TW201726904A - Liquid detergent composition for hard surfaces - Google Patents

Abstract

The present invention pertains to a liquid detergent composition for hard surfaces, the liquid detergent composition containing (a) a specific sulfosuccinic acid ester or a salt thereof, (b) at least 0 mass% and less than 3 mass% of an anionic surfactant (excluding component (a)) having a hydrocarbon group with 8 to 21 carbon atoms and a sulfuric ester group or sulfonic acid group, (c) an amphoteric surfactant, and water, wherein the mass ratio of (b)/[(a)+(b)+(c)] is 0.3 or less.

Description

Liquid surface cleaner composition for hard surfaces

The present invention relates to a liquid detergent composition for a hard surface, a method for cleaning a hard surface, and a detergent article for a hard surface.

For hand dishwashing detergents, the cleaning power of oil is strongly required. In particular, in a tableware having a hydrophobic surface such as a plastic sealed container or a lunch box, oil containing a large amount of solid oil such as butter or lard is hard to fall off, and a high cleaning power is required. Therefore, a cleaning method in which hot water of about 40 ° C to 45 ° C is used or cleaning is performed twice is usually used. Japanese Laid-Open Patent Publication No. 2013-100461 discloses a liquid detergent composition for hand dishwashing which contains (a) an alkyl sulfosuccinate type surfactant at a specific content and a specific content ratio. (b) one or more selected from the group consisting of alkyl sulfate salts and polyoxyalkylene alkyl ether sulfate salts, and (c) sulfobetaine type surfactants, and are described at lower temperatures (10) ～35°C) The cleaning power of liquid oil and solid oil adhering to oil stains such as tableware or conditioning equipment having a hydrophobic surface. A liquid detergent composition for hand-washing dishes containing (a) an alkyl sulfosuccinate or a salt thereof and (b) having a carbon number of 8 to 21 is disclosed in Japanese Laid-Open Patent Publication No. 2013-100462. An anionic surfactant of a hydrocarbon group, a sulfate group or a sulfonate group [excluding (a) 5 to 35 mass%, and (c) a sulfobetaine type surfactant, and is described in tableware cleaning It exhibits rich lathering and the persistence of foam during cleaning. The foam disappears instantly during rinsing, and the rinsing is completed with a small amount of water. It is described that the liquid detergent composition for hand dishwashing is adhered to a flexible material such as a sponge to foam the tableware, and the tableware is scrubbed, as disclosed in Japanese Laid-Open Patent Publication No. 2013-100462.

According to the present invention, it is possible to clean the oil containing solid fats and oils adhering to the hard surface of a hard article such as plastic without any mechanical force, even if the friction is not applied. A liquid detergent composition for hard surfaces and a cleaning method for hard surfaces. The present invention relates to a liquid detergent composition for a hard surface, which comprises the following component (a), (b) component 0% by mass or less and less than 3% by mass, (c) component, and water, and (b) The mass ratio of the component / [(a) component + (b) component + (c) component] is 0.3 or less. <Component (a)> Sulfosuccinate or a salt thereof represented by the following formula (a1) [Chemical Formula 1] In the formula, R ^1a and R ^2a are each independently a hydrocarbon group having 5 or more and 18 or less carbon atoms; and A ¹ and A ² are each independently an alkyl group having 2 or more and 4 or less carbon atoms, and x and y are average additions. The number of ears is independently 0 or more and 6 or less; M ¹ is a hydrogen atom or a cation] <(b) component> An anionic surfactant having a hydrocarbon group having 8 or more and 21 or less and a sulfate group or a sulfonic acid group [Part of the (a) component] <(c) component> One or more kinds of amphoteric surfactants selected from the group consisting of sulfobetaine and carbonyl betaine. In one aspect, the present invention relates to a hard surface for oil removal. A liquid detergent composition containing (a) component, (b) component 0 mass% or more, less than 3% by mass, (c) component, and water, and (b) component / [(a) component The mass ratio of +(b) component + (c) component] is 0.3 or less. Hereinafter, the liquid detergent composition for a hard surface according to the present invention is included in the liquid detergent composition for a hard surface for oil removal. <Component (a)> Sulfosuccinate or a salt thereof represented by the following formula (a1) [Chemical 2] In the formula, R ^1a and R ^2a are each independently a hydrocarbon group having 5 or more and 18 or less carbon atoms; and A ¹ and A ² are each independently an alkyl group having 2 or more and 4 or less carbon atoms, and x and y are average additions. The number of ears is independently 0 or more and 6 or less; M ¹ is a hydrogen atom or a cation] <(b) component> An anionic surfactant having a hydrocarbon group having 8 or more and 21 or less and a sulfate group or a sulfonic acid group [Including (a) component] <(c) component> One or more amphoteric surfactants selected from the group consisting of sulfobetaine and carbonyl betaine, and the present invention relates to a method for cleaning a hard surface, which is The above-described liquid surface cleaner composition for hard surfaces of the present invention is in contact with a hard surface. Further, the present invention relates to a method of cleaning a hard surface, which comprises contacting the above-described hard surface liquid detergent composition of the present invention with a hard surface to which oil is adhered. Moreover, the present invention relates to a spray container-mounted clean surface cleaning article, which is obtained by filling the above-described hard surface liquid detergent composition of the present invention in a container having a sprayer. According to the present invention, it is possible to provide a cleaning force capable of cleaning the oil containing the solid oil or the like adhered to the article having a hard surface such as plastic without rubbing the flexible material such as a sponge. An excellent hard surface liquid detergent composition, a hard surface cleaning method, and a spray container for a hard surface cleaning article.

<Liquid Cleaner Composition for Hard Surface> The liquid detergent composition for hard surface of the present invention has an anion interface having a hydrocarbon group having a carbon number of 8 or more and 21 or less and a sulfate group or a sulfonic acid group for the component (b) The content of the active agent is defined so that the interaction between the (a) component having two hydrocarbon groups having a high hydrophobicity and the hydrophilic group having a high hydrophilicity and the component (c) as an amphoteric surfactant can be made strong. It is presumed that the surfactant contained in the liquid surface cleaner composition for hard surfaces of the present invention easily penetrates into the oil stain containing solid fats and oils, and the solid fats and oils are easily peeled off from the hard surface, and as a result, the cleaning power is improved. effect. Further, in the case where the liquid surface cleaning composition for a hard surface of the present invention is used in a method of directly contacting a hard surface, the concentration of the surfactant applied to the hard surface becomes higher than that of using a water-containing sponge to make it hard. Surface contact. Therefore, the effect produced by the surfactant of the present invention will be more clearly exhibited. According to these circumstances, by using the liquid surface cleaner composition for hard surfaces of the present invention, even if a flexible material such as a sponge is not used, the oil containing the solid oil adhered to the hard surface of the plastic or the like is rubbed, that is, not applied. The mechanical cleaning method also provides excellent cleaning power. <Component (a)> The component (a) of the present invention is a sulfosuccinate represented by the following formula (a1) or a salt thereof. [Chemical 3] [where, R ^1a , R ^2a Hydrocarbon groups having a carbon number of 5 or more and 18 or less, respectively; A ¹ , A ² Each of them is independently an alkylene group having a carbon number of 2 or more and 4 or less, and x and y are the average addition molar number and are independently 0 or more and 6 or less; ¹ Is a hydrogen atom or a cation] in the formula (a1), R ^1a , R ^2a Each of the hydrocarbon groups independently having a carbon number of 5 or more, preferably 6 or more, more preferably 7 or more, and having a carbon number of 18 or less, preferably 16 or less, more preferably 14 or less, is preferably a straight chain or a branched chain. alkyl. R ^1a , R ^2a Separately, more preferably an alkyl group having a branched structure. In the general formula (a1), A ¹ , A ² Each is independently an alkylene group having 2 or more carbon atoms and 4 or less carbon atoms, preferably 3 or less. In the general formula (a1), x and y are the average addition molar number, and are independently 0 or more, and 6 or less, preferably 4 or less, more preferably 2 or less, and more preferably from the viewpoint of the cleaning power. Is 0. Further, x + y is preferably 0 or more, and is preferably 12 or less, more preferably 6 or less, still more preferably 3 or less, and still more preferably 0, from the viewpoint of the cleaning power. In the general formula (a1), R ^1a , R ^2a Preferably, it is selected from the group consisting of ketone, octyl, decyl, decyl, dodecyl, tridecyl, tetradecyl, 2-ethylhexyl, n-octyl, second octyl, isopentyl. An isodecyl group, an isodecyl group, an alkyl group of a cyclohexyl group, more preferably an alkyl group selected from the group consisting of n-octyl, second octyl, decyl, isodecyl, tridecyl, and 2-ethylhexyl Further, it is more preferably 2-ethylhexyl, tridecyl, and even more preferably 2-ethylhexyl. In the formula (a1), M ¹ An organic cation such as a hydrogen atom, or an inorganic cation such as a sodium ion, an ammonium ion, a potassium ion or a magnesium ion, a monoethanolamine, a diethanolamine, a triethanolamine or a salt of a salt, preferably selected from the group consisting of sodium ion and ammonium. Inorganic cations of ions, potassium ions, and magnesium ions. As component (a) is R ^1a , R ^2a The preparation method of the same compound is not particularly limited, and it can be produced, for example, by the method described in U.S. Patent No. 2,028,091, and R. ^1a , R ^2a For example, a different asymmetric compound can be produced by referring to Japanese Patent Laid-Open Publication No. Sho 58-24555. For the case of using commercially available compounds, PELEX OT-P (R) manufactured by Kao (share) can be used. ^1a , R ^2a PELEX TR (R) which is made of 2-ethylhexyl) and Kao (share) ^1a , R ^2a All are tridecyl compounds), Luensit A-BO (R) manufactured by BASF ^1a , R ^2a Airrol CT-1L (R) manufactured by Toho Chemical Industry Co., Ltd. ^1a , R ^2a Are 2-ethylhexyl compounds), AEROSOL AY-100 (R) obtained from Mitsui Cytec Co., Ltd. ^1a , R ^2a Are compounds of amyl group), AEROSOL A-196 (R) obtained from Mitsui Cytec Co., Ltd. ^1a , R ^2a All are cyclohexyl compounds) and the like. As a raw material of the component (a), an alkylene oxide can be added to a specific carbon number. The liquid surface cleaner composition for hard surfaces of the present invention preferably contains 0.5% by mass or more, more preferably 0.8% by mass or more, and still more preferably 1% by mass or more, from the viewpoint of the cleaning power. Furthermore, it is more preferably 1.5% by mass or more, and still more preferably 1.7% by mass or more, and from the viewpoint of lowering the raw material cost, it is preferable to contain (a) a component of 30% by mass or less, more preferably 20% by mass or less. Further, it is preferably 15% by mass or less, more preferably 10% by mass or less, still more preferably 8% by mass or less, still more preferably 5% by mass or less, and still more preferably 3% by mass or less. Furthermore, in the present invention, the description of the quality of the component (a) (% by mass or mass ratio) is based on ¹ The mass is assumed to be sodium (the ratio in terms of sodium salt). <Component (b)> The component (b) of the present invention is an anionic surfactant having a hydrocarbon group having 8 or more and 21 or less carbon atoms and a sulfate group or a sulfonic acid group (excluding the component (a)). The hydrocarbon group as the component (b) preferably has a carbon number of 8 or more, preferably 10 or more, more preferably 12 or more, and 21 or less, preferably 18 or less, more preferably from the viewpoint of cleaning power. An alkyl group or an aryl group of 14 or less, more preferably 12 or less. The anionic surfactant as the component (b) is preferably one or more selected from the group consisting of alkyl sulfate salts, polyoxyalkylene alkyl ether sulfate salts, and alkanesulfonates. The anionic surfactant having a sulfate group preferably has a carbon number of 8 or more, preferably 10 or more, 21 or less, preferably 18 or less, more preferably 14 in terms of cleaning power. The alkyl sulfate ester of a linear or branched alkyl group of 12 or less is preferably further hereinafter. Further, the above-mentioned anionic surfactant having a sulfate group is preferably a polyoxyalkylene alkyl ether sulfate salt having a carbon number of 8 or more, preferably 10, from the viewpoint of cleaning power. The above-mentioned and 21 or less, preferably 18 or less, more preferably 14 or less, further preferably 12 or less linear or branched alkyl groups, and having an average of oxygen alkyl groups having 2 or more and 3 or less carbon atoms The addition molar number is preferably 0.1 or more, more preferably 0.3 or more, still more preferably 0.4 or more, and is preferably 6 or less, more preferably 3 or less, still more preferably 1.5 or less. Further, the anionic surfactant having a sulfonic acid group is preferably an alkylbenzenesulfonate selected from the group consisting of an alkyl group having 6 or more and 15 or less carbon atoms, and a carbon number 8 from the viewpoint of cleaning power. The anionic surfactant of at least one of the alkanesulfonate salts of the above, preferably 10 or more, and 21 or less, preferably 18 or less, more preferably 14 or less, and still more preferably 12 or less. The salt of the anionic surfactant as the component (b) is preferably an inorganic salt selected from the group consisting of a sodium salt, an ammonium salt, a potassium salt, and a magnesium salt, and is selected from the group consisting of monoethanolammonium salt, diethanolammonium salt, and triethanolammonium salt. , &#134156; organic ammonium salts such as porphyrin salts. The component (b) is preferably a compound of the following formula (b1) from the viewpoint of blending stability and foaming properties. R ^1b -O-(R ^2b O) _n -SO ₃ M ² (b1) [where, R ^1b a linear or branched alkyl group having a carbon number of 8 or more and 21 or less, R ^2b For stretching ethyl and/or stretching propyl, n is the average addition molar number and is 0 or more and 6 or less; M ² Is a hydrogen atom or a cation, preferably an inorganic or organic cation] in the formula (b1), regarding R ^1b From the viewpoint of the cleaning power, it is a linear or branched chain having a carbon number of 8 or more, preferably 10 or more, and 21 or less, preferably 18 or less, more preferably 14 or less, still more preferably 12 or less. An