TW201725252A - Pest-resistant fiber masterbatch composition comprising at least a fiber constituent agent, an insect repellent, and an additive - Google Patents

Abstract

The present invention provides a pest-resistant fiber masterbatch composition, comprising at least a fiber constituent agent, an insect repellent, and an additive. The fiber constituent agent is at least one selected from the group consisting of natural fiber, plant fiber, animal fiber, regenerated fiber, semi-synthetic fiber, synthetic fiber, and mixtures thereof. The insect repellent is at least one selected from the group consisting of pyrethrin-based compound, organochlorine-based compound, organophosphorus-based compound, carbamate-based compound, derivatives thereof, and mixtures thereof. The pest-resistant fiber masterbatch composition of the present invention has insect proofing and removing effect to prevent insects from contacting, approaching and staying, shortening the resident time of insects, etc. The masterbatch prepared by the pest-resistant fiber masterbatch composition of the invention is also suitable for being produced in PE, PP, PLA, TPU and the like. In addition, the fibers formed from the pest-resistant fiber masterbatch composition of the invention can be further blended with any fibers to produce various kinds of textiles.

Description

Insect-resistant fiber masterbatch composition

The present invention relates to a pesticidal fiber masterbatch composition, and more particularly to a pesticidal fiber masterbatch composition comprising at least a fiber constituting agent, an insect repellent and an additive capable of achieving a highly insecticidal effect.

In many countries in the tropics, there are many infectious diseases that cause humans and animals to weaken or even die, such as malaria, dengue fever, yellow fever, lymphatic filariasis, and Leishmaniasis. Among them, malaria has the highest disability-adjusted life-years, and has been rated as the most vulnerable to human inability to adjust; especially for children outside the newborn period. The mortality rate will be as high as 25% when bitten by mosquito parasites of malaria parasites. As a result, most of the recent medical efforts to improve health services and reduce resistance to drug resistance have focused on methods and techniques for controlling and preventing vector mosquito and insect transmission.

The methods for controlling these vector mosquitoes and insects usually include the treatment of the surface of the barracks and houses, and the method of spraying insecticides on the air. In addition, there are also cockroaches or mosquito nets that have been treated with bathing insecticides, and nets with insect control functions. Fabrics and fibrous articles, for example, by immersing the textile material in an insecticide emulsion or suspension, or by spraying insecticides on mosquito nets and pestles. Among these insecticides, synthetic pyrethroid compounds such as chlorpyrifos, chlorpyrifos, xeronine, alphamethrin, and cyprodin are now more commonly used today. A strong and safe insecticide for use.

In addition to the above means, the addition of an insect repellent to the fabric or the coating or coating of the insect repellent on the surface of the fabric is one of the effective methods for protecting the fabric from insect damage. In recent years, many studies have reported that the long-acting insecticide-treated net (LLITN) is more reliable and effective in preventing diseases carried by protozoa. For example, Sumitomo Chemical Co., Ltd. is an example of an OLESET polyethylene monofilament insect-repellent fiber produced by adding a permethrin-based masterbatch during high-density polyethylene jet spinning.

However, the above-mentioned polyethylene monofilament insect-repellent fiber, although the permethrin will migrate outward from the inside of the fiber during use, and then covers the polysilicate glass having a low glass transition temperature, crystallinity and density, and a large inter-molecular void in the resin. The surface of the vinyl fiber fiber acts on the mosquitoes; however, the amount of permethrin must be increased to more than 2% of the polyethylene resin, which is not only costly, the spinnability of the fiber is deteriorated, and the fiber strength is also lowered. .

In addition, when such fibers are used as screen doors, screens, insect-proof yarns, clothing materials, agricultural insect nets, etc., the chlorinus contained in the fibers is affected by the climatic factors of the use environment, outdoor wind and rain, and ultraviolet rays. The ester accelerates decomposition and loss, so that it is often impossible to obtain a satisfactory pest control effect or even completely lose insect control efficiency.

Therefore, all walks of life are not expecting to develop a pest-preventing fiber masterbatch composition that can solve the traditional technical problems that are harmful to the environment, human health, and insect-repellent effects, and eagerly develop a kind of light stability that can be solved. Insect-resistant fiber with problems of conventional techniques such as lack of ultraviolet light resistance and weak insect resistance.

In view of the above, the present inventors have diligently studied various possible solutions for solving the problems of the conventional technology, and have developed a problem that not only improves the above-mentioned conventional technology, but also has no harm to the environment and human health, and has conformity. The home environment and the outdoor and field activities require excellent insect control functions, and can effectively reduce the pest control effect of pests approaching or passing, preventing the reproduction and growth of pests, and being able to produce strong antioxidant capacity and high light stability. The novel insect-resistant fiber masterbatch composition of the insect-resistant fiber which is resistant to ultraviolet rays and long-term insect-repellent properties, and the insect-repellent fiber made therefrom, have heretofore completed the present invention. Summary of Invention

Specifically, according to one aspect of the present invention, a fiber masterbatch composition having insecticidal efficacy can be provided, which comprises at least: a fiber constituting agent, an insect repellent, and an additive; the insect repellent is a pyrethrin a compound, an organochlorine-based compound, an organophosphorus-based compound, an aminoformate-based compound, a derivative thereof, and a mixture thereof are at least one selected from the group consisting of: an antioxidant, a filler, The anti-UV agent, the derivative thereof, and the mixture and derivative thereof are at least one selected from the group; when the total amount of the insecticidal fiber masterbatch composition is 100 parts by weight, the fiber constituting agent The total content is in the range of from about 50.0 parts by weight to about 95.0 parts by weight; the total content of the insecticide is in the range of from about 1.0 part by weight to about 45.0 parts by weight; and the total content of the antioxidant contained in the additive It is in the range of about 0.01 parts by weight to about 5.00 parts by weight, and the filler is included in the range of about 0.5 parts by weight to about 15.0 parts by weight; the anti-UV agent is contained in an amount of from about 0.05 parts by weight to about 5.00 parts by weight. The scope of the share.

In some embodiments, the fiber constituting agent contained in the insecticidal fiber masterbatch composition of the present invention is from ABS resin (ABS), epoxy resin (EPOXY), polyester (Polyester), polyparaphenylene. Butane dicarboxylate (PBT), propylene glycol phthalate (PTT), polyacrylonitrile (PAN), polydecylamine (PA), polyacrylic acid (PAA), polyamidimide (PAI), polybutylene Alkene (PB), polybenzimidazole (PBI), polybenzoxazole (PBO), polybenzothiazole (PBTh), polycarbonate (PC), polyethylene (PE), polyetheretherketone (PEEK) , polyethylene terephthalate (PET), phenolic resin (PF), high-coefficient polyethylene (HMPE), polyimine (PI), polyisobutylene (PIB), polylactic acid (PLA), polymethyl Methyl acrylate (PMMA), polyacetal (POM), polypropylene (PP), polyphenylene sulfide (PPS), polystyrene (PS), polyfluorene (PSF), plastic starch (PSM), polytetra Vinyl fluoride (PTFE), polyurethane (PU), polyvinyl alcohol (PVA), polyvinyl chloride (PVC), polyvinylidene fluoride (PVDF), butadiene rubber (BR), styrene butadiene rubber (SBR) Nitrile rubber (NBR), neoprene (CR), butadiene rubber, ethylene propylene rubber, polysulfide rubber, acrylate rubber, fluororubber, enamel rubber (SP.SI), butyl rubber (IIR), isoprene Rubber, Acetic Acid, Triacetate, Polyamide, Polypropylene, Polyester (Daikelun), Nylon (Nylon/Nylon), Nylon 6 (Nylon 6), Nylon 6.6 (Nylon 6.6), Nylon 11 (Nylon 11) And a mixture of acrylic, polyvinyl chloride, vinylon, spandex, keflon, and the like to form at least one selected from the group.

