series: the mineral-imparting material (B1) in the first water-passing container contains 70% by weight of limestone, respectively. a mixture of a percentage by weight of coral fossil and 15% by weight of shells; and a mineral-imparting material (B2) in the second water-passing container containing 40% by weight of limestone, 15% by weight of coral fossil, and 40% by weight of shells, respectively. a mixture of 5% by weight of activated carbon; the mineral-imparting material (B3) in the third water-passing container is a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells, respectively; The mineral-imparting material (B4) in the water container is a mixture containing 90% by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shells, respectively; and the mineral-imparting material (B5) in the fifth water-passing container is a mixture comprising 80% by weight of limestone, 10% by weight of coral fossils, and 10% by weight of shells; The mineral-imparting material (B6) in the sixth water-passing container contains 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shellfish. a mixture of shells.

The ceramic material according to the above <3>, wherein the mineral material (A) is formed by a weight ratio of the plant material (A1-1) to the wood material (A2-1). a mineral-donating material (A'-1) obtained by mixing 1:2.7~1:3.3, in which large scorpions (leaf, stem, and flower), wormwood (leaf and stem), The dried pulverized material of the compositae of the compositae (leaf and stem) which are mixed at a ratio of 8 to 12% by weight, 55 to 65% by weight, and 27 to 33% by weight, respectively, and then pulverized; Wild rose (leaf, flower), bayberry (leaf and stem), raspberry (leaf, stem and flower) are respectively 17-23% by weight, 8-12% by weight, 65~75 weight The dry pulverized material of the Rosaceae plant which is mixed, dried and then pulverized, and the dried pulverized material of the compositae plant and the dried pulverized material of the Rosaceae plant are mixed at a ratio of 1:0.8 to 1:1.2 (weight ratio). The obtained grass plant material (A1-1) is used as the raw material of the grass plant, and is composed of maple (leaf and stem), birch (leaf, stem, and bark), cedar (leaf, stem, And the bark) A woody plant material (A2-1) composed of a dry pulverized material which is mixed, dried, and pulverized at a ratio of 22 to 28% by weight, 22 to 28% by weight, and 45 to 55% by weight as the raw material of the woody plant .

The ceramic material according to the above <3>, wherein the mineral-imparting material (A) is formed by a weight ratio of the plant material (A1-2) to the wood material (A2-2). 1:5 way mixed place The mineral-improving material (A'-2) obtained, in which the big cockroach (leaf, stem, and flower), the wormwood (leaf and stem), and the mountain daisy (leaf and stem) are respectively a dry pulverized material of a compositae plant which is mixed, dried, and pulverized at a ratio of 10% by weight, 60% by weight, and 30% by weight; and wild rose (leaf, flower), arbutus (leaf and stem), The dried pulverized material of the Rosaceae plant in which the raspberry (leaf, stem, and flower parts) are mixed at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively, and then pulverized by a ratio of 1:1 (weight ratio) The plant material (A1-2) obtained by mixing is used as the raw material of the above-mentioned plant, which will be composed of maple (deciduous), birch (deciduous, stem, and bark), cedar (deciduous, stem, and bark) The woody plant material (A2-2) which consists of the dry-pulverized material which mix|blended, and dried, and is pulverized in the ratio of 20 weight%, 60 weight%, and 20 weight%, respectively, as the said woody plant raw material.

<6> A ceramic material according to any one of <1> to <5>, wherein the ceramic material is a cement hardened body, and the manufacturing method has the following: The functional water and the cement composition are mixed to obtain a mixing process of the cement mixture; and the curing process of curing and solidifying the obtained cement mixture.

<7> A method of producing a ceramic material, which is a ceramic material according to any one of <1> to <5>, characterized in that: The ceramic material is a cement hardened body, and the manufacturing method has a process of mixing a liquid for mixing with a ceramic powder for a carrier into a clay-like mixture (I); and heat-treating the clay-like mixture to obtain a ceramic porous body (II) And a process (III) of allowing the mineral functional water to permeate the pores of the ceramic porous body and then drying the mineral component to fix the mineral component to the ceramic porous body.

<8> A method for producing a solute functional water, characterized in that the ceramic material as described in <1> to <5> is brought into contact with an extraction solvent mainly composed of water, and the mineral material contained in the ceramic material is contained The components are dissolved in the aforementioned extraction solvent.

<X1> A ceramic material comprising a mineral component immobilized to be soluble and which is a source of mineral functional water, characterized in that the mineral functional water meets all of the following requirements (i) to (iv) (i) The sample having the weight of 15 parts by weight or more of the mineral functional water fixed to the weight of the ceramic carrier 100 has an average emission ratio (measuring temperature: 25 ° C) to the black body at a wavelength of 5 to 7 μm and a wavelength of 14 to 24 μm. (ii) the mineral functional water is pH 12 or higher; (iii) has a control effect on at least one of single-celled organisms and viruses; and (iv) contains organic components derived from plants.

<X2> The ceramic material according to <X1>, wherein the ceramic material is a cement hardened body containing a mineral component or a ceramic porous body supporting a mineral component in a pore.

<X3> A method for producing a water for solute functionalizing, characterized in that the ceramic material as described in <X1> or <X2> is brought into contact with an extraction solvent mainly composed of water, and the mineral material contained in the ceramic material is made The components are dissolved in the aforementioned extraction solvent.

<X4> A method for controlling, wherein the ceramic material as described in <X1> or <X2> is brought into contact with an extraction solvent mainly composed of water, and the mineral component contained in the ceramic material is dissolved in the foregoing The solvent is obtained by extracting the solvent, and the water of the lysing machine is applied to the single-celled organism and/or virus of the control object.

According to the present invention, a ceramic material in which a beneficial mineral component can be immobilized (held) can be provided.

1‧‧‧Mineral functional water manufacturing equipment

2‧‧‧Mineral water (A) manufacturing equipment

3‧‧‧Mineral water (B) manufacturing equipment

10‧‧‧Methods for the production of raw materials and mineral aqueous solutions

11, W‧‧‧ water

12‧‧‧ Mineral Substance (A)

13‧‧‧Reaction container

13a‧‧‧ wall

14‧‧‧Insulator

15‧‧‧Flexible wire

16‧‧‧Ultrasonic generation means

17‧‧‧DC power supply unit

18a, 18b, 18c‧‧ ‧ cycle path

19‧‧‧Drainage

20, 23‧‧‧ opening adjustment valve

21, 25‧‧‧Drain valve

22‧‧‧ housing trough

24‧‧‧Drainage pipe

26‧‧‧Water temperature meter

29, 29a~29g, 29s, 29t‧‧‧ conductive cable

30‧‧‧ Terminal

31‧‧‧ storage container

31f‧‧‧ hook

40‧‧‧Processing container

41‧‧‧ Raw material mineral aqueous solution (A)

42‧‧‧Agitating blades

43‧‧‧ far infrared ray generation means

44‧‧‧ Mineral water (A)

45‧‧‧ Mineral water (B)

46‧‧‧ mixing tank

47‧‧‧Mineral functional water

51‧‧‧1st water container

52‧‧‧2nd water container

53‧‧‧3rd water container

54‧‧‧4th water container

55‧‧‧5th water container

56‧‧‧6th water container

51a~56a‧‧‧ Body Department

51b~56b‧‧‧Switch button

51c~56c‧‧‧Axis

51d~56d‧‧‧ cover

51f~56f‧‧‧Flange

51m~56m‧‧‧ Mineral Substance (B)

51p~56p‧‧‧迂回回路

51v~56v‧‧‧Water flow switching valve

57, 57x, 57y‧‧‧ water supply path

57a‧‧‧ Inlet

57b‧‧‧Water outlet

57c‧‧‧Filter

57d‧‧‧Automatic air valve

58‧‧‧Operation panel

59‧‧‧Signal cable

60‧‧‧ 台台

61‧‧‧ casters

62‧‧‧Level adjuster

63‧‧‧ original sink

DC‧‧‧ DC current

DW‧‧‧ tap water

R‧‧‧Water flow

Fig. 1 is a block diagram showing the schematic structure of a mineral water manufacturing facility.

Fig. 2 is a schematic view showing a part of a mineral-containing water (A) manufacturing apparatus which constitutes the mineral-functional water producing apparatus shown in Fig. 1, that is, a means for producing a mineral-containing aqueous solution.

Figure 3 is a partially omitted cross-sectional view taken along line A-A of Figure 2;

Fig. 4 is a perspective view showing a storage container of the mineral-importing material (A) used in the raw material mineral aqueous solution production means shown in Fig. 2 .

Fig. 5 is a perspective view showing a reaction state in the vicinity of a conductive wire of the raw material mineral aqueous solution manufacturing means shown in Fig. 2.

Fig. 6 is a schematic cross-sectional view showing a far infrared ray irradiation apparatus which is a part of a mineral water (A) manufacturing apparatus which constitutes the mineral water manufacturing apparatus shown in Fig. 1.

Fig. 7 is a block diagram showing a mineral-containing water (B) manufacturing apparatus constituting the mineral-functional water producing apparatus shown in Fig. 1.

Fig. 8 is a front elevational view showing a mineral-containing water (B) manufacturing apparatus constituting the mineral-functional water producing apparatus shown in Fig. 1.

Fig. 9 is a side view showing the apparatus for producing mineral-containing water (B) shown in Fig. 8.

Fig. 10 is a partially omitted perspective view showing the structure of the apparatus for producing mineral-containing water (B) shown in Fig. 8.

Fig. 11 is a side view showing a water-passing container constituting the apparatus for producing mineral-containing water (B) shown in Fig. 8.

Fig. 12 is a spectroscopic emissivity spectrum of a sample in which 20 parts by weight of the mineral functional water of the first embodiment is fixed to the weight of the ceramic carrier 100, and a spectroradiance spectrum (theoretical value) of the black body (temperature: 25 ° C, wavelength range) : 4~24μm, carrier: ceramic powder).

Fig. 13 is a graph showing the ratio of the black body to the black body in which the weight of the mineral water of the first embodiment is 20 parts by weight of the weight of the ceramic carrier 100. Rate (measurement temperature: 25 ° C).

In the following, the present invention is described in detail with reference to the embodiments, and the present invention is not limited to the embodiments described below, and can be arbitrarily changed without departing from the scope of the invention.

<1. Ceramic material>

The present invention relates to a ceramic material (hereinafter referred to as [ceramic material of the present invention]) which is immobilized into a mineral component which is soluble and can be derived from mineral functional water. The ceramic material of the present invention is obtained by elution of a mineral component derived from mineral functional water, and the mineral component can be eluted by contact with an extraction solvent. The mineral component derived from the mineral functional water (hereinafter also referred to as "mineral component") will be described later.

In the present specification, [mineral functional water] means water containing a mineral component and capable of producing at least one or more effective effects.

Further, in the present specification, [mineral-containing water] means raw material water in a previous stage when mineral water is produced, and mineral-containing water also contains a mineral component. The details of the method for producing the mineral functional water of the present invention will be described later. Furthermore, mineral-containing water itself may have effective efficacy or may not have effective efficacy.

In addition, in the present specification, [mineral component] does not mean the definition of minerals in a narrow sense, that is, [inorganic components (including trace elements) other than four elements (carbon, hydrogen, nitrogen, oxygen)], but With inorganic ingredients The above-mentioned four elements (carbon, hydrogen, nitrogen, oxygen) may be excluded from the narrow definition. Therefore, for example, [a mineral component derived from a plant] is also a concept including an inorganic component derived from a plant such as calcium and an organic component derived from a plant.

