TW201914427A - Herbicide, herbicidal aid and preparation method and implementation method thereof - Google Patents
Herbicide, herbicidal aid and preparation method and implementation method thereof Download PDFInfo
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- TW201914427A TW201914427A TW106134563A TW106134563A TW201914427A TW 201914427 A TW201914427 A TW 201914427A TW 106134563 A TW106134563 A TW 106134563A TW 106134563 A TW106134563 A TW 106134563A TW 201914427 A TW201914427 A TW 201914427A
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- 239000004009 herbicide Substances 0.000 title claims abstract description 104
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims description 7
- 238000002360 preparation method Methods 0.000 title abstract description 6
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 239000000618 nitrogen fertilizer Substances 0.000 claims abstract description 14
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims abstract description 12
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- -1 polyoxy Polymers 0.000 claims description 46
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 36
- 239000003921 oil Substances 0.000 claims description 23
- 235000019198 oils Nutrition 0.000 claims description 23
- 239000002671 adjuvant Substances 0.000 claims description 22
- 239000003337 fertilizer Substances 0.000 claims description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 18
- 239000011259 mixed solution Substances 0.000 claims description 16
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 13
- 239000008158 vegetable oil Substances 0.000 claims description 13
- 150000002170 ethers Chemical class 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- 239000004359 castor oil Substances 0.000 claims description 9
- 235000019438 castor oil Nutrition 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 9
- 239000002480 mineral oil Substances 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- 238000005507 spraying Methods 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 150000002989 phenols Chemical class 0.000 claims description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 5
- 235000019482 Palm oil Nutrition 0.000 claims description 5
- 239000005662 Paraffin oil Substances 0.000 claims description 5
- 235000019483 Peanut oil Nutrition 0.000 claims description 5
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 5
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 5
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 5
- 239000011609 ammonium molybdate Substances 0.000 claims description 5
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 5
- 229940010552 ammonium molybdate Drugs 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical group N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 235000019868 cocoa butter Nutrition 0.000 claims description 5
- 229940110456 cocoa butter Drugs 0.000 claims description 5
- 239000003240 coconut oil Substances 0.000 claims description 5
- 235000019864 coconut oil Nutrition 0.000 claims description 5
- 235000012343 cottonseed oil Nutrition 0.000 claims description 5
- 239000002385 cottonseed oil Substances 0.000 claims description 5
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 5
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 5
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 5
- 239000003895 organic fertilizer Substances 0.000 claims description 5
- 239000002540 palm oil Substances 0.000 claims description 5
- 239000000312 peanut oil Substances 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 239000003549 soybean oil Substances 0.000 claims description 5
- 235000012424 soybean oil Nutrition 0.000 claims description 5
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical compound OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 claims description 3
- CDMGNVWZXRKJNS-UHFFFAOYSA-N 2-benzylphenol Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1 CDMGNVWZXRKJNS-UHFFFAOYSA-N 0.000 claims description 3
- HFDUROPAUBZDNU-UHFFFAOYSA-N 3-methyl-2-nonylphenol Chemical compound CCCCCCCCCC1=C(C)C=CC=C1O HFDUROPAUBZDNU-UHFFFAOYSA-N 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 229940100389 Sulfonylurea Drugs 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohex-2-enone Chemical compound O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- 235000010981 methylcellulose Nutrition 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 235000021317 phosphate Nutrition 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 229940124530 sulfonamide Drugs 0.000 claims description 3
- 150000003456 sulfonamides Chemical class 0.000 claims description 3
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims 1
- 229940070765 laurate Drugs 0.000 claims 1
- 239000004615 ingredient Substances 0.000 abstract description 3
- 241000196324 Embryophyta Species 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000001103 potassium chloride Substances 0.000 description 4
- 235000011164 potassium chloride Nutrition 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002420 orchard Substances 0.000 description 2
- VOYADQIFGGIKAT-UHFFFAOYSA-N 1,3-dibutyl-4-hydroxy-2,6-dioxopyrimidine-5-carboximidamide Chemical compound CCCCn1c(O)c(C(N)=N)c(=O)n(CCCC)c1=O VOYADQIFGGIKAT-UHFFFAOYSA-N 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000002895 emetic Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
本發明係關於一種除草劑，尤指人體危害性相對較低之除草劑、除草劑用助劑及其製備方法、使用方法。The invention relates to a herbicide, especially a herbicide with relatively low human hazard, an adjuvant for a herbicide, a preparation method and a use method thereof.
