TW201725291A - Composite fabrics - Google Patents

Composite fabrics Download PDF

Info

Publication number
TW201725291A
TW201725291A TW105139051A TW105139051A TW201725291A TW 201725291 A TW201725291 A TW 201725291A TW 105139051 A TW105139051 A TW 105139051A TW 105139051 A TW105139051 A TW 105139051A TW 201725291 A TW201725291 A TW 201725291A
Authority
TW
Taiwan
Prior art keywords
textile
weight
parts
composite
powder
Prior art date
Application number
TW105139051A
Other languages
Chinese (zh)
Other versions
TWI623658B (en
Inventor
黃泳彬
李君敏
葉佩宜
李榮哲
Original Assignee
財團法人工業技術研究院
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 財團法人工業技術研究院 filed Critical 財團法人工業技術研究院
Publication of TW201725291A publication Critical patent/TW201725291A/en
Application granted granted Critical
Publication of TWI623658B publication Critical patent/TWI623658B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61—Polyamines polyimines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/281—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/08—Processes in which the treating agent is applied in powder or granular form
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Disclosed is a composite fabric includes a fabric substrate and a material layer. The material layer including a mixture is on the fabric substrate. The mixture includes an amine containing polymer and a powder. The powder is dispersed in the amine containing polymer. The amine containing polymer includes polyethylenimine, derivatives of polyethylenimine or a combination thereof. The powder includes doped zinc oxide, indium tin oxide, doped indium tin oxide or a combination thereof. The amine containing polymer has an amount of 0.1 to 40 parts by weight relative to 100 parts by weight of the powder.

Description

複合紡織品 Composite textile

本發明係關於複合紡織品。 The present invention relates to composite textiles.

一般而言，以毛、棉或化學纖維等材質為例，要提升保暖效果，通常需使用經緯密度高的織物或增加織物的厚度，但是這些方式會使得紡織成品的透氣性變差且重量增加。因此，發展提升保暖效果的織物，使得使用者穿著相對少量的衣物便能獲得足夠的保暖效果，提升行動便利性，是時勢所趨。 Generally speaking, in the case of materials such as wool, cotton or chemical fiber, in order to improve the warmth effect, it is usually necessary to use a fabric having a high warp density or to increase the thickness of the fabric, but these methods may deteriorate the gas permeability of the finished textile product and increase the weight. . Therefore, the development of fabrics that enhance the warmth effect, so that the user can obtain sufficient warmth effect by wearing a relatively small amount of clothes, and improve the convenience of movement, is the trend of the times.

本發明揭示一種複合紡織品，包括紡織物基材；以及材料層，形成於該紡織物基材之上，該材料層包括一混合物，該混合物包括，含胺基(amine)的高分子以及一粉體，其中該含胺基的高分子包括聚乙烯亞胺(polyethylenimine)、或聚乙烯亞胺之衍生物，該聚乙烯亞胺之衍生物包括末端具乙氧基(ethoxyl group)之聚乙烯亞胺、末端具羧酸基(carboxylic acid group)之聚乙烯亞胺、末端具異氰酸酯基(isocyanate group)之聚乙烯亞胺或上述之組合，該粉體分散於該含胺基的高分子之中，該粉體包括具有摻雜元素的氧化鋅、銦錫氧化物、具有摻雜元素的銦錫氧化物或上述之組合，其中以100重量份之該粉 體為基準，該含胺基的高分子為0.1至40重量份。 The present invention discloses a composite textile comprising a textile substrate; and a material layer formed on the textile substrate, the material layer comprising a mixture comprising an amine-containing polymer and a powder And the amine-containing polymer comprises a polyethylenimine or a derivative of polyethyleneimine, and the derivative of the polyethyleneimine comprises a polyethylene having an ethoxyl group at the end. An amine, a polyethyleneimine having a carboxylic acid group at the end, a polyethyleneimine having an isocyanate group at the end, or a combination thereof, the powder being dispersed in the amine-containing polymer The powder includes zinc oxide having a doping element, indium tin oxide, indium tin oxide having a doping element, or a combination thereof, wherein the powder is 100 parts by weight The amine group-containing polymer is used in an amount of 0.1 to 40 parts by weight based on the body.

本發明提供一種複合紡織品，由於複合紡織品包含紡織物基材與形成於紡織物基材之上的材料層，材料層包括一混合物，混合物包括含胺基(amine)的高分子以及粉體，使複合紡織品可具有良好的紅外線吸收率與照光溫升的功效。 The present invention provides a composite textile, wherein the composite textile comprises a textile substrate and a material layer formed on the textile substrate, the material layer comprises a mixture, and the mixture comprises an amine-containing polymer and a powder. Composite textiles can have good infrared absorption rate and illumination temperature rise.