In addition, examples of the inorganic component (constituting the mineral component) include sodium, potassium, calcium, magnesium, and phosphorus. Examples of the trace element include iron, zinc, copper, manganese, iodine, selenium, and chromium. And molybdenum, etc., but are not limited to this.

The ceramic material of the present invention can be roughly classified into the following two aspects.

The first aspect of the ceramic material of the present invention is a cement hardened body containing a mineral component derived from mineral functional water.

Further, the second aspect of the ceramic material of the present invention is a ceramic porous body in which a mineral component derived from mineral functional water is supported in pores.

The first aspect and the second aspect of the ceramic material of the present invention are ceramic materials in which the mineral component is immobilized and dissolved. Here, [the mineral component is immobilized by elution] means that when the target ceramic material is brought into contact with an extraction solvent (generally a solvent mainly composed of water), the mineral component is gradually dissolved and eventually becomes not formed. Remains in the state of ceramic materials (except for unavoidable residual components).

The mineral component contained in the ceramic material of the present invention is derived from the mineral-containing water (A) formed by the following process (1) in a ratio of 1:5 to 1:20 (weight ratio). And the mineral component of the mineral functional water containing the mineral water (B) formed by the following process (2) is preferred.

In addition, the mineral component derived from [mineral functional water] refers to a mineral component remaining after the solvent component is removed from the target mineral water. However, as described above, the mineral component derived from a plant contains not only an inorganic component but also an organic component derived from a plant.

Process (1): a conductive material covered with an insulator, and a plant material containing a plant of the family Asteraceae and a plant of the family Rosaceae, and one or more selected from the group consisting of maple, birch, pine, and cedar The mineral-importing material (A) of the woody plant material composed of the woody plant is immersed in water to conduct a direct current to the conductive wire, and the water around the conductive wire generates a water flow in the same direction as the direct current. Ultrasonic vibration is applied to the water to form a raw material mineral aqueous solution (A), and then the raw mineral aqueous solution (A) is irradiated with far infrared rays (wavelength: 6 to 14 μm) to form a mineral-containing water (A). The amount of the mineral-imparting material (A) added to the water is 10 to 15% by weight, and the current value and the voltage value of the direct current which is conducted to the conductive wire are in the range of 0.05 to 0.1 A and 8000 to 8600 V, respectively; : a process for forming mineral-containing water (B) containing mineral water (B) by passing water through six water-passing containers, wherein the six water-passing containers are filled with inorganic mineral-affecting materials of different types ( B) and the first water connected in series 6 is to pass the water container: The mineral-imparting material (B1) in the first water-passing container is a mixture containing 70% by weight of limestone, 15% by weight of coral fossil, and 15% by weight of shells, and a mineral-giving material in the second water-passing container ( B2) is a mixture containing 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shell, and 5% by weight of activated carbon, respectively; and the mineral-imparting material (B3) in the third water-passing container is contained separately a mixture of 80% by weight of limestone, 15% by weight of coral fossils, and 5% by weight of shells; and the mineral-donating material (B4) in the fourth water-passing container contains 90% by weight of limestone and 5% by weight of coral fossils, respectively. a mixture of 5% by weight of the shell; the mineral-imparting material (B5) in the fifth water-passing container is a mixture containing 80% by weight of limestone, 10% by weight of coral fossil, and 10% by weight of shells, respectively; The mineral imparting material (B6) in the water container is a mixture containing 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shells, respectively.

The details of the method for producing the mineral functional water will be described later together with the method for producing the ceramic material of the present invention.

In the following, the mineral water which is used for the production of the ceramic material of the present invention is exemplified by the mineral functional water developed by the present inventors (there is a case called [mineral functional water of the present invention]). The mineral functional water of the present invention has excellent properties such as for single-celled organisms, viruses, and the like. Benefits of control (WO2016/043213), body activation (WO2016/043214), combustion promotion of hydrocarbons (PCT/JP2016/058141), antioxidant effects (PCT/JP2016/058362), etc.

Further, as a common feature of the mineral functional water of the present invention, a mineral component derived from a plant (particularly, an organic component derived from a plant) may be mentioned.

One of the ideal mineral functional waters is a mineral functional water having excellent control effects on cell organisms, viruses, and the like as described in Patent Document 3 (WO2016/043213) (hereinafter referred to as [mineral functional water (1)) ]Case). The content of the method for producing the mineral functional water will be described later.

Further, the mineral functional water (1) meets all of the following requirements (i) to (iv): (i) a sample in which the weight of the mineral water is 15 parts or more and the weight of the ceramic carrier 100 is fixed. The average emission ratio (measuring temperature: 25 ° C) of the black body between the wavelengths of 5 to 7 μm and the wavelength of 14 to 24 μm is 90% or more; (ii) the functional water of the mineral is pH 12 or higher; (iii) having a single cell organism and The prevention and control of at least one of the viruses; (iv) the inclusion of mineral components derived from plants (especially organic components derived from plants).

To make minerals containing mineral water (1) In the case where the ceramic material of the present invention is dissolved in contact with a water-based extraction solvent and dissolved by a water-based extraction solvent (hereinafter referred to as [solubilization function water (1)]), as a useful effect thereof First, it has a control effect of single cell organisms, viruses, and the like which are causes of infectious diseases of humans and/or animals. Furthermore, [having a preventive effect] includes not only the single-celled organism, the virus, and the like as a target, but also a single-celled organism, a virus, and the like, which can suppress hyperplasia. Therefore, by using the lysing machine water for the single-celled organism and/or virus to be controlled, it is possible to control the single-celled organism and/or virus to be controlled.

Furthermore, the dissolution of the functional water (1), when compared with the mineral functional water (1), is relatively low in the prevention and control of single-celled organisms and/or viruses, so that it is directly It is preferred to apply and apply it by application, spraying, or the like.

In the present specification, [single cell organism] is a concept including bacteria, fungi, protozoa, and the like. The single-celled organism to be controlled by the elution functional water (1) is a bacteria that can be inactivated (extinct) by the action of the components contained in the water (1) of the elution function. The single-cell pathogenic bacteria such as fungi and protozoa are not particularly limited. Further, the virus to be controlled is not particularly limited as long as it can be inactivated (extinct) by the action of the component contained in the water (1) of the elution function.

One of the ideal mineral functional waters is mineral functional water (hereinafter referred to as [mineral functional water (2)] having a body activation action such as that promotes blood circulation as described in Patent Document 4 (WO2016/043214). Case). About the manufacturing method of the mineral functional water The content is as described later. The dissolving functional water (solvent water (2)) obtained by contacting the ceramic material of the present invention containing the mineral component derived from the functional water of the mineral with the extraction solvent, and the mineral functional water (2) The same mineral ingredients help to promote body activation such as blood circulation.

One of the ideal mineral functional waters is a mineral functional water having a combustion-promoting action of a hydrocarbon type as described in Patent Document 5 (WO2016/043214) (hereinafter referred to as [mineral functional water (3)]. Happening). The content of the method for producing the mineral functional water will be described later.

The dissolving functional water (solvent water (3)) obtained by contacting the ceramic material of the present invention containing the mineral component derived from the functional water of the mineral with the extracting solvent, and the mineral functional water (3) The same mineral composition.

One of the ideal mineral functional waters is a mineral functional water (hereinafter referred to as [mineral functional water (4)) having an antioxidant action as described in Patent Document 6 (WO2016/058362). The content of the method for producing the mineral functional water will be described later.

The dissolving functional water (solvent water (4)) obtained by contacting the ceramic material of the present invention containing the mineral component derived from the functional water of the mineral water with the extracting solvent, and the mineral functional water (4) The same mineral composition.

The above is exemplified as an ideal mineral functional water which is a raw material which is immobilized on the mineral component of the ceramic material of the present invention, but does not Limited to this.

Further, the mineral component derived from the mineral functional water fixed to the ceramic material of the present invention may differ depending on the type of the ceramic material to be used as the carrier, the type of the extraction solvent, the extraction conditions, and the like. There may be cases where the entire mineral component is not extracted due to contact with the extraction solvent. Therefore, the composition of the mineral functional water used for the immobilization of the mineral component and the composition of the dissolution functional water obtained by the dissolution are generally not completely identical.

Hereinafter, the ceramic material of the first aspect and the second aspect will be described in detail together with the production method. Further, the mineral functional water fixed to the ceramic material will be described later together with the production method thereof.

(1) The first aspect (cement hardened body)

The first aspect of the ceramic material of the present invention is a cement hardened body containing a mineral component (hereinafter referred to as "the cement hardened body of the present invention"). The cement hardened body according to the first aspect of the ceramic material of the present invention has an advantage that the mineral component can be immobilized (held) in a larger amount than the ceramic porous body of the second aspect.

The cement hardening system of the present invention can be produced by solidifying a cement mixture using mineral functional water containing a mineral component.

That is, the cement hardened body of the present invention is characterized in that: the mineral functional water containing the mineral component is mixed with the cement composition to obtain a mixing process of the cement mixture; and the obtained cement is mixed. Conservation The curing process of curing.

In addition, the term "cement mixture" as used herein refers to a material in which a cement powder is mixed, and [cement mixture] means a fluidity in which a cement mixture is hydrated and uncured. Further, the [cement hardened body] of the present invention means that the cement mixture is hardened, and generally includes the concept of mortar and concrete having components other than cement powder.

The [cement mixture] of the mixing process can be a conventional cement powder or a mixed material (aggregate or the like) used for the production of a cemented body.

The type of cement body of cement powder is not particularly limited, and general Portland cement, early strength Portland cement, super early strong Portland cement, moderate hot Portland cement, low heat Portland cement, and resistance can be used. Portland cement and alumina cement such as sulfate Portland cement and white Portland cement (white cement).

Further, blast furnace cement in which fine powder of blast furnace slag is mixed with Portland cement, fly ash cement in which fly ash (incineration ash of lime produced in a thermal power plant or the like) and Portland cement are mixed may be used.

The mixture of the aggregates and the like which are mixed with the cement powder may be a mixture of the conventionally produced cement hardened body, and examples thereof include calcium carbonate powder containing cerium oxide powder or limestone such as vermiculite. Wait.

The mixing ratio of the mineral functional water and the cement powder can be considered as the amount of the mineral component contained in the mineral functional water, the pH, etc., and the type and amount of the aggregate of the cement powder, etc., which are necessary for the cement mixture. Viscosity, etc. are determined. As an ideal example, the moisture content is 15 to 30% by weight, and the cement powder is 40 to 60% by weight (the residual portion is mixed). Other ingredients such as wood).

The method of mixing the mineral functional water and the cement powder is not particularly limited, and it may be sufficiently mixed and synthesized using a conventional mixing device. In addition, water can be added in case of insufficient water. The water to be added may be water other than the mineral water. Further, conventionally used components for the production of a cemented body can be added as needed. The additive is not particularly limited as long as it does not impair the object of the present invention, and examples thereof include a pH adjuster, a water reducing agent, and a curing accelerator.

As a curing process, the cement mixture obtained in the aforementioned mixing process is cured and solidified to form a cement hardened body. The curing conditions are various conditions such as the cement powder to be used for the purpose of the cement hardened body, the type of the mixed material, the hardness of the cement hardened body to be used, the amount of the mineral component to be retained, and the like, and it is suitable to select the room temperature curing, Conventional curing methods such as heat curing, steam curing, and the like.