除草劑除了一般去除雜草的目的外，為方便採收作物(例如玉米、豆類等)，於實務上也會利用除草劑進行落葉處理，使作物有較為一致的成熟與乾枯。In addition to the general purpose of weed removal, herbicides are also used to facilitate the harvesting of crops (such as corn, beans, etc.). In practice, herbicides are also used for deciduous treatment to make the crops more mature and dry.
除草劑中的巴拉刈由於有落葉效果佳、便宜易取的優點，因此在過去一直是台灣廣受使用的除草劑。但巴拉刈對人體來說致死率非常高，因此近來各界不斷呼籲禁用或加強管制。Parabens in herbicides have been widely used as herbicides in Taiwan in the past due to their advantages of good deciduous effect and cheap and easy to take. However, the death rate of Balazone is very high for the human body. Therefore, various circles have recently called for banning or strengthening control.
針對上述問題，過去雖有技術是用來降低巴拉刈的危害性，例如台灣專利公告第229153號之「用於抑制巴拉刈所引致之毒性之醫藥組成物」，或者是添加嘔吐劑、臭味劑、警戒色素、抑制吸收成分等方式，但仍成效有限，也因此台灣近來已經規劃在2019年2月1日起全面禁用。In view of the above problems, although there are technologies used to reduce the harmfulness of balazone, for example, Taiwan Patent Publication No. 229153, "Medical composition for inhibiting the toxicity caused by balazone", or adding vomiting agents, Odors, alert pigments, and inhibiting the absorption of ingredients, but still have limited effectiveness, so Taiwan has recently planned to completely ban from February 1, 2019.
是以，如何開發出其他落葉效果佳且對人體低危害的除草劑，以取代巴拉刈或風險性相當的除草劑，便成為各界亟欲解決的課題。Therefore, how to develop other herbicides with good deciduous effect and low harm to human body to replace balazone or equivalent risky herbicides has become an urgent problem for all circles.
爰此，本發明人為開發出其他落葉效果佳且對人體低危害的除草劑，而提出一種除草劑，包含：介於30重量份至60重量份之間的氯酸鈉或/及氯酸鉀；介於5重量份至30重量份之間的油類，前述油類為礦物油或/及植物油；介於5重量份至30重量份之間的氮肥。Therefore, in order to develop other herbicides with good deciduous effect and low harm to the human body, the inventors proposed a herbicide comprising: sodium chlorate or potassium chlorate between 30 parts by weight and 60 parts by weight; Oils between 5 parts by weight and 30 parts by weight, the aforementioned oils are mineral oils and / or vegetable oils; nitrogen fertilizers between 5 parts by weight and 30 parts by weight.
本發明亦為一種除草劑用助劑，包含：介於30重量份至60重量份之間的氯酸鈉或/及氯酸鉀；介於5重量份至30重量份之間的油類，前述油類為礦物油或/及植物油；介於5重量份至30重量份之間的氮肥；介於5重量份至20重量份之間的表面活性劑。The present invention is also an auxiliary for herbicides, comprising: sodium chlorate or potassium chlorate between 30 parts by weight and 60 parts by weight; oils between 5 parts by weight and 30 parts by weight, the aforementioned oil Classes are mineral oils and / or vegetable oils; nitrogen fertilizers between 5 and 30 parts by weight; surfactants between 5 and 20 parts by weight.
本發明並可為一種除草劑用助劑之製備方法，包含下列步驟：介於5重量份至30重量份之間的氮肥加入50重量份至100重量份的純水，以形成一第一混合溶液；將介於5重量份至20重量份之間的表面活性劑加入該第一混合溶液中，以形成一第二混合溶液；將介於5重量份至30重量份之間的油類加入該第二混合溶液中，以形成一第三混合溶液；將介於30重量份至60重量份之間的氯酸鈉或/及氯酸鉀加入該第三混合溶液，以形成一除草劑用助劑。The present invention may also be a method for preparing an herbicide adjuvant, comprising the following steps: adding 50 to 100 parts by weight of nitrogen to a nitrogen fertilizer between 5 to 30 parts by weight to form a first mixture A solution; a surfactant between 5 and 20 parts by weight is added to the first mixed solution to form a second mixed solution; an oil between 5 and 30 parts by weight is added In the second mixed solution, a third mixed solution is formed; sodium chlorate or potassium chloride is added to the third mixed solution between 30 parts by weight and 60 parts by weight to form a herbicide additive .