根據本發明實施例，將混合物中之粉體分散於含胺基的高分子與溶劑之中，形成膠體混合物，將膠體混合物塗布在紡織物基材上，經乾燥後得到複合紡織品。上述乾燥過程可達到減少或去除溶劑。根據本發明實施例，將膠體混合物塗布在紡織物基材上，可能使膠體混合物部分滲入紡織物基材，形成複合層，複合層位於紡織物基材與材料層之間，該複合層包括部分該混合物以及部分該紡織物基材。亦可使膠體混合物幾乎不滲入紡織物基材，因此材料層位於紡織物基材之表面。可視需求調整膠體混合物之加工性以形成或不形成複合層。 According to an embodiment of the present invention, the powder in the mixture is dispersed in the amine-containing polymer and the solvent to form a colloidal mixture, and the colloidal mixture is coated on the textile substrate, and dried to obtain a composite textile. The above drying process can achieve the reduction or removal of solvent. According to an embodiment of the invention, coating the colloidal mixture on the textile substrate may partially penetrate the colloidal mixture into the textile substrate to form a composite layer between the textile substrate and the material layer, the composite layer comprising a portion The mixture and a portion of the textile substrate. It is also possible to make the colloidal mixture hardly penetrate into the textile substrate, so that the material layer is located on the surface of the textile substrate. The processability of the colloidal mixture can be adjusted as needed to form or not form a composite layer.

根據本發明實施例，添加至少一種高分子基質於膠體混合物中，形成混合溶液，將此混合溶液覆蓋於離型基材(例如離型紙)上，覆蓋的方法例如塗布，經乾燥後得到膜材，將膜材轉移至紡織物基材上，製得複合紡織品，複合紡織品中組成物位於紡織物基材之上。上述乾燥過程可達到減少或去除溶劑。上述轉移的方法可以是熱壓貼合(溫度約60℃至150℃) 到紡織物基材上。 According to an embodiment of the present invention, at least one polymer matrix is added to the colloidal mixture to form a mixed solution, and the mixed solution is coated on a release substrate (for example, a release paper), and the covering method is, for example, coating, and drying to obtain a film. The film is transferred to a textile substrate to produce a composite textile in which the composition is located on the textile substrate. The above drying process can achieve the reduction or removal of solvent. The above transfer method may be a thermocompression bonding (temperature of about 60 ° C to 150 ° C) Onto the textile substrate.

根據本發明實施例，粉體可以是具有摻雜元素的氧化鋅(doped zinc oxide)、銦錫氧化物(indium tin oxide)、具有摻雜元素的銦錫氧化物(doped indium tin oxide)或上述之組合。摻雜元素包括IIIB族元素(例如鎵、鋁或上述之組合)、鐵、或上述之組合，於具有摻雜元素的氧化鋅粉體中，以100重量份之氧化鋅為基準，摻雜元素約為0.1至20重量份(例如約為1至6重量份)。若摻雜元素太少則可能造成紅外線吸收率與照光溫升效果不足。粉體的粒徑可視需求選擇，例如約為10nm至200nm。粉體的使用量可視需求調整，例如以100重量份之紡織物基材為基準，粉體可約為0.1至15重量份(例如約為1至10重量份)，若粉體太多則容易造成複合紡織品中的材料層之耐洗強度降低，若粉體太少則容易造成複合紡織品的紅外線吸收率與照光溫升效果降低。 According to an embodiment of the present invention, the powder may be a doped zinc oxide having a doping element, an indium tin oxide, a doped indium tin oxide having a doping element, or the like. The combination. The doping element includes a group IIIB element (for example, gallium, aluminum or a combination thereof), iron, or a combination thereof, and is doped with zinc oxide powder having a doping element based on 100 parts by weight of zinc oxide. It is about 0.1 to 20 parts by weight (for example, about 1 to 6 parts by weight). If the doping element is too small, the infrared absorption rate and the illumination temperature increase effect may be insufficient. The particle size of the powder may be selected as desired, for example, from about 10 nm to 200 nm. The amount of the powder to be used may be adjusted as needed. For example, the powder may be about 0.1 to 15 parts by weight (for example, about 1 to 10 parts by weight) based on 100 parts by weight of the textile substrate, and if the powder is too much, it is easy. The washing strength of the material layer in the composite textile is lowered, and if the powder is too small, the infrared absorption rate and the temperature rising effect of the composite textile are likely to be lowered.