The shape of the cement hardened body of the present invention is not particularly limited, and it can be used in an ideal shape for use in the application, and examples thereof include a powder, a pellet, and a plate. The size is also arbitrary and can be appropriately determined depending on the purpose of use. The molded body or the unformed mass may be pulverized and used as a powder, a granule or the like.

When the cement hardened body of the present invention of the first aspect of the ceramic material of the present invention is brought into contact with an extraction solvent mainly composed of water, the mineral component contained in the cement hardened body of the present invention can be dissolved in the extraction solvent. in. Here, [water-based extraction solvent] means a liquid containing 50% by weight or more (including 100% by weight) of water, and is formed as a water other than water. The fraction contains an organic solvent having compatibility with water such as ethanol. Further, in the extraction solvent, an optional component such as a pH adjuster may be contained in a range that does not impair the effects of the present invention.

The extract (solution water) after contact with the cement hardened body of the present invention contains a part or all of the mineral component immobilized (maintained) in the cement hardened body.

(2) The second aspect (ceramic porous body)

The second aspect of the ceramic material of the present invention is a ceramic porous body (hereinafter referred to as "ceramic porous body of the present invention") in which a mineral component is supported in a pore.

In the ceramic porous body of the second aspect of the ceramic material of the present invention, the absolute amount of the mineral component that can be immobilized (maintained) is small, but the cement hardened body of the first aspect is used to dissolve the mineral component. After that, the ceramic porous body of the second aspect can be reused after the mineral component is eluted, and then the mineral functional water is again immersed in the water to be regenerated, thereby having the advantage of being reusable.

The mineral component of the ceramic porous body of the present invention contains a ceramic porous body as a carrier, and is fixed by elution.

The type of the oxide which is a raw material of the ceramic porous body is not particularly limited as long as it is an oxide having moderate sinterability. Examples of the oxide to be used as such a raw material include cerium oxide, titanium oxide, aluminum oxide, and a composite oxide thereof. Further, it is also desirable to use diatomaceous earth (main component: cerium oxide) and kaolin (main component: cerium oxide-oxidation) Alumina, hydrotalcite and other clays. Rocks containing such clays can also be pulverized and used as a raw material for ceramic carriers. For example, the rock powder produced by the Amakusa Oyao Island used in the examples described later is an ideal example of a ceramic carrier raw material.

The ceramic porous body of the present invention may contain a conventional component which can be used for a ceramic porous body composed of an oxide. The optional component is not particularly limited as long as it does not impair the object of the present invention.

The shape of the ceramic porous body of the present invention is not particularly limited, and can be used in an ideal shape for use in the application, and examples thereof include a powder, a pellet, and a plate. The size is also arbitrary and can be appropriately determined depending on the purpose of use. The molded body or the unformed mass may be pulverized and used as a powder, a granule or the like.

The ceramic porous body of the present invention is a method in which a mineral functional water is immobilized on a carrier composed of a ceramic porous body by a physical action or a chemical action.

That is, the method for producing a ceramic porous body of the present invention comprises a process of mixing a liquid for mixing and a ceramic powder for a carrier into a clay-like mixture (I); and heat-treating the clay-like mixture to obtain a ceramic porous body The process (II); and the process (III) of allowing the mineral water to permeate the pores of the ceramic porous body and then drying the mineral component to the ceramic porous body.

According to the production method of the present invention, the ceramic porous body of the present invention described above can be produced. Especially the ceramics obtained in the process (II) The porous body (before the immobilization of the mineral component) has a large number of pores, and the mineral component derived from the mineral functional water can be immobilized (held) inside the pores, thereby improving the ceramic porous body of the present invention. The content of the mineral component that is the purpose.

Hereinafter, each process of the method for producing a ceramic porous body of the present invention will be described.

The process (I) is a process in which a mixing liquid (mixing dispersion medium) and a carrier ceramic powder are mixed to form a clay-like mixture.

The oxide of the raw material of the ceramic powder for the carrier is not particularly limited as long as it is an oxide which has been described as the ceramic carrier and has an appropriate sinterability.

Examples of the oxide to be used as such a raw material include cerium oxide, titanium oxide, aluminum oxide, and a composite oxide thereof. Further, clays such as diatomaceous earth (main component: cerium oxide), kaolin (main component: cerium oxide-alumina), and hydrotalcite may be preferably used. Rocks containing such clays can also be pulverized and used as a raw material for ceramic carriers. For example, the rock powder produced by the Amakusa Oyao Island used in the examples described later is an ideal example of a ceramic carrier raw material.

The ceramic powder for the carrier is preferably a ceramic powder. The particle diameter of the powder is selected in a favorable range such as moldability and sinterability, and is generally 100 μm or less.

The liquid to be mixed is a liquid to be added when the ceramic powder for a carrier is mixed, and any liquid can be used. However, water or a liquid mainly composed of water is generally used. [Water-based liquid] means 50 heavy The liquid of % or more (including 100% by weight) of water contains, as a component other than water, an organic solvent having compatibility with water such as ethanol. Further, the mixing liquid may contain an optional component such as a pH adjuster in a range that does not impair the effects of the present invention.

The mixing method of the ceramic powder for the carrier and the liquid for mixing may be carried out by any method, and may be carried out by hand, or may be carried out by using a conventional mixing device.

In addition, the mixing ratio of the ceramic powder for carrier and the liquid for mixing is set in a range in which the viscosity can be maintained, and the weight of the ceramic powder for the carrier is 100 parts by weight, and the liquid for mixing is generally 5 parts by weight or more and 500 parts by weight. Hereinafter, it is preferably 10 parts by weight or more and 300 parts by weight or less.

Further, in the clay-like mixture, in addition to the carrier ceramic powder and the mixing liquid, it may contain a conventional tackifier, a pore generating agent, and a pH adjustment for use in ceramics, without damaging the effects of the present invention. Any component such as a agent.

The process (II) is a process in which the obtained clay-like mixture is formed into a predetermined shape as needed, and then heat-treated to obtain a ceramic porous body having a plurality of pores.

Since the formation of the clay-like mixture is viscous, it is easy to carry out, and the appropriate shape can be controlled depending on the intended use. When it is formed into a particulate form, it can adjust to about 50-500 micrometers, for example. Further, the clay-like mass may be dried, and then pulverized to adjust the particle diameter, followed by heat treatment. In this way, since the ceramic powder for the carrier can be formed into a clay-like mixture of an arbitrary shape, and then heat-molded, it can be easily A ceramic porous body having a desired shape is obtained.

The heat treatment can be carried out by a conventional firing device. The heat treatment temperature is determined so that the obtained ceramic porous body has sufficient pores and has a degree of mechanical strength which can be used in a post-process, and is determined by the type of the ceramic powder for the carrier, and is usually 500 ° C or more. Below °C, it is preferably 700 ° C or more and 900 ° C or less. Further, the environment at the time of heat treatment is not particularly limited, but is generally an atmospheric environment. The heat treatment time can be appropriately determined depending on the heat treatment temperature, the porosity of the object, the degree of sintering, and the like.

The process (III) is a process in which the mineral functional water containing the mineral component is permeated into the pores of the ceramic porous body and then dried to fix the mineral component to the ceramic porous body. By this process, the mineral component is immobilized on the ceramic porous body in a soluble state.

Since the ceramic porous body has a large number of pores, the fine pores contain the mineral functional water and then dried, and the mineral components contained in the mineral functional water can be contained in a larger amount.

Further, the mineral functional water containing the mineral component will be described later together with the production method thereof.

The method of allowing the mineral water to permeate the pores of the ceramic porous body is arbitrary, and for example, a method of immersing the ceramic porous body in the mineral functional water is not limited thereto. Further, by repeating the operation of allowing the mineral functional water to permeate the ceramic porous body and allowing the mineral water to permeate again after the solvent (water) evaporates, more mineral components can be immobilized.

The amount of mineral functional water impregnated in the porous ceramic body is determined by considering the type and concentration of the mineral component contained in the mineral functional water, depending on the pore physical properties and porosity of the ceramic porous body, but generally The weight of the ceramic porous body is 15% by weight or more.

When the ceramic porous body of the present invention of the second aspect of the ceramic material of the present invention is brought into contact with an extraction solvent mainly composed of water, the mineral component contained in the ceramic porous body of the present invention can be eluted into the foregoing. Extract solvent. Here, [the extraction solvent mainly composed of water] is as described in the above (1) cement hardened body, and thus the description thereof is omitted here.

The extract (solution water) after contact with the ceramic porous body of the present invention contains part or all of the mineral component immobilized (maintained) in the ceramic porous body.

The ceramic porous body of the present invention after use (after extracting the mineral component) can be regenerated by performing the process (III) again.

<3. Method for producing mineral functional water>

The mineral functional water containing the mineral component used in the production of the ceramic material of the present invention (hereinafter referred to as "the mineral functional water of the present invention") is not particularly limited, but it is preferably used. The apparatus disclosed in the above-mentioned Patent Document 2 (JP-A-2011-56366) is manufactured by a method according to the method disclosed in the document.

In addition, the production method is not particularly limited as long as the mineral functional water containing a beneficial mineral component can be obtained in addition to the production method using the production apparatus.

In the following, a preferred embodiment of the method for producing the mineral functional water of the present invention using the apparatus disclosed in Patent Document 2 (JP-A-2011-56366) will be described with reference to the drawings. In the following description, for example, various mineral functional waters can be produced by appropriately changing the manufacturing conditions including raw materials.

As shown in Fig. 1, the mineral water manufacturing facility 1 is provided with: a mineral water (A) manufacturing apparatus 2; a mineral water (B) manufacturing apparatus 3; and a mixing tank 46 as a mixing means, the mixing tank The mineral-containing water (B) 45 produced in the mineral-containing water (B) manufacturing apparatus 3 is mixed with the mineral-containing water (A) 44 produced in the mineral-containing water (A) manufacturing apparatus 2 to form Mineral function water 47.

In the mineral water (A) manufacturing apparatus 2, the water 11 supplied from the water pipe and the mineral material (A) 12 (see FIG. 4) to be described later are used as raw materials to form a raw material of the raw material mineral aqueous solution (A) 41. The mineral aqueous solution production means 10; and the far-infrared rays generating means 43 which irradiates the far-infrared rays with the raw material mineral aqueous solution (A) 41 obtained by the raw material mineral aqueous solution manufacturing means 10, and changes to the mineral-containing water (A) 44.

The mineral water (B) manufacturing apparatus 3 has a function of forming a water containing a mineral component from a mineral-containing material by passing water W supplied from the outside through the water-passing containers 51 to 56. Mineral water (B) 45 function.

Hereinafter, the mineral-containing water (A) manufacturing apparatus 2 and the mineral-containing water (B) manufacturing apparatus 3 will be described in detail.

(3-1: Mineral-containing water (A) manufacturing device)

Next, a mineral-containing water (A) manufacturing apparatus 2 constituting the mineral-functional water producing apparatus 1 shown in Fig. 1 will be described with reference to Figs. 2 to 6 . As shown in Fig. 1, the mineral water (A) manufacturing apparatus 2 forms a raw material mineral aqueous solution by using the water 11 supplied from the water pipe and the mineral material (A) 12 (see Fig. 4) to be described later as a raw material. (A) 41 raw material mineral aqueous solution manufacturing means 10 (refer to FIG. 2); and the mineral-containing water (A) solution 41 obtained by the raw material mineral aqueous solution manufacturing means 10 is irradiated with far infrared rays, and is changed into mineral-containing water. The far infrared ray generating means 43 of (A) 44 (refer FIG. 6).