本發明也可以是一種除草劑用助劑之使用方法，係使用如前所述之除草劑用助劑，將前述除草劑用助劑添加於一除草劑中進行噴灑作業，前述除草劑用助劑的含量為0.1重量份至5重量份，該除草劑選自由磺酰脲類除草劑、磺酰胺類除草劑、嘧唑啉酮類除草劑、三嗪類除草劑、環己烯酮類除草劑、芳氧基苯氧羧酸類除草劑、三酮類除草劑、有機磷類除草劑所組成之群組；或者於除草劑噴霧作業時以0.1重量份至5重量份的用量在除草劑噴灑液中噴霧。The present invention may also be a method for using an herbicide adjuvant, which uses the herbicide adjuvant as described above, and adds the aforementioned herbicide adjuvant to a herbicide for spraying operation, and the aforementioned herbicide adjuvant The content of the agent is 0.1 to 5 parts by weight, and the herbicide is selected from the group consisting of sulfonylurea herbicides, sulfonamide herbicides, pyrazolinone herbicides, triazine herbicides, and cyclohexenone herbicides. A group consisting of an agent, an aryloxyphenoxycarboxylic acid herbicide, a trione herbicide, an organophosphorus herbicide; or spraying the herbicide in an amount of 0.1 to 5 parts by weight during the herbicide spraying operation Spray in liquid.
進一步，前述油類選自由石蠟油、甘油、大豆油、花生油、棉籽油、菜籽油、棕櫚油、椰子油、可可油、烷基化的酯化植物油所組成之群組。Further, the aforementioned oils are selected from the group consisting of paraffin oil, glycerin, soybean oil, peanut oil, cottonseed oil, rapeseed oil, palm oil, coconut oil, cocoa butter, and alkylated esterified vegetable oil.
進一步，前述氮肥選自無機肥或/及有機肥。Further, the nitrogen fertilizer is selected from inorganic fertilizers and / or organic fertilizers.
進一步，前述無機肥選自由硫酸銨、硝酸銨、磷酸氫二銨、磷酸二氫銨、鉬酸銨、氨水所組成之群組；前述有機肥為尿素。Further, the foregoing inorganic fertilizer is selected from the group consisting of ammonium sulfate, ammonium nitrate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, ammonium molybdate, and ammonia water; the organic fertilizer is urea.
進一步，前述表面活性劑選自由甲基纖維素、陰離子表面活性劑、非離子表面活性劑、陽離子型表面活性劑所組成之群組。Further, the aforementioned surfactant is selected from the group consisting of methyl cellulose, an anionic surfactant, a non-ionic surfactant, and a cationic surfactant.
進一步，前述表面活性劑選自由烷氧基聚氧乙烯醚類、烷基酚聚氧、烷基醚類、烷基酚聚氧乙烯醚類、烷基酚聚氧丙烯醚類、垸基二苯醚類、芐基酚聚氧乙烯醚類、垸基萘磺酸鹽類、脂肪醇聚氧乙烯醚類、聚氧乙烯三矽氧垸、蓖麻油聚氧乙烯醚類、乙二醇聚氧乙烯醚類、垸基磷酸酯類、季銨鹽類、垸基吡啶鹽類、烷基酚聚氧乙烯醚甲醛縮合物鹽類、脂肪酸環氧乙烷加成物、松香酸環氧乙烷類、蓖麻油環氧乙垸加成物及其衍生物、山梨醇脂肪酸酯及其環氧乙垸加成物、苯酚衍生物乙氧基化物、甲縮壬基酚乙氧基化物、苯酚衍生物乙氧基丙氧基化物、聚乙二醇月桂酸酯類所組成之群組。Further, the surfactant is selected from the group consisting of alkoxy polyoxyethylene ethers, alkylphenol polyoxy, alkyl ethers, alkylphenol polyoxyethylene ethers, alkylphenol polyoxypropylene ethers, and fluorenyl diphenyl. Ethers, benzylphenol polyoxyethylene ethers, fluorenyl naphthalene sulfonates, fatty alcohol polyoxyethylene ethers, polyoxyethylene trisiloxane, castor oil polyoxyethylene ethers, ethylene glycol polyoxyethylene Ethers, fluorenyl phosphates, quaternary ammonium salts, fluorenyl pyridine salts, alkylphenol polyoxyethylene ether formaldehyde condensate salts, fatty acid ethylene oxide adducts, rosin acid ethylene oxide, Castor oil ethylene oxide adduct and its derivatives, sorbitol fatty acid ester and its ethylene oxide adduct, phenol derivative ethoxylate, methylnonylphenol ethoxylate, phenol derivative A group of ethoxypropoxylates and polyethylene glycol laurates.
