TW201731925A - Method for preparing heat-dissipating coating and the prepared heat-dissipating metal composite film to obtain a heat dissipating coating having good pollution resistance and high heat dissipation - Google Patents

Abstract

A method for preparing heat-dissipating coating includes the steps: a plastic material selected from the group consisting of fluorocarbon resin, fluorine resin, acrylic resin, polyurethane, polyurea, unsaturated polyester, epoxy resin, and mixtures of any two or more of the above substances being dissolved in a mixed solvent to obtain a plastic material mixture, wherein the weight ratio of the plastic material to the mixed solvent is 0.6 to 1.4; a filler selected from the group consisting of bamboo charcoal, carbon tube, graphite, graphene flakes, graphene, carbon sphere, carbon fiber, boron nitride, aluminum nitride, mica, silicon dioxide, titanium dioxide, silicon carbide, zinc oxide, germanium oxide, and mixtures of any two or more of the above substances, being added with the weight ratio in 0.1 to 10 of the plastic material into the mixed solvent to obtain a filler mixture, wherein the weight ratio of the filler to the mixed solvent is 0.3 to 10; stirring and mixing the plastic material mixture and the filler mixture uniformly. The heat dissipating coating prepared by this method has the advantages of good pollution resistance and high heat dissipation.

Description

Method for preparing heat-dissipating coating and metal heat-dissipating composite film made thereof

The invention relates to a preparation method of a heat dissipation coating and a metal heat dissipation composite film prepared thereby, in particular to a heat dissipation coating prepared by mixing a filler with a rubber compound, which has good anti-pollution property and high heat dissipation property.

According to heat dissipation components such as metal heat sinks and heat pipes, the heat dissipation effect is good, but it is expensive and not suitable for light-weight product design, so there is the development and application of heat-dissipating coatings. However, the existing heat-dissipating coating is cured on the heat-dissipating surface to form a heat-dissipating layer, and the heat-resistant layer formed after curing due to poor weather resistance, heat resistance, low-temperature resistance, and chemical resistance of the base material used. The heat dissipation is easily reduced by the adhesion of contaminants; in addition, the filler used in the existing heat-dissipating coatings does not take into account the powder density accumulation theory and reduces the contact area between the fillers, so the heat dissipation that can be exhibited is not high.

Sub-press, smart phones, tablets, notebooks, navigators or portable electronic devices, which have evolved from dual-core, quad-core, and eight-core... to increasingly higher processing clock processing chips; The development of mobile electronic devices is designed with short, thin and light design. Therefore, in order to achieve high computing efficiency and short and light requirements, the heat dissipation efficiency of mobile electronic devices is important. At present, the heat dissipation method of the mobile electronic device mainly uses simple opening, heat conduction, heat convection, etc., but these heat dissipation methods cannot load the heat energy generated by the high-performance wafers of today, and thus there is a problem of heat accumulation, heat energy. Uniform distribution, resulting in reduced heat dissipation efficiency inside the mobile electronic device.

In addition, usually, the chip of the electronic device is the main heat source during operation, and the heat dissipation is not only to lower the temperature of the chip itself to ensure that it can work normally within the required temperature range, but also to prevent partial overheating of the casing when the heat is dissipated. Consumers experience a bad experience. Therefore, solving the above problems of the conventional mobile electronic device is a main subject of the present invention.

The main object of the present invention is to provide a heat-dissipating paint preparation method and a metal heat-dissipating composite film thereof, which have the advantages of good anti-pollution property and high heat dissipation property.

Another object of the present invention is to provide a coating which can improve the surface heat dissipation effect, thereby solving the problem of high temperature when the electronic components of the mobile electronic device operate.

In order to achieve the above effects, the method adopted by the present invention comprises: (a) providing a compound selected from the group consisting of: fluorocarbon resin, fluororesin, acrylic resin, polyurethane, polyurea, unsaturated poly a group consisting of an ester, an epoxy resin and a mixture of any two or more of the above, dissolved in a mixed solvent, the weight ratio of the compound to the mixed solvent being 0.6 to 1.4 times, thereby obtaining a rubber compound mixture; b). providing a filler selected from the group consisting of: bamboo charcoal, carbon tube, graphite, graphene microchip, graphene, carbon sphere, carbon fiber, tantalum nitride, aluminum nitride, mica, ceria, titanium dioxide, a group consisting of cerium carbide, zinc oxide, cerium oxide and a mixture of any two or more of the above, adding a filler having a weight ratio of 0.1 to 10 times the weight of the rubber to a mixed solvent, the weight ratio of the filler to the mixed solvent 0.3 to 10 times to obtain a filler mixture; (c) to filter the mixture obtained by the step (a) and the mixture obtained by the step (b); (d). c) After mixing, the mixture of the rubber compound and the filler mixture are stirred and mixed. And (e). The heat-dissipating paint which is uniformly mixed by the step (d) is sprayed, coated, impregnated or transferred onto the surface of an object to be dried to form a heat-dissipating coating having a thickness of 3 um to 100 um. .

