TW202000883A - 合成清潔劑皂條組成物 - Google Patents
合成清潔劑皂條組成物 Download PDFInfo
- Publication number
- TW202000883A TW202000883A TW108119680A TW108119680A TW202000883A TW 202000883 A TW202000883 A TW 202000883A TW 108119680 A TW108119680 A TW 108119680A TW 108119680 A TW108119680 A TW 108119680A TW 202000883 A TW202000883 A TW 202000883A
- Authority
- TW
- Taiwan
- Prior art keywords
- composition
- weight
- present
- combination
- composition according
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 102
- 239000003599 detergent Substances 0.000 title abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 32
- -1 alkyl sulfosuccinate Chemical compound 0.000 claims abstract description 27
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 16
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 13
- 239000003906 humectant Substances 0.000 claims abstract description 13
- 150000004671 saturated fatty acids Chemical class 0.000 claims abstract description 13
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000008051 alkyl sulfates Chemical class 0.000 claims abstract description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 11
- 239000000194 fatty acid Substances 0.000 claims abstract description 11
- 229930195729 fatty acid Natural products 0.000 claims abstract description 11
- 150000004702 methyl esters Chemical class 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 6
- 229960000541 cetyl alcohol Drugs 0.000 claims abstract description 6
- 239000000344 soap Substances 0.000 claims description 117
- 239000000271 synthetic detergent Substances 0.000 claims description 65
- 239000004909 Moisturizer Substances 0.000 claims description 13
- 230000001333 moisturizer Effects 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- 229920002472 Starch Polymers 0.000 claims description 9
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000005336 cracking Methods 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 229940081733 cetearyl alcohol Drugs 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 235000021314 Palmitic acid Nutrition 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 4
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 claims description 4
- 239000008172 hydrogenated vegetable oil Substances 0.000 claims description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 4
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims description 3
- 244000075850 Avena orientalis Species 0.000 claims description 3
- 235000007319 Avena orientalis Nutrition 0.000 claims description 3
- 229920002261 Corn starch Polymers 0.000 claims description 3
- 240000005979 Hordeum vulgare Species 0.000 claims description 3
- 235000007340 Hordeum vulgare Nutrition 0.000 claims description 3
- 239000005639 Lauric acid Substances 0.000 claims description 3