根據本發明實施例，含胺基的高分子可以是聚乙烯亞胺(polyethylenimine)或聚乙烯亞胺之衍生物，上述聚乙烯亞胺或聚乙烯亞胺之衍生物的型態可以是線性(linear)、分枝狀(branched)、樹枝狀(dendrimer)或上述之組合。聚乙烯亞胺之衍生物可以是末端具乙氧基(ethoxyl group)之聚乙烯亞胺、末端具羧酸基(carboxylic acid group)之聚乙烯亞胺、末端具異氰酸酯基(isocyanate group)之聚乙烯亞胺或上述之組合。含胺基的高分子之重量平均分子量約為500至100000(例如約為1500至12000)。若重量平均分子量太大則容易造成膠體混合物黏度太高，若重量平均分子量太小則可能造成粉體容易沉降。根據 本發明實施例，以100重量份之粉體為基準，含胺基的高分子約為0.1至40重量份(例如約為1至20重量份)。若含胺基的高分子太多，則容易造成膠體混合物黏度太高，若含胺基的高分子太少，則可能造成粉體容易沉降。 According to an embodiment of the present invention, the amine group-containing polymer may be a derivative of polyethylenimine or polyethyleneimine, and the type of the above polyethyleneimine or polyethyleneimine derivative may be linear ( Linear), branched, dendrimer or a combination of the above. The derivative of polyethyleneimine may be a polyethyleneimine having an ethoxyl group at the end, a polyethyleneimine having a carboxylic acid group at the end, and a polyisocyanate group at the end. Ethyleneimine or a combination thereof. The amine group-containing polymer has a weight average molecular weight of about 500 to 100,000 (e.g., about 1,500 to 12,000). If the weight average molecular weight is too large, the viscosity of the colloidal mixture is likely to be too high, and if the weight average molecular weight is too small, the powder may be easily settled. according to In the embodiment of the present invention, the amine group-containing polymer is about 0.1 to 40 parts by weight (e.g., about 1 to 20 parts by weight) based on 100 parts by weight of the powder. If the amount of the amine-containing polymer is too large, the viscosity of the colloidal mixture is likely to be too high. If the amount of the amine-containing polymer is too small, the powder may be easily settled.

根據本發明實施例，溶劑可以使用二甲基乙醯胺(dimethylacetamide)、二甲基甲醯胺(dimethylformamide)二甲基亞碸(dimethyl sulfoxide)、或上述之組合，以100重量份之膠體混合物為基準，溶劑可為20至90重量份。若溶劑太多則膠體混合物中之粉體容易沉降，若溶劑太少則可能影響膠體混合物在塗布製程中的加工性。 According to an embodiment of the present invention, the solvent may be dimethylacetamide, dimethylformamide dimethyl sulfoxide, or a combination thereof, in an amount of 100 parts by weight of a colloidal mixture. The solvent may be 20 to 90 parts by weight based on the standard. If the solvent is too much, the powder in the colloidal mixture is likely to settle, and if the solvent is too small, the workability of the colloidal mixture in the coating process may be affected.

根據本發明實施例，膠體混合物之膠體平均粒徑約為150nm至390nm，界面電位(zeta potential)約為7mV至20mV。若膠體平均粒徑太大則容易造成膠體混合物中膠體的分散不均勻及不穩定。若界面電位太小則容易造成膠體混合物中膠體的分散不穩定。 According to an embodiment of the invention, the colloidal mixture has a colloidal average particle size of about 150 nm to 390 nm and an zeta potential of about 7 mV to 20 mV. If the average particle size of the colloid is too large, the dispersion of the colloid in the colloidal mixture is likely to be uneven and unstable. If the interface potential is too small, the dispersion of the colloid in the colloidal mixture is liable to be unstable.

根據本發明實施例，高分子基質可以使用聚氨酯(polyurethane)、聚丙烯酸酯(polyacrylate)或上述之組合，以100重量份之粉體為基準，高分子基質可為50至10000重量份(例如約為100至1000重量份)。 According to an embodiment of the present invention, the polymer matrix may be a polyurethane, a polyacrylate or a combination thereof, and the polymer matrix may be 50 to 10,000 parts by weight based on 100 parts by weight of the powder (for example, about It is 100 to 1000 parts by weight).

根據本發明實施例，紡織物基材可以是聚乙烯纖維布、聚丙烯纖維布、聚醯胺纖維布、聚酯纖維布、棉纖維布、嫘縈纖維布、醋酸纖維布、毛纖維布或前述之組合。 According to an embodiment of the present invention, the textile substrate may be a polyethylene fiber cloth, a polypropylene fiber cloth, a polyamide fiber cloth, a polyester fiber cloth, a cotton fiber cloth, a crepe fiber cloth, an acetate fiber cloth, a wool fiber cloth or Combination of the foregoing.

根據本發明實施例，複合紡織品對於波長約在780nm以上(例如1,000nm至2,500nm)的紅外線具有吸收能 力。 According to an embodiment of the invention, the composite textile has an absorption energy for infrared rays having a wavelength of about 780 nm or more (for example, 1,000 nm to 2,500 nm). force.

在本發明之實施例中，上述複合紡織品還可以透過紡織物基材的選擇而具有其他功能，例如抗紫外線、抗菌、抗靜電、陽離子可染、高氨價低溫可染、異形斷面吸濕排汗或中空保暖等功能。 In the embodiment of the present invention, the composite textile can also have other functions through the selection of the textile substrate, such as anti-ultraviolet, antibacterial, antistatic, cationic dyeable, high ammonia low temperature dyeable, profiled cross section moisture absorption. Features such as perspiration or hollow warmth.

為了讓本發明之上述和其他目的、特徵、和優點能更明顯易懂，下文特舉數實施例配合所附圖示，作詳細說明如下： The above and other objects, features, and advantages of the present invention will become more apparent and understood.