The heat-dissipating coating prepared according to the above-mentioned preparation method can be further coated on a metal layer to form a metal heat-dissipating composite film for mounting in an electronic device near a heat source or directly installed at a heat source; wherein the metal layer is composed of at least one layer of a thermally conductive metal and has a thickness of 3 um to 150 um, the metal layer has a first surface and a second surface; and the heat dissipation coating layer is coated on a first surface or/and a second surface of the metal layer; thereby forming a two-layer or three-layer metal heat-dissipating composite film.

With the above technical features, the heat-dissipating coating prepared by the invention has the advantages of good anti-pollution and high heat dissipation.

First, referring to FIG. 1, the method for preparing a nano heat-dissipating paint of the present invention comprises the following steps:

(a). Providing a compound selected from the group consisting of: a fluorocarbon resin, a fluororesin, an acrylic resin, a polyurethane, a polyurea ester, an unsaturated polyester, an epoxy resin, and a mixture of any two or more of the foregoing. The composition group is dissolved in a mixed solvent, and the weight ratio of the rubber compound to the mixed solvent is 0.6 to 1.4 times, thereby obtaining a rubber compound mixture 10; in this embodiment, the rubber compound mixed solvent is selected from the group consisting of: A group consisting of water, ethyl acetate, absolute ethanol, distilled water, and a mixture of any two or more of the foregoing.

(b). Providing a filler selected from the group consisting of: bamboo charcoal, carbon tube, graphite, graphene microchip, graphene, carbon sphere, carbon fiber, tantalum nitride, aluminum nitride, mica, cerium oxide, titanium dioxide a group consisting of cerium carbide, zinc oxide, cerium oxide and a mixture of any two or more of the above, adding 0.1 to 10 times the weight of the filler to a mixed solvent, preferably by weight ratio. A 0.1 to 0.6 times filler of the compound is added to a mixed solvent. The weight ratio of the filler to the mixed solvent is 0.3 to 10 times, preferably 0.3 to 0.8 times by weight of the filler to the mixed solvent, thereby obtaining a filler mixture 20; in this embodiment, the filler may have pores. The structure may or may not have a pore structure, or a filler having a pore structure and a non-porous structure may be added to the mixed solvent in different proportions; however, a filler having a pore structure is preferred. The mixed solvent of the filler includes a group selected from the group consisting of: Tina water, ethyl acetate, absolute ethanol, distilled water, and a mixture of any two or more of the above.

(c) filtering the compound mixture 10 obtained in the step (a) and the filler mixture 20 obtained in the step (b); in this embodiment, the mixture can be filtered using a 350 mesh screen. The liquid 10 is mixed with the filler 20.

(d). Mixing and mixing the compound mixture 10 and the filler mixture 20 which have been filtered through the step (c); in this embodiment, the compound mixture can be mixed with the filler by using a shear emulsifier at a high speed. The liquid was mixed for 10 minutes and uniformly mixed into a heat-dissipating paint 30.

And step (e). The heat-dissipating paint 30 which is uniformly mixed by the step (d) is sprayed, coated, impregnated or transferred onto the surface of an object G, as shown in FIGS. 2A and 2B, and dried to form A heat dissipation coating 40 having a thickness of 3 um to 100 um. In this embodiment, the object G is included as a heat source or a metal piece. In this embodiment, the heat dissipation coating 40 has a pore structure 41. Figure 9 is an electron micrograph showing the heat-dissipating coating 40 of the present invention.