- 240000003183 Manihot esculenta Species 0.000 claims description 3
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 239000008120 corn starch Substances 0.000 claims description 3
- 229940099112 cornstarch Drugs 0.000 claims description 3
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 claims description 3
- 229940116985 potassium lauryl sulfate Drugs 0.000 claims description 3
- 229940100486 rice starch Drugs 0.000 claims description 3
- 239000001540 sodium lactate Substances 0.000 claims description 3
- 229940005581 sodium lactate Drugs 0.000 claims description 3
- 235000011088 sodium lactate Nutrition 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 235000012222 talc Nutrition 0.000 claims description 3
- 229940100445 wheat starch Drugs 0.000 claims description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims 1
- 235000007558 Avena sp Nutrition 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims 1
- LTVJJSFLSYSCEF-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfonatobutanoate Chemical group [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S([O-])(=O)=O)CC([O-])=O LTVJJSFLSYSCEF-UHFFFAOYSA-L 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 29
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 abstract description 5
- 229940012831 stearyl alcohol Drugs 0.000 abstract description 5
- 238000004851 dishwashing Methods 0.000 abstract description 4
- 238000010412 laundry washing Methods 0.000 abstract description 2
- 229940082500 cetostearyl alcohol Drugs 0.000 abstract 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 abstract 1
- 210000003491 skin Anatomy 0.000 description 21
- 230000000694 effects Effects 0.000 description 17
- 238000012360 testing method Methods 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 10
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 238000001134 F-test Methods 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000007794 irritation Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 241001465754 Metazoa Species 0.000 description 4
- 235000003441 saturated fatty acids Nutrition 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 235000019482 Palm oil Nutrition 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 210000000434 stratum corneum Anatomy 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- WMCMCZTWKQMHBE-UHFFFAOYSA-N 1-decoxydecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCOCCCCCCCCCC WMCMCZTWKQMHBE-UHFFFAOYSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 1
- GJJVAFUKOBZPCB-UHFFFAOYSA-N 2-methyl-2-(4,8,12-trimethyltrideca-3,7,11-trienyl)-3,4-dihydrochromen-6-ol Chemical compound OC1=CC=C2OC(CCC=C(C)CCC=C(C)CCC=C(C)C)(C)CCC2=C1 GJJVAFUKOBZPCB-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 238000000692 Student's t-test Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 1