As shown in FIG. 2 and FIG. 3, the raw material mineral aqueous solution production means 10 includes a reaction container 13 that can accommodate the water 11 and the mineral-importing material (A) 12, and is immersed in the reaction container in a state of being covered with the insulator 14. a conductive line 15 in the water 11 in the 13; an ultrasonic generating means 16 for imparting ultrasonic vibration to the water 11 in the reaction vessel 13, a direct current power source means 17 for conducting a direct current DC to the conductive line 15, and a conductive line The water 11 around the 15 generates circulation paths 18a and 18b and a circulation pump P of the means of the water flow R in the same direction as the direct current DC. The DC power supply unit 17, the ultrasonic generating means 16 and the circulating pump P are all operated by power supply from a general commercial power source.

The reaction container 13 has an inverted conical tubular shape with an upper opening, and a drain port 19 is provided at a bottom portion corresponding to the apex thereof, and a circulation path 18a communicating with the suction port P1 of the circulation pump P is connected to the drain port 19 at the drain port. Directly below 19 is provided for adjusting the displacement toward the circulation path 18a. The opening degree regulating valve 20 and a drain valve 21 for discharging water or the like in the reaction vessel 13 are provided.

A proximal end portion of the circulation path 18b is connected to the discharge port P2 of the circulation pump P, and a distal end portion of the circulation path 18b is connected to the accommodation groove 22. A proximal end portion for conveying the water 11 in the storage tub 22 to the circulation path 18c in the reaction container 13 is connected in the vicinity of the bottom of the outer periphery of the housing groove 22, and the distal end portion of the circulation path 18c is disposed in the opening facing the reaction container 13. The location. An opening degree regulating valve 23 for adjusting the amount of water sent from the storage tub 22 to the reaction container 13 is provided in the circulation path 18c.

At the bottom of the storage tub 22, a drain pipe 24 having a drain valve 25 and a water temperature gauge 26 is connected in a hanging manner. When the drain valve 25 is opened as needed, the water in the storage tub 22 can be discharged from the lower end portion of the drain pipe 24. At this time, the temperature of the water 11 passing through the drain pipe 24 can be measured by the water temperature gauge 26.

As shown in FIG. 5, a plurality of conductive cables 29 (29a to 29g) composed of a conductive wire 15 and an insulator 14 covering the conductive wire are arranged in a ring shape so as to have different depths in the reaction container 13 At these positions, the annular conductive cables 29a to 29g are disposed slightly coaxially with the reaction container 13. The inner diameters of the respective conductive cables 29a to 29g are gradually reduced in diameter in accordance with the inner diameter of the reaction container 13 having an inverted cone shape, and are formed to have inner diameters corresponding to the respective arrangement portions. Since the respective conductive cables 29a to 29g are detachably connected to the insulating terminal device 30 provided in the wall body 13a of the reaction container 13, the annular portion can be removed or attached from the terminal device 30 as needed.

A bottomed cylindrical storage container 31 formed of an insulating mesh body is disposed in a portion corresponding to the axial center of the reaction container 13, and the storage container 31 is filled with the mineral providing material (A) 12. The storage container 31 is detachably locked to the upper edge portion of the wall body 13a of the reaction container 13 by a hook 31f provided on the upper portion thereof.

As shown in Fig. 2, the outer circumferences of the circulation paths 18a and 18b are spirally wound around the conductive cables 29s and 29t, respectively, and DC current DC is supplied from the DC power supply unit 17 to the conductive cables 29s and 29t. The direction of the direct current DC flowing through the conductive cables 29s and 29t is set to substantially coincide with the direction of the water flow flowing through the circulation paths 18a and 18b.

In the raw material mineral aqueous solution production means 10, a predetermined amount of water 11 is placed in the reaction container 13 and in the storage tank 22, and the storage container 31 filled with the mineral-importing material (A) 12 is attached to the reaction container 13. After the center, the circulation pump P is actuated, and the opening degree adjustment valve 20 at the bottom of the reaction vessel 13 and the opening degree adjustment valve 23 of the circulation path 18c are adjusted, and the water 11 is passed from the reaction vessel 13 through the drain port 19, the circulation path 18a, The circulation pump P, the circulation path 18b, the storage tank 22, and the circulation path 18c are circulated again so as to return to the upper portion of the reaction container 13. When the DC power source device 17 and the ultrasonic wave generating means 16 are actuated, the mineral component starts from the elution reaction of the mineral material (A) 12 in the storage container 31 toward the water 11.

The working conditions in the case of producing the raw material mineral aqueous solution (A) using the raw material mineral aqueous solution manufacturing means 10 are not particularly limited, but in the present embodiment, the raw material mineral aqueous solution (A) is carried out under the following working conditions. Manufacturing.

(1) A direct current DC of a voltage of 8000 to 8600 V and a current of 0.05 to 0.1 A is conducted to the conductive cables 29, 29s, and 29t. Further, the insulator 14 constituting the conductive cable 29 and the like is formed of a polytetrafluoroethylene resin.

(2) The mineral-importing material (A) 12 filled in the reaction container 13 is filled with water 11 at a mass ratio of 10 to 15%. The specific description of the mineral-imparting material (A) 12 will be described later.

(3) The water 11 may be a catalyst containing a DC current DC. For example, sodium carbonate which dissolves about 10 g of electrolyte for 100 liters of water can be used, and if it is groundwater, it can be used as it is.

(4) The ultrasonic wave generating means 16 is a means for supersonic waves having a frequency of 30 to 100 kHz, and the ultrasonic wave generating portion (not shown) is placed in direct contact with the water 11 in the reaction container 13 to oscillate the ultrasonic wave. Means 16.

When the raw material mineral aqueous solution manufacturing apparatus 10 is operated under such conditions, the water flow R sucked by the drain port 19 while rotating in the left spiral direction is generated in the reaction container 13, and the water 11 discharged from the drain port 19 passes through the foregoing. The state in which the circulation paths 18a, 18b, and the like are returned to the reaction vessel 13 again continues.

Therefore, the action of the water flow R, the action of the direct current flowing through the conductive cable 29, and the ultrasonic vibration imparted by the ultrasonic wave generating means 16 to the water 11 can make the mineral component from the mineral material (A) 12 By rapidly dissolving into the water 11, the raw material mineral aqueous solution (A) in which the desired mineral component is moderately dissolved can be efficiently produced.

In the raw material mineral aqueous solution production means 10, a plurality of conductive cables 29a to 29g which are formed in an annular shape are disposed on substantially the same axis in the reaction container 13, and a water flow R which is rotated in the left-hand spiral direction is generated in the reaction container 13. Therefore, a relatively dense electric field can be formed in the reaction container 13 having a constant volume, and the raw material mineral aqueous solution (A) can be efficiently produced in the reaction container 13 having a small volume.

Further, since the reaction container 13 has an inverted conical tubular shape, it is easier and stable to generate a water flow R flowing along a plurality of annular conductive cables 29a to 29g, thereby facilitating elution of mineral components. . Further, since the flow rate of the water R flowing in the inverted conical tubular reaction vessel 13 increases toward the drain port 19 at the bottom of the reaction vessel 13, the frequency of contact with the mineral-importing material (A) 12 is also Increasing, the mass of the mineral that captures and ionizes the free electrons e present in the water 11 can be increased.

Further, since the storage tank 22 that discharges the water 11 while being stored is provided between the circulation paths 18b and 18c, the mineral elution reaction can be performed while circulating the water 11 exceeding the volume of the reaction container 13. . Therefore, the raw material mineral aqueous solution (A) can be mass-produced efficiently.

When the circulation pump P is continuously operated to continue the reaction, the raw material mineral aqueous solution (A) in which the mineral component is eluted can be finally produced. The water can be controlled by the size of the drain port 19 at the bottom of the reaction vessel 13, the amount of circulating water, the shape of the reaction vessel 13 (especially the angle γ formed by the axis C and the wall 13a as shown in Fig. 2), and the like. 11 The appearance of the free electrons e in the middle, by the action of the free electrons e on the mineral-imparting material (A) 12, can influence the water solubility of the mineral components.

After the raw material mineral aqueous solution (A) is formed, the raw mineral aqueous solution (A) 41 is transferred to the processing container 40 as shown in FIG. In this case, the residue of the mineral-imparting material (A) 12 leaking from the storage container 31 in the reaction container 13 can be discharged from the drain valve 21 located at the bottom of the reaction container 13. The raw material mineral aqueous solution (A) 41 accommodated in the processing container 40 is irradiated with far infrared rays by the far infrared ray generating means 43 disposed in the processing container 40 while being slowly stirred by the stirring blade 42.

Further, the far-infrared ray generating means 43 may be a far-infrared ray having a wavelength of about 6 to 14 μm, and may be a heating method because it is not affected by materials, generating means, or the like. However, it is desirable to have a radiation ratio of 85% or more for black body radiation in a wavelength region of 6 to 14 μm at 25 °C.

In the raw material mineral aqueous solution manufacturing apparatus 10 shown in FIG. 2, the mineral-containing material (A) can be contained by the stirring action of the water flow R, the action of the direct current DC flowing through the conductive wire 15, and the ultrasonic vibration. The mineral component in 12 is rapidly dissolved in the water 11, and the desired mineral component is appropriately dissolved, whereby the mineral aqueous solution 41 can be efficiently produced.

Further, in the far-infrared ray generating means 43 shown in FIG. 6, by irradiating the mineral aqueous solution 41 with far-infrared rays, the dissolved mineral component is fused with water molecules to form a mineral-containing water having improved electronegativity (A). 44.

In the mineral-containing water (A) manufacturing apparatus 2, the mineral-containing water (A) 44 formed by the above-described process is transported to the mixing tank 46 via the water supply path 57y as shown in Fig. 1, and is mixed in the mixing tank 46. The mineral-containing water (B) 45 sent from the mineral water (B) manufacturing apparatus 3 is mixed.

Hereinafter, the mineral-imparting material (A) will be described.

The mineral-improving material (A) is a plant material containing a plant of the genus Compositae and a plant of the family Rosaceae; and one or more woody plants selected from maple, birch, pine, and saplings. The woody plant material that is composed. The site to be used is preferably a part which is easy to elute mineral components such as leaves, stems, flowers, and bark, and can be used as it is, or a dried product can be used.

Furthermore, in addition to the plants of the genus Compositae and Rosaceae, other plants may be included, but only plants of the genus Compositae and Rosaceae are preferred.

An example of the mineral-imparting material (A) is a mineral-imparting material (A'-1). By using the mineral-imparting material (A'-1), it is possible to obtain mineral functional water (corresponding to the aforementioned mineral functional water (1)) having a control action against at least one of a single-celled organism and a virus.

For the mineral-improving material (A'-1), the scorpion (leaf, stem, and flower), wormwood (leaf and stem), and mountain daisy (leaf and stem) are respectively 8 a dry pulverized material of a compositae plant which is mixed, dried, and pulverized in a ratio of ~12% by weight, 55 to 65% by weight, and 27 to 33% by weight; And use wild rose (leaf, flower), bayberry (leaf and stem), raspberry (leaf, stem, and flower) to be 17 to 23% by weight, 8 to 12% by weight, and 65, respectively. ~75% by weight of the dried pulverized material of the Rosaceae plant which is mixed, dried and then pulverized, and the dried pulverized material of the Compositae plant and the dried pulverized material of the Rosaceae plant are 1:0.8-1:1.2 (weight ratio) The plant material (A1-1) obtained by mixing is used as the raw material of the plant, from maple (leaf and stem), birch (leaf, stem, and bark), cedar (leaf, Woody plant material consisting of dried pulverized material which is mixed at a ratio of 22 to 28% by weight, 22 to 28% by weight, and 45 to 55% by weight, respectively, in the stem portion and the bark portion (A2- 1) The mineral material obtained by mixing the plant material (A1-1) and the woody plant material (A2-1) in a weight ratio of 1:2.7 to 1:3.3 as the raw material of the woody plant material.