According to the foregoing feature, a preferred embodiment of the heat-dissipating paint 30 of the present invention dissolves 120 g of fluorocarbon resin in 100 g of ethyl acetate to obtain a rubber compound mixture 10; and dissolves 30 g of bamboo charcoal in 100 g of distilled water to obtain a filler mixture. 20. The compound mixture 10 and the filler mixture 20 were filtered by a 350 mesh screen, and then the mixture of the compound and the filler were stirred at a high speed by a shear emulsifier for 10 minutes to obtain a uniform heat-dissipating paint 30.

Moreover, in the second embodiment of the heat-dissipating paint 30 of the present invention, 120 g of fluorocarbon resin is dissolved in 100 g of water to obtain a rubber compound mixture 10, and 30 g of naphtha charcoal is dissolved in 60 g of ethyl acetate to obtain a filler mixture 20 . Then, the preparation method of the above embodiment is filtered and mixed to obtain a uniform heat-dissipating paint 30.

Based on the composition of the above, the two embodiments of the heat dissipating coating 30 of the present invention mainly use a fluorocarbon resin as a rubber material for a heat dissipating coating, and the fluorine element introduced by the fluorocarbon resin has a large electronegativity and a strong fluorocarbon bond. Therefore, it has excellent weather resistance, heat resistance, low temperature resistance and chemical resistance, and has unique self-cleaning properties, which in turn produces anti-pollution and environmental protection; and fluororesin, acrylic resin, polyurethane, polyurea ester, unsaturated Polyester or epoxy resin, etc., also have equivalent functions to fluorocarbon resins. In addition, the filler is selected from the group consisting of bamboo charcoal, carbon tube, graphite, graphene microchip, graphene, carbon sphere, carbon fiber, tantalum nitride, aluminum nitride, mica, cerium oxide, titanium dioxide, tantalum carbide, zinc oxide, cerium oxide or The combination of the foregoing fillers is used as a filler for the heat-dissipating coating, and since the filler has a highly developed pore structure 41, the surface area is large, the diffusion surface area is increased, and the heat dissipation rate is accelerated; and the high radiant energy and low heat enthalpy are also advantageous. Improve the heat dissipation effect of the material; it has the effect of good anti-pollution and high heat dissipation. Further, a combination selected from the group consisting of dicamba, ethyl acetate, absolute ethanol, distilled water or the aforementioned mixed solvent is used as a mixed solvent, and since the mixed solvent has a good dissolving effect, it also has an effect of facilitating uniform dispersion of the filler.

The heat dissipation characteristic test of the heat dissipation coating 40 of the present invention is carried out by using two aluminum plates whose length and width are about the size of a five-inch mobile phone, that is, a length (140 mm) x a width (700 mm) x a thickness (3 mm) as a substrate. One of the aluminum plates was used as a control group for the die, and the other was sprayed with a heat-dissipating paint 30 on the surface thereof to form a heat-dissipating coating 40 having a dry film thickness of 100 μm. Then, two aluminum plates were placed on a heating plate, and the output power was fixed at 38 volts (V). The whole temperature change process was observed and recorded. As shown in FIG. 8, the curve A was an aluminum plate not sprayed with the heat dissipation coating 40. The temperature change curve of the heat source when in contact with the heat source, and the curve B is the temperature change curve of the heat source when the aluminum plate coated with the heat-dissipating coating is in contact with the heat source, and thus the comparison of the two curves shows that the heat-dissipating coating 40 of the present invention is sprayed. The aluminum plate has a faster surface temperature rise reaction and a lower temperature of the heat source, indicating a faster heat transfer rate. The heat dissipation coating 40 of the present invention contributes to heat conduction and heat radiation functions.

Based on the above configuration, as shown in FIG. 3, the present invention can apply the heat dissipation coating 40 to a metal layer 50 to form a metal heat dissipation composite film 60 for mounting in an electronic device 70. The position of the heat source is directly mounted on the heat source; wherein the metal layer 50 is composed of at least one layer of heat conductive metal and has a thickness of 3 um to 150 um, and the metal layer 50 has a first surface 51 and a second surface. The heat dissipation coating 40 is applied to the first surface 51 or the second surface 52 of the metal layer 50, thereby forming a two-layer metal heat dissipation composite film 60. In addition, as shown in FIG. 4, the heat dissipation coating 40 may be simultaneously coated on the first surface 51 and the second surface 52 of the metal layer 50; thereby forming a three-layer metal heat dissipation composite film 60. Therefore, the heat dissipation coating 40 may be applied to any surface of the metal layer 50 as needed, or the first surface 51 and the second surface 52 may be simultaneously coated. Of course, the heat dissipation coating 40 may also be coated on the surface. The non-metallic surface may also be coated on the layered or three-dimensional structure of the temperature uniform layer, for example, a uniform temperature layer is first coated on the surface of the metal layer 50, and then the heat dissipation coating 40 is coated. On the uniform temperature layer, it is more effective to obtain longitudinal and lateral heat dissipation.

