TW201919578A - 油中水型乳化化妝料 - Google Patents
油中水型乳化化妝料 Download PDFInfo
- Publication number
- TW201919578A TW201919578A TW107130720A TW107130720A TW201919578A TW 201919578 A TW201919578 A TW 201919578A TW 107130720 A TW107130720 A TW 107130720A TW 107130720 A TW107130720 A TW 107130720A TW 201919578 A TW201919578 A TW 201919578A
- Authority
- TW
- Taiwan
- Prior art keywords
- oil
- water
- cosmetic
- present
- mass
- Prior art date
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 67
- 239000000839 emulsion Substances 0.000 title abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000002734 clay mineral Substances 0.000 claims abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 19
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- 239000000341 volatile oil Substances 0.000 claims abstract description 13
- -1 polysiloxane Polymers 0.000 claims description 57
- 229920001296 polysiloxane Polymers 0.000 claims description 32
- 239000000843 powder Substances 0.000 claims description 21
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000000806 elastomer Substances 0.000 claims description 3
- 229920002050 silicone resin Polymers 0.000 claims description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 1
- 239000004926 polymethyl methacrylate Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 30
- 238000002156 mixing Methods 0.000 abstract description 18
- 230000003020 moisturizing effect Effects 0.000 abstract description 10
- 238000002844 melting Methods 0.000 abstract description 8
- 230000008018 melting Effects 0.000 abstract description 8
- 229920002379 silicone rubber Polymers 0.000 abstract description 7
- 230000035807 sensation Effects 0.000 abstract description 3
- 230000001747 exhibiting effect Effects 0.000 abstract description 2
- 239000003814 drug Substances 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 33
- 235000019198 oils Nutrition 0.000 description 26
- 239000001993 wax Substances 0.000 description 19
- 239000000463 material Substances 0.000 description 18
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 16
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 16
- 239000004205 dimethyl polysiloxane Substances 0.000 description 15
- 239000000203 mixture Substances 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000004359 castor oil Substances 0.000 description 8
- 235000019438 castor oil Nutrition 0.000 description 8
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 8
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 7
- 241001135917 Vitellaria paradoxa Species 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 229920006037 cross link polymer Polymers 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 229940057910 shea butter Drugs 0.000 description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000000440 bentonite Substances 0.000 description 6
- 229910000278 bentonite Inorganic materials 0.000 description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 239000003093 cationic surfactant Substances 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 239000012188 paraffin wax Substances 0.000 description 6
- 239000013543 active substance Substances 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000010445 mica Substances 0.000 description 5
- 229910052618 mica group Inorganic materials 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 5
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000004200 microcrystalline wax Substances 0.000 description 4
- 235000019808 microcrystalline wax Nutrition 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- SOAINXKLHJAHCP-UHFFFAOYSA-N [Li+].C(CCCCCCCCCCCCCCCCC)[N+](C)(C)CCCCCCCCCCCCCCCCCC Chemical compound [Li+].C(CCCCCCCCCCCCCCCCC)[N+](C)(C)CCCCCCCCCCCCCCCCCC SOAINXKLHJAHCP-UHFFFAOYSA-N 0.000 description 3