alkyl group is preferably a linear alkyl group. Specifically, R ^1b It is preferably an alkyl group selected from the group consisting of octyl, decyl, dodecyl, tridecyl, and tetradecyl, and more preferably dodecyl. In the general formula (b1), from the viewpoint of the cleaning power, n is preferably 0.1 or more, more preferably 0.3 or more, still more preferably 0.4 or more, and is preferably 6 or less, more preferably 3 or less. Further preferably, it is 1.5 or less. In the general formula (b1), in R ^2b In the case of an ethyl group, n is preferably 0.1 or more, more preferably 0.5 or more, still more preferably 6 or less, still more preferably 3 or less, from the viewpoint of the cleaning power. Also, in the general formula (b1), in R ^2b In the case of a propyl group, n is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.4 or more, and more preferably 1.5 or less, more preferably 1.0, from the viewpoint of the cleaning power. Hereinafter, it is more preferably 0.8 or less. Also, in the general formula (b1), in R ^2b In the case of an ethyl group and a propyl group, n can be selected from these ranges. In the general formula (b1), M ² Examples thereof include a hydrogen atom, an inorganic cation such as a sodium ion, an ammonium ion, a potassium ion, or a magnesium ion, an organic cation such as a monoethanolammonium ion, a diethanolammonium ion, a triethanolammonium ion, or a 134156; a silane, preferably a sodium ion. Inorganic cations of potassium ions, ammonium ions and magnesium ions. The method for producing the compound of the formula (b1) is not particularly limited, for example, for R ^1b The fatty alcohol represented by -OH is added to a specific amount of ethylene oxide and/or propylene oxide depending on the purpose, and thereafter, a gas selected from sulfur trioxide (liquid or gas), sulfur trioxide containing gas, fuming sulfuric acid, The sulfating agent of chlorosulfonic acid is sulfated and produced by neutralization using a specific alkali agent. The addition reaction of ethylene oxide (hereinafter referred to as EO) and/or propylene oxide (hereinafter referred to as PO) requires a catalyst, and an alkali metal hydroxide such as NaOH or KOH can be used. Further, a catalyst containing magnesium oxide as a main component described in Japanese Laid-Open Patent Publication No. Hei 8-323200, which is capable of obtaining a polyoxyethylene alkyl ether having a relatively wide molar distribution, can be obtained. A relatively narrow compound that adds a molar distribution. Further, the addition of the molar distribution can be controlled by using a base catalyst in combination with a metal oxide catalyst as disclosed in Japanese Laid-Open Patent Publication No. Hei 10-158384. In the case where n is 0 in the general formula (b1), R is preferred. ^1b In the case of a compound containing an alkyl group having a branched structure, regarding R as a raw material ^1b The alcohol represented by -OH may, for example, be an alcohol obtained by hydroformylating a 1-olefin having 8 or more carbon atoms and 14 or less (including an alkyl group having a methyl group branched at a β position relative to an OH group) a gibbut type alcohol obtained by condensing an aldehyde having a carbon number of 4 or more and 8 or less and having a carbon number of 3 or more and 6 or less is relative to the OH group. 100% of the structure for branching at the β position, 3,5,5-trimethylhexanol obtained by hydroformylating the dimer of isobutylene, and hydroformamide of the terpolymer of isobutylene A multi-branched tridecyl alcohol (branched ratio of 100 mol%) obtained by chemical conversion, a synthetic alcohol derived from petroleum or coal (a branching ratio of about 20 mol% or more and 100 mol% or less of an alkyl group). In the present invention, the component (b) is preferably a compound represented by the formula (b1), and preferably contains a carbon number of 8 or more, more preferably 10 or more, and preferably 18 or less, and further preferably. a linear alkyl group of 14 or less, and more preferably 12 or less is used as R ^1b , containing propyl as R ^2b n is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.4 or more, and is preferably 1.5 or less, more preferably 1.0 or less, still more preferably 0.8 or less. In the present invention, the description (mass % or mass ratio) of the mass of the component (b) is based on the M in the formula (b1) of the component (b). ² The mass is assumed to be sodium (the ratio in terms of sodium salt). The liquid surface cleaner composition for hard surfaces of the present invention contains 0% by mass or more of the component (b) and is not more than 3% by mass, preferably 2.5% by mass or less, more preferably 2% by mass or less, more preferably 1.5% by mass or less, further preferably 1% by mass or less, further preferably less than 1% by mass, further preferably 0.5% by mass or less, and further preferably less than 0.5% by mass % is further preferably 0.1% by mass or less, and further preferably less than 0.1% by mass. The content of the component (b) may be 0% by mass in the composition. Further, in the case of using the liquid surface cleaner composition for a hard surface of the present invention in the form of a foam, the liquid surface cleaner composition for a hard surface of the present invention preferably has a foam specific volume. The component (b) is contained in an amount of 0.1% by mass or more, more preferably 0.3% by mass or more, further preferably 0.5% by mass or more, and still more preferably 1% by mass or more. The upper limit of the case can be selected from the above range. <Component (c)> The component (c) of the present invention is one or more kinds of amphoteric surfactants selected from the group consisting of sulfobetaine and carbonyl betaine. From the viewpoint of cleaning power, sulfobetaine is preferred. The sulfobetaine may, for example, be an N-alkyl-N,N-dimethyl-N-sulfopropane having a carbon number of the alkyl group of preferably 10 or more, preferably 18 or less, more preferably 14 or less. The N-alkyl-N,N-dimethyl-N-(2-hydroxyl group) having a carbon number of the alkyl ammonium sulfobetaine or an alkyl group is preferably 10 or more, and preferably 18 or less, more preferably 14 or less. The sulfopropyl)ammonium sulfobetaine or alkanoyl group preferably has a carbon number of 10 or more, preferably 18 or less, more preferably 14 or less, of N-alkyldecylaminopropyl-N,N-di The N-alkylmercaptopropylpropyl-N having a carbon number of methyl-N-sulfopropylammonium sulfobetaine or an alkane group is preferably 10 or more, and preferably 18 or less, more preferably 14 or less. , N-dimethyl-N-(2-hydroxysulfopropyl) ammonium sulfobetaine. The carbonyl betaine may, for example, be an N-alkyl-N,N-dimethyl-N-carboxymethylammonium having an alkyl group having a carbon number of preferably 10 or more, preferably 18 or less, more preferably 14 or less. The betaine or the compound represented by the following formula (c1) is preferably a compound represented by the formula (c1) from the viewpoint of cleaning power. [Chemical 4] (where, R ^1c An alkyl group or an alkenyl group having a carbon number of 7 or more and 21 or less, R ^2c Express propyl, R ^3c And R ^4c Respectively, respectively, an alkyl group having a carbon number of 1 or more and 3 or less. In the formula (c1), R ^1c Preferred is an alkyl group or an alkenyl group having a carbon number of 9 or more, more preferably 11 or more, and preferably 15 or less, more preferably 13 or less, preferably an anthracenyl group, a decyl group, an undecyl group or a dodecane group. Base, tridecyl. In the general formula (c1), R ^C3 And R ^C4 Separate, preferably methyl. The compound represented by the formula (c1) may, for example, be an almond amido propyl betaine, apricot melamine (apricotamido) betaine or avocado oil amidinopropyl beet. Alkali, babassu oil guanidinopropyl betaine, behenylpropyl betaine, rapeseed oil guanylpropyl betaine, octyl/caprolactam propyl betaine, coconut decylamine Propyl betaine, coconut oil/oil propyl propyl betaine, isostearyl propyl propyl betaine, lauryl propyl betaine, chymidyl propyl betaine, eucalyptus Aminopropyl betaine, myristyl propyl betaine, oleyl propyl betaine, olive oil guanylpropyl betaine, palm oil palaminodo propyl betaine, palm Palmitamido propyl betaine, castor oil guanamine propyl betaine, sesame oil guanamine propyl betaine, soybean oil guanamine propyl betaine, stearyl propyl betaine, Tallow guanamine propyl betaine, undecylenyl allylamyl betaine, and wheat germ guanidinopropyl betaine. The compound represented by the formula (c1) is preferably selected from the group consisting of lauryl propyl propyl betaine, myristyl propyl betaine, oleyl propyl betaine, and tallow amide. More than one type of propyl betaine. These are the R in the general formula (c1) ^3c And R ^4c Compounds which are each a methyl group. The liquid surface cleaner composition for hard surfaces of the present invention preferably contains the component (c) in an amount of 0.1% by mass or more, more preferably 0.3% by mass or more, and still more preferably 0.5% by mass or more from the viewpoint of cleaning power. Furthermore, it is more preferably 1% by mass or more, and still more preferably 1.5% by mass or more, and from the viewpoint of reducing the raw material cost, it is preferable to contain the component (c) in an amount of 30% by mass or less, more preferably 20% by mass or less. Further, it is preferably 15% by mass or less, more preferably 10% by mass or less, still more preferably 8% by mass or less, still more preferably 5% by mass or less, and still more preferably 3% by mass or less. In the liquid detergent composition for a hard surface of the present invention, the total content of the component (a), the component (b), and the component (c) is preferably 0.6% by mass or more from the viewpoint of the cleaning power. It is preferably 1% by mass or more, more preferably 2% by mass or more, further preferably 2% by mass or more, more preferably 2.5% by mass or more, still more preferably 3% by mass or more, and still more preferably 4% by mass. In addition, from the viewpoint of improving the discharge property, reducing the raw material cost of the surfactant, and reducing the amount of the solvent, it is preferably 40% by mass or less, more preferably 35% by mass or less, and further preferably 30% by mass or less, more preferably 25% by mass or less, further preferably 20% by mass or less, further preferably 18% by mass or less, further preferably 15% by mass or less, and still more preferably 10% by mass or less. The hard surface liquid detergent composition of the present invention, preferably a liquid surface cleaner composition for hard surface which is used for contact with a hard surface and which is not subjected to mechanical force, can be obtained from (a) The total content of the component, the component (b), and the component (c) is 0.1% by mass, 0.64% by mass, 2% by mass, and/or 20% by mass. In the liquid detergent composition for a hard surface of the present invention, the ratio of the total content of the component (a), the component (b), and the component (c) in all the surfactants is compared with respect to the cleaning power. The content is preferably 50% by mass or more, more preferably 60% by mass or more, further preferably 70% by mass or more, more preferably 80% by mass or more, still more preferably 90% by mass or more, and still more preferably 100% by mass or less. In the liquid surface cleaner composition for a hard surface of the present invention, the mass ratio of the content of the component (a) to the total content of the component (a), the component (b) and the component (c) is (a) component / [( The mass ratio of a) component + (b) component + (c) component] is preferably 0.1 or more, more preferably 0.2 or more, further preferably 0.3 or more, and further preferably 0.35 in terms of cleaning power. The above is more preferably 0.4 or more, and from the same viewpoint, it is preferably 0.9 or less, more preferably 0.85 or less, further preferably 0.8 or less, further preferably 0.75 or less, and further preferably 0.7 or less. Further, it is preferably 0.65 or less. Further, [(a) component + (b) component + (c) component] is the meaning of the total content of the component (a), the component (b), and the component (c) (the same applies to the following mass ratio). In the liquid surface cleaner composition for hard surfaces of the present invention, the mass ratio of the content of the component (b) to the total content of the component (a), the component (b) and the component (c) is (b) component / [( The mass ratio of a) component + (b) component + (c) component is 0.3 or less from the viewpoint of cleaning power, preferably less than 0.3, preferably 0.26 or less, more preferably 0.2 or less, and further It is preferably less than 0.2, more preferably 0.15 or less, still more preferably less than 0.15, still more preferably 0.1 or less. Further, in the liquid surface cleaner composition for a hard surface of the present invention, the present invention is used in the form of a foam in the mass ratio of the component (b) / [component (b) + component (c)] In the case of the liquid surface cleaner composition for a hard surface, it is 0 or more, preferably 0.03 or more, more preferably 0.05 or more, and still more preferably 0.07 or more from the viewpoint of foam specific volume which can increase the specific volume of the foam. Further, it is preferably 0.1 or more, more preferably 0.15 or more, still more preferably 0.2 or more. The mass ratio of the component (b)/[(a) component + (b) component + (c) component] may also be zero. In the liquid surface cleaner composition for hard surfaces of the present invention, the mass ratio of the content of the component (c) to the total content of the component (a), the component (b), and the component (c) is (c) component / [( The mass ratio of a) component + (b) component + (c) component] is preferably 0.1 or more, more preferably 0.2 or more, further preferably 0.3 or more, and further preferably 0.35 in terms of cleaning power. The above is more preferably 0.4 or more, and from the same viewpoint, it is preferably 0.9 or less, more preferably 0.85 or less, further preferably 0.8 or less, further preferably 0.75 or less, and further preferably 0.7 or less. Further, it is preferably 0.65 or less. In the liquid surface cleaner composition for hard surfaces of the present invention, the mass ratio of the content of the component (a) to the content of the component (c), that is, the mass ratio of the component (a) component (c), is in terms of cleaning power. It is preferably 0.1 or more, more preferably 0.2 or more, further preferably 0.3 or more, further preferably 0.4 or more, further preferably 0.5 or more, further preferably 0.6 or more, and storage stability and From the viewpoint of the cleaning power, it is preferably 10 or less, more preferably 8 or less, further preferably 7 or less, further preferably 6 or less, further preferably 5 or less, further preferably 4 or less, and further preferably It is 3 or less, and more preferably 2 or less, and further preferably 1 or less, and further preferably 0.8 or less from the viewpoint of storage stability. <Component (d)> The liquid surface cleaner composition for hard surfaces of the present invention may contain an alkyl glyceryl ether as the component (d) from the viewpoint of cleaning power. The component (d) is an alkyl monoglyceryl ether having an alkyl group having 6 or more and 18 or less carbon atoms. Specifically, a compound of the following formula (d1) is preferred. R ^1d -O-(Gly) _r -H (d1) [where, R ^1d An alkyl group having 6 or more