As used herein, "fiber structuring agent" refers to a forming material that can be used to form various forms of fibers including, but not limited to, compounds, derivatives, fiber masterbatches, fibers, composite filaments, natural fibers, synthetic fibers, and the like. According to one aspect of the present invention, the fiber constituting agent contained in the insecticidal fiber masterbatch composition is not particularly limited as long as it is conventionally used for producing chemical fibers and is synthesized without departing from the spirit of the invention. Any of the conventional textile fiber forming materials of fibers and semi-synthetic fibers.

According to some specific embodiments, the fiber constituting agent contained in the insecticidal fiber masterbatch composition of the present invention is not particularly limited. For example, for example, ABS resin (ABS), epoxy resin (EPOXY), polyester (Polyester), polybutylene terephthalate (PBT), propylene carbonate (PTT), poly Acrylonitrile (PAN), polydecylamine (PA), polyacrylic acid (PAA), polyamidimide (PAI), polybutene (PB), polybenzimidazole (PBI), polybenzoxazole ( PBO), polybenzothiazole (PBTh), polycarbonate (PC), polyethylene (PE), polyetheretherketone (PEEK), polyethylene terephthalate (PET), phenolic resin (PF), High-coefficient polyethylene (HMPE), polyimine (PI), polyisobutylene (PIB), polylactic acid (PLA), polymethyl methacrylate (PMMA), polyacetal (POM), polypropylene (PP) , polyphenylene sulfide (PPS), polystyrene (PS), polyfluorene (PSF), plastic starch (PSM), polytetrafluoroethylene (PTFE), polyurethane (PU), polyvinyl alcohol ( PVA), polyvinyl chloride (PVC), polyvinylidene fluoride (PVDF), butadiene rubber (BR), styrene butadiene rubber (SBR), nitrile rubber (NBR), neoprene (CR), butadiene rubber , ethylene propylene rubber, polysulfide rubber, acrylate rubber, fluororubber, enamel rubber (SP.SI), butyl rubber (IIR), isoprene rubber, acetic acid, triacetate, polyamide, polypropylene, polyester (Daclon), nylon (nylon / nylon), nylon 6 (Nylon 6), nylon 6.6 (Nylon 6.6), nylon 11 (Nylon 11), acrylic, chlorin, vinylon, spandex, kefulun And a mixture of the same constitutes at least one selected from the group.

In some specific embodiments, the total content of the fiber constituting agent contained in the insecticidal fiber masterbatch composition of the present invention is not particularly limited as long as it does not contradict or deviate from the spirit of the present invention and can be attained. The insect control effect can be. For example, the total content of the fiber constituting agent may be, for example, in the range of from about 50.0 parts by weight to about 95.0 parts by weight, based on 100 parts by weight of the insecticidal fiber masterbatch composition; preferably at 52.5 parts by weight. To a range of about 92.5 parts by weight; more preferably in the range of from about 55.0 parts by weight to 90.0 parts by weight; particularly preferably in the range of from about 57.5 parts by weight to about 87.5 parts by weight; most preferably from about 60.0 parts by weight to about 85.0 parts. The range of parts by weight.

Further, the fiber constituting agent contained in the fiber master batch composition of the present invention may further contain other fiber forming materials as long as it does not contradict or depart from the spirit of the present invention. Specifically, the fiber-forming material can be not particularly limited; for example, it may be a natural fiber, a plant fiber, an animal fiber, a regenerated fiber, a semi-synthetic fiber, or a mixture thereof. More specifically, the above-mentioned fiber forming material may be, for example, cotton, seed fiber of Kapok; Linen, Jute, Hemp, ramie ( Ramie) Bast Fiber; Manila Hemp, Sisal, New Zealand Hemp, Piña, etc. Leaf Fiber; Coconut Fruit Fiber of Coir, etc.; Sheep Wool, Camel Wool, Alpaca, Cashmere Hair, Mohair Hair, Mountain Wool (Wool & Hair Fiber) of Goat Hair; Mineral Fiber of Silky Silk, Silk of Tussah Silk, Mineral Fiber of Asbestos, Glass Fiber (Inorganic Regenerated Fiber), such as Glass Fiber, Metal Fiber, Rock Fiber, Slag Fiber, etc.; Casein Fiber, Groundnut Fiber , Soybean Fiber, Maize Fiber, Polylactic Acid Fiber (Protein Fiber) such as (PLA Fiber); Cellulose Fiber of Bamboo Carbon Fiber, Viscose Rayon, Cuprammonium Rayon, and New Solvent Cellulose Fiber (Lyocell) And other fiber forming materials, for example, Rush, Chitin Fiber, and the like.

According to one aspect of the present invention, the insect repellent in the fiber masterbatch composition of the present invention is a compound having a function of removing insects, preventing insects, or regulating insect growth, or a formulation containing the same, a growth controlling agent, A pesticide or the like can be used without particular limitation; for example, it can be used, but not limited to, a pyrethroid-based compound or an organic chlorine-based compound which is generally used for insect removal, insect control, or insect growth inhibition. An organophosphorus compound, an aminoformate compound, a derivative thereof, and a mixture thereof are at least one selected from the group consisting of insect repellents.

In certain embodiments, the insecticide in the fiber masterbatch composition of the present invention preferably contains a pyrethroid-based compound, an organochlorine-based compound, within the scope of the spirit of the present invention. , the organophosphorus compound, and the carbamate compound constitute at least one insecticide selected in the group; more preferably, the pyrethroid compound, the organochlorine compound, the organophosphorus compound Or an insect repellent comprising at least one of a urethane compound; and particularly preferably a compound comprising a pyrethroid compound, an organochlorine compound, and an organophosphorus compound. An insect repellent; particularly preferably an insect repellent comprising at least one compound of a pyrethroid compound and an organophosphorus compound; and most preferably at least one compound containing a pyrethroid compound The insecticide formed.

The total content of the insecticide contained in the insecticidal fiber masterbatch composition of the present invention is not particularly limited as long as it does not contradict or depart from the spirit of the present invention and can achieve an insect control effect. For example, in some specific embodiments of the insecticidal fiber masterbatch composition of the present invention, for example, the total content of the insecticide may be relative to 100 parts by weight of the insecticidal fiber masterbatch composition. It is in the range of from about 1.0 part by weight to about 45.0 parts by weight; in some embodiments, preferably in the range of from 2.0 parts by weight to about 42.0 parts by weight; more preferably from about 3.0 parts by weight to 40.0 parts by weight The range; particularly preferably in the range of from about 4.0 parts by weight to about 37.5 parts by weight; most preferably in the range of from about 5.0 parts by weight to about 35.0 parts by weight.