In the mineral-improving material (A'-1), in particular, as the raw material of the plant, the cockroach (leaf, stem, and flower), the wormwood (leaf and stem), and the daisy (leaf) And the stem portion) is a dried pulverized material of the Compositae plant which is mixed, dried, and pulverized at a ratio of 10% by weight, 60% by weight, and 30% by weight, respectively, and wild rose (leaf, flower) and arbutus (leaf) And the dried pulverized material of the Rosaceae plant which is mixed, dried, and pulverized at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively, of the raspberry) :1 (weight ratio) of the plant material (A1-1) obtained by mixing; and as the raw material of the woody plant, from maple (leaf and stem), birch (leaf, stem, and bark) Woody plant material (A2) consisting of dried pulverized material which is mixed, dried, and pulverized at a ratio of 25% by weight, 25% by weight, and 50% by weight, respectively, in cedar (leaf, stem, and bark) -1) Preferably, the mineral-imparting material obtained by mixing the plant material (A1-1) and the woody plant material (A2-1) in a weight ratio of 1:3 is preferable.

For example, the RIKEN Techno System Co., Ltd. product [P-100 (product number)] is used as the plant material (A1-1) which is a raw material of the mineral-based material (A'-1). For example, [P-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd. is used as the woody plant material (A2-1). In addition, the mineral functional water CAC-717 [Tera Protect (product name), CAC-717 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. is [P-100 (product number)], [P-200] (Product No.)] Mineral functional water.

Further, as an example of another preferable mineral-imparting material (A), a mineral-imparting material (A'-2) can be mentioned. By using the mineral-imparting material (A'-2), mineral functional water (corresponding to the aforementioned mineral functional water (2)) having body activation can be obtained.

The mineral-improving material (A'-2) is a mineral-improving material, that is, as the raw material of the plant, the cockroach (leaf, stem, and flower), and the wormwood (leaf and stem) , mountain chrysanthemum (leaf and stem) to separate The dried pulverized material of the Compositae plant which is mixed, dried, and pulverized at a ratio of 10% by weight, 60% by weight, and 30% by weight, and wild rose (leaf, flower), arbutus (leaf and stem), wood The dried pulverized material of the Rosaceae plant in which the berry (leaf, stem, and flower part) is mixed at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively, and then pulverized is 1:1 (weight ratio) a plant material (A1-2) obtained by mixing; and as a raw material of the aforementioned woody plant, from maple (deciduous), birch (deciduous, stem, and bark), cedar (deciduous, stem, And a bark plant material (A2-2) which is a dry pulverized material which is mixed, dried, and pulverized at a ratio of 20% by weight, 60% by weight, and 20% by weight, respectively, and a plant material (A1) -2) A mineral imparting material obtained by mixing the weight ratio of the woody plant material (A2-2) to 1:5.

For example, the RIKEN Techno System Co., Ltd. product [P-101 (product) is used as the raw material of the plant material (A1-2) which is a raw material of the mineral-based material (A'-2). In the case of the woody plant material (A2-2), for example, [P-201 (product number)] manufactured by Riken Chemical Technology Co., Ltd. is mentioned. In this way, the mineral functional water A20ACA-717 [Tera Support (trade name), A20ACA-717 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. can be obtained.

Further, as an example of another preferable mineral-imparting material (A), a mineral-imparting material (A'-3) can be mentioned. By using minerals The material (A'-3) is capable of obtaining mineral functional water (corresponding to the aforementioned mineral functional water (3)) having a combustion-promoting action of hydrocarbons.

The mineral-improving material (A'-3) is a mineral-imparting material, that is, as the raw material of the plant, the cockroach (leaf, stem, and flower), and the wormwood (leaf and stem) The dried pulverized material of the compositae and the wild rose (leaf part, flower part) which are mixed, dried, and pulverized at a ratio of 10% by weight, 60% by weight, and 30% by weight, respectively. , Rosaceae (leaf and stem), raspberry (leaf, stem, and flower) are mixed, dried, and pulverized in a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively. The dried pulverized material is obtained by mixing 1:1 (weight ratio) of the plant material (A1-1); and as the woody plant material, by maple (leaf and stem), birch (leaf) , the stem portion, and the bark portion, and the sap tree (leaf portion, stem portion, and bark portion) are mixed, dried, and pulverized at a ratio of 25% by weight, 25% by weight, and 50% by weight, respectively. a woody plant material (A2-1); and as activated carbon, an activated carbon powder (A3-1) which carbonizes a coconut shell at an activation temperature of 1000 ° C, The wood plant material (A1-1) and the woody plant material (A2-1) are mixed at a weight ratio of 1:3, and the activated carbon powder (A3-1) is formed into a weight of 2 to 8 parts. The mineral-donating material obtained by mixing is mixed.

Here, the activated carbon powder (A3-1) is made by using a coconut shell. In the activated carbon powder which is carbonized at an activation temperature of 1000 ° C in an inert gas atmosphere, the pH is 9 to 11, preferably 9.5 to 10.5, more preferably pH 10, when it is added to pure water so as to form 10 wt%. Activated carbon powder.

Further, when the coconut shell is activated at a low temperature, the alkali tends to become strong, but when activated at 1000 ° C, it is formed into a weakly alkaline state.

The addition amount of the activated carbon powder (A3-1) is added to the mineral-imparting material (A-1) to form a pH of 11 to 12 when the mineral-containing water (A) and the mineral-containing water (B) are mixed. When the mixture of the plant material (A1-1) and the woody plant material (A2-1) is 100 parts by weight in a weight ratio of 1:3, it is formed into a range of 2 to 8 parts by weight. .

For example, the RIKEN Techno System Co., Ltd. product [P-100 (product number)] is used as the plant material (A1-1) which is a raw material of the mineral-based material (A'-3). In the case of the woody plant material (A2-1), for example, [P-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd., and the activated carbon powder (A3-1), for example, Riken Chemical Co., Ltd. Technical System Co., Ltd. [AS-100 (Product No.)].

Further, as an example of another preferable mineral-importing material (A), a mineral-imparting material (A'-4) can be mentioned. By using the mineral-imparting material (A'-4), it is possible to obtain mineral functional water (corresponding to the aforementioned mineral functional water (4)) having an antioxidant action.

Mineral-based material (A'-4), which is the following mineral-giving material, In other words, as the raw material of the plant, the cockroach (leaf, stem, and flower), wormwood (leaf and stem), and gerbera (leaf and stem) were 10% by weight and 60% by weight, respectively. a dry pulverized material of a compositae plant which is mixed, dried, and pulverized at a ratio of 30% by weight, and wild rose (leaf, flower), bayberry (leaf and stem), raspberry (leaf, stem, and Flower part) The plant material obtained by mixing the dried ground material of the Rosaceae plant which is mixed, dried and then pulverized at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively, at a ratio of 1:1 (weight ratio) (A1-2); and as the raw material of the woody plant, the maple (deciduous), birch (deciduous, stem, and bark), cedar (deciduous, stem, and bark) are respectively 20 Woody plant material (A2-2) composed of dry pulverized material which is mixed, dried, and pulverized in a ratio of weight%, 60% by weight, and 20% by weight; and volcanic sulfur (A3-2) as a sulfur raw material In the composition, the plant material (A1-2) and the woody plant material (A2-2) are mixed at a weight ratio of 1:5, and the volcanic sulfur is used. (A3-2) obtained by forming mineral mix is 2 to 8 parts by weight of imparting member embodiment.

Here, volcanic sulfur (A3-2) is a sulfur-containing substance present in a volcano. The volcanic sulphur (A3-2) is dissolved or dispersed when the water is circulated, and the sulphur component is dissolved in the mineral-containing water (A). When volcanic sulfur (A3-2) is used as sulfur, it can strongly produce the characteristics of anti-inflammatory and anti-oxidation effects unique to the mineral functional water of the present invention, and thus good. It is preferred to pulverize the volcanic sulfur (A3-2) to form a powder.

The volcanic sulfur (A3-2) is added in an amount of 100 parts by mixing the plant material (A1-2) with the woody plant material (A2-2) in a weight ratio of 1:5. In the case of the part, it is formed in the range of 2 to 8 parts by weight.

As the grass plant material (A1-2), it is preferable to use [P-101 (product number)] manufactured by RIKEN Techno System Co., Ltd. as a woody plant material (A2-2). [P-201 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. was used. Further, as the volcanic sulfur (A3-2), [S-100 (product number)] manufactured by Riken Chemical Technology Co., Ltd. can be preferably used.

(3-2: Mineral water (B) manufacturing equipment)

Next, the structure, function, and the like of the mineral-containing water (B) manufacturing apparatus 3 will be described with reference to Figs. 1 and 7 .

As shown in Fig. 1 and Fig. 7, the mineral water (B) manufacturing apparatus 3 is provided with a first water-passing container 51 to a sixth water-passing container 56 which are filled with mineral-specific material (B) of different types; The water supply path 57 that connects the first water-passing container 51 to the sixth water-passing container 56 in series, and is connected to the water-passing path of the water-feeding path 57 in a state in which the first water-passing container 51 to the sixth water-passing container 56 are arranged in parallel with each other. 51p to 56p; and water flow switching valves 51v to 56v respectively provided in the branch portions of the respective return water passages 51p to 56p and the water supply path 57.

The switching operation of the water flow switching valve 51v~56v can be operated by The six switching buttons 51b to 56b provided on the operation panel 58 connected to the water flow switching valves 51v to 56v by the signal cable 59 are executed. Since the six switching buttons 51b to 56b and the six water flow switching valves 51v to 56v correspond to individual numbers, when one of the switching buttons 51b to 56b is operated, the water flow switching valve 51v of the corresponding number is operated. The 56v is switched to change the direction of the water flow.

Further, the first water-passing container 51 is filled with a mineral-imparting material (B) 51m containing cerium oxide and iron oxide, and the second water-passing container 52 is filled with a cerium oxide-containing activated carbon ore. The material-imparting material (B) is 52 m, and the third water-passing container 53 is filled with a mineral-imparting material (B) 53 m containing cerium oxide and titanium nitride, and is filled in the fourth water-passing container 54 with two The mineral-supporting material (B) of cerium oxide and calcium carbonate is 54 m, and the fifth water-passing container 55 is filled with a mineral-imparting material (B) containing cerium oxide and magnesium carbonate (B) 55 m, and is in the sixth water-passing container 56. The inside was filled with a mineral-imparting material (B) containing cerium oxide and calcium phosphate (56 m).

Here, the mineral-imparting material (B) is 51 m to 56 m, and it is preferable to be produced by mixing raw materials containing limestone, coral fossils, and shells as a base material.

First, the components contained in limestone, coral fossils, and shells were analyzed, and the amounts of cerium oxide, iron oxide, activated carbon, titanium nitride, calcium carbonate, magnesium carbonate, and calcium phosphate contained in each of them were evaluated. In addition, limestone, coral fossils, and shells are mixed to prepare a mineral-importing material (B) of 51 m to 56 m based on the content of each component.