- 241001135917 Vitellaria paradoxa Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 1
- 238000000540 analysis of variance Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 229940093797 bioflavonoids Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229940057910 shea butter Drugs 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000000528 statistical test Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229930003802 tocotrienol Natural products 0.000 description 1
- 239000011731 tocotrienol Substances 0.000 description 1
- 235000019148 tocotrienols Nutrition 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/002—Surface-active compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
本發明係關於一種合成清潔劑皂條組成物，包括鏈長為16至18個碳原子(C16-C18)之一脂肪酸之磺化甲基酯，其中該磺化甲基酯係以該組成物之5重量%至30重量%之量存在；一助表面活性劑，選自由以下組成之群：磺基琥珀酸烷基酯、硫酸烷基酯、硫酸烷基醚、烷基聚葡萄糖苷或其組合；一脂肪醇，選自由以下組成之群：鯨蠟醇、硬脂醇或鯨蠟硬脂醇；一飽和脂肪酸；一填充劑；及一保濕劑/增濕劑。該合成清潔劑皂條組成物可用作一個人清潔、洗衣或洗碗皂條。
Description
本發明係關於合成清潔劑(syndet)皂條(合成清潔劑(synthetic detergent)皂條)組成物。更具體而言，本發明係關於含有天然源磺化甲基酯之合成清潔劑皂條組成物，該組成物可用作個人清潔或洗衣皂條。
肥皂自公元前2500年美索不達米亞文明(Mesopotamian civilization)時期存在或發明以來，在個人衛生方面發揮著重要作用。除了個人衛生之外，肥皂今天亦用於許多家庭及工業清潔過程。在目前之技術中，條皂係藉由甘油三酯之連續皂化或用鹼中和脂肪酸來工業化生產。
近幾十年來，肥皂之作用隨著時間之推移而演變，肥皂不僅用於清潔之目的，亦用於護膚。肥皂有望產生豐富的乳脂狀泡沫，從而提供極佳之清潔效果。同時，消費者亦期望肥皂能提供增濕或保濕效果，以防止皮膚在清潔後變乾，並保護皮膚免受對皮膚有害之外部影響。因此，條皂製造商不斷尋找新的成分來滿足消費者日益增長之需求及期望。
市場上可購得之高pH鹼性肥皂僅含有脂肪酸鹽及視情況游離脂肪酸，不能提供預期之護膚及清潔特性。由於該等肥皂化學性質苛刻(高pH)，其可能會對消費者之皮膚造成刺激及開裂效果。因此，行業中引入了另一種類型之條皂，即組合皂條或組合肥皂以最大化清潔效果，同時最小化刺激。除脂肪酸鹽外，組合肥皂亦使用合成表面活性劑之組合，例如椰油基羥乙基磺酸鈉或磺基琥珀酸鈉，以促進皮膚溫和。組合肥皂含有脂肪酸鹽，比傳統肥皂刺激性小，但不如合成清潔劑皂條溫和。
合成清潔劑皂條(Syndet bars或synthetic detergent bars)係一種新型之無皂清潔皂條，由具有清潔特性之不同表面活性劑或表面張力活性劑之組合構成。除雜質外，合成清潔劑皂條亦不含脂肪酸鹽，且僅含合成表面活性劑。合成表面活性劑通常來源於天然來源之礦物油、植物油或動物脂肪，因此已知所生產之合成清潔劑皂條係溫和的，並且作為個人清潔皂條或潔膚皂條係有益的。此外，合成清潔劑皂條通常具有中性pH，防止皮膚刺激。
工業上可用之合成清潔劑皂條通常由椰油基羥乙基磺酸鈉製成。由於椰油基羥乙基磺酸鈉廣泛用於製造合成清潔劑皂條，此成分之價格在工業上亦變得過高。現有技術中存在許多與由椰油基羥乙基磺酸鈉製成之合成清潔劑皂條組成物相關之技術。例如，美國專利第US 5691287號揭示一種低刺激性清潔皂條組成物，其含有佔清潔皂條之重量20%至35%之椰油基羥乙基磺酸鈉。此組成物亦含有脂肪酸量相對較低之脂肪醇。除了低刺激效果之外，鑒於清潔皂條組成物之清潔或軟化效果，文件中未揭示清潔皂條組成物之效能。由於使用椰油基羥乙基磺酸鈉作為主要成分，此清潔皂條之製造成本相對較高。此外，椰油基羥乙基磺酸鈉亦視為溫和表面活性劑，且可能不會產生合意清潔。
SME，亦稱為α-磺基脂肪酸甲基酯或甲基酯磺酸鹽(methyl ester sulfonate; MES)，近年來越來越多地用作表面活性劑。SME代表一類陰離子表面活性劑，適用於各種工業應用，包括洗衣清潔劑及洗碗清潔劑。已知SME源自諸如棕櫚油等天然可再生資源，可生物降解，且視為綠色替代性表面活性劑。由於該等可再生特性，SME逐漸成為更有吸引力之選擇，作為表面活性劑納入某些合成清潔劑配方中。因此，有限數量之皂條製造技術已開始使用SME替代椰油基羥乙基磺酸鈉作為皂條組成物之主要成分。
作為一個實例，美國專利公開案第2007004611號揭示適用於個人清潔或清潔劑皂條之組成物，該皂條亦稱為「皂粒」，含有SME作為主要表面活性劑。此組成物亦包括二級表面活性劑，如磺基琥珀酸鹽及硫酸烷基酯。然而，所揭示之組成物含有肥皂、較佳牛油及/或椰子皂作為主要成分。文件中亦指出，該組成物係前驅物清潔或洗衣皂條，具有改善之硬度、改善之抗擦傷性、降低之磨損率及在消費者使用期間減少之糊狀物形成。該文件未揭示任何改善之增濕或軟化效果。此含牛油及/或椰子皂之皂條組成物視為組合皂條組成物。此文件亦指出，合成清潔劑皂條通常具有較差之物理特性，並且大多由難以製造之溫和表面活性劑製成。
在先前技術中沒有提供關於任何特定之合成清潔劑皂條組成物之教示，該組成物含有長碳鏈SME作為基本成分，該組成物可以產生具有改進之軟化效果以及相當清潔效能之合成清潔劑皂條。因此，業內期望一種改進之基於SME之合成清潔劑皂條組成物。
本發明之一個目標係提供合成清潔劑皂條組成物，該組成物含有SME作為提供具有改善軟化效果之天然溫和清潔產品之基本成分，該產品可用作個人清潔、洗衣或洗碗之清潔及護膚產品。