In this embodiment, the metal layer 50 may comprise any one of a two-dimensional or three-dimensional structure. The metal layer 50 is a single metal layer, which may be selected from the group consisting of copper, aluminum, titanium, silver, gold, copper alloys, aluminum alloys, silver alloys, titanium alloys or stainless steels, of any of which. The main function of the metal layer is heat conduction, heat dissipation and structural function. The composition can be divided into single metal layer or composite metal layer. The single metal layer can be copper or aluminum or titanium or silver or gold or copper alloy or aluminum alloy or silver alloy. Or titanium or stainless steel. The composite metal layer may be formed by the above-mentioned single metal or the third method according to the stacking manner, and the stacking manner is a dense structure formed by physical or chemical means, and has heat conduction, heat dissipation and structural functions.

5 to 7, the metal heat-dissipating composite film 60 of the present invention is shown in a state of use of the electronic device 70, which is shown in FIG. The electronic device 70 generally includes: a panel 71; a liquid crystal display module 72 is disposed under the transparent substrate 71; a middle bracket 73 is disposed under the liquid crystal display module 72; a circuit board 74, disposed under the middle casing bracket 73, at least an electronic chip 75 is disposed thereon; a battery 76 is disposed below the middle casing bracket 73; and a rear cover 77 is relatively coupled to the middle casing The bottom edge of the bracket 73 has an accommodating space 771 for accommodating the aforementioned components. However, the above-mentioned member is a prior art (Prior Art), and is not a patent of the present invention.

The heat dissipating composite film 60 of the present invention helps the inside of the electronic device 70 or the heat sink of the housing. For example, the metal heat dissipating composite film 60 is cut according to the shape of the shell bracket 73 or the back cover 77 of the electronic device 70. Cut into an appropriate size, and then attached to the middle shell bracket 73 or the rear cover 77, or the member close to the heat source such as the middle shell bracket 73 or the back cover 77, or directly mounted on the heat source, integrally injection molding The heat of the electronic chip 75 is transmitted upward or downward in a vertical direction, the heat generated by the electronic chip 75 is transmitted, the heat is dispersed horizontally, and then passed through the metal heat dissipation composite film 60 to achieve uniformity. Therefore, the metal heat dissipating composite film 60 formed by the sandwich type stack of the present invention has three functions of combining heat dissipation, heat conduction and temperature equalization, thereby maintaining the reliability of the mobile electronic device 70 and saving cost. . Furthermore, the metal layer can be composed of a multi-layer composite, thereby forming a high-strength and high-conductivity composite metal layer, which not only enhances the heat conduction function, but also strengthens the overall structural strength of the electronic device.

In summary, the technical means disclosed in the present invention have the invention patents such as "novelty", "progressiveness" and "available for industrial use", and pray for the patent to encourage the invention. German sense.

The drawings and the descriptions of the present invention are merely preferred embodiments of the present invention, and those skilled in the art, which are subject to the spirit of the present invention, should be included in the scope of the patent application.

10‧‧‧ compound mixture
20‧‧‧Filling mixture
30‧‧‧heating coating
40‧‧‧ Thermal coating
41‧‧‧Pore structure
50‧‧‧metal layer
51‧‧‧ first surface
52‧‧‧ second surface
60‧‧‧Metal heat-dissipating composite film
70‧‧‧Electronic devices
71‧‧‧Transparent substrate
72‧‧‧LCD module
73‧‧‧Shed bracket
74‧‧‧ boards
75‧‧‧Electronic chip
76‧‧‧Battery
77‧‧‧Back cover
771‧‧‧ accommodating space