進一步，前述表面活性劑選自由烷氧基聚氧乙烯醚類、烷基酚聚氧烷基醚類、垸基酚聚氧乙烯醚類、垸基酚聚氧丙烯醚類、脂肪醇聚氧乙烯醚類、聚氧乙烯三矽氧烷、蓖麻油聚氧乙烯醚類、乙二醇聚氧乙烯醚類、烷基酚聚氧乙烯醚甲醛縮合物鹽類、脂肪酸環氧乙烷加成物所組成之群組。Further, the surfactant is selected from the group consisting of alkoxy polyoxyethylene ethers, alkylphenol polyoxyalkyl ethers, fluorenyl phenol polyoxyethylene ethers, fluorenyl phenol polyoxypropylene ethers, and fatty alcohol polyoxyethylene. Ethers, polyoxyethylene trisiloxanes, castor oil polyoxyethylene ethers, ethylene glycol polyoxyethylene ethers, alkylphenol polyoxyethylene ether formaldehyde condensate salts, fatty acid ethylene oxide adducts Groups of people.
根據上述技術特徵可達成以下功效：According to the above technical features, the following effects can be achieved:
1.採用對人體危害較低的氯酸鈉或/及氯酸鉀與高量氮肥來作為除草劑或除草劑用助劑，以提供高人體危害性除草劑(例如巴拉刈)的替代方案。1. Sodium chlorate or / and potassium chlorate and high nitrogen fertilizer with low harm to human body are used as herbicides or herbicide adjuvants to provide an alternative solution for high human harm herbicides (such as balazone).
2.除草劑或除草劑用助劑含有礦物油或/及植物油之油類，使除草劑或除草劑用助劑可有效附著於植物表面，使植物可快速被脫水、乾燥。2. Herbicides or herbicide adjuvants contain mineral oils and / or vegetable oils, so that the herbicides or herbicide adjuvants can be effectively attached to the plant surface, and the plants can be quickly dehydrated and dried.
3.除草劑用助劑含有表面活性劑而可充分混合於除草劑中。3. The herbicide adjuvant contains a surfactant and can be sufficiently mixed in the herbicide.
綜合上述技術特徵，本發明除草劑、除草劑用助劑及其製備方法、使用方法的主要功效將可於下述實施例清楚呈現。In summary of the above technical features, the main effects of the herbicide, the herbicide adjuvant, the preparation method and the use method of the present invention will be clearly shown in the following examples.
以下揭示本發明第一實施例一種除草劑，包含：介於30重量份至60重量份之間的氯酸鈉或/及氯酸鉀，用以使植物脫水；介於5重量份至30重量份之間的油類，前述油類為礦物油或/及植物油，藉此讓除草劑可藉由油類有效附著於植物表面；介於5重量份至30重量份之間的氮肥，用以藉由高量氮肥使植物無法及時代謝氨，造成植物氨中毒，而可達到除草目的。The following discloses a herbicide according to the first embodiment of the present invention, which comprises: sodium chlorate or potassium chloride and / or potassium chlorate between 30 parts by weight and 60 parts by weight for dehydrating plants; between 5 parts by weight and 30 parts by weight Oils, the aforementioned oils are mineral oils and / or vegetable oils, so that the herbicide can be effectively attached to the plant surface by the oils; nitrogen fertilizers between 5 parts by weight and 30 parts by weight are used for The high amount of nitrogen fertilizer makes the plant unable to metabolize ammonia in time, causing plant ammonia poisoning, and can achieve the purpose of weeding.