本發明旨在提供基於SME之合成清潔劑皂條組成物，與基於椰油基羥乙基磺酸鈉之合成清潔劑皂條相比，該組成物提供改進之軟化效果及相當之清潔效能。基於SME之合成清潔劑皂條組成物亦應降低生產成本，並對消費者而言係成本有效的。
本發明全部或部分滿足了至少一個前述目標，其中本發明之一個實施例描述一種合成清潔劑皂條或合成清潔劑皂條組成物，其包括鏈長為16至18個碳原子(C16-C18)之脂肪酸之SME，其中SME以組成物之5重量%至30重量%之量存在；助表面活性劑，選自由以下組成之群：磺基琥珀酸烷基酯、硫酸烷基酯、硫酸烷基醚或其組合；脂肪醇，選自由以下組成之群：鯨蠟醇、硬脂醇或鯨蠟硬脂醇；飽和脂肪酸；填充劑；及保濕劑/增濕劑。
在本說明書中，以下術語具有下文作為陰離子表面活性劑指配之含義：
「磺基琥珀酸烷基酯」係磺基琥珀酸鹽型陰離子表面活性劑，包括具有式M+
(O3
SCH(CO2
R1
)CH2
CO2
R2
)-
之磺基琥珀酸酯，其中M+
係陽離子，包括鹼金屬陽離子如鈉Na+
，且其中R1
係氫H，且R2
係烷基，或其中R1
及R2
皆為烷基。
「硫酸烷基酯」係具有官能基結構R-O-SO3 -
之有機硫酸鹽，其中R係有機殘基，包括烷基。
「硫酸烷基醚」 (alkyl ether sulfate; AES)係具有通式RO(CH2
CH2
O)n
SO3
M之硫酸烷基酯之特定基團，其中R表示具有8-18個碳原子之烷基，n表示平均加成莫耳數，例如約2-10，且M表示產生水溶性鹽之陽離子，該等水溶性鹽包括以化妝品成分國際命名(International Nomenclature of Cosmetic Ingredient; INCI)名稱已知之化合物，例如月桂基聚氧乙烯醚硫酸鈉(sodium laureth sulfate; SLES) (月桂基醚硫酸鈉(sodium lauryl ether sulfate SLES)之公認縮寫)、癸基醚硫酸銨等。
根據本發明之較佳實施例，SME係以化合物之重量計含有55%至99%之C16 SME及45%至1%之C18 SME之化合物。
根據本發明之另一實施例，助表面活性劑係以組成物之1重量%至40重量%之量存在。在某些實施例中，助表面活性劑可為磺基琥珀酸烷基酯，例如月桂基磺基琥珀酸二鈉；或硫酸烷基酯，例如月桂基硫酸鈉(sodium lauryl sulfate; SLS)、月桂基硫酸鉀或其組合；或硫酸烷基醚，例如月桂基醚硫酸鈉(sodium lauryl ether sulfate; SLES)。
本發明之另一實施例揭示脂肪醇係以組成物之1重量%至30重量%之量存在。
本發明之另一實施例揭示飽和脂肪酸係以組成物之1重量%至30重量%之量存在。較佳地，飽和脂肪酸可為硬脂酸、棕櫚酸、月桂酸或其任兩者或更多者之組合。
本發明之另一實施例揭示填充劑係以組成物之1重量%至40重量%之量存在。在某些實施例中，填充劑係小麥澱粉、玉米澱粉、稻米澱粉、大麥澱粉、燕麥、木薯澱粉、滑石、硫酸鈉或其任兩者或更多者之組合。
根據本發明之實施例，保濕劑/增濕劑係以組成物之1重量%至10重量%之量存在。較佳地，保濕劑/增濕劑係甘油、水、尿素、乳酸鈉或其任兩者或更多者之組合。為了方便起見，水在此處分組，儘管其更像一種溶劑，並且經添加以將配方補足至100%。
本發明之其他實施例揭示合成清潔劑皂條組成物進一步包括組成物之1重量%至15重量%之量之防裂劑。例如，防裂劑可為氫化植物油、聚乙二醇或其組合。
本發明之當前較佳實施例由新穎之特徵及部件之組合組成，該等特徵及部件在下文中在附圖中充分描述或圖解說明，並且在所附申請專利範圍中特別指出；應當理解，熟習此項技術者可以對細節進行各種改變，但不脫離本發明之範圍或犧牲本發明之任何優點。
在下文中，將根據本發明之較佳實施例並參考隨附描述及附圖來描述本發明。然而，應當理解，將描述限於本發明之較佳實施例及附圖僅僅係為了便於討論本發明，並且可以預見，熟習此項技術者可以在不脫離所附申請專利範圍之範圍下設計各種修改。
本發明揭示合成清潔劑皂條組成物，其包括鏈長為16至18個碳原子(C16-C18)之脂肪酸之SME，其中SME係以組成物之5重量%至30重量%之量存在；助表面活性劑，選自由以下組成之群：磺基琥珀酸烷基酯、硫酸烷基酯、硫酸烷基醚或其組合；脂肪醇，選自由以下組成之群：鯨蠟醇、硬脂醇或鯨蠟硬脂醇；飽和脂肪酸；填充劑；及保濕劑/增濕劑。
SME在合成清潔劑皂條組成物中用作表面活性劑，其提供清潔以及對皮膚之有益效果，例如天然、溫和及軟化效果。術語「表面活性劑」或「表面活性劑系統」係指能夠降低液體及氣體之間或兩種液體之間或液體及固體之間之表面張力或界面張力之一或多種化合物。因此，表面活性劑可用作潤濕劑、乳化劑或清潔劑。
根據本發明之實施例，用於合成清潔劑皂條組成物中之SME係鏈長為16至18個碳原子之脂肪酸之長碳鏈SME (即C16-C18 SME)。C16 SME及C18 SME分別具有如下式(I)及式(II)中所顯示之分子結構：
(I)
(II)
C16及C18 SME皆可源自天然來源，如植物油(plant oil) (植物油(vegetable oil))或動物脂肪，包括棕櫚油。具體而言，C16 SME可自棕櫚酸中獲得；而C18 SME可自棕櫚油之硬脂酸中獲得。該兩種SME皆係經由甲基酯磺化獲得。
如前述描述所述，SME係以組成物之約5重量%至30重量%之量存在於合成清潔劑皂條組成物中。例如，其可以組成物之5重量%至25重量%、或10重量%至25重量%、或15重量%至20重量%之量存在。
在某些實施例中，用於合成清潔劑皂條組成物中之SME係含有特定組合比率之C16 SME及C18 SME之化合物(摻合物或混合物)。較佳地，以化合物之重量計，本發明之SME化合物可含有約55%至99%之C16 SME及約1%至45%之C18 SME。例如，SME化合物可為60%至90%之C16 SME及10%至40% C18 SME之摻合物或65%至85%之C16 SME及15%至35% C18 SME之摻合物。或者，SME化合物亦可為90%至99%之C16 SME及1%至10% C18 SME之摻合物。
除SME作為表面活性劑之外，本發明之合成清潔劑皂條組成物亦含有助表面活性劑，其可以組成物之約1重量%至40重量%之量存在。在某些實施例中，助表面活性劑可為磺基琥珀酸烷基酯，例如月桂基磺基琥珀酸二鈉；或硫酸烷基酯，例如SLS、月桂基硫酸鉀或其組合；或硫酸烷基醚，例如SLES；或烷基聚葡萄糖苷。不希望受限於理論，在助表面活性劑存在下，預期SME在合成清潔劑皂條之清潔方面產生協同效應。應當理解，若加入SLES，應當以少量(例如，組成物之2重量%至3重量%)使用，以防止所產生之合成清潔劑皂條之任何不期望特性，例如防止皂條在使用時變得油膩及黏稠。