- 239000010495 camellia oil Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 229910052901 montmorillonite Inorganic materials 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- JPPRXACMNPYJNK-UHFFFAOYSA-N 1-docosoxydocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC JPPRXACMNPYJNK-UHFFFAOYSA-N 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 2
- GQQNRZHWHWHOLI-UHFFFAOYSA-N 11-(2-decyltetradecoxymethyl)tricosane Chemical compound CCCCCCCCCCCCC(CCCCCCCCCC)COCC(CCCCCCCCCC)CCCCCCCCCCCC GQQNRZHWHWHOLI-UHFFFAOYSA-N 0.000 description 2
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 2
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- OCBUKACKKBOFNY-UHFFFAOYSA-N 9-(2-octyldecoxymethyl)heptadecane Chemical compound CCCCCCCCC(CCCCCCCC)COCC(CCCCCCCC)CCCCCCCC OCBUKACKKBOFNY-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004909 Moisturizer Substances 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000008278 cosmetic cream Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical group COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 2
- 230000001333 moisturizer Effects 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- YZUUTMGDONTGTN-UHFFFAOYSA-N nonaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCO YZUUTMGDONTGTN-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- 229960005323 phenoxyethanol Drugs 0.000 description 2
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- 230000037072 sun protection Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- HBGPNLPABVUVKZ-POTXQNELSA-N (1r,3as,4s,5ar,5br,7r,7ar,11ar,11br,13as,13br)-4,7-dihydroxy-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-2,3,4,5,6,7,7a,10,11,11b,12,13,13a,13b-tetradecahydro-1h-cyclopenta[a]chrysen-9-one Chemical compound C([C@@]12C)CC(=O)C(C)(C)[C@@H]1[C@H](O)C[C@]([C@]1(C)C[C@@H]3O)(C)[C@@H]2CC[C@H]1[C@@H]1[C@]3(C)CC[C@H]1C(=C)C HBGPNLPABVUVKZ-POTXQNELSA-N 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- GWKNUVAXSQNESV-UHFFFAOYSA-N 1-decan-2-yloxypentadecane Chemical compound C(CCCCCCCCCCCCCC)OC(C)CCCCCCCC GWKNUVAXSQNESV-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- YSHMWGYFMVENKI-UHFFFAOYSA-N 11-(2-decylpentadecoxymethyl)tetracosane Chemical compound CCCCCCCCCCCCCC(CCCCCCCCCC)COCC(CCCCCCCCCC)CCCCCCCCCCCCC YSHMWGYFMVENKI-UHFFFAOYSA-N 0.000 description 1
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 1
- PFRGGOIBYLYVKM-UHFFFAOYSA-N 15alpha-hydroxylup-20(29)-en-3-one Natural products CC(=C)C1CCC2(C)CC(O)C3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 PFRGGOIBYLYVKM-UHFFFAOYSA-N 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical class CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- 229940043268 2,2,4,4,6,8,8-heptamethylnonane Drugs 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- GNCOVOVCHIHPHP-UHFFFAOYSA-N 2-[[4-[4-[(1-anilino-1,3-dioxobutan-2-yl)diazenyl]-3-chlorophenyl]-2-chlorophenyl]diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(C)=O)C(=O)NC1=CC=CC=C1 GNCOVOVCHIHPHP-UHFFFAOYSA-N 0.000 description 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- ODMZDMMTKHXXKA-QXMHVHEDSA-N 8-methylnonyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCCCC(C)C ODMZDMMTKHXXKA-QXMHVHEDSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 235000002147 Australian walnut Nutrition 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- MDBFQTYHUHRROQ-UHFFFAOYSA-N C(CCCCCCCC=C/CCCCCCCC)(=O)O.C(CCCCCCCC=C/CCCCCCCC)(=O)O.C(CCCCCCCC=C/CCCCCCCC)(=O)O.C(CCCCCCCC=C/CCCCCCCC)(=O)O.OCC(O)CO Chemical compound C(CCCCCCCC=C/CCCCCCCC)(=O)O.C(CCCCCCCC=C/CCCCCCCC)(=O)O.C(CCCCCCCC=C/CCCCCCCC)(=O)O.C(CCCCCCCC=C/CCCCCCCC)(=O)O.OCC(O)CO MDBFQTYHUHRROQ-UHFFFAOYSA-N 0.000 description 1