【膠體混合物】 [colloidal mixture]

實施例1 Example 1

將100克摻雜鎵之氧化鋅(gallium doped zinc oxide)(Ga/Zn=5.0wt%)分散於5克聚乙烯亞胺(重量平均分子量約為10000)與400克二甲基乙醯胺溶液中形成膠體混合物，粒徑分析測得膠體平均粒徑約為199.5nm，界面電位約為15mV。在室溫下觀察其穩定性，約可維持溶液態至少2小時，甚至達6小時。 100 g of gallium doped zinc oxide (Ga/Zn = 5.0 wt%) was dispersed in 5 g of polyethyleneimine (weight average molecular weight of about 10,000) and 400 g of dimethylacetamide solution A colloidal mixture was formed, and the particle size analysis showed that the colloidal average particle diameter was about 199.5 nm, and the interface potential was about 15 mV. The stability was observed at room temperature, and the solution state was maintained for at least 2 hours, even up to 6 hours.

實施例2 Example 2

將100克摻雜鎵之氧化鋅(Ga/Zn=5.0wt%)分散於5克聚乙烯亞胺(重量平均分子量約為1800)與400克二甲基乙醯胺溶液中形成膠體混合物，粒徑分析測得膠體平均粒徑約為310.8nm，界面電位約為11mV。在室溫下觀察其穩定性，約可維持溶液態至少2小時，甚至達6小時。 100 g of gallium-doped zinc oxide (Ga/Zn = 5.0 wt%) was dispersed in 5 g of polyethyleneimine (weight average molecular weight of about 1800) and 400 g of dimethylacetamide solution to form a colloidal mixture, The diameter analysis showed that the average colloidal particle diameter was about 310.8 nm, and the interface potential was about 11 mV. The stability was observed at room temperature, and the solution state was maintained for at least 2 hours, even up to 6 hours.

比較例1 Comparative example 1

將100克摻雜鎵之氧化鋅(Ga/Zn=5.0wt%)分散於5克聚丙 烯酸(polyacrylic acid)(重量平均分子量約為8000)與400克二甲基乙醯胺溶液中形成膠體混合物，粒徑分析測得膠體平均粒徑約為227.7nm，界面電位約為4.8mV。在室溫下觀察其穩定性，約在2小時內凝聚形成果凍狀(gelled)，不利加工。 Disperse 100 grams of gallium-doped zinc oxide (Ga/Zn = 5.0 wt%) in 5 grams of polypropylene A colloidal mixture was formed in a polyacrylic acid (weight average molecular weight of about 8,000) and 400 g of dimethylacetamide solution, and the particle size analysis showed that the colloidal average particle diameter was about 227.7 nm, and the interface potential was about 4.8 mV. The stability was observed at room temperature, and it formed a jelly shape within about 2 hours, which was unfavorable.

比較例2 Comparative example 2

將20克摻雜鎵之氧化鋅(Ga/Zn=5.0wt%)分散於1克油醯基磷酸酯(oleyl phosphate)與80克二甲基乙醯胺溶液中形成膠體混合物，粒徑分析測得膠體平均粒徑約為493.5nm，界面電位約為2.2mV。在室溫下觀察其穩定性，約在2小時內凝聚形成果凍狀，不利加工。 20 g of gallium-doped zinc oxide (Ga/Zn=5.0 wt%) was dispersed in 1 g of oleyl phosphate and 80 g of dimethylacetamide solution to form a colloidal mixture. The gel has an average particle size of about 493.5 nm and an interface potential of about 2.2 mV. The stability was observed at room temperature, and it formed a jelly in about 2 hours, which was unfavorable.

比較例3 Comparative example 3

將20克摻雜鎵之氧化鋅(Ga/Zn=5.0wt%)分散於1克油胺(oleylamide)與80克二甲基乙醯胺溶液中形成膠體混合物，粒徑分析測得膠體平均粒徑約為642.5nm，界面電位約為5.0mV。在室溫下觀察其穩定性，約在2小時內凝聚形成果凍狀，不利加工。 20 g of gallium-doped zinc oxide (Ga/Zn=5.0 wt%) was dispersed in 1 g of oleylamide and 80 g of dimethylacetamide solution to form a colloidal mixture, and the colloidal average particle was determined by particle size analysis. The diameter is about 642.5 nm and the interface potential is about 5.0 mV. The stability was observed at room temperature, and it formed a jelly in about 2 hours, which was unfavorable.

比較例4 Comparative example 4

將20克摻雜鎵之氧化鋅(Ga/Zn=5.0wt%)分散於1克二甲基乙醯胺溶液中，粒徑分析測得平均粒徑約為645.7nm，界面電位約為9.8mV。在室溫下觀察其穩定性，約在2小時內凝聚形成果凍狀，不利加工。 20 g of gallium-doped zinc oxide (Ga/Zn = 5.0 wt%) was dispersed in 1 g of dimethylacetamide solution, and the average particle diameter of the particle size analysis was about 645.7 nm, and the interface potential was about 9.8 mV. . The stability was observed at room temperature, and it formed a jelly in about 2 hours, which was unfavorable.