將助表面活性劑添加至組成物以提供良好的清潔及起泡特性。在某些實施例中，主要表面活性劑及助表面活性劑之組合亦能夠減少皮膚刺激。例如，將綠色表面活性劑(例如烷基聚葡萄糖苷(alkyl polyglucoside; APG))添加至直鏈烷基苯磺酸鹽(linear alkylbenzene sulfonate; LAS)可減少LAS之刺激。或者，APG及SLES之間以特定比率組合亦可減少SLES之刺激。
根據本發明之另一實施例，合成清潔劑皂條組成物亦含有脂肪醇，其係以組成物之約1重量%至30重量%之量存在。例如，脂肪醇可以組成物之5重量%至20重量%之量存在。如前述描述中所述，用於本發明中之脂肪醇可為鯨蠟醇、硬脂醇或鯨蠟硬脂醇(即鯨蠟醇及硬脂醇之混合物)。脂肪醇在合成清潔劑皂條組成物中起結構劑及潤滑劑之功能。由於脂肪醇亦起防裂劑之作用，脂肪醇(例如鯨蠟硬脂醇)及SME之間之組合能夠為合成清潔劑皂條提供改善之軟化及防裂效果。
除脂肪醇外，本發明之合成清潔劑皂條組成物亦含有飽和脂肪酸，其亦起增強脂肪醇作用之結構劑及潤滑劑之功能。在某些實施例中，納入長鏈脂肪酸亦可有助於硬化合成清潔劑皂條。較佳地，飽和脂肪酸係以組成物之約1重量%至30重量%之量存在。根據本發明之一個實施例，飽和脂肪酸可為硬脂酸、棕櫚酸、月桂酸或其任兩者或更多者之組合。可用於合成清潔劑皂條組成物中之一種較佳飽和脂肪酸係三壓硬脂酸。在某些實施例中，三壓硬脂酸可以組成物之5重量%至20重量%之量存在。
根據本發明之另一實施例，合成清潔劑皂條組成物亦含有填充劑。填充劑可以組成物之約1重量%至40重量%之量存在。具體而言，填充劑可以組成物之10重量%至30重量%之量存在。在某些實施例中，填充劑係小麥澱粉、玉米澱粉、稻米澱粉、大麥澱粉、燕麥、木薯澱粉、滑石、硫酸鈉或其任兩者或更多者之組合。
根據本發明之另一實施例，保濕劑/增濕劑係以組成物之約1重量%至10重量%之量存在。例如，保濕劑/增濕劑可以組成物之約1重量%至10重量%之量存在。較佳地，保濕劑/增濕劑係甘油、水、尿素、乳酸鈉或其任兩者或更多者之組合。保濕劑/增濕劑(例如甘油及水)亦可用作黏合劑，其黏結性地黏合合成清潔劑皂條組成物之組成成分以形成皂條。
本發明之其他實施例揭示合成清潔劑皂條組成物進一步包括組成物之1重量%至15重量%之量之防裂劑。例如，防裂劑可為氫化植物油、聚乙二醇或其組合。較佳地，防裂劑可為氫化蓖麻油。合成清潔劑皂條有時可能難以成型。為增加合成清潔劑皂條在不同應用中之硬度，可增加氫化植物油之重量百分比。
成分之組合不需要調節二鹽含量，但由於特定配方及成分之特定摻合物，其能夠提供硬條皂。本發明之合成清潔劑皂條基本上不含肥皂，溫和並產生乳脂狀泡沫。因此，適合消費者用作個人清潔皂條。由於其低pH及對皮膚溫和，亦可用作動物(如寵物)之清潔劑。在某些實施例中，可向動物清潔產品中添加額外成分，例如抗細菌劑及半胱胺酸。其亦可用於工業或家庭洗衣、洗碗或硬表面清潔。
在本發明之某些實施例中，合成清潔劑皂條組成物可進一步包括防腐劑、穩定劑、調味劑、著色劑或其任兩者或更多者之組合。作為亦提供護膚效果之個人清潔皂條，合成清潔劑皂條組成物可進一步包括添加劑，例如皮膚調理劑、皮膚增濕劑、皮膚保濕劑、控油劑、舒緩劑或增白劑。
根據本發明之另一實施例，合成清潔劑皂條組成物可進一步包括營養組分，例如維生素及礦物質、天然來源之精油、生物類黃酮及抗氧化劑，其保護皮膚免於因清潔效應而變乾，藉由給皮膚留下保護層來防止皮膚受到外部損傷，或改善皮膚之整體衛生及健康。例如，維生素及礦物質可為維生素E (生育三烯酚、生育酚或其組合)、維生素A、二氧化矽、鎂、鈣、鉀、鋅、銅、硒、鉻及硫。在某些實施例中，可添加二氧化鈦以增加合成清潔劑皂條之白度，並為皂條提供均勻之顏色外觀。
合成清潔劑皂條組成物可以固體條皂之形式或任何其他合適之固體形式(如皂粒或皂片)製備。在實例中進一步詳細說明了此基於SME之合成清潔劑皂條之示例性配方。合成清潔劑皂條可經由粉末及液體成分之簡單混合製程由各種成分產生。該製程包括在冷過程中混合液體成分之步驟。液體成分包括保濕劑/增濕劑(例如甘油及水)及聚乙二醇。然後在高溫下熔化固體成分，包括SME、助表面活性劑、脂肪醇、飽和脂肪酸及填充劑。熔化成分之熱液體及來自冷過程之冷液體可以在螺桿混合單元中在熱溫度下混合以形成糊狀物，該糊狀物在冷滾筒上經受剝落過程。獲得之薄片可經包裝以形成皂條。
可測試基於SME之合成清潔劑皂條與市售合成清潔劑皂條或組合皂條相比之效能。在實例2中進一步詳細說明了比較測試之實例，即皂條效能之F-測試及T-測試。如表4及5中之比較數據所顯示，基於SME之合成清潔劑皂條顯示提供與市售合成清潔劑皂條或市售基於月桂醯羥乙基磺酸鈉之組合皂相當之清潔，同時與該等市售皂條相比，產生了改善之軟化效果。實驗數據顯示，本發明之合成清潔劑皂條溫和且刺激性低。使用合成清潔劑皂條及洗滌後，皮膚不會感覺乾燥，且角質層(皮膚之最上層)完好無損。不希望受限於理論，據信合成清潔劑皂條中活性成分之組合可幫助角質層保持水分，從而顯示出皮膚軟化之效果。實例 實例 1 合成清潔劑皂條配方
基於SME之合成清潔劑皂條可基於如表1-3中所顯示之配方製備。表 1 
表 2 
表 3 
實例 2 合成清潔劑皂條配方之 F- 測試及 T- 測試
實施統計學測試，包括F-測試及T-測試，以評估基於SME之合成清潔劑皂條組成物之效能。將基於表1之配方製備之SME合成清潔劑皂條用作測試樣品，與市售合成清潔劑皂條(含有月桂基磺基琥珀酸二鈉作為主要成分)及組合皂(含有月桂醯羥乙基磺酸鈉作為主要成分)相比，市售合成清潔劑皂條及組合皂條皆不含SME。該等測試樣品係基於肥皂效能參數來評估，該等效能參數包括可漂洗性、光滑度、軟化、潤滑性及起泡性。具體而言，要求所有受試者(即參與小組測試之參與者)填寫一份包含所有該等效能參數之問卷，並要求該等受試者以定量方式評價不同樣品。基於SME之合成清潔劑皂條及商業合成清潔劑皂條之間之F-測試及T-測試之比較數據如表4所示；而基於SME之合成清潔劑皂條及商業組合皂條之間之F-測試及T-測試之比較數據如表5所示。表 4 
表5 
F-測試側重於樣品數據之方差分析，而T-測試係指測試樣品平均值之假設，以評估樣品集是否存在顯著差異。基於表4及5中所示之測試結果，證實基於SME之合成清潔劑皂條之效能與市售組合皂一樣良好，同時與市售合成清潔劑皂條相比提供改進之軟化效果。T-測試結果表明軟化效果之該改善係顯著的。
無
無
國內寄存資訊 (請依寄存機構、日期、號碼順序註記)
無
國外寄存資訊 (請依寄存國家、機構、日期、號碼順序註記)