More specifically, the pyrethroid-based compound which can be used as the insect repellent of the fiber masterbatch composition of the present invention is not particularly limited as long as it does not contradict or depart from the spirit of the present invention. It can be used; for example, it can be from Alphacypermethrin, Bifenthrin, Cyfluthrin, Cyhalothrin, Cypermethrin (also known as Cypermethin). ), deltamethrin (also known as Ding Ning), Esfenvalerate Fenvalerate, Flucythrinate, Fluvalinate, Permethrin At least one selected from the group consisting of Allethrin, Tetramethrin, Fenpropathrin, and mixtures thereof.

According to some embodiments of the present invention, the pyrethroid-based compound contained in the insecticide of the fiber masterbatch composition preferably contains self-derived, cypermethrin, deltamethrin, and fentanyl. Mixtures of Husaining, Fuhuali, Baishenning, Yaliening, Zhiningning, Fenpanning, and others are at least one selected from the group; cypermethrin and deltamethrin are more preferably used At least one selected from the group consisting of arsenicin, cypermethrin, deltamethrin, chloramphenicol, fuhuali, baifening, yalining, or zhining, and the mixture thereof; Using at least one selected from the group consisting of arsenicin, cypermethrin, deltamethrin, chloramphenicol, fuhuali, baifening, arylene, zhining, and the like; At least one selected from the group consisting of a mixture comprising arsenic, fentanyl, cypermethrin, deltamethrin, fumarate, arylene, chlorpyrifos, and the like.

In some specific embodiments, in the insecticide contained in the insecticidal fiber masterbatch composition of the present invention, the content of the arsenic is not particularly limited; for example, relative to 100 parts by weight The insecticidal fiber masterbatch composition may have a content of the imipenem in the range of, for example, about 0.5 parts by weight to about 20.0 parts by weight; preferably in the range of from 1.0 part by weight to about 18.0 parts by weight; more preferably It is in the range of from about 1.5 parts by weight to 16.0 parts by weight; particularly preferably in the range of from about 2.0 parts by weight to about 15.0 parts by weight; most preferably in the range of from about 2.5 parts by weight to about 12.0 parts by weight.

In some specific embodiments, the content of the cypermethrin in the insecticide contained in the insecticidal fiber masterbatch composition of the present invention is not particularly limited; for example, relative to 100 parts by weight of the insect control The content of the cypermethrin in the fiber masterbatch composition may range, for example, from about 0.5 parts by weight to about 20.0 parts by weight; preferably from 1.0 part by weight to about 18.0 parts by weight; more preferably at about 1.5 parts by weight The fraction is in the range of 16.0 parts by weight; particularly preferably in the range of from about 2.0 parts by weight to about 15.0 parts by weight; most preferably in the range of from about 2.5 parts by weight to about 12.0 parts by weight.

In some specific embodiments, the content of the deltamethrin in the insecticide contained in the insecticidal fiber masterbatch composition of the present invention is not particularly limited; for example, relative to 100 parts by weight The insecticide fiber masterbatch composition may have a content of the deltamethrin in a range of, for example, about 0.5 parts by weight to about 20.0 parts by weight; preferably in a range of from 1.0 part by weight to about 18.0 parts by weight; It is preferably in the range of from about 1.5 parts by weight to 16.0 parts by weight; particularly preferably in the range of from about 2.0 parts by weight to about 15.0 parts by weight; most preferably in the range of from about 2.5 parts by weight to about 12.0 parts by weight.

In some specific embodiments, the insecticide contained in the insecticidal fiber masterbatch composition of the present invention is not particularly limited in content; for example, relative to 100 parts by weight The insecticide fiber masterbatch composition may be in a range of, for example, from about 0.5 part by weight to about 20.0 parts by weight; preferably from 1.0 part by weight to about 18.0 parts by weight; more preferably It is in the range of from about 1.5 parts by weight to 16.0 parts by weight; particularly preferably in the range of from about 2.0 parts by weight to about 15.0 parts by weight; most preferably in the range of from about 2.5 parts by weight to about 12.0 parts by weight.

Further, according to another aspect of the present invention, the organochlorine-based compound which can be used as an insect repellent for the fiber masterbatch composition; for example, in some embodiments, may be, for example, α-worm mortal ( α-BHC), cis-Chlordane, Aldrin, β-worm (β-BHC), trans-Chlordane, Bifino ( Bifenox), Captafol, Captan, Chlorfluazuron, Chloropropylate, Chlorothalonil, Chlozolinate, Big smash (Dicloran), Dicofol, Dieldrin, Difenoconazole, Diniconazole, α-Endosulfan, Endrin, Fenmo Fenarimol, Hexaconazole, Iprodione, Lindane, Mirex, Myclobutanil, Penconazole, and pp' -DDE), DDT (pp'-DDT), Pretilachlor, Prochloraz, Procymidone, Propiconon, Pyridaben, Pyrifenox, Tetradifon, Triadimefon, Vinclozolin, δ-worm (δ-BHC), Heptachlor, Epoxy Heptachlor epoxide).

According to some specific embodiments, in the pest control fiber masterbatch composition of the present invention, the total content of the organochlorine-based compound contained in the insect repellent is not particularly limited as long as it does not violate or separate The spirit of the present invention and the insecticidal effect can be achieved. For example, the content of the organochlorine-based compound may be, for example, in the range of from about 0.5 part by weight to about 20.0 parts by weight relative to 100 parts by weight of the insecticidal fiber masterbatch composition; in some embodiments Preferably, it is in the range of from 1.0 part by weight to about 18.0 parts by weight; more preferably in the range of from about 1.5 parts by weight to 16.0 parts by weight; particularly preferably in the range of from about 2.0 parts by weight to about 15.0 parts by weight; most preferably It is in the range of from about 2.5 parts by weight to about 12.0 parts by weight.

According to some embodiments, the organophosphorus compound can be used as an insect repellent for the insecticidal fiber masterbatch composition of the present invention; for example, it can be Acephate, Valley Speed Azinphos-methyl, Bromophos-ethyl, Bromophos-methyl, Carbophenothion, Chlorpyrifos, Chlorpyrifos-methyl, Cyanofenphos, Demeton-s-methyl, Diazinon, Dichlorvos, Dimethoate, Disulfoton, Ditalimfos, Yipinsong (EPN), Ethion, Ethoprophos, Fenamiphos, Fenitrothion, Fensulfothion, Fenthion, Fonofos ), Formothion, Iprobenfos, Isoxathion, Malathion, Mephosfolan, Methacrifos, Methamidophos, Grams Kresoxim-methyl, Propaphos, Methidathion, American (Mevinphos), Monocrotophos, Omethoate, Parathion-ethyl, Parathion-methyl, Phenthoate, Phorate , Phosalone, Phosmet, Phosphamidon, Pirimiphos-ethyl, Pirimiphos-methyl, Propenophos, Prothiofos, Pyraclofos, Pyrazophos, Pyridaphenthion, Quinalphos, Salithion, Terbufos, Triazophos ), Trichlorfon, Vamidothion, Dicrotophos, Edifenphos, Etrimfos, Heptenophos, Isazofos, Isofenphos.