and 18 or less carbon atoms, and Gly means a structural unit derived from glycerin, preferably a residue obtained by removing one hydroxyl group and one hydrogen atom from glycerin, and r is 1 or more and 4 or less. Number] in the general formula (d1), R ^1d The alkyl group having 6 or more carbon atoms, more preferably 8 or more carbon atoms, more preferably 18 or less carbon atoms, still more preferably 12 or less carbon atoms, is preferably an octyl group or a 2-ethylhexyl group. Mercapto, dodecyl. r is preferably 1. The liquid surface cleaner composition for a hard surface of the present invention preferably contains (d) a component of 0.1% by mass or more, more preferably 0.2% by mass or more, and still more preferably 0.5% by mass or more from the viewpoint of cleaning power. It is preferably 6% by mass or less, more preferably 4% by mass or less, and still more preferably 2% by mass or less. <Component (e)> The liquid surface cleaner composition for hard surfaces of the present invention preferably contains a solvent as the component (e) from the viewpoint of cleaning power and formulation stability. The solvent is preferably a water-soluble organic solvent having a carbon number of 2 or more, more preferably 3 or more carbon atoms, more preferably 10 or less carbon atoms, still more preferably 8 or less carbon atoms, and more preferably a specific example. Selected from the group consisting of ethanol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerin, isoprene glycol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, 3-methyl-3-methoxybutanol , phenoxyethanol, phenethylene glycol, phenoxyisopropanol, butyl diethylene glycol (diethylene glycol monobutyl ether), dibutyl butyl diethylene glycol, and benzyl alcohol Solvent. Among them, one or more kinds of water-soluble organic solvents selected from the group consisting of butyl diethylene glycol, ethanol, and propylene glycol are more preferable. Here, the water-soluble organic solvent means a solvent having an octanol/water partition coefficient (LogPow) of 3.5 or less. The ratio of the butyl diethylene glycol in the component (e) is preferably 25% by mass or more, more preferably 50% by mass or more, and is preferably 100% by mass or less. In the component (e), the ratio of ethanol is preferably 50% by mass or less, more preferably 25% by mass or less, still more preferably 10% by mass or less. The liquid surface cleaner composition for a hard surface of the present invention preferably contains 0.5% by mass or more, more preferably 2% by mass or more, more preferably 2% by mass or more, more preferably 2% by mass or more, from the viewpoint of cleaning power and blending stability. 4% by mass or more, and preferably 30% by mass or less, more preferably 20% by mass or less, still more preferably 10% by mass or less. In the case where the liquid detergent composition for a hard surface of the present invention contains the component (e), the mass ratio of the content of the component (e) to the total content of the component (a) and the component (c) is (e) component/ The mass ratio of the component (a component + (c) component) is preferably 0.5 or more, more preferably 1 or more, still more preferably 1.2 or more, and still more preferably from the viewpoint of storage stability and cleansing power. From the viewpoint of the same, it is preferably 5 or less, more preferably 4 or less, still more preferably 3 or less, still more preferably 2.1 or less, still more preferably 2 or less. Further, the mass ratio of the content of the component (e) to the total content of the component (a), the component (b), and the component (c) is (e) component / [(a) component + (b) component + (c) The mass ratio of the component is preferably 0.5 or more, more preferably 1 or more, still more preferably 1.2 or more, still more preferably 1.5 or more, from the viewpoint of storage stability and cleaning power, and the same viewpoint The amount is preferably 5 or less, more preferably 4 or less, still more preferably 3 or less, still more preferably 2.1 or less, and still more preferably 2 or less. <Component (f)> The liquid surface cleaner composition for hard surfaces of the present invention may contain a dissolution aid as the component (f) from the viewpoint of formulation stability. As the dissolution aid, toluenesulfonic acid, xylenesulfonic acid, cumenesulfonic acid or such sodium, potassium or magnesium salts are good, especially p-toluenesulfonic acid or a salt thereof. The liquid surface cleaner composition for hard surfaces of the present invention preferably contains (f) a component of 0.5% by mass or more, more preferably 1% by mass or more, and still more preferably 1.5% by mass, from the viewpoint of blending stability. The above is preferably 15% by mass or less, more preferably 10% by mass or less, and still more preferably 5% by mass or less. <Component (g)> The liquid surface cleaner composition for hard surfaces of the present invention may contain a fatty acid having a carbon number of 8 or more and 22 or less as a (g) from the viewpoint of foaming property and rinsing property. ingredient. The component (g) of the present invention preferably has a carbon number of 8 or more, more preferably 10 or more, and preferably has a carbon number of 22 or less, more preferably from the viewpoint of foaming property, rinsing property, and cleaning power. A fatty acid or a salt thereof of 18 or less, more preferably 14 or less. Examples of the component (g) include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, linoleic acid, linoleic acid, and the like. Further, a coconut fatty acid such as a fatty acid may be used. The salt of a fatty acid is an inorganic salt selected from the group consisting of a sodium salt, a potassium salt, a magnesium salt, and an ammonium salt, and an organic amine salt such as a monoethanolammonium salt, a diethanolammonium salt, or a triethanolammonium salt, and preferably a sodium salt or a potassium salt. Salt, magnesium salt, more preferably sodium salt, potassium salt. The component (g) is preferably capric acid, lauric acid, myristic acid, palmitic acid or the like, and more preferably one or more selected from the group consisting of capric acid, lauric acid, myristic acid or the like. More preferably, it is one or more selected from the group consisting of citric acid, lauric acid or a salt thereof. The component (g) preferably contains lauric acid or a salt thereof, and the ratio of lauric acid or a salt thereof in the component (g) is preferably 20% by mass or more, more preferably 50% by mass. The above is more preferably 80% by mass or more, and is preferably 100% by mass or less, and more preferably 100% by mass. The liquid surface cleaner composition for a hard surface of the present invention preferably contains (g) a component of 0% by mass or more from the viewpoint of foaming property and rinsing property, and is preferably in terms of cleaning power. The content of the component (g) is preferably 3% by mass or less, more preferably 3% by mass or less, still more preferably 2.5% by mass or less, further preferably 2% by mass or less, further preferably 1.5% by mass or less, and further preferably 1.5% by mass or less. It is 1% by mass or less, more preferably less than 1% by mass, still more preferably 0.5% by mass or less, further preferably less than 0.5% by mass, further preferably 0.1% by mass or less, and further preferably less than 0.1% by mass. The content of the component (g) may be 0% by mass in the composition. In the present invention, the description (mass% or mass ratio) of the mass of the component (g) is based on the conversion of the fatty acid. In the liquid detergent composition for a hard surface of the present invention, it is preferable that the component (b) and the component (g) are contained in a total amount of 0% by mass or more in terms of foaming property and rinsing property, and the cleaning power is The viewpoint is preferably less than 3% by mass, more preferably 2.5% by mass or less, still more preferably 2% by mass or less, further preferably 1.5% by mass or less, further preferably 1% by mass or less, and further preferably The amount is preferably less than 1% by mass, more preferably 0.5% by mass or less, further preferably less than 0.5% by mass, further preferably 0.1% by mass or less, and further preferably less than 0.1% by mass. The total content of the component (b) and the component (g) may be 0% by mass in the composition. In the liquid detergent composition for a hard surface of the present invention, the total content of the component (a), the component (b), the component (c), and the component (g) is preferably 0.6 in terms of cleaning power. The mass% or more is more preferably 1% by mass or more, further preferably 2% by mass or more, more preferably 3% by mass or more, still more preferably 4% by mass or more, and the raw material cost of the surfactant is lowered. From the viewpoint of reducing the amount of the solvent, it is preferably 40% by mass or less, more preferably 35% by mass or less, further preferably 30% by mass or less, further preferably 25% by mass or less, and further preferably 20% by mass. % or less is further preferably 15% by mass or less, and more preferably 10% by mass or less. In the liquid surface cleaner composition for hard surfaces of the present invention, the ratio of the total content of the component (a), the component (b), the component (c), and the component (g) in all the surfactants is the cleaning power. The viewpoint is preferably 50% by mass or more, more preferably 60% by mass or more, still more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass or more, and more preferably Preferably, it is 100% by mass or less. In the liquid surface cleaner composition for hard surfaces of the present invention, the mass ratio of the content of the component (a) to the total content of the component (a), the component (b), the component (c) and the component (g) is (a) The mass ratio of the component / [(a) component + (b) component + (c) component + (g) component] is preferably 0.1 or more, more preferably 0.2 or more, from the viewpoint of cleaning power, and further It is preferably 0.3 or more, more preferably 0.35 or more, further preferably 0.4 or more, and from the same viewpoint, it is preferably 0.9 or less, more preferably 0.85 or less, still more preferably 0.8 or less, and further preferably It is 0.75 or less, more preferably 0.7 or less, still more preferably 0.65 or less. In the liquid surface cleaner composition for hard surfaces of the present invention, the total content of the components (b) and (g) and the total content of the components (a), (b), (c) and (g) The mass ratio is the mass ratio of [(b) component + (g) component] / [(a) component + (b) component + (c) component + (g) component], in terms of cleaning power, Preferably, it is 0.3 or less, more preferably not more than 0.3, further preferably 0.26 or less, further preferably 0.2 or less, further preferably less than 0.2, further preferably 0.15 or less, further preferably less than 0.15, and further preferably More preferably, it is 0.1 or less. Further, in the liquid surface cleaner composition for a hard surface of the present invention, [(b) component + (g) component] / [(a) component + (b) component + (c) component + (g) component] The mass ratio is 0 or more, preferably 0.03 or more from the viewpoint of the foam specific volume in which the specific volume of the foam can be increased in the case of using the liquid surface cleaner composition for a hard surface of the present invention in the form of a foam. It is more preferably 0.05 or more, further preferably 0.07 or more, further preferably 0.1 or more, further preferably 0.15 or more, and further preferably 0.2 or more. The mass ratio of [(b) component + (g) component] / [(a) component + (b) component + (c) component + (g) component] may also be zero. In the liquid surface cleaner composition for a hard surface of the present invention, the mass ratio of the content of the component (c) to the total content of the component (a), the component (b), the component (c), and the component (g) is (c) The mass ratio of the component / [(a) component + (b) component + (c) component + (g) component] is preferably 0.1 or more, more preferably 0.2 or more, from the viewpoint of cleaning power, and further It is preferably 0.3 or more, more preferably 0.35 or more, further preferably 0.4 or more, and from the same viewpoint, it is preferably 0.9 or less, more preferably 0.85 or less, still more preferably 0.8 or less, and further preferably It is 0.75 or less, more preferably 0.7 or less, still more preferably 0.65 or less. The liquid surface cleaner composition for hard surfaces of the present invention may contain a gelation preventing agent such as a polyalkylene glycol, a tackifier such as polyacrylic acid, an enzyme, a fragrance, a dye, a pigment, a bactericide, a preservative, and a pH adjustment. Ingredients such as agents. In the liquid detergent composition for a hard surface of the present invention, the content of the solid content component is preferably 0.6% by mass or more, more preferably 1% by mass or more, and still more preferably 2 from the viewpoint of the cleaning power. The mass% or more is more preferably 3% by mass or more, and still more preferably 4% by mass or more, and from the viewpoint of lowering the raw material cost and the discharge property when using a container having a sprayer, it is preferably 60. The mass% or less is more preferably 50% by mass or less, further preferably 45% by mass or less, further preferably 40% by mass or less, further preferably 35% by mass or less, further preferably 30% by mass or less, and further preferably 30% by mass or less. Good is 28% by mass or less. Here, the solid content component is the components (a) to (c) and other optional components, that is, components other than water. The hard surface liquid detergent composition of the present invention contains water. That is, the components other than the above components (a) to (c) and the optional components are water. The liquid surface cleaner composition for hard surfaces of the present invention preferably contains 30% by mass or more, more preferably 50% by mass or more, more preferably 60% by mass or more, still more preferably 70% by mass or more, and more preferably water. It is 98% by mass or less, more preferably 95% by mass or less, still more preferably 90% by mass or less. The water is preferably ion-exchanged water, sterilized ion-exchanged water or the like. The pH value of the liquid surface cleaner composition for hard surfaces of the present invention at 25 ° C is preferably 2 or more, more preferably 4 or more, still more preferably 5 or more, from the viewpoint of the mildness of the opponent, and It is preferably 10 or less, more preferably 9 or less, still more preferably 8 or less. The viscosity of the liquid surface cleaner composition for hard surfaces of the present invention at 20 ° C is preferably 0.5 mPa·s or more, more preferably 1 mPa·s or more, and preferably 50 mPa·s or less, more preferably 20 mPa. In the case of s or less, it is preferably 10 mPa·s or less, more preferably 7 mPa·s or less, and still more preferably 5 mPa·s or less. The viscosity can be adjusted by using a solvent or a dissolution aid. The hard surface liquid detergent composition of the present invention is preferably used for a hard surface of a hard article, and is more preferably a hard surface for a hard object around a tableware or a kitchen, and is preferably a hard surface for tableware. Further, it is preferably a hand-washing cleaning of a hard surface of a hard article, and further