無
Claims (16)
- 一種合成清潔劑皂條組成物，包括： 鏈長為16至18個碳原子(C16-C18)之一脂肪酸之磺化甲基酯，其中該磺化甲基酯係以該組成物之5重量%至30重量%之量存在；一助表面活性劑，其選自由以下組成之群：磺基琥珀酸烷基酯、硫酸烷基酯、硫酸烷基醚或其組合；一脂肪醇，其選自由以下組成之群：鯨蠟醇、硬脂醇或鯨蠟硬脂醇；一飽和脂肪酸；一填充劑；及一保濕劑/增濕劑。
- 如請求項1所述之組成物，其中該磺化甲基酯係一化合物，以該化合物之重量計含有55%至99%之C16磺化甲基酯及1%至45%之C18磺化甲基酯。
- 如請求項1或2所述之組成物，其中該助表面活性劑係以該組成物之1重量%至40重量%之量存在。
- 如請求項1或2所述之組成物，其中該磺基琥珀酸烷基酯係月桂基磺基琥珀酸二鈉。
- 如請求項1或2所述之組成物，其中該硫酸烷基酯係月桂基硫酸鈉、月桂基硫酸鉀或其組合。
- 如請求項1或2所述之組成物，其中該硫酸烷基醚係月桂基醚硫酸鈉。
- 如請求項1或2所述之組成物，其中該脂肪醇係以該組成物之1重量%至30重量%之量存在。
- 如請求項1或2所述之組成物，其中該飽和脂肪酸係以該組成物之1重量%至30重量%之量存在。
- 如請求項1或2所述之組成物，其中該飽和脂肪酸係硬脂酸、棕櫚酸、月桂酸或其任兩者或更多者之組合。
- 如請求項1或2所述之組成物，其中該填充劑係以該組成物之1重量%至40重量%之量存在。
- 如請求項1或2所述之組成物，其中該填充劑係小麥澱粉、玉米澱粉、稻米澱粉、大麥澱粉、燕麥、木薯澱粉、滑石、硫酸鈉或其任兩者或更多者之組合。
- 如請求項1或2所述之組成物，其中該保濕劑/增濕劑係以該組成物之1重量%至10重量%之量存在。
- 如請求項1或2所述之組成物，其中該保濕劑/增濕劑係甘油、水、尿素、乳酸鈉或其任兩者或更多者之組合。
- 如請求項1或2所述之組成物，進一步包括該組成物之1重量%至15重量%之量之一防裂劑。
- 如請求項14所述之組成物，其中該防裂劑係一氫化植物油、聚乙二醇或其組合。
- 如請求項1所述之組成物，其中該助表面活性劑基團進一步包括烷基聚葡萄糖苷用於選擇。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MYPI2018702242 | 2018-06-07 | ||
| MYPI2018702242A MY186674A (en) | 2018-06-07 | 2018-06-07 | A syndet bar composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW202000883A true TW202000883A (zh) | 2020-01-01 |
| TWI875699B TWI875699B (zh) | 2025-03-11 |
Family
ID=68770407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108119680A TWI875699B (zh) | 2018-06-07 | 2019-06-06 | 合成清潔劑皂條組成物 |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US11932826B2 (zh) |
| EP (1) | EP3810738B1 (zh) |
| JP (1) | JP7263399B2 (zh) |
| KR (1) | KR102798604B1 (zh) |
| CN (1) | CN112313320B (zh) |
| AU (1) | AU2019283637B2 (zh) |
| CA (1) | CA3102239A1 (zh) |
| EC (1) | ECSP20079152A (zh) |
| IL (1) | IL278738B2 (zh) |
| MX (1) | MX2020012983A (zh) |
| MY (1) | MY186674A (zh) |
| NZ (1) | NZ771582A (zh) |
| PH (1) | PH12020552057A1 (zh) |
| PL (1) | PL3810738T3 (zh) |
| SG (1) | SG11202011457WA (zh) |
| TW (1) | TWI875699B (zh) |
| WO (1) | WO2019235911A1 (zh) |
| ZA (1) | ZA202007644B (zh) |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4565647B1 (en) | 1982-04-26 | 1994-04-05 | Procter & Gamble | Foaming surfactant compositions |
| JPS5984995A (ja) * | 1982-11-04 | 1984-05-16 | 味の素株式会社 | 洗浄剤組成物 |
| US5017302A (en) | 1989-08-15 | 1991-05-21 | Colgate-Palmolive Company | Bar soap having improved resistance to cracking |
| HU212980B (en) * | 1990-09-28 | 1997-01-28 | Procter & Gamble | Zeolite/layered silicate built detergent composition containing polyhydroxy fatty acid amides |
| US5227086A (en) * | 1992-03-20 | 1993-07-13 | The Procter & Gamble Company | Framed skin pH cleansing bar |
| AU5678194A (en) * | 1992-11-30 | 1994-06-22 | Procter & Gamble Company, The | High sudsing detergent compositions with specially selected soaps |
| WO1995010585A1 (en) * | 1993-10-12 | 1995-04-20 | Stepan Company | Liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters, and anionic surfactants |