由表1可知，添加含胺基的高分子可使膠體混合物之膠體平均粒徑約為150nm至390nm，且界面電位約為7mV至20mV，以達到膠體在膠體混合物中比較穩定的效果，有利於加工。 It can be seen from Table 1 that the addition of the amine group-containing polymer allows the colloidal mixture to have a colloidal average particle diameter of about 150 nm to 390 nm and an interfacial potential of about 7 mV to 20 mV, so as to achieve a relatively stable effect of the colloid in the colloidal mixture, which is advantageous. machining.

【複合紡織品】 【Composite Textiles】

實施例3 Example 3

將200克摻雜鋁的氧化鋅(aluminum doped zinc oxide)粉體(Al/Zn=0.4wt%)分散於6克聚乙烯亞胺(polyethylenimine)(重量平均分子量約為1,800)與800克二甲基亞碸(dimethyl sulfoxide)溶液中形成膠體混合物，粒徑分析測得膠體平均粒徑約為240nm。測試其界面電位(zeta potential)約為12mV。 200 g of aluminum-doped zinc oxide powder (Al/Zn = 0.4 wt%) was dispersed in 6 g of polyethylenimine (weight average molecular weight of about 1,800) and 800 g of dimethyl A colloidal mixture was formed in the dimethyl sulfoxide solution, and the particle size analysis determined that the colloidal average particle diameter was about 240 nm. The zeta potential was tested to be about 12 mV.

將此膠體混合物利用刮刀塗佈在聚乙二醇對苯二甲酸酯纖維布之紡織物基材上，經乾燥後，得到複合紡織品，測得摻雜鋁的氧化鋅粉體約佔紡織物基材重量的0.15wt%。將該複合紡織品進行TN-037規範之照光溫升試驗，其溫度高於未塗布膠體混合物的紡織物基材約2.1℃。進行紅外線吸收率試驗(測試波長約1,000nm至2,500nm)，其吸收率高於未塗布膠體混合物的紡織物基材約9%。其數據如表2所列。 The colloidal mixture is coated on a textile substrate of polyethylene terephthalate fiber cloth by a doctor blade, and after drying, a composite textile is obtained, and the aluminum oxide-doped zinc oxide powder is determined to be about the textile fabric. The weight of the substrate was 0.15 wt%. The composite textile was subjected to the TN-037 specification illumination temperature rise test at a temperature of about 2.1 ° C higher than the textile substrate of the uncoated colloidal mixture. An infrared absorption test (test wavelength of about 1,000 nm to 2,500 nm) was carried out, and the absorption rate was higher than that of the woven substrate of the uncoated colloidal mixture by about 9%. The data is listed in Table 2.

實施例4 Example 4

將200克摻雜鎵之氧化鋅(gallium doped zinc oxide)(Ga/Zn=5.0wt%)分散於20克聚乙烯亞胺(重量平均分子量約為10,000)與800克二甲基乙醯胺(dimethylacetamide)溶液中形成膠體混合物，粒徑分析測得膠體平均粒徑約為199nm。測試其界面電位約為15mV。 200 g of gallium doped zinc oxide (Ga/Zn = 5.0 wt%) was dispersed in 20 g of polyethyleneimine (weight average molecular weight of about 10,000) and 800 g of dimethylacetamide ( A colloidal mixture was formed in the dimethylacetamide solution, and the particle size analysis determined that the colloidal average particle diameter was about 199 nm. The interface potential was tested to be approximately 15 mV.

將此膠體混合物利用刮刀塗布在尼龍纖維布之紡織物基材上，經乾燥後，得到複合紡織品，測得摻雜鎵的氧化鋅粉體約佔紡織物基材重量的1.5wt%。將該複合紡織品進行TN-037規範之照光溫升試驗，其溫度高於未塗佈膠體混合物的紡織物基材約5.7℃。進行紅外線吸收率試驗(測試波長約1,000nm至2,500nm)，其吸收率高於未塗布膠體混合物的紡織物基材約14%。其數據如表2所列。 The colloidal mixture was coated on a textile substrate of nylon fiber cloth by a doctor blade, and after drying, a composite textile was obtained, and the gallium-doped zinc oxide powder was found to be about 1.5 wt% of the weight of the textile substrate. The composite textile was subjected to the TN-037 specification illumination temperature rise test at a temperature of about 5.7 ° C higher than the textile substrate of the uncoated colloidal mixture. The infrared absorption test (test wavelength of about 1,000 nm to 2,500 nm) was carried out, and the absorption rate was higher than that of the textile substrate of the uncoated colloidal mixture by about 14%. The data is listed in Table 2.