preferably a hand-washing cleaning of a hard surface of a tableware or a hard article around the kitchen, and further preferably a hand-washing cleaning of a hard surface of the tableware. Specifically, the liquid surface cleaner composition for hard surfaces of the present invention is preferably a cleaning agent for applying a hard surface to a hard article, and more preferably for cleaning a hard surface of a hard object around a tableware or a kitchen. The agent is further preferably a cleaning agent for applying a hard surface to a tableware. Further, in particular, the liquid surface cleaner composition for hard surfaces of the present invention is preferably a cleaning agent for spraying a hard surface of a hard article, and more preferably for cleaning a hard surface of a hard object around a tableware or a kitchen. The agent is further preferably a cleaning agent for spraying onto the hard surface of the tableware. Examples of the hard food include a food manufacturing machine such as a pipe or a part, a hard article around the kitchen, and a tableware. The liquid surface cleaner composition for a hard surface of the present invention is excellent in the cleansing property of the solid fat or oil. It is a hard object, preferably a tableware and a hard object around the kitchen, and more preferably a tableware. The hard objects around the kitchen are used in the kitchen. In particular, it is the storage place for food, tableware and conditioning equipment such as refrigerators and sideboards; drains, flow tables, range hoods, sinks, gas stoves, Food conditioning places such as microwave ovens; and floors or walls around them. In the present invention, for the sake of convenience, these are referred to as "hard objects around the kitchen". In addition, as a tableware, a dishware, a bowl, and the like, a storage container such as a sealed container or a bottle, a conditioning tool such as a kitchen knife or a chopping board, a pan, a frying pan, and a grilled fish rack; a food processing machine and a mixer are mentioned. A member or appliance that is in contact with the foodstuff, such as a home appliance. In the present invention, these are referred to as "tableware" for the sake of convenience. Moreover, the liquid surface cleaner composition for hard surfaces of the present invention is preferably selected from the group consisting of a tableware, a storage container, a conditioning device, and a conditioning appliance, and more preferably selected from the group consisting of a dish, a bowl, a sealed container, a bottle, a kitchen knife, For chopping boards, pots, frying pans, grilled fish racks, food processing machines, and mixers. Moreover, as a hard surface of the cleaning object of the present invention, a hard surface around the tableware and the kitchen, and a hard surface of the tableware, a plastic (including a polyphthalocyanine resin), a metal, a pottery, a wood, and the like may be mentioned. combination. <Method for Cleaning Hard Surface> The method for cleaning a hard surface of the present invention is to bring the hard surface liquid detergent composition of the present invention into contact with a hard surface. That is, the hard surface liquid detergent composition of the present invention is used in the method of cleaning a hard surface of the present invention. The preferred aspect of the composition is the same as the above-described liquid surface cleaner composition for hard surfaces of the present invention. The method for cleaning a hard surface of the present invention can be preferably used as a cleaning method for the hard surface of the hard surface liquid detergent composition of the present invention which is in contact with a hard surface to which oil is adhered and which is adhered to a hard surface containing oil of solid grease. Implementation. These methods are methods for cleaning the hard surface of the hard surface of the present invention in contact with the oil stain adhered to the hard surface. In one aspect, the present invention provides a method of cleaning a hard surface by contacting the hard surface liquid detergent composition for degreasing of the present invention with a hard surface to which oil is adhered. The oily soil containing solid fats and oils contains stains of oils and fats which are solid at normal temperature (for example, 20 ° C). Oil stains containing solid oils and fats are typically oil stains containing solid oils and fats, and oil stains containing solid oils and liquid oils. The form of the oil stain containing the solid fat or oil when it is in contact with the liquid surface cleaner composition for a hard surface may be in a state in which a solid fat or a liquid oil is mixed. From the viewpoint of foam specific volume, the hard surface cleaning method of the present invention may use (b) component / [(a) component + (b) component + (c) component of the above-mentioned hard surface liquid detergent composition] The quality is preferably 0.15 or more, more preferably 0.2 or more, and is 0.3 or less of a hard surface liquid detergent composition. Further, in terms of cleaning power, the method for cleaning a hard surface of the present invention may use (b) component / [(a) component + (b) component + (c) component of the above-mentioned hard surface liquid detergent composition. The quality is preferably carried out for a hard surface liquid detergent composition which is less than 0.2 and preferably 0 or more. In the method of cleaning a hard surface of the present invention, the hard surface liquid detergent composition of the present invention is brought into contact with a hard surface. Specifically, a cleaning method in which the hard surface liquid detergent composition is brought into contact with a hard surface without being diluted, that is, the hard surface liquid detergent composition is not diluted and brought into contact with the hard surface is mentioned. Further, a cleaning method in which the hard surface liquid detergent composition is not diluted and brought into contact with a hard surface to which oil is adhered is preferably used, and it is preferably brought into contact with a hard surface to which oil stain containing solid oil and fat is adhered. Cleaning method. The hard surface liquid detergent composition is not diluted and adhered to a hard surface surface to which oil stain containing solid oil and fat is adhered, and the detergent composition is not intentionally diluted with water or the like and then adhered thereto. Hard surface contact with oily grease containing solid grease. For example, the case where the liquid detergent composition is brought into contact with a hard surface to which water droplets or the like are attached or the liquid detergent composition is brought into contact with the hard surface and the water droplet adheres to the hard surface can be understood as the liquid detergent composition. Dilution is carried out to bring it into contact with a hard surface to which oil stains containing solid oils and fats are attached. In the present invention, the stock solution of the hard surface liquid detergent composition is adhered to the hard surface directly, that is, without changing the composition. For example, the hard surface liquid detergent composition is brought into contact with a hard surface to which oil stains containing solid fats and oils are adhered without adhering to the water-containing sponge. The composition of the above-described hard surface liquid detergent composition can be varied after contact with a hard surface. That is, after contacting the hard surface, the composition of the above-mentioned hard surface liquid detergent composition can be diluted or concentrated. In the method for cleaning a hard surface of the present invention, the concentrated composition comprising the component (a), the component (b), and the component (c) of the present invention may be prepared in advance, and the concentrated composition is diluted with water to prepare the present invention. The hard surface is cleaned with a liquid detergent composition and brought into contact with a hard surface. In other words, the hard surface liquid detergent composition of the present invention may be prepared by diluting the concentrated composition containing the component (a), the component (b), and the component (c) of the present invention with water to form the hard surface. A method of cleaning a hard surface that is in contact with a hard surface without dilution with a liquid detergent composition. Moreover, the cleaning method of the hard surface of the present invention is a cleaning method in which the hard surface liquid detergent composition is brought into contact with a hard surface and then placed without applying mechanical force. This method is suitable for the cleaning of parts that are not accessible by hand or tool or that are not easily accessible. By placing without applying mechanical force, for example, it means that the operation for cleaning is not performed except for the contact of the composition. For example, it is understood that the composition to be contacted naturally flows down the surface of the hard surface, or the vibration for the purpose of cleaning is transmitted to the hard surface, etc., and can be understood to be placed without applying mechanical force. That is, as a cleaning method of the present invention, a cleaning method in which the hard surface liquid detergent composition is brought into contact with a hard surface without using a flexible material such as a sponge, and is directly placed without applying mechanical force is mentioned. After placement, it is usually rinsed with water. At the time of rinsing, mechanical force (physical force) may be applied by hand or the like, or rinsing may be performed only by a water flow. The cleaning method of the present invention is characterized in that the hard surface liquid detergent composition is brought into contact with a hard surface to which oily stains containing solid oil and fat are adhered, and the cleaning by the flexible material, the cleaning by flowing water, and A cleaning method in which the cleaning is performed without applying mechanical force by any of ultrasonic cleaning. That is, as a cleaning method of the present invention, the hard surface liquid detergent composition is brought into contact with a hard surface to which oily stains containing solid oil and fat are adhered, and the frictional force by a flexible material such as a sponge is not used. A cleaning method in which the flow of water in the automatic tableware cleaning machine or the like and the vibration by ultrasonic waves are directly placed without applying mechanical force. In the method for cleaning a hard surface of the present invention, it is preferred that the hard surface liquid detergent composition has an area of 100 cm with respect to a hard surface as an object. ² Preferably, the contact is carried out at a ratio of 0.1 g or more, more preferably 0.3 g or more, further preferably 0.4 g or more, and preferably 5 g or less, more preferably 3 g or less, still more preferably 2 g or less. It is preferably coated or sprayed. In the method for cleaning a hard surface of the present invention, in order to improve the cleaning power, after the hard surface liquid detergent composition is brought into contact with the hard surface, it is preferably placed for 10 seconds or more without applying mechanical force, more preferably It is 20 seconds or longer, more preferably 30 seconds or longer, further preferably 40 seconds or longer, more preferably 50 seconds or longer, still more preferably 1 minute or longer, and it is preferably from the viewpoint of shortening the cleaning time. It is 60 minutes or less, more preferably 30 minutes or less, further preferably 20 minutes or less, more preferably 10 minutes or less, still more preferably 5 minutes or less. In this case, the point at which the composition is initially brought into contact with the hard surface may be set as the beginning of the placement. Further, the temperature at the time of standing may be room temperature, and examples thereof include 10° C. or higher and 30° C. or lower. Further, in the method for cleaning a hard surface of the present invention, it is preferable that the liquid detergent composition is brought into contact with a hard surface to be cleaned for 10 seconds or more, more preferably 20 seconds or more, from the viewpoint of improving the cleaning power. Furthermore, it is preferably 30 seconds or longer, more preferably 40 seconds or longer, still more preferably 50 seconds or longer, still more preferably 1 minute or longer, and preferably 60 minutes or shorter from the viewpoint of shortening the cleaning time. It is more preferably 30 minutes or shorter, further preferably 20 minutes or shorter, further preferably 10 minutes or shorter, more preferably 5 minutes or shorter. Further, the temperature during the contact may be room temperature, for example, 10 ° C or more and 30 ° C or less. In the method for cleaning a hard surface of the present invention, the hard surface to which the oil stain is adhered may be immersed in the hard surface liquid detergent composition to contact the composition, and the cleaning power is efficiently improved. A method of spraying or coating with a hard surface to which oil is adhered. Preferably, the method for contacting the hard surface liquid detergent composition with the oily hard surface is sprayed or coated, and preferably the hard surface liquid detergent composition is sprayed into a droplet form or A method of coating in a foam form. Specifically, it is preferred to use the spray device to bring the hard surface liquid detergent composition into contact with the oily hard surface. That is, it is preferable to use a hard surface cleaning agent article obtained by filling the liquid surface cleaning agent composition for a hard surface of the present invention in a container having a sprayer. The present invention provides a spray container-packed hard surface cleaning article which is obtained by filling a hard surface liquid detergent composition of the present invention in a container having a sprayer. Further, from the viewpoint of exerting the effects of the present invention on the hard surface to which the oil is adhered, it is preferable to adhere a hard surface containing oil stains of solid fats and oils. In the spray container-mounted hard surface cleaning agent article of the present invention, the container having the sprayer for the hard surface liquid detergent composition of the present invention includes a manual spray container, a pump spray container, and the like which do not use a propellant. The spray device, the aerosol using the propellant, and the like are preferably a trigger sprayer capable of spraying or coating the contents into droplets or foams, and more preferably having the contents sprayed into droplets. A trigger sprayer of the mechanism or a trigger sprayer with a mechanism for forming a foam (foam forming mechanism). In the case of using a trigger sprayer having a mechanism for spraying the liquid surface cleaner composition of the hard surface of the present invention into a droplet form in the spray container for a hard surface of the present invention, The diameter of the nozzle hole of the spray nozzle of the spray container is preferably 0.1 mm or more, more preferably in order to facilitate the spraying or the sprayed droplets are not disordered or sprayed linearly, and the area that can be sprayed is not extremely narrow. It is 0.3 mm or more, and preferably 2 mm or less, more preferably 1 mm or less. In the case of using a trigger sprayer