- UBBKDJKBUNGAGL-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC(C)C)(=O)O.C(CCCCCCCCCCCCCCC(C)C)(=O)O.C(CCCCCCCCCCCCCCC(C)C)(=O)O.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO Chemical compound C(CCCCCCCCCCCCCCC(C)C)(=O)O.C(CCCCCCCCCCCCCCC(C)C)(=O)O.C(CCCCCCCCCCCCCCC(C)C)(=O)O.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO UBBKDJKBUNGAGL-UHFFFAOYSA-N 0.000 description 1
- WFUJTYXPIYURIF-UHFFFAOYSA-N CC(C)CCCCCCCCCCCCCCCCCNCC1=CC=CC=C1.[Li+] Chemical compound CC(C)CCCCCCCCCCCCCCCCCNCC1=CC=CC=C1.[Li+] WFUJTYXPIYURIF-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
- MLSJBGYKDYSOAE-DCWMUDTNSA-N L-Ascorbic acid-2-glucoside Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)=C1O MLSJBGYKDYSOAE-DCWMUDTNSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 244000070406 Malus silvestris Species 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- BAVYZALUXZFZLV-UHFFFAOYSA-O Methylammonium ion Chemical compound [NH3+]C BAVYZALUXZFZLV-UHFFFAOYSA-O 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000219925 Oenothera Species 0.000 description 1
- 235000004496 Oenothera biennis Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- SOKRNBGSNZXYIO-UHFFFAOYSA-N Resinone Natural products CC(=C)C1CCC2(C)C(O)CC3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 SOKRNBGSNZXYIO-UHFFFAOYSA-N 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 1
- NGHUOSKIZOQGBY-PMDAXIHYSA-N [3-[3-[3-[3-[3-[3-[3-[3-[3-[2,3-bis[[(Z)-octadec-9-enoyl]oxy]propoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-[(Z)-octadec-9-enoyl]oxypropyl] (Z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(COC(=O)CCCCCCC\C=C/CCCCCCCC)OC(=O)CCCCCCC\C=C/CCCCCCCC)OC(=O)CCCCCCC\C=C/CCCCCCCC NGHUOSKIZOQGBY-PMDAXIHYSA-N 0.000 description 1
- YNCUWXXRGAOWRU-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(CO)(CO)CO YNCUWXXRGAOWRU-UHFFFAOYSA-N 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- OENHQHLEOONYIE-UKMVMLAPSA-N all-trans beta-carotene Natural products CC=1CCCC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C OENHQHLEOONYIE-UKMVMLAPSA-N 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229940009868 aluminum magnesium silicate Drugs 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- 229940067599 ascorbyl glucoside Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- OCBHHZMJRVXXQK-UHFFFAOYSA-M benzyl-dimethyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 OCBHHZMJRVXXQK-UHFFFAOYSA-M 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 235000013734 beta-carotene Nutrition 0.000 description 1
- 239000011648 beta-carotene Substances 0.000 description 1
- TUPZEYHYWIEDIH-WAIFQNFQSA-N beta-carotene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2=CCCCC2(C)C TUPZEYHYWIEDIH-WAIFQNFQSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 229960002747 betacarotene Drugs 0.000 description 1
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229940106189 ceramide Drugs 0.000 description 1
- 150000001783 ceramides Chemical class 0.000 description 1
- 239000012185 ceresin wax Substances 0.000 description 1
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 description 1
- 229960000228 cetalkonium chloride Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- JBTHDAVBDKKSRW-UHFFFAOYSA-N chembl1552233 Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 JBTHDAVBDKKSRW-UHFFFAOYSA-N 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 239000010630 cinnamon oil Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- LFSBSHDDAGNCTM-UHFFFAOYSA-N cobalt(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Co+2] LFSBSHDDAGNCTM-UHFFFAOYSA-N 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- LRFIFBMQILCQBA-UHFFFAOYSA-N diethyl(hexadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[NH+](CC)CC LRFIFBMQILCQBA-UHFFFAOYSA-N 0.000 description 1