According to some specific embodiments, in the pest control fiber masterbatch composition of the present invention, the total content of the organophosphorus compound contained in the insect repellent is not particularly limited as long as it does not contradict or detach The spirit of the present invention and the insecticidal effect can be achieved. For example, the content of the organophosphorus compound may be, for example, in the range of from about 0.5 parts by weight to about 20.0 parts by weight relative to 100 parts by weight of the insecticidal fiber masterbatch composition; in some embodiments Preferably, it is in the range of from 1.0 part by weight to about 18.0 parts by weight; more preferably in the range of from about 1.5 parts by weight to 16.0 parts by weight; particularly preferably in the range of from about 2.0 parts by weight to about 15.0 parts by weight; most preferably It is in the range of from about 2.5 parts by weight to about 12.0 parts by weight.

According to some embodiments, the aminoformate compound which can be used as an insect repellent for the insecticidal fiber masterbatch composition of the present invention; for example, it can be 3-keto plus (3-keto carbofuran), 3-OH carbofuran, Aldicarb, Aldicarb sulfone, dexamethasone (dehydrogenate) Aldicarb sulfoxide), Bendiocarb, Butocarboxim, Carbaryl, Carbofuran, Fenobucarb, Pirimicarb, Thiobencarb ), Isoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Promecarb, Propoxur, Thiodicarb, XMC, Benfuracarb, Carbosulfan, Molinate.

According to some specific embodiments, in the pest control fiber masterbatch composition of the present invention, the total content of the carbamate compound contained in the insect repellent is not particularly limited as long as it is not It is possible to violate the spirit of the present invention and to achieve the pest control effect. For example, the content of the carbamate-based compound may be, for example, in the range of from about 0.5 part by weight to about 20.0 parts by weight relative to 100 parts by weight of the insecticidal fiber masterbatch composition; In the embodiment, it is preferably in the range of from 1.0 part by weight to about 18.0 parts by weight; more preferably in the range of from about 1.5 parts by weight to 16.0 parts by weight; particularly preferably in the range of from about 2.0 parts by weight to about 15.0 parts by weight; Most preferably in the range of from about 2.5 parts by weight to about 12.0 parts by weight.

In addition, compounds having insecticidal, insect-repellent, or insect-regulating properties may also be used in certain embodiments within the scope of the spirit of the invention; for example, for example, three-fortin may be used. (Trifluralin), Lufenuron, Benfluralin, Bromopropylate, Bupirimate, Butralin, Carbendazim, and 螨 丹Chinomethionat), Dichlofluanid, Dinitramine, Isoprothiolane, Thiabendazole, Chlorfenapyr, Alachlor, Bitertanol, Ding Butachlor, Acetamiprid, Clothianidin, Cyproconazole, Diphenamid, Fenazaquin, Fenpyroximate, Volt Flazasulfuron, Flufenoxuron, Flusilazole, Flutolanil, Flutriafol, Halfenprox, Haloxyfop-methyl ), Hexaflumuron, Hexythiazox, Easy Imibenconazole, Imidacloprid, Mefenacet, Mepronil, Metolachlor, Metribuzin, Napropamide, Nerimo Nuarimol), Oxadiazon, Paclobutrazol, Pencycuron, Pendimethalin, Propanil, Pyriproxyfen, Pyroquilon, Dickley (Tebuconazole), Tetraconazole, Triadimenol, Azoxystrobin, Cyazofamid, Dimethomorph, Indoxacarb, Oxycarboxin, Quizalofop-ethyl, Thiamethoxam, Trifloxystrobin, Triflumizole, 2,4-D, Bentazone, II Diflubenzuron, Fipronil, Tolfenpyrad, Teflubenzuron, Abamectin, Bensulfuron-methyl, Boscalid, Clomazone, Cyclosulfamuron, Famoxadone, Fluazif op-P-butyl), Fludioxonil, Metconazole, Propargite, Pyraclostrobin, Quinoxyfen, β-Endosulfan , pentachlorophenyl methyl sulfide, pentachloroaniline, drip (PP'-DDD), DDT (OP'-DDT), pentachloronitride (Quzene (PCNB)), sulfonate Endosulfan sulfate, Dithiocarbamates, Epoxiconazole, Fenbuconazole, Fenpropimorph, Fthalide, Oxadixyl , Oxyfluorfen, Hexazinone, Benthiazole, Carpropamid, Chlorantraniliprole, Clofentezine, Cyflumetofen, Gram Cymoxanil, Cyprodinil, Dimethenamid, Ethirimol, Etoxazole, Fenoxycarb, Flonicamid, Fluoride (Fluopicolide), beauty Metaflumizon, Spirodiclofen, Tebufenozide, Tebufenpyrad, Tepraloxydim, Thiaclocrid, Tricyclazole, Safford (Triforine), Methoxyfenozide, tomato auxin (4-CPA), Aachen, Benalaxyl, Benomyl, Bensulde, Bromuconazole , Buprofezin, Butylate, Cartap, Chlorobenzilate, Chlorthal, Chromafenozide, Clethodim, Ring Cycoxydim, Cyhalofop-butyl, Dalapon, Dazomet, Diafenthiuron, Diclomezine, Dinotefuran , Diuron, Emamectin benzoate, Ethephon, Ethiofencarb, Ethiprole, Ethoxyquin, Etofenprox, Fenbu (Fenbutatin oxide), Fenchlorphos, Fenoxycarb, Fuji Amine (Fluazinam), Formetanate, Fosetyl, Fosthiazate, Furametpyr, Glufosinate, Glyphosate, Ignite Imazalil), Imazapyr, Iminoctadine-triacetate, Isouron, Kasugamycin, Linuron, Mepanipyrim, Metazachlor, Paraquat, Penoxsulam, phlegm fever, Pyrimidifen, Quinclorac, Thiaclocrid, Thiophanate, Methyl Thiophanate methyl, Tridemorph, Maleic hydrazide, and derivatives thereof constitute at least one selected from the group, or a mixture thereof.

Further, in order to suppress or regulate the growth rate of the insect, an insect growth regulator may be further added to the insecticide contained in the insecticidal fiber masterbatch composition of the present invention. According to one aspect of the present invention, the insect growth regulator is not particularly limited. For example, it may be Erfulong, Liu Fulong, Yasulong, Qifenlong, Kefulong, Defulong, cloth. A mixture of Fenjing, Saigen, Defen, Balinepfen, and the like, and mixtures and derivatives thereof, constitute at least one selected from the group. According to some embodiments of the present invention, the insect growth regulator suitable for use in the present invention is preferably Erfulong, Liufulong, Yasulong, Qifenlong, Kefulong, Defulong; more preferably Use Fufulong, Liu Fulong, Yasulong, Qifenlong, or Kefulong; more preferably Erfulong, Liu Fulong, Yasulong, or Qiufenlong; Tejia is Erfulong, or Six Fulong.