having a mechanism for spraying into a droplet, the spray container of the present invention preferably has a spray for a hard surface with a spray of 0.1 mL or more, more preferably 0.3 mL or more. A composition of preferably 5 mL or less, more preferably 2 mL or less is preferred. Further, in the case of using the lubricant spray article having a foam forming mechanism in the spray container of the present invention, it is preferable to have a rotating member and a space portion having a circular shape of 4 to 8 mm in diameter. A liquid having a plurality of rod-like projections is provided through the panel. Here, the rotating element is a mechanism that imparts rotation to the flow of the liquid material by the rotating element and finally ejects from the nozzle. As a detailed structure thereof, Japanese Patent Laid-Open No. Hei 8-332422 or Japanese Patent Laid-Open No. Hei 8 Fig. 4(b) of the Japanese Patent Publication No. 108-102, and Fig. 1 of Japanese Patent Laid-Open Publication No. 2002-68265. In the case of using a trigger type sprayer having a foam forming mechanism, the spray container containing a hard surface cleaning agent of the present invention preferably has a spray of 0.5 mL or more, more preferably 1 mL or more, and preferably 30, in one operation. The composition of mL or less, more preferably 15 mL or less, further preferably 5 mL or less. The liquid passage plate which is another member of the foam forming mechanism is provided with a protrusion of preferably 3 to 8 rods in a space portion of a circular shape having a diameter of 5 to 7 mm, and is observed in a plane through the sheet. It is preferably a rectangular rod-shaped protrusion having a width of 0.8 to 1.2 mm and a length of 2 to 4 mm. Further, the area occupied by the rod-shaped projections with respect to the space portion other than the rod-shaped projections is preferably 30 area% or more, more preferably 40 area% or more, and is preferably 90 area% or less, more preferably 80 area% or less, further preferably 70 area% or less, by providing such a liquid passage plate, the adhesion retention of the foam on the vertical surface becomes good. In the spray container of the present invention, a container for a hard surface cleaning agent can be used as a container which is generally used. For example, those obtained by using polyethylene, polypropylene, or polyethylene terephthalate as raw materials can be produced by blow molding or the like. Regarding the thickness of the container, the bottom surface and the side surface may be different, preferably 0.01 to 2 mm, and the capacity of the container is preferably 100 to 1000 mL. The amount of the liquid composition for the hard surface filled in the container is preferably from 200 to 500 mL in operation. Further, the filling of the liquid is carried out by leaving a void of common knowledge. The method for cleaning a hard surface of the present invention is preferably a method of cleaning a hard surface of a hard article, a hard surface of a tableware and a hard object around the kitchen, and a hard surface of the tableware. Further, it is preferably a hand-washing cleaning method for a hard surface of a hard article, a hand-washing cleaning method for a hard surface of a tableware and a hard object around the kitchen, and a hand-washing cleaning method for a hard surface of the tableware. The method for cleaning a hard surface of the present invention is to be cleaned by a hard surface of a hard article, preferably a hard surface of a tableware and a hard object around the kitchen, and a hard surface which is more preferably a tableware. Regarding hard articles, tableware, and hard articles around the kitchen, the above may be mentioned. Moreover, the method for cleaning a hard surface of the present invention is preferably a hard surface selected from the group consisting of a tableware, a storage container, a conditioning device, and a conditioning appliance, and more preferably selected from the group consisting of a dish, a bowl, a sealed container, and a bottle. The hard surface of the kitchen knife, chopping board, pot, frying pan, grilled fish rack, food processor, and mixer. The material of the hard surface which is the object of the cleaning method of the hard surface of the present invention may, for example, be a plastic (including a polyoxyxylene resin), a metal, a ceramic, a wood, or a combination thereof. Further, the method for cleaning a hard surface of the present invention can effectively clean the oil containing solid oil and fat adhering to the hard surfaces. In the method of cleaning a hard surface of the present invention, the hard surface liquid detergent composition of the present invention is brought into direct contact with a hard surface. Further, since it can be placed in a state of being in contact with the above composition, it is not necessary to apply a mechanical force such as scrubbing with a flexible material such as a sponge during cleaning. Therefore, the method for cleaning a hard surface of the present invention can also be applied to a food manufacturing machine, a refrigerator, a sideboard, etc., a tube, a part, a drain, and the like, which are inconvenient for hand-washing and cleaning, and the storage place of food, tableware, and conditioning equipment. Flowing tables, range hoods, sinks, gas stoves, microwave ovens, and other food conditioning areas, and surrounding kitchens such as floors or walls, etc., which contain solid oils and oils, which have hard surfaces, kitchen knives, peelers, Peeling tools, slicers, blades of juicers, blades of food processor, etc. Hand-washing and cleaning, dangerous items, water cans, tumblers, kettles, pots, etc. It is difficult to use an article such as a sponge having a complicated shape and the like, and it is difficult to use an article such as a sponge to clean the article. Furthermore, scrubbing can also be performed as needed. Further, in the method for cleaning a hard surface of the present invention, the composition for a hard surface of the present invention is preferably applied by applying a liquid detergent composition for a hard surface, preferably a foamed composition, to a hard surface. Stay on the hard surface for a long time. The method of cleaning a hard surface of the present invention may comprise the step of rinsing a hard surface in contact with the hard surface liquid detergent composition with water, preferably a hard surface in contact with the hard surface liquid detergent composition. The step of rinsing with water after standing. In the above embodiment, the present invention further discloses the following hard surface liquid detergent composition, a hard surface cleaning method, a spray container-mounted hard surface cleaning article, and use. In these aspects, the hard surface liquid detergent composition of the present invention, the hard surface cleaning method, and the spray container-mounted hard surface cleaning article can be suitably used. <1> A liquid detergent composition for a hard surface comprising (a) component, (b) component 0 mass% or more, less than 3% by mass, (c) component, and water, and (b) component The mass ratio of /[(a) component + (b) component + (c) component] is 0.3 or less. <Component (a)> Sulfosuccinate or a salt thereof represented by the following formula (a1) [Chemical 5] [where, R ^1a , R ^2a Hydrocarbon groups having a carbon number of 5 or more and 18 or less, respectively; A ¹ , A ² Each of them is independently an alkylene group having a carbon number of 2 or more and 4 or less, and x and y are the average addition molar number and are independently 0 or more and 6 or less; ¹ a hydrogen atom or a cation] <(b) component> An anionic surfactant having a hydrocarbon group having 8 or more and 21 or less carbon atoms, and a sulfate group or a sulfonic acid group [excluding the component (a)] < (c) component > Two or more kinds of amphoteric surfactants selected from the group consisting of sulfobetaine and carbonyl betaine <2> A liquid surface cleaner composition for hard surface removal, which contains the following (a) component and (b) component 0 The mass ratio is not more than 3% by mass, the component (c), and water, and the mass ratio of the component (b)/[(a) component + (b) component + (c) component is 0.3 or less. <Component (a)> Sulfosuccinate or a salt thereof represented by the following formula (a1) [Chemical Formula 6] [where, R ^1a , R ^2a Hydrocarbon groups having a carbon number of 5 or more and 18 or less, respectively; A ¹ , A ² Each of them is independently an alkylene group having a carbon number of 2 or more and 4 or less, and x and y are the average addition molar number and are independently 0 or more and 6 or less; ¹ a hydrogen atom or a cation] <(b) component> An anionic surfactant having a hydrocarbon group having 8 or more and 21 or less carbon atoms, and a sulfate group or a sulfonic acid group [excluding the component (a)] < (c) component A liquid surfactant composition for a hard surface according to the above <1> or <2>, wherein the compound (a1) is in the formula (a1) ,R ^1a , R ^2a Each of the hydrocarbon groups independently having a carbon number of 5 or more, preferably 6 or more, more preferably 7 or more, and having a carbon number of 18 or less, preferably 16 or less, more preferably 14 or less, is preferably a straight chain or a branched chain. An alkyl group, more preferably a branched alkyl group. (4) The liquid surface cleaner composition for hard surfaces according to any one of the above-mentioned <1>, wherein A in the formula (a1), A ¹ , A ² Each is independently an alkylene group having 2 or more carbon atoms and 4 or less carbon atoms, preferably 3 or less. The hard surface liquid detergent composition as described in any one of the above-mentioned <1>, wherein x and y are the average addition molar number, and each independently is 0 or more, and 6 or less, preferably 4 or less, more preferably 2 or less, still more preferably 0. The hard surface liquid detergent composition according to any one of the above-mentioned items, wherein x+y is preferably 0 or more, and preferably 12 or less, in the formula (a1), More preferably, it is 6 or less, further preferably 3 or less, and still more preferably 0. <7> The liquid surface cleaner composition for hard surfaces according to any one of the above-mentioned <1>, wherein R in the formula (a1), R ^1a , R ^2a Preferably, it is selected from the group consisting of ketone, octyl, decyl, decyl, dodecyl, tridecyl, tetradecyl, 2-ethylhexyl, n-octyl, second octyl, isopentyl. Or an alkyl group of an isodecyl group, an isodecyl group or a cyclohexyl group, more preferably an alkyl group selected from the group consisting of n-octyl group, second octyl group, decyl group, isodecyl group and 2-ethylhexyl group, and further preferably 2-ethylhexyl, tridecyl, and more preferably 2-ethylhexyl. The hard surface liquid detergent composition as described in any one of the above-mentioned <1>, wherein M in the formula (a1), M ¹ Preferably, it is a hydrogen atom, or an inorganic cation such as a sodium ion, an ammonium ion, a potassium ion or a magnesium ion, or an organic cation such as a monoethanolamine, a diethanolamine, a triethanolamine or a salt of a salt, more preferably selected from sodium. Inorganic cations of ions, ammonium ions, potassium ions, and magnesium ions. The hard surface liquid detergent composition as described in any one of the above-mentioned <1> to <8> preferably contains the component (a) in an amount of 0.5% by mass or more, more preferably 0.8% by mass or more. It is preferably 1% by mass or more, more preferably 1.5% by mass or more, still more preferably 1.7% by mass or more, and is preferably 30% by mass or less, more preferably 20% by mass or less, and still more preferably 15% by mass. % or less is more preferably 10% by mass or less, still more preferably 8% by mass or less, still more preferably 5% by mass or less, and still more preferably 3% by mass or less. The hard surface liquid detergent composition according to any one of the above aspects, wherein the hydrocarbon group of the component (b) has a carbon number of 8 or more, preferably 10 or more, more preferably An alkyl group or an aryl group of 12 or more and 21 or less, preferably 18 or less, more preferably 14 or less, still more preferably 12 or less. The hard surface liquid detergent composition as described in any one of the above-mentioned <1>, wherein the component (b) is selected from the group consisting of alkyl sulfate salts and polyoxyalkylene alkyl ether sulfates. An anionic surfactant of one or more of an ester salt and an alkanesulfonate. The hard surface liquid detergent composition as described in any one of the above-mentioned <1>, wherein the component (b) is an anionic surfactant selected from one or more of the following: having a carbon number of a linear or branched alkyl alkyl sulfate having 8 or more, preferably 10 or more, 21 or less, preferably 18 or less, more preferably 14 or less, still more preferably 12 or less; having a carbon number a linear or branched alkyl group having 8 or more, preferably 10 or more, 21 or less, preferably 18 or less, more preferably 14 or less, still more preferably 12 or less, and having a carbon number of 2 or more and 3 The average addition molar number of the following oxygen alkyl group is preferably 0.1 or more, more preferably 0.3 or more, still more preferably 0.4 or more, and is preferably 6 or less, more preferably 3 or less, still more preferably 1.5. a polyoxyalkylene alkyl sulfate ether salt of the following polyoxyalkylene alkyl group; and preferably an alkylbenzene sulfonate having an alkyl group having 6 or more and 15 or less carbon atoms; and a carbon number of 8 or more The alkanesulfonate is preferably 10 or more, and 21 or less, preferably 18 or less, more preferably 14 or less, still more preferably 12 or less. The hard surface liquid detergent composition as described in any one of the above-mentioned <1>, wherein the component (b) is a compound of the following formula (b1). R ^1b -O-(R ^2b O) _n -SO ₃ M ² (b1) [where, R ^1b a linear or branched alkyl group having a carbon number of 8 or more and 21 or less, R ^2b For stretching ethyl and/or stretching propyl, n is the average addition molar number and is 0 or more and 6 or less; M ² The hydrogen atom or a cation, preferably an inorganic or organic cation. The liquid cleansing composition for a hard surface according to the above <13>, wherein R in the formula (b1), R ^1b It is preferably a linear or branched alkyl group having a carbon number of 8 or more, more preferably 10 or more, and preferably 18 or less, more preferably 14 or less, still more preferably 12 or less, preferably a linear alkyl group. . <15> The liquid surface cleaner composition for hard surfaces according to the above <13> or <14>, wherein, in the formula (b1), R ^1b It is an alkyl group selected from the group consisting of octyl, decyl, dodecyl, tridecyl, and tetradecyl, preferably dodecyl. The hard surface liquid detergent composition of any one of the above-mentioned <13>, wherein n is preferably 0.1 or more, more preferably 0.3 or more, and further, in the formula (b1). It is preferably 0.4 or more, and is preferably 6 or less, more preferably 3 or less, still more preferably 1.5 or less. <17> The liquid surface cleaner composition for hard surfaces according to any one of the above <13>, wherein, in the formula (b1), M ² Is a hydrogen atom, an inorganic cation or an organic cation, preferably a hydrogen atom, an inorganic cation selected from the group consisting of sodium ion, ammonium ion, potassium ion, and magnesium ion, or selected from the group consisting of monoethanolammonium