- HRFLSKZPDQHTHI-UHFFFAOYSA-N diethyl(icosyl)azanium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCC[NH+](CC)CC HRFLSKZPDQHTHI-UHFFFAOYSA-N 0.000 description 1
- OWLCGQZKRYSCIZ-UHFFFAOYSA-N diethyl(octadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[NH+](CC)CC OWLCGQZKRYSCIZ-UHFFFAOYSA-N 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- PFKRTWCFCOUBHS-UHFFFAOYSA-N dimethyl(octadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[NH+](C)C PFKRTWCFCOUBHS-UHFFFAOYSA-N 0.000 description 1
- VXKJCYOFOIIBHH-UHFFFAOYSA-N dimethyl(tetradecyl)azanium;chloride Chemical compound Cl.CCCCCCCCCCCCCCN(C)C VXKJCYOFOIIBHH-UHFFFAOYSA-N 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- OOYIOIOOWUGAHD-UHFFFAOYSA-L disodium;2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [Na+].[Na+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C([O-])C(Br)=C1OC1=C(Br)C([O-])=C(Br)C=C21 OOYIOIOOWUGAHD-UHFFFAOYSA-L 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- XWBDWHCCBGMXKG-UHFFFAOYSA-N ethanamine;hydron;chloride Chemical compound Cl.CCN XWBDWHCCBGMXKG-UHFFFAOYSA-N 0.000 description 1
- TVQGDYNRXLTQAP-UHFFFAOYSA-N ethyl heptanoate Chemical compound CCCCCCC(=O)OCC TVQGDYNRXLTQAP-UHFFFAOYSA-N 0.000 description 1
- NPWWVBBVHOUDAG-UHFFFAOYSA-M ethyl-dimethyl-(1-phenylheptadecan-2-yl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC([N+](C)(C)CC)CC1=CC=CC=C1 NPWWVBBVHOUDAG-UHFFFAOYSA-M 0.000 description 1
- YWTLITFYUZSHFJ-UHFFFAOYSA-M ethyl-dimethyl-(19-phenylnonadecyl)azanium;chloride Chemical compound [Cl-].CC[N+](C)(C)CCCCCCCCCCCCCCCCCCCC1=CC=CC=C1 YWTLITFYUZSHFJ-UHFFFAOYSA-M 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DWMMZQMXUWUJME-UHFFFAOYSA-N hexadecyl octanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC DWMMZQMXUWUJME-UHFFFAOYSA-N 0.000 description 1
- URXQDXAVUYKSCK-UHFFFAOYSA-N hexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[NH+](C)C URXQDXAVUYKSCK-UHFFFAOYSA-N 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229940078545 isocetyl stearate Drugs 0.000 description 1
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 1
- 229940093629 isopropyl isostearate Drugs 0.000 description 1
- 229940074928 isopropyl myristate Drugs 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229960001855 mannitol Drugs 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- XRSFQLOANYRGRT-UHFFFAOYSA-N n,n-dimethyldocosan-1-amine;hydrochloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[NH+](C)C XRSFQLOANYRGRT-UHFFFAOYSA-N 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N n-Decanedioic acid Natural products OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000346 nonvolatile oil Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- KSCKTBJJRVPGKM-UHFFFAOYSA-N octan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-] KSCKTBJJRVPGKM-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000008385 outer phase Substances 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000002942 palmitic acid derivatives Chemical class 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 239000004170 rice bran wax Substances 0.000 description 1
- 235000019384 rice bran wax Nutrition 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000012176 shellac wax Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229950004959 sorbitan oleate Drugs 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- GYDJEQRTZSCIOI-LJGSYFOKSA-N tranexamic acid Chemical compound NC[C@H]1CC[C@H](C(O)=O)CC1 GYDJEQRTZSCIOI-LJGSYFOKSA-N 0.000 description 1
- 229960000401 tranexamic acid Drugs 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 210000000707 wrist Anatomy 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