According to some embodiments, the total content of the insect growth regulator contained in the insecticidal fiber masterbatch composition of the present invention is not particularly limited as long as it does not contradict or depart from the spirit of the present invention and can be achieved. The insecticidal effect may be within a range; for example, the insect growth regulator may be included in an amount of, for example, about 0.5 part by weight to about 15.0 parts by weight relative to 100 parts by weight of the insecticidal fiber masterbatch composition. The range; in some embodiments, preferably from about 1.0 part by weight to about 13.0 parts by weight; more preferably from about 1.5 parts by weight to 11.0 parts by weight; more preferably from about 2.0 parts by weight to A range of about 9.0 parts by weight; most preferably in the range of from about 2.5 parts by weight to about 7.0 parts by weight.

In addition, according to one aspect of the present invention, in some embodiments, in order to improve the antioxidant strength, light stability, ultraviolet resistance, and/or long-term insect resistance of the insect-repellent fiber, the present invention may also be used. The desired additive is further added to the insecticidal fiber masterbatch composition. The type and source of the additive are not particularly limited, and may be within the scope of the spirit of the present invention; for example, an antioxidant, a filler, and an anti-additive which are conventionally used in conventional fibers may be used. A UV agent, and a compound having a function of removing insects, preventing insects, or regulating insect growth.

According to one aspect of the present invention, in the insecticidal fiber masterbatch composition of the present invention, the antioxidant compound used as the additive is not particularly limited, and for example, it may be self-dodecanol Ester, ditetradecyl alcohol ester, bis-octadecyl alcohol ester, dicofyl thiodipropionate (DLTDP), 2 (2'-hydroxy-5'-methylphenyl) benzotriazole, 2-hydroxy-4-n-octyloxybenzophenone (HOBP), 2,6 di-tert-butyl-p-cresol (BHT), β(3,5-di-tert-butyl-4-hydroxyphenyl)propane Octadecyl acid ester, 1,1,3 tris(2-methyl-4hydroxy-5-tert-butylphenyl)butane, 1,3,5-trimethyl 2,4,6 tris (3,5 two tert-Butyl-4hydroxybenzyl)benzene, 2,2'-methylene bis(4-ethyl-6-tert-butylphenol) (MEB), N,N'-hexamethylenebis-3 (3, 5 di-tert-butyl-4-hydroxyphenyl)propanamide (HBP), 1,3,5-tris(3,5-tert-butyl-4-hydroxybenzyl)trimethylbenzene (TBM), 1, 3,5-tris(3,5-di-tert-butyl-4-hydroxyphenyl)isocyanate (TBHI), 4-hydroxydodecanoic acid anilide (HLS), 4-hydroxyoctadecanoic acid anilide ( HSS), 4,4'-thiobis(3-methyl-6-tert-butylphenol), 2,2'-methylene bis(4-methyl-6-tert-butyl) Phenol) (MMB), 4,4'-di-tert-octyldiphenylamine (DOD), 1,6-hexamethylenebis(3,5-di-tert-J-hydroxyphenyl)propionate (EBP) , tris(fluorenylphenyl)phosphite (TNP), tris(2,4-di-tert-butylphenyl)phosphite (TBP), dioctadecyl diphosphite pentaerythritol ester (DPD), four (2,4-di-tert-butylphenyl) 4,4'-biphenylene diphosphate, thiodipropionic acid dilaurate (DLTDP), N-salt fork-N'salicarp (SSE) , 1,2 bis(2-hydroxybenzhydrazide) oxime (BHH), N,N'-diethyl thiodipropyl hydrazide (DTD), derivatives thereof, and mixtures thereof At least one selected from the group.

In certain particular embodiments, the antioxidant is based on certain embodiments of the invention, and the antioxidant used as an additive is preferably self-dodecanol ester, ditetradecyl alcohol ester, double The octadecyl alcohol ester, bis-didecyl thiodipropionate (DLTDP), a derivative thereof, and a mixture thereof are at least one selected from the group; a suitable antioxidant is used from the double twelve A carbon alcohol ester, a tetradecyl alcohol ester, a bis-octadecyl alcohol ester, and a dimethyldidecyl thiodipropionate (DLTDP) constitute at least one selected from the group; more preferably a double twelve carbon Alcohol ester, ditetradecyl alcohol ester, or dodecyl thiodipropionate (DLTDP); particularly preferably using dodecyl alcohol ester or thiodipropionate (DLTDP) .

According to some specific embodiments, the total content of the antioxidant contained in the insecticidal fiber masterbatch composition of the present invention is not particularly limited as long as it does not contradict or deviate from the spirit of the present invention and can achieve pest control. Within the scope of the effect. For example, the antioxidant may be present in an amount ranging, for example, from about 0.01 parts by weight to about 5.00 parts by weight relative to 100 parts by weight of the insecticidal fiber masterbatch composition; in certain embodiments, It is preferably in the range of from about 0.05 parts by weight to about 4.00 parts by weight; more preferably in the range of from about 0.10 parts by weight to 3.00 parts by weight; particularly preferably in the range of from about 0.15 parts by weight to about 2.00 parts by weight; most preferably in the range of from about 0.15 parts by weight to about 2.00 parts by weight It is in the range of 0.20 parts by weight to about 1.00 parts by weight.

According to one aspect of the present invention, in the insecticidal fiber masterbatch composition of the present invention, the filler compound which can be used as the additive is not particularly limited, and for example, may be calcium carbonate (white peony), Nano-calcium carbonate, limestone, calcite, white-killed, Datian stone, carbon black, natural gas tank black, aeration tank black, shredded paper, wood flour, cotton shavings, α-cellulose, peanut shell, walnut shell, glass fiber , asbestos, clay, mica, muscovite, biotite, phlogopite, talc, calcium citrate (silver), hollow microspheres, diatomaceous earth, quartz, vermiculite, colloidal cerium oxide, hydrated cerium oxide, The gas phase cerium oxide, titanium dioxide (titanium dioxide), zinc oxide, antimony trioxide, metal powder, random polypropylene (APP), and mixtures thereof are at least one selected from the group consisting of.

According to some embodiments of the present invention, the filler used as an additive may be, for example, calcium carbonate (white peony), nano calcium carbonate, carbon black, wood flour, cotton swarf, alpha-cellulose, colloid. At least one selected from the group consisting of cerium oxide, hydrated cerium oxide, gas phase cerium oxide, titanium dioxide (titanium dioxide), metal powder, random polypropylene (APP), and mixtures and derivatives thereof; The filler suitable for use in the additive of the present invention preferably uses calcium carbonate (white peony), nano calcium carbonate, carbon black, wood flour, cotton swarf, α-cellulose, colloidal cerium oxide, hydrated cerium oxide, Gas phase cerium oxide, titanium dioxide (titanium dioxide), metal powder, or atactic polypropylene (APP); more preferably calcium carbonate (white peony), nano calcium carbonate, carbon black, wood powder, colloidal cerium oxide , hydrated cerium oxide, gas phase cerium oxide, titanium dioxide (titanium dioxide), metal powder, or atactic polypropylene (APP); particularly preferably used calcium carbonate (white peony), nano calcium carbonate, carbon black, wood Powder, colloidal cerium oxide, titanium dioxide (titanium dioxide), metal powder, or Atactic polypropylene (APP).