1 is a process flow diagram of a method for preparing a heat-dissipating paint of the present invention. 2A is a schematic view showing the appearance of a heat dissipation coating of the present invention. Fig. 2B is an enlarged schematic view showing a part of the structure of Fig. 2A. 3 is an embodiment of a two-layer metal heat-dissipating composite film made by the heat-dissipating coating of the present invention. 4 is an embodiment of a three-layer metal heat-dissipating composite film made by the heat-dissipating coating of the present invention. FIG. 5 is a reference diagram (1) of the state in which the metal heat dissipating composite film of the present invention is installed in an electronic device. FIG. 6 is a reference diagram (2) of the state in which the metal heat dissipating composite film of the present invention is installed in an electronic device. Fig. 7 is a reference view (3) of the state in which the metal heat dissipating composite film of the present invention is mounted in an electronic device. Fig. 8 is a graph showing a comparison of temperature changes of an uncoated heat-dissipating aluminum sheet and an aluminum sheet coated with the heat-dissipating paint of the present invention. Figure 9 is an electron micrograph of the heat-dissipating coating of the present invention.

10‧‧‧ compound mixture

20‧‧‧Filling mixture

30‧‧‧heating coating

40‧‧‧ Thermal coating

Claims (8)

A method for preparing a heat-dissipating coating comprises the following steps: (a) providing a rubber selected from the group consisting of: a fluorocarbon resin, a fluororesin, an acrylic resin, a polyurethane, a polyurea ester, an unsaturated polyester, a group consisting of an epoxy resin and a mixture of any two or more of the above materials, dissolved in a mixed solvent, and the weight ratio of the rubber compound to the mixed solvent is 0.6 to 1.4 times, thereby obtaining a rubber compound mixture; (b) Providing a filler selected from the group consisting of: bamboo charcoal, carbon tube, graphite, graphene microchip, graphene, carbon sphere, carbon fiber, tantalum nitride, aluminum nitride, mica, cerium oxide, titanium dioxide, tantalum carbide a group consisting of zinc oxide, cerium oxide and a mixture of any two or more of the above, and a filler having a weight ratio of 0.1 to 10 times the compound is added to a mixed solvent, and the weight ratio of the filler to the mixed solvent is 0.3. Up to 10 times, thereby obtaining a filler mixture; (c) filtering the mixture of the mixture obtained in the step (a) and the mixture obtained by the step (b); (d). going through the step (c) The filtered rubber mixture and the filler mixture are stirred Mixing uniformly; and (e) cooling and uniformly mixing the heat-dissipating paint through the step (d), spraying, coating, impregnating or transferring onto the surface of an object to dry to form a heat dissipation of 3 um to 100 um. coating. The method for producing a heat-dissipating coating according to claim 1, wherein the filler has a pore structure. The method for preparing a heat-dissipating coating according to claim 2, wherein the mixed solvent of the compound and the filler comprises a mixture selected from the group consisting of: Tina water, ethyl acetate, absolute ethanol, distilled water, and a mixture of any two or more of the above. The group formed. The method for preparing a heat-dissipating coating according to claim 3 , wherein in the step (b), the filler is added in a mixed solvent in a weight ratio of 0.1 to 0.6 times the weight of the compound; and the weight of the filler and the mixed solvent The ratio is 0.3 to 0.8 times. The method for preparing a heat-dissipating coating according to claim 4 , wherein in the step (a), the compound mixture is composed of 120 g of a fluorocarbon resin compound and dissolved in a mixed solvent of 100 g of ethyl acetate. In the step (b): the filler mixture is composed of 30 g of a bamboo charcoal filler dissolved in a mixed solvent of 100 g of distilled water. The method for preparing a heat-dissipating coating according to claim 1, wherein the object of the step (e) comprises a heat source or a metal piece. A metal heat dissipating composite film comprising: a heat dissipating coating prepared by the preparation method of any one of claims 1 to 6, which is coated on a metal layer to form a metal heat dissipating composite film for mounting Provided in a position of the electronic device near the heat source or directly on the heat source; wherein the metal layer is composed of at least one layer of heat conductive metal and has a thickness of 3um-150um, the metal layer has a first surface and a a second surface; and the heat dissipation coating is applied on the first surface or/and the second surface of the metal layer; thereby forming a two-layer or three-layer metal heat dissipation composite film. The metal heat dissipating composite film of the electronic device of claim 7, wherein the metal layer is a single metal layer or a metal layer of two or more layers selected from the group consisting of copper, aluminum, titanium, silver, copper alloy, aluminum. An alloy, a silver alloy, a titanium alloy or a stainless steel, wherein any one or more of the metals are formed by stacking.