本發明提供一種化妝料，其係具有可謂膏狀之程度之硬度之固形或半固形之油中水型乳化化妝料，且保濕效果優異，並且於塗抹於肌膚時發揮如融化般滲透之獨特之使用觸感，並且可穩定地調配水溶性或親水性之化學劑。本發明之特徵在於含有：(A)有機改性黏土礦物、(B)HLB6以下之界面活性劑、(C)蠟、(D)聚矽氧彈性體、(E)揮發性油分、及(F)水。
Description
本發明係關於一種油中水型乳化化妝料。更詳細而言，係關於一種為具有某種程度之硬度之膏狀且於塗抹於肌膚時發揮如融化般之獨特之使用觸感之油中水型乳化化妝料。
作為膏狀之皮膚外用劑，熟知有Vaselin(商品名)、Son Bahyu(商品名)、或L'Occitane之Shea butter(商品名)等。該等含有凡士林、馬油、或Shea butter等高黏度之油性成分，藉由以油性覆膜被覆肌膚而發揮優異之保濕效果。尤其是調配Shea butter者已知有於肌膚上融化之獨特之使用觸感。然而，由於含有高黏度之油性成分，故而有於塗抹時難以擴散，於塗抹後產生黏膩之問題。
於化妝料中，於油中水型乳化化妝料之外相(油相)中調配有蠟或油性增黏劑等之固形或半固形之形態之化妝料主要於口紅等化妝用化妝料中通用。關於護膚化妝料，亦於專利文獻1中提出有一種油性固形化妝料，其係將自先前以來用作油性增黏劑之糊精脂肪酸酯與蜜蠟及Shea butter等來自天然之固形脂及/或半固形脂以及具有特定範圍之分子量及動黏度之異構石蠟組合而成，不黏膩，且發揮獨特之融合感，良好地緊致皮膚。
於專利文獻2中揭示有一種含有糊精脂肪酸酯、液態石蠟及/或角鯊烷、三醯甘油之油性固形化妝料，外觀之透明感、使用感及保濕感、進而保存穩定性優異。但是，專利文獻1及2所記載者為不含水之油性化妝料，例如難以調配水溶性或親水性之化學劑等。
關於內相中含有水之油中水型乳化化妝料，可知藉由在不含可能導致黏膩之固形或半固形油分之系中調配低級醇、揮發性聚矽氧油、有機改性黏土礦物、HLB(Hydrophile Lipophile Balance，親水/油比值)為7以下之聚醚改性聚矽氧界面活性劑(乳化劑)、及清涼劑，穩定性良好，延展性良好，發揮水潤且清爽之使用感與清涼感(專利文獻3)。然而，專利文獻3之油中水型乳化化妝料由於不含蠟等，故而不具有可謂膏狀之程度之硬度(黏度)，無法被覆肌膚而發揮保濕效果。 [先前技術文獻] [專利文獻]
[專利文獻1]日本專利特開2017-114780號公報 [專利文獻2]日本專利特開2017-114806號公報 [專利文獻3]日本專利第3524717號公報
[發明所欲解決之問題]
因此，本發明之目的在於提供一種化妝料，其係具有可謂膏狀之程度之硬度之固形或半固形之油中水型乳化化妝料，且保濕效果優異，並且於塗抹於肌膚時發揮如融化般滲透之獨特之使用觸感，並且可穩定地調配水溶性或親水性之化學劑。 [解決問題之技術手段]
為了解決上述問題，本發明者等人反覆努力研究，結果發現，於調配有機改性黏土礦物及HLB為6以下之界面活性劑、蠟、聚矽氧彈性體、及揮發性油分而成之油中水型乳化化妝料中，有機改性黏土礦物及HLB6以下之界面活性劑與油分一起形成油凝膠而使乳化物穩定化，藉由調配蠟而達成所需之硬度，藉由調配聚矽氧彈性體及揮發性油分而可抑制黏膩而不於肌膚上殘留油膩感，從而完成本發明。
即，本發明提供一種油中水型乳化化妝料，其特徵在於含有： (A)有機改性黏土礦物、 (B)HLB6以下之界面活性劑、 (C)蠟、 (D)聚矽氧彈性體、 (E)揮發性油分、及 (F)水。 [發明之效果]
本發明之油中水型乳化化妝料係具有稱為膏狀之程度之硬度之固形或半固形者，藉由以含有蠟之覆膜被覆肌膚而具有優異之保濕效果。又，於塗抹時賦予如於肌膚上融化而崩解般之獨特之觸感，且可穩定地調配水溶性或親水性之化學劑。發揮此種美容效果之膏狀之化妝料迄今為止未知，藉由本發明首次提供。
以下，對本發明之油中水型乳化化妝料(以下亦簡稱為「化妝料」)進行詳細敍述。本發明之化妝料係如上所述呈現具有稱為「膏狀」之程度之硬度之固形或半固形之形態。本說明書中之「膏狀」及「固形或半固形」係指於常溫(25℃)下之保存時不顯示流動性。例如較佳為常溫(25℃)下之硬度成為5～200之範圍內。
此處，上述中之「硬度」係使用流變計(不動工業公司製造)等公知測定裝置於下述條件下測定之情形時由下述式(1)所表示之硬度(γ)。 γ＝(G ﹡L)/(l ﹡a) (N/cm2
) (1) (式中，G：測定應力，L：樣品之厚度(mm)，l：壓縮距離(mm)，a：針之截面積(cm2
)) (測定條件) 針徑：5.6 mmf，針入速度：2 cm/min，針入距離：10 mm，測定溫度：25℃
(A)有機改性黏土礦物 本發明所使用之有機改性黏土礦物只要為自先前以來調配於化妝料等中者即可，例如較佳為具有三層結構之膠體性含水矽酸鋁之一種，且為將下述通式： (X, Y)2-3
(Si, Al)4
O10
(OH)2
Z1/3
∙nH2
O (其中，X＝Al、Fe(III)、Mn(III)、Cr(III)，Y＝Mg、Fe(II)、Ni、Zn、Li，Z＝K、Na、Ca) 所表示之黏土礦物利用四級銨鹽型陽離子界面活性劑進行處理所獲得者。
具體而言，可例示將蒙脫石、皂石、及鋰膨潤石等天然之蒙脫石類、合成之蒙脫石類(例如上述通式中之OH基經氟取代者；市售品有Veegum、Kunipia、合成鋰皂石等)、及以鈉矽雲母、鈉或鋰帶雲母之名周知之合成雲母(市售品有Dimonite：Topy Industries股份有限公司等)等黏土礦物利用四級銨鹽型陽離子界面活性劑進行處理所獲得者。
作為用以對黏土礦物進行有機改性之四級銨鹽型陽離子界面活性劑，適宜為下述通式所表示者。
[化1](式中，R1
表示碳數10～22之烷基或苄基，R2
表示甲基或碳數10～22之烷基，R3
與R4
表示碳數1～3之烷基或羥基烷基，X表示鹵素原子或甲基硫酸鹽殘基)
作為具體例，可列舉：氯化十二烷基三甲基銨、氯化肉豆蔻基三甲基銨、氯化鯨蠟基三甲基銨、氯化硬脂基三甲基銨、氯化花生基三甲基銨、氯化山崳基三甲基銨、氯化肉豆蔻基二甲基銨、氯化鯨蠟基二甲基銨、氯化硬脂基二甲基銨、氯化花生基二甲基銨、氯化山崳基二甲基銨、氯化鯨蠟基二乙基銨、氯化硬脂基二乙基銨、氯化花生基二乙基銨、氯化山崳基二乙基銨、氯化苄基二甲基肉豆蔻基銨、氯化苄基二甲基鯨蠟基銨、氯化苄基二甲基硬脂基銨、氯化苄基二甲基山崳基銨、氯化苄基二甲基乙基鯨蠟基銨、氯化苄基二甲基乙基硬脂基銨、氯化二硬脂基二甲基銨、氯化二山崳基二羥基乙基銨、及相應之溴化物等，進而可列舉：二棕櫚基丙基乙基銨甲基硫酸鹽等，可任意地選擇該等中之一種或兩種以上。
再者，於利用上述四級銨鹽型陽離子界面活性劑對黏土礦物進行處理時，亦可併用非離子性界面活性劑進行處理。例如可列舉：聚氧乙烯2～30莫耳加成(POE(2～30))油醚、POE(2～35)硬脂醚、POE(2～20)月桂醚、POE(1～20)烷基苯醚、POE(6～18)山崳醚、POE(5～25)2-癸基十五烷基醚、POE(3～30)2-癸基十四烷基醚、POE(8～16)2-辛基癸醚等醚型活性劑、及POE(4～60)氫化蓖麻油、POE(3～14)脂肪酸單酯、POE(6～30)脂肪酸二酯、POE(5～20)山梨醇酐脂肪酸酯等酯型活性劑、進而POE(2～30)甘油單異硬脂酸酯、POE(10～60)甘油三異硬脂酸酯、POE(7～50)氫化蓖麻油單異硬脂酸酯、POE(12～60)氫化蓖麻油三異硬脂酸酯等醚酯型活性劑等環氧乙烷加成型界面活性劑及十甘油四油酸酯、六甘油三異硬脂酸酯、二甘油二異硬脂酸酯、甘油單油酸酯等甘油脂肪酸酯等多元醇脂肪酸酯型界面活性劑。於該等之中，較佳為使用十甘油四油酸酯、六甘油三異硬脂酸酯、二甘油二異硬脂酸酯等二甘油以上之聚甘油脂肪酸酯、POE(2～12)月桂醚、POE(6～15)山崳醚、POE(5～20)2-癸基十五烷基醚、POE(5～17)2-癸基十四烷基醚、POE(8～16)2-辛基癸醚等POE加成醚型活性劑、及POE(10～20)氫化蓖麻油、POE(5～14)油酸單酯、POE(6～20)油酸二酯、POE(5～10)山梨醇酐油酸酯等POE加成酯型活性劑、POE(3～15)甘油單異硬脂酸酯、POE(10～40)甘油三異硬脂酸酯等POE加成醚酯活性劑等環氧乙烷加成型非離子性界面活性劑之一種或兩種以上。
本發明所使用之有機改性黏土礦物例如可藉由在水、丙酮或低級醇等低沸點溶劑中將上述黏土礦物與四級銨鹽型陽離子界面活性劑進行分散攪拌處理後去除低沸點溶劑而獲得。
本發明所使用之有機改性黏土礦物中之四級銨鹽型陽離子界面活性劑之含量較佳為相對於黏土礦物100 g為60～140毫當量(meq)。