ion, diethanolammonium ion, and triethanolammonium salt. The organic cation of the ion, &#134156; porphyrin is more preferably an inorganic cation selected from the group consisting of sodium ion, potassium ion, ammonium ion, and magnesium ion. The hard surface liquid detergent composition according to any one of the above-mentioned items, wherein the component (b) contains 0% by mass or more, and is less than 3% by mass, preferably 2.5% by mass. % or less is more preferably 2% by mass or less, further preferably 1.5% by mass or less, further preferably 1% by mass or less, further preferably less than 1% by mass, further preferably 0.5% by mass or less, and further preferably The amount is preferably less than 0.5% by mass, more preferably 0.1% by mass or less, still more preferably less than 0.1% by mass, or 0% by mass. The hard surface liquid detergent composition as described in any one of the above-mentioned <1> to <18> preferably contains (b) component 0.1% by mass or more, more preferably 0.3% by mass or more, and further It is preferably 0.5% by mass or more, and more preferably 1% by mass or more. The liquid surface cleaner composition for hard surfaces according to any one of the above aspects, wherein the sulfobetaine is a sulfobetaine selected from the group consisting of: the carbon number of the alkyl group is preferably N-alkyl-N,N-dimethyl-N-sulfopropyl ammonium sulfobetaine having 10 or more, preferably 18 or less, more preferably 14 or less; the carbon number of the alkyl group is preferably 10 or more, Preferably, it is 18 or less, more preferably 14 or less, of N-alkyl-N,N-dimethyl-N-(2-hydroxysulfonyl)ammonium sulfobetaine; the carbon number of the alkylhydrazine group is preferably N-alkylmercaptopropylpropyl-N,N-dimethyl-N-sulfopropyl ammonium sulfobetaine having 10 or more, preferably 18 or less, more preferably 14 or less; carbon number of alkyl fluorenyl group N-alkyldecylaminopropyl-N,N-dimethyl-N-(2-hydroxysulfonyl)ammonium sulfone beet is preferably 10 or more, preferably 18 or less, and more preferably 14 or less. Alkali. The hard surface liquid detergent composition according to any one of the above aspects, wherein the carbonyl betaine is preferably a carbon number selected from the group consisting of alkyl groups, preferably 10 or more, preferably 18 or less. More preferably, it is an N-alkyl-N,N-dimethyl-N-carboxymethylammonium betaine having 14 or less, and a carbonyl betaine of a compound represented by the following formula (c1). [Chemistry 7] (where, R ^1c An alkyl group or an alkenyl group having a carbon number of 7 or more and 21 or less, R ^2c Express propyl, R ^3c And R ^4c The liquid cleansing composition for a hard surface according to the above <21>, wherein R in the formula (c1), R ^1c It is preferably an alkyl group or an alkenyl group having a carbon number of 9 or more, more preferably 11 or more, and preferably 15 or less, more preferably 13 or less, and further an anthracenyl group, a fluorenyl group, an undecyl group, or a dodecyl group. , tridecyl. <23> The liquid surface cleaner composition for hard surfaces according to <21> or <22> above, wherein in the formula (c1), R ^C3 And R ^C4 Separate, preferably methyl. The hard surface liquid detergent composition as described in any one of the above-mentioned <1>, wherein the component (c) is preferably a sulfobetaine. The hard surface liquid detergent composition as described in any one of the above-mentioned <1> to <24> preferably contains the component (c) 0.1% by mass or more, more preferably 0.3% by mass or more, and further It is preferably 0.5% by mass or more, more preferably 1% by mass or more, still more preferably 1.5% by mass or more, and is preferably 30% by mass or less, more preferably 20% by mass or less, and still more preferably 15% by mass. % or less is more preferably 10% by mass or less, still more preferably 8% by mass or less, still more preferably 5% by mass or less, and still more preferably 3% by mass or less. The hard surface liquid detergent composition according to any one of the above-mentioned, wherein the total content of the component (a), the component (b) and the component (c) is preferably 0.6 mass. More preferably, it is 1% by mass or more, more preferably 2% by mass or more, further preferably 2% by mass or more, further preferably 2.5% by mass or more, further preferably 3% by mass or more, and further preferably 3% by mass or more. It is 4% by mass or more, and preferably 40% by mass or less, more preferably 35% by mass or less, further preferably 30% by mass or less, further preferably 25% by mass or less, and further preferably 20% by mass or less. Further, it is preferably 18% by mass or less, more preferably 15% by mass or less, still more preferably 10% by mass or less, and more preferably a total content of the components (a), (b) and (c). 0.1% by mass, 0.64% by mass, 2% by mass, and/or 20% by mass were removed. The hard surface liquid detergent composition as described in any one of the above-mentioned <1>, wherein the total of (a) component, (b) component, and (c) component among all surfactants. The ratio of the content is preferably 50% by mass or more, more preferably 60% by mass or more, still more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass or more, and more preferably It is 100% by mass or less. The hard surface liquid detergent composition as described in any one of the above-mentioned [a] component / [(a) component + (b) component + (c) component] The mass is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.3 or more, further preferably 0.35 or more, further preferably 0.4 or more, and more preferably 0.9 or less, still more preferably 0.85 or less, and further It is preferably 0.8 or less, more preferably 0.75 or less, further preferably 0.7 or less, and further preferably 0.65 or less. The hard surface liquid detergent composition as described in any one of the above-mentioned <1> (b) component / [(a) component + (b) component + (c) component] The mass ratio is 0.3 or less, preferably less than 0.3, preferably 0.26 or less, more preferably 0.2 or less, still more preferably less than 0.2, still more preferably 0.15 or less, still more preferably less than 0.15, and further more preferably Good is 0.1 or less, or 0. The hard surface liquid detergent composition as described in any one of the above-mentioned <1> (b) component / [(a) component + (b) component + (c) component] The mass ratio is 0 or more, preferably 0.03 or more, more preferably 0.05 or more, still more preferably 0.07 or more, further preferably 0.1 or more, further preferably 0.15 or more, further preferably 0.2 or more, or 0. The hard surface liquid detergent composition as described in any one of the above-mentioned <1> (c) component / [(a) component + (b) component + (c) component] The mass is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.3 or more, further preferably 0.35 or more, further preferably 0.4 or more, and more preferably 0.9 or less, still more preferably 0.85 or less, and further It is preferably 0.8 or less, more preferably 0.75 or less, further preferably 0.7 or less, and further preferably 0.65 or less. The hard surface liquid detergent composition according to any one of the above-mentioned, wherein the component (a) component/(c) component is preferably 0.1 or more, more preferably 0.2 or more. Further, it is preferably 0.3 or more, further preferably 0.4 or more, further preferably 0.5 or more, further preferably 0.6 or more, and more preferably 10 or less, still more preferably 8 or less, still more preferably 7 or less. Further, it is preferably 6 or less, more preferably 5 or less, further preferably 4 or less, further preferably 3 or less, further preferably 2 or less, further preferably 1 or less, and further preferably 0.8 or less. The hard surface liquid detergent composition of any one of the above-mentioned <1> which contains the alkyl glyceryl ether as (d) component. <34> The liquid surface cleaner composition for hard surfaces according to the above <33>, wherein the component (d) is preferably an alkyl monoglyceride having an alkyl group having 6 or more and 18 or less carbon atoms, more preferably the following a compound of the formula (d1). R ^1d -O-(Gly) _r -H (d1) [where, R ^1d An alkyl group having 6 or more carbon atoms and 18 or less carbon atoms, and Gly is a residue obtained by removing one hydroxyl group and one hydrogen atom from glycerin, and r is a number of 1 or more and 4 or less. <35> As described above, <34> A liquid surface cleaner composition for hard surfaces, wherein R in the formula (d1) ^1d It is preferably an alkyl group having a carbon number of 6 or more, more preferably a carbon number of 8 or more, and preferably a carbon number of 18 or less, more preferably a carbon number of 12 or less. <36> The liquid surface cleaner composition for hard surfaces according to the above <34> or <35>, wherein, in the formula (d1), R ^1d Preferred are alkyl groups selected from the group consisting of octyl, 2-ethylhexyl, decyl, and dodecyl. The hard surface liquid detergent composition as described in any one of the above-mentioned <34>, wherein r is preferably 1 in the formula (d1). The hard surface liquid detergent composition as described in any one of the above-mentioned <33>, which preferably contains (d) component 0.1 mass % or more, More preferably, it is 0.2 mass % or more, and further. It is preferably 0.5% by mass or more, more preferably 6% by mass or less, still more preferably 4% by mass or less, and still more preferably 2% by mass or less. The hard surface liquid detergent composition of any one of the above-mentioned <1> to <38> containing a solvent, preferably a water-soluble organic solvent as (e) component. <40> The liquid surface cleaner composition for hard surfaces according to the above <39>, wherein the component (e) is preferably a carbon number of 2 or more, more preferably a carbon number of 3 or more, more preferably a carbon number of 10 or less, more preferably It is a water-soluble organic solvent having a carbon number of 8 or less. The hard surface liquid detergent composition of any one of the above-mentioned <39>, wherein the component (e) is preferably selected from the group consisting of ethanol, isopropanol, ethylene glycol, propylene glycol, and Ethylene glycol, dipropylene glycol, glycerin, isoprene glycol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, 3-methyl-3-methoxybutanol, phenoxyethanol, phenylethylene glycol, phenoxy More than one water-soluble organic solvent of propanol, butyl diethylene glycol (diethylene glycol monobutyl ether), dibutyl butyl diethylene glycol, and benzyl alcohol, more preferably selected from butyl di One or more water-soluble organic solvents of diol, ethanol, and propylene glycol are more preferably one or more water-soluble organic solvents selected from the group consisting of butyl diethylene glycol, ethanol, and propylene glycol. The hard surface liquid detergent composition as described in any one of the above-mentioned <39>, preferably containing (e) component 0.5 mass % or more, more preferably 2 mass % or more, and further It is preferably 4% by mass or more, and is preferably 30% by mass or less, more preferably 20% by mass or less, and still more preferably 10% by mass or less. <43> The liquid surface cleaner composition for hard surfaces according to any one of the above-mentioned <39>, wherein the (e) component / [(a) component + (c) component] is preferably 0.5 in mass. The above is more preferably 1 or more, still more preferably 1.2 or more, still more preferably 1.5 or more, and further preferably 5 or less, more preferably 4 or less, further preferably 3 or less, and still more preferably 2.1 or less. More preferably, it is 2 or less. The hard surface liquid detergent composition as described in any one of the above-mentioned <39>, wherein the content of (e) component and (a) component, (b) component, and (c) component are. The mass ratio of the total content (e) component / [(a) component + (b) component + (c) component] is preferably 0.5 or more, more preferably 1 or more, still more preferably 1.2 or more, and furthermore It is preferably 1.5 or more, and is preferably 5 or less, more preferably 4 or less, still more preferably 3 or less, still more preferably 2.1 or less, still more preferably 2 or less. The hard surface liquid detergent composition as described in any one of <1> to <44> which contains a dissolution adjuvant as (f) component. <46> The liquid surface cleaner composition for hard surfaces according to the above <45>, wherein the component (f) is preferably toluenesulfonic acid, xylenesulfonic acid, or cumenesulfonic acid, or the sodium salt thereof. A potassium salt or a magnesium salt is more preferably p-toluenesulfonic acid or a salt thereof. <47> The liquid surface cleaner composition for a hard surface according to the above <45> or <46>, which preferably contains (f) a component of 0.5% by mass or more, more preferably 1% by mass or more, and still more preferably 1.5. The mass% or more is preferably 15% by mass or less, more preferably 10% by mass or less, and still more preferably 5% by mass or less. The hard surface liquid detergent composition of any one of the above-mentioned <1> which contains the fatty acid of 8 or more and 22 or less, or the salt of (g). <49> The liquid surface cleaner composition for hard surfaces according to the above <48>, wherein the component (g) has a carbon number of 8 or more, more preferably 10 or more, and preferably has a carbon number of 22 or less, more preferably 18 or less. Further, it is preferably 14 or less fatty acids or salts thereof. <50> The liquid surface cleaner composition for hard surfaces according to the above <48>, wherein the component (g) is one selected from the group consisting of citric acid, lauric acid, myristic acid, palmitic acid or a salt thereof. The above is more preferably one or more selected from the group consisting of citric acid, lauric acid, myristic acid, and the like, and more preferably one or more selected from the group consisting of citric acid, lauric acid, and a salt thereof. The hard surface liquid detergent composition as described in any one of the above-mentioned <48>, preferably containing (g) component 0 mass % or more, and preferably 3% by mass or less More preferably, it is less than 3% by mass, more preferably 2.5% by mass or less, further preferably 2% by mass or less, further preferably 1.5% by mass or less, further preferably 1% by mass or less, and further preferably It is less than 1% by mass, more preferably 0.5% by mass or less, further preferably less than 0.5% by mass, further preferably 0.1% by mass or less, further preferably less than 0.1% by mass, or 0% by mass. The hard surface liquid detergent composition as described in any one of the above-mentioned <48>, preferably, the total (b) component and (g) component are 0 mass % or more, and The amount is preferably less than 3% by mass, more preferably 2.5% by mass or less, still more preferably 2% by mass or less, further preferably 1.5% by mass or less, further preferably 1% by mass or less, and further preferably less than 1% by mass. The mass% is more preferably 0.5% by mass or less, further preferably less than 0.5% by mass, further preferably 0.1% by mass or less, further preferably less than 0.1% by mass, or 0% by mass. The liquid surface cleaner composition for hard surfaces as described in any one of the above-mentioned <48>, the total content of (a) component, (b) component, (c) component, and (g) component. It is preferably 0.6% by mass or more, more preferably 1% by mass or more, further preferably 2% by mass or more, further preferably 3% by mass or more, further