舉例來說，前述油類可選自由石蠟油、甘油、大豆油、花生油、棉籽油、菜籽油、棕櫚油、椰子油、可可油、烷基化的酯化植物油所組成之群組。前述氮肥可選自無機肥或/及有機肥。詳細而言，前述無機肥可選自由硫酸銨、硝酸銨、磷酸氫二銨、磷酸二氫銨、鉬酸銨、氨水所組成之群組；前述有機肥為尿素。For example, the foregoing oils can be selected from the group consisting of paraffin oil, glycerin, soybean oil, peanut oil, cottonseed oil, rapeseed oil, palm oil, coconut oil, cocoa butter, and alkylated vegetable oils. The nitrogen fertilizer may be selected from inorganic fertilizers and / or organic fertilizers. In detail, the aforementioned inorganic fertilizer may be selected from the group consisting of ammonium sulfate, ammonium nitrate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, ammonium molybdate, and ammonia; the organic fertilizer is urea.
上述除草劑實際施用之成效，可先參閱第一A圖、第二A圖及第三A圖，皆為植物尚未被噴灑前除草劑之狀態。接著可分別對照第一B圖、第二B圖及第三B圖，皆為植物已經被噴灑前述除草劑且經過一天後的狀態，可見植物已有明顯乾枯的現象。其中施用條件：除草劑與水的比例為1:100(0.1L除草劑稀釋10l水)、利用噴霧器均勻噴灑於25平方公尺面積之蔬菜園畦間雜草及果樹園雜草。For the effectiveness of the above herbicide application, please refer to the first diagram A, the second diagram A, and the third diagram A, which are the states of the herbicide before the plants have been sprayed. Then, the first diagram B, the second diagram B, and the third diagram B can be compared, which are the states in which the plants have been sprayed with the herbicide and after one day, it can be seen that the plants have obviously dried up. The application conditions are as follows: the ratio of herbicide to water is 1: 100 (0.1L herbicide diluted 10 l of water), and the sprayer is used to uniformly spray weeds in the vegetable garden between 25 square meters and orchards in the orchard.
以下揭示本發明第二實施例除草劑用助劑，主要包含：介於30重量份至60重量份之間的氯酸鈉或/及氯酸鉀；介於5重量份至30重量份之間的油類，前述油類為礦物油或/及植物油；介於5重量份至30重量份之間的氮肥；介於5重量份至20重量份之間的表面活性劑。較佳的比例為：50重量份之氯酸鈉或/及氯酸鉀、5重量份之油類(礦物油或/及植物油)、30重量份之氮肥、10重量份之表面活性劑。The following discloses the auxiliary agent for the herbicide according to the second embodiment of the present invention, which mainly comprises: sodium chlorate or potassium chlorate between 30 parts by weight and 60 parts by weight; oil between 5 parts by weight and 30 parts by weight The aforementioned oils are mineral oils and / or vegetable oils; nitrogen fertilizers between 5 parts by weight and 30 parts by weight; and surfactants between 5 parts by weight and 20 parts by weight. The preferred ratio is: 50 parts by weight of sodium chlorate or potassium chloride, 5 parts by weight of oils (mineral oil or / and vegetable oil), 30 parts by weight of nitrogen fertilizer, and 10 parts by weight of surfactant.
前述油類可選自由石蠟油、甘油、大豆油、花生油、棉籽油、菜籽油、棕櫚油、椰子油、可可油、烷基化的酯化植物油所組成之群組。The aforementioned oils can be selected from the group consisting of paraffin oil, glycerin, soybean oil, peanut oil, cottonseed oil, rapeseed oil, palm oil, coconut oil, cocoa butter, and alkylated esterified vegetable oil.
前述氮肥可選自無機肥或/及有機肥。詳細而言，前述無機肥可選自由硫酸銨、硝酸銨、磷酸氫二銨、磷酸二氫銨、鉬酸銨、氨水所組成之群組；前述有機肥為尿素。The nitrogen fertilizer may be selected from inorganic fertilizers and / or organic fertilizers. In detail, the aforementioned inorganic fertilizer may be selected from the group consisting of ammonium sulfate, ammonium nitrate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, ammonium molybdate, and ammonia; the organic fertilizer is urea.