According to some specific embodiments, the total content of the filler contained in the insecticidal fiber masterbatch composition of the present invention is not particularly limited as long as it does not contradict or deviate from the spirit of the present invention and can achieve pest control. Within the scope of the effect. For example, the filler may be present in an amount ranging, for example, from about 0.5 parts by weight to about 15.0 parts by weight relative to 100 parts by weight of the insecticidal fiber masterbatch composition; in certain embodiments, Preferably, it is in the range of from about 1.0 part by weight to about 13.0 parts by weight; more preferably in the range of from about 1.5 parts by weight to 11.0 parts by weight; particularly preferably in the range of from about 2.0 parts by weight to about 9.0 parts by weight; most preferably in the range of from about 2.0 parts by weight to about 9.0 parts by weight; It is in the range of 2.5 parts by weight to about 7.0 parts by weight.

According to one aspect of the present invention, the anti-UV agent compound which can be used as the additive in the insecticidal fiber masterbatch composition of the present invention is not particularly limited, and for example, may be, for example, titanium dioxide (TiO2), 2 (2'-hydroxy-5'-methylphenyl)benzotriazole, 2-hydroxy-4-n-octyloxybenzophenone (HOBP), benzophenones, benzotriazoles, Zinc oxide (ZnO), cerium oxide, zirconium oxide, aluminum oxide, p-aminobenzoic acid (PABA), octyl dimethyl PABA, benzophenone compound, avobenzone, salicylate The compound, the cinnamate compound, and a mixture thereof are at least one selected from the group consisting of. According to some embodiments of the invention, the anti-UV agent used as an additive may be, for example, from titanium dioxide (TiO2), 2(2'-hydroxy-5'-methylphenyl)benzotriazole, 2 -hydroxy-4-n-octyloxybenzophenone (HOBP), benzophenones, benzotriazoles, zinc oxide (ZnO), cerium oxide, zirconium oxide, aluminum oxide, p-aminobenzoic acid (PABA), octyl dimethyl PABA, benzophenone compound, avobenzone, salicylate compound, cinnamic acid ester compound, and mixtures and derivatives thereof At least one of the selected ones.

According to some embodiments, the anti-UV agent contained in the additive of the present invention is preferably a benzophenone compound, a benzotriazole compound, titanium dioxide (TiO2), 2 (2'-hydroxy-5'- Methylphenyl)benzotriazole, 2-hydroxy-4-n-octyloxybenzophenone (HOBP), benzophenone compound, avobenzone, or salicylate More preferably, a benzophenone compound, a benzotriazole compound, titanium dioxide (TiO2), 2(2'-hydroxy-5'-methylphenyl)benzotriazole, 2-hydroxy-4-n -octyloxybenzophenone (HOBP), benzophenone compound, or avobenzone; particularly preferred for use of benzophenones, benzotriazoles, titanium dioxide (TiO2), 2 (2'-hydroxy-5'-methylphenyl)benzotriazole, 2-hydroxy-4-n-octyloxybenzophenone (HOBP), benzophenone compound, phorbolone ( Avobenzone), or a salicylate compound, and mixtures thereof, constitute at least one selected from the group.

According to some embodiments, the total content of the anti-UV agent contained in the insect-resistant fiber masterbatch composition of the present invention is not particularly limited as long as it does not contradict or depart from the spirit of the present invention and can achieve prevention. Within the scope of the insect effect. For example, the anti-UV agent may be included in an amount ranging, for example, from about 0.05 parts by weight to about 5.0 parts by weight relative to 100 parts by weight of the insecticidal fiber masterbatch composition; in certain embodiments, It is preferably in the range of from about 0.10 parts by weight to about 4.5 parts by weight; more preferably in the range of from about 0.15 parts by weight to 4.0 parts by weight; particularly preferably in the range of from about 0.20 parts by weight to about 3.5 parts by weight; most preferably It is in the range of about 0.25 parts by weight to about 3.0 parts by weight.

Further, according to still another aspect of the present invention, the insecticidal fiber masterbatch composition of the present invention can be further processed into a pest control fiber masterbatch by a granulator as needed. The kind and type of the granulator which can be used in the present invention are not particularly limited; for example, in some specific embodiments, for example, a calcium carbonate high-fill masterbatch granulator, a talc-filled masterbatch granulator can be used. Any one or a combination of a mica-filled masterbatch granulator, a wood flour-filled masterbatch granulator, a single-screw masterbatch granulator, a double-helical masterbatch granulator, and the like.

Further, according to other aspects of the present invention, the insecticidal fiber masterbatch composition of the present invention can be processed into a pest control fiber masterbatch by a granulator as needed, and then further subjected to a spinning process; for example, In some embodiments, it can be processed into single yarn, monofilament, double yarn, mixed yarn, short yarn, filament, etc.; or can be processed into various fabrics, for example, gauze, yarn bags, non-woven fabrics, Textile products such as gauze and gauze. Further, according to another aspect of the present invention, the masterbatch prepared from the insecticidal fiber masterbatch composition of the present invention is also suitably produced in materials such as PE, PP, PLA, TPU and the like. Further, according to still another aspect of the present invention, the fiber formed by the insecticidal fiber masterbatch composition of the present invention can be further processed with animal fibers, plant fibers, mineral fibers, natural fibers, semi-synthetic fibers, synthetic fibers, and regeneration. Any of the fibers such as fibers are blended together to form a variety of different textiles.

In the following, the embodiments of the present invention will be described in more detail in the detailed description of the embodiments of the present invention so that the spirit and content of the present invention are more complete and easy to understand; however, those of ordinary skill in the art should understand The invention is of course not limited to these examples, and other similar or equivalent functions and order of steps may be utilized to achieve the invention.

In addition, the scope of the invention may be further exemplified by the following specific examples, which are not intended to limit the scope of the invention. "Examples 1 to 4" "Preparation of insect-resistant fiber masterbatch"

First, the components constituting the insect-repellent fiber were blended at room temperature according to the blending ratio shown in Table 1, and the insecticidal fiber masterbatch compositions EC1 to EC4 of the invention were formulated. Next, the insecticidal fiber masterbatch compositions EC1 to EC4 were respectively introduced into a twin-screw granulator (Dechun Company Granulator, model: MS01T), and the extrusion temperature was controlled at 135 to 145 ° C to prepare a pest-proof fiber matrix. Grain EM1~EM4. "Spinning Preparation of Insect Fibers"

Then, the above-mentioned insect-resistant fiber masterbatch EM1~EM4 are respectively fed into an extrusion spinning machine with a screw output of 90N and a barrel and a head temperature maintained at 220 ° C to 235 ° C (Dechun company spinning) Yarn machine, model MS01Y×20), with a pulling roller speed of 20.5, 125, 180m/mm, and a ring blowing temperature of 30°C~40°C, a supply air temperature of 15°C~25°C, and a wind speed of 0.3~0.8m/s. The wind was cooled and molded to form a 0.15 mm insect-resistant polyethylene fiber monofilament, which was continuously woven into an insect-resistant gauze ES1~ES4 with a mesh of 0.2×0.2 mm. "Table 1" Comparative Example 1~4

First, in Comparative Examples 1 to 4, in addition to the constituent components in which the insect repellent was not added, the various components were sufficiently mixed at room temperature according to the blending ratio shown in Table 2 to prepare a fiber masterbatch composition of the comparative example. Then, the fiber master batches CM1 to CM4 were prepared by referring to the production methods of Examples 1 to 4, respectively. Then, the fiber mother particles produced as described above were continuously woven into the gauze frames CS1 to CS4 having a mesh size of 0.2 × 0.2 mm under the same conditions as in Examples 1 to 4. "Table 2" "Insect Resistance Test"

According to the WHO medicinal window curtain efficacy bioassay method (WHO 2005, Kasilia et al 2010), the specific test method is as follows. Insecticide efficacy test

Firstly, the insect-proof gauze ES1~ES4 obtained in the above embodiments 1~4 are respectively cut into six pieces of 25m*25cm insect-proof gauze ES5~ES28, and each gauze is used as a test unit. A total of six test units. Place the gauze flat on the acrylic plate and cover the funnel cone. Ten 3-5 day old, healthy Aedes aegypti were placed in the funnel and allowed to contact the gauze for 3 minutes. The mosquitoes were then transferred to a transparent acrylic cage and the cage was supplied with 10% syrup. The 60-minute knockdown (KD) rate of mosquitoes in the acrylic box and the 24-hour mortality rate were recorded.