實施例5 Example 5

將100克摻雜鎵之氧化鋅(Ga/Zn=0.5wt%)分散於15克聚乙烯亞胺(重量平均分子量約為10,000)與150克二甲基乙醯胺溶液中形成膠體混合物，粒徑分析測得膠體平均粒徑約為310nm。測試界面電位約為9mV。 100 g of gallium-doped zinc oxide (Ga/Zn = 0.5 wt%) was dispersed in 15 g of polyethyleneimine (weight average molecular weight of about 10,000) and 150 g of dimethylacetamide solution to form a colloidal mixture, The diameter analysis determined that the colloidal average particle size was about 310 nm. The test interface potential is approximately 9 mV.

混合此膠體混合物、聚氨酯(polyurethane)(膠體混合物與聚氨酯之重量比約為1：4)與二甲基乙醯胺，形成混合溶液，利用滾輪塗布此混合溶液在離型紙上，經乾燥後得到膜材，將此膜材以約120℃熱壓貼合到壓克力/尼龍/嫘縈/羊毛混紡(重量比約為61：18：15：6)纖維布之紡織物基材上，製得複合紡織品，測得摻雜鎵的氧化鋅粉體約佔紡織物基材重量的5wt%。將該複合紡織品進行TN-037規範之照光溫升試驗，其溫度高於未貼合 膜材的紡織物基材約8.5℃。進行紅外線吸收率試驗(測試波長約1,000nm至2,500nm)，其吸收率高於未貼合膜材的紡織物基材約18%。其數據如表2所列。 Mixing the colloidal mixture, polyurethane (weight ratio of colloidal mixture to polyurethane is about 1:4) and dimethylacetamide to form a mixed solution, and coating the mixed solution on a release paper by a roller, and drying Membrane material, the film is heat-pressed at about 120 ° C to a textile substrate of acrylic/nylon/嫘萦/wool blend (weight ratio of about 61:18:15:6) fiber cloth. In the composite textile, the gallium-doped zinc oxide powder was found to be about 5% by weight of the textile substrate. The composite textile was subjected to the TN-037 specification illumination temperature rise test, and the temperature was higher than that of the unbonded The textile substrate of the film was about 8.5 °C. The infrared absorption rate test (test wavelength of about 1,000 nm to 2,500 nm) was carried out, and the absorption rate was higher than that of the unwoven film substrate of about 18%. The data is listed in Table 2.

實施例6 Example 6

將100克摻雜鎵之氧化鋅(gallium doped zinc oxide)(Ga/Zn=1.2wt%)分散於20克聚乙烯亞胺(重量平均分子量約為900)與400克二甲基甲醯胺中形成膠體混合物，粒徑分析測得膠體平均粒徑約為350nm。測試其界面電位約為10mV。 100 g of gallium doped zinc oxide (Ga/Zn = 1.2 wt%) was dispersed in 20 g of polyethyleneimine (weight average molecular weight of about 900) and 400 g of dimethylformamide A colloidal mixture was formed and the particle size analysis determined that the colloidal average particle size was about 350 nm. The interface potential was tested to be approximately 10 mV.

混合此膠體混合物、聚氨酯(膠體混合物與聚氨酯之重量比約為1：4)與二甲基甲醯胺，形成混合溶液，利用滾輪塗布此混合溶液在離型紙上，經乾燥後得到膜材，將此膜材以約120℃熱壓貼合到嫘縈/棉混紡纖維布(重量比約為60：40)之紡織物基材上，製得複合紡織品，其中摻雜鎵的氧化鋅粉體約佔紡織物基材重量的0.15wt%。將該複合紡織品進行TN-037規範之照光溫升試驗，其溫度高於未貼合膜材的紡織物基材約3.2℃。進行紅外線吸收率試驗(測試波長約1,000nm至2,500nm)，其吸收率高於未貼合膜材的紡織物基材約10%。其數據如表2所列。 Mixing the colloidal mixture, polyurethane (the weight ratio of the colloidal mixture to the polyurethane is about 1:4) and dimethylformamide to form a mixed solution, and coating the mixed solution on the release paper by a roller, and drying to obtain a film. The film was bonded to a textile substrate of a crepe/cotton blended fiber cloth (weight ratio of about 60:40) at a temperature of about 120 ° C to obtain a composite textile in which gallium-doped zinc oxide powder was obtained. About 0.15 wt% of the weight of the textile substrate. The composite textile was subjected to the TN-037 specification illumination temperature rise test at a temperature of about 3.2 ° C higher than the textile substrate of the unbonded film. The infrared absorption rate test (test wavelength of about 1,000 nm to 2,500 nm) was carried out, and the absorption rate was higher than that of the unwoven film substrate of about 10%. The data is listed in Table 2.

由表2可知，本發明複合紡織品，其吸收紅外線與照光溫升效果良好。在一些實施例中可提升約20%的紅外線吸收率，以及可提升約10℃的照光溫升。可應用於具有保暖需求之布料，進一步應用於服飾、寢具和睡袋等產品。 As can be seen from Table 2, the composite textile of the present invention has a good effect of absorbing infrared rays and illuminating the temperature. In some embodiments, the infrared absorption rate of about 20% can be increased, and the illumination temperature rise of about 10 °C can be increased. It can be applied to fabrics with warmth requirements and is further used in apparel, bedding and sleeping bags.