前述表面活性劑可選自由甲基纖維素、陰離子表面活性劑、非離子表面活性劑、陽離子型表面活性劑所組成之群組。詳細而言，前述表面活性劑可選自由烷氧基聚氧乙烯醚類、烷基酚聚氧、烷基醚類、烷基酚聚氧乙烯醚類、烷基酚聚氧丙烯醚類、垸基二苯醚類、芐基酚聚氧乙烯醚類、垸基萘磺酸鹽類、脂肪醇聚氧乙烯醚類、聚氧乙烯三矽氧垸、蓖麻油聚氧乙烯醚類、乙二醇聚氧乙烯醚類、垸基磷酸酯類、季銨鹽類、垸基吡啶鹽類、烷基酚聚氧乙烯醚甲醛縮合物鹽類、脂肪酸環氧乙烷加成物、松香酸環氧乙烷類、蓖麻油環氧乙垸加成物及其衍生物、山梨醇脂肪酸酯及其環氧乙垸加成物、苯酚衍生物乙氧基化物、甲縮壬基酚乙氧基化物、苯酚衍生物乙氧基丙氧基化物、聚乙二醇月桂酸酯類所組成之群組。或者，前述表面活性劑可選自由烷氧基聚氧乙烯醚類、烷基酚聚氧烷基醚類、垸基酚聚氧乙烯醚類、垸基酚聚氧丙烯醚類、脂肪醇聚氧乙烯醚類、聚氧乙烯三矽氧烷、蓖麻油聚氧乙烯醚類、乙二醇聚氧乙烯醚類、烷基酚聚氧乙烯醚甲醛縮合物鹽類、脂肪酸環氧乙烷加成物所組成之群組。The aforementioned surfactants can be selected from the group consisting of methyl cellulose, anionic surfactants, non-ionic surfactants, and cationic surfactants. In detail, the aforementioned surfactants can be selected from free alkoxy polyoxyethylene ethers, alkyl phenol polyoxy, alkyl ethers, alkyl phenol polyoxyethylene ethers, alkyl phenol polyoxypropylene ethers, Diphenyl ethers, benzyl phenol polyoxyethylene ethers, fluorenyl naphthalene sulfonates, fatty alcohol polyoxyethylene ethers, polyoxyethylene trisiloxane, castor oil polyoxyethylene ethers, ethylene glycol Polyoxyethylene ethers, fluorenyl phosphates, quaternary ammonium salts, fluorenyl pyridine salts, alkylphenol polyoxyethylene ether formaldehyde condensate salts, fatty acid ethylene oxide adducts, rosin acid ethylene oxide Alkanes, castor oil ethylene oxide adducts and derivatives, sorbitol fatty acid esters and ethylene oxide adducts, phenol derivatives ethoxylates, methylnonylphenol ethoxylates, A group of phenol derivatives, ethoxypropoxylates, and polyethylene glycol laurates. Alternatively, the aforementioned surfactants can be selected from alkoxy polyoxyethylene ethers, alkylphenol polyoxyalkyl ethers, fluorenyl phenol polyoxyethylene ethers, fluorenyl phenol polyoxypropylene ethers, and fatty alcohol polyoxylates. Vinyl ethers, polyoxyethylene trisiloxanes, castor oil polyoxyethylene ethers, ethylene glycol polyoxyethylene ethers, alkylphenol polyoxyethylene ether formaldehyde condensate salts, fatty acid ethylene oxide adducts A group of people.