| US5691287A (en) | 1995-12-21 | 1997-11-25 | S. C. Johnson & Son, Inc. | Low irritation cleansing bar |
| GB9717723D0 (en) * | 1997-08-21 | 1997-10-29 | Ici Plc | Synthetic detergent formulations |
| US5965508A (en) * | 1997-10-21 | 1999-10-12 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids |
| US6458751B1 (en) * | 2001-07-23 | 2002-10-01 | Unilever Home & Personal Care Usa | Skin cleansing bar comprising a fatty alcohol with low mush |
| JP2003096489A (ja) * | 2001-09-25 | 2003-04-03 | Tsumura & Co | 固形石鹸 |
| MY148956A (en) | 2002-01-31 | 2013-06-14 | Stepan Co | Soap bar compositions comprising alpha sulfonated alkyl esters or sulfonated fatty acid and process for producing the same |
| CA2474704A1 (en) * | 2002-01-31 | 2003-08-07 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and polyhydridic alcohols and process for producing same |
| US20050153853A1 (en) * | 2002-01-31 | 2005-07-14 | Stepan Company | Soap bar compositions comprising alpha sulfonated alkyl ester or sulfonated fatty acid and synthetic surfactant and processes for producing same |
| BRPI0413620A (pt) * | 2003-08-27 | 2006-10-17 | Unilever Nv | composição de limpeza sólida moldada em fusão livre de sabão que não encolhe, e, processo para fornecer uma composição de limpeza sólida moldada em fusão |
| US7109154B2 (en) * | 2004-04-13 | 2006-09-19 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Combination toilet bar composition |
| US20060003908A1 (en) * | 2004-07-01 | 2006-01-05 | Brennan Michael A | Mild synthetic detergent toilet bar composition |
| CN101784651B (zh) | 2007-08-17 | 2012-08-08 | 罗迪亚亚太有限公司 | 结构化的肥皂组合物 |
| MX2012005154A (es) * | 2009-11-03 | 2012-09-12 | Stepan Co | Sulfometilsuccinatos, procedimiento para formar los mismos y composiciones que los contienen. |
| MX355621B (es) * | 2011-09-20 | 2018-04-25 | Henkel IP & Holding GmbH | Formulaciones de limpieza con solubilidad tensioactiva mejorada y metodos para produccion y uso de las mismas. |
| CN103242992B (zh) * | 2013-05-02 | 2015-06-03 | 广州立白企业集团有限公司 | 一种含功能有色粒子洗衣皂及其生产方法 |
| DE102014224216A1 (de) * | 2014-11-27 | 2016-06-02 | Henkel Ag & Co. Kgaa | Kosmetische Stückseifen enthaltend Seife und Mikroemulsionen |
| MY179544A (en) * | 2017-07-19 | 2020-11-10 | Kl Kepong Oleomas Sdn Bhd | A surfactant system |
-
2018
- 2018-06-07 MY MYPI2018702242A patent/MY186674A/en unknown
-
2019
- 2019-04-24 SG SG11202011457WA patent/SG11202011457WA/en unknown
- 2019-04-24 US US15/734,802 patent/US11932826B2/en active Active
- 2019-04-24 PL PL19816126.7T patent/PL3810738T3/pl unknown
- 2019-04-24 NZ NZ771582A patent/NZ771582A/en unknown
- 2019-04-24 CN CN201980033172.XA patent/CN112313320B/zh active Active
- 2019-04-24 MX MX2020012983A patent/MX2020012983A/es unknown