In addition, it is expected that the mineral-based material (B) 51m to 56m is controlled by the mixing ratio of limestone, coral fossil, and shell, but the limestone, coral fossil, and shell as raw materials may have a relationship with the place of origin. In the case where the content of the component is insufficient, the cerium oxide, the iron oxide, the activated carbon, the titanium nitride, the calcium carbonate, the magnesium carbonate, or the calcium phosphate may be added as needed. In particular, activated carbon is rarely contained in limestone, coral fossils, and shells, so it is generally added.

The mineral-importing material (B) is 51 m to 56 m, and the mineral-imparting material (B1) in the first water-passing container 51 contains 70% by weight of limestone, 15% by weight of coral fossil, and 15% by weight of shells. a mixture; the mineral-importing material (B2) in the second water-passing container 52 is a mixture containing 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, and 5% by weight of activated carbon; The mineral material supply material (B3) in the water-passing container 53 is a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells, respectively; and the mineral in the fourth water-passing container 54 is imparted. The material (B4) is a mixture containing 90% by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shells, respectively; and the mineral-imparting material (B5) in the fifth water-passing container 55 is 80% by weight, respectively. a mixture of limestone, 10% by weight of coral fossil, 10% by weight of shells; and a mineral-giving material (B6) in the sixth water-passing container 56 respectively When there is a mixture of 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shells, mineral water with excellent control effect can be obtained when mixed with mineral water (A) (B) .

In particular, it is preferable that the limestone, the coral fossil, and the shell used for the mineral-imparting materials (B1) to (B6) are the following (1-1) to (1-3).

(1-1) Limestone:

About 3 cm of pebbles formed by pulverizing limestone in which volcanic sediments containing the following components are mixed

Calcium carbonate: 50% by weight or more

Iron oxide: 3~9 wt% iron

The total of titanium oxide, titanium carbide, and titanium nitride: 0.8% by weight or more

Magnesium carbonate: 7~10% by weight

As such a limestone, [CC-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd. can be preferably used.

(1-2) Coral fossils:

The following two kinds of coral fossils are mixed in a weight ratio of 1:9 and pulverized into granules formed by 3 to 5 mm.

A coral fossil that is produced by a weight of about 100 meters under the ground, which is made into a denatured crystal by a heavy pressure; a coral fossil (a trace element containing calcium carbonate, calcium phosphate, etc.) produced from the land near Okinawa Oshima.

As such a coral fossil, [CC-300 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. can be preferably used.

(1-3) Shell:

Abalone, nine-hole, and barnacle are mixed and pulverized into 3~5mm granules with the same weight.

As such a shell, [CC-400 (product number)] manufactured by Riken Chemical Technology Co., Ltd. can be preferably used.

(1-4) Activated carbon

As the activated carbon, those produced from any raw material can be used, but activated carbon produced by using coconut shell as a raw material is preferable. For example, [CC-500 (Product No.)] manufactured by Riken Chemical Technology Systems Co., Ltd., which is made from coconut shells made in Thailand.

When the switching knobs 51b to 56b of the operation panel 58 are operated and the water flow switching valves 51v to 56v are switched toward the water container side, the water flowing through the water supply path 57 is directed to the downstream side of the water flow switching valve that is already operated. When the first water-passing container 51 to the sixth water-passing container 56 are inflow, if the water-flow switching valves 51v to 56v are switched to the bypass waterway side, the water flowing through the water supply path 57 is further downstream toward the water flow switching valve that is already operated. The side of the bypass waterway flows in from 51p to 56p. Therefore, by selectively switching the water flow switching valves 51v to 56v by operating any of the switching buttons 51b to 56b, it is possible to form different mines for each of the first water passing containers 51 to the sixth water passing container 56. Material Substance (B) Selection of Mineral Compositions Dissolved from 51m to 56m Mineralized water (B) 45 dissolved in nature.

Next, the structure and function of the mineral-containing water (B) manufacturing apparatus 3 will be described with reference to Figs. 8 to 11 . Further, in FIGS. 8 to 10, the bypass water passages 51p to 56p, the water flow switching valves 51v to 56v, the operation panel 58 and the signal cable 59 are omitted.

As shown in FIG. 8 and FIG. 9 , the mineral water-containing (B) manufacturing apparatus 3 includes a first water-passing container 51 to a sixth water-passing container 56 that are mounted on the gantry 60 in a substantially cylindrical shape; The water supply path 57 in which the first water-passing container 51 to the sixth water-passing container 56 are connected in series, and the raw water tank 63 for storing the water W supplied from the water pipe is disposed at the uppermost portion of the gantry 60. In the raw water tank 63, an inorganic porous body 64 having a function of adsorbing impurities in the water W is housed. At the bottom of the gantry 60, a plurality of casters 61 and a level adjuster 62 are provided. The first water-passing container 51 to the sixth water-passing container 56 having a substantially cylindrical shape are placed on the gantry 60 of the rectangular parallelepiped lattice structure while holding the respective axial centers 51c to 56c (see FIG. 9) in the horizontal direction. The first water-passing container 51 to the sixth water-passing container 56 can detach the gantry 60.

As shown in FIG. 10, the first water-passing container 51 to the sixth water-passing container 56 have the same structure, and the disk-shaped lid bodies 51d to 56d are attached to the cylindrical body portions 51a to 56a. The flange portions 51f to 56f at both end portions form an airtight structure. When the axial centers 51c to 56c are in a horizontal state, a water inlet 57a communicating with the water supply path 57 is provided at a portion located at the lowermost portion of the main body portions 51a to 56a, and a cover 51d at a position farther from the water inlet 57a. The uppermost part of ~56d is connected to the water supply path 57. The water outlet 57b has a screen 57c attached to the water outlet 57b. An automatic air valve 57d for detaching the gas in the first water-passing container 51 to the sixth water-passing container 56 is attached to a portion directly above the water outlet 57b on the outer circumference of the main body portions 51a to 56a.

The water supplied from the upstream water supply path 57 flows into the first water-passing container 51 to the sixth water-passing container 56 through the water inlet 57a, and the mineral-imparting material (B) filled in each of the interiors is 51 m to 56 m. After the contact, the mineral components are dissolved in the water. Therefore, the water is contained in the water containing the mineral component corresponding to the individual mineral material (B) 51m to 56m, and the water is supplied from the water outlet 57b to the downstream side. Path 57 flows out.

The mineral-containing water (B) manufacturing apparatus 3 shown in Figs. 8 to 10 is operated in the raw water tank 63 by operating one of the switching knobs 51b to 56b of the operation panel 58 as shown in Fig. 7. The water W passes through one or more water-passing containers in the first water-passing container 51 to the sixth water-passing container 56, and can form mineral-containing water (B) 45, which is selectively dissolved in individual water. The mineral component contained in the mineral-importing material (B) 51m to 56m filled in the first water-passing container 51 to the sixth water-passing container 56 is characteristic.

Further, in the mineral water-containing (B) manufacturing apparatus 3, since the first water-passing container 51 to the sixth water-passing container 56 are connected in series by the water supply path 57, the water is continuously flown to the water supply path. 57. The mineral-containing water (B) 45 is produced in a large amount, and the mineral-containing water (B) 45 is dissolved in a mineral-imparting material corresponding to the first water-passing container 51 to the sixth water-passing container 56 ( B) Mineral composition of 51m~56m.

Further, the mineral-containing water (B) 45 formed in the mineral-containing water (B) manufacturing apparatus 3 is transported into the mixing tank 46 via the water supply path 57x located further downstream than the sixth water-passing container 56. In the inside, it is mixed with the mineral-containing water (A) 44 produced by the mineral-containing water (A) manufacturing apparatus 2 shown in Fig. 1, thereby forming the mineral functional water 47.

The ratio of the mineral-containing water (A) to the mineral-containing water (B) is determined by considering the type of the raw material contained in the mineral-containing water (A) and the mineral-containing water (B) and the concentration of the dissolved components. Decide, however, that the weight ratio of mineral-containing water (A) to mineral-containing water (B) ([mineral water (A)]: [mineral water (B)]) is 1:5~ The range of 1:20 is ideally in the range of 1:7 to 1:12, and more preferably in the range of 1:10.

In the case of too little mineral water (A) (excessive mineral water (B)), and too much mineral water (A) (mineral water (B) too little), there will be mineral water The active ingredient is diluted and the effect of the desired purpose becomes insufficient.

In the above, a preferred embodiment of the method for producing mineral water according to the present invention is described. However, the present invention is not limited to the embodiments, and the mineral functional water of the present invention having the above configuration can be produced, and in addition to the above-described preferred embodiment. Various structures can also be used. In particular, in the embodiments disclosed herein, items that are not explicitly disclosed, such as operating conditions, operating conditions, various parameters, size, weight, volume, etc. of the components, are used without exceeding the scope generally practiced by the industry. A value that can be easily imagined by a general practitioner.

[Examples]

Hereinafter, the present invention will be specifically described by way of examples, but the invention is not limited to the examples.

[Example 1]

<1>Manufacture of mineral functional water

As the mineral functional water, the mineral functional water produced in the above-described embodiment of the present invention is used, and the mineral water of the first embodiment produced by the following raw materials and methods is used. .

1. Manufacture of mineral-containing water (A)

The mineral-imparting material (A'-1) was used as the mineral-imparting material (A). As the plant material (A1-1) of the raw material of the mineral-importing material (A'-1) of the first embodiment, the RIKEN Techno System Co., Ltd. product [P-100 (product number)] was used. As a woody plant material (A2-1), [P-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd. was used.

[P-100] is a plant material obtained by mixing the dried ground material of the following Compositae plants with the dried ground material of the Rosaceae plant at a ratio of 1:1 (weight ratio), [P-200] is described below. Woody plant material.

(A1) Raw material of grass plants (dried plants)

(A1-1) Dry pulverized material of Compositae

The cockroach (leaf, stem, and flower), wormwood (leaf and stem), and gerbera (leaf and stem) were each 10% by weight, 60% by weight, and 30% by weight, respectively. The dried pulverized material is mixed, dried, and pulverized.

(A1-2) Dry pulverized material of Rosaceae plants

The ratio of 20% by weight, 10% by weight, and 70% by weight of wild rose (leaf, flower), bayberry (leaf and stem), and raspberry (leaf, stem, and flower) was used. The dried pulverized material is mixed, dried, and pulverized.

(A2) Woody plant material (dried woody plant)

Maple (leaf and stem), birch (leaf, stem, and bark), cedar (leaf, stem, and bark) are 25% by weight, 25% by weight, and 50, respectively. The dry pulverized material is mixed, dried, and pulverized in a ratio of % by weight.

The mineral material (A) formed by mixing the grass plant material (A1) and the woody plant material (A2) in a ratio of 1:3 (by weight) is placed in a manner of 10 to 15% by weight of water. In the raw material mineral aqueous solution manufacturing means 10 (see FIG. 2) in the mineral-containing water (A) manufacturing apparatus 2 shown in FIG. 1, a direct current (DC8300V, 100 mA) is further connected to a raw material mineral aqueous solution manufacturing means. The conductive line of 10 causes the water around the conductive line to generate a flow of water in the same direction as the direct current. Then, ultrasonic vibration (oscillation frequency: 50 kHz, amplitude: 1.5/1000 mm) was applied to the water to form a raw material mineral aqueous solution (A). Then, the mineral-containing water (A) of Example 1 is irradiated with far-infrared rays (wavelength: 6 to 14 μm) by the raw material mineral aqueous solution (A) supplied to the far-infrared generation means 43 of the subsequent stage, thereby obtaining the mineral-containing water (A) of the first embodiment.