preferably 4% by mass or more, and more preferably 40% by mass. % or less is more preferably 35% by mass or less, further preferably 30% by mass or less, further preferably 25% by mass or less, further preferably 20% by mass or less, further preferably 15% by mass or less, and further preferably more preferably It is 10% by mass or less. The hard surface liquid detergent composition as described in any one of the above-mentioned <48>, wherein (a) component, (b) component, (c) component, and ( The ratio of the total content of the components of g) is preferably 50% by mass or more, more preferably 60% by mass or more, still more preferably 70% by mass or more, still more preferably 80% by mass or more, and still more preferably 90% by mass or more. And, it is preferably 100% by mass or less. The hard surface liquid detergent composition as described in any one of the above-mentioned <48>, wherein (a) component / [(a) component + (b) component + (c) component + ( The mass of the component g) is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.3 or more, further preferably 0.35 or more, further preferably 0.4 or more, and more preferably 0.9 or less, more preferably It is 0.85 or less, more preferably 0.8 or less, further preferably 0.75 or less, further preferably 0.7 or less, and further preferably 0.65 or less. The liquid surface cleaner composition for hard surfaces of any one of the above-mentioned <48>, [(b) component + (g) component] / [(a) component + (b) component. The mass of the (c) component + (g) component is preferably 0.3 or less, preferably less than 0.3, preferably 0.26 or less, more preferably 0.2 or less, still more preferably less than 0.2, still more preferably 0.15 or less, more preferably less than 0.15, still more preferably 0.1 or less, and further preferably 0 or more, preferably 0.03 or more, more preferably 0.05 or more, still more preferably 0.07 or more, still more preferably 0.1 The above is further preferably 0.15 or more, further preferably 0.2 or more, or 0. The hard surface liquid detergent composition according to any one of the above-mentioned <48>, wherein (c) component / [(a) component + (b) component + (c) component + ( The mass of the component g) is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.3 or more, further preferably 0.35 or more, further preferably 0.4 or more, and more preferably 0.9 or less, more preferably It is 0.85 or less, more preferably 0.8 or less, further preferably 0.75 or less, further preferably 0.7 or less, and further preferably 0.65 or less. The liquid surface cleaner composition for hard surfaces of any one of the above-mentioned <1>, wherein the total content of the solid content component is preferably 0.6% by mass or more, more preferably 1% by mass or more. Further, it is preferably 2% by mass or more, more preferably 3% by mass or more, still more preferably 4% by mass or more, and is preferably 60% by mass or less, more preferably 50% by mass or less, and still more preferably 45% by mass. The mass% or less is more preferably 40% by mass or less, further preferably 35% by mass or less, further preferably 30% by mass or less, and still more preferably 28% by mass or less. The liquid surface cleaner composition for hard surfaces of any one of the above-mentioned <1> which contains water. The liquid surface cleaner composition for hard surfaces according to any one of the above-mentioned items, which preferably contains 30% by mass or more, more preferably 50% by mass or more, and still more preferably 60%. The mass% or more is more preferably 70% by mass or more, and is preferably 98% by mass or less, more preferably 95% by mass or less, and still more preferably 90% by mass or less. The liquid surface cleaner composition for hard surfaces of any one of the above-mentioned <1> which is a pH value of 25 or more, Preferably it is 2 or more, More preferably, it is 4 or more, More preferably. The above is preferably 10 or less, more preferably 9 or less, still more preferably 8 or less. The hard surface liquid detergent composition according to any one of the above aspects, wherein the viscosity at 20 ° C is preferably 0.5 mPa·s or more, more preferably 1 mPa·s or more. Further, it is preferably 50 mPa·s or less, more preferably 20 mPa·s or less, further preferably 10 mPa·s or less, more preferably 7 mPa·s or less, and still more preferably 5 mPa·s or less. . The hard surface liquid detergent composition as described in any one of the above-mentioned <1> which is a hard surface of a hard article, and is a hard item selected from the hard goods of a tableware and a kitchen. It is used for hard surfaces, and is used for hard surfaces of tableware, and is also used for hand-washing and cleaning of hard surfaces of hard articles, and further for hand-washing and cleaning of hard surfaces of hard articles selected from tableware and hard objects around the kitchen, and further for tableware. Hand wash for hard surfaces. The liquid surface cleaner composition for hard surfaces of any one of the above-mentioned <1> which is a cleaning agent for the hard surface coating of a hard article, Preferably it is selected from the tableware and a cleaning agent for hard surface coating of hard articles of hard articles around the kitchen, more preferably a cleaning agent for applying a hard surface to tableware; or a cleaning agent for spraying a hard surface to a hard article, preferably A cleaning agent for a hard surface spray of a hard article selected from tableware and a hard object around the kitchen is more preferably a detergent for spraying a hard surface of the tableware. The hard surface liquid detergent composition as described in any one of the above-mentioned <1> to <64> which is not diluted, and is directly to a hard surface, preferably a hard object selected from a tableware and a kitchen. The hard surface of the hard object is better used for the hard surface contact of the tableware. The hard surface liquid detergent composition as described in any one of the above-mentioned <1> to <65>, which is a hard article, preferably selected from a food manufacturing machine such as a tube or a part, a tableware, and a kitchen. Hard articles for hard articles, more preferably hard articles selected from tableware and hard objects around the kitchen, and further preferably tableware as a cleaning object; or storage places for foods, tableware, conditioning utensils, and drains in refrigerators, sideboards, and the like , the flow table, the range hood, the sink, the gas stove, the microwave oven and other food conditioning places, and the surrounding floor or wall as a cleaning object; or the tableware, preferably dishes, bowls and other so-called tableware, sealed containers, Storage containers such as bottles, kitchen knives or chopping boards, pots, frying pans, grilled fish racks, and other conditioning appliances such as food processing machines and mixers; or selected from tableware, storage containers, conditioning equipment, and conditioning appliances It is used for articles, and is selected from the group consisting of dishes, bowls, sealed containers, bottles, kitchen knives, chopping boards, pots, frying pans, grilled fish racks, food processing machines, and mixers. The hard surface liquid detergent composition according to any one of the above-mentioned items, wherein the hard material is made of plastic, metal, ceramics, wood, and the like. In the liquid detergent composition for a hard surface according to the above <1> to <67>, 0.1% by mass, 0.64% by mass, and 2 parts may be removed from the total content of the component (a), the component (b), and the component (c). quality%. The liquid surface cleaner composition for hard surfaces of any one of the above-mentioned <1>- <67>, and the hard surface, and the hard surface adhered with oil stain, More preferably, it is a hard surface contact to which oily stains containing solid oils are adhered. The (b) component / [(a) of the hard surface liquid detergent composition of any one of the above-mentioned <1> to <67>. The mass of the component + (b) component + (c) component is preferably 0.15 or more, more preferably 0.2 or more, and 0.3 or less. The (b) component / [(a) of the hard surface liquid detergent composition of any one of the above-mentioned <1> to <67>. The mass of the component + (b) component + (c) component is preferably less than 0.2, and preferably 0 or more. The hard surface cleaning agent according to any one of the above-mentioned <1> to <67>, The material is in contact with the hard surface. The method of cleaning a hard surface according to any one of the above-mentioned <1> to <67>, wherein The material does not dilute and comes into contact with the hard surface. The hard surface cleaning agent according to any one of the above-mentioned <1> to <67>, wherein the hard surface liquid cleaning agent combination according to any one of the above-mentioned <1> to <67> The material is not diluted and is in contact with a hard surface to which oil stains containing solid oils are attached. The hard surface cleaning agent according to any one of the above-mentioned <1> to <67>, wherein the hard surface liquid cleaning agent combination according to any one of the above-mentioned <1> to <67> After the object is in contact with the hard surface, it is placed without applying mechanical force. The hard surface cleaning agent according to any one of the above-mentioned <1> to <67>, wherein the hard surface liquid cleaning agent combination according to any one of the above-mentioned items <1> to <67> The object is 100 cm in area relative to the hard surface ² It is preferably 0.1 g or more, more preferably 0.3 g or more, further preferably 0.4 g or more, and preferably 5 g or less, more preferably 3 g or less, still more preferably 2 g or less in contact ratio, preferably It is contacted by coating or spraying. The hard surface cleaning agent according to any one of the above-mentioned <1> to <67>, wherein the hard surface liquid cleaning agent combination according to any one of the above-mentioned <1> to <67> After the object is in contact with the hard surface, it is preferably placed for 10 seconds or longer, more preferably 20 seconds or longer, further preferably 30 seconds or longer, further preferably 40 seconds or longer, more preferably 50 seconds or longer, and still more preferably It is 1 minute or more, and is preferably 60 minutes or shorter, more preferably 30 minutes or shorter, further preferably 20 minutes or shorter, and still more preferably 10 minutes or shorter. The hard surface cleaning agent according to any one of the above-mentioned <1> to <67>, wherein the hard surface liquid cleaning agent combination according to any one of the above-mentioned <1> to <67> After the object is in contact with the hard surface, it is preferably placed for 10 seconds or longer, more preferably 20 seconds or longer, more preferably 30 seconds or longer, further preferably 40 seconds or longer, and more preferably 50 seconds or longer. Further, it is more preferably 1 minute or longer, and is preferably 60 minutes or shorter, more preferably 30 minutes or shorter, further preferably 20 minutes or shorter, further preferably 10 minutes or shorter, and still more preferably 5 minutes or shorter. The hard surface cleaning agent according to any one of the above-mentioned <1> to <67>, wherein the hard surface liquid cleaning agent combination according to any one of the above-mentioned <1> to <67> The contact with the hard surface is preferably 10 seconds or longer, more preferably 20 seconds or longer, further preferably 30 seconds or longer, further preferably 40 seconds or longer, more preferably 50 seconds or longer, and still more preferably 1 minute or longer. Further, it is preferably 60 minutes or shorter, more preferably 30 minutes or shorter, further preferably 20 minutes or shorter, further preferably 10 minutes or shorter, more preferably 5 minutes or shorter. The method for cleaning a hard surface according to any one of the above-mentioned items <1> to <78>, wherein the hard surface is immersed in the hard surface according to any one of the above items <1> to <67>. In the liquid detergent composition, the above-mentioned hard surface liquid detergent composition is brought into contact with a hard surface. The hard surface cleaning agent according to any one of the above-mentioned <1> to <67>, wherein the hard surface liquid cleaning agent according to any one of the above-mentioned <1> to <67> The article is sprayed or coated to contact the hard surface. The hard surface cleaning agent according to any one of the above-mentioned <1> to <67>, wherein the hard surface liquid cleaning agent is combined as described in any one of the above-mentioned <1> to <67>. The material is sprayed in the form of a droplet or coated in a foam form to be in contact with the hard surface. The hard surface cleaning method according to any one of the above-mentioned items <1> to <67>, wherein the hard surface liquid cleaning agent according to any one of the above items <1> to <67>, The composition is filled in a hard surface cleaning article made of a container having a sprayer, and the hard surface liquid detergent composition is brought into contact with the hard surface. The method for cleaning a hard surface according to any one of the above <68>, wherein the hard surface is a hard surface of a hard article, preferably a hard surface of a hard object around the tableware or the kitchen, and more preferably Preferably, the hard surface is a hard surface of a food manufacturing machine such as a tube or a part, a tableware or a hard object around the kitchen, preferably a hard surface of a hard object around the tableware or the kitchen, more preferably selected from the group consisting of Storage of foods, tableware, conditioning utensils such as refrigerators, sideboards, drains, flow tables, range hoods, sinks, gas stoves, microwave ovens, etc., and hard objects such as floors or walls around them. The surface; or the hard surface is a hard surface of the tableware, preferably a storage container such as a dish, a bowl, or the like, a sealed container, a bottle, etc., a kitchen knife or a chopping board, a pan, a frying pan, a grilled fish rack, and the like. a hard surface for conditioning utensils such as a food processor or a mixer; or the hard surface is selected from the group consisting of a tableware, a storage container, a conditioning device, and conditioning The hard surface of the article of the home appliance is further a hard surface selected from the group consisting of a dish, a bowl, a sealed container, a bottle, a kitchen knife, a chopping board, a pot, a frying pan, a grilled fish rack, a food processor, and a mixer. The method for cleaning a hard surface according to any one of the above <68>, wherein the hard surface is made of a plastic, a metal, a pottery, a wood, and the like. The method for cleaning a hard surface according to any one of the above aspects, wherein the hard surface liquid detergent composition is a hard surface liquid detergent composition for degreasing. <86> A detergent composition for a hard surface according to any one of the items <1> to <67>, wherein the liquid surface cleaner composition for a hard surface is filled in a container having a sprayer. <87> The hard surface cleaning agent article according to the above <86>, wherein the container having the atomizer is a manual spray device that does not use a propellant or an aerosol that uses a propellant, and is preferably selected from a trigger spray container and A manual spray device that does not use a propellant for a pump spray container is more preferably a trigger sprayer that can spray