- 2019-04-24 EP EP19816126.7A patent/EP3810738B1/en active Active
- 2019-04-24 AU AU2019283637A patent/AU2019283637B2/en active Active
- 2019-04-24 CA CA3102239A patent/CA3102239A1/en active Pending
- 2019-04-24 WO PCT/MY2019/050029 patent/WO2019235911A1/en not_active Ceased
- 2019-04-24 KR KR1020207037225A patent/KR102798604B1/ko active Active
- 2019-04-24 IL IL278738A patent/IL278738B2/en unknown
- 2019-04-24 JP JP2020567851A patent/JP7263399B2/ja active Active
- 2019-06-06 TW TW108119680A patent/TWI875699B/zh active
-
2020
- 2020-12-01 PH PH12020552057A patent/PH12020552057A1/en unknown
- 2020-12-08 ZA ZA2020/07644A patent/ZA202007644B/en unknown
- 2020-12-09 EC ECSENADI202079152A patent/ECSP20079152A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IL278738A (zh) | 2021-03-01 |
| JP7263399B2 (ja) | 2023-04-24 |
| US20210230507A1 (en) | 2021-07-29 |
| CA3102239A1 (en) | 2019-12-12 |
| WO2019235911A1 (en) | 2019-12-12 |
| SG11202011457WA (en) | 2020-12-30 |
| CN112313320B (zh) | 2022-06-07 |
| NZ771582A (en) | 2023-07-28 |
| PH12020552057A1 (en) | 2021-05-31 |
| BR112020024845A2 (pt) | 2021-03-02 |
| EP3810738A4 (en) | 2022-03-09 |
| US11932826B2 (en) | 2024-03-19 |
| TWI875699B (zh) | 2025-03-11 |
| KR20210019458A (ko) | 2021-02-22 |
| CN112313320A (zh) | 2021-02-02 |
| ZA202007644B (en) | 2022-04-28 |
| IL278738B2 (en) | 2024-08-01 |
| EP3810738A1 (en) | 2021-04-28 |
| JP2021527144A (ja) | 2021-10-11 |
| IL278738B1 (en) | 2024-04-01 |
| ECSP20079152A (es) | 2021-01-29 |
| MY186674A (en) | 2021-08-05 |
| EP3810738C0 (en) | 2024-08-28 |
| PL3810738T3 (pl) | 2024-11-18 |
| KR102798604B1 (ko) | 2025-04-23 |
| AU2019283637A1 (en) | 2021-01-21 |
| AU2019283637B2 (en) | 2021-10-14 |
| MX2020012983A (es) | 2021-02-16 |
| EP3810738B1 (en) | 2024-08-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5409706A (en) | Anhydrous foaming composition containing low concentrations of detergents and high levels of glycerin and emollients such as oils and esters | |
| CA2930724C (en) | Soap bar formulations with improved skin softness comprising nonionic polymer structuring system | |
| US11744792B2 (en) | Solid soap | |
| Friedman | Chemistry, formulation, and performance of syndet and combo bars | |
| EP1709147B1 (en) | Fatty acid soap / fatty acid bars which process well and have good lather | |
| CN105874051A (zh) | 皂条 | |
| TWI875699B (zh) | 合成清潔劑皂條組成物 | |
| RU2800638C2 (ru) | Композиция кускового синдета | |
| HK40037566A (zh) | 合成洗涤剂棒组合物 | |
| HK40037566B (zh) | 合成洗涤剂棒组合物 | |
| JP4918327B2 (ja) | クレンジング組成物 | |
| BR112020024845B1 (pt) | Composição de barra syndet | |
| JP2005171219A (ja) | 米糠油由来化粧品原料組成物 | |
| CN107002001B (zh) | 具有苯氧乙醇的清洁条 | |
| US20250059464A1 (en) | Process for preparing 'soap-free', 'sulphate-free' and 'grit-free' solid cleansing compositions | |
| JPH03277698A (ja) | 固形洗浄剤 |