作為良好地用於本發明之有機改性黏土礦物之代表例，可列舉：二甲基烷基銨鋰膨潤石、苄基二甲基硬脂基銨鋰膨潤石、氯化二硬脂基二甲基銨處理矽酸鋁鎂等。作為市售品，有二硬脂二甲銨鋰膨潤石(Bentone 38VCG：Elementis Specialities公司製造)等。
有機改性黏土礦物係於油中水型乳化組合物或乳化化妝料之總量中調配0.1～5.0質量%。較佳為調配0.5～3.0質量%，更佳為調配0.5～1.5質量%。若未達0.1質量%，則難以獲得充分之穩定性，若多於5.0質量%而調配，則向手指上之取得變差，於肌膚上之延展性變重等之於使用性方面欠佳。
(B)HLB6以下之界面活性劑 本發明所使用之HLB6以下之界面活性劑可調配於化妝料中，只要為HLB值為6以下者，則無特別限定，例如可列舉：聚醚改性聚矽氧、山梨醇酐三硬脂酸酯等山梨醇酐脂肪酸酯類、甘油單硬脂酸酯、甘油單油酸酯等甘油脂肪酸酯類、POE(5)氫化蓖麻油、POE(7)氫化蓖麻油等聚氧乙烯氫化蓖麻油等。於該等之中，尤佳為使用聚醚改性聚矽氧。
具體而言，聚醚改性聚矽氧可例示下述式所表示者。 [化2](式中，R表示氫原子或碳數1～5之烷基，m表示平均值1～150之數，n表示平均值1～50之數，a及b表示平均值0～35之數)
HLB6以下之界面活性劑之調配量相對於化妝料總量為0.1～5質量%，較佳為0.5～3質量%，更佳為1～2.5質量%。 再者，本發明之油中水型乳化化妝料中所含之HLB6以下之界面活性劑亦可於吸附於上述成分(A)有機改性黏土礦物之狀態下含有。即，本發明中，可分別添加(A)有機改性黏土礦物與(B)HLB6以下之界面活性劑而製造油中水型乳化化妝料，亦可將(A)有機改性黏土礦物預先利用(B)HLB6以下之界面活性劑進行處理而於使HLB6以下之界面活性劑吸附於有機改性黏土礦物之狀態下調配。
(C)蠟 本發明所使用之蠟只要為能夠調配於化妝料中之蠟，則無特別限定。若列舉具體例，則可列舉：地蠟、石蠟、微晶蠟、巴西棕櫚蠟、木蠟、堪地里拉蠟、米糠蠟、蜜蠟、蟲膠蠟、蟲蠟等。其中，較佳為使用選自地蠟、石蠟及微晶蠟之1種或2種以上之組合。
本發明之油中水型乳化化妝料中之蠟之調配量相對於油中水型乳化化妝料總量為1～15質量%，較佳為3～9質量%，更佳為3～5質量%。若含量超過15質量%，則有難以獲得良好之使用觸感之情形，又，若含量未達1質量%，則有破壞經時穩定性之情形。
(D)聚矽氧彈性體 本發明之化妝料進而含有(D)聚矽氧彈性體。藉由調配聚矽氧彈性體，可賦予如塗抹中崩解般之獨特觸感，抑制塗抹後之黏膩。
本發明所使用之聚矽氧彈性體例如可列舉：二甲基聚矽氧烷交聯聚合物、(二甲基聚矽氧烷/苯基二乙烯基甲基聚矽氧烷)交聯聚合物、(二甲基聚矽氧烷/乙烯基二甲基聚矽氧烷/甲基聚矽氧烷)交聯聚合物、(二甲基聚矽氧烷/乙烯基二甲基聚矽氧烷)交聯聚合物、(二苯基二甲基聚矽氧烷/乙烯基二苯基二甲基聚矽氧烷/倍半矽氧烷)交聯聚合物等交聯型聚矽氧樹脂粉末之一種或兩種以上。
聚矽氧彈性體亦可於包含交聯型聚矽氧樹脂粉末與溶劑之聚矽氧凝膠之狀態下調配。此種聚矽氧凝膠可使用市售品，例如可列舉KSG-15、KSG-18A、KSG-16(以上為信越化學工業股份有限公司製造)等。
本發明之化妝料中之聚矽氧彈性體之調配量通常為0.5～5質量%，較佳為0.5～4質量%，更佳為0.8～3質量%，尤佳為0.8～2質量%。若調配量未達0.5質量%，則有產生黏膩之情形，若超過5質量%而調配，則有難以製備穩定之化妝料之情形。
(E)揮發性油分 本發明所使用之(E)揮發性油分係於常溫(25℃)下具有流動性之(液狀之)揮發性油分，可選自能夠用於化妝料等之油分。例如可列舉低沸點(常壓下之沸點260℃以下)之異構石蠟系烴油或聚矽氧油，可使用1種或2種以上。
作為低沸點異構石蠟系烴油之具體例，可列舉異十二烷、異十六烷等。 低沸點聚矽氧油包含矽原子數4～6之環狀二甲基聚矽氧烷、矽原子數2～5之鏈狀二甲基聚矽氧烷。作為具體例，可列舉：六甲基環三矽氧烷(D3)、八甲基四環矽氧烷(D4)、十甲基環五矽氧烷(D5)、及十二甲基環六矽氧烷(D6)等環狀聚矽氧油、黏度未達5 cs之直鏈狀或支鏈狀之聚矽氧油(例如二甲基聚矽氧烷(黏度未達5 cs))等。
本發明之化妝料中之揮發性油分之調配量為5～50質量%，較佳為10～50質量%，更佳為20～50質量%。若調配量未達5質量%，則會失去如融化般滲透之獨特之使用觸感，若超過50質量%而調配，則乳化穩定性降低。
又，於本發明中，較佳為將(E)揮發性油分與(C)蠟之調配量比率([(E)/(C)])設為50以下。該調配量比率進而較佳為設為30以下，尤佳為設為20以下。
(F)水 本發明之化妝料係於內相中含有(F)水之油中水型乳化化妝料。本發明之化妝料係於內相中含有水，且於外相中調配蠟而維持硬度，因此可穩定地保持水溶性或親水性之化學劑等。
本發明之化妝料中之水之調配量並無特別限定，較佳為60質量%以下。更佳為50質量%以下，進而較佳為40質量%以下。
本發明之化妝料除含有上述必須成分(A)～(F)以外，亦可於無損本發明之效果之範圍內含有能夠調配於油中水型乳化化妝料中之其他任意成分。作為其他任意成分，可例示以下者，但並不限定於該等。
(G)保濕劑 藉由調配保濕劑，可進一步提高由本發明之化妝料所產生之肌膚之保濕效果。作為保濕劑之具體例，可列舉：丙二醇、二丙二醇、1,3-丁二醇、1,4-丁二醇、二乙二醇、三乙二醇、聚乙二醇等二醇類；甘油、二甘油、聚甘油等甘油類；山梨糖醇、甘露糖醇、麥芽糖醇、木糖醇、赤藻糖醇等糖醇類；果糖、葡萄糖、半乳糖、麥芽糖、乳糖、海藻糖等糖類。
於在本發明之化妝料中調配保濕劑之情形時，其調配量通常為1～15質量%，較佳為2～12質量%，更佳為3～10質量%。若調配量未達1質量%，則保濕效果之提高並不顯著，若超過15質量%而調配，則反而有產生黏膩之情形。
(H)非揮發性流動油分 藉由調配非揮發性流動油分，可適當調整化妝料之硬度。本發明所使用之非揮發性流動油分係於常溫(25℃)下具有流動性之(液狀之)非揮發性油分，可選自能夠用於化妝料等之油分。例如可列舉常壓下之沸點高於260℃之油性成分即烴油及/或聚矽氧油，該等可使用1種或2種以上。
作為非揮發性流動油分之具體例，可列舉：亞麻仁油、山茶油、澳洲胡桃油、玉米油、橄欖油、萼梨油、山茶花油、蓖麻油、紅花油、杏仁油(apricot kernel oil)、錫蘭肉桂油、葡萄油、杏仁油(almond oil)、菜籽油、芝麻油、葵花籽油、小麥胚芽油、米胚芽油、米糠油、棉籽油、大豆油、花生油、茶籽油、月見草油、蛋黃油、肝油、三甘油、三辛酸甘油酯、三異棕櫚酸甘油酯等液狀油脂；辛酸鯨蠟酯等辛酸酯、三-2-乙基己酸甘油酯、四-2-乙基己酸季戊四醇酯等異辛酸酯、月桂酸己酯等月桂酸酯、肉豆蔻酸異丙酯、肉豆蔻酸辛基十二烷基酯等肉豆蔻酸酯、棕櫚酸辛酯等棕櫚酸酯、硬脂酸異鯨蠟酯等硬脂酸酯、異硬脂酸異丙酯等異硬脂酸酯、異棕櫚酸辛酯等異棕櫚酸酯、油酸異癸酯等油酸酯、己二酸二異丙酯等己二酸二酯、癸二酸二乙酯等癸二酸二酯、蘋果酸二異硬脂酯等蘋果酸二異硬脂酯等酯油；液態石蠟、角鯊烷等液狀烴油；進而，作為聚矽氧油之二甲基聚矽氧烷、甲基苯基聚矽氧烷、甲基氫聚矽氧烷等鏈狀聚矽氧、胺基改性聚矽氧、聚醚改性聚矽氧、羧基改性聚矽氧、烷基改性聚矽氧、銨鹽改性聚矽氧、氟改性聚矽氧等。
於在本發明之化妝料中調配非揮發性流動油分之情形時，其調配量通常為30質量%以下，較佳為20質量%以下。
(I)粉末成分 本發明之化妝料亦可含有能夠調配於皮膚用化妝料中之各種粉末成分。作為粉末成分之具體例，可列舉：滑石、高嶺土、雲母、二氧化矽、沸石等無機粉末；聚矽氧樹脂粉末、聚醯胺樹脂粉末(尼龍粉末)、聚乙烯粉末、聚甲基丙烯酸甲酯粉末、聚苯乙烯粉末、苯乙烯與丙烯酸之共聚物樹脂粉末、纖維素粉末等有機粉末；二氧化鈦、氧化鋅等無機白色顏料；氧化鐵(鐵丹)等無機紅色系顏料；氧化鐵黃、黃土等無機黃色系顏料；氧化鐵黑、碳黑等黑色系顏料；氧化鉻、氫氧化鉻、鈦酸鈷等無機綠色系顏料；群青、鐵藍等無機藍色系顏料；經氧化鈦塗抹之雲母、經著色氧化鈦塗抹之雲母、氧氯化鉍、魚鱗箔等珍珠顏料；鋁粉、銅粉等金屬粉末顏料；紅色201號、紅色202號、紅色204號、紅色205號、紅色220號、紅色226號、紅色228號、紅色405號、橙色203號、橙色204號、黃色205號、黃色401號、及藍色404號等有機顏料；紅色3號、紅色104號、紅色106號、紅色227號、紅色230號、紅色401號、紅色505號、橙色205號、黃色4號、黃色5號、黃色202號、黃色203號、綠色3號及藍色1號等鋯、鋇或鋁色澱等有機顏料；葉綠素、β-胡蘿蔔素等天然色素。其中，藉由調配聚矽氧樹脂粉末，使用性進一步提高。
於在本發明之化妝料中調配粉末成分之情形時，其調配量通常為1～10質量%，較佳為2～5質量%。