or coat the contents into droplets or foams, and is preferably provided with a spray of contents. A trigger sprayer of a droplet-like mechanism or a trigger sprayer having a mechanism for forming a foam (foam forming mechanism). <88> The use of the composition according to any one of the above <1> to <67>, which is used as a liquid surface cleaner for a hard surface, preferably as a hard surface for a tableware or a hard object around a kitchen. A liquid detergent is preferably used as a liquid surface cleaner for tableware. <89> The use of the composition according to any one of the above <1> to <67>, which is used as a liquid surface cleaner for oil removal, preferably as a tableware or a hard object around a kitchen. It is a liquid surface cleaner for hard surfaces for oil removal, and more preferably used as a liquid surface cleaner for oil removal for tableware. <90> The use of the composition according to any one of the above <1> to <67>, which is used as a method of bringing the composition into contact with a hard surface without dilution and applying mechanical force without applying mechanical force. The liquid surface cleaner for hard surfaces to be used is preferably a liquid surface cleaner for hard surfaces used as a tableware or a hard object around the kitchen, and more preferably a liquid surface cleaner for tableware. <91> The use of the composition according to any one of the above <1> to <67>, which is a method for cleaning a hard surface, which is to make the composition undiluted and hard surface, preferably It is a hard surface to which oil is adhered, and it is more preferable to adhere to a hard surface to which oil stain containing solid oil adheres. EXAMPLES The liquid surface cleaner composition for hard surfaces shown in Tables 1 and 2 was prepared using the following formulation components, and evaluated for the following items. The compositions of Tables 1 and 2 are liquid detergent compositions for hard surfaces for degreasing. The results are shown in Tables 1 and 2. The hard surface liquid detergent compositions of Tables 1 and 2 were prepared by a conventional method. That is, the components (a) to (g) are added to an appropriate amount of ion-exchanged water, and dissolved at room temperature (25 ° C), and then the pH (25 ° C) is adjusted to 6 by adding sodium hydroxide or/and hydrochloric acid. . Furthermore, the mass % of the formulated components in Table 1 are all based on the effective amount. The component (b) represents the mass% based on the amount based on the sodium salt, and the component (g) represents the mass% based on the amount based on the acid compound. Further, the component (f) represents the mass % based on the amount of the compound containing crystal water. <Mixing component> (a) component, sodium di-2-ethylhexyl sulfosuccinate (product name "Airrol CT-1L", manufactured by Toho Chemical Industry Co., Ltd.); in the general formula (a1), R ^1a , R ^2a Both are 2-ethylhexyl, x, y are 0, M ¹ It is a sodium compound, sodium ditridecyl sulfosuccinate (product name "PELEX TR", manufactured by Kao (stock)); in the formula (a1), R ^1a , R ^2a All are tridecyl, x, y are 0, M ¹ It is a sodium compound (b) component, PO0.6 sodium lauryl sulfate; in the formula (b1), R ^1b Is an alkyl group derived from a natural alcohol (octyl/indenyl/dodecyl=5/5/90 by mass), R ^2b For the propyl group, n is 0.6, M ² It is a sodium compound, sodium lauryl sulfate (product name "Emal 0", manufactured by Kao (stock)); in the formula (b1), R ^1b Is dodecyl, n is 0, M ² It is a sodium compound, EO2 sodium lauryl sulfate (product name "Emal 270J", manufactured by Kao (stock)); in the formula (b1), R ^1b Dodecyl, R ^2b For stretching ethyl, n is 2, M ² It is a sodium compound (c) component, and a lauryl hydroxy sulfobetaine (product name "AMPHITOL 20HD", manufactured by Kao (stock)) ・Lauryl propyl propyl carbonyl betaine (product name "AMPHITOL 20AB", Kao ( (manufacturing of the company) ・Lauryl betaine (product name "AMPHITOL 20BS", manufactured by Kao (stock)) (d) Component: 2-ethylhexyl glyceryl ether (product name "Penetol GE-EH", manufactured by Kao (share) (e) Ingredients: butyl diethylene glycol (product name "BDG-NS", manufactured by Japan Emulsifier (share)) (f) Component: p-toluenesulfonic acid monohydrate (product name "PTS M-7000" (Make): (g) Ingredients: lauric acid (product name "Lunac L-98", manufactured by Kao (stock)) (1) Cleansing power (solution immersion evaluation) Preparation of butter and rapeseed oil The sample was stained at a mass ratio of 9:1 (sample stains containing oil stains of solid oils, the same applies hereinafter). The mass of a polypropylene test piece of 30 mm (horizontal) × 80 mm (vertical) × 1 mm (thickness) was measured using a 4-position balance (x). A sample of the sample was prepared by uniformly coating the sample stain from the lower end to a height of 50 mm on both sides of the polypropylene test piece in a total of 0.02 to 0.03 g on both sides. The mass of the stained sheet was measured using a 4-position balance (y). 50 g of the hard surface liquid detergent composition was added to a 50 mL container (a cylindrical shape having an inner diameter of 35 mm × a height of 68 mm), and then one piece of the stain was placed in the container to be in contact with the above composition. At this time, the stain-adhered portion of the stained sheet is entirely immersed in the above composition in the container. The stained sheet was placed in the state shown in Table 1 in the state of the hard surface liquid detergent composition immersed in the above container, and then the stained sheet was taken out and rinsed with running water for 1 minute. At this time, the conditions of the running water rinse were as follows: the tap water temperature was 25 ° C, the flow rate was about 4 L/min, and the diameter of the opening of the faucet was about 15 mm. The stained sheet is held in such a manner that the tap water falling down from the stain sheet located vertically below 5 cm from the opening portion becomes 45°, and the angle is fixed until the upper end portion of the stain sheet is not attached with the stain, and the flow is passed through the stain. The tap water on the sheet rinses the entire surface of the cleaning part. At this time, the front and back sides were alternately washed every 10 seconds. After the completion of the rinsing, the stained sheet was dried, and thereafter, the mass was measured by a 4-position balance (z). The cleaning rate was determined by the following formula. Cleaning rate (%)={(y)-(z)}/{(y)-(x)}×100 (2) Cleaning power (evaluation of foam impregnation) Preparation of butter and rapeseed oil at 9:1 The mass is better than the one obtained by mixing it as a sample stain. The mass of a polypropylene test piece of 30 mm (horizontal) × 80 mm (vertical) × 1 mm (thickness) was measured using a 4-position balance (x). As a stained sheet, the sample stain was uniformly applied from the lower end to a height of 5 cm on both sides of the polypropylene test piece in such a manner that the total surface was 0.02 to 0.03 g. The mass of the stained sheet was measured using a 4-position balance (y). The hard surface was filled with a liquid detergent composition in a trigger spray container (Magiclean Handy Spray, manufactured by Kao), and sprayed in a foam in a 50 mL container (inner cylindrical shape having an inner diameter of 35 mm × a height of 68 mm). The above composition was repeated. The total amount of spray of the composition was about 5 g. Then, one piece of the stain is placed in the container, and the stained sheet is brought into contact with the foamy hard surface in the container with the liquid detergent composition. At this time, the portion of the stained sheet to which the stain adhered is entirely immersed in the foamed composition described above in the container. The stained sheet was placed in a state of being immersed in the foam for the time shown in Table 1, and thereafter, the stained sheet was taken out and rinsed with running water for 1 minute. At this time, the conditions of the running water rinse were as follows: the tap water temperature was 25 ° C, the flow rate was about 4 L/min, and the diameter of the opening of the faucet was about 15 mm. The stained sheet is held in such a manner that the tap water falling down from the stain sheet located vertically below 5 cm from the opening portion becomes 45°, and the angle is fixed until the upper end portion of the stain sheet is not attached with the stain, and the flow is passed through the stain. The tap water on the sheet rinses the entire surface of the cleaning part. At this time, the front and back sides were alternately washed every 10 seconds. After the completion of the rinsing, the stained sheet was dried, and thereafter, the mass was measured by a 4-position balance (z). The cleaning rate was determined by the following formula. Cleaning rate (%) = {(y) - (z)} / {(y) - (x)} × 100 (3) Foam specific volume Fill the hard surface with a liquid detergent composition in a trigger spray container (Magiclean Handy Spray, manufactured by Kao), was sprayed 10 times into a 200 mL graduated cylinder (inner diameter 40 mm) using the wide bubble mode of the above container. The mass of the 200 mL cylinder after spraying was measured using a 4-position balance, and the difference from the mass of the measuring cylinder before the spraying was set as the foam coating amount (g) (a). The volume (mL) (b) of the foam in the graduated cylinder was visually read. The specific volume of the foam was calculated by the following formula. Foam specific volume (mL/g) = (b) / (a) [Table 1] [Table 2] Comparing Example 5 of Table 1 with Examples 14 to 17 of Table 2 and Comparative Examples 4 to 5, it was confirmed that the mass ratio of (b) / [(a) + (b) + (c)] Example 5, which is 0, is excellent in cleaning power. On the other hand, it was confirmed that the foams of Examples 14 to 17 having a relatively large mass of (b)/[(a)+(b)+(c)] were large in specific volume. When the hard surface of the present invention is brought into contact with the liquid detergent composition, if Example 5 of Table 1 is compared with Examples 18 and 19 of Table 2, it can be confirmed that: (a) component + (b) Example 5, in which the total content of the component + (c) component is 5% by mass, is more excellent in the balance between the cleaning power and the raw material cost of the surfactant. When the hard surface composition of the present invention is brought into contact with the liquid detergent composition, it can be confirmed that the mass ratio of the component (a) to the component (c) is 1.5 in comparison with the examples 2 to 8 of Table 1. Example 6 is superior in terms of cleaning power. When the hard surface of the present invention is brought into contact with the liquid detergent composition, if Example 6 and Examples 9 to 13 of Table 1 are compared, it can be confirmed that (e) component / [(a) + ( Example 10 in which c)] has a mass ratio of 1.8 is superior in cleaning power. Further, if Example 5, Example 6, Example 16, and Example 17 were observed, the relationship between the cleaning rate under solution immersion of the examples and the cleaning rate under the foam impregnation of the examples Show the same tendency. According to this situation, it is known that the cleaning rate under solution immersion is related to the cleaning rate under foam immersion. In other examples, it can be confirmed that the value of the cleaning rate under the foam immersion can be estimated from the result of the solution immersion (cleaning rate). .

no

Claims (16)

A liquid surface cleaner composition for hard surface for oil removal, which comprises the following (a) component, (b) component 0 mass% or more, less than 3% by mass, (c) component, and water, and (b) component The mass ratio of the /[(a) component + (b) component + (c) component] is 0.3 or less; <(a) component> The sulfosuccinate or its salt represented by the following general formula (a1) 1] In the formula, R ^1a and R ^2a are each independently a hydrocarbon group having 5 or more and 18 or less carbon atoms; and A ¹ and A ² are each independently an alkyl group having 2 or more and 4 or less carbon atoms, and x and y are average additions. The number of ears is independently 0 or more and 6 or less; M ¹ is a hydrogen atom or a cation] <(b) component> An anionic surfactant having a hydrocarbon group having 8 or more and 21 or less and a sulfate group or a sulfonic acid group [Part of the (a) component] <Component (c)> One or more kinds of amphoteric surfactants selected from the group consisting of sulfobetaine and carbonyl betaine. The liquid detergent composition for a hard surface for oil removal according to claim 1, which comprises (a) a component of 0.5% by mass or more and 30% by mass or less. The liquid detergent composition for a hard surface for oil removal according to claim 1 or 2, which contains the component (c) in an amount of 0.1% by mass or more and 30% by mass or less. The liquid detergent composition for a hard surface for oil removal according to any one of claims 1 to 3, wherein the total content of the component (a), the component (b), and the component (c) is 0.6% by mass or more and 40% by mass. the following. The liquid surface cleaner composition for hard surfaces for degreasing according to any one of claims 1 to 4, which contains a fatty acid having a carbon number of 8 or more and 22 or less or a salt thereof of 0% by mass or more and 3% by mass or less. The liquid surface cleaner composition for hard surfaces for oil removal according to any one of claims 1 to 5, wherein the mass ratio of the component (a) to the component (c) is 0.1 or more and 10 or less. The liquid surface cleaner composition for hard surface removal according to any one of claims 1 to 6, which further contains (e) a solvent. The liquid surface cleaner composition for oil removal for oil removal according to any one of claims 1 to 7, which is for use in contact with a hard surface and for cleaning without applying mechanical force. A method of cleaning a hard surface, which comprises contacting the hard surface liquid detergent composition for oil removal according to any one of claims 1 to 8 with a hard surface to which oil is adhered. A method of cleaning a hard surface according to claim 9, wherein the hard surface liquid detergent composition for degreasing is contacted with the hard surface without being diluted. A method of cleaning a hard surface according to claim 9 or 10, wherein the liquid surface cleaner composition for hard surface for oil removal is placed in contact with the hard surface without applying a mechanical force. The method for cleaning a hard surface according to any one of claims 9 to 11, wherein the liquid surface cleaning agent composition for hard surface for oil removal is placed in contact with the hard surface for 10 seconds or more. The method for cleaning a hard surface according to any one of claims 9 to 12, wherein the hard surface liquid detergent composition for degreasing is sprayed or coated to be in contact with the hard surface. A method of cleaning a hard surface according to claim 13, wherein the liquid surface cleaner composition for hard surface for oil removal is sprayed onto the hard surface or sprayed onto the hard surface. The method of cleaning a hard surface according to any one of claims 9 to 14, wherein the oil stain is an oil stain containing solid oil. A spray container containing a hard surface cleaning agent article, which is obtained by filling a container for a degreaser hard surface liquid detergent composition according to any one of claims 1 to 8 in a container having a sprayer.