2. Manufacture of mineral-containing water (B)

As a raw material of the mineral-imparting material (B), a mixture in which limestone, coral fossil, shell, and activated carbon are pulverized and mixed is used. The raw material of the mineral-imparting material (B) and the mixture (mineral-imparting materials (B1) to (B6)) used in the first to sixth water-passing containers are as follows.

(1) Raw materials

(1-1) Limestone: manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-200 (Product No.)]

About 3 cm of pebbles formed by pulverizing limestone in which volcanic sediments containing the following components are mixed

Calcium carbonate: 50% by weight or more

Iron oxide: 3~9 wt% iron

The total of titanium oxide, titanium carbide, and titanium nitride: 0.8% by weight or more

Magnesium carbonate: 7 to 10% by weight.

(1-2) Coral fossil: manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-300 (Product No.)]

The following two kinds of coral fossils are mixed in a weight ratio of 1:9 and pulverized into granules formed by 3 to 5 mm.

A coral fossil that is produced from a depth of about 100 meters under the ground, which is made into a denatured crystal by heavy pressure; a coral fossil (a trace element containing calcium carbonate, calcium phosphate, etc.) produced from the land near Okinawa Oshima.

(1-3) Shell: manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-400 (Product No.)]

The abalone, the nine holes, and the barnacle are mixed and pulverized into the granules of 3 to 5 mm with the same weight.

(1-4) Activated carbon (used only in the second water container): manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-500 (product number)]

(2) Proportion of use in the first to sixth water containers

First water-passing container: mineral-imparting material (B1): a mixture containing 70% by weight of limestone, 15% by weight of coral fossil, and 15% by weight of shells, and a second water-passing container: mineral-giving material (B2) : a mixture containing 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, 5% by weight of activated carbon (corresponding to cerium oxide and activated carbon); Mineral material-imparting material (B3): a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells, respectively; and 4th water-passing container: mineral-giving material (B4): 90% by weight, respectively Limestone, 5% by weight of coral fossil, 5% by weight of shell mixture; 5th water container: mineral material (B5): 80% by weight of limestone, 10% by weight of coral fossil, 10% by weight Mixture of shells; 6th water-passing container: mineral-giving material (B6): a mixture containing 60% by weight of limestone, 30% by weight of coral fossils, and 10% by weight of shells respectively; the mineral function of the structure of Fig. 1 The water-making equipment 1 obtains mineral-containing water (B) by circulating water to the first to sixth water-passing containers using the mineral-imparting materials (B1) to (B6). (B1) to (B6) were set to 50 kg (total 300 kg), the amount of water flowing was 1000 kg, and the flow rate was 500 mL/40 s.

The mineral-containing water (A) of Example 1 and the mineral-containing water (B) which were carried out in the above method were mixed to form a 1:10 (weight ratio) to obtain the mineral functional water of Example 1. . The mineral functional water of Example 1 was measured by a pH measuring device (Glass Electrode Hydrogen Concentration Indicator TPX-90 manufactured by Dongxing Chemical Research Institute), which was pH 12.5.

In addition, the mineral functional water of the first embodiment is equivalent to the mineral functional water CAC-717 manufactured by Riken Chemical Technology Co., Ltd. [Tera Protect (product name), CAC-717 (product number), development product No. CA-C-01].

(Evaluation of spectroradiance)

The spectroscopic emissivity of the sample in which the mineral functional water of Example 1 was immobilized on the ceramic carrier was measured by a far-infrared radiation rate measuring apparatus (JIR-E500 manufactured by JEOL Ltd.). The device is composed of a Fourier transform infrared spectrophotometer (FTIR) body, a black body furnace, a sample heating furnace, a temperature controller, and an attached optical system.

The evaluation sample of the spectral emissivity was produced by the following procedure.

To 100 parts by weight of the ceramic powder for carrier (the rock powder of Amakusa Oyao), 20 parts by weight of the mineral functional water of Example 1 was added to prepare a clay state. This was processed into a flat plate shape having a circular surface having a thickness of about 5 mm and a diameter of 2 cm, and was fired at 1000 ° C to obtain an evaluation sample in which the mineral component contained in the sample (mineral functional water) was immobilized.

Fig. 12 is a view showing the spectral emissivity spectrum of the mineral functional water of Example 1 as a measurement sample (measurement temperature: 25 ° C: wavelength range: 4 to 24 μm). Further, in Fig. 12, the spectral emissivity spectrum (theoretical value) of the black body is shown together. Further, in Fig. 12, the vertical axis scale indicates the intensity of the radiation energy and is displayed in W number per square centimeter. Further, the curve of the [sample] means a curve closer to the black body, and the radiation ability is higher.

In addition, FIG. 13 shows an emission ratio (wavelength range: 4 to 24 μm) obtained from the spectral radiance spectrum of the measurement sample and the spectral radiance spectrum (theoretical value) of the black body.

From Fig. 13, the average placement ratio of the wavelength of 5 to 7 μm and the wavelength of 14 to 24 μm was calculated to be 91.7%.

<2-1>Manufacture of hardened cement

20 parts by weight of the mineral functional water of the first embodiment, white cement (made of Pacific cement) as a cement composition: 50 parts by weight, vermiculite powder (SiO ₂ ) 15 parts by weight, limestone (containing 50% by weight of CaCO) ₃ of sedimentary rocks) to 15 wt mixer unit for mixing to obtain a cement mixing material. The obtained cement mixture was cured for 3 days and cured to obtain a cement hardened body of Example 1.

<2-2>Manufacture of ceramic porous body

A predetermined amount of water was added to 100 parts by weight of the ceramic powder for carrier (the rock powder of Amakusa Oyao Island) to obtain a clay-like mixture. The obtained clay-like mixture was formed into a flat plate shape having a circular surface having a thickness of about 5 mm and a diameter of 2 cm, and baked at 500 ° C for 8 hours to obtain a porous calcined body.

Then, the weight portion of the porous calcined body 100 was uniformly impregnated with 15 parts by weight of the mineral functional water of Example 1, and dried for several days, thereby obtaining a mineral component soluble in the mineral functional water. The ceramic porous body of Example 1 was immobilized.

<3> Evaluation of dissolving functional water

<3-1 Solvent Test>

As a mineral elution test, 100 parts by weight of water as an extraction solvent and 40 parts by weight of the cemented body of Example 1 were placed in a predetermined container, and then allowed to stand (6 hours or more) until pH 11.5 to 12.5 was formed. And then take the water. The water after the test was subjected to component analysis, and it was confirmed that mineral mineral mineral components such as calcium ions, strontium ions, and sodium ions and plant organic components (polyphenols) were eluted.

Moreover, when the ceramic porous body of Example 1 was subjected to the same dissolution test, it was confirmed that the same mineral inorganic mineral component and the vegetable organic component were eluted.

From this result, it was confirmed that the cement hardened body of Example 1 and the ceramic porous body of Example 1 were all eluted and fixed with a mineral component.

<3-2 Single cell biological control test>

The following bacteria (single cell organism) control test was carried out using water containing a mineral component eluted from the cement hardened body (hereinafter referred to as [the solvent water of Example 1]).

[Evaluation 1: Staphylococcus aureus]

The Staphylococcus aureus was prepared to have a bacterial liquid concentration of 2.2 × 10 ⁶ /mL using 1/500 ordinary broth medium which was sterilized, and the bacterial liquid was used as a test bacterial liquid.

100 mL of the solute functional water of Example 1 was placed in a sterilized Erlenmeyer flask, and 1 mL of the test bacterial solution was further dropped, and allowed to stand at room temperature at about 25 ° C for 1 hour. After standing for 1 hour, shake the water in the Erlenmeyer flask by hand. The solution was appropriately diluted with phosphate buffered physiological saline, and the number of bacteria per 1 mL in one sample was measured by pouring plate culture. As a comparative example (control), one mL of the test bacterial liquid was dropped using 100 mL of ion-exchanged water which had been sterilized.

Table 1 shows the number of bacteria per 1 mL after 1 mL of the test bacterial solution immediately after dropping 1 in Example 1 and Comparative Example (control).

In the comparative example (control) containing no crystallization water of the liquefied material of Example 1, almost no difference in the number of bacteria was observed immediately after the dropping of the bacterial liquid and after dropping for 1 hour. Further, in the example containing the deciduous functional water of Example 1, almost no bacteria were formed immediately after the dropping of the bacterial liquid and after dropping for 1 hour. From this result, it was confirmed that the leaching machine water of Example 1 has an excellent control effect against Staphylococcus aureus.

[Evaluation 2: Escherichia coli]

Using 1/500 ordinary broth medium which was sterilized, the coliform was prepared to have a bacterial liquid concentration of 2.5×10 ⁶ /mL, and the bacterial liquid was used as a test bacterial liquid.

100 mL of the lysing functional water of Example 1 was placed in a sterilized Erlenmeyer flask, and 1 mL of the test bacterial solution was dropped, and allowed to stand at room temperature at 25 ° C. 1 hour. After standing for 1 hour, the aqueous solution in the Erlenmeyer flask was shaken by hand, and the mixture was appropriately diluted with phosphate buffered physiological saline, and the number of bacteria per 1 mL of the sample was measured by a pour plate culture method. As a comparative example (control), one mL of the test bacterial liquid was dropped using 100 mL of ion-exchanged water which had been sterilized.

Table 2 shows the number of bacteria per 1 mL after 1 mL of the test bacterial solution immediately after dropping 1 in Example 1 and Comparative Example (control).

In the comparative example (control) containing no crystallization water of the liquefied material of Example 1, almost no difference in the number of bacteria was observed immediately after the dropping of the bacterial liquid and after dropping for 1 hour. Further, in the example containing the deciduous functional water of Example 1, almost no bacteria were formed immediately after the dropping of the bacterial liquid and after dropping for 1 hour. From this result, it was confirmed that the leaching machine water of Example 1 has an excellent control effect against coliform bacteria.

[Embodiment 2]

The cement hardened body and the ceramic porous body of Example 2 were produced by the following methods. In addition, in the manufacturing method of the Example 2, the part common to the manufacturing method of Example 1 is suitably abbreviate|omitted.

<1>Manufacture of mineral functional water

The mineral functional water of Example 2 produced by the following raw materials and methods was produced.

1. Manufacture of mineral-containing water (A)

Example 1 was obtained in the same manner as in Example 1 except that the mineral-importing material (A'-2) was used as the mineral-importing material (A) in place of the mineral-imparting material (A'-1) of Example 1. 2 mineral water (A).

2. Manufacture of mineral-containing water (B)

Since it is the same as that of the first embodiment, the description thereof is omitted here.

The mineral-containing water (A) of Example 2 of the above method and the mineral-containing water (B) were mixed so as to form 1:10 (weight ratio) to obtain the mineral functional water of Example 2.

In addition, the mineral functional water of the second embodiment is equivalent to the mineral functional water A20ACA-717 [Tera Support (trade name), A20ACA-717 (product number)] manufactured by Riken Chemical Technology Co., Ltd.

<2>Manufacture of cement hardened body and ceramic porous body

The cement hardening of Example 2 was obtained by the same method as the production of the cement hardened body (or ceramic porous body) of Example 1 except that the mineral functional water of Example 2 was used instead of the mineral functional water of Example 1. Body (or ceramic porous body).