雖然本發明已以數個實施例揭露如上，然其並非用以限定本發明，任何本技術領域中具有通常知識者，在不脫離本發明之精神和範圍內，當可作任意之更動與潤飾，因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 While the invention has been described above in terms of several embodiments, it is not intended to limit the invention, and any one of ordinary skill in the art can be modified and modified without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.

Claims (11)

一種複合紡織品，包括：一紡織物基材；以及一材料層，形成於該紡織物基材之上，該材料層包括一混合物，該混合物包括：一含胺基的高分子，其中該含胺基的高分子包括聚乙烯亞胺、或聚乙烯亞胺之衍生物，該聚乙烯亞胺之衍生物包括末端具乙氧基之聚乙烯亞胺、末端具羧酸基之聚乙烯亞胺、末端具異氰酸酯基之聚乙烯亞胺或上述之組合；以及一粉體，該粉體分散於該含胺基的高分子之中，該粉體包括具有摻雜元素的氧化鋅、銦錫氧化物、具有摻雜元素的銦錫氧化物或上述之組合，其中以100重量份之該粉體為基準，該含胺基的高分子為0.1至40重量份。 A composite textile comprising: a textile substrate; and a material layer formed on the textile substrate, the material layer comprising a mixture comprising: an amine-containing polymer, wherein the amine The base polymer includes a polyethyleneimine or a derivative of polyethyleneimine, and the polyethyleneimine derivative includes a polyethyleneimine having an ethoxy group at the end and a polyethyleneimine having a carboxylic acid group at the terminal. a polyethyleneimine having an isocyanate group at the end or a combination thereof; and a powder dispersed in the amine group-containing polymer, the powder comprising zinc oxide having a doping element, indium tin oxide Indium tin oxide having a doping element or a combination thereof, wherein the amine group-containing polymer is 0.1 to 40 parts by weight based on 100 parts by weight of the powder. 如申請專利範圍第1項所述之複合紡織品，其中該混合物更包含至少一高分子基質。 The composite textile of claim 1, wherein the mixture further comprises at least one polymeric matrix. 如申請專利範圍第2項所述之複合紡織品，其中該混合物係以膜之形態位於該紡織物基材之上。 The composite textile of claim 2, wherein the mixture is placed on top of the textile substrate in the form of a film. 如申請專利範圍第2項所述之複合紡織品，其中以100重量份之粉體為基準，該高分子基質為50至10000重量份。 The composite textile according to claim 2, wherein the polymer matrix is 50 to 10,000 parts by weight based on 100 parts by weight of the powder. 如申請專利範圍第2項所述之複合紡織品，其中該高分子基質包括聚氨酯、聚丙烯酸酯或上述之組合。 The composite textile of claim 2, wherein the polymeric matrix comprises polyurethane, polyacrylate or a combination thereof. 如申請專利範圍第1項所述之複合紡織品，其中該摻雜元素包括IIIB族元素、鐵、或上述之組合。 The composite textile of claim 1, wherein the doping element comprises a Group IIIB element, iron, or a combination thereof. 如申請專利範圍第6項所述之複合紡織品，其中該IIIB族元素包括鎵、鋁、或上述之組合。 The composite textile of claim 6, wherein the Group IIIB element comprises gallium, aluminum, or a combination thereof. 如申請專利範圍第1項所述之複合紡織品，其中以100重量份之該氧化鋅為基準，該摻雜元素為0.1至20重量份。 The composite textile according to claim 1, wherein the doping element is 0.1 to 20 parts by weight based on 100 parts by weight of the zinc oxide. 如申請專利範圍第1項所述之複合紡織品，其中該含胺基的高分子之重量平均分子量係500至100000。 The composite textile of claim 1, wherein the amine group-containing polymer has a weight average molecular weight of 500 to 100,000. 如申請專利範圍第1項所述之複合紡織品，以100重量份之該紡織物基材為基準，該粉體為0.1至15重量份。 The composite textile of claim 1, wherein the composite is from 0.1 to 15 parts by weight based on 100 parts by weight of the textile substrate. 如申請專利範圍第1項所述之複合紡織品，該紡織物基材包括聚乙烯纖維布、聚丙烯纖維布、聚醯胺纖維布、聚酯纖維布、棉纖維布、嫘縈纖維布、醋酸纖維布、毛纖維布或上述之組合。 The composite textile according to claim 1, wherein the textile substrate comprises a polyethylene fiber cloth, a polypropylene fiber cloth, a polyamide fiber cloth, a polyester fiber cloth, a cotton fiber cloth, a rayon cloth, and an acetic acid. Fiber cloth, wool fiber cloth or a combination of the above.
TW105139051A 2016-01-08 2016-11-28 Composite fabrics TWI623658B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662276412P 2016-01-08 2016-01-08
US62/276,412 2016-01-08

Publications (2)