續請參閱第四圖，係進一步說明上述除草劑用助劑之製備方法，包含步驟一(S1)、步驟二(S2)、步驟三(S3)及步驟四(S4)。其中該步驟一(S1)：將介於5重量份至30重量份之間的氮肥與50重量份至100重量份的純水相互混合，以形成一第一混合溶液。該步驟二(S2)：將介於5重量份至20重量份之間的表面活性劑與該第一混合溶液相互混合，以形成一第二混合溶液。該步驟三(S3)：介於5重量份至30重量份之間的油類與該第二混合溶液相互混合，以形成一第三混合溶液。該步驟四(S4)：將介於30重量份至60重量份之間的氯酸鈉或/及氯酸鉀與該第三混合溶液相互混合，以形成一除草劑用助劑。Continue to refer to the fourth figure, which further illustrates the preparation method of the herbicide auxiliary agent, including step one (S1), step two (S2), step three (S3), and step four (S4). The first step (S1): mixing nitrogen fertilizer between 5 parts by weight and 30 parts by weight with 50 parts by weight with 100 parts by weight of pure water to form a first mixed solution. The second step (S2): mixing the surfactant between 5 parts by weight and 20 parts by weight with the first mixed solution to form a second mixed solution. The third step (S3): the oil between 5 parts by weight and 30 parts by weight is mixed with the second mixed solution to form a third mixed solution. Step four (S4): mixing sodium chlorate or potassium chloride and / or potassium chlorate between 30 parts by weight and 60 parts by weight with the third mixed solution to form an herbicide adjuvant.
上述除草劑用助劑之使用方法，是將前述除草劑用助劑添加於一除草劑中，含量約為0.1重量份至5重量份。該除草劑可選自由磺酰脲類除草劑、磺酰胺類除草劑、嘧唑啉酮類除草劑、三嗪類除草劑、環己烯酮類除草劑、芳氧基苯氧羧酸類除草劑、三酮類除草劑、有機磷類除草劑所組成之群組。或者，使用上也可於除草劑噴霧作業時以0.1重量份至5重量份的用量在除草劑噴灑液中噴霧。The above-mentioned herbicide adjuvant is used by adding the foregoing herbicide adjuvant to a herbicide in an amount of about 0.1 parts by weight to 5 parts by weight. The herbicide can be selected from sulfonylurea herbicides, sulfonamide herbicides, pyrazolinone herbicides, triazine herbicides, cyclohexenone herbicides, and aryloxyphenoxycarboxylic acid herbicides. , Triketone herbicides, organophosphorus herbicides. Alternatively, it can also be sprayed into the herbicide spraying liquid in the amount of 0.1 to 5 parts by weight during the herbicide spraying operation.
綜合上述實施例之說明，當可充分瞭解本發明之操作、使用及本發明產生之功效，惟以上所述實施例僅係為本發明之較佳實施例，當不能以此限定本發明實施之範圍，即依本發明申請專利範圍及發明說明內容所作簡單的等效變化與修飾，皆屬本發明涵蓋之範圍內。Based on the description of the above embodiments, the operation, use, and effects of the present invention can be fully understood, but the above-mentioned embodiments are only preferred embodiments of the present invention, and it cannot be used to limit the implementation of the present invention. The scope, that is, simple equivalent changes and modifications made according to the scope of the patent application and the description of the invention, are all within the scope of the present invention.
(S1)‧‧‧步驟一(S1) ‧‧‧Step 1
(S2)‧‧‧步驟二(S2) ‧‧‧Step 2
(S3)‧‧‧步驟三(S3) ‧‧‧Step Three
(S4)‧‧‧步驟四(S4) ‧‧‧Step 4
[第一A圖]係本發明第一實施例除草劑使用前之照片一。 [第一B圖]係本發明第一實施例除草劑使用後之照片一。 [第二A圖]係本發明第一實施例除草劑使用前之照片二。 [第二B圖]係本發明第一實施例除草劑使用後之照片二。 [第三A圖]係本發明第一實施例除草劑使用前之照片三。 [第三B圖]係本發明第一實施例除草劑使用後之照片三。 [第四圖]係本發明第二實施例之除草劑用助劑之製備流程示意圖。[Figure A] Photograph 1 of the first embodiment of the herbicide before use. [Picture B] Photograph 1 after the application of the herbicide according to the first embodiment of the present invention. [Figure A] Photograph 2 of the first embodiment of the present invention before the herbicide is used. [Second B] Photograph 2 after the application of the herbicide according to the first embodiment of the present invention. [Third A] Photograph 3 of the first embodiment of the present invention before the herbicide is used. [Third B] Photograph III of the first embodiment of the present invention after the herbicide is used. [Fourth diagram] It is a schematic diagram of the preparation process of the herbicide auxiliary agent according to the second embodiment of the present invention.
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