Next, the gauze CS1~CS4 prepared in the above Comparative Examples 1 to 4 are respectively cut into six pieces of 25cm*25cm gauze CS5~CS28, and each gauze is used as a test unit, for a total of six tests. unit. Place the gauze flat on the acrylic plate and cover the funnel cone. Ten 3-5 day old, healthy Aedes aegypti were placed in the funnel and allowed to contact the gauze for 3 minutes. The mosquitoes were then transferred to a transparent acrylic cage and the cage was supplied with 10% syrup. The 60-minute knockdown (KD) rate of mosquitoes in the acrylic box and the 24-hour mortality rate were recorded. 2. Anti-washing test

Next, use the WHO to specify Savon de Marseille, a 1,000ml beaker, a 2,000ml beaker, and an adjustable shaker to clean the insect-resistant gauze ES5~ES28 and the gauze CS5~CS28.

When cleaning, first take 2 grams of Marseille soap dissolved in 500ml of water and heat to 30 °C. Another 2,000 ml beaker was placed, 400 ml of water was placed, and heated to 30 °C. Pour the dissolved soapy water into a 1,000 ml beaker and place the beaker in a 2,000 ml beaker. Insect gauze ES1~ES4 and gauze CS1~CS4 were placed in soapy water, incubated at 155 rpm for 10 minutes, washed and dried.

The washing test was washed every 24 hours, and the contact insecticidal efficacy test was carried out before washing, after washing for the first, fifth, ten, fifteen, and twenty times, and the test was washed a total of 20 times. For each 5 replicates, a total of 50 insects were tested for each time. The 60-minute knockdown (KD) and 24-hour mortality were recorded.

Next, the number, the number of stays, and the number of stays and the number of mosquitoes observed in the gauze CS5~CS28 are set to 100%, and the average number of mosquitoes in the insect-resistant gauze ES5~ES28 relative to the gauze CS5~CS28 is determined. The faint rate (%), the average mosquito mortality rate (%) measured at 24 hours, and the results are shown in Table 3.

"table 3"

According to the results shown in the above Table 3, it is understood that the insect-resistant gauze frames CS1 to CS4 made of the fiber masterbatch composition of the insect repellents of the present invention, which are not used in Comparative Examples 1 to 4, are examples. The insecticidal gauze ES1~ES6 made of the insecticidal fiber masterbatch composition of the present invention has an average smothering rate (%) of mosquitoes of up to 100%, and the average mortality rate (%) of mosquitoes is as high as 1~4. From 100% to 80%, it is apparent that Examples 1 to 4 have significantly superior and superior insecticidal effects over Comparative Examples 1 to 4. Therefore, it can be confirmed that the insecticidal fiber masterbatch composition of the present invention has an effect of reducing and preventing the insects from approaching and staying, and it is possible to achieve a reduction in the use of the insecticide and an effective insect control function. "Dust-proof effect test"

The insect-resistant gauze lines CS1 to ES4 obtained in the above-mentioned Examples 1 to 4 and the insect-resistant gauze frames CS1 to CS4 obtained in Comparative Examples 1 to 4 were each cut into six circular samples of diameter 4 cm and ES29. ~ES52, CS29~CS52 are placed in the dust mites terrarium, and the bait is disposed at the center of the circular sample. Ten thousand dust mites are placed around the circular sample at 25 ° C, 75 %RH, in a matte environment, allowed to stand for 24 hours for dust-proof effect test. During the test, the insect-resistant gauze ES29~ES52 was used as the sample group, and the gauze CS29~CS52 was used as the control group. At the end of the experiment, the number of live dust mites on the sample group and the control group were calculated, and the average value was obtained to obtain the average dust mites (Me) of the sample group and the average dust mites (Mc) of the control group, and then the following The dust mite repellent rate was obtained by the equation calculation, and the test results are shown in Table 4. Repellent rate (%) = [(Mc- Me)/ Mc] ✕100 where, Mc: the average number of dust mites in the control group; however, Mc should be at least greater than 1,000; Me: the average number of dust mites in the sample group.

"Table 4"

As shown in the above Table 4, it can be confirmed from the results of the dust mites effect test that the repellent rate of the insect nets ES29 to ES52 against dust mites is as high as 44.9% with respect to CS29 to CS52, that is, using the present invention. The insect-proof gauze made of the insect-resistant fiber masterbatch composition has an excellent dust-proof effect. Therefore, it was confirmed that the insecticidal fiber masterbatch composition of the present invention has an effect of reducing and preventing the proximity and retention of pest dust mites, and can achieve an insect-repellent function effectively.

In the above, the specific content of the present invention has been exemplified in the above embodiments, but those skilled in the art to which the present invention pertains should understand that the present invention is not limited to the embodiments, and does not deviate from Various changes and modifications can be made in the spirit and scope of the present invention; for example, the technical contents exemplified in the foregoing embodiments are combined or changed to become new embodiments, and such embodiments are of course regarded as the present invention. Its content. Therefore, the scope of protection to be covered in this case also includes the scope of the patent application described below and the scope defined by it.

Claims (10)