<3> Mineral dissolution test

In the same manner as in the case of the cement hardened body or the ceramic porous body of the second embodiment, the mineral inorganic mineral component and the vegetable organic component were eluted.

From the results, it was confirmed that the cement hardened body of Example 2 and the ceramic porous body of Example 2 were all eluted and fixed with a mineral component.

[Example 3]

The cement hardened body and the ceramic porous body of Example 3 were produced by the following methods. In addition, in the manufacturing method of Example 3, the part common to the manufacturing method of Example 1 is suitably abbreviate|omitted.

<1>Manufacture of mineral functional water

The mineral functional water of Example 3 produced by the following raw materials and methods was produced.

1. Manufacture of mineral-containing water (A)

The same procedure as in Example 1 was carried out except that the mineral-importing material (A'-3) was used as the mineral-importing material (A) in place of the mineral-imparting material (A'-1) of Example 1. 3 mineral water (A).

2. Manufacture of mineral-containing water (B)

Since it is the same as that of the first embodiment, the description thereof is omitted here.

The mineral-containing water (A) of Example 3 and the mineral-containing water (B) which were carried out in the above method were mixed to form 1:10 (weight ratio) to obtain the mineral functional water of Example 3. .

<2>Manufacture of cement hardened body and ceramic porous body

The cement hardening of Example 3 was obtained by the same method as the production of the cement hardened body (or ceramic porous body) of Example 1 except that the mineral functional water of Example 3 was used instead of the mineral functional water of Example 1. Body (or ceramic porous body).

<3> Mineral dissolution test

In the same manner as in the case of the cement hardened body or the ceramic porous body of the third embodiment, the mineral inorganic mineral component and the vegetable organic component were eluted.

From the results, it was confirmed that the cement hardened body of Example 3 and the ceramic porous body of Example 3 were all eluted and fixed with a mineral component.

[Example 4]

The cement hardened body and the ceramic porous body of Example 4 were produced by the following methods. In addition, in the manufacturing method of the fourth embodiment, the part common to the manufacturing method of the first embodiment will be appropriately omitted.

<1>Manufacture of mineral functional water

The mineral functional water of Example 4 produced by the following raw materials and methods was produced.

1. Manufacture of mineral-containing water (A)

Example 1 was obtained in the same manner as in Example 1 except that the mineral-importing material (A'-4) was used as the mineral-importing material (A) in place of the mineral-imparting material (A'-1) of Example 1. 3 mineral water (A).

2. Manufacture of mineral-containing water (B)

Since it is the same as that of the first embodiment, the description thereof is omitted here.

The mineral-containing water (A) of Example 4 and the mineral-containing water (B) which were carried out in the above method were mixed to form a 1:10 (weight ratio) to obtain the mineral functional water of Example 4. .

<2>Manufacture of cement hardened body and ceramic porous body

The cement hardening of Example 4 was obtained by the same method as the production of the cement hardened body (or ceramic porous body) of Example 1 except that the mineral functional water of Example 4 was used instead of the mineral functional water of Example 1. Body (or ceramic porous body).

<3> Mineral dissolution test

In the same manner as in the case of the cement hardened body or the ceramic porous body of the fourth embodiment, the mineral-based inorganic body was confirmed. Mineral components and plant organic components are dissolved.

From the results, it was confirmed that the cement hardened body of Example 4 and the ceramic porous body of Example 4 were all eluted with a mineral component.

[Industrial use possibility]

The ceramic material of the present invention has the advantage that it has an effective effect due to the mineral component contained, and is solid and easy to handle.

1‧‧‧Mineral functional water manufacturing equipment

2‧‧‧Mineral water (A) manufacturing equipment

3‧‧‧Mineral water (B) manufacturing equipment

10‧‧‧Methods for the production of raw materials and mineral aqueous solutions

11, W‧‧‧ water

41‧‧‧ Raw material mineral aqueous solution (A)

43‧‧‧ far infrared ray generation means

44‧‧‧ Mineral water (A)

45‧‧‧ Mineral water (B)

46‧‧‧ mixing tank

47‧‧‧Mineral functional water

51‧‧‧1st water container

52‧‧‧2nd water container

53‧‧‧3rd water container

54‧‧‧4th water container

55‧‧‧5th water container

56‧‧‧6th water container

51m~56m‧‧‧ Mineral Substance (B)

51p~56p‧‧‧迂回回路

51v~56v‧‧‧Water flow switching valve

57, 57x, 57y‧‧‧ water supply path

Claims (12)

A ceramic material comprising a mineral component that is immobilized and is a source of mineral water. The ceramic material according to claim 1, wherein the ceramic material is a cement hardened body containing a mineral component, or a ceramic porous body supporting a mineral component in the pores. The ceramic material according to claim 1 or 2, wherein the mineral functional water is contained in a ratio of 1:5 to 1:20 (weight ratio) and is formed by the following process (1) Mineral water (A), and mineral water (B) mineral water process (1) formed by the following process (2): conductive wire covered with insulator, and grass containing Asteraceae Mineral material-giving material of woody plant material consisting of plants and plants of the genus Rosaceae, and woody plant materials consisting of one or more woody plants selected from maple, birch, pine and cedar (A) Immersed in water to conduct a direct current to the conductive wire, and a water flow in the same direction as the direct current is generated in the water around the conductive wire, and ultrasonic vibration is applied to the water to form a raw material mineral aqueous solution (A). The raw mineral aqueous solution (A) is irradiated with far infrared rays (wavelength 6 to 14 μm) to form a mineral-containing water (A), wherein the mineral-imparting material (A) is added to the water in an amount of 10 to 15% by weight. a current value and a voltage value of a direct current that is conducted to the conductive line Do is 0.05 ~ 0.1A, and the 8000 ~ 8600V Scope; Process (2): a process for forming mineral-containing water (B) containing mineral water (B) through six water-passing containers, wherein the six water-passing containers are filled with inorganic substances of different kinds The first water-passing container to the sixth water-passing container in which the mineral-based material (B) is connected in series: the mineral-imparting material (B1) in the first water-passing container contains 70% by weight of limestone, respectively. a mixture of a percentage by weight of coral fossil and 15% by weight of shells; and a mineral-imparting material (B2) in the second water-passing container containing 40% by weight of limestone, 15% by weight of coral fossil, and 40% by weight of shells, respectively. a mixture of 5% by weight of activated carbon; the mineral-imparting material (B3) in the third water-passing container is a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells, respectively; The mineral-imparting material (B4) in the water container is a mixture containing 90% by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shells, respectively; and the mineral-imparting material (B5) in the fifth water-passing container is a mixture comprising 80% by weight of limestone, 10% by weight of coral fossils, and 10% by weight of shells; The mineral-imparting material (B6) in the sixth water-passing container contains 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shellfish. a mixture of shells. The ceramic material according to item 3 of the patent application, wherein the mineral material imparting material (A) is formed by a weight ratio of the grass plant material (A1-1) to the woody plant material (A2-1): 1:2.7 The mineral-donating material (A'-1) obtained by mixing ~1:3.3, in which the big cockroach (leaf, stem, flower), wormwood (leaf, stem), and mountain daisy ( The leaves and stems are dried and pulverized in a ratio of 8 to 12% by weight, 55 to 65% by weight, and 27 to 33% by weight, respectively, and then pulverized; and the wild rose (leaf) is used. Department, flower part), bayberry (leaf part, stem part), raspberry (leaf part, stem part, flower part) are respectively 17 to 23% by weight, 8 to 12% by weight, and 65 to 75% by weight The dried pulverized material of the Rosaceae plant which is mixed, dried and then pulverized, and the dried pulverized material of the compositae plant and the dried pulverized material of the Rosaceae plant are mixed at a ratio of 1:0.8 to 1:1.2 (weight ratio). The plant material (A1-1) is used as the raw material of the above-mentioned plant, from maple (leaf, stem), birch (leaf, stem, and bark), cedar (leaf, stem, and bark) ) A woody plant material (A2-1) composed of a dry pulverized material which is mixed, dried, and pulverized at a ratio of 22 to 28% by weight, 22 to 28% by weight, and 45 to 55% by weight as the raw material of the woody plant . The ceramic material according to claim 3, wherein the mineral-affecting material (A) is formed by a weight ratio of the grass plant material (A1-2) to the woody plant material (A2-2) of 1:5. Way to mix The obtained mineral-imparting material (A'-2) in which the above-mentioned mineral-giving material (A'-2) is used as the raw material of the plant, and the cockroach (leaf, stem, flower), wormwood (leaf part, stem part), mountain chrysanthemum (leaf part and stem part), dried, pulverized and dried in a ratio of 10% by weight, 60% by weight, and 30% by weight, respectively, and then pulverized (leaf, flower), bayberry (leaf, stem), raspberry (leaf, stem, flower) mixed and dried at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively a plant material (A1-2) obtained by mixing a dry pulverized plant of a Rosaceae plant which is pulverized and then pulverized at a ratio of 1:1 (weight ratio); and as a raw material of the aforementioned woody plant, a maple tree (deciduous), a birch tree (deciduous, stem, and bark), cedar (deciduous, stem, and bark), which are mixed at a ratio of 20% by weight, 60% by weight, and 20% by weight, dried, and then pulverized. The woody plant material (A2-2). A ceramic material, which is a ceramic material as described in any one of claims 1 to 5, characterized in that the ceramic material is a cement hardened body, and the manufacturing method has the following functions: The water and the cement composition are mixed to obtain a mixing process of the cement mixture; and the curing process of curing and curing the obtained cement mixture is obtained. A method of producing a ceramic material, the ceramic material being the ceramic material as described in any one of claims 1 to 5, characterized in that The ceramic material is a cement hardened body, and the manufacturing method has the following steps: a process of mixing a liquid for mixing with a ceramic powder for a carrier into a clay-like mixture; (I); a process of heat-treating the clay-like mixture to obtain a ceramic porous body (II); and a process (III) of allowing the mineral functional water to permeate the pores of the ceramic porous body, followed by drying to fix the mineral component to the ceramic porous body. A method for producing a water for emulsification, characterized in that a ceramic material as described in any one of claims 1 to 5 is brought into contact with an extraction solvent mainly composed of water to make the ceramic material contain The aforementioned mineral component is dissolved in the aforementioned extraction solvent. A ceramic material comprising a mineral component immobilized to be soluble and which is a source of mineral functional water, characterized in that: the mineral functional water meets all of the following requirements (i) to (iv): (i) The sample having the weight of 15 parts by weight or more of the mineral functional water fixed to the weight of the ceramic carrier 100 is 90% or more in the average emission ratio (measuring temperature: 25° C.) to the black body at a wavelength of 5 to 7 μm and a wavelength of 14 to 24 μm. (ii) the mineral functional water is above pH 12; (iii) has a control effect on at least one of single-celled organisms and viruses; (iv) contains organic components derived from plants. The ceramic material according to claim 9, wherein the ceramic material is a cement hardened body containing a mineral component, or a ceramic porous body supporting a mineral component in the pores. A method for producing a water for solvating water, characterized in that a ceramic material as described in claim 9 or 10 is brought into contact with an extraction solvent mainly composed of water to dissolve the aforementioned mineral component contained in the ceramic material It is precipitated in the aforementioned extraction solvent. A control method characterized in that the ceramic material described in claim 9 or 10 is brought into contact with an extraction solvent mainly composed of water, and the mineral component contained in the ceramic material is dissolved in the extraction solvent. The solvating machine water is obtained, and the lysing machine water is applied to the single cell organism and/or virus of the control object.