Publication Number Publication Date
TW201725291A true TW201725291A (en) 2017-07-16
TWI623658B TWI623658B (en) 2018-05-11

Family

ID=59275506

Family Applications (1)

Application Number Title Priority Date Filing Date
TW105139051A TWI623658B (en) 2016-01-08 2016-11-28 Composite fabrics

Country Status (3)

Country Link
US (1) US20170198430A1 (en)
CN (1) CN107009707B (en)
TW (1) TWI623658B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI732227B (en) * 2018-12-26 2021-07-01 財團法人工業技術研究院 Composite fiber and textile

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109986848A (en) * 2017-12-29 2019-07-09 财团法人工业技术研究院 composite textiles
US10519595B2 (en) 2017-12-29 2019-12-31 Industrial Technology Research Institute Composite textile
CN111364118A (en) * 2018-12-26 2020-07-03 财团法人工业技术研究院 Composite fiber and fabric

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2961349A (en) * 1956-08-21 1960-11-22 Hoechst Ag Process for fixing pigments on fibrous materials
CH475410A (en) * 1963-11-02 1969-07-15 Degussa Process for the preparation of aqueous suspensions suitable for treating natural or synthetic textiles
DE4327620A1 (en) * 1993-08-17 1995-02-23 Merck Patent Gmbh Stabilized, conductive pigment
JP3695604B2 (en) * 1996-03-04 2005-09-14 日本エクスラン工業株式会社 Deodorant
TW422898B (en) * 1998-10-26 2001-02-21 Nanya Plastics Corp The warm keeping cellulose and cloth and their manufacturing method
WO2001085827A2 (en) * 2000-05-02 2001-11-15 Tribond, Inc. Temperature-controlled induction heating of polymeric materials
US7048771B2 (en) * 2001-10-22 2006-05-23 University Of California Dyeing textiles using nanoparticles
CN1181964C (en) * 2001-11-08 2004-12-29 柯枝连 Method for preparing film with far infrared radiation and product thereof
US6749982B2 (en) * 2002-09-27 2004-06-15 Eastman Kodak Company Imaging member with polyester base
TW200938670A (en) * 2008-03-12 2009-09-16 Huang-Shan Huang Manufacturing method of multi-functional spun-yarn fiber matrix
TWI418676B (en) * 2010-07-12 2013-12-11 Ind Tech Res Inst Fibers having infrared absorption ability, fabrication methods thereof and fabrics containing the same
TWI555890B (en) * 2013-12-18 2016-11-01 財團法人工業技術研究院 Yarns having infrared absorbing ability and textiles containing the yarns

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI732227B (en) * 2018-12-26 2021-07-01 財團法人工業技術研究院 Composite fiber and textile

Also Published As

Publication number Publication date
CN107009707A (en) 2017-08-04
CN107009707B (en) 2019-11-08
US20170198430A1 (en) 2017-07-13
TWI623658B (en) 2018-05-11

Similar Documents

Publication Publication Date Title
KR101402408B1 (en) Coated articles formed of microcapsules with reactive functional groups
TWI623658B (en) Composite fabrics
CN103437146B (en) Nano-fabric finishing agent and its preparation method and application
US9284682B2 (en) Fabric having ultraviolet radiation protection
WO2017092236A1 (en) Method for using in situ polymerization to prepare antibacterial material based on copper oxide/cuprous oxide
KR101805528B1 (en) Silicone-based water repellent emulsion and process of water repellent treatment for fabric using the same
CN108951136A (en) A kind of preparation method of medical non-woven fabric
CN1520481A (en) Method for producing cellulosic sheath surrounding textile fibers and textile produced therefrom
CN108842439A (en) A kind of moisture absorbing and sweat releasing agent and preparation method thereof
KR20160046626A (en) High-hydraulic pressure and high-permeable polyurethane resin compositions containing surface activated nano-silica
JP2011246866A (en) Allergen-reducing processing agent for fiber products
US20180313029A1 (en) Encapsulated additives
JP5396010B2 (en) Moisture permeable waterproof fabric and method for producing the same
US10519595B2 (en) Composite textile
KR102493596B1 (en) Manufacturing method of cool pad fabric and cool pad fabric fabric manufactured thereby
US12071548B2 (en) Product having ultraviolet radiation protection
TWI606157B (en) Fiber, fiber masterbatch and method of fabricating the same, and textile product and method of fabricating the same
JP2013087386A (en) Fiber product having antiallergic activities and allergen reducing processing agent
TWI655329B (en) Composite textile
KR20110120400A (en) Fabrication of high moisture-permeable, water-repellent, oil-repellent, water-repellent, moisture-permeable fabrics using double-sided dispersion and coating
CN102442698B (en) Preparation method of neutral titanium dioxide sol for ultraviolet-proof textile
CN101811027A (en) Gas adsorbent and gas adsorption base material
TW201843362A (en) Method of fabricating fiber masterbatch and fiber
US20250257522A1 (en) Dyed fabric having ultraviolet radiation protection and antimicrobial protection
CN109986848A (en) composite textiles