(J)其他任意成分 作為上述以外之任意成分，例如可列舉：增黏劑、腦醯胺類、維生素類、紫外線吸收劑、螯合劑、殺菌劑、防腐劑、植物萃取液、胺基酸、各種化學劑、乙醇等低級醇類等。
本發明之化妝料可依照先前用於油中水型乳化化妝料之方法而製造。簡言之，可藉由如下方式製造，即，一面將油性成分與水性成分分別視需要進行加熱一面混合，於油相中使水相乳化，繼而將所獲得之乳化物填充至容器中並進行冷卻。
本發明之化妝料為膏狀，並且於塗抹時發揮如於肌膚上融合般崩解之獨特之使用觸感。而且，於肌膚上擴散之覆膜發揮優異之保濕效果，並且藉由穩定地調配之各種化學劑亦發揮優異之美容效果。 因此，本發明之化妝料尤其適宜用作調配有美白成分等化學劑之美容膏、或保濕效果優異之基底膏，又，適宜用作賦予紫外線防禦效果、SPF(Sun Protection Factor，防曬係數)之防曬製劑、對頭髮賦予適度之濕潤之護髮製劑，亦可用作享受香味之香氛膏。 [實施例]
以下，列舉實施例對本發明進而進行詳細敍述，但本發明並不受該等實施例任何限定。再者，調配量若無特別記載，則意指質量%。
根據下述表1～4所示之配方製備油中水型乳化化妝料，並依照下述評價方法、評價基準對其等之特性進行評價。將該等之結果一起示於表。
「乳化穩定性」 將受驗試樣於50℃下放置4週後，恢復至室溫，目視觀察狀態，根據以下基準進行評價。 A：無異常。 B：略微地觀察到分離。 C：觀察到分離。
「融化感」 用手將受驗試樣塗抹於女性官能檢查員20人之上腕部，針對塗抹中之融化感(＝如融化般滲透之觸感)進行問卷調查，根據以下基準進行評價。 AA：回答為如融化般滲透之官能檢查員為16人以上。 A：回答為如融化般滲透之官能檢查員為12～15人以上。 B：回答為如融化般滲透之官能檢查員為8～11人。 C：回答為如融化般滲透之官能檢查員為7人以下。
[表1]
[表2]
[表3]
[表4]
由上述表1～4所示之結果明確，不含蠟之比較例1之乳化穩定性不充分，亦無法獲得塗抹於肌膚時之獨特之觸感。又，不含揮發性油分之比較例2雖可穩定地乳化，但無法獲得獨特之使用觸感。相對於該等，本發明之化妝料(實施例1～12、14～17)之乳化穩定性及使用觸感均優異。再者，揮發性油與蠟之調配量比率超過50之實施例13為於實際應用中無問題之程度，但發現特性略微降低。
其次，測定關於上述實施例6及作為比較例3之調配Shea butter之市售品(商品名：L'Occitane Shea Hand Cream)之流變特性。 流變測定係使用流變計(Anton-Paar公司製造之MCR301，50 mmf之錐板)，於溫度32℃下，一面以1[1/s]之角頻率將施加至測定樣品之應變(γ)自0.05增加至500一面進行。將結果示於圖1。
如圖1所示，本發明之實施例6及作為含有Shea butter之霜之比較例3之儲存彈性模數(G')及損耗彈性模數(G'')均隨著應變增大而降低。但是，於本發明之實施例中，於應變＝約1之點，tanδ(＝G''(損耗彈性模數)/G'(儲存彈性模數))成為「1」，自彈性優勢變化為黏性優勢，相對於此，於比較例中，tanδ＝1之點偏向應變較大之側。即，於比較例中，於難以滲透至肌膚之狀態下，黏度急遽降低，相對於此，本發明之實施例顯示出可獲得於肌膚上逐漸融化滲透之觸感。
以下表示本發明之化妝料之其他配方例。再者，本案發明並不限定於本配方例。
配方例1：美白膏 調配成分 調配量(質量%) (1)純化水 剩餘 (2)甘油 2 (3)二丙二醇 2 (4)聚乙二醇6000 1 (5)二硬脂二甲銨鋰膨潤石(Bentone 38VCG) 1 (6)微晶蠟 0.2 (7)石蠟 1.8 (8)PEG-9聚二甲基矽烷氧基苯基三甲基聚矽氧烷 (聚醚改性聚矽氧界面活性劑) 2 (9)環甲基聚矽氧烷 35 (10)己酸鯨蠟基乙酯 3 (11)(二甲基聚矽氧烷/乙烯基二甲基聚矽氧烷)交聯聚合物 1.5 (12)傳明酸 2 (13)乙烯基二甲基聚矽氧烷/甲基聚矽氧烷倍半矽氧烷交聯聚合物 3 (14)氯化鈉 0.5 (15)苯氧基乙醇 0.5
配方例2：美容膏 調配成分 調配量(質量%) (1)純化水 剩餘 (2)甘油 5 (3)二丙二醇 5 (4)聚乙二醇6000 1 (5)二硬脂二甲銨鋰膨潤石(Bentone 38VCG) 1 (6)微晶蠟 0.3 (7)石蠟 2 (8)PEG-9聚二甲基矽烷氧基苯基三甲基聚矽氧烷 (聚醚改性聚矽氧界面活性劑) 2 (9)環甲基聚矽氧烷 40 (10)己酸鯨蠟基乙酯 3 (11)(二甲基聚矽氧烷/乙烯基二甲基聚矽氧烷)交聯聚合物 2 (12)抗壞血酸葡萄糖苷 2 (13)乙烯基二甲基聚矽氧烷/甲基聚矽氧烷倍半矽氧烷交聯聚合物 3 (14)氯化鈉 0.5 (15)苯氧基乙醇 0.5 (16)檸檬酸 0.02 (17)檸檬酸鈉 0.18 (18)氫氧化鉀 0.4
圖1係表示本發明之油中水型乳化化妝料(實施例6)及含有Shea butter之比較例3(L'Occitane之Shea Hand Cream(商品名))之流變特性之曲線圖。
Claims (4)
- 一種油中水型乳化化妝料，其特徵在於含有： (A)有機改性黏土礦物、 (B)HLB6以下之界面活性劑、 (C)蠟、 (D)聚矽氧彈性體、 (E)揮發性油分、及 (F)水。
- 如請求項1之化妝料，其中上述(E)揮發性油分與上述(C)蠟之調配量比率([(E)/(C)])為50以下。
- 如請求項1或2之化妝料，其進而含有選自聚矽氧樹脂粉末及聚甲基丙烯酸甲酯粉末之至少1種粉末成分。
- 如請求項1至3中任一項之化妝料，其為具有5～200之硬度之固形或半固形。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017-168195 | 2017-09-01 | ||
| JP2017168195 | 2017-09-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201919578A true TW201919578A (zh) | 2019-06-01 |
Family
ID=65527540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW107130720A TW201919578A (zh) | 2017-09-01 | 2018-08-31 | 油中水型乳化化妝料 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20210077378A1 (zh) |
| EP (1) | EP3677245A4 (zh) |
| JP (3) | JP7240318B2 (zh) |
| CN (1) | CN111032000B (zh) |
| TW (1) | TW201919578A (zh) |
| WO (1) | WO2019045056A1 (zh) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112807234A (zh) * | 2019-11-15 | 2021-05-18 | 株式会社Lg生活健康 | 具有流动性以及稳定性的油包水型化妆料组合物 |
| JP7621787B2 (ja) * | 2020-12-15 | 2025-01-27 | 株式会社 資生堂 | 油中水型乳化固形化粧料 |
| JP7665331B2 (ja) * | 2020-12-23 | 2025-04-21 | 株式会社 資生堂 | 油中水型乳化化粧料 |
| FR3150117B1 (fr) * | 2023-06-20 | 2026-03-13 | Oreal | Composition cosmétique à base de chitosan et d’argile modifiée |
| FR3162638A1 (fr) * | 2024-05-31 | 2025-12-05 | L'oreal | Composition solide mate comprenant un elastomere silicone emulsionnant, une huile hydrocarbonee apolaire, une huile non volatile addtionnelle, une charge et procede la mettant en œuvre |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS524717B1 (zh) | 1971-07-06 | 1977-02-05 | ||