An insect-resistant fiber masterbatch composition comprising at least: a fiber constituting agent, an insect repellent, and an additive; wherein the insect repellent is a pyrethroid compound, an organic chlorine compound, an organic phosphorus compound, or an amine a base formate compound, a derivative thereof, and a mixture thereof, at least one selected from the group consisting of: an antioxidant, a filler, an anti-UV agent, and a mixture thereof, At least one selected; when the total amount of the woven mother particle composition is 100 parts by weight, the total content of the fiber constituting agent is in the range of about 50.0 parts by weight to about 95.0 parts by weight; the total of the insecticide The content is in the range of from about 1.0 part by weight to about 45.0 parts by weight; and the total content of the antioxidant contained in the additive is in the range of from about 0.01 part by weight to about 5.00 part by weight, and the content of the filler is It is in the range of from about 0.5 parts by weight to about 15.0 parts by weight; the anti-UV agent is included in the range of from about 0.05 parts by weight to about 5.00 parts by weight. The insecticidal fiber masterbatch composition as claimed in claim 1, wherein the fiber constituting agent is derived from ABS resin (ABS), epoxy resin (EPOXY), polyester (Polyester), polybutylene terephthalate ( PBT), propylene glycol phthalate (PTT), polyacrylonitrile (PAN), polydecylamine (PA), polyacrylic acid (PAA), polyamidimide (PAI), polybutene (PB), poly Benzimidazole (PBI), polybenzoxazole (PBO), polybenzothiazole (PBTh), polycarbonate (PC), polyethylene (PE), polyetheretherketone (PEEK), polyterephthalic acid Ethylene glycol (PET), phenolic resin (PF), high-coefficient polyethylene (HMPE), polyimine (PI), polyisobutylene (PIB), polylactic acid (PLA), polymethyl methacrylate (PMMA) Polyacetal (POM), polypropylene (PP), polyphenylene sulfide (PPS), polystyrene (PS), polyfluorene (PSF), plastic starch (PSM), polytetrafluoroethylene (PTFE), Polyurethane (PU), polyvinyl alcohol (PVA), polyvinyl chloride (PVC), polyvinylidene fluoride (PVDF), butadiene rubber (BR), styrene butadiene rubber (SBR), nitrile rubber (NBR) ), neoprene (CR), butadiene rubber, ethylene propylene rubber, polysulfide rubber, acrylate rubber, fluororubber, enamel rubber (SP.SI), butyl rubber (IIR), isoprene rubber, acetic acid, three Triacetate, Polyamide, Polypropylene, Polyester (Daikelun), Nylon (Nylon/Nylon), Nylon 6 (Nylon 6), Nylon 6.6, Nylon 11, Acrylic, Chlorine Polyurethane, vinylon, spandex, keflon, and mixtures thereof are at least one selected from the group consisting of. The insecticidal fiber masterbatch composition as claimed in claim 1, wherein the pyrethroid compound contained in the insecticide is derived from Alphacypermethrin, Bifenthrin, Cyfluthrin. , Cyhalothrin, Cypermethrin (also known as Cypermethin), deltamethrin (also known as Ding Ning), Esfenvalerate Fenvalerate, escort Flucythrinate, Fluvalinate, Permethrin, Allethrin, Tetramethrin, Fenpropathrin, and a mixture of these selected from the group At least one of them. The insecticidal fiber masterbatch composition as claimed in claim 1, wherein the insecticide further comprises from the group of Fufulong, Liu Fulong, Yasulong, Qifenlong, Kefulong, Defulong, and cloth. The mixture of fentanyl, chlorpyrifos, fentanyl, baclipren, and the like constitutes at least one insect growth regulator selected in the group. The insecticidal fiber masterbatch composition as claimed in claim 1, wherein the antioxidant used as an additive is from dodecyl alcohol ester, ditetradecyl alcohol ester, distearyl alcohol ester, 2 ( 2'-hydroxy-5'-methylphenyl)benzotriazole, 2-hydroxy-4-n-octyloxybenzophenone (HOBP), 2,6 di-tert-butyl-p-cresol (BHT) , octadecyl β(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate, 1,1,3 tris(2-methyl-4hydroxy-5-tert-butylphenyl)butane, 1 , 3,5 trimethyl 2,4,6 tris(3,5 di-tert-butyl-4 hydroxybenzyl)benzene, 2,2'-methylene bis(4-ethyl-6-tert-butylphenol) MEB), N, N'-hexamethylenebis-3(3,5-di-tert-butyl-4-hydroxyphenyl)propanamide (HBP), 1,3,5-tris (3,5-tert-butyl) 4--4-hydroxybenzyl)trimethylbenzene (TBM), 1,3,5-tris(3,5-di-tert-butyl-4-hydroxyphenyl)isocyanate (TBHI), 4-hydroxydodecanoic acid Anthraquinone (HLS), 4-hydroxyoctadecanoic acid anilide (HSS), 4,4'-thiobis(3-methyl-6-tert-butylphenol), 2,2'-methylene Bis(4-methyl-6-tert-butylphenol) (MMB), 4,4'-di-tert-octyldiphenylamine (DOD), 1,6 hexamethylene bis (3,5 di-tert-J-) 4-hydroxyphenyl)propionate (EBP), three ( Phenyl phenyl) phosphite (TNP), tris(2,4-di-tert-butylphenyl) phosphite (TBP), dioctadecyl diphosphite pentaerythritol ester (DPD), four (2, 4 -di-tert-butylphenyl) 4,4'-biphenyl diphosphate, thiodipropionic acid dilaurate (DLTDP), N-salt fork-N'salicarp (SSE), 1,2 Bis(2-hydroxybenzhydrazide) oxime (BHH), N,N'-diethyl thiodipropyl hydrazide (DTD), derivatives thereof, and mixtures thereof are selected from the group At least one of them. The insecticidal fiber masterbatch composition according to claim 1, wherein the filler used as an additive is derived from carbon black, cellulose, silicate, cerium oxide, metal oxide, Calcium carbonates, nanocalcium carbonates, derivatives thereof, and mixtures thereof constitute at least one selected from the group. The insecticidal fiber masterbatch composition as claimed in claim 1, wherein the filler used as an additive is self-calcium carbonate (white peony), limestone, calcite, white smear, daejeon stone, carbon black, natural gas tank black. , aeration tank black, shredded paper, wood powder, cotton shavings, α-cellulose, peanut shell, walnut shell, glass fiber, asbestos, clay, mica, muscovite, biotite, phlogopite, talc, calcium citrate矽石石), hollow microspheres, diatomaceous earth, quartz, vermiculite, colloidal cerium oxide, hydrated cerium oxide, gas phase cerium oxide, titanium dioxide (titanium dioxide), zinc oxide, antimony trioxide, metal powder A random polypropylene (APP), and a mixture thereof, constitute at least one selected from the group. The insecticidal fiber masterbatch composition as claimed in claim 1, wherein the anti-UV agent compound used as an additive is derived from titanium oxide (TiO2), zinc oxide (ZnO), cerium oxide, zirconium oxide, aluminum oxide, P-aminobenzoic acid (PABA), octyl dimethyl PABA, benzophenones, benzophenones, benzotriazoles, avobenzone, salicylate, cinnamon The acid ester compounds and mixtures thereof constitute at least one selected from the group. The insecticidal fiber masterbatch composition as claimed in claim 1, further comprising cotton, kapok, flax, jute, hemp, castor, manila hemp, kenaf, New Zealand hemp, pineapple in the fiber constituting agent. Fiber, coconut fiber, rush, sheep wool, camel hair, camel wool, cashmere, mohair, mountain wool, silk, wild silk, asbestos, fiberglass, metal fiber, rock fiber, slag fiber, protein fiber, cheese Plain fiber, peanut fiber, soybean fiber, corn fiber, polylactic acid fiber, bamboo carbon fiber, mucilage, copper ammonia, new solvent cellulose fiber, chitin fiber, and a mixture thereof, selected from the group At least one. The insecticidal fiber masterbatch composition as claimed in claim 1, which is used for fabricating a single yarn, a monofilament, a double yarn, a mixed yarn, a short yarn, a filament having an insect control function; and/or Manufacture of textile products with gauze, yarn bags, non-woven fabrics, gauze and yarn sleeves with insect-proof functions.