| US5763497A (en) * | 1994-07-21 | 1998-06-09 | Shiseido Company, Ltd. | Oil-in-water type cosmetic composition |
| EP1159954A3 (en) * | 2000-05-31 | 2003-01-02 | Shiseido Company, Ltd. | Solid water-in-oil type emulsion cosmetic composition |
| JP4860045B2 (ja) * | 2001-02-28 | 2012-01-25 | 株式会社コーセー | 油中水型化粧料 |
| JP4275872B2 (ja) * | 2001-04-18 | 2009-06-10 | 株式会社資生堂 | 用時混合型皮膚外用組成物 |
| JP2004067628A (ja) * | 2002-08-08 | 2004-03-04 | Shiseido Co Ltd | 油中水型乳化組成物 |
| DE602005014915D1 (de) | 2004-07-16 | 2009-07-30 | Oreal | Kosmetische feste W/Ö Emulsion |
| US20080038216A1 (en) * | 2006-08-11 | 2008-02-14 | Joseph Michael Zukowski | Personal care composition |
| FR2916630B1 (fr) * | 2007-06-01 | 2009-07-24 | Oreal | Composition cosmetique comprenant des cires et des elastomeres de silicone. |
| JP2009137900A (ja) * | 2007-12-07 | 2009-06-25 | Shiseido Co Ltd | 油中水型固形乳化化粧料及びその製造方法 |
| EP2556822B1 (en) * | 2010-04-07 | 2016-09-28 | Shiseido Company, Ltd. | Solid emulsified cosmetic |
| FR2986427B1 (fr) | 2012-02-06 | 2017-03-17 | Oreal | Composition cosmetique comprenant des particules d'aerogel de silice et un elastomere de silicone emulsionnant |
| JP5694273B2 (ja) * | 2012-10-30 | 2015-04-01 | 株式会社 資生堂 | 日焼け止め化粧料 |
| JP5732165B1 (ja) | 2014-05-14 | 2015-06-10 | 株式会社 資生堂 | うるおい補給用スティック状化粧料 |
| CN107072919A (zh) * | 2014-10-31 | 2017-08-18 | 株式会社资生堂 | 油包水型乳化防晒化妆品 |
| US20160367470A1 (en) * | 2015-06-19 | 2016-12-22 | L'oreal | Water-in-oil sunscreen composition having organic sunscreen actives |
| KR102496893B1 (ko) * | 2015-08-03 | 2023-02-07 | 가부시키가이샤 시세이도 | 유중수형 유화 고형 화장료 |
| JP2017114780A (ja) | 2015-12-21 | 2017-06-29 | ポーラ化成工業株式会社 | 油性固形化粧料 |
| JP2017114806A (ja) | 2015-12-24 | 2017-06-29 | クラシエホームプロダクツ株式会社 | 油性固形化粧料 |
| WO2017167667A1 (en) * | 2016-03-31 | 2017-10-05 | L'oreal | Aqueous emulsion comprising a silicone-based dendritic polymer, a silicone gum and a semi-crystalline polymer or a wax and treatment of the lips |
-
2018
- 2018-08-31 TW TW107130720A patent/TW201919578A/zh unknown
- 2018-08-31 CN CN201880055507.3A patent/CN111032000B/zh active Active
- 2018-08-31 JP JP2019539671A patent/JP7240318B2/ja active Active
- 2018-08-31 US US16/642,176 patent/US20210077378A1/en active Pending
- 2018-08-31 EP EP18851745.2A patent/EP3677245A4/en active Pending
- 2018-08-31 WO PCT/JP2018/032410 patent/WO2019045056A1/ja not_active Ceased
-
2023
- 2023-03-03 JP JP2023032427A patent/JP7438425B2/ja active Active
-
2024
- 2024-02-13 JP JP2024019144A patent/JP2024056833A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP3677245A4 (en) | 2021-06-30 |
| JPWO2019045056A1 (ja) | 2020-10-01 |
| JP7240318B2 (ja) | 2023-03-15 |
| WO2019045056A1 (ja) | 2019-03-07 |
| CN111032000B (zh) | 2024-02-06 |
| EP3677245A1 (en) | 2020-07-08 |
| US20210077378A1 (en) | 2021-03-18 |
| JP7438425B2 (ja) | 2024-02-26 |
| CN111032000A (zh) | 2020-04-17 |
| JP2024056833A (ja) | 2024-04-23 |
| JP2023071875A (ja) | 2023-05-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5732165B1 (ja) | うるおい補給用スティック状化粧料 | |
| JP7438425B2 (ja) | 油中水型乳化化粧料 | |
| JP6392419B1 (ja) | Ｗ／ｏ型乳化物 | |
| EP2692333B1 (en) | Water-in-oil emulsified cosmetic | |
| JP6792353B2 (ja) | 油中水型乳化組成物 | |
| JP5722615B2 (ja) | ジェル状組成物 | |
| CN111278407A (zh) | 固体w/o化妆品组合物 | |
| JP5547123B2 (ja) | 油中水型乳化化粧料 | |
| JP7559040B2 (ja) | エモリエント剤を含む油中水型エマルジョン及びその使用方法 | |
| JP2005314258A (ja) | 固形状油中水型化粧料 | |
| JP6277307B1 (ja) | 油中水型液状乳化組成物 | |
| KR102423954B1 (ko) | 유중수형 화장료 조성물 | |
| JPWO2019230578A1 (ja) | 温感化粧料 | |
| JP2020029417A (ja) | ゲル状組成物及びこれを含む化粧料 | |
| JP2021070686A (ja) | 乳化化粧料 | |
| KR102453891B1 (ko) | 모공 가림용 또는 피부 보습용 화장료 조성물 | |
| JP7308669B2 (ja) | 乳化化粧料 | |
| TW202539614A (zh) | 皮膚化妝料 | |
| JP2017214313A (ja) | 水中油型乳化組成物 | |
| HK1228781A1 (zh) | 补水保湿用棒状化妆品 |